CN110452478A - A kind of down toy and its processing method using PVC complex plastic material - Google Patents
A kind of down toy and its processing method using PVC complex plastic material Download PDFInfo
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- CN110452478A CN110452478A CN201910659714.6A CN201910659714A CN110452478A CN 110452478 A CN110452478 A CN 110452478A CN 201910659714 A CN201910659714 A CN 201910659714A CN 110452478 A CN110452478 A CN 110452478A
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- 239000000463 material Substances 0.000 title claims abstract description 60
- 229920003023 plastic Polymers 0.000 title claims abstract description 43
- 239000004033 plastic Substances 0.000 title claims abstract description 43
- 238000003672 processing method Methods 0.000 title abstract description 9
- 239000002131 composite material Substances 0.000 claims abstract description 60
- GZCWPZJOEIAXRU-UHFFFAOYSA-N tin zinc Chemical compound [Zn].[Sn] GZCWPZJOEIAXRU-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 239000003381 stabilizer Substances 0.000 claims abstract description 10
- 239000000945 filler Substances 0.000 claims abstract description 4
- 239000003063 flame retardant Substances 0.000 claims abstract description 4
- 239000000314 lubricant Substances 0.000 claims abstract description 4
- 239000004014 plasticizer Substances 0.000 claims abstract description 4
- 239000012745 toughening agent Substances 0.000 claims abstract description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 27
- 238000002156 mixing Methods 0.000 claims description 24
- 239000007822 coupling agent Substances 0.000 claims description 22
- -1 zirconium ester Chemical class 0.000 claims description 22
- 229910001887 tin oxide Inorganic materials 0.000 claims description 21
- 229910052726 zirconium Inorganic materials 0.000 claims description 21
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 12
- 235000019441 ethanol Nutrition 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 7
- 239000004246 zinc acetate Substances 0.000 claims description 7
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims description 6
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 claims description 6
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical group [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims description 6
- QWJYDTCSUDMGSU-UHFFFAOYSA-N [Sn].[C] Chemical compound [Sn].[C] QWJYDTCSUDMGSU-UHFFFAOYSA-N 0.000 claims description 6
- DBJUEJCZPKMDPA-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O DBJUEJCZPKMDPA-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000012065 filter cake Substances 0.000 claims description 6
- 239000003365 glass fiber Substances 0.000 claims description 6
- 239000011812 mixed powder Substances 0.000 claims description 6
- 238000005453 pelletization Methods 0.000 claims description 6
- 235000012424 soybean oil Nutrition 0.000 claims description 6
- 239000003549 soybean oil Substances 0.000 claims description 6
- KHMOASUYFVRATF-UHFFFAOYSA-J tin(4+);tetrachloride;pentahydrate Chemical compound O.O.O.O.O.Cl[Sn](Cl)(Cl)Cl KHMOASUYFVRATF-UHFFFAOYSA-J 0.000 claims description 6
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 claims description 6
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical group C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 5
- 230000008859 change Effects 0.000 claims description 4
- 230000006835 compression Effects 0.000 claims description 4
- 238000007906 compression Methods 0.000 claims description 4
- 238000004321 preservation Methods 0.000 claims description 4
- 239000004809 Teflon Substances 0.000 claims description 3
- 229920006362 Teflon® Polymers 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000008188 pellet Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 238000005461 lubrication Methods 0.000 claims 1
- 239000010959 steel Substances 0.000 claims 1
- 230000005855 radiation Effects 0.000 abstract description 21
- 230000032683 aging Effects 0.000 abstract description 14
- 229920000915 polyvinyl chloride Polymers 0.000 description 48
- 239000004800 polyvinyl chloride Substances 0.000 description 48
- 230000000052 comparative effect Effects 0.000 description 39
- 239000000243 solution Substances 0.000 description 29
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 13
- 230000007423 decrease Effects 0.000 description 10
- 230000004048 modification Effects 0.000 description 8
- 238000012986 modification Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 239000011787 zinc oxide Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- 239000006087 Silane Coupling Agent Substances 0.000 description 4
- 238000013019 agitation Methods 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 238000012216 screening Methods 0.000 description 4
- 239000002699 waste material Substances 0.000 description 3
- RAZLJUXJEOEYAM-UHFFFAOYSA-N 2-[bis[2-(2,6-dioxomorpholin-4-yl)ethyl]azaniumyl]acetate Chemical compound C1C(=O)OC(=O)CN1CCN(CC(=O)O)CCN1CC(=O)OC(=O)C1 RAZLJUXJEOEYAM-UHFFFAOYSA-N 0.000 description 2
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 2
- QUUCYKKMFLJLFS-UHFFFAOYSA-N Dehydroabietan Natural products CC1(C)CCCC2(C)C3=CC=C(C(C)C)C=C3CCC21 QUUCYKKMFLJLFS-UHFFFAOYSA-N 0.000 description 2
- NFWKVWVWBFBAOV-UHFFFAOYSA-N Dehydroabietic acid Natural products OC(=O)C1(C)CCCC2(C)C3=CC=C(C(C)C)C=C3CCC21 NFWKVWVWBFBAOV-UHFFFAOYSA-N 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000011258 core-shell material Substances 0.000 description 2
- NFWKVWVWBFBAOV-MISYRCLQSA-N dehydroabietic acid Chemical compound OC(=O)[C@]1(C)CCC[C@]2(C)C3=CC=C(C(C)C)C=C3CC[C@H]21 NFWKVWVWBFBAOV-MISYRCLQSA-N 0.000 description 2
- 229940118781 dehydroabietic acid Drugs 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- XFTALRAZSCGSKN-UHFFFAOYSA-M sodium;4-ethenylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=C(C=C)C=C1 XFTALRAZSCGSKN-UHFFFAOYSA-M 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 241000208340 Araliaceae Species 0.000 description 1
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- KYKLWYKWCAYAJY-UHFFFAOYSA-N oxotin;zinc Chemical compound [Zn].[Sn]=O KYKLWYKWCAYAJY-UHFFFAOYSA-N 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention provides a kind of down toys using PVC complex plastic material, the PVC complex plastic material is made of raw material from the following weight: 100 parts of PVC, 6-9 parts of plasticizer, 15-18 parts of toughener, 8-12 parts of fire retardant, 12-15 parts of filler, 2-3 parts of stabilizer, 0.5-1 parts of lubricant, modified 5-6 parts of zinc-tin composite oxides.The present invention also provides the processing methods of the PVC complex plastic material.Down toy provided by the invention using PVC complex plastic material has stronger light fastness aging, infrared radiation property and heat resistance.
Description
Technical field
The present invention relates to a kind of down toy, more particularly to a kind of down toy using PVC complex plastic material and
Its processing method.
Background technique
The entitled polyvinyl chloride of Chinese of PVC is one of maximum plastic material product of yield in the world, cheap, is answered
With extensive.PVC is the white powder of amorphous structure, and the degree of branching is smaller, poor to the stability of light and heat.According to different purposes
Different additives can be added, different physical property and mechanical property is presented.Suitable plasticising is added in polyvinyl chloride resin
Agent can be made into a variety of hard, soft and transparent article.
PVC can be divided into hard PVC and soft pvc.Hard PVC has preferable tension, bending resistance, resistance to compression and impact resistance, can be independent
It is used as structural material.Flexibility, elongation at break, the cold resistance of soft pvc will increase, but brittleness, hardness, tensile strength can drop
It is low.PVC has preferable electrical insulation properties, can make low frequency insulating materials, and chemical stability might as well.Due to the thermostabilization of PVC
Property it is poor, long-time heating will lead to decomposition, release HCl gas, so that PVC is changed colour, so its application range is relatively narrow, uses temperature
Generally between -15-55 degree.Soft pvc cooperates various molds using injection (mo(u)lding) machine, can be made into plastic sandals, sole, slippers,
Down toy, automobile parts etc..
Chinese patent application CN201810466380.6 discloses a kind of " shock resistance PVC prepared using waste PET material
Material and preparation method thereof ", the shock resistance PVC material include the raw material of following parts by weight: 10-20 parts of waste PET micro mist,
45-70 parts of PVC master batch, 13-17 parts of sodium p styrene sulfonate, 11-14 parts of diethylene-triamine pentaacetic acid dianhydride, 3- phenyl -2-
5-8 parts of acrylic acid 2- phenyl chlorocarbonate, 6-12 parts of p-tert-butylphenol, 4-7 parts of dehydroabietic acid.The invention utilizes waste PET material
Material with PVC master batch, sodium p styrene sulfonate, diethylene-triamine pentaacetic acid dianhydride, cinnamic acid 2- phenyl chlorocarbonate,
P-tert-butylphenol and dehydroabietic acid compounding are prepared, and have tensile strength, impact strength, heat Aging Tensile strength, heat
Aging impact strength and the high advantage of compressive resistance, and wear-resistant, long service life；Preparation method is simple, is conducive to produce.So
And the PVC material still has the bad problem of light fastness aging, infrared radiation property and heat resistance, therefore it uses the longevity
Life is not grown.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of down toys using PVC complex plastic material, have
Stronger light fastness aging, infrared radiation property and heat resistance, service life are longer.
In order to solve the above technical problems, the technical scheme is that
A kind of down toy using PVC complex plastic material, the PVC complex plastic material by following parts by weight original
Material is made: 100 parts of PVC, 6-9 parts of plasticizer, and 15-18 parts of toughener, 8-12 parts of fire retardant, 12-15 parts of filler, stabilizer 2-3
Part, 0.5-1 parts of lubricant, modified 5-6 parts of zinc-tin composite oxides.
Further, plasticizer of the present invention is epoxidized soybean oil.
Further, toughener of the present invention is MBS.
Further, fire retardant of the present invention is triphenyl phosphate.
Further, filler of the present invention is glass fibre.
Further, stabilizer of the present invention is calcium-zinc composite stabilizing agent.
Further, lubricant of the present invention is butyl stearate.
Further, the preparation step of modified zinc-tin composite oxides of the present invention are as follows:
1) carbon ball is added in ethyl alcohol, obtains carbon ball solution within ultrasonic mixing 30 minutes, second is added in Tin tetrachloride pentahydrate
In alcohol, tin tetrachloride solution is obtained within ultrasonic mixing 30 minutes, by carbon ball solution and after tin tetrachloride solution ultrasonic mixing 90 minutes
Magnetic agitation 6 hours, mixture is obtained after standing 24 hours, is obtained drying at 80 DEG C after mixture ethanol washing to constant weight
Carbon tin mixture is put into Muffle furnace by carbon tin mixture, is kept the temperature 2.5 hours at 550 DEG C and is obtained sphere tin oxide；
2) sphere tin oxide is added in deionized water, obtains tin oxide solution within ultrasonic mixing 30 minutes, by zinc acetate plus
Enter ultrasonic mixing 30 minutes in deionized water and obtain acetic acid zinc solution, tin oxide solution and acetic acid zinc solution ultrasonic mixing 90 are divided
It clock magnetic agitation 3 hours, is added after cetyl trimethylammonium bromide and continues stirring and obtain mixed liquor in 11 hours, mixed liquor is moved
In Teflon liner into stainless steel autoclave, mixed liquor is taken out after 130 lower heat preservations 15 hours, with deionized water and
It is dried at 80 DEG C to constant weight after ethanol washing 3 times and obtains mixed powder, mixed powder is put into Muffle furnace, it is small that 2.5 are kept the temperature at 650 DEG C
When obtain zinc-tin composite oxides；
3) zinc-tin composite oxides are added in isopropanol, obtain zinc-tin composite oxides solution within ultrasonic mixing 30 minutes,
Zirconium ester coupling agent is added in isopropanol, zirconium ester coupling agent solution is obtained within ultrasonic mixing 30 minutes, by zinc-tin combined oxidation
Object solution opens stirring after being heated to 50 DEG C, and zirconium ester coupling agent solution is added dropwise while stirring, and drop is heated to 80 DEG C after finishing, and continues
Stirring obtains reaction solution in 3 hours, and filter cake is obtained by filtration in reaction solution, dries at 80 DEG C to perseverance after filter cake is washed with deionized
Restore modified zinc-tin composite oxides.
Further, in step 1) of the present invention, the mass ratio of carbon ball and Tin tetrachloride pentahydrate is 1:12；The step
It is rapid 2) in, sphere tin oxide, zinc acetate, cetyl trimethylammonium bromide mass ratio be 6:3:1；In the step 3), zinc
The mass ratio of the material of tin composite oxides and zirconium ester coupling agent is 9:1.
Another technical problem to be solved by the present invention is that providing adding for the above-mentioned down toy using PVC complex plastic material
Work method.
In order to solve the above technical problems, technical solution is:
A kind of processing method of the down toy using PVC complex plastic material, comprising the following steps:
Each raw material is added in blender according to parts by weight, stirring discharges after reaching 125 DEG C to material temperature, is cooled to room temperature
To mixture, extruding pelletization in conical double-screw extruding granulator is added mixture into, fervent pellet obtains after being cooled to room temperature
Using the down toy of PVC complex plastic material, PVC complex plastic material is then processed into down toy；Conical double-screw
The screw compression ratio of extruding granulator is 4.98, and the temperature of extruding pelletization is 160-190 DEG C.
Compared with prior art, the invention has the following advantages:
(1) present invention obtains hollow sphere tin oxide using carbon ball as templated synthesis, then leads to sphere tin oxide
It crosses hydro-thermal method and reacts obtained zinc-tin composite oxides with zinc acetate, the structure of the zinc-tin composite oxides is that zinc oxide is core, oxygen
Change the core-shell structure that tin is shell, zinc oxide itself has stronger ultraviolet screening ability, and infra-red radiation ability is weaker, tin oxide
Then in contrast, infra-red radiation ability is stronger, and ultraviolet screening ability is weaker, and the zinc-tin combined oxidation with core-shell structure
Object can effectively promote the infra-red radiation ability of zinc oxide and the ultraviolet screening ability of tin oxide, therefore zinc-tin composite oxides
Ultraviolet screening ability and infra-red radiation ability it is all good, light aging resisting property and red can be effectively improved by making an addition in PVC material
External radiation performance, and then extend the service life of the down toy using PVC complex plastic material.
(2) zinc-tin composite oxides have hydrophily, and PVC has lipophilicity, therefore zinc-tin composite oxides directly add
Compatibility and bond strength both when being added on PVC is bad, and zinc-tin composite oxides are not easy to be uniformly dispersed, and it is multiple to reduce zinc-tin
Oxide is closed to PVC ageing-resistant performance, the improvement effect of infrared radiation property, thus the present invention utilizes zirconium ester coupling agent to it
It carrying out surface coating modification and modified zinc-tin composite oxides is made, modified zinc-tin composite oxides are can be uniformly dispersed in PVC, and
Bond strength between PVC is also relatively strong, can be further improved the light fastness aging of PVC complex plastic material and down toy
And infrared radiation property, in addition, it is compound to effectively improve PVC using modification of the zirconium ester coupling agent to zinc-tin composite oxides
Such effect is not achieved in the heat resistance of plastic material and down toy, other coupling agents.
Specific embodiment
Below in conjunction with specific embodiment, the present invention will be described in detail, herein illustrative embodiments and their description of the invention
For explaining the present invention, but it is not as a limitation of the invention.
Embodiment 1
Using the down toy of PVC complex plastic material, PVC complex plastic material is made of raw material from the following weight:
100 parts of PVC, 6 parts of epoxidized soybean oil, 18 parts of MBS, 10 parts of triphenyl phosphate, 14 parts of glass fibre, calcium-zinc composite stabilizing agent 2
Part, 1 part of butyl stearate, modified 5.5 parts of zinc-tin composite oxides.
The preparation step of modified zinc-tin composite oxides are as follows:
1) carbon ball is added in ethyl alcohol, obtains carbon ball solution within ultrasonic mixing 30 minutes, second is added in Tin tetrachloride pentahydrate
In alcohol, tin tetrachloride solution is obtained within ultrasonic mixing 30 minutes, the mass ratio of carbon ball and Tin tetrachloride pentahydrate is 1:12, by carbon ball
Solution and tin tetrachloride solution ultrasonic mixing obtain mixture after standing 24 hours, will mix magnetic agitation 6 hours after 90 minutes
It is dried at 80 DEG C to constant weight after object ethanol washing and obtains carbon tin mixture, carbon tin mixture is put into Muffle furnace, at 550 DEG C
Heat preservation obtains sphere tin oxide in 2.5 hours；
2) sphere tin oxide is added in deionized water, obtains tin oxide solution within ultrasonic mixing 30 minutes, by zinc acetate plus
Enter ultrasonic mixing 30 minutes in deionized water and obtain acetic acid zinc solution, tin oxide solution and acetic acid zinc solution ultrasonic mixing 90 are divided
It clock magnetic agitation 3 hours, is added after cetyl trimethylammonium bromide and continues stirring and obtain within 11 hours mixed liquor, sphere oxidation
Tin, zinc acetate, cetyl trimethylammonium bromide mass ratio be 6:3:1, mixed liquor is moved in stainless steel autoclave
Teflon liner in, mixed liquor is taken out after 130 lower heat preservations 15 hours, at 80 DEG C after deionized water and ethanol washing 3 times
It is dry to obtain mixed powder to constant weight, mixed powder is put into Muffle furnace, 2.5 hours is kept the temperature at 650 DEG C and obtains zinc-tin combined oxidation
Object；
3) zinc-tin composite oxides are added in isopropanol, obtain zinc-tin composite oxides solution within ultrasonic mixing 30 minutes,
Zirconium ester coupling agent is added in isopropanol, obtains zirconium ester coupling agent solution, zinc-tin composite oxides within ultrasonic mixing 30 minutes
The mass ratio of the material with zirconium ester coupling agent is 9:1, stirring is opened after zinc-tin composite oxides solution is heated to 50 DEG C, while stirring
It mixes side and zirconium ester coupling agent solution is added dropwise, drop is heated to 80 DEG C after finishing, and continues stirring and obtains reaction solution in 3 hours, by reaction solution mistake
Filter obtains filter cake, dries at 80 DEG C to constant weight after filter cake is washed with deionized and obtains modified zinc-tin composite oxides.
This using PVC complex plastic material down toy processing method the following steps are included:
Each raw material is added in blender according to parts by weight, stirring discharges after reaching 125 DEG C to material temperature, is cooled to room temperature
To mixture, extruding pelletization in conical double-screw extruding granulator is added mixture into, fervent pellet obtains after being cooled to room temperature
Using the down toy of PVC complex plastic material, PVC complex plastic material is then processed into down toy；Conical double-screw
The screw compression ratio of extruding granulator is 4.98, and the temperature of extruding pelletization is 160-190 DEG C.
Embodiment 2
Using the down toy of PVC complex plastic material, PVC complex plastic material is made of raw material from the following weight:
100 parts of PVC, 7 parts of epoxidized soybean oil, 17 parts of MBS, 8 parts of triphenyl phosphate, 15 parts of glass fibre, calcium-zinc composite stabilizing agent 2.5
Part, 0.8 part of butyl stearate, modified 6 parts of zinc-tin composite oxides.
The processing method of the present embodiment and the preparation step of modified zinc-tin composite oxides are same as Example 1.
Embodiment 3
Using the down toy of PVC complex plastic material, PVC complex plastic material is made of raw material from the following weight:
100 parts of PVC, 8 parts of epoxidized soybean oil, 16 parts of MBS, 12 parts of triphenyl phosphate, 12 parts of glass fibre, calcium-zinc composite stabilizing agent 3
Part, 0.5 part of butyl stearate, modified 5 parts of zinc-tin composite oxides.
The processing method of the present embodiment and the preparation step of modified zinc-tin composite oxides are same as Example 1.
Embodiment 4
Using the down toy of PVC complex plastic material, PVC complex plastic material is made of raw material from the following weight:
100 parts of PVC, 9 parts of epoxidized soybean oil, 15 parts of MBS, 9 parts of triphenyl phosphate, 13 parts of glass fibre, calcium-zinc composite stabilizing agent 2.7
Part, 0.6 part of butyl stearate, modified 5.4 parts of zinc-tin composite oxides.
The processing method of the present embodiment and the preparation step of modified zinc-tin composite oxides are same as Example 1.
Comparative Examples 1
With embodiment 1 except that the modification zinc-tin composite oxides in raw material replace with modified oxidized tin, preparation
Step reduction step 1), 2) unlike modified zinc-tin composite oxides, directly carries out tin oxide with zirconium ester coupling agent
It is modified.Comparative Examples 2
With embodiment 1 except that the modification zinc-tin composite oxides in raw material replace with modified zinc oxide, preparation
Step reduction step 1), 2) unlike modified zinc-tin composite oxides, directly carries out zinc oxide with zirconium ester coupling agent
It is modified.Comparative Examples 3
With embodiment 1 except that the modification zinc-tin composite oxides in raw material replace with zinc-tin composite oxides,
Preparation step reduces step 3) unlike modified zinc-tin composite oxides.
Comparative Examples 4
With embodiment 1 except that the preparation step 3 of the modification zinc-tin composite oxides in raw material) in zirconate it is even
Connection agent replaces with silane coupling agent.
Comparative example: application No. is the embodiments 1 of the Chinese patent of CN201810466380.6.
Experimental example one: light aging resisting property test
Embodiment 1-4, Comparative Examples 1-4, comparative example are measured respectively respectively in fluorescence purple with reference to GB/T 16422-1997
Elongation at break conservation rate under outside line after exposure 400 hours, elongation at break/test after elongation at break conservation rate=test
Preceding elongation at break × 100%, the numerical value is higher to show that light aging resisting property is stronger.Test result is as shown in table 1:
Table 1
Table 1 shows that the elongation at break conservation rate of 1-4 of the embodiment of the present invention shows this hair obviously higher than comparative example
Bright to have stronger light aging resisting property, wherein the light aging resisting property of embodiment 1 is most strong.The part of Comparative Examples 1-4 is former
Material is different from embodiment 1, and the decline degree of the elongation at break conservation rate of Comparative Examples 1 is maximum, illustrates that modified zinc-tin is compound
Zinc oxide in oxide is the main cause for improving light aging resisting property, the decline of the elongation at break conservation rate of Comparative Examples 2
Degree is smaller than Comparative Examples 1, illustrates raising of the tin oxide in modified zinc-tin composite oxides to light aging resisting property
Also it can play a role；The decline degree of the elongation at break conservation rate of Comparative Examples 3 is larger than Comparative Examples 2,
Illustrate that zirconium ester coupling agent is fine to the modified effect of zinc-tin composite oxides, the decline of the elongation at break of Comparative Examples 4
Degree is larger than Comparative Examples 3, illustrates that silane coupling agent is even not as good as zirconate to the modified effect of zinc-tin composite oxides
Join agent.
Experimental example two: infrared radiation property test
It is remote red at 8-14 μm to measure embodiment 1-4, Comparative Examples 1-4, comparative example respectively using infrared radiometer
The normal direction total radiation emissivity of wave section, the numerical value is higher to show that infrared radiation property is stronger.Test result is as shown in table 2:
Table 2
Table 2 shows that the far infrared total radiation emissivity of 1-4 of the embodiment of the present invention shows this obviously higher than comparative example
Invention has stronger infrared radiation property, and wherein the infrared radiation property of embodiment 1 is most strong.The part of Comparative Examples 1-4
Raw material is different from embodiment 1, and the decline degree of the far infrared total radiation emissivity of Comparative Examples 2 is maximum, illustrates modified zinc-tin
Tin oxide in composite oxides is the main cause for improving infrared radiation property, the far infrared total radiation emissivity of Comparative Examples 1
Decline degree it is smaller than Comparative Examples 2, illustrate the zinc oxide in modified zinc-tin composite oxides to infrared radiation property
Raising can also play a role；The decline degree of the far infrared total radiation emissivity of Comparative Examples 3 is than Comparative Examples 1
It is larger, illustrate that zirconium ester coupling agent is fine to the modified effect of zinc-tin composite oxides, the full spoke of the far infrared of Comparative Examples 4
The decline degree for penetrating emissivity is larger than Comparative Examples 3, illustrates that silane coupling agent imitates the modified of zinc-tin composite oxides
Fruit is not so good as zirconium ester coupling agent.
Experimental example three: heat resistance test
The vitrifying for being measured embodiment 1-4, Comparative Examples 1-4, comparative example respectively using dynamic thermomechanical analysis apparatus is turned
Temperature, the numerical value is higher to show that thermal stability is stronger.Test result is as shown in table 3:
| Glass transition temperature (DEG C) | |
| Embodiment 1 | 105.7 |
| Embodiment 2 | 105.2 |
| Embodiment 3 | 105.5 |
| Embodiment 4 | 105.3 |
| Comparative Examples 1 | 105.6 |
| Comparative Examples 2 | 105.7 |
| Comparative Examples 3 | 90.4 |
| Comparative Examples 4 | 91.0 |
| Comparative example | 90.2 |
Table 3
Table 3 shows that the glass transition temperature of 1-4 of the embodiment of the present invention shows the present invention obviously higher than comparative example
With stronger heat resistance, wherein the heat resistance of embodiment 1 is most strong.The part material and embodiment 1 of Comparative Examples 1-4 is not
Together, the glass transition temperature of Comparative Examples 1,2 and embodiment 1 almost, illustrate the oxygen in modified zinc-tin composite oxides
Change tin and zinc oxide does not act on the raising of heat resistance；The decline degree of the glass transition temperature of Comparative Examples 3 is maximum,
Illustrate that zirconium ester coupling agent is the key that improve heat resistance, the decline degree of the glass transition temperature of Comparative Examples 4 is than ginseng
It is more slightly smaller than embodiment 3, illustrate that silane coupling agent is obviously not so good as zirconium ester coupling agent to the improvement effect of heat resistance.
The principle of the present invention and its performance is only illustrated in above-described embodiment, and is not intended to limit the present invention.It is any ripe
The personage for knowing this technology all without departing from the spirit and scope of the present invention, carries out modifications and changes to above-described embodiment.Cause
This, institute is complete without departing from the spirit and technical ideas disclosed in the present invention by those of ordinary skill in the art such as
At all equivalent modifications or change, should be covered by the claims of the present invention.
Claims (10)
1. a kind of down toy using PVC complex plastic material, it is characterised in that: the PVC complex plastic material is by following
The raw material of parts by weight is made: 100 parts of PVC, 6-9 parts of plasticizer, and 15-18 parts of toughener, 8-12 parts of fire retardant, filler 12-15
Part, 2-3 parts of stabilizer, 0.5-1 parts of lubricant, modified 5-6 parts of zinc-tin composite oxides.
2. a kind of down toy using PVC complex plastic material according to claim 1, it is characterised in that: the increasing
Modeling agent is epoxidized soybean oil.
3. a kind of down toy using PVC complex plastic material according to claim 1, it is characterised in that: the increasing
Tough dose is MBS.
4. a kind of down toy using PVC complex plastic material according to claim 1, it is characterised in that: the resistance
Combustion agent is triphenyl phosphate.
5. a kind of down toy using PVC complex plastic material according to claim 1, it is characterised in that: described to fill out
Material is glass fibre.
6. a kind of down toy using PVC complex plastic material according to claim 1, it is characterised in that: described steady
Determining agent is calcium-zinc composite stabilizing agent.
7. a kind of down toy using PVC complex plastic material according to claim 1, it is characterised in that: the profit
Lubrication prescription is butyl stearate.
8. a kind of down toy using PVC complex plastic material according to claim 1, it is characterised in that: described to change
The preparation step of property zinc-tin composite oxides are as follows:
1) carbon ball is added in ethyl alcohol, obtains carbon ball solution within ultrasonic mixing 30 minutes, Tin tetrachloride pentahydrate is added in ethyl alcohol,
Obtain tin tetrachloride solution within ultrasonic mixing 30 minutes, magnetic force stirs by carbon ball solution and after tin tetrachloride solution ultrasonic mixing 90 minutes
It mixes 6 hours, obtains mixture after standing 24 hours, drying at 80 DEG C after mixture ethanol washing is obtained into carbon tin to constant weight and is mixed
Object is closed, carbon tin mixture is put into Muffle furnace, 2.5 hours is kept the temperature at 550 DEG C and obtains sphere tin oxide；
2) sphere tin oxide is added in deionized water, obtains tin oxide solution within ultrasonic mixing 30 minutes, zinc acetate addition is gone
Acetic acid zinc solution is obtained within ultrasonic mixing 30 minutes in ionized water, by 90 minutes magnetic of tin oxide solution and acetic acid zinc solution ultrasonic mixing
Power stirs 3 hours, continues stirring after addition cetyl trimethylammonium bromide and obtains mixed liquor in 11 hours, mixed liquor is moved to not
In Teflon liner in rust steel autoclave, mixed liquor is taken out after 130 lower heat preservations 15 hours, with deionized water and ethyl alcohol
It is dried at 80 DEG C to constant weight after washing 3 times and obtains mixed powder, mixed powder is put into Muffle furnace, keep the temperature 2.5 hours at 650 DEG C
To zinc-tin composite oxides；
3) zinc-tin composite oxides are added in isopropanol, zinc-tin composite oxides solution are obtained within ultrasonic mixing 30 minutes, by zirconium
Acid esters coupling agent is added in isopropanol, obtains zirconium ester coupling agent solution within ultrasonic mixing 30 minutes, and zinc-tin composite oxides are molten
Liquid opens stirring after being heated to 50 DEG C, and zirconium ester coupling agent solution is added dropwise while stirring, and drop is heated to 80 DEG C after finishing, continues to stir
It obtains reaction solution within 3 hours, filter cake is obtained by filtration in reaction solution, dry at 80 DEG C to constant weight and obtain after filter cake is washed with deionized
To modified zinc-tin composite oxides.
9. a kind of down toy using PVC complex plastic material according to claim 8, it is characterised in that: the step
It is rapid 1) in, the mass ratio of carbon ball and Tin tetrachloride pentahydrate is 1:12；In the step 2), sphere tin oxide, zinc acetate, 16
The mass ratio of alkyl trimethyl ammonium bromide is 6:3:1；In the step 3), the object of zinc-tin composite oxides and zirconium ester coupling agent
The amount ratio of matter is 9:1.
10. a kind of processing of the down toy using PVC complex plastic material described in any one according to claim 1~9
Method, it is characterised in that: the following steps are included:
Each raw material is added in blender according to parts by weight, stirring discharges after reaching 125 DEG C to material temperature, is cooled to room temperature and is mixed
Material is closed, extruding pelletization in conical double-screw extruding granulator is added mixture into, fervent pellet obtains described after being cooled to room temperature
Then PVC complex plastic material is processed into down toy by PVC complex plastic material；The spiral shell of conical double-screw extruding granulator
Bar compression ratio is 4.98, and the temperature of extruding pelletization is 160-190 DEG C.
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| CN105129805A (en) * | 2015-07-10 | 2015-12-09 | 上海纳旭实业有限公司 | Preparation method of silicon oxide/tin antimony oxide/zinc oxide ternary composite material |
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2019
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| CN105129805A (en) * | 2015-07-10 | 2015-12-09 | 上海纳旭实业有限公司 | Preparation method of silicon oxide/tin antimony oxide/zinc oxide ternary composite material |
| CN106751173A (en) * | 2016-12-07 | 2017-05-31 | 佛山市飞时达新材料科技有限公司 | The pvc material and manufacture method of a kind of Wear-resistant, high-temperature resistant |
| CN108717072A (en) * | 2018-05-15 | 2018-10-30 | 大连理工大学 | A kind of light activated formaldehyde gas sensor and its preparation process |
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