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CN110438797A - A kind of radiation-proof polyester covering yarn and preparation method thereof - Google Patents

A kind of radiation-proof polyester covering yarn and preparation method thereof Download PDF

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Publication number
CN110438797A
CN110438797A CN201910618861.9A CN201910618861A CN110438797A CN 110438797 A CN110438797 A CN 110438797A CN 201910618861 A CN201910618861 A CN 201910618861A CN 110438797 A CN110438797 A CN 110438797A
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China
Prior art keywords
radiation
covering yarn
modified
silk
yarn
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Pending
Application number
CN201910618861.9A
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Chinese (zh)
Inventor
吴晓虹
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Zhuzhou Tianlun Textile Co Ltd
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Zhuzhou Tianlun Textile Co Ltd
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Priority to CN201910618861.9A priority Critical patent/CN110438797A/en
Publication of CN110438797A publication Critical patent/CN110438797A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/36Cored or coated yarns or threads
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • D02G3/441Yarns or threads with antistatic, conductive or radiation-shielding properties
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B1/00Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
    • D06B1/02Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by spraying or projecting
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B15/00Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/52Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with selenium, tellurium, polonium or their compounds; with sulfur, dithionites or compounds containing sulfur and halogens, with or without oxygen; by sulfohalogenation with chlorosulfonic acid; by sulfohalogenation with a mixture of sulfur dioxide and free halogens
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/10Animal fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/10Animal fibres
    • D06M2101/12Keratin fibres or silk
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00Protein-based fibres, e.g. animal fibres
    • D10B2211/01Natural animal fibres, e.g. keratin fibres
    • D10B2211/02Wool
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00Protein-based fibres, e.g. animal fibres
    • D10B2211/01Natural animal fibres, e.g. keratin fibres
    • D10B2211/04Silk
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/02Moisture-responsive characteristics
    • D10B2401/022Moisture-responsive characteristics hydrophylic
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/06Load-responsive characteristics
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/06Load-responsive characteristics
    • D10B2401/061Load-responsive characteristics elastic
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/06Load-responsive characteristics
    • D10B2401/062Load-responsive characteristics stiff, shape retention
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/14Dyeability

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Artificial Filaments (AREA)

Abstract

The present invention relates to textile technology fields, and in particular to a kind of radiation-proof polyester covering yarn and preparation method thereof;The composition of the radiation-proof polyester covering yarn are as follows: modified polyester fibre silk is outer layer as sandwich layer, modified natural silk cotton and modified woolen fiber silk, obtains the blended covering yarn of ternary by blended and post-processing modification.Radiation protection spray is coated in terylene covered yarn by the way of high pressure painting by radiation-proof polyester covering yarn prepared by the present invention, and rush makes it have very high radiation resistance, while it also has that elasticity is good, softness, and mechanical property is also very excellent;Not fugitive color while the cloth easy dyeing prepared with it, in addition its permeability and moisture pick-up properties characteristics such as preferably.

Description

A kind of radiation-proof polyester covering yarn and preparation method thereof
Technical field
The invention belongs to textile technology fields, and in particular to a kind of radiation-proof polyester covering yarn and preparation method thereof.
Background technique
With the development of science and technology, electromagnetic radiation pollution has become the important pollution sources for endangering ecological environment.And it is electric The extensive use of magnetic technology, bring it is benefited when while, also bring serious prestige to our health The side of body.In our daily life, the use of the electronic apparatus such as computer, micro-wave oven, refrigerator, television set, mobile phone can all be generated Electromagnetic radiation, and our present people be unable to do without the use of these electronic apparatus leads to the contact electromagnetism spoke that people can be long-term It penetrates, and since electromagnetic radiation pollution is invisible, can not touch, there is latency and concealment, so that electromagnetic radiation pollution is often not While being easily noticeable, also it is not easy to guard against.Therefore, the clothes of radiation protection or other shieldings just become our bodies The guarantee of health, the thing or quality of present protection class are too heavy, and wearing is inconvenient, and unsightly poor with comfort, Protection effect is poor, can not play real protection effect, therefore the present invention is directed to these problems, has invented a kind of anti- Terylene covered yarn is radiated, can be widely applied to the fields such as weaving and clothes, while also can be good at solving now similar Product there are the problem of.
Summary of the invention
In order to achieve the purpose that in background technique, a kind of radiation-proof polyester covering yarn proposed by the present invention and its preparation side Method;
What the present invention realized by the following technical solutions:
A kind of radiation-proof polyester covering yarn, which is characterized in that the composition of the radiation-proof polyester covering yarn are as follows: modified dacron Fiber filament is outer layer as sandwich layer, modified natural silk cotton and modified woolen fiber silk, is obtained by blended and post-processing modification The blended covering yarn of ternary;
The radiation-proof polyester covering yarn the preparation method comprises the following steps: by fine for the modified dacron of 70-80% with mass percent The wool fiber silk that silk is tieed up as sandwich layer, the natural silk wadding of 10-15% and 5-10% is outer layer, using Technology of Air Vortex Spinning to it Carry out it is blended covering yarn is prepared, then under vacuum conditions by the covering yarn being prepared, use high pressure vacuum spray gun The radiation protection spray of high concentration is uniformly sprayed above covering yarn, its thick bottom is controlled, is then placed in clear water It after being washed, is dried, the silk obtained after dry is exactly radiation-proof polyester covering yarn.
Further, the modified polyester fibre silk are as follows: be modified using the modified method of heat fusing, be by mass fraction The glass fibre of 100-120 parts PET, 10-15 part, 6-10 parts of conch meal, the powdered graphite of 5-10,2-4 parts of stearic acid, 1-2 parts of G60, which is added in batch mixer, after mixing, material is added in twin-screw granulating extruder and carries out granulation extrusion Modification obtains modified materials grain, and obtained modified particle is then carried out heat fusing extrusion and is reeled off raw silk from cocoons, modified polyester fibre silk is obtained.
Further, the radiation protection spray are as follows: the naumannite of collection is added in ball mill, adds suitable water Afterwards, it is ground, when grinding its granular size of matter is 400-800 nanometers, stops grinding, be filtered drying, obtain solid powder End weighs the powder that mass fraction is 100-120 parts and is added in reaction kettle, and the concentration for then adding 30-40 parts is 20% Poly-vinyl alcohol solution and the suitable water concentration of solid powder (control in 50-60%), must after then carrying out reaction 2-3 hour The substance arrived, the substance are exactly radiation protection spray.
Further, described that the radiation protection spray of high concentration is uniformly sprayed into cored using high pressure vacuum spray gun Above yarn, thickness are as follows: 0.1-0.15mm.
Further, the drying condition of the radiation-proof polyester covering yarn are as follows: the terylene covered yarn of preparation is used into temperature It is dried for 60-70 DEG C of hot-air.
Beneficial to benefit
Radiation protection spray is coated in by radiation-proof polyester covering yarn prepared by the present invention by the way of high pressure painting to be washed Synthetic fibre covering yarn, rush makes it have very high radiation resistance, while it also has that elasticity is good, softness, mechanical property It is very excellent;Not fugitive color while the cloth easy dyeing prepared with it, in addition its permeability and moisture pick-up properties are preferable Etc. characteristics.
Specific embodiment
In order to keep the purpose of the present invention, technical scheme and beneficial effects clearer, below in conjunction with experimental data, to this The preferred embodiment of invention is described in detail, to facilitate the technical staff to understand.
Embodiment 1
A kind of radiation-proof polyester covering yarn the preparation method comprises the following steps:
It will be using the modified polyester fibre silk that mass percent is 80% as sandwich layer, 12% natural silk wadding and 8% Wool fiber silk is outer layer, and the blended packet that covering yarn is prepared, then will be prepared is carried out to it using Technology of Air Vortex Spinning Heart yarn under vacuum conditions, using high pressure vacuum spray gun uniformly sprays the radiation protection spray of high concentration on covering yarn Face controls its thick bottom, is then placed on after being washed in clear water, is dried, the silk obtained after dry is exactly anti-spoke Penetrate terylene covered yarn.
Further, the modified polyester fibre silk are as follows: be modified using the modified method of heat fusing, be by mass fraction 110 parts of PET, 10 parts of glass fibre, 8 parts of conch meal, 10 powdered graphite, 3 parts of stearic acid, 2 parts of G60 are added mixed It is carried out in material machine after mixing, obtains modified materials for be granulated squeezing out to be modified in material addition twin-screw granulating extruder Then obtained modified particle is carried out heat fusing extrusion and reeled off raw silk from cocoons, obtains modified polyester fibre silk by grain.
Further, the radiation protection spray are as follows: the naumannite of collection is added in ball mill, adds suitable water Afterwards, it is ground, when grinding its granular size of matter is 400-800 nanometers, stops grinding, be filtered drying, obtain solid powder End weighs the powder that mass fraction is 120 parts and is added in reaction kettle, the polyethylene that the concentration for then adding 38 parts is 20% Alcoholic solution and suitable water (concentration of solid powder is controlled in 50-60%), the object obtained after then carrying out reaction 2-3 hours Matter, the substance are exactly radiation protection spray.
Further, described that the radiation protection spray of high concentration is uniformly sprayed into cored using high pressure vacuum spray gun Above yarn, thickness are as follows: 0.1-0.15mm.
Further, the drying condition of the radiation-proof polyester covering yarn are as follows: the terylene covered yarn of preparation is used into temperature It is dried for 60-70 DEG C of hot-air.
Embodiment 2
A kind of radiation-proof polyester covering yarn the preparation method comprises the following steps:
It will be using the modified polyester fibre silk that mass percent is 78% as sandwich layer, 12% natural silk wadding and 10% Wool fiber silk is outer layer, and the blended packet that covering yarn is prepared, then will be prepared is carried out to it using Technology of Air Vortex Spinning Heart yarn under vacuum conditions, using high pressure vacuum spray gun uniformly sprays the radiation protection spray of high concentration on covering yarn Face controls its thick bottom, is then placed on after being washed in clear water, is dried, the silk obtained after dry is exactly anti-spoke Penetrate terylene covered yarn.
Further, the modified polyester fibre silk are as follows: be modified using the modified method of heat fusing, be by mass fraction 120 parts of PET, 12 parts of glass fibre, 10 parts of conch meal, 8 powdered graphite, 4 parts of stearic acid, 1 part of G60 are added mixed It is carried out in material machine after mixing, obtains modified materials for be granulated squeezing out to be modified in material addition twin-screw granulating extruder Then obtained modified particle is carried out heat fusing extrusion and reeled off raw silk from cocoons, obtains modified polyester fibre silk by grain.
Further, the radiation protection spray are as follows: the naumannite of collection is added in ball mill, adds suitable water Afterwards, it is ground, when grinding its granular size of matter is 400-800 nanometers, stops grinding, be filtered drying, obtain solid powder End weighs the powder that mass fraction is 110 parts and is added in reaction kettle, the polyethylene that the concentration for then adding 35 parts is 20% Alcoholic solution and suitable water (concentration of solid powder is controlled in 50-60%), the object obtained after then carrying out reaction 2-3 hours Matter, the substance are exactly radiation protection spray.
Further, described that the radiation protection spray of high concentration is uniformly sprayed into cored using high pressure vacuum spray gun Above yarn, thickness are as follows: 0.1-0.15mm.
Further, the drying condition of the radiation-proof polyester covering yarn are as follows: the terylene covered yarn of preparation is used into temperature It is dried for 60-70 DEG C of hot-air.
Embodiment 3
It will be using the modified polyester fibre silk that mass percent is 80% as sandwich layer, 15% natural silk wadding and 5% Wool fiber silk is outer layer, and the blended packet that covering yarn is prepared, then will be prepared is carried out to it using Technology of Air Vortex Spinning Heart yarn under vacuum conditions, using high pressure vacuum spray gun uniformly sprays the radiation protection spray of high concentration on covering yarn Face controls its thick bottom, is then placed on after being washed in clear water, is dried, the silk obtained after dry is exactly anti-spoke Penetrate terylene covered yarn.
Further, the modified polyester fibre silk are as follows: be modified using the modified method of heat fusing, be by mass fraction 120 parts of PET, 15 parts of glass fibre, 10 parts of conch meal, 10 powdered graphite, 4 parts of stearic acid, 2 parts of G60 are added It is carried out in batch mixer after mixing, obtains modified materials for be granulated squeezing out to be modified in material addition twin-screw granulating extruder Then obtained modified particle is carried out heat fusing extrusion and reeled off raw silk from cocoons, obtains modified polyester fibre silk by grain.
Further, the radiation protection spray are as follows: the naumannite of collection is added in ball mill, adds suitable water Afterwards, it is ground, when grinding its granular size of matter is 400-800 nanometers, stops grinding, be filtered drying, obtain solid powder End weighs the powder that mass fraction is 120 parts and is added in reaction kettle, the polyethylene that the concentration for then adding 40 parts is 20% Alcoholic solution and suitable water (concentration of solid powder is controlled in 50-60%), the object obtained after then carrying out reaction 2-3 hours Matter, the substance are exactly radiation protection spray.
Further, described that the radiation protection spray of high concentration is uniformly sprayed into cored using high pressure vacuum spray gun Above yarn, thickness are as follows: 0.1-0.15mm.
Further, the drying condition of the radiation-proof polyester covering yarn are as follows: the terylene covered yarn of preparation is used into temperature It is dried for 60-70 DEG C of hot-air.
Embodiment 4
It will be using the modified polyester fibre silk that mass percent is 75% as sandwich layer, 15% natural silk wadding and 10% Wool fiber silk is outer layer, and the blended packet that covering yarn is prepared, then will be prepared is carried out to it using Technology of Air Vortex Spinning Heart yarn under vacuum conditions, using high pressure vacuum spray gun uniformly sprays the radiation protection spray of high concentration on covering yarn Face controls its thick bottom, is then placed on after being washed in clear water, is dried, the silk obtained after dry is exactly anti-spoke Penetrate terylene covered yarn.
Further, the modified polyester fibre silk are as follows: be modified using the modified method of heat fusing, be by mass fraction 100 parts of PET, 10 parts of glass fibre, 6 parts of conch meal, 5 powdered graphite, 2 parts of stearic acid, 1 part of G60 are added mixed It is carried out in material machine after mixing, obtains modified materials for be granulated squeezing out to be modified in material addition twin-screw granulating extruder Then obtained modified particle is carried out heat fusing extrusion and reeled off raw silk from cocoons, obtains modified polyester fibre silk by grain.
Further, the radiation protection spray are as follows: the naumannite of collection is added in ball mill, adds suitable water Afterwards, it is ground, when grinding its granular size of matter is 400-800 nanometers, stops grinding, be filtered drying, obtain solid powder End weighs the powder that mass fraction is 100 parts and is added in reaction kettle, the polyethylene that the concentration for then adding 30 parts is 20% Alcoholic solution and suitable water (concentration of solid powder is controlled in 50-60%), the object obtained after then carrying out reaction 2-3 hours Matter, the substance are exactly radiation protection spray.
Further, described that the radiation protection spray of high concentration is uniformly sprayed into cored using high pressure vacuum spray gun Above yarn, thickness are as follows: 0.1-0.15mm.
Further, the drying condition of the radiation-proof polyester covering yarn are as follows: the terylene covered yarn of preparation is used into temperature It is dried for 60-70 DEG C of hot-air.
Experimental analysis:
1, properties of product are tested
The similar product that the radiation-proof polyester covering yarn of the preparation of embodiment 1-4 and market are sold carries out properties survey Examination, test result is as follows shown in table:
It is found that radiation-proof polyester covering yarn prepared by the present invention is compared with similar product, receipts are broken above-mentioned test result Elongation is relatively high, illustrate its with good resilience performance, meanwhile, wear-resisting property is preferable, and material is effectively guaranteed Wear-resisting property, while its anti-uv-ray improves 40% or more than the similar product that market is sold, and effectively reaches anti- Radiation effect.
Finally, it is stated that preferred embodiment above is only used to illustrate the technical scheme of the present invention rather than limits, although logical It crosses above preferred embodiment the present invention is described in detail, however, those skilled in the art should understand that, can be Various changes are made to it in form and in details, without departing from defined by claims of the present invention.

Claims (5)

1. a kind of radiation-proof polyester covering yarn, which is characterized in that the composition of the radiation-proof polyester covering yarn are as follows: modified dacron is fine It is outer layer that silk, which is tieed up, as sandwich layer, modified natural silk cotton and modified woolen fiber silk, obtains three by blended and post-processing modification The blended covering yarn of member;
The radiation-proof polyester covering yarn the preparation method comprises the following steps: by the modified polyester fibre silk with mass percent for 70-80% Wool fiber silk as sandwich layer, the natural silk wadding of 10-15% and 5-10% is outer layer, is carried out using Technology of Air Vortex Spinning to it It is blended that covering yarn is prepared, it then under vacuum conditions by the covering yarn being prepared, will be high using high pressure vacuum spray gun The radiation protection spray of concentration uniformly sprays above covering yarn, controls its thick bottom, is then placed on carrying out in clear water It after washing, is dried, the silk obtained after dry is exactly radiation-proof polyester covering yarn.
2. a kind of radiation-proof polyester covering yarn according to claim 1 and preparation method thereof, which is characterized in that the modification Polyester fiber yarn are as follows: be modified using the modified method of heat fusing, by the glass of PET, 10-15 part that mass fraction is 100-120 parts Glass fiber, 6-10 parts of conch meal, the powdered graphite of 5-10,2-4 parts of stearic acid, 1-2 parts of G60 are added in batch mixer and carry out After mixing, will material be added twin-screw granulating extruder in carry out be granulated squeeze out modification obtain modified materials grain, then will To modified particle carry out heat fusing extrusion reel off raw silk from cocoons, obtain modified polyester fibre silk.
3. a kind of radiation-proof polyester covering yarn according to claim 1 and preparation method thereof, which is characterized in that the anti-spoke Penetrate spray are as follows: the naumannite of collection is added in ball mill, after adding suitable water, is ground, its particle of matter is ground When size is 400-800 nanometers, stops grinding, be filtered drying, obtain solid powder, weighing mass fraction is 100-120 The powder of part is added in reaction kettle, the poly-vinyl alcohol solution and suitable water that the concentration for then adding 30-40 parts is 20% (concentration of solid powder is controlled in 50-60%), the substance obtained after then carrying out reaction 2-3 hours, which is exactly anti-spoke Penetrate spray.
4. a kind of radiation-proof polyester covering yarn according to claim 1 and preparation method thereof, which is characterized in that the use High pressure vacuum spray gun uniformly sprays the radiation protection spray of high concentration above covering yarn, thickness are as follows: 0.1- 0.15mm。
5. a kind of radiation-proof polyester covering yarn according to claim 1 and preparation method thereof, which is characterized in that the anti-spoke Penetrate the drying condition of terylene covered yarn are as follows: use temperature to be dried for 60-70 DEG C of hot-air on the terylene covered yarn of preparation.
CN201910618861.9A 2019-07-10 2019-07-10 A kind of radiation-proof polyester covering yarn and preparation method thereof Pending CN110438797A (en)

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CN111893612A (en) * 2020-07-02 2020-11-06 苏州维杰纺织有限公司 High-elastic antistatic covering yarn
CN112501782A (en) * 2020-11-27 2021-03-16 叶鲜花 Anti-radiation composite heat-insulation fabric and preparation method thereof
CN112708979A (en) * 2020-12-21 2021-04-27 杭州奥华纺织有限公司 Electromagnetic shielding core-spun yarn and preparation process thereof
CN115305612A (en) * 2022-09-14 2022-11-08 罗莱生活科技股份有限公司 Polyester fiber core-spun yarn and preparation method thereof
EP4328364A4 (en) * 2022-07-11 2024-11-13 The Japan Wool Textile Co., Ltd. Multilayer structured spun yarn, production method for same, and fabric and clothing from same

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111893612A (en) * 2020-07-02 2020-11-06 苏州维杰纺织有限公司 High-elastic antistatic covering yarn
CN112501782A (en) * 2020-11-27 2021-03-16 叶鲜花 Anti-radiation composite heat-insulation fabric and preparation method thereof
CN112708979A (en) * 2020-12-21 2021-04-27 杭州奥华纺织有限公司 Electromagnetic shielding core-spun yarn and preparation process thereof
EP4328364A4 (en) * 2022-07-11 2024-11-13 The Japan Wool Textile Co., Ltd. Multilayer structured spun yarn, production method for same, and fabric and clothing from same
CN115305612A (en) * 2022-09-14 2022-11-08 罗莱生活科技股份有限公司 Polyester fiber core-spun yarn and preparation method thereof

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