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CN110565394A - Anti-sticking gloss oil for case cloth with PVC coating and preparation method thereof - Google Patents

Anti-sticking gloss oil for case cloth with PVC coating and preparation method thereof Download PDF

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Publication number
CN110565394A
CN110565394A CN201910861942.1A CN201910861942A CN110565394A CN 110565394 A CN110565394 A CN 110565394A CN 201910861942 A CN201910861942 A CN 201910861942A CN 110565394 A CN110565394 A CN 110565394A
Authority
CN
China
Prior art keywords
gloss oil
pvc coating
stirring
polyvinyl chloride
chloride resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910861942.1A
Other languages
Chinese (zh)
Inventor
龙志亮
谢少鑫
何启倩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHONGSHAN ZHONGYI INK PAINT CO Ltd
Original Assignee
ZHONGSHAN ZHONGYI INK PAINT CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZHONGSHAN ZHONGYI INK PAINT CO Ltd filed Critical ZHONGSHAN ZHONGYI INK PAINT CO Ltd
Priority to CN201910861942.1A priority Critical patent/CN110565394A/en
Publication of CN110565394A publication Critical patent/CN110565394A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/10Properties of the materials having mechanical properties
    • D06N2209/108Slipping, anti-blocking, low friction
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/16Properties of the materials having other properties
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/12Decorative or sun protection articles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/12Decorative or sun protection articles
    • D06N2211/125Awnings, sunblinds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Paints Or Removers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a bag cloth anti-sticking gloss oil for a PVC coating, which comprises 30-35% of modified polyvinyl chloride resin, 40-45% of solvent, 19-29% of isophorone, 0.5-1% of defoaming agent and 0.3-0.5% of leveling agent, wherein the modified polyvinyl chloride resin has excellent adhesive force on a smooth surface, the solvent is used as a diluent to obviously improve the photocuring degree, the isophorone is a high-boiling point solvent and can stably disperse the modified polyvinyl chloride resin so as to form gloss oil with more stable and uniform performance, the defoaming agent has the function of reducing the surface tension of the product, and the leveling agent can promote the product to form a flat, smooth and uniform coating film in the drying and film-forming process. The prepared novel LED coating gloss oil ink has the advantages of no reverse adhesion, no bubbling and good leveling property, and is suitable for large-scale continuous production.

Description

anti-sticking gloss oil for case cloth with PVC coating and preparation method thereof
[ technical field ] A method for producing a semiconductor device
The invention relates to the technical field of high polymer materials, in particular to anti-sticking gloss oil for luggage cloth of a PVC coating and a preparation method thereof.
[ background of the invention ]
gloss oil is a product that has emerged with the rapid development of the packaging and printing industry. The gloss oil is coated on the surface of an object by adopting different printing processes to form a continuous solid layer with firm adhesion and certain strength, and the gloss oil is shiny after film formation, has superior performances such as hardness and wear resistance and the like, can well play a role in protecting printed pictures and texts, and is widely applied to the outer surfaces of food, beverage, shoes, clothes and packing boxes for cigarettes and wines based on the advantages.
in order to ensure the waterproof effect when the case cloth is made, a designer usually adds a PVC coating on the inner surface of the case cloth, and the PVC coating contains a large amount of plasticizer which can not be dried at normal temperature and can easily migrate to the surface of the bottom material when the temperature rises. The phenomenon of ink anti-sticking is easily caused when the traditional solvent type ink is printed on the luggage cloth, so that a large amount of defective products in a printing factory are accumulated, and the requirements of people cannot be met.
[ summary of the invention ]
The invention aims to solve the problem that the traditional printing ink for a PVC coating easily causes the phenomenon of ink anti-sticking, and provides the anti-sticking oil for the luggage cloth of the PVC coating, which has the advantages of no anti-sticking, no bubbling and good leveling property, wherein the luggage cloth of the PVC coating is mainly used for travel bags, sun umbrellas and various outdoor advertising sun-shading products, and the products of the type need more printed patterns, so the anti-sticking oil for the luggage cloth of the PVC coating has a great application prospect.
the invention also aims to provide a preparation method of the anti-sticking gloss oil for the luggage cloth of the PVC coating.
The technical scheme provided by the invention is as follows: the anti-sticking gloss oil for the luggage cloth of the PVC coating comprises the following components in parts by weight:
The modified polyvinyl chloride resin is one or a combination of CP-430 or CP-450. Preferably, the modified polyvinyl chloride resin is CP-450 produced by Korea company, is a white loose powdery low-polymerization-degree vinyl chloride-vinyl acetate copolymer, has an average polymerization degree of 450 +/-50 and a volatile content of less than 4.0 percent, has excellent water resistance and heat resistance, has excellent adhesive force on a smooth surface, good printability and high drying speed, and is suitable for high-speed printing.
preferably, the solvent is one or a combination of cyclohexanone, butanone and toluene. Preferably, the solvent is cyclohexanone which is used as a diluent to fully dissolve the modified polyvinyl chloride resin, so that the photocuring degree can be obviously improved, and the adhesive force can be improved.
Preferably, the isophorone is 3,5, 5-trimethyl-2-cyclic ethylene-1-one produced by WingIngdiosai. The modified polyvinyl chloride resin can be well dissolved as a high-boiling point solvent, so that the modified polyvinyl chloride resin is stably dispersed, and the gloss oil with more stable and uniform performance is formed.
Preferably, the defoaming agent is one or a combination of BYK-034, BYK-036 and BYK-054. The defoaming agent has the functions of reducing the surface tension of the product, inhibiting the generation of foam and eliminating the generated foam, so that the invention has good stability and good leveling property. The preferable defoaming agent is Germany Bick BYK-054, has excellent defoaming and defoaming performances, can eliminate bubbles on the surface of a coating film, and is favorable for improving the leveling performance of the gloss oil.
Preferably, the leveling agent is one or a combination of BYK-301, BYK-306 and BYK-333. The leveling agent can promote the product to form a flat, smooth and uniform coating film in the drying film-forming process. Preferably, the leveling agent is German Bick BYK-333, which has excellent substrate wetting properties, reduces surface tension, prevents cratering and increases surface smoothness.
A preparation method of anti-sticking gloss oil for case cloth of a PVC coating comprises the following steps:
S1, weighing the components in parts by weight for later use;
S2, putting the solvent and the isophorone into a stirrer to be mixed and stirred at the stirring speed of 80-120 r/min to obtain a mixed material A;
s3, slowly adding the modified polyvinyl chloride resin into the mixed material A for mixing and stirring, wherein the stirring speed is 800-1200 r/min, the stirring time is 30-50 minutes, and after stirring, standing for 18-30 hours to obtain a mixed material B;
and S4, adding the defoaming agent and the flatting agent into the mixed material B, mixing and stirring at the stirring speed of 800-1200 r/min for 8-15 minutes to obtain the composite material.
Preferably, the stirring time in step S2 is 30 to 150 minutes.
compared with the prior art, the invention has the following advantages:
The technical scheme of the anti-sticking gloss oil for the luggage cloth of the PVC coating comprises 30-35% of modified polyvinyl chloride resin, 40-45% of solvent, 19-29% of isophorone, 0.5-1% of defoaming agent and 0.3-0.5% of flatting agent, wherein the modified polyvinyl chloride resin is CP-450, has excellent water resistance and heat resistance, has excellent adhesive force on a smooth surface, good printability and high drying speed, is suitable for high-speed printing, the solvent is used as a diluent to fully dissolve the modified polyvinyl chloride resin, can obviously improve the photocuring degree and the adhesive force, the isophorone is a high-boiling point solvent and can well dissolve the modified polyvinyl chloride resin to stably disperse the modified polyvinyl chloride resin, so that the gloss oil with more stable and uniform performance is formed, and the defoaming agent has the function of reducing the surface tension of the product, the leveling agent can promote the product to form a flat, smooth and uniform coating film in the drying film-forming process, so that the foam-free water-based paint has good stability and leveling property. The product is prepared in the embodiment of the application, and is printed on the PVC coating case cloth through an anti-adhesion performance test, the PVC coating case cloth is dried for 24 hours, the PVC coating case cloth is placed in a 60-degree oven, five kilograms of PVC coating case cloth are pressed by weight, the anti-adhesion performance is observed after 72 hours, the anti-adhesion phenomenon does not occur in the test result, and meanwhile, the printing test does not foam and has good leveling property, so that the PVC coating case cloth has a good curing effect and excellent adhesive force.
the preparation method of the anti-sticking oil for the luggage cloth of the PVC coating has the advantages of simple preparation technology, mild reaction and environmental protection, and the prepared novel LED coating gloss oil ink has the characteristics of no anti-sticking, no bubbling and good leveling property, and the luggage cloth of the PVC coating is mainly used for travel bags, sun umbrellas and various outdoor advertising sun-shading products, and the products of the type need more printed patterns, so the anti-sticking oil for the luggage cloth of the PVC coating has a great application prospect and is suitable for large-batch continuous production.
[ detailed description ] embodiments
The following describes a specific technical scheme of the present invention with reference to specific examples 1 to 4:
example 1:
an anti-sticking gloss oil for luggage cloth of a PVC coating comprises the following components by weight,
the preparation method comprises the following steps:
Weighing the components according to the weight ratio in the table 1, putting the solvent and the isophorone into a stirrer, setting the stirring speed to be 100r/min, mixing, stirring and stirring for 100 minutes, slowly adding the modified polyvinyl chloride resin, mixing and stirring for 40 minutes at the stirring speed of 1000r/min, standing for 24 hours after stirring is finished, slowly adding the defoaming agent and the flatting agent, and mixing and stirring for 10 minutes at the stirring speed of 1000r/min to obtain the polyvinyl chloride resin.
example 2:
an anti-sticking gloss oil for luggage cloth of a PVC coating comprises the following components by weight,
The preparation method comprises the following steps:
weighing the components according to the weight ratio in the table 1, putting the solvent and the isophorone into a stirrer, setting the stirring speed to 80r/min, mixing, stirring and stirring for 150 minutes, slowly adding the modified polyvinyl chloride resin, mixing and stirring for 30 minutes at the stirring speed of 1200r/min, standing for 28 hours after stirring is finished, slowly adding the defoaming agent and the flatting agent, stirring for 900r/min, and mixing and stirring for 15 minutes to obtain the polyvinyl chloride resin.
example 3:
an anti-sticking gloss oil for luggage cloth of a PVC coating comprises the following components by weight,
The preparation method comprises the following steps:
Weighing the components according to the weight ratio in the table 1, putting the solvent and the isophorone into a stirrer, setting the stirring speed to 120r/min, mixing and stirring for 60 minutes, slowly adding the modified polyvinyl chloride resin, mixing and stirring for 50 minutes at the stirring speed of 900r/min, standing for 22 hours after stirring is finished, slowly adding the defoaming agent and the flatting agent, and mixing and stirring for 12 minutes at the stirring speed of 1200r/min to obtain the polyvinyl chloride resin.
example 4:
an anti-sticking gloss oil for luggage cloth of a PVC coating comprises the following components by weight,
The preparation method comprises the following steps:
Weighing the components according to the weight ratio in the table 1, putting the solvent and the isophorone into a stirrer, setting the stirring speed to 90r/min, mixing, stirring and stirring for 100 minutes, slowly adding the modified polyvinyl chloride resin, mixing and stirring for 40 minutes at the stirring speed of 800r/min, standing for 20 hours after stirring is finished, slowly adding the defoaming agent and the flatting agent, and mixing and stirring for 8 minutes at the stirring speed of 800r/min to obtain the polyvinyl chloride resin.
Table 1: the anti-sticking gloss oil for the luggage cloth of the PVC coating in the embodiments 1 to 4 has the following components:
The novel LED coating gloss oil ink prepared in the examples 1 to 4 is subjected to performance test, and the test results are shown in Table 2:
as can be seen from the test data in Table 2, the product prepared in the example of the application is printed on the PVC coated luggage cloth through the anti-adhesion performance test, the PVC coated luggage cloth is dried for 24 hours, the PVC coated luggage cloth is placed in a 60-degree oven, the anti-adhesion performance is observed after five kilograms of heavy pressure is carried out for 72 hours, the anti-adhesion phenomenon does not occur in the test result, and meanwhile, the printing test does not foam, the leveling property is good, and the application has a good curing effect and excellent adhesive force. The technical scheme of the anti-sticking gloss oil for the luggage cloth of the PVC coating comprises 30-35% of modified polyvinyl chloride resin, 40-45% of solvent, 19-29% of isophorone, 0.5-1% of defoaming agent and 0.3-0.5% of flatting agent, wherein the modified polyvinyl chloride resin is CP-450, has excellent water resistance and heat resistance, has excellent adhesive force on a smooth surface, good printability and high drying speed, is suitable for high-speed printing, the solvent is used as a diluent to fully dissolve the modified polyvinyl chloride resin, can obviously improve the photocuring degree and the adhesive force, the isophorone is a high-boiling point solvent and can well dissolve the modified polyvinyl chloride resin to stably disperse the modified polyvinyl chloride resin, so that the gloss oil with more stable and uniform performance is formed, and the defoaming agent has the function of reducing the surface tension of the product, the leveling agent can promote the product to form a flat, smooth and uniform coating film in the drying film-forming process, so that the foam-free water-based paint has good stability and leveling property. The application provides a case cloth anti-sticking gloss oil for PVC coating, and the case cloth of PVC coating is mainly used for traveling bag, sun umbrella and various outdoor advertisement sunshade articles, and this type of product needs the printing pattern variety more, therefore the case cloth anti-sticking gloss oil for PVC coating has very big application prospect.

Claims (8)

1. The anti-sticking gloss oil for the luggage cloth of the PVC coating is characterized by comprising the following components in parts by weight:
2. The anti-stick gloss oil for the luggage cloth of the PVC coating layer, according to the claim 1, is characterized in that: the modified polyvinyl chloride resin is one or a combination of CP-430 or CP-450.
3. The anti-stick gloss oil for the luggage cloth of the PVC coating layer, according to the claim 1, is characterized in that: the solvent is one or a combination of cyclohexanone, butanone and toluene.
4. The anti-stick gloss oil for the luggage cloth of the PVC coating layer, according to the claim 1, is characterized in that: the isophorone is 3,5, 5-trimethyl-2-cyclic ethylene-1-ketone produced by Wingchuang Delgaseitai company.
5. the anti-stick gloss oil for the luggage cloth of the PVC coating layer, according to the claim 1, is characterized in that: the defoaming agent is one or a combination of BYK-034, BYK-036 and BYK-054.
6. The anti-stick gloss oil for the luggage cloth of the PVC coating layer, according to the claim 1, is characterized in that: the leveling agent is one or a combination of BYK-301, BYK-306 and BYK-333.
7. The preparation method of the anti-sticking gloss oil for the luggage cloth of the PVC coating layer according to any one of claims 1 to 6, characterized by comprising the following steps:
S1, weighing the components in parts by weight for later use;
S2, putting the solvent and the isophorone into a stirrer to be mixed and stirred at the stirring speed of 80-120 r/min to obtain a mixed material A;
s3, slowly adding the modified polyvinyl chloride resin into the mixed material A for mixing and stirring, wherein the stirring speed is 800-1200 r/min, the stirring time is 30-50 minutes, and after stirring, standing for 18-30 hours to obtain a mixed material B;
And S4, adding the defoaming agent and the flatting agent into the mixed material B, mixing and stirring at the stirring speed of 800-1200 r/min for 8-15 minutes to obtain the composite material.
8. the preparation method of the anti-stick gloss oil for the PVC coated luggage cloth according to claim 7, wherein the anti-stick gloss oil comprises the following steps: in the step S2, the stirring time is 30-150 minutes.
CN201910861942.1A 2019-09-12 2019-09-12 Anti-sticking gloss oil for case cloth with PVC coating and preparation method thereof Pending CN110565394A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910861942.1A CN110565394A (en) 2019-09-12 2019-09-12 Anti-sticking gloss oil for case cloth with PVC coating and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910861942.1A CN110565394A (en) 2019-09-12 2019-09-12 Anti-sticking gloss oil for case cloth with PVC coating and preparation method thereof

Publications (1)

Publication Number Publication Date
CN110565394A true CN110565394A (en) 2019-12-13

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102002280A (en) * 2009-09-01 2011-04-06 尚盟运动用品(惠阳)有限公司 Low-temperature quick-drying type thermosetting ink
CN102250513A (en) * 2011-01-19 2011-11-23 一可油墨涂料(深圳)有限公司 Polycyclic aromatic hydrocarbon-free screen printing ink for polyvinyl chloride (PVC) and polycarbonate (PC) materials
CN104817661A (en) * 2015-04-24 2015-08-05 陈良伢 A kind of safe and environment-friendly water-based ink coating varnish resin and its preparation process
CN105925190A (en) * 2016-06-22 2016-09-07 苏州中亚油墨有限公司 Anti-static and scratch-resisting transparent matte gloss oil
CN105949978A (en) * 2016-06-22 2016-09-21 苏州中亚油墨有限公司 Antiaging high-covering-power matte gloss oil
CN106479262A (en) * 2016-10-20 2017-03-08 中华制漆(深圳)有限公司 IMR dumb light ink and its preparation and application
CN110204979A (en) * 2019-05-29 2019-09-06 安徽集友新材料股份有限公司 Dumb paint and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102002280A (en) * 2009-09-01 2011-04-06 尚盟运动用品(惠阳)有限公司 Low-temperature quick-drying type thermosetting ink
CN102250513A (en) * 2011-01-19 2011-11-23 一可油墨涂料(深圳)有限公司 Polycyclic aromatic hydrocarbon-free screen printing ink for polyvinyl chloride (PVC) and polycarbonate (PC) materials
CN104817661A (en) * 2015-04-24 2015-08-05 陈良伢 A kind of safe and environment-friendly water-based ink coating varnish resin and its preparation process
CN105925190A (en) * 2016-06-22 2016-09-07 苏州中亚油墨有限公司 Anti-static and scratch-resisting transparent matte gloss oil
CN105949978A (en) * 2016-06-22 2016-09-21 苏州中亚油墨有限公司 Antiaging high-covering-power matte gloss oil
CN106479262A (en) * 2016-10-20 2017-03-08 中华制漆(深圳)有限公司 IMR dumb light ink and its preparation and application
CN110204979A (en) * 2019-05-29 2019-09-06 安徽集友新材料股份有限公司 Dumb paint and preparation method thereof

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Application publication date: 20191213

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