CN110527906A - 600-grade wear-resistant composite board and production method thereof - Google Patents
600-grade wear-resistant composite board and production method thereof Download PDFInfo
- Publication number
- CN110527906A CN110527906A CN201910821754.6A CN201910821754A CN110527906A CN 110527906 A CN110527906 A CN 110527906A CN 201910821754 A CN201910821754 A CN 201910821754A CN 110527906 A CN110527906 A CN 110527906A
- Authority
- CN
- China
- Prior art keywords
- composite
- wear
- billet
- resistant
- base material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 153
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 72
- 239000010959 steel Substances 0.000 claims abstract description 72
- 238000003466 welding Methods 0.000 claims abstract description 55
- 238000000034 method Methods 0.000 claims abstract description 39
- 239000000463 material Substances 0.000 claims abstract description 37
- 238000010438 heat treatment Methods 0.000 claims abstract description 25
- 230000008569 process Effects 0.000 claims abstract description 24
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 22
- 238000007789 sealing Methods 0.000 claims abstract description 21
- 229910000851 Alloy steel Inorganic materials 0.000 claims abstract description 10
- 238000010894 electron beam technology Methods 0.000 claims abstract description 8
- 238000005096 rolling process Methods 0.000 claims description 28
- 238000001816 cooling Methods 0.000 claims description 11
- 229910052719 titanium Inorganic materials 0.000 claims description 9
- 229910052796 boron Inorganic materials 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 7
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 230000009467 reduction Effects 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 229910052758 niobium Inorganic materials 0.000 claims description 4
- 238000004321 preservation Methods 0.000 claims description 4
- 238000009749 continuous casting Methods 0.000 claims description 3
- 238000005238 degreasing Methods 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- 230000035515 penetration Effects 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 2
- 229910001055 inconels 600 Inorganic materials 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 238000004381 surface treatment Methods 0.000 claims description 2
- 238000009966 trimming Methods 0.000 claims description 2
- 238000009489 vacuum treatment Methods 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 13
- 239000010949 copper Substances 0.000 description 13
- 239000010936 titanium Substances 0.000 description 10
- 239000010955 niobium Substances 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000011651 chromium Substances 0.000 description 7
- 239000000758 substrate Substances 0.000 description 6
- 229910001566 austenite Inorganic materials 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 230000035945 sensitivity Effects 0.000 description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 229910000734 martensite Inorganic materials 0.000 description 4
- 238000012827 research and development Methods 0.000 description 4
- 238000005728 strengthening Methods 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000006104 solid solution Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 229910017464 nitrogen compound Inorganic materials 0.000 description 2
- 150000002830 nitrogen compounds Chemical class 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- INZDTEICWPZYJM-UHFFFAOYSA-N 1-(chloromethyl)-4-[4-(chloromethyl)phenyl]benzene Chemical compound C1=CC(CCl)=CC=C1C1=CC=C(CCl)C=C1 INZDTEICWPZYJM-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910002555 FeNi Inorganic materials 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- 229910000617 Mangalloy Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000011157 advanced composite material Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- UPHIPHFJVNKLMR-UHFFFAOYSA-N chromium iron Chemical compound [Cr].[Fe] UPHIPHFJVNKLMR-UHFFFAOYSA-N 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- UNASZPQZIFZUSI-UHFFFAOYSA-N methylidyneniobium Chemical compound [Nb]#C UNASZPQZIFZUSI-UHFFFAOYSA-N 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000002436 steel type Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/38—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling sheets of limited length, e.g. folded sheets, superimposed sheets, pack rolling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C37/00—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
- B21C37/02—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
- B32B15/011—Layered products comprising a layer of metal all layers being exclusively metallic all layers being formed of iron alloys or steels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/0012—Mechanical treatment, e.g. roughening, deforming, stretching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/16—Drying; Softening; Cleaning
- B32B38/162—Cleaning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/08—Interconnection of layers by mechanical means
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/20—Ferrous alloys, e.g. steel alloys containing chromium with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/38—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling sheets of limited length, e.g. folded sheets, superimposed sheets, pack rolling
- B21B2001/386—Plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
Abstract
本发明公开一种600级耐磨复合板及其生产方法。复合板由基材和复材组成,基材为低碳低合金钢;复材为600级别耐磨钢。将复合坯抽取真空后进行真空电子束密封焊接,焊接工艺为双枪联动,且每条焊缝的进行焊接时,将其分为N段,N≥10,每段长度为100~200mm;复合坯加热时采用“中心加热”方式,使复合坯处于由中心直接受热并向四周传导的方式升温;复合坯在出炉前1~2h,提高复合坯头尾处上表面火焰口温度50~60℃;成品复合板厚度为20~100mm。复合板复合面抗剪切强度≥508MPa,结合率为100%,复合层布氏硬度≥572,室温冲击功≥132J,用于易磨损设备上。
The invention discloses a 600-grade wear-resistant composite plate and a production method thereof. The composite plate is composed of a base material and a composite material, the base material is low-carbon low-alloy steel; the composite material is 600-grade wear-resistant steel. Vacuum the composite billet and carry out vacuum electron beam sealing welding. The welding process is double gun linkage, and when welding each weld seam, it is divided into N sections, N≥10, and the length of each section is 100-200mm; composite When the billet is heated, the "center heating" method is adopted, so that the composite billet is heated directly from the center and conducted to the surroundings; the composite billet is heated 1 to 2 hours before it is released from the furnace, and the temperature of the flame port on the upper surface of the composite billet at the head and tail is increased by 50-60 °C ; The thickness of the finished composite board is 20-100mm. The shear strength of the composite surface of the composite board is ≥508MPa, the bonding rate is 100%, the Brinell hardness of the composite layer is ≥572, and the impact energy at room temperature is ≥132J. It is used for wear-resistant equipment.
Description
技术领域technical field
本发明属于金属材料加工技术领域,特别涉及到一种高应用真空复合+轧制技术生产600级耐磨复合板的方法。The invention belongs to the technical field of metal material processing, and in particular relates to a method for producing a 600-grade wear-resistant composite plate using a highly applied vacuum composite + rolling technology.
背景技术Background technique
复合耐磨钢板是一种采用先进复合制造技术生产的耐磨复合材料,是工业领域先进的耐磨复合材料。由于耐磨复合钢板的基板采用塑韧性很好的普碳低合金钢,可在受冲击的过程中吸收能量,因而,耐磨复合钢板较单质耐磨钢具有很强的抗冲击性能和抗裂性能,可以应用的振动、冲击较强的工况条件下。同时,耐磨复合钢板可以制成标准尺寸的钢板,重量轻,加工方便灵活。由于采用软质基板,因而可以向内冷弯成形,可以用等离子弧、碳弧等热源切割。另外,复合钢板虽然因材料和工艺原因价格高于普通钢板,但其使用寿命的大幅提高,使得应用在磨损环境下的设备停机检修时间和维修费用大为减少。据估算,复合钢板的性价比比普通耐磨钢板高约2~4倍,物料处理量越大,设备磨损越严重的企业,使用复合钢板的经济效益越明显。因此,复合耐磨钢板广泛应用在冶金机械、建材机械、电力机械、矿山机械等行业中的各种易磨损设备上。Composite wear-resistant steel plate is a kind of wear-resistant composite material produced by advanced composite manufacturing technology, and it is an advanced wear-resistant composite material in the industrial field. Since the substrate of the wear-resistant composite steel plate is made of ordinary carbon low-alloy steel with good plasticity and toughness, it can absorb energy during the impact process. Therefore, the wear-resistant composite steel plate has stronger impact resistance and crack resistance than simple wear-resistant steel. performance, it can be applied under working conditions with strong vibration and impact. At the same time, the wear-resistant composite steel plate can be made into a standard-sized steel plate, which is light in weight and convenient and flexible in processing. Due to the use of soft substrates, it can be cold-bent inwards, and can be cut by heat sources such as plasma arcs and carbon arcs. In addition, although the price of composite steel plate is higher than that of ordinary steel plate due to material and process reasons, its service life is greatly improved, which greatly reduces the downtime and maintenance time and maintenance costs of equipment used in abrasive environments. According to estimates, the cost performance of composite steel plates is about 2 to 4 times higher than that of ordinary wear-resistant steel plates. The greater the material handling capacity and the more serious equipment wear, the more obvious the economic benefits of using composite steel plates. Therefore, composite wear-resistant steel plates are widely used in various wear-resistant equipment in metallurgical machinery, building materials machinery, electric machinery, mining machinery and other industries.
目前,国内耐磨复合板主要以堆焊法为主,如耐磨焊条堆焊、药芯焊丝堆焊、等离子堆焊。同时,关于粉末法、钎焊法和扩散法等也开展了相关的研发工作。但是,这些工艺都有其各自的局限性耐磨焊条堆焊采用高Cr高C铸铁焊条进行堆焊,受铸铁焊条长度限制,难以实现自动化焊接;药芯焊丝堆焊层的性能受药芯填充率和外围铁皮稀释的影响,强化相含量难以提高,进而影响耐磨板性能;等离子堆焊制备的耐磨板具有硬度和耐磨性高的特点,但是该工艺堆焊效率较低,难以大规模推广。在此背景下,广大学者开展了大量关于耐磨复合板制备技术的研发工作。At present, domestic wear-resistant composite panels are mainly based on surfacing methods, such as wear-resistant electrode surfacing, flux-cored wire surfacing, and plasma surfacing. At the same time, related research and development work has also been carried out on powder method, brazing method and diffusion method. However, these processes have their own limitations. Wear-resistant electrode surfacing welding uses high Cr and high C cast iron electrodes for surfacing welding. Due to the length limitation of cast iron electrodes, it is difficult to realize automatic welding; Influenced by the rate and the dilution of the peripheral iron sheet, it is difficult to increase the content of the strengthening phase, which in turn affects the performance of the wear-resistant plate; the wear-resistant plate prepared by plasma surfacing welding has the characteristics of high hardness and wear resistance, but the surfacing welding efficiency of this process is low, and it is difficult to increase Scale promotion. In this context, scholars have carried out a lot of research and development work on the preparation technology of wear-resistant composite plates.
CN101774288A公开了一种“金属机件耐磨复合板及其修复工艺”、文献“一种耐磨复合板的制造工艺方法研究”(许可贵,程志国,刘健威等,发表在《焊接》2010年第8期37~40页)和文献“带极堆焊制备耐磨复合板”(陆峰,王元宗,王林彦发表在《第十四届全国耐磨材料大会》2015年390~394页)均采用在基体钢板上堆焊耐磨焊缝的方式进行耐磨复合板的制备,其耐磨性比低碳钢高12~18倍,比不锈钢、高锰钢高5倍,比铸态高铬铁高1倍。但是其生产效率较低,生产成本较高,并不适用于工业化大生产。CN101774288A discloses a "wear-resistant composite plate for metal parts and its repair process", and the document "Research on a Manufacturing Process Method for Wear-resistant Composite Plate" (Xuangui, Cheng Zhiguo, Liu Jianwei, etc., published in "Welding" 2010 No. 8 Issue 37-40 pages) and the literature "Preparation of Wear-resistant Composite Plates by Overlay Welding" (Lu Feng, Wang Yuanzong, Wang Linyan published in "The Fourteenth National Conference on Wear-resistant Materials" 2015, pages 390-394) are used in The wear-resistant composite plate is prepared by surfacing wear-resistant welds on the base steel plate. Its wear resistance is 12 to 18 times higher than that of low carbon steel, 5 times higher than stainless steel and high manganese steel, and higher than cast high chromium iron. 1 times. However, its production efficiency is low and production cost is high, so it is not suitable for industrialized large-scale production.
CN102212821A公开了“一种强化碳化钨耐磨复合板的制备方法”、CN102212822A公开了“一种金属耐磨复合板的加工方法及其加工装置”、CN102218615A公开了“一种制备加厚耐磨层复合板的方法”,上述三个专利均采用在基体钢板上铺撒相关粉末经加热炉热处理后形成耐磨复合板的方法进行耐磨复合板的制备,其工作层的耐磨合金不仅表面平整、美观,而且可以直接用于要求表面平整的工况(如挡板等)。但是,该工艺制备耐磨复合板耐磨层致密性较差,耐磨性能和使用寿命较低,无法满足日益增长的工程应用的实际需求。CN102212821A discloses "a method for preparing a reinforced tungsten carbide wear-resistant composite plate", CN102212822A discloses "a processing method and a processing device for a metal wear-resistant composite plate", and CN102218615A discloses "a method for preparing a thickened wear-resistant layer The above three patents all use the method of spreading relevant powder on the base steel plate to form a wear-resistant composite plate after heat treatment in a heating furnace. The wear-resistant alloy of the working layer is not only smooth , beautiful, and can be directly used in working conditions that require smooth surfaces (such as baffles, etc.). However, the wear-resistant composite plate prepared by this process has poor compactness, low wear resistance and low service life, and cannot meet the actual needs of increasing engineering applications.
CN107557537A公开了“高韧高耐磨复合板的制备方法”、CN103264259A公开了“一种耐磨耐火砖模具板及其快速制备方法”,上述两个专利均采用加热或添加过渡金属的方式使耐磨板和基体钢板之间形成冶金连接的方式进行耐磨复合板的制备,其耐磨耐腐蚀性高,生产效率高,寿命长,成本低,节能环保。但是,该工艺依靠无压力扩散或钎料连接的方式进行耐磨复合板的制备,其复合界面的抗剪切性能较低,易出现分层、剥落等缺陷,无法满足高负载使用环境下的应用,且使用寿命无可靠保障。CN107557537A discloses "preparation method of high-toughness and high wear-resistance composite board", CN103264259A discloses "a kind of wear-resistant refractory brick mold board and its rapid preparation method", both of the above two patents use heating or adding transition metals to make resistant The wear-resistant composite plate is prepared by forming a metallurgical connection between the grinding plate and the base steel plate, which has high wear resistance and corrosion resistance, high production efficiency, long service life, low cost, energy saving and environmental protection. However, this process relies on pressure-free diffusion or solder connection to prepare wear-resistant composite plates. The shear resistance of the composite interface is low, and defects such as delamination and peeling are prone to occur, which cannot meet the requirements of high-load environments. application, and there is no reliable guarantee for the service life.
综上所述,目前耐磨复合板的制备工艺仍是以传统的堆焊法为主,其它生产工艺虽然也逐步开展了相关研发工作,但仍存在较多的问题,具有较大的局限性。同时,目前国内市场常用的耐磨复合板为360至450级别,对于450级别以上的耐磨复合板展开的研发工作较少,缺乏大量的研究数据支持,极大的限制了耐磨复合板的应用。To sum up, the current preparation process of wear-resistant composite plates is still dominated by the traditional surfacing method. Although other production processes have gradually carried out related research and development work, there are still many problems and limitations. . At the same time, the commonly used wear-resistant composite panels in the domestic market are 360 to 450 grades. There is less research and development work on wear-resistant composite panels above 450 grades, and there is a lack of a large amount of research data support, which greatly limits the use of wear-resistant composite panels. application.
面对工程应用领域日益增长的耐磨复合板的需求,特别是高硬度级别的耐磨复合板,迫切需要一种高效、稳定的制备工艺用以生产高级别的耐磨复合板。轧制法是一种新兴的高效的复合板制备工艺,一般由真空组坯、加热和轧制工艺构成。但是在高级别耐磨复合板的制备过程中,由于耐磨钢和基层钢材的物理化学性能差异,常出现接头失效和板型控制问题。首先,由于耐磨钢含碳量较高,在组坯封焊时易出现焊接裂纹,尤其在大规格的复合坯料封焊时,其焊接形变和焊接应力集中明显,更容易发生接头开裂、失效。其次,在复合坯加热过程中,由于复合坯的加热形变不一致,应力直接作用在焊接接头位置,也容易出现封焊接头开裂失效问题。在采用常规轧制法制备高耐磨复合板的过程中,经常出现复合坯在封焊后或加热过程中封焊接头就开裂失效的情况。另外,在复合坯轧制的过程中,也常出现耐磨钢和基层钢材变形不一致,发生翘曲的问题,甚至由于翘曲过大无法继续轧制。基于上述问题,常规轧制法复合工艺制备高级别耐磨钢复合板的成功率仅为50%左右。Faced with the increasing demand for wear-resistant composite panels in the field of engineering applications, especially high-hardness wear-resistant composite panels, an efficient and stable preparation process is urgently needed to produce high-grade wear-resistant composite panels. The rolling method is a new and efficient composite plate preparation process, which generally consists of vacuum forming, heating and rolling processes. However, in the preparation process of high-grade wear-resistant composite plates, due to the difference in physical and chemical properties between wear-resistant steel and base steel, joint failure and plate shape control problems often occur. First of all, due to the high carbon content of wear-resistant steel, welding cracks are prone to occur when the billets are sealed and welded, especially when large-scale composite billets are sealed and welded, the welding deformation and welding stress concentration are obvious, and joint cracking and failure are more likely to occur . Secondly, during the heating process of the composite blank, due to the inconsistent heating deformation of the composite blank, the stress directly acts on the position of the welded joint, and the problem of cracking and failure of the welded joint is also prone to occur. In the process of preparing high wear-resistant composite plates by conventional rolling method, it often occurs that the sealing and welding joints of the composite billet crack and fail after sealing or heating. In addition, in the process of rolling the composite billet, the deformation of the wear-resistant steel and the base steel are often inconsistent, and the problem of warping occurs, and even the rolling cannot be continued due to excessive warping. Based on the above problems, the success rate of producing high-grade wear-resistant steel clad plates by the conventional rolling process is only about 50%.
发明内容Contents of the invention
基于上述现有技术的不足,本发明的目的是提供了一种高效、稳定的600级耐磨复合板的制备方法,通过优化组坯封焊和加热工艺,调控组坯封焊过程中的应力分布状态和复合坯的温度场分布状态,取得明显的控制效果,大幅度提高制备600级耐磨复合板的成功率,生产的高级别复合板复合面抗剪切强度≥500MPa、耐磨层硬度达到600级别,复合板成功率可达80%以上。板形平整,复合界面性能稳定,且具备优异的耐磨性能。Based on the deficiencies of the above-mentioned prior art, the purpose of the present invention is to provide an efficient and stable preparation method of 600-grade wear-resistant composite plate, by optimizing the sealing welding and heating process of the blank assembly, the stress in the sealing welding process of the blank assembly is regulated The distribution state and the temperature field distribution state of the composite billet have achieved obvious control effects, greatly improving the success rate of preparing 600-grade wear-resistant composite panels. Reaching level 600, the success rate of composite panels can reach more than 80%. The plate shape is flat, the composite interface performance is stable, and it has excellent wear resistance.
一种600级耐磨复合板,由低碳低合金钢与600级耐磨钢复合而成,其中,低碳低合金钢中的C含量按质量百分比计为C≤0.22%,复材为600级耐磨钢,按质量百分比计,钢中含有C:0.35%~0.40%、Si:0.4%~0.6%、Mn:0.40%~1.00%、Cr:0.8%~1.8%、Mo:0.2%~0.6%、Nb:0.01%~0.03%、Ni≤0.60%、Cu≤0.60%、B:0.0005%~0.0022%、Ti:0.025%~0.04%、Als:0.025%~0.045%、P≤0.015%、S≤0.005%、[N]≤0.0080%、[O]≤0.0020%,且Ti/N≥3.4,余量为Fe及不可避免的杂质。A 600-grade wear-resistant composite plate, which is composed of low-carbon low-alloy steel and 600-grade wear-resistant steel, wherein the C content in the low-carbon low-alloy steel is C≤0.22% by mass percentage, and the composite material is 600 Grade wear-resistant steel, by mass percentage, the steel contains C: 0.35% ~ 0.40%, Si: 0.4% ~ 0.6%, Mn: 0.40% ~ 1.00%, Cr: 0.8% ~ 1.8%, Mo: 0.2% ~ 0.6%, Nb: 0.01%~0.03%, Ni≤0.60%, Cu≤0.60%, B: 0.0005%~0.0022%, Ti: 0.025%~0.04%, Als: 0.025%~0.045%, P≤0.015%, S≤0.005%, [N]≤0.0080%, [O]≤0.0020%, and Ti/N≥3.4, and the balance is Fe and unavoidable impurities.
基材成分中碳含量要求在0.22%以下,一方面较低的碳含量可以保证耐磨复合坯封焊接头的质量,降低焊接接头的裂纹倾向;另一方面较低的碳含量可以保证在单面在线超快冷处理的过程中,基层可以具有较好的抗冲击性能。The carbon content in the substrate composition is required to be less than 0.22%. On the one hand, the lower carbon content can ensure the quality of the wear-resistant composite billet sealing and welding joints and reduce the crack tendency of the welded joints; In the process of surface-on-line ultra-fast cooling treatment, the base layer can have better impact resistance.
复材钢中元素作用机理为:The action mechanism of elements in composite steel is:
C:为了保证钢板超高的表面硬度和厚钢板水冷时的淬透性需要相当的碳含量做保证,在一定范围内钢的硬度随碳含量的增加而相应的增加,同时一定的碳含量可以和Nb、Ti、Cr、Mo等形成碳化物析出,增加耐磨性。碳含量过高则塑性韧性降低焊接性能下降,为了保证钢板的高硬度及焊接性能和低温韧性,因此本发明中C含量控制在0.35%~0.40%;C: In order to ensure the ultra-high surface hardness of the steel plate and the hardenability of the thick steel plate when it is water-cooled, a considerable amount of carbon content is required. Within a certain range, the hardness of the steel increases with the increase of the carbon content. At the same time, a certain carbon content can be Form carbide precipitation with Nb, Ti, Cr, Mo, etc. to increase wear resistance. If the carbon content is too high, the plastic toughness will be reduced and the welding performance will be reduced. In order to ensure the high hardness, welding performance and low temperature toughness of the steel plate, the C content is controlled at 0.35% to 0.40% in the present invention;
Si:主要作用是固溶强化和脱氧,是非碳化物形成元素,Si含量较多时会抑制碳化物的析出,但过多时会使焊接性能下降,同时影响韧性,因此本发明中Si含量控制在0.4%~0.6%;Si: The main function is solid solution strengthening and deoxidation. It is a non-carbide forming element. When the Si content is high, it will inhibit the precipitation of carbides, but if it is too much, it will reduce the welding performance and affect the toughness. Therefore, the Si content in the present invention is controlled at 0.4 %~0.6%;
Mn:主要作用是固溶强化,含量大于0.4%时可以提高淬透性,提高马氏体中碳的过饱和度,有利于强度和硬度的提高,且成本低廉,但含量高于1.0时易形成中心偏析,会使板坯有易发裂纹的倾向;因此本发明中Mn含量控制在0.4%~1.0%;Mn: The main function is solid solution strengthening. When the content is greater than 0.4%, it can improve hardenability and increase the supersaturation of carbon in martensite, which is beneficial to the improvement of strength and hardness, and the cost is low, but when the content is higher than 1.0, it is easy to The formation of central segregation will make the slab prone to cracks; therefore, the Mn content in the present invention is controlled at 0.4% to 1.0%;
Nb:是强碳和氮化合物形成元素,主要作用是通过在钢中形成细小碳氮化物抑制加热时晶粒长大,空冷时又具有一定的析出强化的作用;Nb加入钢中,通过抑制奥氏体晶粒界面运动,从而提高钢板的再结晶温度。钢板中加入适量的Nb,高温奥氏体化时,未溶解的NbC起到钉轧奥氏体晶界的作用,从而阻碍奥氏体晶界过分粗化。溶解在奥氏体中的Nb,在两阶段轧制过程中抑制奥氏体再结晶,细化奥氏体晶粒。但Nb含量过高,则会形成粗大的NbC,影响钢板的力学性能。因此,本发明中Nb的加入量为0.01%~0.03%。Nb: It is a strong carbon and nitrogen compound forming element. Its main function is to inhibit the grain growth during heating by forming fine carbonitrides in the steel, and it has a certain precipitation strengthening effect when it is air-cooled; Nb is added to the steel. Tensitic grain interface movement, thereby increasing the recrystallization temperature of the steel plate. When an appropriate amount of Nb is added to the steel plate, the undissolved NbC plays the role of pinning the austenite grain boundary during high-temperature austenitization, thereby hindering the excessive coarsening of the austenite grain boundary. Nb dissolved in austenite inhibits austenite recrystallization and refines austenite grains during two-stage rolling. However, if the Nb content is too high, coarse NbC will be formed, which will affect the mechanical properties of the steel plate. Therefore, the added amount of Nb in the present invention is 0.01%-0.03%.
Ti:可以与氮、碳和硫形成化合物,主要作用是通过在钢中形成细小碳氮化物抑制加热时晶粒长大,钛与氮的化合物形成温度较高,碳化钒和碳化铌的析出温度较碳化钛和氮化钛低,加钛时通过控制钛氮的比例(Ti/N≥3.4),使铌主要与碳化合,同时可以阻止钢中的游离N与B形成化合物,提高酸溶硼收得率充分发挥B提高淬透性的作用,但含量过高时会形成粗大的TiN,降低钢板的低温韧性和疲劳性能,因此本发明中Ti的加入量控制在0.025%~0.04%且Ti/N≥3.4。Ti: It can form compounds with nitrogen, carbon and sulfur. The main function is to inhibit grain growth during heating by forming fine carbonitrides in steel. The formation temperature of titanium and nitrogen compounds is higher, and the precipitation temperature of vanadium carbide and niobium carbide It is lower than titanium carbide and titanium nitride. When adding titanium, by controlling the ratio of titanium and nitrogen (Ti/N≥3.4), niobium is mainly combined with carbon, and at the same time, it can prevent free N and B in the steel from forming compounds and improve acid-soluble boron. Yield fully exerts the effect of B to improve hardenability, but when the content is too high, coarse TiN will be formed, which will reduce the low-temperature toughness and fatigue performance of the steel plate. Therefore, the addition of Ti in the present invention is controlled at 0.025% to 0.04% and Ti /N≥3.4.
Mo、Cr:主要作用是降低临界冷却速度,提高钢板的淬透性,形成完全细小的马氏体组织,另外铬、钼在钢中可形成多种碳化物,提高钢板的强度和硬度,保证厚规格钢板的硬度在600HB以上,Mo含量大于0.2%,Cr含量大于0.8%时效果明显,Mo、Cr含量随厚度增加而适当增加,但Mo价格昂贵,Mo、Cr过多加入,还会使焊接性降低,因此本发明控制Cr:0.8%~1.8%、Mo:0.2%~0.6%。Mo, Cr: The main function is to reduce the critical cooling rate, improve the hardenability of the steel plate, and form a completely fine martensitic structure. In addition, chromium and molybdenum can form a variety of carbides in the steel to improve the strength and hardness of the steel plate, ensuring The hardness of the thick gauge steel plate is above 600HB, the Mo content is more than 0.2%, and the effect is obvious when the Cr content is more than 0.8%. Weldability decreases, so the present invention controls Cr: 0.8% to 1.8%, and Mo: 0.2% to 0.6%.
B:钢中加入微量的硼可极大的提高淬火淬透性,由于硼的加入量很小,且在钢液中与氧、氮有较强的亲和力,很容易与其发生化合反应,从而失去提高淬透性的作用。因此冶炼时加硼之前应尽量降低钢水中氧和氮的含量,但B含量过多时(≥0.0025%)易在晶界处富集,会降低晶界结合能,使钢板在受到冲击载荷时更倾向于沿晶断裂,降低钢板的低温冲击吸收功。因此,本发明中B的加入量为0.0005%~0.0022%,且[N]≤0.0080%,[O]≤0.0020%。B: Adding a small amount of boron to the steel can greatly improve the quenching hardenability. Since the amount of boron added is very small and has a strong affinity with oxygen and nitrogen in molten steel, it is easy to have a chemical reaction with it, thus losing Improve hardenability. Therefore, before adding boron in smelting, the content of oxygen and nitrogen in molten steel should be reduced as much as possible, but when the B content is too much (≥0.0025%), it is easy to enrich at the grain boundary, which will reduce the binding energy of the grain boundary, and make the steel plate more stable when subjected to impact load. It tends to fracture intergranularly, reducing the low-temperature impact energy absorbed by the steel plate. Therefore, the addition amount of B in the present invention is 0.0005%-0.0022%, and [N]≤0.0080%, [O]≤0.0020%.
Cu,Ni,在钢板中添加不高于0.6%的铜,淬火后的自回火过程可形成ε-Cu析出,有效提高钢的强度和硬度,但含Cu钢在加热和热轧过程中易因铜脆而造成边部过烧和表面翘皮等表面质量缺陷。为改善含Cu钢材的表面质量,常向钢中加入高熔点的Ni元素,以形成高熔点的Cu、Ni二元合金相,减少低熔点富Cu相,同时增加Cu在钢中的溶解度。为达到完全抑制含Cu钢铜脆缺陷的目的,一般将Ni:Cu比控制在大于1:2,Ni也是同时提高钢板的硬度和低温韧性的元素,Ni会与Fe形成FeNi化合物,钢板在较低温度下受到低温冲击载荷时,固溶的Ni会提高钢板的低温冲击吸收功,但Ni成本较高,因此本发明中厚规格钢板加入小于等于0.6%的Ni能够保证钢板的力学性能尤其是-40℃低温韧性,并使其具有市场竞争力。Cu, Ni, adding no more than 0.6% copper to the steel plate, the self-tempering process after quenching can form ε-Cu precipitation, which can effectively improve the strength and hardness of the steel, but the Cu-containing steel is easy to Surface quality defects such as edge burning and surface warping are caused by copper brittleness. In order to improve the surface quality of Cu-containing steel, high-melting-point Ni elements are often added to steel to form high-melting-point Cu and Ni binary alloy phases, reduce low-melting-point Cu-rich phases, and increase the solubility of Cu in steel. In order to completely suppress copper brittle defects in Cu-containing steel, the ratio of Ni:Cu is generally controlled to be greater than 1:2. Ni is also an element that improves the hardness and low-temperature toughness of the steel plate at the same time. Ni will form FeNi compounds with Fe. When subjected to low-temperature impact load at low temperature, solid solution Ni will increase the low-temperature impact energy absorption of the steel plate, but the cost of Ni is relatively high, so the addition of 0.6% or less Ni to the medium-thick steel plate of the present invention can ensure the mechanical properties of the steel plate, especially -40℃ low temperature toughness, and make it competitive in the market.
一种600级耐磨复合板的生产方法,生产工艺包括选材、表面处理、复合坯组坯、真空焊接、轧制和表面修磨,具体包括:A production method of a 600-grade wear-resistant composite plate. The production process includes material selection, surface treatment, composite blank assembly, vacuum welding, rolling and surface grinding, specifically including:
(1)选取基材、复材作为组坯用原料,基材为C含量按质量百分比计为C≤0.22%的低碳低合金钢,复材为600级别耐磨钢。(1) The base material and composite material are selected as raw materials for billet assembly. The base material is low-carbon low-alloy steel with a C content of C≤0.22% by mass percentage, and the composite material is 600-grade wear-resistant steel.
基材和复材可以为连铸坯、中间坯、钢板等,且基材与复材的长度、宽度相同,其中,长度为2~4m,宽度为1~3m,基材与复材厚度比为1~2,其中,基材厚度为100~150mm,复材厚度为50~100mm。基材和复合的厚度比例一方面限制了复材在复合坯中所占比,保证了在后续热处理过程中既能获得复层的高耐磨性能又能获得基层的抗冲击性能;另一方面限制了复合坯的总厚度,既限制了组坯封焊过程中应力幅值又保证了复合坯加热过程中的形变一致性。在结构上降低复合坯封焊接头在焊接和加热过程中的裂纹敏感性。The base material and composite material can be continuous casting slabs, intermediate slabs, steel plates, etc., and the length and width of the base material and the composite material are the same. Among them, the length is 2-4m, the width is 1-3m, and the thickness ratio of the base material to the composite material 1 to 2, wherein the thickness of the base material is 100 to 150 mm, and the thickness of the composite material is 50 to 100 mm. On the one hand, the ratio of the thickness of the base material to the compound limits the proportion of the composite material in the composite billet, ensuring that both the high wear resistance of the clad layer and the impact resistance of the base layer can be obtained in the subsequent heat treatment process; on the other hand, The total thickness of the composite blank is limited, which not only limits the stress amplitude during the sealing and welding process of the composite blank, but also ensures the deformation consistency of the composite blank during the heating process. Structurally, it reduces the crack sensitivity of the composite blank sealing joint during welding and heating.
(2)对基材、复材待接触表面进行加工,通过刨床或铣床等机加工方式对其表面进行打磨,去除待接触面的锈层和氧化层。(2) Process the surface of the base material and composite material to be in contact, and polish the surface with a planer or milling machine to remove the rust layer and oxide layer on the surface to be in contact.
采用刨床或铣床等机加工的方法去除基材和复材待复合表面氧化层,加工深度为5~10mm,加工过程无冷却液添加。其中,在组坯之前对坯料待复合表面进行修磨处理,去除锈层和氧化物层,使其在轧制的过程中均以新鲜金属相互接触,有助于两者之间形成冶金结合,提高结合质量,避免夹杂、气孔和未结合等缺陷。Use a planer or milling machine to remove the oxide layer on the surface of the base material and composite material to be composited. The processing depth is 5-10 mm, and no cooling liquid is added during the processing. Among them, before the billet is assembled, the surface of the billet to be compounded is ground to remove the rust layer and the oxide layer, so that they are in contact with each other with fresh metal during the rolling process, which is conducive to the formation of a metallurgical bond between the two. , improve the bonding quality, and avoid defects such as inclusions, pores, and unbonding.
(3)对基材、复材待复合表面进行去油污处理。(3) Degreasing the surface of the base material and composite material to be compounded.
采用99.99%高纯度酒精对基材和复材待复合界面进行去油污处理,并采用无纺布进行擦拭。其中,在基材和复材待复合表面机加处理完成后,进一步用高纯度酒精进行去油污处理并用无纺布擦拭可有效提高待复合表面的洁净度,有助于耐磨复合板复合界面间形成良好的冶金结合。Use 99.99% high-purity alcohol to degrease the interface between the substrate and the composite material to be composited, and wipe it with a non-woven cloth. Among them, after the machining treatment of the composite surface of the substrate and the composite material is completed, further degreasing treatment with high-purity alcohol and wiping with a non-woven cloth can effectively improve the cleanliness of the composite surface and contribute to the composite interface of the wear-resistant composite board. form a good metallurgical bond.
(4)将基材、复材按照由上至下的位置依次居中叠放组坯,形成复合坯。(4) The base material and composite material are stacked in the center according to the position from top to bottom to form a composite blank.
(5)将组坯后的复合坯抽取真空后进行真空电子束密封焊接,使基材与复材待复合界面处于真空环境。(5) Vacuum the composite billet after billet assembly, and conduct vacuum electron beam sealing welding, so that the interface between the base material and the composite material to be compounded is in a vacuum environment.
复合坯所处环境真空度≤4.5×10-2Pa;其中,在真空环境下对复合坯进行真空电子束封装焊接,可最大限度的降低结合面之间的气体含量,避免在轧制后出现气体残留,造成结合率不合。另外,结合面之间气体含量的降低还有助于防止其对结合面表面的二次氧化,有助于结合性能的提高。真空电子束密封焊接的有效熔深为35~40mm,深宽比为5~6,且焦点位置向基材侧偏移1.5~2.5mm;其中,采用电子束焊接工艺进行封装焊接,可以在较低的热输入情况下完成大熔深的焊接,得到的焊接接头深宽比较大,降低焊接过程对复合坯料组织和性能的影响。同时,无需使用焊材并降低焊接能耗均有利于工业大生产的成本控制。其中,采用向基材侧偏移的焊接工艺,可以对焊接熔池内的化学成分进行调控,避免接头组织进行马氏体区,保证接头强度,降低接头裂纹敏感性。The vacuum degree of the environment where the composite billet is located is ≤4.5×10 -2 Pa; Among them, the vacuum electron beam packaging and welding of the composite billet in a vacuum environment can minimize the gas content between the joint surfaces and avoid the occurrence of gas after rolling. The gas remains, causing the binding rate to be inconsistent. In addition, the reduction of the gas content between the bonding surfaces also helps to prevent secondary oxidation on the surface of the bonding surface and contributes to the improvement of the bonding performance. The effective penetration depth of vacuum electron beam sealing welding is 35-40mm, the aspect ratio is 5-6, and the focus position is shifted to the substrate side by 1.5-2.5mm; among them, the electron beam welding process is used for packaging welding, which can Under the condition of low heat input, the welding with large penetration depth is completed, and the obtained welded joint has a large depth-to-width ratio, which reduces the influence of the welding process on the structure and performance of the composite blank. At the same time, no need to use welding consumables and reduce welding energy consumption are conducive to cost control of industrial mass production. Among them, the welding process offset to the base material side can regulate the chemical composition in the weld pool, avoid the martensitic zone of the joint structure, ensure the joint strength, and reduce the crack sensitivity of the joint.
真空电子束焊接顺序为双枪联动先进行两条长边的密封焊接,后进行两条短边的密封焊接。且每条焊缝的进行焊接时,将其分为N段,N≥10,每段长度为100~200mm,焊接顺序为先进行中间段数的焊接然后以左、右交替的顺序进行剩余段数的焊接。采用双枪联动工艺可以保证复合坯形变的一致性,降低应力集中程度;采用先进行长边焊接后进行短边焊接以及采用先焊中间段数然后以左、右顺序焊接剩余段数可以将焊接形变和应力逐步释放,降低焊接应力的幅值。通过特殊的封焊工艺降低耐磨复合坯在组坯封焊过程中的裂纹敏感性。The vacuum electron beam welding sequence is that the two guns are linked together to perform the sealing welding of the two long sides first, and then the sealing welding of the two short sides. And when each weld seam is welded, it is divided into N sections, N≥10, and the length of each section is 100-200mm. The welding sequence is to weld the middle section first and then carry out the remaining sections in the order of left and right. welding. The double-gun linkage process can ensure the consistency of the deformation of the composite billet and reduce the degree of stress concentration; the welding deformation and the welding deformation and The stress is gradually released to reduce the amplitude of welding stress. The crack sensitivity of the wear-resistant composite billet in the process of billet sealing and welding is reduced through a special sealing and welding process.
(6)将真空处理后的组合坯料加热至1200~1250℃保温,保温时间按照复合坯厚度×1min/mm计算。(6) Heat the combined billet after vacuum treatment to 1200-1250°C for heat preservation, and the heat preservation time is calculated according to the thickness of the composite billet × 1min/mm.
复合坯采用火焰室式炉进行加热,加热时采用“中心加热”方式,即加热火焰口处于复合坯长、宽平面的上下中心位置,使复合坯处于由中心直接受热并向四周传导的方式升温。其中,采用火焰室式炉进行中心加热工艺,可以使复合坯由中心开始发生膨胀形变,避免了由于复合坯表层受热,心部升温较慢而引起的形变不一致,封焊接头处发生应力集中,进而开裂失效的情况,降低了复合坯在加热过程中的裂纹敏感性。复合坯在出炉前1~2小时,提高复合坯头尾处上表面火焰口温度50~60℃。其中,采用头尾上表面加热法可以提高头尾部上表面一定范围内基材的温度,提高其轧制过程中的变形程度,有效避免复合坯在轧制过程中易出现的翘头问题,提高复合坯的轧制成功率。The composite billet is heated by a flame chamber furnace, and the heating adopts the "center heating" method, that is, the heating flame port is located at the upper and lower center positions of the long and wide planes of the composite billet, so that the composite billet is heated directly from the center and conducted to the surroundings. . Among them, the central heating process of the flame chamber furnace can make the composite billet expand and deform from the center, avoiding the inconsistent deformation caused by the surface layer of the composite billet heating and the slow temperature rise of the core, and the stress concentration at the sealing and welding joint. Furthermore, the failure of cracking reduces the crack sensitivity of the composite billet during heating. 1-2 hours before the composite billet is released from the furnace, the temperature of the upper surface of the flame port at the head and tail of the composite billet is increased by 50-60°C. Among them, the heating method on the upper surface of the head and tail can increase the temperature of the base material within a certain range on the upper surface of the head and tail, increase the degree of deformation during the rolling process, effectively avoid the warping problem that is easy to occur in the rolling process of the composite billet, and improve the composite strength. Billet rolling success rate.
(7)在1180~1200℃进行轧制,首道次压下率为10%~15%,总压下率≥50%。(7) Rolling is carried out at 1180-1200°C, the reduction rate in the first pass is 10%-15%, and the total reduction rate is ≥50%.
复合坯采用基材在上,600耐磨钢在下的形式进行轧制;其中,采用非对称组坯形式进行600级耐磨复合板的轧制,可以有效的简化工业化大生产的工艺复杂性,提高其生产效率,避免了对称组坯的隔离剂涂覆和轧后的分板环节。The composite billet is rolled in the form of base material on the top and 600 wear-resistant steel on the bottom; among them, rolling the 600-grade wear-resistant composite plate in the form of asymmetrical billet assembly can effectively simplify the process complexity of industrialized mass production. The production efficiency is improved, and the release agent coating of the symmetrical billets and the plate splitting after rolling are avoided.
(8)轧制后进行在线超快冷处理。(8) On-line ultra-fast cooling treatment after rolling.
所述步骤(8)中采用在线超快冷对600耐磨钢侧进行浇水、冷却,使复层的冷却速度为3~5℃/s,且冷却后在复层进行测温返红温度小于300℃。其中,采用在线超快冷对复层进行浇水、冷却,可以使其获得高硬度马氏体组织,保证其耐磨性能。同时,又有效控制了基层侧的冷却速度,使其获得较高的抗冲击性能。In the step (8), the online ultra-fast cooling is used to water and cool the 600 wear-resistant steel side, so that the cooling rate of the multi-layer is 3-5 °C/s, and after cooling, the temperature is measured on the multi-layer and the temperature returns to red. Less than 300°C. Among them, the online ultra-fast cooling is used to water and cool the composite layer, so that it can obtain a high-hardness martensitic structure and ensure its wear resistance. At the same time, the cooling rate of the base layer side is effectively controlled, so that it can obtain higher impact resistance.
(9)经矫直、切边、表面修磨后得到目标厚度耐磨复合板,厚度范围为20~100mm。(9) After straightening, edge trimming and surface grinding, the target thickness wear-resistant composite plate is obtained, and the thickness range is 20-100mm.
有益效果:Beneficial effect:
本发明生产的耐磨复合板与现有产品相比:Compared with the existing products, the wear-resistant composite plate produced by the present invention:
1、制备的耐磨复合板复合界面抗剪切强度可达500MPa以上,结合率为100%,耐磨层布氏硬度可达到530以上,室温冲击功可达到118J以上;1. The shear strength of the composite interface of the prepared wear-resistant composite board can reach more than 500MPa, the bonding rate is 100%, the Brinell hardness of the wear-resistant layer can reach more than 530, and the impact energy at room temperature can reach more than 118J;
2、降低耐磨复合坯在组坯封焊和加热过程中的裂纹敏感性并改善其在轧制过程中发生的翘头问题,生产效率由原来的50%左右提高至80%以上。2. Reduce the crack sensitivity of the wear-resistant composite billet in the process of billet sealing, welding and heating, and improve its warping problem in the rolling process, and the production efficiency is increased from about 50% to more than 80%.
附图说明Description of drawings
图1为NM600耐磨复合板示意图。Figure 1 is a schematic diagram of NM600 wear-resistant composite plate.
具体实施方式Detailed ways
以下实施例用于具体说明本发明内容,这些实施例仅为本发明内容的一般描述,并不对本发明内容进行限制。The following examples are used to specifically illustrate the contents of the present invention, and these examples are only general descriptions of the contents of the present invention, and do not limit the contents of the present invention.
表1为本发明实施例600级耐磨钢的实际材质;表2为本发明实施例实施例600级耐磨钢的原料规格;表3为本发明实施例低碳低合金钢的实际材质及原料规格;表4为本发明实施例实施例复合坯相关信息;表5为实施例轧前工艺及坯料信息;表6本发明实施例轧制制度;表7为实施例复合板的性能检验结果。Table 1 is the actual material of the 600-grade wear-resistant steel of the embodiment of the present invention; Table 2 is the raw material specification of the 600-grade wear-resistant steel of the embodiment of the present invention; Table 3 is the actual material of the low-carbon low-alloy steel of the embodiment of the present invention and Raw material specifications; Table 4 is the relevant information of the composite blank of the embodiment of the present invention; Table 5 is the pre-rolling process and blank information of the embodiment; Table 6 is the rolling system of the embodiment of the present invention; Table 7 is the performance test result of the composite plate of the embodiment .
表1 实施例600级耐磨钢的化学成分(wt%)Table 1 The chemical composition (wt%) of the 600 grade wear-resistant steel of the embodiment
表2 实施例600级耐磨钢的原料规格Table 2 The raw material specifications of the 600-grade wear-resistant steel of the embodiment
表3 实施例低碳低合金钢的实际材质及原料规格Table 3 The actual material and raw material specifications of the low-carbon low-alloy steel of the embodiment
表4 实施例复合坯相关信息Table 4 Relevant information of the composite billet of the embodiment
表5 实施例轧前工艺及坯料信息Table 5 Example pre-rolling process and billet information
表6 实施例轧制制度Table 6 Example rolling system
表7 单面复合板力学性能Table 7 Mechanical properties of single-sided composite panels
由实施例可见,根据本发明一种600级耐磨复合板及其生产方法,生产的600级耐磨复合板屈服强度、抗拉强度和伸长率均满足相关标准要求,室温冲击≥135,复合面抗剪切强度≥508MPa,复合层布氏硬度≥572,超声波检验100%合格,封焊接头在焊接和加热过程中无开裂,复合坯在轧制过程中无翘头问题。It can be seen from the examples that according to a 600-grade wear-resistant composite board and its production method of the present invention, the yield strength, tensile strength and elongation of the 600-grade wear-resistant composite board produced all meet the requirements of relevant standards, and the impact at room temperature is ≥ 135. Surface shear strength ≥ 508MPa, Brinell hardness of the composite layer ≥ 572, 100% qualified by ultrasonic inspection, no cracks in the sealing and welding joints during welding and heating, and no head warping in the rolling process of the composite billet.
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910821754.6A CN110527906B (en) | 2019-09-02 | 2019-09-02 | 600-grade wear-resistant composite board and production method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910821754.6A CN110527906B (en) | 2019-09-02 | 2019-09-02 | 600-grade wear-resistant composite board and production method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN110527906A true CN110527906A (en) | 2019-12-03 |
CN110527906B CN110527906B (en) | 2021-01-08 |
Family
ID=68666057
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201910821754.6A Active CN110527906B (en) | 2019-09-02 | 2019-09-02 | 600-grade wear-resistant composite board and production method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN110527906B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2024160091A1 (en) * | 2023-01-31 | 2024-08-08 | 宝山钢铁股份有限公司 | Composite steel plate and manufacturing method therefor |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105363780A (en) * | 2015-10-16 | 2016-03-02 | 首钢总公司 | Plain carbon steel and wear-resistant steel clad steel plate and production method thereof |
CN105506504A (en) * | 2014-09-26 | 2016-04-20 | 鞍钢股份有限公司 | Ultrahigh-strength wear-resistant steel plate and production method thereof |
CN109694989A (en) * | 2017-10-20 | 2019-04-30 | 鞍钢股份有限公司 | 825/X70 nickel-based alloy composite plate and production method thereof |
CN109692873A (en) * | 2017-10-20 | 2019-04-30 | 鞍钢股份有限公司 | Thin-clad titanium steel composite plate and preparation method thereof |
CN109695000A (en) * | 2017-10-20 | 2019-04-30 | 鞍钢股份有限公司 | Double-sided titanium steel composite plate with IF steel as transition layer and high-temperature preparation method thereof |
CN109692884A (en) * | 2017-10-20 | 2019-04-30 | 鞍钢股份有限公司 | Titanium steel composite board with IF steel as transition layer and high-temperature preparation method thereof |
CN109693430A (en) * | 2017-10-20 | 2019-04-30 | 鞍钢股份有限公司 | Thin-clad double-sided titanium steel composite plate and preparation method thereof |
CN109957729A (en) * | 2017-12-22 | 2019-07-02 | 鞍钢股份有限公司 | Wear-resistant steel plate for tramcar turnout and production method thereof |
-
2019
- 2019-09-02 CN CN201910821754.6A patent/CN110527906B/en active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105506504A (en) * | 2014-09-26 | 2016-04-20 | 鞍钢股份有限公司 | Ultrahigh-strength wear-resistant steel plate and production method thereof |
CN105363780A (en) * | 2015-10-16 | 2016-03-02 | 首钢总公司 | Plain carbon steel and wear-resistant steel clad steel plate and production method thereof |
CN109694989A (en) * | 2017-10-20 | 2019-04-30 | 鞍钢股份有限公司 | 825/X70 nickel-based alloy composite plate and production method thereof |
CN109692873A (en) * | 2017-10-20 | 2019-04-30 | 鞍钢股份有限公司 | Thin-clad titanium steel composite plate and preparation method thereof |
CN109695000A (en) * | 2017-10-20 | 2019-04-30 | 鞍钢股份有限公司 | Double-sided titanium steel composite plate with IF steel as transition layer and high-temperature preparation method thereof |
CN109692884A (en) * | 2017-10-20 | 2019-04-30 | 鞍钢股份有限公司 | Titanium steel composite board with IF steel as transition layer and high-temperature preparation method thereof |
CN109693430A (en) * | 2017-10-20 | 2019-04-30 | 鞍钢股份有限公司 | Thin-clad double-sided titanium steel composite plate and preparation method thereof |
CN109957729A (en) * | 2017-12-22 | 2019-07-02 | 鞍钢股份有限公司 | Wear-resistant steel plate for tramcar turnout and production method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2024160091A1 (en) * | 2023-01-31 | 2024-08-08 | 宝山钢铁股份有限公司 | Composite steel plate and manufacturing method therefor |
Also Published As
Publication number | Publication date |
---|---|
CN110527906B (en) | 2021-01-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN110592473B (en) | High-grade super-thick double-sided wear-resistant composite board and production method thereof | |
CN103882317B (en) | Composite wear-resistant steel plate with good plasticity and toughness and manufacturing method thereof | |
JP6198937B2 (en) | HT550 steel sheet with ultra-high toughness and excellent weldability and method for producing the same | |
CN110527907B (en) | 550-grade wear-resistant composite board and production method thereof | |
AU2017364679B2 (en) | High-strength corrosion-resistant composite chequered iron and manufacturing method therefor | |
CN105363780A (en) | Plain carbon steel and wear-resistant steel clad steel plate and production method thereof | |
CN105772507A (en) | Carbon steel and duplex stainless steel composite steel plate and production method thereof | |
WO2014019353A1 (en) | Abrasion resistant steel plate with super-high strength and high toughness, and process for preparing same | |
WO2014019352A1 (en) | Abrasion resistant steel plate with high strength and high toughness, and process for preparing same | |
EP3719161B1 (en) | High-strength high-toughness and wear-resistant composite steel plate and manufacturing method therefor | |
CN110640288A (en) | Surfacing method for surfacing high-chromium alloy on Q235 steel plate | |
CN104040006A (en) | Wear-resistant welded steel pipe and method for producing same | |
CN105543710A (en) | Carbon steel and martensitic stainless steel clad steel plate and production method thereof | |
CN110509634B (en) | A kind of high-grade double-sided wear-resistant composite plate and production method thereof | |
CN103147022B (en) | A kind of TMCP type E47 steel plate and manufacture method thereof with good low-temperature toughness | |
CN114525506A (en) | Method for quickly repairing foot roller of continuous casting machine through alloy powder laser cladding | |
CN105274433A (en) | Super-thick steel plate and composite production method thereof | |
CN109868469B (en) | Powder material for laser manufacturing mill housing and roller bearing seat composite lining plate and manufacturing method thereof | |
CN110527906A (en) | 600-grade wear-resistant composite board and production method thereof | |
CN104785895A (en) | Submerged arc surfacing manufacturing technology of looper roll for rolling mill | |
CN105420632B (en) | A kind of Q690CF hot rolled steel plates and preparation method thereof | |
CN109692872B (en) | Composite steel plate for rolling mill sliding plate and production method thereof | |
US11130161B2 (en) | High-strength corrosion-resistant composite chequered iron and manufacturing method therefor | |
JP6634616B2 (en) | Steel for friction stir welding and friction stir welding method | |
CN115323272A (en) | Ferritic steel alloy powder for laser additive repair of shaft parts and application method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |