CN110491615A - A kind of neodymium-iron-boron preparation for DC micro-motor - Google Patents
A kind of neodymium-iron-boron preparation for DC micro-motor Download PDFInfo
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- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
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- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
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- H01F1/057—Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B
- H01F1/0571—Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B in the form of particles, e.g. rapid quenched powders or ribbon flakes
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- H01F1/0578—Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B in the form of particles, e.g. rapid quenched powders or ribbon flakes pressed, sintered or bonded together bonded together
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- H01F41/02—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
- H01F41/0253—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets for manufacturing permanent magnets
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Abstract
本发明涉及钕铁硼磁体技术领域,提供了一种用于小型直流电机的钕铁硼磁体制备方法,包括以下步骤:1)包覆粉末制备;2)磁粉复合;3)压制;4)固化;5)热轧或热冲压,最后得到各向异性钕铁硼磁体或弧形的各向同性钕铁硼磁体。本发明使用新型磁粉材料,通过新磁体制备步骤制备得到的新型钕铁硼磁体具有优异的磁性,良好的卷绕能力,较小的尺寸,将新型磁体应用于小型直流电机能够进一步减小直流电机的尺寸,减少直流电机的电流消耗,增加直流电机的机械输出。相比于传统磁体,各向异性钕铁硼磁体应用于小型直流电机可以将电流消耗减少至三分之二;弧形的各向同性钕铁硼磁体应用于小型直流电机可以将直流电机的机械输出增加约0.6倍。
The invention relates to the technical field of NdFeB magnets, and provides a method for preparing NdFeB magnets for small DC motors, comprising the following steps: 1) preparation of coated powder; 2) magnetic powder compounding; 3) pressing; 4) curing ; 5) hot rolling or hot stamping, and finally an anisotropic NdFeB magnet or an arc-shaped isotropic NdFeB magnet. The invention uses new magnetic powder materials, and the new neodymium-iron-boron magnets prepared by the new magnet preparation steps have excellent magnetic properties, good winding capacity, and small size. Applying the new magnets to small DC motors can further reduce the size of DC motors. The size of the DC motor reduces the current consumption of the DC motor and increases the mechanical output of the DC motor. Compared with traditional magnets, the application of anisotropic NdFeB magnets to small DC motors can reduce the current consumption to two-thirds; the application of arc-shaped isotropic NdFeB magnets to small DC motors can reduce the mechanical The output is increased by about 0.6 times.
Description
技术领域technical field
本发明涉及钕铁硼磁体技术领域,具体涉及一种用于小型直流电机的钕铁硼磁体制备方法。The invention relates to the technical field of neodymium-iron-boron magnets, in particular to a method for preparing neodymium-iron-boron magnets used in small DC motors.
背景技术Background technique
钕铁硼(Nd-Fe-B)磁体是最常用的稀土永磁体,广泛的应用于电子产品当中。钕铁硼(Nd-Fe-B)稀土永磁体可分为粘结磁体和烧结磁体两类,其中粘结磁体是由钕铁硼磁粉和粘结剂通过注射成型、压制成型或压延成型等方法来制备。粘结磁体具有形状自由度好、性价比高、体积小、性能优异等优点,因此广泛应用于计算机周边设备、办公自动化、直流电机当中。粘结磁体与烧结磁相比,粘结磁体可一次成形,可以做成各种形状复杂的磁体,将其应用在电机中可以大大减小电机的重量和体积。Neodymium iron boron (Nd-Fe-B) magnets are the most commonly used rare earth permanent magnets and are widely used in electronic products. Nd-Fe-B (Nd-Fe-B) rare earth permanent magnets can be divided into bonded magnets and sintered magnets. Bonded magnets are made of Nd-Fe-B magnetic powder and binder through injection molding, compression molding or calendering. to prepare. Bonded magnets have the advantages of good shape freedom, high cost performance, small size, and excellent performance, so they are widely used in computer peripheral equipment, office automation, and DC motors. Compared with sintered magnets, bonded magnets can be formed at one time and can be made into magnets with various complex shapes. Applying them to motors can greatly reduce the weight and volume of the motor.
为了进一步减小小型直流电机的尺寸,需要开发出一种新的制备具有优异磁性的新型磁体的技术。包括新技术在内的与粘结磁体制备相关的技术构成之间的关系如附图1所示,有必要改变磁体的制备方法,以提高粘结磁体的总性能。各向异性HDDR磁粉和各向同性球状磁粉未主要应用于小直流电动机的环形和弧形磁体的制备。为了将它们应用于小型直流电机,需要开发一种可以制备高密度粘合磁铁的新方法。In order to further reduce the size of small DC motors, a new technique for preparing novel magnets with excellent magnetic properties needs to be developed. The relationship among technical components related to the preparation of bonded magnets, including new technologies, is shown in Figure 1. It is necessary to change the preparation method of magnets to improve the overall performance of bonded magnets. Anisotropic HDDR magnetic powder and isotropic spherical magnetic powder are not mainly used in the preparation of ring and arc magnets for small DC motors. In order to apply them to small DC motors, it is necessary to develop a new method that can prepare high-density bonded magnets.
发明内容Contents of the invention
针对上述现有技术问题,本发明提供了一种用于小型直流电机的钕铁硼磁体制备方法,使用新型磁粉材料,通过新磁体制备方法制备了一种可应用于小型直流电机的粘结钕铁硼磁体。所制备的新型钕铁硼磁体具有优异的磁性,较小的尺寸,将新型磁体应用于小型直流电机可以进一步减小直流电机的尺寸。Aiming at the problems in the prior art above, the present invention provides a method for preparing a NdFeB magnet for a small DC motor, using a new type of magnetic powder material, and preparing a bonded NdFeB magnet that can be applied to a small DC motor through a new magnet preparation method. Iron boron magnets. The new NdFeB magnets prepared have excellent magnetic properties and small size, and applying the new magnets to small DC motors can further reduce the size of DC motors.
本发明采用以下的技术方案:The present invention adopts following technical scheme:
一种用于小型直流电机的钕铁硼磁体制备方法,包括以下步骤:A method for preparing a neodymium-iron-boron magnet for a small DC motor, comprising the following steps:
(1)包覆粉末制备:取固体环氧低聚物和磁粉,使用流化床反应器制备固体环氧低聚物包覆的磁粉,所述磁粉为各向异性HDDR磁粉或各向同性球状磁粉;(1) Coating powder preparation: take solid epoxy oligomer and magnetic powder, and use a fluidized bed reactor to prepare solid epoxy oligomer-coated magnetic powder. The magnetic powder is anisotropic HDDR magnetic powder or isotropic spherical magnetic powder;
(2)磁粉复合:将固体环氧低聚物包覆的磁粉与粉末固化剂和润滑剂使用冷混机进行干混,得到复合磁粉;(2) Magnetic powder compounding: dry-mix the magnetic powder coated with solid epoxy oligomer with powder curing agent and lubricant using a cold mixer to obtain composite magnetic powder;
(3)压制:将复合磁粉倒入粉末压制机的空腔中,在0.4~0.6GPa的压力下,1.5~1.6MA/m的轴向磁场中,80℃的温度下压制成近似网片状的高密度的生坯;(3) Compression: Pour the composite magnetic powder into the cavity of the powder compactor, under the pressure of 0.4-0.6GPa, in the axial magnetic field of 1.5-1.6MA/m, and press it into a similar mesh shape at a temperature of 80°C High-density green body;
(4)固化:将高密度生坯在160℃~200℃的温度下固化20分钟,得到片状的刚性粘结磁铁;(4) Curing: Curing the high-density green body at a temperature of 160°C to 200°C for 20 minutes to obtain a sheet-shaped rigid bonded magnet;
(5)当步骤(1)中的磁粉为各向异性HDDR磁粉时,进行热轧:(5) When the magnetic powder in step (1) is anisotropic HDDR magnetic powder, carry out hot rolling:
将片状的刚性粘结磁铁通过热轧机在60℃-80℃的温度下以20%-80%的轧制率轧制成片状磁体,得到各向异性钕铁硼磁体;The sheet-shaped rigid bonded magnet is rolled into a sheet-shaped magnet by a hot rolling mill at a temperature of 60°C-80°C at a rolling rate of 20%-80%, and an anisotropic NdFeB magnet is obtained;
当步骤(1)中的磁粉为各向同性球状磁粉时,进行热冲压:When the magnetic powder in step (1) is isotropic spherical magnetic powder, carry out hot stamping:
对片状的刚性粘结磁体进行热冲压处理,在1GPa的压力、110℃~130℃的条件下冲压片状刚性粘结磁铁,得到弧形的各向同性钕铁硼磁体。The sheet-shaped rigid bonded magnets are subjected to hot stamping treatment, and the sheet-shaped rigid bonded magnets are stamped under the pressure of 1GPa and 110°C to 130°C to obtain arc-shaped isotropic NdFeB magnets.
进一步地,所述各向异性钕铁硼磁体的厚度为2.0-2.5mm;所述弧形的各向同性钕铁硼磁体的内半径、外半径、最大厚度和最大长度分别为3.55mm、3.65mm、1.9mm和5mm。Further, the thickness of the anisotropic NdFeB magnet is 2.0-2.5mm; the inner radius, outer radius, maximum thickness and maximum length of the arc-shaped isotropic NdFeB magnet are 3.55mm and 3.65mm respectively. mm, 1.9mm and 5mm.
进一步地,将钕铁硼磁体放入到轧机中,在70℃的轧制温度下进行轧制。Further, the NdFeB magnets were put into a rolling mill and rolled at a rolling temperature of 70°C.
上述技术方案中,将所制备的磁体要卷曲成环状安装在小型直流电机上,这就需要新型的钕铁硼磁体具备一定的柔性,通过轧制使得制备的磁体具有一定的卷绕能力。In the above technical solution, the prepared magnet should be coiled into a ring shape and installed on a small DC motor, which requires a new type of NdFeB magnet to have a certain flexibility, and the prepared magnet has a certain winding ability through rolling.
为了使制备的磁体具有一定的柔韧性,将通过上述步骤制备的钕铁硼磁体放入到轧机中,在70℃的轧制温度下进行轧制,使其具有较好的柔韧性,良好的卷绕能力。In order to make the prepared magnets have certain flexibility, put the NdFeB magnets prepared through the above steps into the rolling mill, and roll them at a rolling temperature of 70°C to make them have better flexibility and good winding capacity.
进一步地,钕铁硼磁体轧制后的厚度为1.15mm左右。Further, the thickness of the NdFeB magnet after rolling is about 1.15mm.
进一步地,所述轧机为二辊薄板轧机,所述轧辊上辊和下辊的直径均为90mm。Further, the rolling mill is a two-roll thin plate rolling mill, and the diameters of the upper roll and the lower roll of the rolls are both 90 mm.
进一步地,所述固体环氧低聚物选自溴化双酚A型环氧树脂、酚醛型环氧树脂、双酚A型环氧树脂、苯酚甲醛型环氧树中的一种。Further, the solid epoxy oligomer is selected from one of brominated bisphenol A epoxy resin, novolac epoxy resin, bisphenol A epoxy resin, and phenol formaldehyde epoxy resin.
进一步地,所述粉末固化剂选自氨基树脂、芳香族多胺、酰肼、甲阶酚醛树脂、双氰胺、酸酐中的一种。Further, the powder curing agent is selected from one of amino resins, aromatic polyamines, hydrazides, resole phenolic resins, dicyandiamide, and acid anhydrides.
进一步地,所述润滑剂为十八酸锌盐。Further, the lubricant is zinc octadecanoate.
进一步地,步骤(1)中所述磁粉为各向异性HDDR磁粉时,各向异性HDDR磁粉、固体环氧低聚物、固化剂和润滑剂的质量百分比分别为96.2~98.1wt%、1.5~3.0wt%、0.1~0.3wt%、0.3~0.5wt%。Further, when the magnetic powder described in step (1) is anisotropic HDDR magnetic powder, the mass percentages of anisotropic HDDR magnetic powder, solid epoxy oligomer, curing agent and lubricant are respectively 96.2-98.1wt%, 1.5- 3.0wt%, 0.1-0.3wt%, 0.3-0.5wt%.
优选地,所述各向异性HDDR磁粉按质量百分比组成为:Nd:10%~15%,Dy:0.1%~0.5%,Co:5%~20%,Zr:0.05%~0.2%,Ga:0.2%~0.9%,B:5%~10%,余量为Fe。Preferably, the anisotropic HDDR magnetic powder is composed of: Nd: 10% to 15%, Dy: 0.1% to 0.5%, Co: 5% to 20%, Zr: 0.05% to 0.2%, Ga: 0.2%~0.9%, B: 5%~10%, the balance is Fe.
优选地,所述各向异性HDDR磁粉为通过HDDR(即氢化-歧化-解吸-再结晶)法制备得到的各向异性粘结磁体用磁粉。Preferably, the anisotropic HDDR magnetic powder is an anisotropic bonded magnet magnetic powder prepared by HDDR (ie hydrogenation-disproportionation-desorption-recrystallization) method.
进一步地,步骤(1)中所述磁粉为各向同性球状磁粉时,各向同性球状磁粉、固体环氧低聚物、固化剂和润滑剂的质量百分比分别为96.1~98.1wt%、1.5~3.0wt%、0.1~0.2wt%、0.3~0.7wt%。Further, when the magnetic powder described in step (1) is isotropic spherical magnetic powder, the mass percentages of isotropic spherical magnetic powder, solid epoxy oligomer, curing agent and lubricant are respectively 96.1 to 98.1 wt%, 1.5 to 3.0wt%, 0.1-0.2wt%, 0.3-0.7wt%.
优选地,所述各向同性球状磁粉按质量百分比组成为:Nd:7.0%~9.5%,B:5%~6%,Ti:0.2%~0.4%,Zr:0.1%~0.25%,余量为Fe。Preferably, the isotropic spherical magnetic powder is composed of: Nd: 7.0% to 9.5%, B: 5% to 6%, Ti: 0.2% to 0.4%, Zr: 0.1% to 0.25%, and the balance For Fe.
本发明具有的有益效果是:The beneficial effects that the present invention has are:
本发明将新型钕铁硼磁体制备材料粉末进行复合,通过压制制备高密度生坯,然后将片状生坯进行固化,通过热轧和热冲压的方法分别得到各向异性和各项同性新型磁体,最后通过轧制使磁体具有一定的卷绕能力,可以卷绕成环状应用于小型直流电机。In the present invention, the new-type NdFeB magnet preparation material powder is compounded, and a high-density green body is prepared by pressing, and then the sheet-shaped green body is solidified, and anisotropic and isotropic new-type magnets are respectively obtained by hot rolling and hot stamping. , and finally the magnet has a certain winding ability through rolling, which can be wound into a ring and applied to a small DC motor.
本发明使用新型磁粉材料,通过新磁体制备步骤制备得到的新型钕铁硼磁体与传统磁体相比,具有优异的磁性,良好的卷绕能力,因此通过轧制的磁体可以卷绕呈环状,应用于小型直流电机。Compared with traditional magnets, the new-type NdFeB magnets prepared by the new magnet powder materials in the present invention have excellent magnetic properties and good winding ability, so the rolled magnets can be wound into a ring shape, Applied to small DC motors.
将新型磁体应用于小型直流电机能够进一步减小直流电机的尺寸,减少直流电机的电流消耗,增加直流电机的机械输出。Applying the new type of magnet to a small DC motor can further reduce the size of the DC motor, reduce the current consumption of the DC motor, and increase the mechanical output of the DC motor.
本发明使用各向同性球状磁粉所制备的一种应用于小型直流电机的粘结钕铁硼磁体与传统磁体相比可以减小直流电机的电流消耗,将本发明所制备的磁体应用于小型直流电机可以将电流消耗减少至三分之二。The present invention uses isotropic spherical magnetic powder to prepare a bonded NdFeB magnet applied to small DC motors, which can reduce the current consumption of DC motors compared with traditional magnets. The magnet prepared by the present invention is applied to small DC motors The motor can reduce the current consumption to two-thirds.
本发明使用各向异性HDDR磁粉所制备的一种应用于小型直流电机的粘结钕铁硼磁体与传统磁体相比可以增加直流电机的机械输出,将本发明所制备的磁体应用于小型直流电机可以将直流电机的机械输出增加约0.6倍。The present invention uses anisotropic HDDR magnetic powder to prepare a bonded NdFeB magnet applied to small DC motors, which can increase the mechanical output of DC motors compared with traditional magnets, and apply the magnets prepared by the present invention to small DC motors It is possible to increase the mechanical output of a DC motor by a factor of about 0.6.
附图说明Description of drawings
图1为粘结磁体制备相关的技术构成之间的关系图;Figure 1 is a relationship diagram between the technical components related to the preparation of bonded magnets;
图2为本发明的技术路线图。Fig. 2 is a technical roadmap of the present invention.
具体实施方式Detailed ways
为了使本领域的技术人员进一步的了解本发明,下面结合具体实施例对本发明进行详细地说明。In order to enable those skilled in the art to further understand the present invention, the present invention will be described in detail below in conjunction with specific embodiments.
参阅图2,一种用于小型直流电机的钕铁硼磁体制备方法,包括以下步骤:Referring to Fig. 2, a kind of NdFeB magnet preparation method for small DC motor comprises the following steps:
(1)包覆粉末制备:取固体环氧低聚物和磁粉,使用流化床反应器制备固体环氧低聚物包覆的磁粉,所述磁粉为各向异性HDDR磁粉或各向同性球状磁粉;(1) Coating powder preparation: take solid epoxy oligomer and magnetic powder, and use a fluidized bed reactor to prepare solid epoxy oligomer-coated magnetic powder. The magnetic powder is anisotropic HDDR magnetic powder or isotropic spherical magnetic powder;
(2)磁粉复合:将固体环氧低聚物包覆的磁粉与粉末固化剂和润滑剂使用冷混机进行干混,得到复合磁粉;(2) Magnetic powder compounding: dry-mix the magnetic powder coated with solid epoxy oligomer with powder curing agent and lubricant using a cold mixer to obtain composite magnetic powder;
(3)压制:将复合磁粉倒入粉末压制机的空腔中,在0.4~0.6GPa的压力下,1.5~1.6MA/m的轴向磁场中,80℃的温度下压制成近似网片状的高密度的生坯;(3) Compression: Pour the composite magnetic powder into the cavity of the powder compactor, under the pressure of 0.4-0.6GPa, in the axial magnetic field of 1.5-1.6MA/m, and press it into a similar mesh shape at a temperature of 80°C High-density green body;
(4)固化:将高密度生坯在160℃~200℃的温度下固化20分钟,得到片状的刚性粘结磁铁;(4) Curing: Curing the high-density green body at a temperature of 160°C to 200°C for 20 minutes to obtain a sheet-shaped rigid bonded magnet;
(5)当步骤(1)中的磁粉为各向异性HDDR磁粉时,进行热轧:(5) When the magnetic powder in step (1) is anisotropic HDDR magnetic powder, carry out hot rolling:
将片状的刚性粘结磁铁通过热轧机在60℃-80℃的温度下以20%-80%的轧制率轧制成片状磁体,得到各向异性钕铁硼磁体;The sheet-shaped rigid bonded magnet is rolled into a sheet-shaped magnet by a hot rolling mill at a temperature of 60°C-80°C at a rolling rate of 20%-80%, and an anisotropic NdFeB magnet is obtained;
当步骤(1)中的磁粉为各向同性球状磁粉时,进行热冲压:When the magnetic powder in step (1) is isotropic spherical magnetic powder, carry out hot stamping:
对片状的刚性粘结磁体进行热冲压处理,在1GPa的压力、110℃~130℃的条件下冲压片状刚性粘结磁铁,得到弧形的各向同性钕铁硼磁体。The sheet-shaped rigid bonded magnets are subjected to hot stamping treatment, and the sheet-shaped rigid bonded magnets are stamped under the pressure of 1GPa and 110°C to 130°C to obtain arc-shaped isotropic NdFeB magnets.
实施例1Example 1
包括以下步骤:Include the following steps:
(1)配料:取各向异性HDDR磁粉2915g、双酚A型环氧树脂67g、双氰胺6g、十八酸锌盐12g。(1) Ingredients: Take 2915g of anisotropic HDDR magnetic powder, 67g of bisphenol A epoxy resin, 6g of dicyandiamide, and 12g of zinc octadecanoic acid.
(2)磁粉复合:首先进行预混合,通过流化床反应器制备包覆粉末,使用双酚A型环氧树脂将各向异性HDDR磁粉进行包覆。然后将双酚A型环氧树脂包覆的各向异性HDDR磁粉与双氰胺、十八酸锌盐通过冷混设备进行干混。(2) Magnetic powder compounding: pre-mixing is performed first, coating powder is prepared through a fluidized bed reactor, and anisotropic HDDR magnetic powder is coated with bisphenol A epoxy resin. Then, the anisotropic HDDR magnetic powder coated with bisphenol A epoxy resin, dicyandiamide, and zinc octadecanoic acid are dry-mixed by cold mixing equipment.
(3)压制:将步骤(2)得到的复合磁粉倒入粉末压制机的空腔中,并在0.55GPa的压力下,1.5MA/m的轴向磁场中,80℃的温度下压制成近似网片状的高密度的生坯。(3) Compression: Pour the composite magnetic powder obtained in step (2) into the cavity of a powder compactor, and press it under a pressure of 0.55GPa, an axial magnetic field of 1.5MA/m, and a temperature of 80°C to form an approximate Mesh-like high-density green body.
(4)固化:将步骤(3)得到的高密度生坯在180℃下的温度下固化20分钟,得到片状的刚性粘结磁铁。(4) Curing: curing the high-density green body obtained in step (3) at a temperature of 180° C. for 20 minutes to obtain a sheet-shaped rigid bonded magnet.
(5)热轧:将步骤(4)所得到的片状刚性粘结磁铁通过热轧机在70℃的温度下以约50%的轧制率轧制成片状磁体。(5) Hot rolling: the sheet-shaped rigid bonded magnet obtained in step (4) is rolled into a sheet-shaped magnet at a temperature of 70° C. at a rolling rate of about 50% by a hot rolling mill.
(6)轧制:将通过上述步骤制备的钕铁硼磁体放入到上辊和下辊的直径均为90mm的二辊薄板轧机中,在70℃的轧制温度下进行轧制,使其具有较好的柔韧性,良好的卷绕能力。(6) Rolling: put the NdFeB magnet prepared by the above steps into a two-roll thin plate mill with a diameter of 90mm for the upper roll and the lower roll, and roll at a rolling temperature of 70°C to make it It has good flexibility and good winding ability.
实施例2Example 2
(1)配料:各向同性球状磁粉2900g、双酚A型环氧树脂75g、双氰胺10g、十八酸锌盐15g。(1) Ingredients: 2900g of isotropic spherical magnetic powder, 75g of bisphenol A epoxy resin, 10g of dicyandiamide, and 15g of zinc octadecanoic acid.
(2)磁粉复合:首先进行预混合,通过流化床反应器制备包覆粉末,使用双酚A型环氧树脂将各向同性球状磁粉进行包覆。然后将双酚A型环氧树脂包覆的各向同性球状磁粉与双氰胺、十八酸锌盐通过冷混设备进行干混。(2) Magnetic powder compounding: pre-mixing is performed first, coating powder is prepared through a fluidized bed reactor, and isotropic spherical magnetic powder is coated with bisphenol A epoxy resin. Then dry-mix the isotropic spherical magnetic powder coated with bisphenol A type epoxy resin, dicyandiamide and zinc octadecanoic acid through cold mixing equipment.
(3)压制:将步骤(2)得到的复合磁粉倒入粉末压制机的空腔中,并在0.5GPa的压力下,1.5MA/m的轴向磁场中,80℃的温度下压制成近似网片状的高密度的生坯。(3) Compression: Pour the composite magnetic powder obtained in step (2) into the cavity of a powder compactor, and press it under a pressure of 0.5GPa, an axial magnetic field of 1.5MA/m, and a temperature of 80°C to form an approximate Mesh-like high-density green body.
(4)固化:将步骤(3)得到的高密度生坯在180℃下的温度下固化20分钟,得到片状的刚性粘结磁铁。(4) Curing: curing the high-density green body obtained in step (3) at a temperature of 180° C. for 20 minutes to obtain a sheet-shaped rigid bonded magnet.
(5)热冲压:对步骤(4)得到的片状刚性粘结磁体进行热冲压处理,在1GPa的压力、120℃的条件下冲压出片状刚性粘结磁铁,得到弧形的各向同性钕铁硼磁铁。(5) Hot stamping: Hot stamping is performed on the sheet-shaped rigid bonded magnet obtained in step (4), and the sheet-shaped rigid bonded magnet is stamped out at a pressure of 1GPa and 120°C to obtain an arc-shaped isotropic magnet. NdFeB magnets.
(6)轧制:将通过上述步骤制备的钕铁硼磁体放入到上辊和下辊的直径均为90mm的二辊薄板轧机中,在70℃的轧制温度下进行轧制,使其具有较好的柔韧性,良好的卷绕能力。(6) Rolling: put the NdFeB magnet prepared by the above steps into a two-roll thin plate mill with a diameter of 90mm for the upper roll and the lower roll, and roll at a rolling temperature of 70°C to make it It has good flexibility and good winding ability.
实施例3Example 3
(1)配料:取各向异性HDDR磁粉962g、溴化双酚A型环氧树脂15g、氨基树脂1g、十八酸锌盐3g。(1) Ingredients: Take 962g of anisotropic HDDR magnetic powder, 15g of brominated bisphenol A epoxy resin, 1g of amino resin, and 3g of zinc octadecanoic acid.
(2)磁粉复合:首先进行预混合,通过流化床反应器制备包覆粉末,使用溴化双酚A型环氧树脂将各向异性HDDR磁粉进行包覆;然后将溴化双酚A型环氧树脂包覆的HDDR磁粉与氨基树脂、十八酸锌盐使用冷混机进行干混,得到复合磁粉。(2) Magnetic powder compounding: pre-mix first, prepare coated powder through a fluidized bed reactor, and use brominated bisphenol A type epoxy resin to coat anisotropic HDDR magnetic powder; then brominated bisphenol A type The epoxy resin-coated HDDR magnetic powder is dry-mixed with amino resin and octadecanoic acid zinc salt using a cold mixer to obtain composite magnetic powder.
(3)压制:将复合磁粉倒入粉末压制机的空腔中,在0.4GPa的压力下,1.6MA/m的轴向磁场中,80℃的温度下压制成近似网片状的高密度的生坯。(3) Compression: Pour the composite magnetic powder into the cavity of the powder compactor, under the pressure of 0.4GPa, in the axial magnetic field of 1.6MA/m, and at the temperature of 80°C, it is pressed into a high-density material in the shape of a mesh green body.
(4)固化:将高密度生坯在160℃的温度下固化20分钟,得到片状的刚性粘结磁铁。(4) Curing: The high-density green body was cured at a temperature of 160° C. for 20 minutes to obtain a sheet-shaped rigid bonded magnet.
(5)热轧:将片状刚性粘结磁铁通过热轧机在60℃的温度下以约20%的轧制率轧制成片状磁体。最终所制备的各向异性钕铁硼磁体厚度约为2.5mm。(5) Hot rolling: the sheet-shaped rigid bonded magnet is rolled into a sheet-shaped magnet at a temperature of 60° C. at a rolling rate of about 20% by a hot rolling mill. The finally prepared anisotropic NdFeB magnet has a thickness of about 2.5mm.
(6)轧制:将通过上述步骤制备的钕铁硼磁体放入到上辊和下辊的直径均为90mm的二辊薄板轧机中,在70℃的轧制温度下进行轧制,使其具有较好的柔韧性,良好的卷绕能力。(6) Rolling: put the NdFeB magnet prepared by the above steps into a two-roll thin plate mill with a diameter of 90mm for the upper roll and the lower roll, and roll at a rolling temperature of 70°C to make it It has good flexibility and good winding ability.
实施例4Example 4
(1)配料:取各向异性HDDR磁粉981g、酚醛型环氧树脂30g、芳香族多胺3g、十八酸锌盐5g。(1) Ingredients: Take 981g of anisotropic HDDR magnetic powder, 30g of phenolic epoxy resin, 3g of aromatic polyamine, and 5g of zinc octadecanoic acid.
所述各向异性HDDR磁粉按质量百分比组成为:Nd:10%,Dy:0.1%,Co:5%,Zr:0.05%,Ga:0.2%,B:5%,余量为Fe。The anisotropic HDDR magnetic powder is composed of Nd: 10%, Dy: 0.1%, Co: 5%, Zr: 0.05%, Ga: 0.2%, B: 5%, and the balance is Fe.
(2)磁粉复合:首先进行预混合,通过流化床反应器制备包覆粉末,使用酚醛型环氧树脂将各向异性HDDR磁粉进行包覆;然后将酚醛型环氧树脂包覆的HDDR磁粉与芳香族多胺、十八酸锌盐使用冷混机进行干混,得到复合磁粉。(2) Magnetic powder compounding: pre-mix first, prepare coated powder through a fluidized bed reactor, and use phenolic epoxy resin to coat the anisotropic HDDR magnetic powder; then the phenolic epoxy resin coated HDDR magnetic powder It is dry mixed with aromatic polyamine and octadecanoic acid zinc salt using a cold mixer to obtain composite magnetic powder.
(3)压制:将复合磁粉倒入粉末压制机的空腔中,在0.6GPa的压力下,1.6MA/m的轴向磁场中,80℃的温度下压制成近似网片状的高密度的生坯。(3) Compression: Pour the composite magnetic powder into the cavity of the powder compactor, under the pressure of 0.6GPa, in the axial magnetic field of 1.6MA/m, and at the temperature of 80°C, it is pressed into a high-density, approximately mesh-like green body.
(4)固化:将高密度生坯在200℃的温度下固化20分钟,得到片状的刚性粘结磁铁。(4) Curing: The high-density green body was cured at a temperature of 200° C. for 20 minutes to obtain a sheet-shaped rigid bonded magnet.
(5)热轧:将片状刚性粘结磁铁通过热轧机在80℃的温度下以约80%的轧制率轧制成片状磁体。最终所制备的各向异性钕铁硼磁体厚度约为2.0mm。(5) Hot rolling: the sheet-shaped rigid bonded magnet is rolled into a sheet-shaped magnet at a temperature of 80° C. at a rolling rate of about 80% by a hot rolling mill. The finally prepared anisotropic NdFeB magnet has a thickness of about 2.0 mm.
(6)轧制:将通过上述步骤制备的钕铁硼磁体放入到上辊和下辊的直径均为90mm的二辊薄板轧机中,在70℃的轧制温度下进行轧制,使其具有较好的柔韧性,良好的卷绕能力。(6) Rolling: put the NdFeB magnet prepared by the above steps into a two-roll thin plate mill with a diameter of 90mm for the upper roll and the lower roll, and roll at a rolling temperature of 70°C to make it It has good flexibility and good winding ability.
实施例5Example 5
(1)配料:取各向异性HDDR磁粉970、苯酚甲醛型环氧树20g、甲阶酚醛树脂2g、十八酸锌盐4g。(1) Ingredients: Anisotropic HDDR magnetic powder 970, 20 g of phenol-formaldehyde epoxy resin, 2 g of resole phenolic resin, and 4 g of zinc octadecanoic acid.
所述各向异性HDDR磁粉按质量百分比组成为:Nd:15%,Dy:0.5%,Co:20%,Zr:0.2%,Ga:0.9%,B:10%,余量为Fe。The anisotropic HDDR magnetic powder is composed of Nd: 15%, Dy: 0.5%, Co: 20%, Zr: 0.2%, Ga: 0.9%, B: 10%, and the balance is Fe.
各向异性HDDR磁粉为通过HDDR(即氢化-歧化-解吸-再结晶)法制备得到的各向异性粘结磁体用磁粉。Anisotropic HDDR magnetic powder is an anisotropic bonded magnet magnetic powder prepared by HDDR (ie hydrogenation-disproportionation-desorption-recrystallization) method.
(2)磁粉复合:首先进行预混合,通过流化床反应器制备包覆粉末,使用苯酚甲醛型环氧树将各向异性HDDR磁粉进行包覆;然后将苯酚甲醛型环氧树包覆的HDDR磁粉与甲阶酚醛树脂、十八酸锌盐使用冷混机进行干混,得到复合磁粉。(2) Magnetic powder compounding: first pre-mix, prepare coated powder through a fluidized bed reactor, use phenol formaldehyde epoxy resin to coat anisotropic HDDR magnetic powder; then phenol formaldehyde epoxy resin coated HDDR magnetic powder is dry mixed with resole phenolic resin and zinc octadecanoic acid using a cold mixer to obtain composite magnetic powder.
(3)压制:将复合磁粉倒入粉末压制机的空腔中,在0.45GPa的压力下,1.6MA/m的轴向磁场中,80℃的温度下压制成近似网片状的高密度的生坯。(3) Compression: Pour the composite magnetic powder into the cavity of the powder compactor, press it into a mesh-like high-density powder under a pressure of 0.45GPa, an axial magnetic field of 1.6MA/m, and a temperature of 80°C. green body.
(4)固化:将高密度生坯在180℃的温度下固化20分钟,得到片状的刚性粘结磁铁。(4) Curing: The high-density green body was cured at a temperature of 180° C. for 20 minutes to obtain a sheet-shaped rigid bonded magnet.
(5)热轧:将片状刚性粘结磁铁通过热轧机在65℃的温度下以约60%的轧制率轧制成片状磁体。(5) Hot rolling: the sheet-shaped rigid bonded magnet is rolled into a sheet-shaped magnet at a temperature of 65° C. at a rolling rate of about 60% by a hot rolling mill.
(6)轧制:将通过上述步骤制备的钕铁硼磁体放入到上辊和下辊的直径均为90mm的二辊薄板轧机中,在70℃的轧制温度下进行轧制,使其具有较好的柔韧性,良好的卷绕能力。(6) Rolling: put the NdFeB magnet prepared by the above steps into a two-roll thin plate mill with a diameter of 90mm for the upper roll and the lower roll, and roll at a rolling temperature of 70°C to make it It has good flexibility and good winding ability.
实施例6Example 6
(1)配料:各向同性球状磁粉961g、酚醛型环氧树脂15g、酰肼1g、十八酸锌盐3g。、(1) Ingredients: 961g of isotropic spherical magnetic powder, 15g of phenolic epoxy resin, 1g of hydrazide, 3g of zinc octadecanoate. ,
(2)磁粉复合:首先进行预混合,通过流化床反应器制备包覆粉末,使用酚醛型环氧树脂将各向同性球状磁粉进行包覆;然后将酚醛型环氧树脂包覆的各向同性球状磁粉与酰肼、十八酸锌盐使用冷混机进行干混,得到复合磁粉。(2) Magnetic powder compounding: first pre-mix, prepare coated powder through a fluidized bed reactor, use phenolic epoxy resin to coat the isotropic spherical magnetic powder; then coat the isotropic spherical magnetic powder coated with phenolic epoxy resin The homogeneous spherical magnetic powder is dry mixed with hydrazide and octadecanoic acid zinc salt using a cold mixer to obtain composite magnetic powder.
(3)压制:将复合磁粉倒入粉末压制机的空腔中,在0.4GPa的压力下,1.6MA/m的轴向磁场中,80℃的温度下压制成近似网片状的高密度的生坯。(3) Compression: Pour the composite magnetic powder into the cavity of the powder compactor, under the pressure of 0.4GPa, in the axial magnetic field of 1.6MA/m, and at the temperature of 80°C, it is pressed into a high-density material in the shape of a mesh green body.
(4)固化:将高密度生坯在160℃的温度下固化20分钟,得到片状的刚性粘结磁铁。(4) Curing: The high-density green body was cured at a temperature of 160° C. for 20 minutes to obtain a sheet-shaped rigid bonded magnet.
(5)热冲压:对片状刚性粘结磁体进行热冲压处理,在1GPa的压力、110℃的条件下冲压出片状刚性粘结磁铁,得到弧形的各向同性钕铁硼磁铁。(5) Hot stamping: Perform hot stamping treatment on the sheet-shaped rigid bonded magnet, and stamp out the sheet-shaped rigid bonded magnet under the pressure of 1GPa and 110°C to obtain an arc-shaped isotropic NdFeB magnet.
(6)轧制:将通过上述步骤制备的钕铁硼磁体放入到上辊和下辊的直径均为90mm的二辊薄板轧机中,在70℃的轧制温度下进行轧制,使其具有较好的柔韧性,良好的卷绕能力。(6) Rolling: put the NdFeB magnet prepared by the above steps into a two-roll thin plate mill with a diameter of 90mm for the upper roll and the lower roll, and roll at a rolling temperature of 70°C to make it It has good flexibility and good winding ability.
实施例7Example 7
(1)配料:各向同性球状磁粉981g、苯酚甲醛型环氧树30g、酸酐2g、十八酸锌盐7g。(1) Ingredients: 981g of isotropic spherical magnetic powder, 30g of phenol-formaldehyde epoxy resin, 2g of acid anhydride, 7g of zinc octadecanoic acid.
所述各向同性球状磁粉按质量百分比组成为:Nd:7.0%~9.5%,B:5%~6%,Ti:0.2%~0.4%,Zr:0.1%~0.25%,余量为Fe。The isotropic spherical magnetic powder is composed of Nd: 7.0%-9.5%, B: 5%-6%, Ti: 0.2%-0.4%, Zr: 0.1%-0.25%, and the balance is Fe.
(2)磁粉复合:首先进行预混合,通过流化床反应器制备包覆粉末,使用苯酚甲醛型环氧树将各向同性球状磁粉进行包覆;然后将苯酚甲醛型环氧树包覆的各向同性球状磁粉与酸酐、十八酸锌盐使用冷混机进行干混,得到复合磁粉。(2) Magnetic powder compounding: first pre-mix, prepare coated powder through a fluidized bed reactor, use phenol formaldehyde epoxy resin to coat isotropic spherical magnetic powder; then phenol formaldehyde epoxy resin coated The isotropic spherical magnetic powder is dry mixed with acid anhydride and octadecanoic acid zinc salt using a cold mixer to obtain composite magnetic powder.
(3)压制:将复合磁粉倒入粉末压制机的空腔中,在0.6GPa的压力下,1.6MA/m的轴向磁场中,80℃的温度下压制成近似网片状的高密度的生坯。(3) Compression: Pour the composite magnetic powder into the cavity of the powder compactor, under the pressure of 0.6GPa, in the axial magnetic field of 1.6MA/m, and at the temperature of 80°C, it is pressed into a high-density, approximately mesh-like green body.
(4)固化:将高密度生坯在200℃的温度下固化20分钟,得到片状的刚性粘结磁铁。(4) Curing: The high-density green body was cured at a temperature of 200° C. for 20 minutes to obtain a sheet-shaped rigid bonded magnet.
(5)热冲压:对片状刚性粘结磁体进行热冲压处理,在1GPa的压力、130℃的条件下冲压出片状刚性粘结磁铁,得到弧形的各向同性钕铁硼磁铁。(5) Hot stamping: Perform hot stamping treatment on the sheet-shaped rigid bonded magnet, and punch out the sheet-shaped rigid bonded magnet under the pressure of 1GPa and 130°C to obtain an arc-shaped isotropic NdFeB magnet.
(6)轧制:将通过上述步骤制备的钕铁硼磁体放入到上辊和下辊的直径均为90mm的二辊薄板轧机中,在70℃的轧制温度下进行轧制,使其具有较好的柔韧性,良好的卷绕能力。(6) Rolling: put the NdFeB magnet prepared by the above steps into a two-roll thin plate mill with a diameter of 90mm for the upper roll and the lower roll, and roll at a rolling temperature of 70°C to make it It has good flexibility and good winding ability.
实施例8Example 8
(1)配料:各向同性球状磁粉970g、溴化双酚A型环氧树脂20g、甲阶酚醛树脂1.5g、十八酸锌盐5g。(1) Ingredients: 970g of isotropic spherical magnetic powder, 20g of brominated bisphenol A epoxy resin, 1.5g of resole phenolic resin, 5g of zinc octadecanoic acid.
所述各向同性球状磁粉按质量百分比组成为:Nd:7.0%~9.5%,B:5%~6%,Ti:0.2%~0.4%,Zr:0.1%~0.25%,余量为Fe。The isotropic spherical magnetic powder is composed of Nd: 7.0%-9.5%, B: 5%-6%, Ti: 0.2%-0.4%, Zr: 0.1%-0.25%, and the balance is Fe.
(2)磁粉复合:首先进行预混合,通过流化床反应器制备包覆粉末,使用溴化双酚A型环氧树脂将各向同性球状磁粉进行包覆;然后将溴化双酚A型环氧树脂包覆的各向同性球状磁粉与甲阶酚醛树脂、十八酸锌盐使用冷混机进行干混,得到复合磁粉。(2) Magnetic powder compounding: first pre-mix, prepare coated powder through a fluidized bed reactor, and use brominated bisphenol A type epoxy resin to coat isotropic spherical magnetic powder; then brominated bisphenol A type The isotropic spherical magnetic powder coated with epoxy resin is dry-mixed with resole phenolic resin and zinc octadecanoate using a cold mixer to obtain composite magnetic powder.
(3)压制:将复合磁粉倒入粉末压制机的空腔中,在0.5GPa的压力下,1.6MA/m的轴向磁场中,80℃的温度下压制成近似网片状的高密度的生坯。(3) Compression: Pour the composite magnetic powder into the cavity of the powder compactor, under the pressure of 0.5GPa, in the axial magnetic field of 1.6MA/m, and at the temperature of 80°C, it is pressed into a high-density material in the shape of a mesh green body.
(4)固化:将高密度生坯在190℃的温度下固化20分钟,得到片状的刚性粘结磁铁。(4) Curing: The high-density green body was cured at a temperature of 190° C. for 20 minutes to obtain a sheet-shaped rigid bonded magnet.
(5)热冲压:对片状刚性粘结磁体进行热冲压处理,在1GPa的压力、120℃的条件下冲压出片状刚性粘结磁铁,得到弧形的各向同性钕铁硼磁铁。(5) Hot stamping: Perform hot stamping treatment on the sheet-shaped rigid bonded magnet, and punch out the sheet-shaped rigid bonded magnet under the pressure of 1GPa and 120°C to obtain an arc-shaped isotropic NdFeB magnet.
(6)轧制:将通过上述步骤制备的钕铁硼磁体放入到上辊和下辊的直径均为90mm的二辊薄板轧机中,在70℃的轧制温度下进行轧制,使其具有较好的柔韧性,良好的卷绕能力。(6) Rolling: put the NdFeB magnet prepared by the above steps into a two-roll thin plate mill with a diameter of 90mm for the upper roll and the lower roll, and roll at a rolling temperature of 70°C to make it It has good flexibility and good winding ability.
实施例9Example 9
(1)配料:各向同性球状磁粉975g、双酚A型环氧树脂25g、芳香族多胺1.8g、十八酸锌盐6g。(1) Ingredients: 975g of isotropic spherical magnetic powder, 25g of bisphenol A epoxy resin, 1.8g of aromatic polyamine, 6g of zinc octadecanoate.
所述各向同性球状磁粉按质量百分比组成为:Nd:7.0%~9.5%,B:5%~6%,Ti:0.2%~0.4%,Zr:0.1%~0.25%,余量为Fe。The isotropic spherical magnetic powder is composed of Nd: 7.0%-9.5%, B: 5%-6%, Ti: 0.2%-0.4%, Zr: 0.1%-0.25%, and the balance is Fe.
(2)磁粉复合:首先进行预混合,通过流化床反应器制备包覆粉末,使用双酚A型环氧树脂将各向同性球状磁粉进行包覆;然后将双酚A型环氧树脂包覆的各向同性球状磁粉与芳香族多胺、十八酸锌盐使用冷混机进行干混,得到复合磁粉。(2) Magnetic powder compounding: first pre-mix, prepare coated powder through a fluidized bed reactor, use bisphenol A epoxy resin to coat isotropic spherical magnetic powder; then bisphenol A epoxy resin coated The coated isotropic spherical magnetic powder is dry mixed with aromatic polyamine and octadecanoic acid zinc salt using a cold mixer to obtain composite magnetic powder.
(3)压制:将复合磁粉倒入粉末压制机的空腔中,在0.55GPa的压力下,1.6MA/m的轴向磁场中,80℃的温度下压制成近似网片状的高密度的生坯。(3) Compression: Pour the composite magnetic powder into the cavity of the powder compactor, under the pressure of 0.55GPa, in the axial magnetic field of 1.6MA/m, and at the temperature of 80°C, it is pressed into a high-density material with a similar mesh shape. green body.
(4)固化:将高密度生坯在185℃的温度下固化20分钟,得到片状的刚性粘结磁铁。(4) Curing: The high-density green body was cured at a temperature of 185° C. for 20 minutes to obtain a sheet-shaped rigid bonded magnet.
(5)热冲压:对片状刚性粘结磁体进行热冲压处理,在1GPa的压力、115℃的条件下冲压出片状刚性粘结磁铁,得到弧形的各向同性钕铁硼磁铁。(5) Hot stamping: Perform hot stamping treatment on the sheet-shaped rigid bonded magnet, and punch out the sheet-shaped rigid bonded magnet under the pressure of 1GPa and 115°C to obtain an arc-shaped isotropic NdFeB magnet.
(6)轧制:将通过上述步骤制备的钕铁硼磁体放入到上辊和下辊的直径均为90mm的二辊薄板轧机中,在70℃的轧制温度下进行轧制,使其具有较好的柔韧性,良好的卷绕能力。(6) Rolling: put the NdFeB magnet prepared by the above steps into a two-roll thin plate mill with a diameter of 90mm for the upper roll and the lower roll, and roll at a rolling temperature of 70°C to make it It has good flexibility and good winding ability.
当然,上述说明并非是对本发明的限制,本发明也并不仅限于上述举例,本技术领域的技术人员在本发明的实质范围内所做出的变化、改型、添加或替换,也应属于本发明的保护范围。Of course, the above descriptions are not intended to limit the present invention, and the present invention is not limited to the above examples. Changes, modifications, additions or replacements made by those skilled in the art within the scope of the present invention shall also belong to the present invention. protection scope of the invention.
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