Background technique
Blast furnace gas is the fuel gas of by-product in blast furnace ironmaking production process, and yield is big, widely used, can be used as electricity
Factory's boiler, iron-smelter hot-blast stove, steel mill heating furnace fuel.The main ingredient of blast furnace gas is CO, CO2、N2With a small amount of sulphur
Compound, CL-, sulfide therein is mainly with H2S, based on COS.
Due to the blast furnace gas that generates during current blast furnace ironmaking without desulfurization process directly as boiler of power plant, ironmaking
The fuel use of factory's hot-blast stove, steel mill heating furnace, therefore, lead to the cigarette of boiler of power plant, iron-smelter hot-blast stove, steel mill heating furnace
SO in gas discharge2The ultra-clean emission request of country, usually SO in the flue gas of its discharge is not achieved in content2Content is greater than 50mg/m3,
SO in the flue gas of some factory's discharges2Content be even as high as 250mg/m3More than.
Currently, a domestic seat height producer gas desulfurizing device not yet is used in operation.Traditional coal gas desulfurization device is main
It is the desulfurization process for coke-stove gas, artificial coal gas, such as the packed tower desulphurization plant that people use.Since blast furnace exists
In production process, gas yield and gas pressure fluctuation are big, the general workload of packed tower 60%~110%, therefore, if
Carrying out desulfurization process to blast furnace gas using packed tower will lead to that flooding (load be lower than 60%) occurs in packed tower or model liquid is (negative
Lotus, which is higher than 110%) phenomenon, packed tower, can not work normally, and therefore, packed tower is not suitable for blast furnace gas desulfurization.
In addition, each blast furnace gas user fights separately for environment protection standard, every family is required to add coal gas desulfurization device,
The burden for increasing every blast furnace gas user occupies biggish industrial land.
Summary of the invention
In view of the foregoing, the object of the present invention is to provide a kind of blast furnace gas desulfurizing tower, the blast furnace gas desulfurizing tower is straight
The sulphur removing in the blast furnace gas that will be generated during blast furnace ironmaking is connect, each blast furnace gas user is transmitted further to and uses, thus, make
Each blast furnace gas user need not individually increase flue gas desulfurization device again, save the fund of each blast furnace gas user, save greatly
The industrial land of amount.
To achieve the above object, the invention adopts the following technical scheme: a kind of blast furnace gas desulfurizing tower, it includes that level-one is thick
Connecting pipe between de- tower, second level fine removing tower and tower;Level-one rough removing tower and second level fine removing tower are arranged side by side, and top between tower by connecting
Adapter tube road is connected;
Top in the level-one rough removing tower is equipped with several row's spray guns, and spray contains buck for desulfurization dechlorination;
Top in the second level fine removing tower is equipped with a deflection cone;
Blast furnace gas enters from the bottom of the level-one rough removing tower, carries out desulfurization dechlorination containing buck through what the spray gun sprayed
After processing, enter through connecting pipe between the tower from the top of the second level fine removing tower, after the deflection cone, from the second level
The bottom blast furnace gas of fine removing tower exports output.
In a preferred embodiment of the present invention, the top of interior, the described deflection cone of the second level fine removing tower is equipped with spray gun, and spray is used
Contain buck in desulfurization dechlorination.
In a preferred embodiment of the present invention, the flow velocity of blast furnace gas is 4-5 meter per second in the level-one rough removing tower, and coal gas stops
Stay the time about 10 seconds;The flow velocity of blast furnace gas is 10-25 meter per second in the second level fine removing tower tower.
In a preferred embodiment of the present invention, the pH value containing buck is 7.0-8.0.
In a preferred embodiment of the present invention, in the level-one rough removing tower, the top of blast furnace gas entrance, it is equipped with an air-flow
Distributor.
In a preferred embodiment of the present invention, the level-one rough removing tower blast furnace gas inlet is equipped with an elbow, blast furnace gas
Enter in tower through pipeline, the elbow.
In a preferred embodiment of the present invention, the bottom of the second level fine removing tower be fixed with one be in an angle of 90 degrees blast furnace gas
Output channel, the blast furnace gas output channel export phase with the blast furnace gas being arranged on the second level fine removing tower bottom side wall
Even.
In a preferred embodiment of the present invention, several atomizers are provided on the spray gun.
In a preferred embodiment of the present invention, the bottom in the level-one rough removing tower and second level fine removing tower is equipped with liquid receipts
Collection slot and the leakage fluid dram being connected with liquid collection trough.
In a preferred embodiment of the present invention, it is offered on the side wall of the level-one rough removing tower, near the spray gun conveniently
The access hole that people enters and leaves, is laid with inspection platform in tower near spray gun;
The access hole for facilitating people to enter and leave, the spray gun in tower are offered on the side wall of the second level fine removing tower, near spray gun
Nearby it is laid with inspection platform
Specific embodiment
Structure and feature of the invention are described in detail with reference to the accompanying drawings and examples.It should be noted that can
To make various modifications to disclosed embodiments, therefore, embodiment disclosed in specification be should not be considered as to the present invention
Limitation, and only as the example of embodiment, the purpose is to keep feature of the invention apparent.
As shown in Figure 1, blast furnace gas desulfurizing tower provided by the invention between level-one rough removing tower 1, second level fine removing tower 2 and tower by connecting
Adapter tube road 3 is constituted, and level-one rough removing tower 1 and second level fine removing tower 2 are arranged side by side, and top is connected by connecting pipe 3 between tower.It is high
Producer gas enters level-one rough removing tower from 1 bottom of level-one rough removing tower, after carrying out first time desulfurization process, through connecting pipe 3 between tower into
After entering second of the desulfurization process of progress of second level fine removing tower 2, exports and export from the bottom blast furnace gas of second level fine removing tower 2.
As shown in Figure 1, the bottom of the level-one rough removing tower 1 is equipped with blast furnace gas entrance 11, in level-one rough removing tower, blast furnace
The top of gas entry, is equipped with an air distributor 12, which can make the blast furnace gas entered in tower uniformly, steadily
Ground is distributed in level-one rough removing tower, increases the area that blast furnace gas is contacted with the sweetening liq of spray, avoids the occurrence of air-liquid unevenness
Caused by the low phenomenon of desulfuration efficiency.
In level-one rough removing tower, the top compartment of terrain of air distributor is equipped with several row's spray guns 13, is densely covered with mist on spray gun
Change nozzle, (such as NaOH) containing buck is sprayed into level-one rough removing tower.It is removed in blast furnace gas and contains CO, CO2、N2Outside, also contain
COS、H2S and Cl-, inventive desulfurization tower is mainly the H removed in blast furnace gas2S and Cl-.When blast furnace gas is through level-one rough removing tower
Bottom enter after, through air distributor 12 to the top of tower drift about, during blast furnace gas drift about upwards, chance spray gun 13 to
Lower sprinkling contains buck, the H in blast furnace gas2S is encountered containing after buck (NaOH), is chemically reacted, and Na is generated2S, Na2S is molten
Yu Shuizhong, this is the first time desulfurization process that this present invention level-one rough removing tower carries out blast furnace gas.
Due to the Cl in blast furnace gas-It is also chemically reacted with what spray gun sprayed downwards containing buck, therefore, the present invention is right
Dechlorination also may be implemented while blast furnace gas desulfurization.
In level-one rough removing tower, blast furnace gas enters from the lower part of tower, goes out from the top of tower, and spray gun spray contains buck
It is sprayed downwards by the top of tower, blast furnace gas is reverse with liquid, and the reaction time is long, and desulphurization reaction is abundant, and desulfuration efficiency is high.
Blast furnace gas after 1 desulfurization process of level-one rough removing tower enters second level fine removing tower 2 through connecting pipe 3 between tower.
As shown in Figure 1, the top in second level fine removing tower 2 also is provided with spray gun 21, one is fixed in the lower section of spray gun 21 and is led
Flow cone 22, the bottom of second level fine removing tower 2 be fixed with one be in an angle of 90 degrees blast furnace gas output channel 23, the blast furnace gas output
Pipeline 23 is connected with the blast furnace gas outlet 24 being arranged on second level fine removing tower wall.
After blast furnace gas after level-one rough removing tower desulfurization process enters second level fine removing tower, contain again through what spray gun 21 sprayed
It is defeated by blast furnace gas outlet 24 through the blast furnace gas output channel 23 in an angle of 90 degrees after deflection cone 22 after buck desulfurization process
Out.
Blast furnace gas in second level fine removing tower uses the design structure of upper entering and lower leaving, is equipped with deflection cone, air-liquid in inlet
After deflection cone is oriented to, most of liquid is separated to tower body inner wall and flows down along the side wall of tower, air-flow to down toward exit be in 90
The blast furnace gas output channel for spending angle, since current density is low and easy turn, second level fine removing tower is right again at outlet conduit
Gas and liquid carry out secondary separation, and the blast furnace gas through desulfurization process twice passes through output channel 23, the blast furnace coal in an angle of 90 degrees
24 output of gas outlet.
To collect the liquid that spray gun 13,21 sprays, as shown in Figure 1, the bottom in level-one rough removing tower 1 and second level fine removing tower 2
Portion is equipped with liquid collection trough 14,25, the leakage fluid dram 15,26 being connected with liquid collection trough.
For convenience of overhaul of the equipments, as shown in Figure 1, the present invention is on 1 side wall of level-one rough removing tower, the side of offering near spray gun 13
The access hole 16 that person who happens to be on hand for an errand enters and leaves is laid with inspection platform 17 in tower near spray gun.Equally, on the side wall of second level fine removing tower 2, spray
Rifle 21 nearby offers the access hole 27 for facilitating people to enter and leave, and is laid with inspection platform 28 near spray gun in tower.The connecting tube between tower
Road 3 is equipped with coal gas diffusing device 4, and gas displacement is carried out when convenient for going into operation and overhaul.
In the specific embodiment of the invention, the air distributor being arranged in level-one rough removing tower is a steel grating,
Aperture size, which is subject to, not to be influenced air-flow and passes through, and can be combed to air-flow, is evenly distributed on gas in tower, and with spray
Sweetening liq come into full contact with, to improve gas liquid interfacial area, improve desulfuration efficiency.
An elbow is equipped at the level-one rough removing tower blast furnace gas entrance 11, blast furnace gas enters through inlet pipeline, elbow
In tower, coal gas is avoided directly to wash away tower wall, extends the service life of tower.
As shown in Figure 1, each tower is equipped with support 5, is supported for tower body, facilitate installation.
Constitute level-one rough removing tower and second level fine removing tower of the invention diameter, highly according to blast furnace coal tolerance to be processed and
Design, in general, the flow velocity of blast furnace gas is 4-5 meter per second in level-one rough removing tower, the coal gas residence time about 10 seconds, second level essence was de-
The flow velocity of Ta Tanei blast furnace gas is 10-25 meter per second.PH value of the desulfurization of spray containing buck is 7.0-8.0.
The air-tightness of level-one rough removing tower and second level fine removing tower, pressure-bearing property, leak free design are designed according to national design specification
, details are not described herein.
Advantages of the present invention:
1, the present invention can effectively solve blast furnace gas desulphurization problem, realize qualified discharge after blast furnace gas combustion.
2, the present invention carries out preposition desulfurization to blast furnace gas, and the blast furnace gas after desulfurization process is conveyed to each height again
Producer gas user uses, and makes each blast furnace gas user that need not add desulphurization plant respectively, saves substantial contribution and industrial land.
3, the present invention uses two-step desulfurization tower, and first order desulfurizing tower carries out thick desulfurization, the doctor solution and coal being entrained by the flow of air
The sulphur not removed in gas carries out secondary desulfuration through second level fine removing tower, the doctor solution in coal gas is further decreased after deflection cone,
Realize the fine de-sulfur of blast furnace gas.
4, all production status of blast furnace can be met, be not in flooding or model liquid phenomenon.
5, the blast furnace gas in level-one rough removing tower uses the design structure of bottom in and top out, and spray gun spray uses certainly containing buck
Spray design under above, blast furnace gas and liquid are reverse, and the reaction time is long, and desulphurization reaction is abundant, and desulfuration efficiency is high.
6, the blast furnace gas in second level fine removing tower uses the design structure of upper entering and lower leaving, is equipped with deflection cone, gas in inlet
After flowing through deflection cone guiding, most of liquid is flowed down by the side wall for separating along tower, and air-flow is to the height for down toward exit being in an angle of 90 degrees
Producer gas output channel, since current density is low and easy turn, second level fine removing tower is again to gas and liquid at outlet conduit
Body carries out secondary separation, and removal effect is good.
Finally, it should be noted that above-described embodiments are merely to illustrate the technical scheme, rather than to it
Limitation;Although the present invention is described in detail referring to the foregoing embodiments, those skilled in the art should understand that:
It can still modify to technical solution documented by previous embodiment, or to part of or all technical features into
Row equivalent replacement;And these modifications or substitutions, it does not separate the essence of the corresponding technical solution various embodiments of the present invention technical side
The range of case.