CN110438576A - A kind of spinneret, the pipe tobacco prepared using the spinneret and preparation method thereof - Google Patents
A kind of spinneret, the pipe tobacco prepared using the spinneret and preparation method thereof Download PDFInfo
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- CN110438576A CN110438576A CN201910820357.7A CN201910820357A CN110438576A CN 110438576 A CN110438576 A CN 110438576A CN 201910820357 A CN201910820357 A CN 201910820357A CN 110438576 A CN110438576 A CN 110438576A
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- 241000208125 Nicotiana Species 0.000 title claims abstract description 31
- 235000002637 Nicotiana tabacum Nutrition 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 6
- 238000010099 solid forming Methods 0.000 claims abstract description 4
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 26
- 239000004626 polylactic acid Substances 0.000 claims description 26
- 238000009987 spinning Methods 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 238000001816 cooling Methods 0.000 claims description 13
- 238000002074 melt spinning Methods 0.000 claims description 13
- 238000012856 packing Methods 0.000 claims description 13
- 238000002788 crimping Methods 0.000 claims description 12
- 238000002425 crystallisation Methods 0.000 claims description 12
- 230000008025 crystallization Effects 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 9
- 230000005540 biological transmission Effects 0.000 claims description 6
- 238000009998 heat setting Methods 0.000 claims description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 239000011148 porous material Substances 0.000 claims description 3
- 230000008093 supporting effect Effects 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- 238000013461 design Methods 0.000 claims description 2
- 230000005674 electromagnetic induction Effects 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 230000005571 horizontal transmission Effects 0.000 claims description 2
- 230000007246 mechanism Effects 0.000 claims description 2
- 239000003345 natural gas Substances 0.000 claims description 2
- 238000007747 plating Methods 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 239000010935 stainless steel Substances 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- 239000000853 adhesive Substances 0.000 claims 2
- 230000001070 adhesive effect Effects 0.000 claims 2
- 230000000694 effects Effects 0.000 abstract description 8
- 239000000835 fiber Substances 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 8
- 229920002301 cellulose acetate Polymers 0.000 description 7
- 235000019504 cigarettes Nutrition 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- 230000006835 compression Effects 0.000 description 6
- 238000007906 compression Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- 239000000155 melt Substances 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- -1 polypropylene Polymers 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 239000011165 3D composite Substances 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 2
- 239000000289 melt material Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 230000000391 smoking effect Effects 0.000 description 2
- FMMWHPNWAFZXNH-UHFFFAOYSA-N Benz[a]pyrene Chemical compound C1=C2C3=CC=CC=C3C=C(C=C3)C2=C2C3=CC=CC2=C1 FMMWHPNWAFZXNH-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 235000004035 Cryptotaenia japonica Nutrition 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- FLAQQSHRLBFIEZ-UHFFFAOYSA-N N-Methyl-N-nitroso-4-oxo-4-(3-pyridyl)butyl amine Chemical compound O=NN(C)CCCC(=O)C1=CC=CN=C1 FLAQQSHRLBFIEZ-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 102000007641 Trefoil Factors Human genes 0.000 description 1
- 235000015724 Trifolium pratense Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- MLUCVPSAIODCQM-NSCUHMNNSA-N crotonaldehyde Chemical compound C\C=C\C=O MLUCVPSAIODCQM-NSCUHMNNSA-N 0.000 description 1
- MLUCVPSAIODCQM-UHFFFAOYSA-N crotonaldehyde Natural products CC=CC=O MLUCVPSAIODCQM-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/12—Stretch-spinning methods
- D01D5/16—Stretch-spinning methods using rollers, or like mechanical devices, e.g. snubbing pins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
- D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
- D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
- D02J1/224—Selection or control of the temperature during stretching
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B15/00—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/04—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of yarns, threads or filaments
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
Abstract
本发明提供一种喷丝板、使用该喷丝板制备的烟用丝束及其制备方法。喷丝板上加工有若干个喷丝孔,喷丝孔包括两条空心孔和一条岛型孔,空心孔和岛型孔整体连接成三叶型;岛型孔的内部设有实体的成型岛,成型岛与喷丝板的主体部分一体成型,成型岛将岛型孔分隔成根部和自由端部,根部与空心孔连通,根部与自由端部之间留有成型间隙。利用该喷丝板生产的烟用丝束材质为PLA,所得烟用丝束的单丝为三维卷曲结构,所述单丝的横截面为单孔三叶型,单丝上与岛型孔对应的边内成型有中空孔。本发明可解决烟用丝束的卷曲效果差、出棒率低的问题。
The invention provides a spinneret, tobacco tow prepared by using the spinneret and a preparation method thereof. Several spinneret holes are processed on the spinneret. The spinneret hole includes two hollow holes and one island-shaped hole. The hollow hole and the island-shaped hole are integrally connected to form a three-lobed shape; the island-shaped hole is equipped with a solid forming island. , the forming island is integrally formed with the main part of the spinneret, the forming island separates the island-shaped hole into a root and a free end, the root is connected to the hollow hole, and there is a forming gap between the root and the free end. The material of the tobacco tow produced by the spinneret is PLA, and the monofilament of the obtained tobacco tow has a three-dimensional crimped structure. Hollow holes are formed in the sides. The invention can solve the problems of poor curling effect and low rod yield of the tobacco tow.
Description
技术领域technical field
本发明属于烟用丝束技术领域,具体涉及一种烟用丝束的喷丝板、使用该喷丝板制备的烟用丝束及其制备方法。The invention belongs to the technical field of tobacco tow, and in particular relates to a spinneret of tobacco tow, a tobacco tow prepared by using the spinneret and a preparation method thereof.
背景技术Background technique
在卷烟中,过滤嘴承担了降焦减害的功能,烟用丝束是过滤嘴的主体材料。In cigarettes, the filter tip undertakes the function of reducing tar and harm, and the tow for tobacco is the main material of the filter tip.
目前,国内外市场上商品化应用的过滤嘴材料主要为醋酸纤维素丝束和聚丙烯丝束,其中醋酸纤维素纤维的用量占到了90%以上,由于性能优异,主要用在中高档卷烟中,然而醋酸纤维素丝束的原料完全进口,技术装备主要依赖外国公司,部分国内企业用聚丙烯丝束替代醋酸纤维素丝束,然而聚丙烯丝束过滤效果不佳,只能用于低档烟中。At present, the commercially used filter materials in the domestic and foreign markets are mainly cellulose acetate tow and polypropylene tow, of which the amount of cellulose acetate fiber accounts for more than 90%. Due to its excellent performance, it is mainly used in middle and high-end cigarettes. However, the raw materials of cellulose acetate tow are completely imported, and the technical equipment mainly relies on foreign companies. Some domestic enterprises use polypropylene tow instead of cellulose acetate tow. However, the filtering effect of polypropylene tow is not good, so it can only be used in low-grade cigarettes. .
聚乳酸丝束用于卷烟有以下优点:1)聚乳酸吸附性能优异,可替代醋酸纤维素用在中高档卷烟中;2)来源可再生,生物可降解,主要原料是玉米、木薯、秸秆等农作物及废弃物,推广应用可缓解能源危机、保护生态环境、减少温室气体排放;3)生产工艺简单环保,通过熔融纺丝法制备聚乳酸丝束,解决了醋酸纤维素丝束生产过程复杂、投资大及大量丙酮溶剂环保问题。The use of polylactic acid tow in cigarettes has the following advantages: 1) Polylactic acid has excellent adsorption performance and can replace cellulose acetate in middle and high-end cigarettes; 2) The source is renewable and biodegradable, and the main raw materials are corn, cassava, straw, etc. The popularization and application of crops and waste can alleviate the energy crisis, protect the ecological environment, and reduce greenhouse gas emissions; 3) The production process is simple and environmentally friendly, and polylactic acid tow is prepared by melt spinning, which solves the complex production process of cellulose acetate tow. Large investment and a large amount of acetone solvent environmental protection problems.
现有技术烟用丝束的卷曲都是采用机械卷曲,机械卷曲存在的不足是卷曲度难以保持,在一定张力作用下会大幅度减少卷曲数和卷曲度。常规醋酸纤维素丝束和聚丙烯丝束标准的卷曲数都在22-28个/25mm,在过滤嘴成型机上,丝束在张力作用下开松后收卷成嘴棒;通过对过滤嘴中丝束进行分析,不仅卷曲数有所下降,而且卷曲角明显变大,原先高密度的“山峰形”的卷曲丝束变成了“波浪形”的丝束,降低了丝束的填充支撑效果,降低了出棒率。The crimping of tobacco tow in the prior art is mechanical crimping. The disadvantage of mechanical crimping is that it is difficult to maintain the degree of crimping, and the number and degree of crimping will be greatly reduced under a certain tension. The standard number of crimps of conventional cellulose acetate tow and polypropylene tow is 22-28/25mm. On the filter forming machine, the tow is opened under tension and then rolled into a mouth rod; According to the analysis, not only the number of crimps has decreased, but also the crimp angle has become significantly larger. The original high-density "peak-shaped" crimped tow has become a "wavy" tow, which reduces the filling and supporting effect of the tow and reduces the hit rate.
发明内容Contents of the invention
本发明的目的是提供一种烟用丝束的喷丝板、使用该喷丝板制备的烟用丝束及该烟用丝束制备方法,以解决烟用丝束的卷曲效果差的问题。The object of the present invention is to provide a spinneret for tobacco tow, a tobacco tow prepared by using the spinneret and a method for preparing the tobacco tow, so as to solve the problem of poor curling effect of the tobacco tow.
本发明提供了如下的技术方案:The present invention provides following technical scheme:
一种喷丝板,喷丝板上加工有若干个喷丝孔,所述喷丝孔包括两条空心孔和一条岛型孔,所述空心孔和所述岛型孔整体连接成三叶型;所述岛型孔的内部设有实体的成型岛,所述成型岛与所述喷丝板的主体部分一体成型,所述成型岛将所述岛型孔分隔成根部和自由端部,所述根部与所述空心孔连通,所述根部与所述自由端部之间留有成型间隙。A spinneret, on which several spinneret holes are processed, the spinneret holes include two hollow holes and an island-shaped hole, and the hollow hole and the island-shaped hole are integrally connected to form a three-lobe shape ; The inside of the island-shaped hole is provided with a solid forming island, the forming island is integrally formed with the main body of the spinneret, and the forming island separates the island-shaped hole into a root and a free end. The root is in communication with the hollow hole, and there is a forming gap between the root and the free end.
优选的,所述根部与所述自由端部在所述成型间隙处分别设有第一粘接补偿凸起部和第二粘接补偿凸起部,同一侧的所述第一粘接补偿凸起部和第二粘接补偿凸起部相对设置。Preferably, the root and the free end are respectively provided with a first bonding compensation protrusion and a second bonding compensation protrusion at the forming gap, and the first bonding compensation protrusion on the same side The raised portion and the second bonding compensating raised portion are oppositely arranged.
优选的,所述第一粘接补偿凸起部和所述第二粘接补偿凸起部均向所述成型岛的内侧凸起。Preferably, both the first adhesion compensation protrusion and the second adhesion compensation protrusion protrude toward the inner side of the forming island.
优选的,所述第一粘接补偿凸起部和所述第二粘接补偿凸起部的凸起深度为0.04-0.06mm。Preferably, the protrusion depth of the first adhesion compensation protrusion and the second adhesion compensation protrusion is 0.04-0.06 mm.
优选的,所述成型间隙的宽度为0.05-0.07mm;所述岛型孔的边缘与所述成型岛之间的孔隙宽度为0.07-0.09mm。Preferably, the width of the forming gap is 0.05-0.07 mm; the width of the gap between the edge of the island-shaped hole and the forming island is 0.07-0.09 mm.
优选的,所述岛型孔整体呈椭圆形。Preferably, the island-shaped hole has an overall oval shape.
本发明还提供一种利用上述喷丝板生产的烟用丝束,所述烟用丝束的材质为PLA,所述烟用丝束的单丝为三维卷曲结构,所述单丝的横截面为单孔三叶型,所述单丝上与所述岛型孔对应的边内成型有中空孔。The present invention also provides a tobacco tow produced by the above-mentioned spinneret, the material of the tobacco tow is PLA, the monofilament of the tobacco tow has a three-dimensional crimped structure, and the cross section of the monofilament is It is a single-hole trilobe type, and a hollow hole is formed in the side corresponding to the island-shaped hole on the monofilament.
本发明还提供利用上述喷丝板生产以上所述烟用丝束的方法,包括以下步骤:The present invention also provides a method for producing the above-mentioned tobacco tow by using the above-mentioned spinneret, comprising the following steps:
1)干燥结晶:将聚乳酸切片在60-90℃结晶,90-120℃干燥,结晶和干燥时间为13-20h,控制改性聚乳酸中含水量低于30ppm;1) Dry crystallization: polylactic acid slices are crystallized at 60-90°C, dried at 90-120°C, the crystallization and drying time is 13-20h, and the water content in the modified polylactic acid is controlled to be less than 30ppm;
2)熔融纺丝:喷丝板直径260mm,喷丝板的孔数为600-1000;纺丝螺杆直径120mm,长径比33:1,温度为210-250℃;箱体温度为235-248℃,纺丝速率900-1500m/min;冷却温度18-25℃,风压400-700Pa,风速0.2-0.6m/s,湿度65-85%;2) Melt spinning: the diameter of the spinneret is 260mm, the number of holes in the spinneret is 600-1000; the diameter of the spinning screw is 120mm, the ratio of length to diameter is 33:1, the temperature is 210-250°C; the temperature of the box is 235-248 ℃, spinning speed 900-1500m/min; cooling temperature 18-25℃, wind pressure 400-700Pa, wind speed 0.2-0.6m/s, humidity 65-85%;
3)牵引:六棍牵引机,辊为品字形分布,表面镀硬铬0.1mm,并且犁面处理;3) Traction: Six-stick traction machine, the rollers are distributed in a square shape, the surface is hard chrome-plated 0.1mm, and the plow surface is treated;
4)喂入:喂入轮直径480mm,表面喷陶处理;4) Feeding: The diameter of the feeding wheel is 480mm, and the surface is sprayed with pottery;
5)往复落桶:往复机为纵向链板式,横向导轨;丝桶规格1000x1000x1200mm;纵向传动为伺服电机,纵向速度5-10m/min;横向传动为伺服电机,横向速度0.2-0.5m/min;进出桶传动功率1.5Kw,进出桶速度5-10m/min;5) Reciprocating drop barrel: the reciprocating machine is of longitudinal chain plate type and horizontal guide rail; the size of the wire barrel is 1000x1000x1200mm; the longitudinal transmission is a servo motor, and the longitudinal speed is 5-10m/min; the horizontal transmission is a servo motor, and the lateral speed is 0.2-0.5m/min; The transmission power of entering and exiting the barrel is 1.5Kw, and the speed of entering and exiting the barrel is 5-10m/min;
6)集束:集束桶数48桶,2-6桶/一束;吊栏不锈钢制作,板厚2mm,带导丝棒,带张力调节装置及上导丝架;张力导丝辊直径85mm,表面镀硬铬0.1mm;6) Clustering: 48 barrels for clustering, 2-6 barrels per bundle; hanger rail made of stainless steel, plate thickness 2mm, with guide wire rod, tension adjustment device and upper guide wire frame; tension godet roller diameter 85mm, surface Hard chrome plating 0.1mm;
7)牵伸:牵伸为四道阶梯拉伸工艺,牵伸辊为电磁感应加热,牵伸辊表面镀硬铬0.1mm;第一牵伸辊温度控制在45-50℃,第二牵伸辊温度控制在60-65℃,第三牵伸辊温度控制在65-72℃,第四牵伸辊温度控制在72-80℃;第一二牵伸辊的速率比(牵伸比)为1.5,第二三牵伸辊的速率比(牵伸比)为1.8,第三四牵伸辊的速率比(牵伸比)为1.3;7) Drafting: drafting is a four-step stretching process, the drafting roller is heated by electromagnetic induction, and the surface of the drafting roller is plated with 0.1mm of hard chrome; the temperature of the first drafting roller is controlled at 45-50 ° C, and the second drafting The roll temperature is controlled at 60-65°C, the temperature of the third draft roll is controlled at 65-72°C, and the temperature of the fourth draft roll is controlled at 72-80°C; the speed ratio (drawing ratio) of the first and second draft rolls is 1.5, the speed ratio (drawing ratio) of the second and third drafting rollers is 1.8, and the speed ratio (drawing ratio) of the third and fourth drafting rollers is 1.3;
8)预热卷曲:卷曲前通过蒸汽箱,蒸汽箱的长度为1米,温度控制在80-100℃;卷曲轮内部通循环热水,热水温度控制在50-60℃;卷曲速度为120-180m/min,卷曲轮直径60mm,卷曲轮宽度16-32mm;丝束的总线密度为2.0-5.5ktex;8) Preheating and curling: pass through the steam box before curling, the length of the steam box is 1 meter, and the temperature is controlled at 80-100°C; the circulating hot water is passed inside the curling wheel, and the temperature of the hot water is controlled at 50-60°C; the curling speed is 120 -180m/min, crimping wheel diameter 60mm, crimping wheel width 16-32mm; total density of tow is 2.0-5.5ktex;
9)烘干热定型:烘箱采用天然气加热方式,温度控制在60-90℃,时间12-15min;9) Drying and heat setting: the oven adopts natural gas heating method, the temperature is controlled at 60-90°C, and the time is 12-15min;
10)输送摆丝:PVC钢扣式防滑带,带宽70,带厚3~4mm,传动辊直径100mm;摆丝喂入轮直径150mm,表面镀硬铬0.05mm,摆丝盛丝桶带托脚叶板转臂机构;10) Wobbling wire conveying: PVC steel buckle anti-skid belt, width 70, belt thickness 3-4mm, diameter of transmission roller 100mm; diameter of spinning wire feeding wheel 150mm, hard chrome plated surface 0.05mm, spinning bucket with supporting legs Blade arm mechanism;
11)打包:主压油缸Φ320xΦ250mm;提箱油缸Φ150xΦ85mm;定位油缸Φ50xΦ28mm;设计压力35MPa,电机功率55Kw;包重200-250kg。11) Packing: main pressure cylinder Φ320xΦ250mm; suitcase cylinder Φ150xΦ85mm; positioning cylinder Φ50xΦ28mm; design pressure 35MPa, motor power 55Kw; package weight 200-250kg.
本发明的有益效果是:The beneficial effects of the present invention are:
1、利用本发明的喷丝板生产的丝束单丝纤维为单孔三叶形,孔的位置偏向其中一个叶,纤维在冷却过程中,由于冷却速度的差异导致收缩的不对称,使得丝束呈现永久的三维卷曲效果,叠加机械卷曲,形成二维和三维复合卷曲,保持了良好的丝束卷曲性能,降低了在过滤嘴棒中的填充密度,提高出棒率8-12%,降低了生产成本。1. The tow monofilament fiber produced by the spinneret of the present invention is a single-hole trilobal shape, and the position of the hole is biased towards one of the leaves. During the cooling process of the fiber, the difference in cooling rate causes the shrinkage asymmetry, so that the filament The tow presents a permanent three-dimensional crimp effect, superimposed mechanical crimps to form a two-dimensional and three-dimensional composite crimp, which maintains good tow crimp performance, reduces the packing density in the filter rod, increases the rod yield by 8-12%, and reduces the Cost of production.
2、喷丝板的成型岛将岛型孔分隔成根部和自由端部,根部与自由端部之间留有成型间隙,在熔体纺丝过程中,冷却风由该成型间隙吹进纤维内形成中空结构,后流出的熔体物料在成型间隙处迅速膨胀而填补成型间隙,自然粘合成一体而在纤维内部形成中空孔,保证中空孔的成型稳定性和中空孔的中空度。2. The forming island of the spinneret divides the island-shaped hole into a root and a free end. There is a forming gap between the root and the free end. During the melt spinning process, the cooling air is blown into the fiber through the forming gap A hollow structure is formed, and the molten material that flows out expands rapidly in the forming gap to fill the forming gap, and is naturally bonded into one body to form a hollow hole inside the fiber, ensuring the forming stability of the hollow hole and the hollowness of the hollow hole.
3、本发明丝束的单丝纤维结构为单孔三叶形,其中的中空孔结构相对于现有的醋烟用丝束结构而言,增加了过滤面积,提升了烟气的过滤效果。同时,本发明丝束纤维的中空度达到了18-25%,降低了丝束在过滤嘴棒中的堆积密度,提高了出棒率,从而降低了生产成本。3. The monofilament fiber structure of the tow of the present invention is a single-hole trefoil shape, and the hollow pore structure increases the filtering area and improves the filtering effect of smoke compared with the existing tow structure for vinegar tobacco. At the same time, the hollowness of the tow fiber in the invention reaches 18-25%, which reduces the packing density of the tow in the filter tip rod, improves the rod yield, and thus reduces the production cost.
4、在同等圆周条件下,本发明提供的丝束制成的过滤嘴棒吸阻降低10-15%,改善了抽吸品质,为市场填补了低吸阻烟用丝束产品空白。4. Under the same circumferential conditions, the filter rod made of the tow provided by the present invention reduces the draw resistance by 10-15%, improves the smoking quality, and fills the gap in the market for tow products for low draw resistance cigarettes.
附图说明Description of drawings
附图用来提供对本发明的进一步理解,并且构成说明书的一部分,与本发明的实施例一起用于解释本发明,并不构成对本发明的限制。在附图中:The accompanying drawings are used to provide a further understanding of the present invention, and constitute a part of the description, and are used together with the embodiments of the present invention to explain the present invention, and do not constitute a limitation to the present invention. In the attached picture:
图1是本发明的喷丝板结构示意图;Fig. 1 is a schematic view of spinneret structure of the present invention;
图2是本发明的喷丝孔结构示意图;Fig. 2 is a schematic view of spinneret hole structure of the present invention;
图3是本发明的烟用丝束的单丝横截面结构示意图;Fig. 3 is a schematic diagram of the monofilament cross-sectional structure of the tobacco tow of the present invention;
图中标记为:1.喷丝板;2.喷丝孔;3.空心孔;4.岛型孔;5.根部;6.自由端部;7.成型岛;8.第一粘接补偿凸起部;9.第二粘接补偿凸起部;10.烟用丝束的单丝;11.中空孔。Marked in the figure: 1. spinneret; 2. spinneret hole; 3. hollow hole; 4. island hole; 5. root; 6. free end; 7. forming island; 8. first bonding compensation Raised part; 9. Second bonding compensating raised part; 10. Monofilament of tobacco tow; 11. Hollow hole.
具体实施方式Detailed ways
如图1和图2所示,一种烟用丝束的喷丝板1,喷丝板1上加工有若干个喷丝孔2,喷丝孔2包括两条空心孔3和一条岛型孔4,空心孔3和岛型孔4整体连接成三叶型;岛型孔4整体呈椭圆形,岛型孔4的内部设有实体的成型岛7,成型岛7与喷丝板1的主体部分一体成型,成型岛7将岛型孔4分隔成根部5和自由端部6,根部5与两个空心孔3连通,根部5与自由端部6之间留有成型间隙,成型间隙的宽度a为0.05-0.07mm;岛型孔4的边缘与成型岛7之间的孔隙宽度b为0.07-0.09mm。在熔体纺丝过程中,紧靠喷丝板1下方的冷却风由该成型间隙吹进纤维内形成中空结构,后流出喷丝孔2的熔体物料在成型间隙处迅速膨胀而填补成型间隙,自然粘合成一体而形成中空孔,保证中空孔的成型稳定性和中空孔的中空度。As shown in Figures 1 and 2, a spinneret 1 for tobacco tow has several spinneret holes 2 processed on the spinneret 1, and the spinneret holes 2 include two hollow holes 3 and an island-shaped hole 4. The hollow hole 3 and the island-shaped hole 4 are integrally connected to form a trilobal shape; the island-shaped hole 4 is elliptical as a whole, and the interior of the island-shaped hole 4 is provided with a solid forming island 7, and the forming island 7 and the main body of the spinneret 1 The part is integrally formed, and the forming island 7 separates the island-shaped hole 4 into a root 5 and a free end 6. The root 5 communicates with the two hollow holes 3, and there is a forming gap between the root 5 and the free end 6. The width of the forming gap is a is 0.05-0.07mm; the pore width b between the edge of the island-shaped hole 4 and the forming island 7 is 0.07-0.09mm. During the melt spinning process, the cooling air next to the spinneret 1 is blown into the fiber from the forming gap to form a hollow structure, and the melt material flowing out of the spinneret hole 2 expands rapidly at the forming gap to fill the forming gap , naturally bonded together to form a hollow hole, ensuring the stability of the hollow hole and the hollowness of the hollow hole.
根部5与自由端部6在成型间隙处分别设有第一粘接补偿凸起部8和第二粘接补偿凸起部9,同一侧的第一粘接补偿凸起部8和第二粘接补偿凸起部9相对设置。设置第一粘接补偿凸起部8和第二粘接补偿凸起部9,有利于熔体物料可靠地填补成型间隙,形成密封的中空孔。第一粘接补偿凸起部8和第二粘接补偿凸起部9均向成型岛7的内侧凸起,第一粘接补偿凸起部8和第二粘接补偿凸起部9的凸起深度c为0.04-0.06mm。The root portion 5 and the free end portion 6 are respectively provided with a first bonding compensation protrusion 8 and a second bonding compensation protrusion 9 at the forming gap, and the first bonding compensation protrusion 8 and the second bonding compensation protrusion 9 on the same side The compensation raised portion 9 is oppositely arranged. The provision of the first bonding compensating raised portion 8 and the second bonding compensating raised portion 9 is beneficial for the melt material to reliably fill the molding gap and form a sealed hollow hole. The first bonding compensating raised portion 8 and the second bonding compensating raised portion 9 all protrude toward the inside of the molding island 7, and the protrusions of the first bonding compensating raised portion 8 and the second bonding compensating raised portion 9 The starting depth c is 0.04-0.06mm.
图3所示为利用上述喷丝板生产的烟用丝束的单丝10横截面结构,烟用丝束的材质为PLA,烟用丝束的单丝10为三维卷曲结构,单丝10的横截面为单孔三叶型,单丝上与岛型孔对应的边内成型有中空孔11。该烟用丝束的单丝纤维为单孔三叶形,中空孔11的位置偏向其中一个叶,纤维在冷却过程中,由于冷却速度的差异导致收缩的不对称,使得丝束呈现永久的三维卷曲效果,叠加机械卷曲,形成二维和三维复合卷曲,保持了良好的丝束卷曲性能,降低了在过滤嘴棒中的填充密度,提高出棒率8-12%,降低了生产成本。Fig. 3 shows the monofilament 10 cross-sectional structure of the tobacco tow that utilizes above-mentioned spinneret production, and the material of tobacco tow is PLA, and the monofilament 10 of tobacco tow is three-dimensional curly structure, and the monofilament 10 The cross-section is a single-hole three-leaf shape, and a hollow hole 11 is formed in the side corresponding to the island-shaped hole on the monofilament. The monofilament fiber of the tobacco tow is in the shape of a single hole and three leaves, and the position of the hollow hole 11 is biased toward one of the leaves. During the cooling process, the difference in the cooling rate of the fiber causes the shrinkage asymmetry, so that the tow presents a permanent three-dimensional shape. Curling effect, superimposed mechanical crimping, forming two-dimensional and three-dimensional composite crimping, maintaining good tow crimping performance, reducing the filling density in the filter rod, increasing the rod yield by 8-12%, and reducing production costs.
本发明还提供一种利用上述喷丝板生产烟用丝束的方法,用以下三个实施例和一个对比例作具体说明。The present invention also provides a method for producing tobacco tow by using the above-mentioned spinneret, which will be specifically described with the following three examples and a comparative example.
实施例1Example 1
1、原料切片聚乳酸的特性粘度1.57dl/g,熔融指数26g/10min(210℃,2160g),玻璃化转变温度62℃,熔融温度175℃。1. The intrinsic viscosity of polylactic acid sliced raw material is 1.57dl/g, the melt index is 26g/10min (210°C, 2160g), the glass transition temperature is 62°C, and the melting temperature is 175°C.
2、丝束的制备工艺为:2. The preparation process of tow is:
(1)干燥结晶,将聚乳酸切片在60℃预结晶,90℃条件下干燥,露点温度-90℃,结晶和干燥时间为20h,聚乳酸含水量21ppm。(1) Dry crystallization. Pre-crystallize polylactic acid slices at 60°C and dry at 90°C. The dew point temperature is -90°C. The crystallization and drying time is 20 hours, and the water content of polylactic acid is 21ppm.
(2)熔融纺丝,喷丝板的直径260mm,喷丝板的孔数为1000,单孔为中空三叶形;纺丝螺杆直径120mm,长径比33:1,温度为210-250℃(螺杆一区210℃,二区225℃,三区245℃,四区248℃,五区245℃);箱体温度为245℃,纺丝速率1300m/min;冷却温度18℃,风压680Pa,风速0.6m/s,湿度80%。(2) Melt spinning, the diameter of the spinneret is 260mm, the number of holes in the spinneret is 1000, and the single hole is a hollow trilobal shape; the diameter of the spinning screw is 120mm, the aspect ratio is 33:1, and the temperature is 210-250°C (The first zone of the screw is 210°C, the second zone is 225°C, the third zone is 245°C, the fourth zone is 248°C, the fifth zone is 245°C); the box temperature is 245°C, the spinning speed is 1300m/min; the cooling temperature is 18°C, and the wind pressure is 680Pa , wind speed 0.6m/s, humidity 80%.
(3)牵引、喂入。(3) Traction and feeding.
(4)往复落桶,纵向速度10m/min;横向速度0.5m/min;进出桶速度10m/min。(4) Reciprocating falling barrel, longitudinal speed 10m/min; transverse speed 0.5m/min; speed of entering and leaving the barrel 10m/min.
(5)集束。(5) Clustering.
(6)牵伸,第一牵伸辊温度控制在45℃,第二牵伸辊温度控制在60℃,第三牵伸辊温度控制在68℃,第四牵伸辊温度控制在75℃;第一二牵伸辊的速率比为1.5,第二三牵伸辊的速率比为1.8,第三四牵伸辊的速率比为1.3。(6) drafting, the temperature of the first drafting roller is controlled at 45°C, the temperature of the second drafting roller is controlled at 60°C, the temperature of the third drafting roller is controlled at 68°C, and the temperature of the fourth drafting roller is controlled at 75°C; The speed ratio of the first and second drafting rolls is 1.5, the speed ratio of the second and third drafting rolls is 1.8, and the speed ratio of the third and fourth drafting rolls is 1.3.
(7)预热卷曲,卷曲蒸汽箱温度控制在100℃;卷曲轮内部通循环热水温度50℃;卷曲速度为120m/min,卷曲轮宽度32mm。(7) Preheating and curling, the temperature of the curling steam box is controlled at 100°C; the temperature of the circulating hot water inside the curling wheel is 50°C; the curling speed is 120m/min, and the width of the curling wheel is 32mm.
(8)烘干热定型,烘箱一区温度60℃,二区温度68℃,三区温度75℃,四区温度82℃,五区温度85℃,时间12min。(8) Drying heat setting, the temperature of the first zone of the oven is 60°C, the temperature of the second zone is 68°C, the temperature of the third zone is 75°C, the temperature of the fourth zone is 82°C, the temperature of the fifth zone is 85°C, and the time is 12 minutes.
(9)输送摆丝和打包,打包重量220kg/包。(9) Conveying and packing the spinning wire, the packing weight is 220kg/bag.
3、丝束规格:3. Tow specifications:
单丝中空度22%,单丝线密度3.0dtex,丝束的总线密度为4.2ktex,机械卷曲数27个/25mm,三维卷曲数6个/25mm,卷曲度25%,开松后的压缩回弹率29%。Hollowness of monofilament is 22%, linear density of monofilament is 3.0dtex, total density of tow is 4.2ktex, number of mechanical crimps is 27/25mm, number of three-dimensional crimps is 6/25mm, degree of crimp is 25%, compression rebound after opening rate 29%.
实施例2Example 2
1、原料切片聚乳酸的特性粘度1.57dl/g,熔融指数26g/10min(210℃,2160g),玻璃化转变温度62℃,熔融温度175℃。1. The intrinsic viscosity of polylactic acid sliced raw material is 1.57dl/g, the melt index is 26g/10min (210°C, 2160g), the glass transition temperature is 62°C, and the melting temperature is 175°C.
2、丝束的制备工艺为:2. The preparation process of tow is:
(1)干燥结晶,将聚乳酸切片在65℃预结晶,105℃条件下干燥,露点温度-90℃,结晶干燥时间为13h,聚乳酸含水量20ppm。(1) Dry crystallization, pre-crystallize polylactic acid slices at 65°C, dry at 105°C, dew point temperature -90°C, crystallization drying time 13h, polylactic acid water content 20ppm.
(2)熔融纺丝,熔融纺丝喷丝板的直径尺寸260mm,喷丝板的孔数为600,单孔为中空三叶形;纺丝螺杆直径120mm,长径比33:1,温度为210-250℃(螺杆一区215℃,二区228℃,三区248℃,四区250℃,五区248℃);箱体温度为248℃,纺丝速率1500m/min;冷却温度20℃,风压600Pa,风速0.5m/s,湿度75%。(2) Melt spinning, the diameter of the melt spinning spinneret is 260mm, the number of holes in the spinneret is 600, and the single hole is a hollow trilobal shape; the diameter of the spinning screw is 120mm, the aspect ratio is 33:1, and the temperature is 210-250°C (screw zone 1 215°C, zone 2 228°C, zone 3 248°C, zone 4 250°C, zone 5 248°C); box temperature 248°C, spinning speed 1500m/min; cooling temperature 20°C , wind pressure 600Pa, wind speed 0.5m/s, humidity 75%.
(3)牵引、喂入。(3) Traction and feeding.
(4)往复落桶,往复落桶纵向速度8m/min;横向速度0.2m/min;进出桶速度5m/min。(4) Reciprocating falling barrel, the vertical speed of reciprocating falling barrel is 8m/min; the transverse speed is 0.2m/min; the speed of entering and exiting the barrel is 5m/min.
(5)集束。(5) Clustering.
(6)牵伸,第一牵伸辊温度控制在48℃,第二牵伸辊温度控制在62℃,第三牵伸辊温度控制在70℃,第四牵伸辊温度控制在80℃;第一二牵伸辊的速率比为1.5,第二三牵伸辊的速率比为1.8,第三四牵伸辊的速率比为1.3。(6) drafting, the temperature of the first drafting roller is controlled at 48°C, the temperature of the second drafting roller is controlled at 62°C, the temperature of the third drafting roller is controlled at 70°C, and the temperature of the fourth drafting roller is controlled at 80°C; The speed ratio of the first and second drafting rolls is 1.5, the speed ratio of the second and third drafting rolls is 1.8, and the speed ratio of the third and fourth drafting rolls is 1.3.
(7)预热卷曲,卷曲蒸汽箱温度控制在95℃;卷曲轮内部通循环热水温度60℃;卷曲速度为150m/min,卷曲轮宽度32mm。(7) Preheating and curling, the temperature of the curling steam box is controlled at 95°C; the temperature of the circulating hot water inside the curling wheel is 60°C; the curling speed is 150m/min, and the width of the curling wheel is 32mm.
(8)烘干热定型,烘箱一区温度65℃,二区温度65℃,三区温度70℃,四区温度75℃,五区温度82℃,时间15min。(8) Drying heat setting, the temperature of the first zone of the oven is 65°C, the temperature of the second zone is 65°C, the temperature of the third zone is 70°C, the temperature of the fourth zone is 75°C, the temperature of the fifth zone is 82°C, and the time is 15 minutes.
(9)输送摆丝和打包,打包重量250kg/包。(9) Conveying and packing the spinning wire, the packing weight is 250kg/bag.
3、丝束规格:3. Tow specifications:
单丝中空度25%,单丝线密度3.0dtex,丝束的总线密度为4.2ktex,机械卷曲数28个/25mm,三维卷曲数7个/25mm,卷曲度29%,丝束开松后的压缩回弹率32%。The monofilament hollowness is 25%, the monofilament linear density is 3.0dtex, the total density of the tow is 4.2ktex, the number of mechanical crimps is 28/25mm, the number of three-dimensional crimps is 7/25mm, the degree of crimp is 29%, the compression of the tow after opening The rebound rate is 32%.
实施例3Example 3
1、原料切片聚乳酸的特性粘度1.57dl/g,熔融指数26g/10min(210℃,2160g),玻璃化转变温度62℃,熔融温度175℃。1. The intrinsic viscosity of polylactic acid sliced raw material is 1.57dl/g, the melt index is 26g/10min (210°C, 2160g), the glass transition temperature is 62°C, and the melting temperature is 175°C.
2、丝束的制备工艺为:2. The preparation process of tow is:
(1)干燥结晶,将聚乳酸切片在65℃预结晶,100℃条件下干燥,露点温度-90℃,结晶干燥时间为15h,聚乳酸含水量25ppm。(1) Dry crystallization, pre-crystallize the polylactic acid slices at 65°C, dry at 100°C, the dew point temperature is -90°C, the crystallization drying time is 15h, and the polylactic acid water content is 25ppm.
(2)熔融纺丝,熔融纺丝喷丝板的直径尺寸260mm,喷丝板的孔数为800,单孔为中空三叶形;纺丝螺杆直径120mm,长径比33:1,温度为210-250℃(螺杆一区212℃,二区226℃,三区246℃,四区248℃,五区246℃);箱体温度为246℃,纺丝速率900m/min;冷却温度22℃,风压500Pa,风速0.4m/s,湿度65%。(2) Melt spinning, the diameter of the melt spinning spinneret is 260mm, the number of holes in the spinneret is 800, and the single hole is a hollow trilobal shape; the diameter of the spinning screw is 120mm, the aspect ratio is 33:1, and the temperature is 210-250°C (screw zone 1 212°C, zone 2 226°C, zone 3 246°C, zone 4 248°C, zone 5 246°C); box temperature 246°C, spinning speed 900m/min; cooling temperature 22°C , wind pressure 500Pa, wind speed 0.4m/s, humidity 65%.
(3)牵引、喂入。(3) Traction and feeding.
(4)往复落桶,往复落桶纵向速度6m/min;横向速度0.3m/min;进出桶速度6m/min。(4) Reciprocating falling barrel, the longitudinal speed of reciprocating falling barrel is 6m/min; the transverse speed is 0.3m/min; the speed of entering and exiting the barrel is 6m/min.
(5)集束。(5) Clustering.
(6)牵伸,第一牵伸辊温度控制在50℃,第二牵伸辊温度控制在65℃,第三牵伸辊温度控制在72℃,第四牵伸辊温度控制在75℃;第一二牵伸辊的速率比为1.5,第二三牵伸辊的速率比为1.8,第三四牵伸辊的速率比为1.3。(6) drafting, the temperature of the first drafting roller is controlled at 50°C, the temperature of the second drafting roller is controlled at 65°C, the temperature of the third drafting roller is controlled at 72°C, and the temperature of the fourth drafting roller is controlled at 75°C; The speed ratio of the first and second drafting rolls is 1.5, the speed ratio of the second and third drafting rolls is 1.8, and the speed ratio of the third and fourth drafting rolls is 1.3.
(7)预热卷曲,卷曲蒸汽箱温度控制在80℃;卷曲轮内部通循环热水温度58℃;卷曲速度为180m/min,卷曲轮宽度32mm。(7) Preheating and curling, the temperature of the curling steam box is controlled at 80°C; the temperature of the circulating hot water inside the curling wheel is 58°C; the curling speed is 180m/min, and the width of the curling wheel is 32mm.
(8)烘干热定型,烘箱一区温度68℃,二区温度705℃,三区温度78℃,四区温度78℃,五区温度90℃,时间15min。(8) Drying and heat setting, the temperature of the first zone of the oven is 68°C, the temperature of the second zone is 705°C, the temperature of the third zone is 78°C, the temperature of the fourth zone is 78°C, the temperature of the fifth zone is 90°C, and the time is 15 minutes.
(9)输送摆丝和打包,打包重量250kg/包。(9) Conveying and packing the spinning wire, the packing weight is 250kg/bag.
3、丝束规格:3. Tow specifications:
单丝中空度23%,单丝线密度3.0dtex,丝束的总线密度为4.2ktex,机械卷曲数26个/25mm,三维卷曲数7个/25mm,卷曲度28%,丝束开松后的压缩回弹率30%。The hollowness of monofilament is 23%, the linear density of monofilament is 3.0dtex, the total density of tow is 4.2ktex, the number of mechanical crimps is 26/25mm, the number of three-dimensional crimps is 7/25mm, the degree of crimp is 28%, the compression of tow after opening 30% rebound rate.
实施例4Example 4
1、原料切片聚乳酸的特性粘度1.57dl/g,熔融指数26g/10min(210℃,2160g),玻璃化转变温度62℃,熔融温度175℃。1. The intrinsic viscosity of polylactic acid sliced raw material is 1.57dl/g, the melt index is 26g/10min (210°C, 2160g), the glass transition temperature is 62°C, and the melting temperature is 175°C.
2、丝束的制备工艺为:2. The preparation process of tow is:
(1)干燥结晶,将聚乳酸切片在65℃预结晶,100℃条件下干燥,露点温度-90℃,时间为15h,聚乳酸含水量25ppm。(1) Dry crystallization, pre-crystallize polylactic acid slices at 65°C, dry at 100°C, dew point temperature -90°C, time 15h, polylactic acid water content 25ppm.
(2)熔融纺丝,熔融纺丝喷丝板的直径尺寸260mm,喷丝板的孔数为800,单孔为中空三叶形;纺丝螺杆直径120mm,长径比33:1,温度为210-250℃(螺杆一区212℃,二区226℃,三区246℃,四区248℃,五区246℃);箱体温度为246℃,纺丝速率900m/min;冷却温度22℃,风压500Pa,风速0.4m/s,湿度65%。(2) Melt spinning, the diameter of the melt spinning spinneret is 260mm, the number of holes in the spinneret is 800, and the single hole is a hollow trilobal shape; the diameter of the spinning screw is 120mm, the aspect ratio is 33:1, and the temperature is 210-250°C (screw zone 1 212°C, zone 2 226°C, zone 3 246°C, zone 4 248°C, zone 5 246°C); box temperature 246°C, spinning speed 900m/min; cooling temperature 22°C , wind pressure 500Pa, wind speed 0.4m/s, humidity 65%.
(3)牵引、喂入。(3) Traction and feeding.
(4)往复落桶,往复落桶纵向速度6m/min;横向速度0.3m/min;进出桶速度6m/min。(4) Reciprocating falling barrel, the longitudinal speed of reciprocating falling barrel is 6m/min; the transverse speed is 0.3m/min; the speed of entering and exiting the barrel is 6m/min.
(5)集束。(5) Clustering.
(6)牵伸,第一牵伸辊温度控制在50℃,第二牵伸辊温度控制在65℃,第三牵伸辊温度控制在72℃,第四牵伸辊温度控制在75℃;第一二牵伸辊的速率比为1.5,第二三牵伸辊的速率比为1.8,第三四牵伸辊的速率比为1.3。(6) drafting, the temperature of the first drafting roller is controlled at 50°C, the temperature of the second drafting roller is controlled at 65°C, the temperature of the third drafting roller is controlled at 72°C, and the temperature of the fourth drafting roller is controlled at 75°C; The speed ratio of the first and second drafting rolls is 1.5, the speed ratio of the second and third drafting rolls is 1.8, and the speed ratio of the third and fourth drafting rolls is 1.3.
(7)预热卷曲,卷曲蒸汽箱温度控制在80℃;卷曲轮内部通循环热水温度58℃;卷曲速度为180m/min,卷曲轮宽度20mm。(7) Preheating and curling, the temperature of the curling steam box is controlled at 80°C; the temperature of the circulating hot water inside the curling wheel is 58°C; the curling speed is 180m/min, and the width of the curling wheel is 20mm.
(8)烘干热定型,烘箱一区温度68℃,二区温度705℃,三区温度78℃,四区温度78℃,五区温度90℃,时间15min。(8) Drying and heat setting, the temperature of the first zone of the oven is 68°C, the temperature of the second zone is 705°C, the temperature of the third zone is 78°C, the temperature of the fourth zone is 78°C, the temperature of the fifth zone is 90°C, and the time is 15 minutes.
(9)输送摆丝和打包,打包重量250kg/包。(9) Conveying and packing the spinning wire, the packing weight is 250kg/bag.
3、丝束规格:3. Tow specifications:
单丝中空度23%,单丝线密度3.0dtex,丝束的总线密度为2.0ktex,机械卷曲数29个/25mm,三维卷曲数6个/25mm,卷曲度33%,丝束开松后的压缩回弹率35%。The hollowness of monofilament is 23%, the linear density of monofilament is 3.0dtex, the total density of tow is 2.0ktex, the number of mechanical crimps is 29/25mm, the number of three-dimensional crimps is 6/25mm, the degree of crimp is 33%, the compression of tow after opening The rebound rate is 35%.
对比实施例1:聚乳酸丝束的制备方法(单丝截面为三叶实心)Comparative example 1: the preparation method of polylactic acid tow (monofilament cross section is trilobal solid)
1、原料切片聚乳酸的特性粘度1.57dl/g,熔融指数26g/10min(210℃,2160g),玻璃化转变温度62℃,熔融温度175℃。1. The intrinsic viscosity of polylactic acid sliced raw material is 1.57dl/g, the melt index is 26g/10min (210°C, 2160g), the glass transition temperature is 62°C, and the melting temperature is 175°C.
2、丝束的制备工艺为:2. The preparation process of tow is:
将聚乳酸切片在70℃预结晶,110℃条件下干燥,露点温度-90℃,结晶干燥时间为13h,聚乳酸含水量22ppm。熔融纺丝喷丝板的直径尺寸260mm,喷丝板的孔数为1000,单孔为三叶形;纺丝螺杆直径120mm,长径比33:1,温度为210-250℃(螺杆一区215℃,二区235℃,三区242℃,四区242℃,五区238℃);箱体温度为238℃,纺丝速率1200m/min;冷却温度21℃,风压460Pa,风速0.3m/s,湿度70%。往复落桶纵向速度8m/min;横向速度0.3m/min;进出桶速度8m/min。第一牵伸辊温度控制在45℃,第二牵伸辊温度控制在60℃,第三牵伸辊温度控制在70℃,第四牵伸辊温度控制在76℃;第一二牵伸辊的速率比为1.5,第二三牵伸辊的速率比为1.8,第三四牵伸辊的速率比为1.3。卷曲蒸汽箱温度控制在90℃;卷曲轮内部通循环热水温度55℃;卷曲速度为160m/min,卷曲轮宽度32mm。烘箱一区温度65℃,二区温度68℃,三区温度72℃,四区温度75℃,五区温度82℃,时间13min。打包重量220kg/包。The polylactic acid slices were pre-crystallized at 70°C, dried at 110°C, the dew point temperature was -90°C, the crystallization drying time was 13 hours, and the water content of polylactic acid was 22ppm. The diameter of the melt spinning spinneret is 260mm, the number of holes in the spinneret is 1000, and the single hole is trilobal; the diameter of the spinning screw is 120mm, the ratio of length to diameter is 33:1, and the temperature is 210-250°C (the first area of the screw 215°C, 235°C in the second zone, 242°C in the third zone, 242°C in the fourth zone, and 238°C in the fifth zone); the box temperature is 238°C, the spinning speed is 1200m/min; the cooling temperature is 21°C, the wind pressure is 460Pa, and the wind speed is 0.3m /s, humidity 70%. The longitudinal speed of reciprocating falling barrel is 8m/min; the transverse speed is 0.3m/min; the speed of entering and leaving the barrel is 8m/min. The temperature of the first drafting roll is controlled at 45°C, the temperature of the second drafting roll is controlled at 60°C, the temperature of the third drafting roll is controlled at 70°C, and the temperature of the fourth drafting roll is controlled at 76°C; The speed ratio is 1.5, the speed ratio of the second and third drafting rolls is 1.8, and the speed ratio of the third and fourth drafting rolls is 1.3. The temperature of the curling steam box is controlled at 90°C; the temperature of the circulating hot water inside the curling wheel is 55°C; the curling speed is 160m/min, and the width of the curling wheel is 32mm. The temperature in the first zone of the oven is 65°C, the temperature in the second zone is 68°C, the temperature in the third zone is 72°C, the temperature in the fourth zone is 75°C, the temperature in the fifth zone is 82°C, and the time is 13 minutes. Packing weight 220kg/bag.
3、丝束规格:3. Tow specifications:
单丝线密度3.0dtex,丝束的总线密度为4.2ktex,机械卷曲数27个/25mm,卷曲度20%,开松后的压缩回弹率13%。The linear density of monofilament is 3.0dtex, the total density of tow is 4.2ktex, the number of mechanical crimps is 27/25mm, the degree of crimp is 20%, and the compression rebound rate after opening is 13%.
实施例1-3与对比实施例1及对应传统丝束的指标对比分析如下表所示:Embodiment 1-3 and comparative example 1 and the index comparative analysis of corresponding traditional tow are shown in the table below:
由上表可知,在同样丝束线密度规格条件下,本发明丝束的卷曲度和压缩回弹率明显较高,说明本发明丝束的填充性能好。制成的滤棒,在同等圆周条件下,吸阻较低,有利于卷烟的抽吸;虽然吸阻低,但是过滤效果却很突出,从七大有害物质(一氧化碳、氰化氢、NNK、氨、苯并芘、苯酚和巴豆醛)的危害性指数可见,过滤效果优于对比实施例和传统CA滤棒。关于关键经济指标出棒率,本发明丝束高出同规格对比实施例30%左右,高出CA滤棒15-20%。It can be seen from the above table that under the same specification condition of the linear density of the tow, the curl degree and compression rebound rate of the tow of the present invention are obviously higher, indicating that the filling performance of the tow of the present invention is good. The filter rod made has a lower suction resistance under the same circumferential conditions, which is beneficial to the smoking of cigarettes; although the suction resistance is low, the filtering effect is very outstanding. From the seven harmful substances (carbon monoxide, hydrogen cyanide, NNK, Ammonia, benzopyrene, phenol and crotonaldehyde) hazard index visible, filter effect is better than comparative example and traditional CA filter stick. With regard to the rod yield of key economic indicators, the tow of the present invention is about 30% higher than that of the comparative example with the same specification, and is 15-20% higher than that of the CA filter rod.
以上所述仅为本发明的优选实施例而已,并不用于限制本发明,尽管参照前述实施例对本发明进行了详细的说明,对于本领域的技术人员来说,其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above description is only a preferred embodiment of the present invention, and is not intended to limit the present invention. Although the present invention has been described in detail with reference to the foregoing embodiments, those skilled in the art can still understand the foregoing embodiments The recorded technical solutions are modified, or some of the technical features are equivalently replaced. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention shall be included within the protection scope of the present invention.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111118636A (en) * | 2019-12-29 | 2020-05-08 | 江苏恒力化纤股份有限公司 | Preparation method of toy filler |
CN114905726A (en) * | 2022-05-13 | 2022-08-16 | 青岛正沃机械设备科技有限公司 | Ring winding production device |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0186293A2 (en) * | 1984-11-16 | 1986-07-02 | Teijin Limited | Blood treatment device |
US5263845A (en) * | 1992-10-27 | 1993-11-23 | Basf Corporation | Spinnerette plate for the manufacture of multilobal fibers with projections on each lobe |
JPH07258915A (en) * | 1994-03-14 | 1995-10-09 | Kanegafuchi Chem Ind Co Ltd | Porous polysulfone hollow yarn |
JPH0874142A (en) * | 1994-06-20 | 1996-03-19 | Toray Ind Inc | Cut pile fabric and its production |
DE10012308A1 (en) * | 2000-03-14 | 2001-09-27 | Fraunhofer Ges Forschung | Inorganic hollow fibers |
JP2002339147A (en) * | 2001-05-11 | 2002-11-27 | Toray Ind Inc | Spinneret |
CN203583036U (en) * | 2013-11-14 | 2014-05-07 | 浙江益南纤维科技有限公司 | Spinneret plate for three-leaf bright yarn |
WO2014196642A1 (en) * | 2013-06-06 | 2014-12-11 | 株式会社カネカ | Fiber for artificial hair, and head decoration article including same |
CN104389036A (en) * | 2014-12-16 | 2015-03-04 | 江苏省科学技术情报研究所 | Preparation method of six-leaf porous hollow staple fibers spun from renewable polyester bottle flakes |
CN105297158A (en) * | 2015-11-04 | 2016-02-03 | 马忠华 | Perspiration type polyester staple fiber |
CN109763185A (en) * | 2018-12-14 | 2019-05-17 | 王惟正 | One kind is for cigarette cooling filter hollow acid fiber by polylactic of section and preparation method thereof |
CN211367831U (en) * | 2019-09-01 | 2020-08-28 | 安徽同光邦飞生物科技有限公司 | Spinneret plate and cigarette tow prepared by using same |
-
2019
- 2019-09-01 CN CN201910820357.7A patent/CN110438576A/en active Pending
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0186293A2 (en) * | 1984-11-16 | 1986-07-02 | Teijin Limited | Blood treatment device |
US5263845A (en) * | 1992-10-27 | 1993-11-23 | Basf Corporation | Spinnerette plate for the manufacture of multilobal fibers with projections on each lobe |
JPH07258915A (en) * | 1994-03-14 | 1995-10-09 | Kanegafuchi Chem Ind Co Ltd | Porous polysulfone hollow yarn |
JPH0874142A (en) * | 1994-06-20 | 1996-03-19 | Toray Ind Inc | Cut pile fabric and its production |
DE10012308A1 (en) * | 2000-03-14 | 2001-09-27 | Fraunhofer Ges Forschung | Inorganic hollow fibers |
JP2002339147A (en) * | 2001-05-11 | 2002-11-27 | Toray Ind Inc | Spinneret |
WO2014196642A1 (en) * | 2013-06-06 | 2014-12-11 | 株式会社カネカ | Fiber for artificial hair, and head decoration article including same |
CN203583036U (en) * | 2013-11-14 | 2014-05-07 | 浙江益南纤维科技有限公司 | Spinneret plate for three-leaf bright yarn |
CN104389036A (en) * | 2014-12-16 | 2015-03-04 | 江苏省科学技术情报研究所 | Preparation method of six-leaf porous hollow staple fibers spun from renewable polyester bottle flakes |
CN105297158A (en) * | 2015-11-04 | 2016-02-03 | 马忠华 | Perspiration type polyester staple fiber |
CN109763185A (en) * | 2018-12-14 | 2019-05-17 | 王惟正 | One kind is for cigarette cooling filter hollow acid fiber by polylactic of section and preparation method thereof |
CN211367831U (en) * | 2019-09-01 | 2020-08-28 | 安徽同光邦飞生物科技有限公司 | Spinneret plate and cigarette tow prepared by using same |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111118636A (en) * | 2019-12-29 | 2020-05-08 | 江苏恒力化纤股份有限公司 | Preparation method of toy filler |
CN111118636B (en) * | 2019-12-29 | 2022-03-18 | 江苏恒力化纤股份有限公司 | Preparation method of toy filler |
CN114905726A (en) * | 2022-05-13 | 2022-08-16 | 青岛正沃机械设备科技有限公司 | Ring winding production device |
CN114905726B (en) * | 2022-05-13 | 2024-05-17 | 青岛正沃机械设备科技有限公司 | Winding ring production device |
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Application publication date: 20191112 |