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CN110499018A - A kind of sliding bearing macromolecule polymer material and metal mesh complex method - Google Patents

A kind of sliding bearing macromolecule polymer material and metal mesh complex method Download PDF

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Publication number
CN110499018A
CN110499018A CN201910696656.4A CN201910696656A CN110499018A CN 110499018 A CN110499018 A CN 110499018A CN 201910696656 A CN201910696656 A CN 201910696656A CN 110499018 A CN110499018 A CN 110499018A
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CN
China
Prior art keywords
parts
powder
sliding bearing
metal mesh
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910696656.4A
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Chinese (zh)
Inventor
尹忠慰
高庚员
李虎林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dongtai Miaoren Power Technology Co Ltd
Shanghai Lian Yi Bearing Technology Co Ltd
Original Assignee
Dongtai Miaoren Power Technology Co Ltd
Shanghai Lian Yi Bearing Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dongtai Miaoren Power Technology Co Ltd, Shanghai Lian Yi Bearing Technology Co Ltd filed Critical Dongtai Miaoren Power Technology Co Ltd
Priority to CN201910696656.4A priority Critical patent/CN110499018A/en
Publication of CN110499018A publication Critical patent/CN110499018A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/02Moulding by agglomerating
    • B29C67/04Sintering
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • C08L75/08Polyurethanes from polyethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3009Sulfides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/068Ultra high molecular weight polyethylene

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Sliding-Contact Bearings (AREA)

Abstract

The invention discloses a kind of sliding bearing macromolecule polymer materials and metal mesh complex method, it is related to sliding bearing technical field, comprising the following steps: step A: stock, step B: prepares performed polymer, step C: preparation mixed raw material, step D: molding, step E: metal composite.The present invention solves the disadvantage that prior art middle (center) bearing polymer composite elasticity modulus is low, bearing capacity is poor, not easy to be processed, inorganic nano-particle and self-lubricating component (curing aluminium, ultra-high molecular weight polyethylene powder etc.) are introduced into reaction system, reduce the coefficient of friction of composite material, the abrasion resistance properties of composite material are improved simultaneously, and the coefficient of friction of material is 0.002-0.15.

Description

A kind of sliding bearing macromolecule polymer material and metal mesh complex method
Technical field
The present invention relates to sliding bearing technical field, in particular to a kind of sliding bearing macromolecule polymer material and metal Net complex method.
Background technique
Sliding bearing, the bearing to work under sliding friction, sliding bearing stable working, reliable, noiseless are moistened in liquid Under sliding condition, slidingsurface is separated by lubricating oil without directly contacting, and can also greatly reduce friction loss and surface mill Damage, oil film also has certain vibration absorption ability, but starting friction resistance is larger, and axis is known as axle journal by the part that bearing supports, with The part that axle journal matches is known as bearing shell, the antifriction material cast on its inner surface to improve the frictional property on bearing shell surface The material of layer referred to as jewel, bearing shell and jewel is referred to as material for sliding bearing, and sliding bearing application is generally in high speed Under the conditions of light duty.
Currently, prior art middle (center) bearing polymer composite that there is elasticity modulus is low, bearing capacity is poor, be not easy plus The shortcomings that work.
Therefore, a kind of sliding bearing macromolecule polymer material and metal mesh complex method are invented to solve the above problems very It is necessary to.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of sliding bearing macromolecule polymer materials and metal mesh composite square Method solves existing bearing polymer composite and haves the shortcomings that elasticity modulus is low, bearing capacity is poor, not easy to be processed Problem.
(2) technical solution
In order to achieve the above object, the present invention is achieved by the following technical programs: a kind of sliding bearing high molecular polymer material Material and metal mesh complex method, comprising the following steps:
Step A: stock (being divided by weight): 0.2-0.8 parts of glass fibre, 5-40 parts of ultra-high molecular weight polyethylene powder, nanometer 0.2-0.6 parts of titanium dioxide, 0.2-0.9 parts of Carbon fibe powder, 2-4 parts of aquadag, 0.4-0.7 parts of polytetrafluoroethylene powder, pre-polymerization 80 parts of body, 10-30 parts of chain extender, 8-15 parts of molybdenum disulfide;
Step B: it prepares performed polymer: polytetrahydrofuran diol 2000g, then vacuum dehydration, system cooling being added in the reactor Phenylene diisocyanate powder is added when to 80 DEG C, is stirred obtained performed polymer;
Step C: molybdenum disulfide, polytetrafluoroethylene powder, Carbon fibe powder, supra polymer preparation mixed raw material: are added in the reactor Weight northylen powder, nano-titanium dioxide are stirred obtained mixed raw material;
Step D: molding: chain extender is added in mixed raw material, then feeds injection into grinding tool, then is demoulded and is dried It can be prepared by polymer composite with vulcanization;
Step E: metal composite: by sintering technology on metal mesh sintering metal powder, by mixed raw material in metal powder layer On be sintered, make mixed raw material in conjunction with metal powder, to keep polymer composite compound with metal mesh;
Step F: quality test: the tensile strength that bearing is made and elongation at break and hardness are tested, guarantees the composite material It is qualified.
Optionally, the sliding bearing macromolecule polymer material includes following component (being divided by weight): glass fibers 0.2 part of dimension, 0.2 part of nano-titanium dioxide, 0.2 part of Carbon fibe powder, 2 parts of aquadag, is gathered 5 parts of ultra-high molecular weight polyethylene powder 0.4 part of tetrafluoroethene powder, 60 parts of performed polymer, 10 parts of chain extender, 8 parts of molybdenum disulfide.
Optionally, the sliding bearing macromolecule polymer material includes following component (being divided by weight): glass fibers 0.4 part of dimension, 0.4 part of nano-titanium dioxide, 0.5 part of Carbon fibe powder, 3 parts of aquadag, is gathered 20 parts of ultra-high molecular weight polyethylene powder 0.5 part of tetrafluoroethene powder, 70 parts of performed polymer, 20 parts of chain extender, 10 parts of molybdenum disulfide.
Optionally, the sliding bearing macromolecule polymer material includes following component (being divided by weight): glass fibers 0.8 part of dimension, 0.6 part of nano-titanium dioxide, 0.9 part of Carbon fibe powder, 4 parts of aquadag, is gathered 40 parts of ultra-high molecular weight polyethylene powder 0.7 part of tetrafluoroethene powder, 80 parts of performed polymer, 30 parts of chain extender, 15 parts of molybdenum disulfide.
Optionally, the partial size of the nano-titanium dioxide is 50-300nm;
The draw ratio of the glass fibre is 3-40.
(3) beneficial effect
The present invention provides a kind of sliding bearing macromolecule polymer materials and metal mesh complex method, have following beneficial to effect Fruit:
(1), the present invention solves that prior art middle (center) bearing polymer composite elasticity modulus is low, bearing capacity is poor, is not easy Inorganic nano-particle and self-lubricating component (curing aluminium, ultra-high molecular weight polyethylene powder etc.) are introduced into instead by the shortcomings that processing It answers in system, reduces the coefficient of friction of composite material, while improving the abrasion resistance properties of composite material, the friction system of material Number is 0.002-0.15.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment 1:
A kind of sliding bearing macromolecule polymer material and metal mesh complex method, comprising the following steps:
Step A: stock (being divided by weight): 0.2-0.8 parts of glass fibre, 5-40 parts of ultra-high molecular weight polyethylene powder, nanometer 0.2-0.6 parts of titanium dioxide, 0.2-0.9 parts of Carbon fibe powder, 2-4 parts of aquadag, 0.4-0.7 parts of polytetrafluoroethylene powder, pre-polymerization 80 parts of body, 10-30 parts of chain extender, 8-15 parts of molybdenum disulfide;
Step B: it prepares performed polymer: polytetrahydrofuran diol 2000g, then vacuum dehydration, system cooling being added in the reactor Phenylene diisocyanate powder is added when to 80 DEG C, is stirred obtained performed polymer;
Step C: molybdenum disulfide, polytetrafluoroethylene powder, Carbon fibe powder, supra polymer preparation mixed raw material: are added in the reactor Weight northylen powder, nano-titanium dioxide are stirred obtained mixed raw material, and the partial size of nano-titanium dioxide is 50-300nm, glass The draw ratio of fiber is 3-40;
Step D: molding: chain extender is added in mixed raw material, then feeds injection into grinding tool, then is demoulded and is dried It can be prepared by polymer composite with vulcanization;
Step E: metal composite: by sintering technology on metal mesh sintering metal powder, by mixed raw material in metal powder layer On be sintered, make mixed raw material in conjunction with metal powder, to keep polymer composite compound with metal mesh;
Step F: quality test: the tensile strength that bearing is made and elongation at break and hardness are tested, guarantees the composite material It is qualified.
Embodiment 2:
A kind of sliding bearing macromolecule polymer material and metal mesh complex method, comprising the following steps:
Step A: stock (being divided by weight): 0.4 part of glass fibre, 20 parts of ultra-high molecular weight polyethylene powder, nanometer titanium dioxide 0.4 part of titanium, 0.5 part of Carbon fibe powder, 3 parts of aquadag, 0.5 part of polytetrafluoroethylene powder, 70 parts of performed polymer, 20 parts of chain extender, two 10 parts of molybdenum sulfide;
Step B: it prepares performed polymer: polytetrahydrofuran diol 2000g, then vacuum dehydration, system cooling being added in the reactor Phenylene diisocyanate powder is added when to 80 DEG C, is stirred obtained performed polymer;
Step C: molybdenum disulfide, polytetrafluoroethylene powder, Carbon fibe powder, supra polymer preparation mixed raw material: are added in the reactor Weight northylen powder, nano-titanium dioxide are stirred obtained mixed raw material, and the partial size of nano-titanium dioxide is 50-300nm, glass The draw ratio of fiber is 3-40;
Step D: molding: chain extender is added in mixed raw material, then feeds injection into grinding tool, then is demoulded and is dried It can be prepared by polymer composite with vulcanization;
Step E: metal composite: by sintering technology on metal mesh sintering metal powder, by mixed raw material in metal powder layer On be sintered, make mixed raw material in conjunction with metal powder, to keep polymer composite compound with metal mesh;
Step F: quality test: the tensile strength that bearing is made and elongation at break and hardness are tested, guarantees the composite material It is qualified.
Embodiment 3:
A kind of sliding bearing macromolecule polymer material and metal mesh complex method, comprising the following steps:
Step A: stock (being divided by weight): 0.8 part of glass fibre, 40 parts of ultra-high molecular weight polyethylene powder, nanometer titanium dioxide 0.6 part of titanium, 0.9 part of Carbon fibe powder, 4 parts of aquadag, 0.7 part of polytetrafluoroethylene powder, 80 parts of performed polymer, 30 parts of chain extender, two 15 parts of molybdenum sulfide;
Step B: it prepares performed polymer: polytetrahydrofuran diol 2000g, then vacuum dehydration, system cooling being added in the reactor Phenylene diisocyanate powder is added when to 80 DEG C, is stirred obtained performed polymer;
Step C: molybdenum disulfide, polytetrafluoroethylene powder, Carbon fibe powder, supra polymer preparation mixed raw material: are added in the reactor Weight northylen powder, nano-titanium dioxide are stirred obtained mixed raw material, and the partial size of nano-titanium dioxide is 50-300nm, glass The draw ratio of fiber is 3-40;
Step D: molding: chain extender is added in mixed raw material, then feeds injection into grinding tool, then is demoulded and is dried It can be prepared by polymer composite with vulcanization;
Step E: metal composite: by sintering technology on metal mesh sintering metal powder, by mixed raw material in metal powder layer On be sintered, make mixed raw material in conjunction with metal powder, to keep polymer composite compound with metal mesh;
Step F: quality test: the tensile strength that bearing is made and elongation at break and hardness are tested, guarantees the composite material It is qualified.
Sliding bearing macromolecule polymer material can be made by above three groups of embodiments, wherein third group embodiment mentions Rise effect it is best, the present invention solve prior art middle (center) bearing polymer composite elasticity modulus is low, bearing capacity is poor, Disadvantage not easy to be processed introduces inorganic nano-particle and self-lubricating component (curing aluminium, ultra-high molecular weight polyethylene powder etc.) Into reaction system, the coefficient of friction of composite material is reduced, while improving the abrasion resistance properties of composite material, material rubs Wiping coefficient is 0.002-0.15.
It should be noted that in the present invention unless specifically defined or limited otherwise, fisrt feature is in second feature It can be that the first and second features directly contact or the first and second features are by intermediary mediate contact "up" or "down". Moreover, fisrt feature can be above the second feature " above ", " above " and " above " fisrt feature right above second feature or tiltedly Top, or first feature horizontal height is merely representative of higher than second feature.Fisrt feature second feature " under ", " lower section " and " following " can be fisrt feature and be directly under or diagonally below the second feature, or be merely representative of first feature horizontal height less than Two features.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention, Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features, All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention Within protection scope.

Claims (5)

1. a kind of sliding bearing macromolecule polymer material and metal mesh complex method, which comprises the following steps:
Step A: stock (being divided by weight): 0.2-0.8 parts of glass fibre, 5-40 parts of ultra-high molecular weight polyethylene powder, nanometer 0.2-0.6 parts of titanium dioxide, 0.2-0.9 parts of Carbon fibe powder, 2-4 parts of aquadag, 0.4-0.7 parts of polytetrafluoroethylene powder, pre-polymerization 80 parts of body, 10-30 parts of chain extender, 8-15 parts of molybdenum disulfide;
Step B: it prepares performed polymer: polytetrahydrofuran diol 2000g, then vacuum dehydration, system cooling being added in the reactor Phenylene diisocyanate powder is added when to 80 DEG C, is stirred obtained performed polymer;
Step C: molybdenum disulfide, polytetrafluoroethylene powder, Carbon fibe powder, supra polymer preparation mixed raw material: are added in the reactor Weight northylen powder, nano-titanium dioxide are stirred obtained mixed raw material;
Step D: molding: chain extender is added in mixed raw material, then feeds injection into grinding tool, then is demoulded and is dried It can be prepared by polymer composite with vulcanization;
Step E: metal composite: by sintering technology on metal mesh sintering metal powder, by mixed raw material in metal powder layer On be sintered, make mixed raw material in conjunction with metal powder, to keep polymer composite compound with metal mesh;
Step F: quality test: the tensile strength that bearing is made and elongation at break and hardness are tested, guarantees the composite material It is qualified.
2. a kind of sliding bearing macromolecule polymer material according to claim 1 and metal mesh complex method, feature It is:
The sliding bearing macromolecule polymer material includes following component (being divided by weight): 0.2 part of glass fibre, superelevation 5 parts of molecular weight polyethylene powder, 0.2 part of nano-titanium dioxide, 0.2 part of Carbon fibe powder, 2 parts of aquadag, polytetrafluoroethylene powder 0.4 Part, 60 parts of performed polymer, 10 parts of chain extender, 8 parts of molybdenum disulfide.
3. a kind of sliding bearing macromolecule polymer material according to claim 1 and metal mesh complex method, feature It is:
The sliding bearing macromolecule polymer material includes following component (being divided by weight): 0.4 part of glass fibre, superelevation 20 parts of molecular weight polyethylene powder, 0.4 part of nano-titanium dioxide, 0.5 part of Carbon fibe powder, 3 parts of aquadag, polytetrafluoroethylene powder 0.5 part, 70 parts of performed polymer, 20 parts of chain extender, 10 parts of molybdenum disulfide.
4. a kind of sliding bearing macromolecule polymer material according to claim 1 and metal mesh complex method, feature It is:
The sliding bearing macromolecule polymer material includes following component (being divided by weight): 0.8 part of glass fibre, superelevation 40 parts of molecular weight polyethylene powder, 0.6 part of nano-titanium dioxide, 0.9 part of Carbon fibe powder, 4 parts of aquadag, polytetrafluoroethylene powder 0.7 part, 80 parts of performed polymer, 30 parts of chain extender, 15 parts of molybdenum disulfide.
5. a kind of sliding bearing macromolecule polymer material according to claim 1 and metal mesh complex method, feature It is:
The partial size of the nano-titanium dioxide is 50-300nm;
The draw ratio of the glass fibre is 3-40.
CN201910696656.4A 2019-07-30 2019-07-30 A kind of sliding bearing macromolecule polymer material and metal mesh complex method Pending CN110499018A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110936644A (en) * 2019-12-24 2020-03-31 上海涟屹轴承科技有限公司 Sintering and curing method for polymer material bearing bush

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1312330A (en) * 2000-03-08 2001-09-12 奥依列斯工业株式会社 Resin composition for sliding element and sliding element produced thereby
CN102137885A (en) * 2008-09-26 2011-07-27 安德雷斯·霍芬瑙沃 metal semi-finished products
CN102643529A (en) * 2012-04-27 2012-08-22 中国科学院长春应用化学研究所 Polymer composite for bearing and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1312330A (en) * 2000-03-08 2001-09-12 奥依列斯工业株式会社 Resin composition for sliding element and sliding element produced thereby
CN102137885A (en) * 2008-09-26 2011-07-27 安德雷斯·霍芬瑙沃 metal semi-finished products
CN102643529A (en) * 2012-04-27 2012-08-22 中国科学院长春应用化学研究所 Polymer composite for bearing and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110936644A (en) * 2019-12-24 2020-03-31 上海涟屹轴承科技有限公司 Sintering and curing method for polymer material bearing bush

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Application publication date: 20191126