CN110591431A - Rare earth modified water-based alkyd resin antibacterial luminescent coating - Google Patents
Rare earth modified water-based alkyd resin antibacterial luminescent coating Download PDFInfo
- Publication number
- CN110591431A CN110591431A CN201910820184.9A CN201910820184A CN110591431A CN 110591431 A CN110591431 A CN 110591431A CN 201910820184 A CN201910820184 A CN 201910820184A CN 110591431 A CN110591431 A CN 110591431A
- Authority
- CN
- China
- Prior art keywords
- parts
- rare earth
- alkyd resin
- modified waterborne
- waterborne alkyd
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000180 alkyd Polymers 0.000 title claims abstract description 64
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 229910052761 rare earth metal Inorganic materials 0.000 title claims abstract description 48
- 150000002910 rare earth metals Chemical class 0.000 title claims abstract description 45
- 238000000576 coating method Methods 0.000 title claims abstract description 32
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 31
- 239000011248 coating agent Substances 0.000 title claims abstract description 30
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 36
- -1 carboxylic acid Schiff base Chemical class 0.000 claims abstract description 15
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 10
- 239000002262 Schiff base Substances 0.000 claims abstract description 8
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000005711 Benzoic acid Substances 0.000 claims abstract description 7
- 239000011324 bead Substances 0.000 claims abstract description 7
- 235000010233 benzoic acid Nutrition 0.000 claims abstract description 7
- 239000011521 glass Substances 0.000 claims abstract description 7
- 230000003472 neutralizing effect Effects 0.000 claims abstract description 7
- 150000007524 organic acids Chemical class 0.000 claims abstract description 7
- GYBMSOFSBPZKCX-UHFFFAOYSA-N sodium;ethanol;ethanolate Chemical compound [Na+].CCO.CC[O-] GYBMSOFSBPZKCX-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000007787 solid Substances 0.000 claims abstract description 7
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 7
- 239000008158 vegetable oil Substances 0.000 claims abstract description 7
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000945 filler Substances 0.000 claims abstract description 5
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 5
- 239000011737 fluorine Substances 0.000 claims abstract description 5
- 229920005862 polyol Polymers 0.000 claims abstract description 5
- 150000003077 polyols Chemical class 0.000 claims abstract description 5
- 238000006243 chemical reaction Methods 0.000 claims description 41
- 238000003756 stirring Methods 0.000 claims description 26
- 238000010438 heat treatment Methods 0.000 claims description 24
- 238000004321 preservation Methods 0.000 claims description 20
- 239000002253 acid Substances 0.000 claims description 17
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 10
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 claims description 9
- 238000013461 design Methods 0.000 claims description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 6
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 239000008096 xylene Substances 0.000 claims description 6
- 239000002518 antifoaming agent Substances 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000010992 reflux Methods 0.000 claims description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 4
- 238000007738 vacuum evaporation Methods 0.000 claims description 4
- 239000000080 wetting agent Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 3
- 235000011037 adipic acid Nutrition 0.000 claims description 3
- 239000001361 adipic acid Substances 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 235000021388 linseed oil Nutrition 0.000 claims description 3
- 239000000944 linseed oil Substances 0.000 claims description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 3
- 239000003549 soybean oil Substances 0.000 claims description 3
- 235000012424 soybean oil Nutrition 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- IFPMZBBHBZQTOV-UHFFFAOYSA-N 1,3,5-trinitro-2-(2,4,6-trinitrophenyl)-4-[2,4,6-trinitro-3-(2,4,6-trinitrophenyl)phenyl]benzene Chemical compound [O-][N+](=O)C1=CC([N+](=O)[O-])=CC([N+]([O-])=O)=C1C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C(C=2C(=C(C=3C(=CC(=CC=3[N+]([O-])=O)[N+]([O-])=O)[N+]([O-])=O)C(=CC=2[N+]([O-])=O)[N+]([O-])=O)[N+]([O-])=O)=C1[N+]([O-])=O IFPMZBBHBZQTOV-UHFFFAOYSA-N 0.000 claims description 2
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 2
- BTZVKSVLFLRBRE-UHFFFAOYSA-N 2-methoxypropyl acetate Chemical compound COC(C)COC(C)=O BTZVKSVLFLRBRE-UHFFFAOYSA-N 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims description 2
- 235000019483 Peanut oil Nutrition 0.000 claims description 2
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- 229960002887 deanol Drugs 0.000 claims description 2
- 239000012972 dimethylethanolamine Substances 0.000 claims description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 239000000312 peanut oil Substances 0.000 claims description 2
- 150000005846 sugar alcohols Polymers 0.000 claims description 2
- 239000002383 tung oil Substances 0.000 claims description 2
- 239000003242 anti bacterial agent Substances 0.000 abstract description 7
- 230000002045 lasting effect Effects 0.000 abstract description 3
- 238000010298 pulverizing process Methods 0.000 abstract description 3
- 230000032683 aging Effects 0.000 abstract description 2
- 238000004020 luminiscence type Methods 0.000 abstract description 2
- 239000003973 paint Substances 0.000 description 8
- 238000004146 energy storage Methods 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 4
- 230000007547 defect Effects 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 230000002285 radioactive effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 241000282414 Homo sapiens Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 150000004753 Schiff bases Chemical group 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229910003440 dysprosium oxide Inorganic materials 0.000 description 1
- NLQFUUYNQFMIJW-UHFFFAOYSA-N dysprosium(iii) oxide Chemical compound O=[Dy]O[Dy]=O NLQFUUYNQFMIJW-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910001940 europium oxide Inorganic materials 0.000 description 1
- AEBZCFFCDTZXHP-UHFFFAOYSA-N europium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Eu+3].[Eu+3] AEBZCFFCDTZXHP-UHFFFAOYSA-N 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000005101 luminescent paint Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/46—Polyesters chemically modified by esterification
- C08G63/48—Polyesters chemically modified by esterification by unsaturated higher fatty oils or their acids; by resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Plant Pathology (AREA)
- General Chemical & Material Sciences (AREA)
- Nanotechnology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a rare earth modified water-based alkyd resin antibacterial luminescent coating which comprises the following components in parts by weight: 35.0-55.0 parts of rare earth modified waterborne alkyd resin, 15.0-25.0 parts of fluorine modified waterborne alkyd resin, 0.0-25.0 parts of filler, 1.2-6.0 parts of assistant, 2.5-6.5 parts of solid glass beads, 3.5-6.5 parts of film-forming assistant and 10.0-30.0 parts of deionized water; the rare earth modified waterborne alkyd resin is mainly prepared by reacting vegetable oil, organic acid anhydride, carboxylic acid Schiff base, polyol, benzoic acid, dimethylolpropionic acid, a rare earth ethanol solution, a sodium ethoxide ethanol solution and a neutralizing agent; the rare earth modified waterborne alkyd resin antibacterial luminescent coating prepared by the invention does not need luminescent powder and an antibacterial agent, and has the characteristics of good aging resistance, difficult pulverization, lasting antibacterial property, long luminescence duration and the like.
Description
Technical Field
The invention relates to preparation of a water-based paint, in particular to a rare earth modified water-based alkyd resin antibacterial luminescent paint and a preparation method thereof, belonging to the technical field of water-based functional paints.
Background
With the rapid development of economy in China, the coating is more and more widely applied to industry, agriculture, national defense, scientific research and people's life, the coating is a liquid or fixed material which is coated on the surface of an object and forms a film under certain conditions to play a role in protection, decoration and specification, the existing coating has some defects, such as the decorated object surface is rigid and unchanged, the luminous effect cannot be displayed at night, part of raw materials are toxic or flammable and explosive, and have no environmental protection performance, so that the coating has harm to production and construction personnel, and meanwhile, the coating has a large amount of microorganisms, bacteria and germs in the environment, and most of the coating has no antibacterial effect, so that the coating with single performance cannot meet the diversified demands of the market.
The distribution of microorganisms in the environment is very wide, so that the survival and health of human beings are threatened by various bacteria and viruses all the time, almost all the abiotic surfaces have the microorganisms, at present, many antibacterial coatings are additive antibacterial coatings, and an antibacterial agent is added to achieve a certain antibacterial effect.
The energy storage luminescent materials applied to the coating at present mainly have two types, one type is a copper activated zinc sulfide series luminescent material; one is rare earth activated alkaline earth metal aluminate luminescent material. Copper-activated zinc sulfide series luminescent materials generally have short afterglow time, and radioactive elements are often doped in order to prolong the afterglow time, so that environmental pollution is caused. The rare earth activated alkaline earth metal aluminate luminescent material not only greatly prolongs afterglow time, but also does not contain radioactive elements, and is gradually and widely applied to the fields of traffic signs, safety signs, emergency signs in public places, decorative materials and the like. But most of the components are added in a physical doping mode, so that the components are difficult to disperse uniformly and easy to agglomerate, and the performance of the coating is influenced.
Chinese patent CN108659652A discloses an energy-storage luminous paint and a preparation method thereof. The energy storage luminous paint comprises the following components in percentage by mass: 15-25% of energy storage luminescent powder, 60-70% of water-based resin, 1-2% of polyamide wax and the balance of solvent. The energy storage luminescent powder comprises the following components in percentage by mass: 15-40% of strontium carbonate, 20-40% of barium metaaluminate, 30-50% of aluminum oxide, 1.5-2.5% of dysprosium oxide and 1-2% of europium oxide.
Chinese patent CN101250344A discloses an antibacterial coating and a preparation method thereof, which comprises the following raw materials in parts by weight: 1-10 parts of an antibacterial agent, 2-30 parts of an organic silicate, 10-40 parts of a silane coupling agent and 40-90 parts of water.
Said invention adopts external addition of antibacterial agent or energy-storing luminescent powder to make the paint possess a certain antibacterial property and luminescent property, but the additive type paint has the defects of non-uniform dispersion, easy migration, degradation, colour change, non-durable effect and environmental pollution, etc..
Disclosure of Invention
In order to solve the technical problems, the rare earth modified waterborne alkyd resin with the light-emitting performance and the antibacterial performance is introduced to be used as a film-forming substance of the paint without adding luminescent powder and an antibacterial agent, and the rare earth modified waterborne alkyd resin contains a Schiff base structure, so that the Schiff base compound has good bacteriostatic, bactericidal and antifungal effects; meanwhile, the rare earth ions are directly introduced into the water-based alkyd resin, and the energy efficiency transfer between the rare earth ions and the water-based alkyd resin can be effectively realized because the rare earth ions are directly connected with the water-based alkyd resin. So that the rare earth modified waterborne alkyd resin has good antibacterial property and luminescence property.
The invention aims to provide a rare earth modified waterborne alkyd resin and a preparation method thereof.
The invention also aims to provide the rare earth modified water-based alkyd resin antibacterial luminescent coating and a preparation method thereof.
In order to solve the technical problems, the invention adopts the following technical scheme: the invention relates to a rare earth modified water-based alkyd resin antibacterial luminescent coating which comprises the following components in parts by weight: 35.0-55.0 parts of rare earth modified waterborne alkyd resin, 15.0-25.0 parts of fluorine modified waterborne alkyd resin, 0.0-25.0 parts of filler, 1.2-6.0 parts of assistant, 2.5-6.5 parts of solid glass beads, 3.5-6.5 parts of film-forming assistant and 10.0-30.0 parts of deionized water.
The rare earth modified waterborne alkyd resin comprises the following components in parts by weight: 6.5-13.0 parts of vegetable oil, 6.5-15.0 parts of organic acid anhydride, 1.5-3.0 parts of carboxylic acid Schiff base, 6.0-12.0 parts of polyol, 1.0-2.5 parts of benzoic acid, 1.5-2.5 parts of dimethylolpropionic acid, 0.6-1.5 parts of rare earth ethanol solution, 0.7-2.0 parts of sodium ethoxide ethanol solution, 6.0-12.0 parts of xylene, 3.0-5.0 parts of neutralizer and 45.0-65.0 parts of deionized water.
Wherein the vegetable oil is one or more of dehydrated linseed oil, dehydrated tung oil, dehydrated rapeseed oil, dehydrated peanut oil, dehydrated soybean oil and dehydrated castor oil.
The organic acid anhydride is one or a combination of more of acetic anhydride, maleic anhydride, adipic acid and sebacic acid.
The polyhydric alcohol is one or a combination of more of propylene glycol, 1, 4-butanediol, hexanediol, neopentyl glycol, diethylene glycol, dipropylene glycol, trimethylolpropane, glycerol and pentaerythritol.
The rare earth ethanol solution is 0.1 mol.L-1Nd (NO)3)3Ethanol solution, Eu (NO)3)3Ethanol solution, Gd (NO)3)3Ethanol solution, Dy (NO)3)3One or a combination of several of ethanol solution.
The neutralizing agent is at least one of triethylamine, ammonia water and dimethylethanolamine.
The filler is one or a combination of more of mica powder, titanium dioxide, barium sulfate, lithopone, diatomite and kaolin.
The auxiliary agent comprises one or a combination of more of a flatting agent, a wetting agent, a dispersing agent, a defoaming agent, an anti-settling rheological agent and a pH regulator.
The particle size of the solid glass bead is 50-100 nm.
The film-forming assistant is one or a combination of a plurality of alcohol ester dodeca, propylene glycol monobutyl ether and monopropylene glycol methyl ether acetate.
The invention provides a preparation method of rare earth modified waterborne alkyd resin, which comprises the following steps:
a) adding vegetable oil, organic acid anhydride, polyol, dimethylolpropionic acid and dimethylbenzene in sequence according to the weight part of the formula in a multifunctional reaction kettle, and introducing N under the condition of low-speed stirring2To remove O in the reaction kettle2；
b) Heating to 105-110 ℃ until reflux, keeping the temperature for 0.5h, removing part of water, quickly heating to 150-160 ℃, fully stirring until the materials are dissolved, stirring at a rotating speed of 200-400 r/min for heat preservation reaction for 1h, then heating to 180 ℃ at a speed of 20 ℃/h for heat preservation reaction for 1h, adding benzoic acid, continuing to carry out heat preservation reaction for 1-1.5 h, heating to 210-220 ℃ at a speed of 20 ℃/h, carrying out heat preservation reaction for 3.0-3.5 h, measuring the acid value and the design value until the acid value and the design value are measured, and separating out water generated by the reaction by using a water separator;
c) cooling to 160 ℃ at a speed of 40 ℃/h, adding carboxylic acid Schiff base, stirring for reaction for 1-1.5 h, then quickly heating to 220-230 ℃, carrying out heat preservation for reaction for 3.0-4.0 h, measuring the acid value every 15-30 min, cooling to 160 ℃ when the acid value reaches a theoretical design value, starting vacuum evaporation to remove solvent xylene, cooling to below 50 ℃, adding a neutralizing agent, quickly stirring and dispersing for 15-20 min, adding deionized water with a formula amount, and continuously stirring for 0.5h until the mixture is uniformly dispersed to obtain the water-based alkyd resin;
d) heating the waterborne alkyd resin to 65-70 ℃, then dripping a rare earth ethanol solution, stirring and reacting for 0.5h, and reacting by using 0.5 mol.L-1And slowly adjusting the pH value of the solution to 7.0-7.5 by using the sodium ethoxide ethanol solution, continuously reacting for 2-2.5 h, stopping the reaction, and filtering to obtain the rare earth modified waterborne alkyd resin.
The invention discloses rare earth modified waterborne alkyd resin, which is based on the applied invention patent 'a rare earth modified waterborne alkyd resin and a preparation method thereof' and is described in detail.
The rare earth modified waterborne alkyd resin antibacterial luminescent coating prepared by the invention does not need luminescent powder and an antibacterial agent, and the antibacterial property and the luminescent property of the coating are mainly provided by a film-forming substance, namely the rare earth modified waterborne alkyd resin; the light-emitting material has the characteristics of good aging resistance, difficult pulverization, lasting antibacterial performance, long light-emitting duration and the like, and has wide application prospect.
Compared with the prior art, the invention has the following advantages:
1) the product of the invention takes water as a solvent, and does not contain toxic and harmful components such as heavy metal, organic solvent and the like;
2) the problems of easy pulverization, uneven dispersion and the like of the external luminescent powder are solved without the external luminescent powder;
3) the rare earth modified water-based alkyd resin with lasting antibacterial property is used as a main film forming substance of the coating, so that the coating has good antibacterial capability, and the defect of an additional antibacterial agent is overcome.
Detailed Description
The present invention is further described with reference to the following examples to prepare a rare earth modified waterborne alkyd antibacterial luminescent coating. It is to be understood that the specific embodiments described herein are merely illustrative of the relevant invention and not restrictive of the invention.
Example 1
A rare earth modified water-based alkyd resin X comprises the following steps:
a) adding 8.5 parts of dehydrated linseed oil, 7.8 parts of maleic anhydride, 2.2 parts of 1, 4-butanediol, 5.8 parts of trimethylolpropane, 1.8 parts of dimethylolpropionic acid and 8.0 parts of dimethylbenzene in sequence in a multifunctional reaction kettle according to the weight parts of the formula, and introducing N into the reaction kettle under low-speed stirring2To remove O in the reaction kettle2；
b) Heating to 105-110 ℃ until reflux, keeping the temperature for 0.5h, removing part of water, quickly heating to 150-160 ℃, fully stirring until the materials are dissolved, stirring at a rotating speed of 200-400 r/min for heat preservation reaction for 1h, then heating to 180 ℃ at a speed of 20 ℃/h for heat preservation reaction for 1h, adding 1.4 parts of benzoic acid, continuing to carry out heat preservation reaction for 1-1.5 h, heating to 210-220 ℃ at a speed of 20 ℃/h, carrying out heat preservation reaction for 3.0-3.5 h, measuring the acid value and the designed value until the acid value and the designed value are measured, and separating the water generated by the reaction by using a water separator;
c) cooling to 160 ℃ at a speed of 40 ℃/h, adding 1.8 parts of carboxylic acid Schiff base, stirring for reaction for 1-1.5 h, then quickly heating to 220-230 ℃, carrying out heat preservation reaction for 3.0-4.0 h, measuring the acid value every 15-30 min, cooling to 160 ℃ when the acid value reaches a theoretical design value, starting vacuum evaporation to remove solvent xylene, cooling to below 50 ℃, adding 3.5 parts of a neutralizing agent, quickly stirring for dispersion for 15-20 min, adding 57.5 parts of deionized water according to the formula amount, and continuously stirring for 0.5h until the solution is uniformly dispersed to obtain the water-based alkyd resin;
d) heating the water-based alkyd resin to 65-70 ℃, and then dropwise adding Nd (NO)3)30.8 part of ethanol solution is stirred and reacted for 0.5h, and 0.5 mol.L is used-1And slowly adjusting the pH value of the solution to 7.0-7.5 by using 0.9 part of sodium ethoxide ethanol, continuously reacting for 2-2.5 h, stopping the reaction, and filtering to obtain the rare earth modified waterborne alkyd resin X.
Example 2
A rare earth modified waterborne alkyd resin Y comprises the following steps:
a) adding 9.5 parts of dehydrated soybean oil, 2.8 parts of acetic anhydride, 7.2 parts of adipic acid, 3.2 parts of neopentyl glycol, 5.3 parts of pentaerythritol, 1.6 parts of dimethylolpropionic acid and 9.0 parts of dimethylbenzene in a multifunctional reaction kettle according to the weight parts of the formula in sequence, and introducing N into the mixture under low-speed stirring2To remove O in the reaction kettle2；
b) Heating to 105-110 ℃ until reflux, keeping the temperature for 0.5h, removing part of water, quickly heating to 150-160 ℃, fully stirring until the materials are dissolved, stirring at a rotating speed of 200-400 r/min for heat preservation reaction for 1h, then heating to 180 ℃ at a speed of 20 ℃/h for heat preservation reaction for 1h, adding 1.5 parts of benzoic acid, continuing to carry out heat preservation reaction for 1-1.5 h, heating to 210-220 ℃ at a speed of 20 ℃/h, carrying out heat preservation reaction for 3.0-3.5 h, measuring the acid value and the designed value until the acid value and the designed value are measured, and separating the water generated by the reaction by using a water separator;
c) cooling to 160 ℃ at a speed of 40 ℃/h, adding 2.0 parts of carboxylic acid Schiff base, stirring for reaction for 1-1.5 h, then quickly heating to 220-230 ℃, carrying out heat preservation reaction for 3.0-4.0 h, measuring the acid value every 15-30 min, cooling to 160 ℃ when the acid value reaches a theoretical design value, starting vacuum evaporation to remove solvent xylene, cooling to below 50 ℃, adding 3.8 parts of a neutralizing agent, quickly stirring for dispersion for 15-20 min, adding 52.1 parts of deionized water according to the formula amount, and continuously stirring for 0.5h until the solution is uniformly dispersed to obtain the water-based alkyd resin;
d) heating the water-based alkyd resin to 65-70 ℃, and then dropwise adding Eu (NO)3)30.9 part of ethanol solution is stirred and reacted for 0.5h, and 0.5 mol.L is used-1And slowly adjusting the pH value of the solution to 7.0-7.5 by using 1.1 parts of sodium ethoxide ethanol, continuously reacting for 2-2.5 hours, stopping the reaction, and filtering to obtain the rare earth modified waterborne alkyd resin Y.
Example 3
A rare earth modified water-based alkyd resin antibacterial luminescent coating comprises the following components in parts by weight: 40.0 parts of rare earth modified waterborne alkyd resin X, 18.0 parts of fluorine modified waterborne alkyd resin, 4.5 parts of diatomite, 5.5 parts of titanium dioxide, 3.5 parts of solid glass beads, 0.3 part of flatting agent, 0.5 part of wetting agent, 0.8 part of dispersing agent, 0.6 part of defoaming agent, 0.3 part of anti-settling rheological agent, 2.5 parts of pH regulator, 4.0 parts of film-forming auxiliary agent and 19.5 parts of deionized water.
Example 4
A rare earth modified water-based alkyd resin antibacterial luminescent coating comprises the following components in parts by weight: 52.0 parts of rare earth modified water-based alkyd resin Y, 20.0 parts of fluorine modified water-based alkyd resin, 3.5 parts of solid glass beads, 0.2 part of flatting agent, 0.3 part of wetting agent, 0.2 part of dispersing agent, 0.3 part of defoaming agent, 1.5 parts of pH regulator, 5.0 parts of film-forming assistant and 17.0 parts of deionized water.
The examples of the present invention were compared with aqueous alkyd resin paints (comparative examples) according to the relevant standards of water resistance (GB/T1733-1993), adhesion (GB/T9286-1998), pencil hardness (GB/T6739-1996), acid resistance (GB/T1763-1979), alkali resistance (GB/1763-.
Table 1: performance index of the examples of the invention and the aqueous alkyd resin coating (comparative example)
Although the present invention has been described in detail and with reference to exemplary embodiments thereof, it will be apparent to one skilled in the art that various changes, modifications and variations can be made therein without departing from the spirit and scope of the invention as defined in the appended claims.
Claims (11)
1. A rare earth modified water-based alkyd resin antibacterial luminescent coating is characterized in that: the composition comprises the following components in parts by weight: 35.0-55.0 parts of rare earth modified waterborne alkyd resin, 15.0-25.0 parts of fluorine modified waterborne alkyd resin, 0.0-25.0 parts of filler, 1.2-6.0 parts of assistant, 2.5-6.5 parts of solid glass beads, 3.5-6.5 parts of film-forming assistant and 10.0-30.0 parts of deionized water;
the rare earth modified waterborne alkyd resin comprises the following components in parts by weight: 6.5-13.0 parts of vegetable oil, 6.5-15.0 parts of organic acid anhydride, 1.5-3.0 parts of carboxylic acid Schiff base, 6.0-12.0 parts of polyol, 1.0-2.5 parts of benzoic acid, 1.5-2.5 parts of dimethylolpropionic acid, 0.6-1.5 parts of rare earth ethanol solution, 0.7-2.0 parts of sodium ethoxide ethanol solution, 6.0-12.0 parts of xylene, 3.0-5.0 parts of neutralizer and 45.0-65.0 parts of deionized water.
2. The rare earth-modified waterborne alkyd resin of claim 1, wherein: the vegetable oil is one or more of dehydrated linseed oil, dehydrated tung oil, dehydrated rapeseed oil, dehydrated peanut oil, dehydrated soybean oil and dehydrated castor oil.
3. The rare earth-modified waterborne alkyd resin of claim 1, wherein: the organic acid anhydride is one or a combination of more of acetic anhydride, maleic anhydride, adipic acid and sebacic acid.
4. The rare earth-modified waterborne alkyd resin of claim 1, wherein: the polyhydric alcohol is one or a combination of more of propylene glycol, 1, 4-butanediol, hexanediol, neopentyl glycol, diethylene glycol, dipropylene glycol, trimethylolpropane, glycerol and pentaerythritol.
5. The rare earth-modified waterborne alkyd resin of claim 1, wherein: the rare earth ethanol solution is 0.1 mol.L-1Nd (NO)3)3Ethanol solution, Eu (NO)3)3Ethanol solution, Gd (NO)3)3Ethanol solution, Dy (NO)3)3One or a combination of several of ethanol solution.
6. The rare earth-modified waterborne alkyd resin of claim 1, wherein: the neutralizing agent is at least one of triethylamine, ammonia water and dimethylethanolamine.
7. The rare earth-modified waterborne alkyd antibacterial luminescent coating of claim 1, wherein: the filler is one or a combination of more of mica powder, titanium dioxide, barium sulfate, lithopone, diatomite and kaolin.
8. The rare earth-modified waterborne alkyd antibacterial luminescent coating of claim 1, wherein: the auxiliary agent comprises one or a combination of more of a flatting agent, a wetting agent, a dispersing agent, a defoaming agent, an anti-settling rheological agent and a pH regulator.
9. The rare earth-modified waterborne alkyd antibacterial luminescent coating of claim 1, wherein: the particle size of the solid glass bead is 50-100 nm.
10. The rare earth-modified waterborne alkyd antibacterial luminescent coating of claim 1, wherein: the film-forming assistant is one or a combination of a plurality of alcohol ester dodeca, propylene glycol monobutyl ether and monopropylene glycol methyl ether acetate.
11. The rare earth-modified waterborne alkyd antibacterial luminescent coating of claim 1, wherein: the preparation method of the rare earth modified waterborne alkyd resin comprises the following preparation processes:
a) adding vegetable oil, organic acid anhydride, polyol, dimethylolpropionic acid and dimethylbenzene in sequence according to the weight part of the formula in a multifunctional reaction kettle, and introducing N under the condition of low-speed stirring2To remove O in the reaction kettle2；
b) Heating to 105-110 ℃ until reflux, keeping the temperature for 0.5h, removing part of water, quickly heating to 150-160 ℃, fully stirring until the materials are dissolved, stirring at a rotating speed of 200-400 r/min for heat preservation reaction for 1h, then heating to 180 ℃ at a speed of 20 ℃/h for heat preservation reaction for 1h, adding benzoic acid, continuing to carry out heat preservation reaction for 1-1.5 h, heating to 210-220 ℃ at a speed of 20 ℃/h, carrying out heat preservation reaction for 3.0-3.5 h, measuring the acid value and the design value until the acid value and the design value are measured, and separating out water generated by the reaction by using a water separator;
c) cooling to 160 ℃ at a speed of 40 ℃/h, adding carboxylic acid Schiff base, stirring for reaction for 1-1.5 h, then quickly heating to 220-230 ℃, carrying out heat preservation for reaction for 3.0-4.0 h, measuring the acid value every 15-30 min, cooling to 160 ℃ when the acid value reaches a theoretical design value, starting vacuum evaporation to remove solvent xylene, cooling to below 50 ℃, adding a neutralizing agent, quickly stirring and dispersing for 15-20 min, adding deionized water with a formula amount, and continuously stirring for 0.5h until the mixture is uniformly dispersed to obtain the water-based alkyd resin;
d) heating the waterborne alkyd resin to 65-70 ℃, then dripping a rare earth ethanol solution, stirring and reacting for 0.5h, and reacting by using 0.5 mol.L-1Slowly adjusting the pH value of the sodium ethoxide ethanol solution to 7.0-7.5, continuously reacting for 2-2.5 h, and stoppingAnd after reaction, filtering to obtain the rare earth modified waterborne alkyd resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910820184.9A CN110591431A (en) | 2019-09-01 | 2019-09-01 | Rare earth modified water-based alkyd resin antibacterial luminescent coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910820184.9A CN110591431A (en) | 2019-09-01 | 2019-09-01 | Rare earth modified water-based alkyd resin antibacterial luminescent coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110591431A true CN110591431A (en) | 2019-12-20 |
Family
ID=68856817
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910820184.9A Pending CN110591431A (en) | 2019-09-01 | 2019-09-01 | Rare earth modified water-based alkyd resin antibacterial luminescent coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110591431A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110540636A (en) * | 2019-09-01 | 2019-12-06 | 合众（佛山）化工有限公司 | rare earth modified waterborne alkyd resin and preparation method thereof |
| CN112625566A (en) * | 2020-12-18 | 2021-04-09 | 合众（佛山）化工有限公司 | Tripolyindenone derivative modified alkyd resin water-based paint |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1699374A (en) * | 2005-06-01 | 2005-11-23 | 西北大学 | 2-Acetylbenzimidazole glycine Schiff base rare earth complex and preparation method thereof |
| CN103709885A (en) * | 2013-12-27 | 2014-04-09 | 青岛乐化科技有限公司 | Water-based environment-friendly modified alkyd wood paint |
| CN107189661A (en) * | 2017-07-11 | 2017-09-22 | 合肥尚涵装饰工程有限公司 | A kind of road sign weather-proof reflecting coating material and preparation method thereof |
| CN107987693A (en) * | 2017-12-15 | 2018-05-04 | 合众（佛山）化工有限公司 | A kind of long-lasting antibacterial water alcohol acid coating |
| CN109554099A (en) * | 2018-10-31 | 2019-04-02 | 韶关市合众化工有限公司 | One kind water-base resin of structure polyurethane containing schiff bases and preparation method thereof |
-
2019
- 2019-09-01 CN CN201910820184.9A patent/CN110591431A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1699374A (en) * | 2005-06-01 | 2005-11-23 | 西北大学 | 2-Acetylbenzimidazole glycine Schiff base rare earth complex and preparation method thereof |
| CN103709885A (en) * | 2013-12-27 | 2014-04-09 | 青岛乐化科技有限公司 | Water-based environment-friendly modified alkyd wood paint |
| CN107189661A (en) * | 2017-07-11 | 2017-09-22 | 合肥尚涵装饰工程有限公司 | A kind of road sign weather-proof reflecting coating material and preparation method thereof |
| CN107987693A (en) * | 2017-12-15 | 2018-05-04 | 合众（佛山）化工有限公司 | A kind of long-lasting antibacterial water alcohol acid coating |
| CN109554099A (en) * | 2018-10-31 | 2019-04-02 | 韶关市合众化工有限公司 | One kind water-base resin of structure polyurethane containing schiff bases and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 崔玉民等: "《绿色环保功能涂料》", 31 January 2019, 中国书籍出版社 * |
| 徐迪 高保娇 陈萍虹: "侧链键合双齿席夫碱配基的聚苯乙烯的制备与表征及其Eu(Ⅲ) 配合物荧光发射性能之初探", 《应用化学》 * |
| 谢芳诚，刘国杰: "《最新涂料品种配方和工艺集》", 31 March 1996, 中国轻工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110540636A (en) * | 2019-09-01 | 2019-12-06 | 合众（佛山）化工有限公司 | rare earth modified waterborne alkyd resin and preparation method thereof |
| CN112625566A (en) * | 2020-12-18 | 2021-04-09 | 合众（佛山）化工有限公司 | Tripolyindenone derivative modified alkyd resin water-based paint |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110511603B (en) | Rose essential oil microcapsule emulsion and preparation method and application thereof | |
| CN101333349B (en) | Water-based luminescent coating containing nano-titanium dioxide-coated long-lasting light-storing material and preparation method thereof | |
| CN101423676B (en) | Method for preparing non-toxic visible ultraviolet heat insulating UV coating material | |
| CN101333357B (en) | Luminous paint and method for preparing same | |
| CN111675965B (en) | Energy-storage type environment-friendly luminous paint and preparation method thereof | |
| WO2019233161A1 (en) | Water-based heat-resistant paint and preparation method thereof | |
| CN107987693B (en) | Durable antibacterial water-based alkyd paint | |
| CN104263198A (en) | Nanocomposite road marking coating material | |
| CN103436249B (en) | A kind of luminous paint silicone covering type fluorescent material and its preparation method and application | |
| CN101935487A (en) | Automatic temperature control infrared radiation coating and application thereof | |
| CN106634420A (en) | High-weather-resistance anticorrosive intelligent street lamp | |
| CN105925178A (en) | Water-based organic and inorganic hybrid anticorrosive paint composition and preparing method thereof | |
| CN110591431A (en) | Rare earth modified water-based alkyd resin antibacterial luminescent coating | |
| CN105440925A (en) | Waterborne woodware surface color modifier | |
| CN106634382A (en) | Environment-friendly anticorrosion quick-drying type primer-topcoat integrated air-dry paint and preparation method thereof | |
| CN110564251A (en) | Rare earth functionalized water-based acrylic resin anti-fouling luminescent coating | |
| CN103881557B (en) | A kind of coloured UV coating | |
| CN105949947B (en) | Fluorescent paint, preparation method and application | |
| CN106947354A (en) | Aqueous acrylic modified two component epoxy paint for priming paint and top lacquer and preparation method thereof | |
| CN109370410A (en) | A kind of high performance nanometer energy storage aqueous luminous paint | |
| CN104341925A (en) | Photoluminescent coating material and preparation method thereof | |
| CN104356805A (en) | Anti-static thermal insulation water-based paint and preparation method thereof | |
| CN110643232A (en) | Energy-storage luminous anion water-based interior wall coating and preparation method thereof | |
| CN110564273B (en) | Rare earth modified polyester resin luminous antibacterial water-based paint | |
| CN101412890A (en) | Water-soluble semi-inorganic steel sheet varnish and preparation thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20191220 |
|
| RJ01 | Rejection of invention patent application after publication |