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CN110627521A - Lightweight high-strength ceramsite prepared from slate as raw material and preparation method thereof - Google Patents

Lightweight high-strength ceramsite prepared from slate as raw material and preparation method thereof Download PDF

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CN110627521A
CN110627521A CN201911057987.XA CN201911057987A CN110627521A CN 110627521 A CN110627521 A CN 110627521A CN 201911057987 A CN201911057987 A CN 201911057987A CN 110627521 A CN110627521 A CN 110627521A
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slate
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raw material
strength ceramsite
strength
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CN110627521B (en
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路萍
周立发
焦尊生
张亚芹
高春云
郝昱宇
刘伟刚
罗婷婷
郭京哲
李阳阳
陈永振
巨浩波
白勇
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NORTHWEST UNIVERSITY
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1324Recycled material, e.g. tile dust, stone waste, spent refractory material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1328Waste materials; Refuse; Residues without additional clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/135Combustion residues, e.g. fly ash, incineration waste
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/135Combustion residues, e.g. fly ash, incineration waste
    • C04B33/1352Fuel ashes, e.g. fly ash
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/138Waste materials; Refuse; Residues from metallurgical processes, e.g. slag, furnace dust, galvanic waste
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/009Porous or hollow ceramic granular materials, e.g. microballoons
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/02Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208Calcium oxide or oxide-forming salts thereof, e.g. lime
    • C04B2235/321Dolomites, i.e. mixed calcium magnesium carbonates
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

本发明公开了一种以板岩为原料所制备的轻质高强陶粒及其制备方法,涉及建筑材料的制备技术领域,按质量百分数其原料配比为板岩50%‑90%,粉煤灰5%‑30%,金属镁渣2%‑6%,油页岩半焦1%‑10%,白云石1%‑4%。本发明中以板岩为原料的轻质高强陶粒中添加的粉煤灰既可降低其中SiO2含量又可以增加Al2O3含量,不仅可以减少板岩尾矿堆积对大量土地的占用,减轻它们对生态、环境以及人类健康的严重威胁,也解决了以往市场上陶粒制品本身所存在的高堆积密度、高吸水率和低筒压强度等问题,提高了对板岩尾矿、金属镁渣、油页岩半焦和粉煤灰的利用价值,使固体废弃物变废为宝,适合工业化生产。The invention discloses a light-weight high-strength ceramsite prepared from slate as a raw material and a preparation method thereof, and relates to the technical field of preparation of building materials. According to the mass percentage, the raw material ratio is 50%-90% of slate, pulverized coal Ash 5%‑30%, metal magnesium slag 2%‑6%, oil shale semi-coke 1%‑10%, dolomite 1%‑4%. In the present invention, the fly ash added to the lightweight high-strength ceramsite with slate as raw material can both reduce the SiO2 content and increase the Al2O3 content, which can not only reduce the occupation of a large amount of land by the accumulation of slate tailings, and reduce the They pose a serious threat to ecology, the environment and human health. They also solve the problems of high bulk density, high water absorption and low cylinder compressive strength that existed in the ceramsite products on the market in the past, and improve the protection against slate tailings and metal magnesium slag. , The utilization value of oil shale semi-coke and fly ash, turning solid waste into treasure, suitable for industrial production.

Description

一种以板岩为原料所制备的轻质高强陶粒及其制备方法Lightweight high-strength ceramsite prepared from slate as raw material and preparation method thereof

技术领域technical field

本发明涉及建筑材料的制备技术领域,更具体的涉及一种以板岩为原料所制备的轻质高强陶粒及其制备方法。The invention relates to the technical field of preparation of building materials, in particular to a light-weight high-strength ceramsite prepared from slate as a raw material and a preparation method thereof.

背景技术Background technique

陶粒作为一种轻集料,具有密度小、强度高、吸水率大、保温、隔热、抗震、耐火等特点,它的用途广泛,可取代普通砂石配制轻集料混凝土,用作水处理滤料、吸附剂、透水路面材料,还可用作农业、园林中无土栽培的培养基以及桥面板、空心非承重砌块或混凝土构件等建材原料。现有技术中,公知的陶粒一般采用粘土、生物污泥等为主要原料,通过高温焙烧、膨化而成,由于原料来源所限,公知陶粒制品在实际制备过程中还存在有环境污染较大、生产成本较高及能耗较高等诸多问题,且制品本身的筒压强度也较低(3-5MPa)。As a light aggregate, ceramsite has the characteristics of low density, high strength, high water absorption, heat preservation, heat insulation, shock resistance, and fire resistance. It can also be used as a medium for soilless cultivation in agriculture and gardens, as well as building materials such as bridge decks, hollow non-load-bearing blocks or concrete components. In the prior art, the known ceramsite generally uses clay, biological sludge, etc. as the main raw materials, and is formed by high-temperature roasting and puffing. Due to the limited source of raw materials, the known ceramsite products still have serious environmental pollution in the actual preparation process. There are many problems such as large size, high production cost and high energy consumption, and the cylinder compressive strength of the product itself is also low (3-5MPa).

板岩作为一种建筑装饰材料,已被大量开采及利用。但板岩的开采成品率极低,只有8-10%。在板岩的开采及生产过程中,废弃物高达90%,尽管采取了循环水处理及二次沉积,铢积寸累,废料堆积如山,严重占用大量耕地。但是板岩中含有SiO2、Al2O3、Fe2O3、MgO等化学成分,如表1所示。除此之外,板岩具有较大的烧失量。As a building decoration material, slate has been exploited and utilized in large quantities. But the mining yield of slate is extremely low, only 8-10%. In the process of mining and production of slate, the waste is as high as 90%. Despite the adoption of circulating water treatment and secondary sedimentation, the accumulation of waste accumulates like a mountain, seriously occupying a large amount of cultivated land. However, slate contains chemical components such as SiO 2 , Al 2 O 3 , Fe 2 O 3 , and MgO, as shown in Table 1. In addition, slate has a larger loss on ignition.

表1板岩化学组成成分及含量(%)Table 1 Slate chemical composition and content (%)

SiO<sub>2</sub>SiO<sub>2</sub> Al<sub>2</sub>O<sub>3</sub>Al<sub>2</sub>O<sub>3</sub> Fe<sub>2</sub>O<sub>3</sub>Fe<sub>2</sub>O<sub>3</sub> MgOMgO CaOCaO K<sub>2</sub>OK<sub>2</sub>O 61.2-71.361.2-71.3 12.4-18.712.4-18.7 2.8-5.92.8-5.9 0.9-2.20.9-2.2 0.1-0.20.1-0.2 2.4-3.72.4-3.7 Na<sub>2</sub>ONa<sub>2</sub>O P<sub>2</sub>O<sub>5</sub>P<sub>2</sub>O<sub>5</sub> MnOMnO TiO<sub>2</sub>TiO<sub>2</sub> LOILOI 0.5-2.70.5-2.7 0.01-0.060.01-0.06 0.3-1.90.3-1.9 0.2-0.70.2-0.7 2.1-5.62.1-5.6

镁渣一般是镁厂冶炼金属镁时产生的固体废弃物,每生产1吨金属镁大约排出8-10吨镁渣,如何实现镁渣的资源化利用成为制约我国镁产业发展的一大主题。镁渣的主要化学成分是CaO和SiO2,其具体的化学成分如表2所示。Magnesium slag is generally a solid waste produced during the smelting of metal magnesium in magnesium factories. About 8-10 tons of magnesium slag are discharged for every ton of metal magnesium produced. How to realize the resource utilization of magnesium slag has become a major theme restricting the development of my country's magnesium industry. The main chemical composition of magnesium slag is CaO and SiO 2 , and its specific chemical composition is shown in Table 2.

表2金属镁渣半定量分析结果表(%)Table 2 Semi-quantitative analysis result table of metallic magnesium slag (%)

CaOCaO Al<sub>2</sub>O<sub>3</sub>Al<sub>2</sub>O<sub>3</sub> SiO<sub>2</sub>SiO<sub>2</sub> Fe<sub>2</sub>O<sub>3</sub>Fe<sub>2</sub>O<sub>3</sub> 55.27-61.8755.27-61.87 0.69-1.980.69-1.98 25.21-30.2325.21-30.23 3.52-4.563.52-4.56 Na<sub>2</sub>ONa<sub>2</sub>O MgOMgO K<sub>2</sub>OK<sub>2</sub>O LOILOI 0-0.080-0.08 5.34-7.865.34-7.86 0-0.280-0.28 0.4-3.760.4-3.76

油页岩半焦是油页岩经低温干馏燃烧后所得的固体产物,其化学成分如下表3所示。油页岩半焦的堆积量巨大,需要占用大量土地。除此之外,油页岩半焦含有大量重金属元素,经过雨水淋溶这些元素严重污染周围的土地、水源,从而破坏了土壤的生产能力,进而破坏了农业生产。但是油页岩半焦中含有大量的矿物成分,并具有较大的烧失量和较轻的密度。Oil shale semi-coke is a solid product obtained after low-temperature dry distillation and combustion of oil shale, and its chemical composition is shown in Table 3 below. The accumulation of oil shale semi-coke is huge and requires a lot of land. In addition, oil shale semi-coke contains a large amount of heavy metal elements. After rainwater leaching, these elements seriously pollute the surrounding land and water sources, thereby destroying the productive capacity of the soil and thus destroying agricultural production. However, oil shale semi-coke contains a large amount of mineral components, and has a larger loss on ignition and a lighter density.

表3油页岩半焦化学成分表(%)Table 3 Chemical composition of oil shale semi-coke (%)

SiO<sub>2</sub>SiO<sub>2</sub> Al<sub>2</sub>O<sub>3</sub>Al<sub>2</sub>O<sub>3</sub> Fe<sub>2</sub>O<sub>3</sub>Fe<sub>2</sub>O<sub>3</sub> MgOMgO CaOCaO K<sub>2</sub>OK<sub>2</sub>O 48.16-54.2348.16-54.23 12.98-16.2812.98-16.28 9.08-16.329.08-16.32 1.02-4.351.02-4.35 1.25-5.231.25-5.23 2.31-4.652.31-4.65 P<sub>2</sub>O<sub>5</sub>P<sub>2</sub>O<sub>5</sub> MnOMnO TiO<sub>2</sub>TiO<sub>2</sub> Na<sub>2</sub>ONa<sub>2</sub>O LOILOI 0.41-1.260.41-1.26 0-0.380-0.38 0.37-0.650.37-0.65 0.71-1.870.71-1.87 14.55-23.8414.55-23.84

粉煤灰是热电厂所排放的废渣,其化学成分如下表4所示。粉煤灰排放量巨大,如何合理使这些粉煤灰变废为宝是当前环保工作的重要任务。粉煤灰的微细颗粒飘入空气中,随气流进行远距离的输送会对环境造成区域性的污染;堆放的粉煤灰中的有毒有害物质渗透到地表水及地下水体中会造成水体污染;粉煤灰的高盐高碱性会导致土地盐碱性,影响生态环境和农业生产;粉煤灰中的重金属等有害物质经淋溶作用进入水体,或通过农作物被人体摄入后对人体健康造成严重危害。Fly ash is waste residue discharged from thermal power plants, and its chemical composition is shown in Table 4 below. Fly ash emissions are huge, how to reasonably turn these fly ash into treasures is an important task in the current environmental protection work. The fine particles of fly ash float into the air, and the long-distance transportation with the airflow will cause regional pollution to the environment; the toxic and harmful substances in the piled fly ash will infiltrate into surface water and groundwater, causing water pollution; The high salt and high alkalinity of fly ash will lead to salinity of the land, affecting the ecological environment and agricultural production; harmful substances such as heavy metals in fly ash enter the water body through leaching, or are harmful to human health after being ingested by the human body through crops. cause serious harm.

表4粉煤灰化学组成成分及含量(%)Table 4 Fly ash chemical composition and content (%)

Al<sub>2</sub>O<sub>3</sub>Al<sub>2</sub>O<sub>3</sub> SiO<sub>2</sub>SiO<sub>2</sub> Fe<sub>2</sub>O<sub>3</sub>Fe<sub>2</sub>O<sub>3</sub> K<sub>2</sub>OK<sub>2</sub>O Na<sub>2</sub>ONa<sub>2</sub>O MgOMgO CaOCaO LOILOI 12.8-33.112.8-33.1 38.1-61.738.1-61.7 4.21-10.24.21-10.2 1.23-2.561.23-2.56 0.4-2.30.4-2.3 0.7-1.40.7-1.4 5.0-24.55.0-24.5 0.7-8.10.7-8.1

发明内容Contents of the invention

本发明提供一种以板岩为原料所制备的轻质高强陶粒及其制备方法,不仅解决了陶粒制品高堆积密度、高吸水率和低筒压强度等问题,并且可以减少板岩尾矿堆积对大量土地的占用,减轻对生态、环境及人类健康的严重威胁。The invention provides a light-weight high-strength ceramsite prepared from slate as a raw material and a preparation method thereof, which not only solve the problems of high bulk density, high water absorption rate and low cylinder compressive strength of ceramsite products, but also can reduce slate tailings Accumulation occupies a large amount of land and reduces the serious threat to ecology, environment and human health.

本发明提供一种以板岩为原料的以板岩为原料所制备的轻质高强陶粒,按质量百分数其原料配比为:板岩50-90%,粉煤灰5-30%,金属镁渣2-6%,油页岩半焦1-10%,白云石1-4%。The invention provides a light-weight high-strength ceramsite prepared from slate as a raw material. The ratio of raw materials according to mass percentage is: 50-90% of slate, 5-30% of fly ash, metal Magnesium slag 2-6%, oil shale semi-coke 1-10%, dolomite 1-4%.

优选的,板岩的化学组成成分包括SiO2,Al2O3,Fe2O3,MgO,CaO,K2O,Na2O,P2O5,MnO,TiO2和LOI。Preferably, the chemical composition of the slate includes SiO 2 , Al 2 O 3 , Fe 2 O 3 , MgO, CaO, K 2 O, Na 2 O, P 2 O 5 , MnO, TiO 2 and LOI.

优选的,金属镁渣的化学组成成分包括CaO,Al2O3,SiO2,Fe2O3,Na2O,MgO,F和K2O。Preferably, the chemical composition of the metal magnesium slag includes CaO, Al 2 O 3 , SiO 2 , Fe 2 O 3 , Na 2 O, MgO, F and K 2 O.

一种以板岩为原料所制备的轻质高强陶粒的制备方法,包括以下步骤A preparation method of light high-strength ceramsite prepared from slate as raw material, comprising the following steps

(1)按照质量百分数分别称取50-90%的板岩,5-30%的粉煤灰,2-6%的金属镁渣,1-10%的油页岩半焦,1-4%的白云石,并将板岩粉碎研磨至200目-400目,将上述原料混匀,得到混合料;(1) Weigh 50-90% slate, 5-30% fly ash, 2-6% magnesium metal slag, 1-10% oil shale semi-coke, 1-4% Dolomite, and crushing and grinding the slate to 200 mesh-400 mesh, mixing the above-mentioned raw materials to obtain a mixture;

(2)将混合料投入强力混合机内,使用喷雾器械将水喷洒在强力混合机内的混合料上,滚动成球,得到湿料球;(2) Put the mixture into the intensive mixer, use a spraying device to spray water on the mixture in the intensive mixer, roll it into a ball, and obtain a wet ball;

(3)将湿料球自然烘干后再置于回转窑中烘干,得到干燥的料球;(3) drying the wet balls naturally and then drying them in a rotary kiln to obtain dry balls;

(4)将干燥的料球置于回转窑内焙烧1h-2.5h;(4) Place the dried pellets in a rotary kiln and roast for 1h-2.5h;

(5)将焙烧后的料球在回转窑内冷却至75℃-125℃,出窑自然冷却后筛选,即得成品。(5) Cool the calcined pellets to 75°C-125°C in a rotary kiln, leave the kiln to cool naturally, and then sieve to obtain the finished product.

优选的,步骤(2)中湿料球粒度小于15mm。Preferably, the particle size of the wet material balls in step (2) is less than 15 mm.

优选的,步骤(3)中回转窑中烘干温度为80℃-200℃。Preferably, the drying temperature in the rotary kiln in step (3) is 80°C-200°C.

优选的,步骤(4)中,焙烧温度为1200-1300℃,焙烧时间为5-10min。Preferably, in step (4), the calcination temperature is 1200-1300° C., and the calcination time is 5-10 min.

优选的,步骤(5)中,成品粒度筛选范围为5-15mm。Preferably, in step (5), the particle size screening range of the finished product is 5-15mm.

本发明中,以板岩为原料的轻质高强陶粒中添加的粉煤灰既可降低其中SiO2含量又可以增加Al2O3含量,使得料球在膨胀能较高的情况下保证陶粒的良好强度;配方中Fe2O3组分在加热高温时分解产生大量的O2,同时Fe2O3还可与过量的C反应生成CO气体,这些气体对陶粒的烧胀起关键作用;配方中Na2O、K2O、CaO及MgO等助剂组分含量较高且起到助熔作用,可降低陶粒烧成温度,同时这些助剂还有利于液相的形成,从而扩大熔融温度范围,提高陶粒品质;本发明技术方案的实施不仅可以减少板岩尾矿堆积对大量土地的占用,减轻它们对生态、环境以及人类健康的严重威胁,也解决了以往市场上陶粒制品本身所存在的高堆积密度、高吸水率和低筒压强度等问题,提高了对板岩尾矿和粉煤灰的利用价值,使板岩尾矿变废为宝,适合工业化生产。In the present invention, the fly ash added to the light high-strength ceramsite with slate as raw material can not only reduce the content of SiO 2 but also increase the content of Al 2 O 3 , so that the ceramsite can be guaranteed under the condition of high expansion energy of the material ball. Good strength of ceramsite; the Fe 2 O 3 component in the formula decomposes to produce a large amount of O 2 when heated at high temperature, and at the same time Fe 2 O 3 can also react with excess C to generate CO gas, which plays a key role in the swelling of ceramsite Function; Na 2 O, K 2 O, CaO and MgO and other additives in the formula are high in content and play a fluxing role, which can reduce the firing temperature of ceramsite. At the same time, these additives are also conducive to the formation of liquid phase. Thereby expanding the melting temperature range and improving the quality of ceramsite; the implementation of the technical solution of the present invention can not only reduce the occupation of a large amount of land by the accumulation of slate tailings, alleviate their serious threat to ecology, the environment and human health, but also solve the problem of ceramics on the market in the past. The problems of high bulk density, high water absorption and low cylinder compressive strength in the granular product itself have improved the utilization value of slate tailings and fly ash, turning waste into treasure and suitable for industrial production.

具体实施方式Detailed ways

实施例1Example 1

本发明实施例1提供一种以板岩为原料的轻质高强陶粒,按照质量百分数其原料配比为:Embodiment 1 of the present invention provides a kind of lightweight high-strength ceramsite with slate as raw material, and its raw material ratio according to mass percentage is:

本实施例1中以板岩为原料的轻质高强陶粒,原料化学组成成分及含量如下表5所示:In this embodiment 1, the light high-strength ceramsite with slate as raw material, the chemical composition and content of the raw material are shown in Table 5 below:

表5实施例1所涉及的原料化学组成成分及含量(%)The raw material chemical composition and content (%) involved in table 5 embodiment 1

其制造方法按照以下步骤实施:Its manufacturing method is implemented according to the following steps:

(1)按照质量百分数分别称取80%的板岩,10%的粉煤灰,5%的金属镁渣,3%的油页岩半焦,2%的白云石,并将板岩粉碎研磨至200目,金属镁渣、油页岩半焦和白云石研磨至200目,将上述原料混匀,得到混合料;(1) Weigh 80% of slate, 10% of fly ash, 5% of magnesium metal slag, 3% of oil shale semi-coke, and 2% of dolomite according to mass percentage, and crush and grind the slate to 200 mesh, the metal magnesium slag, oil shale semi-coke and dolomite are ground to 200 mesh, and the above raw materials are mixed to obtain a mixture;

(2)将混合料投入强力混合机内,使用喷雾器械将水喷洒在强力混合机内的混合料上,滚动成球,得到湿料球,其中,湿料球粒度小于15mm;(2) Put the mixture into the intensive mixer, spray water on the mixture in the intensive mixer with a spraying device, roll into balls, and obtain wet pellets, wherein the wet pellets have a particle size less than 15 mm;

(3)将湿料球自然烘干后再置于回转窑中烘干,得到干燥的料球,其中,回转窑中烘干温度为120℃;(3) drying the wet pellets naturally and then drying them in a rotary kiln to obtain dried pellets, wherein the drying temperature in the rotary kiln is 120°C;

(4)将干燥的料球置于回转窑内焙烧1h-2.5h,其中,焙烧温度为1250℃,焙烧时间为5min;(4) Place the dried pellets in a rotary kiln and roast for 1h-2.5h, wherein the roasting temperature is 1250°C and the roasting time is 5min;

(5)将焙烧后的料球在回转窑内冷却至75℃-125℃,出窑自然冷却后筛选,即得成品,其中成品粒度筛选范围为5-15mm。(5) Cool the calcined balls to 75°C-125°C in the rotary kiln, and screen after leaving the kiln for natural cooling to obtain the finished product, wherein the particle size screening range of the finished product is 5-15mm.

参照《轻集料》实验条件的要求,对实施例1中得到的产品的相关性能进行了检测。本发明实施例1中得到的轻质高强陶粒,堆积密度为814kg/m3,吸水率4.2%,筒压强度为6.7Mpa,达到国家轻质高强陶粒的标准。With reference to the requirements of the experimental conditions of "Light Aggregate", the relevant performance of the product obtained in Example 1 was tested. The lightweight high-strength ceramsite obtained in Example 1 of the present invention has a bulk density of 814kg/m 3 , a water absorption rate of 4.2%, and a cylinder compressive strength of 6.7Mpa, meeting the national standard for lightweight high-strength ceramsite.

实施例2Example 2

本发明实施例2提供一种以板岩为原料的轻质高强陶粒,按照质量百分数其原料配比为:Embodiment 2 of the present invention provides a kind of lightweight high-strength ceramsite with slate as raw material, and its raw material ratio according to mass percentage is:

本实施例2中以板岩为原料的轻质高强陶粒,原料化学组成成分及含量如下表6所示:In this embodiment 2, the light high-strength ceramsite with slate as raw material, the chemical composition and content of the raw material are shown in Table 6 below:

表6实施例2所涉及的原料化学组成成分及含量(%)The raw material chemical composition and content (%) involved in table 6 embodiment 2

化学成分chemical composition 板岩slate 粉煤灰fly ash 金属镁渣Magnesium slag 油页岩半焦Oil Shale Semi-coke 白云石dolomite 总量Total SiO<sub>2</sub>SiO<sub>2</sub> 49.3549.35 8.228.22 1.361.36 2.442.44 61.3761.37 Al<sub>2</sub>O<sub>3</sub>Al<sub>2</sub>O<sub>3</sub> 9.109.10 5.965.96 0.080.08 0.700.70 15.8415.84 Fe<sub>2</sub>O<sub>3</sub>Fe<sub>2</sub>O<sub>3</sub> 4.124.12 1.101.10 0.200.20 0.500.50 5.925.92 MgOMgO 1.321.32 0.130.13 0.270.27 0.050.05 1.771.77 CaOCaO 0.130.13 0.920.92 3.053.05 0.070.07 1.121.12 5.295.29 K<sub>2</sub>OK<sub>2</sub>O 2.312.31 0.230.23 0.000.00 0.140.14 2.682.68 Na<sub>2</sub>ONa<sub>2</sub>O 1.541.54 0.070.07 0.000.00 0.050.05 1.661.66 P<sub>2</sub>O<sub>5</sub>P<sub>2</sub>O<sub>5</sub> 0.040.04 0.090.09 0.000.00 0.030.03 0.160.16 MnOMnO 1.321.32 0.010.01 0.000.00 0.000.00 1.331.33 TiO<sub>2</sub>TiO<sub>2</sub> 0.490.49 0.270.27 0.000.00 0.020.02 0.780.78 LOILOI 1.491.49 0.750.75 0.020.02 0.980.98 3.243.24

其制造方法按照以下步骤实施:Its manufacturing method is implemented according to the following steps:

(1)按照质量百分数分别称取70%的板岩,18%的粉煤灰,5%的金属镁渣,5%的油页岩半焦,2%的白云石,并将板岩粉碎研磨至200目,金属镁渣、油页岩半焦和白云石研磨至200目,将上述原料混匀,得到混合料;(1) Weigh 70% of slate, 18% of fly ash, 5% of magnesium metal slag, 5% of oil shale semi-coke, and 2% of dolomite according to mass percentage, and crush and grind the slate to 200 mesh, the metal magnesium slag, oil shale semi-coke and dolomite are ground to 200 mesh, and the above raw materials are mixed to obtain a mixture;

(2)将混合料投入强力混合机内,使用喷雾器械将水喷洒在强力混合机内的混合料上,滚动成球,得到湿料球,其中,湿料球粒度小于15mm;(2) Put the mixture into the intensive mixer, spray water on the mixture in the intensive mixer with a spraying device, roll into balls, and obtain wet pellets, wherein the wet pellets have a particle size less than 15mm;

(3)将湿料球自然烘干后再置于回转窑中烘干,得到干燥的料球,其中,回转窑中烘干温度为120℃;(3) drying the wet pellets naturally and then drying them in a rotary kiln to obtain dried pellets, wherein the drying temperature in the rotary kiln is 120°C;

(4)将干燥的料球置于回转窑内焙烧1h-2.5h,其中,焙烧温度为1250℃,焙烧时间为5min;(4) Place the dried pellets in a rotary kiln and roast for 1h-2.5h, wherein the roasting temperature is 1250°C and the roasting time is 5min;

(5)将焙烧后的料球在回转窑内冷却至75℃-125℃,出窑自然冷却后筛选,即得成品,其中成品粒度筛选范围为5-15mm。(5) Cool the calcined balls to 75°C-125°C in the rotary kiln, and screen after leaving the kiln for natural cooling to obtain the finished product, wherein the particle size screening range of the finished product is 5-15mm.

参照《轻集料》实验条件的要求,对实施例2中得到的产品的相关性能进行了检测。本发明实施例2中得到的轻质高强陶粒,堆积密度为765kg/m3,吸水率4.9%,筒压强度为6.9Mpa,达到国家轻质高强陶粒的标准。With reference to the requirements of the experimental conditions of "Light Aggregate", the relevant performance of the product obtained in Example 2 was tested. The lightweight high-strength ceramsite obtained in Example 2 of the present invention has a bulk density of 765kg/m 3 , a water absorption rate of 4.9%, and a cylinder compressive strength of 6.9Mpa, which meet the national standard for lightweight high-strength ceramsite.

实施例3Example 3

本发明实施例3提供一种以板岩为原料的轻质高强陶粒,按照质量百分数其原料配比为:Embodiment 3 of the present invention provides a kind of lightweight high-strength ceramsite with slate as raw material, and its raw material ratio according to mass percentage is:

本实施例3中以板岩为原料的轻质高强陶粒,原料化学组成成分及含量如下表7所示:In this embodiment 3, the light high-strength ceramsite with slate as raw material, the chemical composition and content of the raw material are shown in Table 7 below:

表7实施例3所涉及的原料化学组成成分及含量(%)The raw material chemical composition and content (%) involved in table 7 embodiment 3

化学成分chemical composition 板岩slate 粉煤灰fly ash 金属镁渣Magnesium slag 油页岩半焦Oil Shale Semi-coke 白云石dolomite 总量Total SiO<sub>2</sub>SiO<sub>2</sub> 42.3242.32 12.7912.79 1.361.36 2.442.44 58.9158.91 Al<sub>2</sub>O<sub>3</sub>Al<sub>2</sub>O<sub>3</sub> 7.807.80 9.279.27 0.080.08 0.700.70 17.8517.85 Fe<sub>2</sub>O<sub>3</sub>Fe<sub>2</sub>O<sub>3</sub> 3.533.53 1.711.71 0.200.20 0.500.50 5.945.94 MgOMgO 1.131.13 0.200.20 0.270.27 0.050.05 1.641.64 CaOCaO 0.110.11 1.411.41 3.053.05 0.070.07 1.121.12 5.765.76 K<sub>2</sub>OK<sub>2</sub>O 1.981.98 0.360.36 0.000.00 0.140.14 2.482.48 Na<sub>2</sub>ONa<sub>2</sub>O 1.321.32 0.110.11 0.000.00 0.050.05 1.471.47 P<sub>2</sub>O<sub>5</sub>P<sub>2</sub>O<sub>5</sub> 0.030.03 0.140.14 0.000.00 0.030.03 0.210.21 MnOMnO 1.131.13 0.010.01 0.000.00 0.000.00 1.151.15 TiO<sub>2</sub>TiO<sub>2</sub> 0.420.42 0.410.41 0.000.00 0.020.02 0.860.86 LOILOI 1.281.28 1.171.17 0.020.02 0.980.98 3.453.45

其制造方法按照以下步骤实施:Its manufacturing method is implemented according to the following steps:

(1)按照质量百分数分别称取60%的板岩,28%的粉煤灰,5%的金属镁渣,5%的油页岩半焦,2%的白云石,并将板岩粉碎研磨至200目,金属镁渣、油页岩半焦和白云石研磨至200目,将上述原料混匀,得到混合料;(1) Weigh 60% of slate, 28% of fly ash, 5% of magnesium metal slag, 5% of oil shale semi-coke, and 2% of dolomite according to mass percentage, and crush and grind the slate to 200 mesh, the metal magnesium slag, oil shale semi-coke and dolomite are ground to 200 mesh, and the above raw materials are mixed to obtain a mixture;

(2)将混合料投入强力混合机内,使用喷雾器械将水喷洒在强力混合机内的混合料上,滚动成球,得到湿料球,其中,湿料球粒度小于15mm;(2) Put the mixture into the intensive mixer, spray water on the mixture in the intensive mixer with a spraying device, roll into balls, and obtain wet pellets, wherein the wet pellets have a particle size less than 15 mm;

(3)将湿料球自然烘干后再置于回转窑中烘干,得到干燥的料球,其中,回转窑中烘干温度为120℃;(3) drying the wet pellets naturally and then drying them in a rotary kiln to obtain dried pellets, wherein the drying temperature in the rotary kiln is 120°C;

(4)将干燥的料球置于回转窑内焙烧1h-2.5h,其中,焙烧温度为1260℃,焙烧时间为5min;(4) Place the dried pellets in a rotary kiln and roast for 1h-2.5h, wherein the roasting temperature is 1260°C and the roasting time is 5min;

(5)将焙烧后的料球在回转窑内冷却至75℃-125℃,出窑自然冷却后筛选,即得成品,其中成品粒度筛选范围为5-15mm。(5) Cool the calcined balls to 75°C-125°C in the rotary kiln, and screen after leaving the kiln for natural cooling to obtain the finished product, wherein the particle size screening range of the finished product is 5-15mm.

参照《轻集料》实验条件的要求,对实施例3中得到的产品的相关性能进行了检测。本发明实施例3中得到的轻质高强陶粒,堆积密度为680kg/m3,吸水率5.6%,筒压强度为7.8Mpa,达到国家轻质高强陶粒的标准。With reference to the requirements of the experimental conditions of "Light Aggregate", the relevant properties of the product obtained in Example 3 were tested. The lightweight high-strength ceramsite obtained in Example 3 of the present invention has a bulk density of 680kg/m 3 , a water absorption rate of 5.6%, and a cylinder compressive strength of 7.8Mpa, meeting the national standard for lightweight high-strength ceramsite.

实施例4Example 4

本发明实施例4提供一种以板岩为原料的轻质高强陶粒,按照质量百分数其原料配比为:Embodiment 4 of the present invention provides a kind of lightweight high-strength ceramsite with slate as raw material, and its raw material ratio according to mass percentage is:

本实施例4中以板岩为原料的轻质高强陶粒,原料化学组成成分及含量如下表8所示:In this embodiment 4, the light high-strength ceramsite with slate as raw material, the chemical composition and content of the raw material are shown in Table 8 below:

表8实施例4所涉及的原料化学组成成分及含量(%)The raw material chemical composition and content (%) involved in table 8 embodiment 4

其制造方法按照以下步骤实施:Its manufacturing method is implemented according to the following steps:

(1)按照质量百分数分别称取60%的板岩,30%的粉煤灰,3%的金属镁渣,5%的油页岩半焦,2%的白云石,并将板岩粉碎研磨至200目,金属镁渣、油页岩半焦和白云石研磨至200目,将上述原料混匀,得到混合料;(1) Weigh 60% of slate, 30% of fly ash, 3% of magnesium metal slag, 5% of oil shale semi-coke, and 2% of dolomite according to mass percentage, and crush and grind the slate to 200 mesh, the metal magnesium slag, oil shale semi-coke and dolomite are ground to 200 mesh, and the above raw materials are mixed to obtain a mixture;

(2)将混合料投入强力混合机内,使用喷雾器械将水喷洒在强力混合机内的混合料上,滚动成球,得到湿料球,其中,湿料球粒度小于15mm;(2) Put the mixture into the intensive mixer, spray water on the mixture in the intensive mixer with a spraying device, roll into balls, and obtain wet pellets, wherein the wet pellets have a particle size less than 15 mm;

(3)将湿料球自然烘干后再置于回转窑中烘干,得到干燥的料球,其中,回转窑中烘干温度为120℃;(3) drying the wet pellets naturally and then drying them in a rotary kiln to obtain dried pellets, wherein the drying temperature in the rotary kiln is 120°C;

(4)将干燥的料球置于回转窑内焙烧1h-2.5h,其中,焙烧温度为1220℃,焙烧时间为5min;(4) Place the dried pellets in a rotary kiln and roast for 1h-2.5h, wherein the roasting temperature is 1220°C and the roasting time is 5min;

(5)将焙烧后的料球在回转窑内冷却至75℃-125℃,出窑自然冷却后筛选,即得成品,其中成品粒度筛选范围为5-15mm。(5) Cool the calcined balls to 75°C-125°C in the rotary kiln, and screen after leaving the kiln for natural cooling to obtain the finished product, wherein the particle size screening range of the finished product is 5-15mm.

参照《轻集料》实验条件的要求,对实施例4中得到的产品的相关性能进行了检测。本发明实施例4中得到的轻质高强陶粒,堆积密度为653kg/m3,吸水率6.1%,筒压强度为7.6Mpa,达到国家轻质高强陶粒的标准。With reference to the requirements of the experimental conditions of "Light Aggregate", the relevant properties of the product obtained in Example 4 were tested. The lightweight high-strength ceramsite obtained in Example 4 of the present invention has a bulk density of 653kg/m 3 , a water absorption rate of 6.1%, and a cylinder compressive strength of 7.6Mpa, meeting the national standard for lightweight high-strength ceramsite.

实施例5Example 5

本发明实施例5提供一种以板岩为原料的轻质高强陶粒,按照质量百分数其原料配比为:Embodiment 5 of the present invention provides a kind of lightweight high-strength ceramsite with slate as raw material, and its raw material ratio according to mass percentage is:

本实施例5中以板岩为原料的轻质高强陶粒,原料化学组成成分及含量如下表9所示:In this embodiment 5, the light high-strength ceramsite with slate as raw material, the chemical composition and content of the raw material are shown in Table 9 below:

表9实施例5所涉及的原料化学组成成分及含量(%)The raw material chemical composition and content (%) involved in table 9 embodiment 5

化学成分chemical composition 板岩slate 粉煤灰fly ash 金属镁渣Magnesium slag 油页岩半焦Oil Shale Semi-coke 白云石dolomite 总量Total SiO<sub>2</sub>SiO<sub>2</sub> 38.7938.79 13.7013.70 0.820.82 4.884.88 58.1958.19 Al<sub>2</sub>O<sub>3</sub>Al<sub>2</sub>O<sub>3</sub> 7.157.15 9.939.93 0.050.05 1.401.40 18.5318.53 Fe<sub>2</sub>O<sub>3</sub>Fe<sub>2</sub>O<sub>3</sub> 3.243.24 1.831.83 0.120.12 1.001.00 6.196.19 MgOMgO 1.041.04 0.210.21 0.160.16 0.100.10 1.511.51 CaOCaO 0.100.10 1.511.51 1.831.83 0.140.14 1.121.12 4.704.70 K<sub>2</sub>OK<sub>2</sub>O 1.821.82 0.390.39 0.000.00 0.280.28 2.492.49 Na<sub>2</sub>ONa<sub>2</sub>O 1.211.21 0.120.12 0.000.00 0.100.10 1.431.43 P<sub>2</sub>O<sub>5</sub>P<sub>2</sub>O<sub>5</sub> 0.030.03 0.150.15 0.000.00 0.060.06 0.240.24 MnOMnO 1.041.04 0.010.01 0.000.00 0.000.00 1.051.05 TiO<sub>2</sub>TiO<sub>2</sub> 0.380.38 0.440.44 0.000.00 0.040.04 0.860.86 LOILOI 1.171.17 1.261.26 0.010.01 1.961.96 4.404.40

其制造方法按照以下步骤实施:Its manufacturing method is implemented according to the following steps:

(1)按照质量百分数分别称取55%的板岩,30%的粉煤灰,3%的金属镁渣,10%的油页岩半焦,2%的白云石,并将板岩粉碎研磨至200目,金属镁渣、油页岩半焦和白云石研磨至200目,将上述原料混匀,得到混合料;(1) Weigh 55% of slate, 30% of fly ash, 3% of magnesium metal slag, 10% of oil shale semi-coke, and 2% of dolomite according to mass percentage, and crush and grind the slate to 200 mesh, the metal magnesium slag, oil shale semi-coke and dolomite are ground to 200 mesh, and the above raw materials are mixed to obtain a mixture;

(2)将混合料投入强力混合机内,使用喷雾器械将水喷洒在强力混合机内的混合料上,滚动成球,得到湿料球,其中,湿料球粒度小于15mm;(2) Put the mixture into the intensive mixer, spray water on the mixture in the intensive mixer with a spraying device, roll into balls, and obtain wet pellets, wherein the wet pellets have a particle size less than 15 mm;

(3)将湿料球自然烘干后再置于回转窑中烘干,得到干燥的料球,其中,回转窑中烘干温度为120℃;(3) drying the wet pellets naturally and then drying them in a rotary kiln to obtain dried pellets, wherein the drying temperature in the rotary kiln is 120°C;

(4)将干燥的料球置于回转窑内焙烧1h-2.5h,其中,焙烧温度为1250℃,焙烧时间为8min;(4) Place the dried pellets in a rotary kiln and roast for 1h-2.5h, wherein the roasting temperature is 1250°C and the roasting time is 8min;

(5)将焙烧后的料球在回转窑内冷却至75℃-125℃,出窑自然冷却后筛选,即得成品,其中成品粒度筛选范围为5-15mm。(5) Cool the calcined balls to 75°C-125°C in the rotary kiln, and screen after leaving the kiln for natural cooling to obtain the finished product, wherein the particle size screening range of the finished product is 5-15mm.

参照《轻集料》实验条件的要求,对实施例4中得到的产品的相关性能进行了检测。本发明实施例4中得到的轻质高强陶粒,堆积密度为638kg/m3,吸水率6.5%,筒压强度为8.1Mpa,达到国家轻质高强陶粒的标准。With reference to the requirements of the experimental conditions of "Light Aggregate", the relevant properties of the product obtained in Example 4 were tested. The lightweight high-strength ceramsite obtained in Example 4 of the present invention has a bulk density of 638kg/m 3 , a water absorption rate of 6.5%, and a cylinder compressive strength of 8.1Mpa, meeting the national standard for lightweight high-strength ceramsite.

实施例6Example 6

本发明实施例6提供一种以板岩为原料的轻质高强陶粒,按照质量百分数其原料配比为:Embodiment 6 of the present invention provides a kind of lightweight high-strength ceramsite with slate as raw material, and its raw material ratio according to mass percentage is:

本实施例6中以板岩为原料的轻质高强陶粒,原料化学组成成分及含量如下表10所示:In this embodiment 6, the light high-strength ceramsite with slate as raw material, the chemical composition and content of the raw material are shown in Table 10 below:

表10实施例6所涉及的原料化学组成成分及含量(%)The raw material chemical composition and content (%) involved in table 10 embodiment 6

其制造方法按照以下步骤实施:Its manufacturing method is implemented according to the following steps:

(1)按照质量百分数分别称取71%的板岩,15%的粉煤灰,5%的金属镁渣,5%的油页岩半焦,4%的白云石,并将板岩粉碎研磨至200目,金属镁渣、油页岩半焦和白云石研磨至200目,将上述原料混匀,得到混合料;(1) Weigh 71% of slate, 15% of fly ash, 5% of magnesium metal slag, 5% of oil shale semi-coke, and 4% of dolomite according to mass percentage, and crush and grind the slate to 200 mesh, the metal magnesium slag, oil shale semi-coke and dolomite are ground to 200 mesh, and the above raw materials are mixed to obtain a mixture;

(2)将混合料投入强力混合机内,使用喷雾器械将水喷洒在强力混合机内的混合料上,滚动成球,得到湿料球,其中,湿料球粒度小于15mm;(2) Put the mixture into the intensive mixer, spray water on the mixture in the intensive mixer with a spraying device, roll into balls, and obtain wet pellets, wherein the wet pellets have a particle size less than 15 mm;

(3)将湿料球自然烘干后再置于回转窑中烘干,得到干燥的料球,其中,回转窑中烘干温度为120℃;(3) drying the wet pellets naturally and then drying them in a rotary kiln to obtain dried pellets, wherein the drying temperature in the rotary kiln is 120°C;

(4)将干燥的料球置于回转窑内焙烧1h-2.5h,其中,焙烧温度为1200℃,焙烧时间为8min;(4) Place the dried pellets in a rotary kiln and roast for 1h-2.5h, wherein the roasting temperature is 1200°C and the roasting time is 8min;

(5)将焙烧后的料球在回转窑内冷却至75℃-125℃,出窑自然冷却后筛选,即得成品,其中成品粒度筛选范围为5-15mm。(5) Cool the calcined balls to 75°C-125°C in the rotary kiln, and screen after leaving the kiln for natural cooling to obtain the finished product, wherein the particle size screening range of the finished product is 5-15mm.

参照《轻集料》实验条件的要求,对实施例6中得到的产品的相关性能进行了检测。本发明实施例6中得到的轻质高强陶粒,堆积密度为735kg/m3,吸水率5.9%,筒压强度为7.2Mpa,达到国家轻质高强陶粒的标准。With reference to the requirements of the experimental conditions of "Light Aggregate", the relevant performance of the product obtained in Example 6 was tested. The lightweight high-strength ceramsite obtained in Example 6 of the present invention has a bulk density of 735kg/m 3 , a water absorption rate of 5.9%, and a cylinder compressive strength of 7.2Mpa, reaching the national standard for lightweight high-strength ceramsite.

实施例7Example 7

本发明实施例7提供一种以板岩为原料的轻质高强陶粒,按照质量百分数其原料配比为:Embodiment 7 of the present invention provides a kind of lightweight high-strength ceramsite with slate as raw material, and its raw material ratio according to mass percentage is:

本实施例7中以板岩为原料的轻质高强陶粒,原料化学组成成分及含量如下表11所示:In this embodiment 7, the light high-strength ceramsite with slate as raw material, the chemical composition and content of the raw material are shown in Table 11 below:

表11实施例7所涉及的原料化学组成成分及含量(%)The raw material chemical composition and content (%) involved in table 11 embodiment 7

化学成分chemical composition 板岩slate 粉煤灰fly ash 金属镁渣Magnesium slag 油页岩半焦Oil Shale Semi-coke 白云石dolomite 总量Total SiO<sub>2</sub>SiO<sub>2</sub> 61.3661.36 2.282.28 0.820.82 1.461.46 65.9265.92 Al<sub>2</sub>O<sub>3</sub>Al<sub>2</sub>O<sub>3</sub> 11.3111.31 1.661.66 0.050.05 0.420.42 13.4413.44 Fe<sub>2</sub>O<sub>3</sub>Fe<sub>2</sub>O<sub>3</sub> 5.125.12 0.310.31 0.120.12 0.300.30 5.855.85 MgOMgO 1.641.64 0.030.03 0.160.16 0.030.03 1.861.86 CaOCaO 0.160.16 0.250.25 1.831.83 0.040.04 1.121.12 3.403.40 K<sub>2</sub>OK<sub>2</sub>O 2.872.87 0.070.07 0.000.00 0.080.08 3.023.02 Na<sub>2</sub>ONa<sub>2</sub>O 1.911.91 0.020.02 0.000.00 0.030.03 1.961.96 P<sub>2</sub>O<sub>5</sub>P<sub>2</sub>O<sub>5</sub> 0.040.04 0.030.03 0.000.00 0.020.02 0.090.09 MnOMnO 1.641.64 0.000.00 0.000.00 0.000.00 1.641.64 TiO<sub>2</sub>TiO<sub>2</sub> 0.610.61 0.070.07 0.000.00 0.010.01 0.690.69 LOILOI 1.861.86 0.210.21 0.010.01 0.590.59 2.672.67

其制造方法按照以下步骤实施:Its manufacturing method is implemented according to the following steps:

(1)按照质量百分数分别称取87%的板岩,5%的粉煤灰,3%的金属镁渣,3%的油页岩半焦,2%的白云石,并将板岩粉碎研磨至200目,金属镁渣、油页岩半焦和白云石研磨至200目,将上述原料混匀,得到混合料;(1) Weigh 87% of slate, 5% of fly ash, 3% of magnesium metal slag, 3% of oil shale semi-coke, and 2% of dolomite according to mass percentage, and crush and grind the slate to 200 mesh, the metal magnesium slag, oil shale semi-coke and dolomite are ground to 200 mesh, and the above raw materials are mixed to obtain a mixture;

(2)将混合料投入强力混合机内,使用喷雾器械将水喷洒在强力混合机内的混合料上,滚动成球,得到湿料球,其中,湿料球粒度小于15mm;(2) Put the mixture into the intensive mixer, spray water on the mixture in the intensive mixer with a spraying device, roll into balls, and obtain wet pellets, wherein the wet pellets have a particle size less than 15 mm;

(3)将湿料球自然烘干后再置于回转窑中烘干,得到干燥的料球,其中,回转窑中烘干温度为120℃;(3) drying the wet pellets naturally and then drying them in a rotary kiln to obtain dried pellets, wherein the drying temperature in the rotary kiln is 120°C;

(4)将干燥的料球置于回转窑内焙烧1h-2.5h,其中,焙烧温度为1230℃,焙烧时间为5min;(4) Place the dried pellets in a rotary kiln and roast for 1h-2.5h, wherein the roasting temperature is 1230°C and the roasting time is 5min;

(5)将焙烧后的料球在回转窑内冷却至75℃-125℃,出窑自然冷却后筛选,即得成品,其中成品粒度筛选范围为5-15mm。(5) Cool the calcined balls to 75°C-125°C in the rotary kiln, and screen after leaving the kiln for natural cooling to obtain the finished product, wherein the particle size screening range of the finished product is 5-15mm.

参照《轻集料》实验条件的要求,对实施例7中得到的产品的相关性能进行了检测。本发明实施例7中得到的轻质高强陶粒,堆积密度为805kg/m3,吸水率5.5%,筒压强度为6.4Mpa,达到国家轻质高强陶粒的标准。With reference to the requirements of the experimental conditions of "Light Aggregate", the relevant performance of the product obtained in Example 7 was tested. The lightweight high-strength ceramsite obtained in Example 7 of the present invention has a bulk density of 805kg/m 3 , a water absorption rate of 5.5%, and a cylinder compressive strength of 6.4Mpa, meeting the national standard for lightweight high-strength ceramsite.

尽管已描述了本发明的优选实施例,但本领域内的技术人员一旦得知了基本创造性概念,则可对这些实施例作出另外的变更和修改。所以,所附权利要求意欲解释为包括优选实施例以及落入本发明范围的所有变更和修改。While preferred embodiments of the invention have been described, additional changes and modifications to these embodiments can be made by those skilled in the art once the basic inventive concept is appreciated. Therefore, it is intended that the appended claims be construed to cover the preferred embodiment as well as all changes and modifications which fall within the scope of the invention.

显然,本领域的技术人员可以对本发明进行各种改动和变型而不脱离本发明的精神和范围。这样,倘若本发明的这些修改和变型属于本发明权利要求及其等同技术的范围之内,则本发明也意图包含这些改动和变型在内。Obviously, those skilled in the art can make various changes and modifications to the present invention without departing from the spirit and scope of the present invention. Thus, if these modifications and variations of the present invention fall within the scope of the claims of the present invention and their equivalent technologies, the present invention also intends to include these modifications and variations.

Claims (8)

1. The light high-strength ceramsite prepared from slate is characterized by comprising the following raw materials in percentage by mass: 50-90% of slate, 5-30% of fly ash, 2-6% of metal magnesium slag, 1-10% of oil shale semi-coke and 1-4% of dolomite.
2. The light-weight high-strength ceramsite prepared from slate as claimed in claim 1, wherein the chemical composition of the slate comprises SiO2,Al2O3,Fe2O3,MgO,CaO,K2O,Na2O,P2O5,MnO,TiO2And LOI.
3. The lightweight high-strength ceramsite prepared from slate as raw material according to claim 1, wherein the magnesium slag comprises CaO and Al2O3,SiO2,Fe2O3,Na2O, MgO, F and K2O。
4. The preparation method of the light-weight high-strength ceramsite prepared from slate as claimed in claim 1, which comprises the following steps:
(1) respectively weighing 50-90% of slate, 5-30% of fly ash, 2-6% of metal magnesium slag, 1-10% of oil shale semi-coke and 1-4% of dolomite according to the mass percentage, crushing and grinding the slate to 200-400 meshes, and uniformly mixing the raw materials to obtain a mixture;
(2) putting the mixture into a powerful mixer, spraying water on the mixture in the powerful mixer by using a spraying instrument, and rolling to form balls to obtain wet material balls;
(3) naturally drying the wet material balls, and then placing the wet material balls in a rotary kiln for drying to obtain dried material balls;
(4) placing the dried pellets in a rotary kiln to be roasted for 1-2.5 h;
(5) and cooling the roasted material balls to 75-125 ℃ in a rotary kiln, taking the material balls out of the kiln, naturally cooling and screening to obtain the finished product.
5. The method for preparing lightweight high-strength ceramsite by using slate as raw material according to claim 4, wherein the wet pellet size in the step (2) is less than 15 mm.
6. The method for preparing light-weight high-strength ceramsite by using slate as raw material according to claim 4, wherein the drying temperature in the rotary kiln in the step (3) is 80-200 ℃.
7. The method for preparing the light-weight high-strength ceramsite from the slates as the raw material according to claim 4, wherein the roasting temperature in the step (4) is 1200-1300 ℃, and the roasting time is 5-10 min.
8. The method for preparing light-weight high-strength ceramsite by using slates as raw materials according to claim 4, wherein in the step (5), the granularity screening range of the finished product is 5mm-15 mm.
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