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CN110410787A - A hydrogen water vapor oxygen-enriched flameless burner - Google Patents

A hydrogen water vapor oxygen-enriched flameless burner Download PDF

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Publication number
CN110410787A
CN110410787A CN201910666886.6A CN201910666886A CN110410787A CN 110410787 A CN110410787 A CN 110410787A CN 201910666886 A CN201910666886 A CN 201910666886A CN 110410787 A CN110410787 A CN 110410787A
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hydrogen
oxygen
vapor
combustion chamber
jet pipe
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CN110410787B (en
Inventor
李鹏飞
邹远龙
李文浩
张萌杰
周博斐
李颖
柳朝晖
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Wuhan Dingbofeng Intelligent Technology Co ltd
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Huazhong University of Science and Technology
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D14/00Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
    • F23D14/02Premix gas burners, i.e. in which gaseous fuel is mixed with combustion air upstream of the combustion zone
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D14/00Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
    • F23D14/46Details, e.g. noise reduction means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D14/00Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
    • F23D14/46Details, e.g. noise reduction means
    • F23D14/48Nozzles
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D14/00Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
    • F23D14/46Details, e.g. noise reduction means
    • F23D14/62Mixing devices; Mixing tubes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/06Arrangements of devices for treating smoke or fumes of coolers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L9/00Passages or apertures for delivering secondary air for completing combustion of fuel 
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/34Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)

Abstract

本发明属于无焰燃烧器领域,并具体公开了一种氢气水蒸气富氧无焰燃烧器,其中氢气喷管与燃烧室连接;第一水蒸气喷管套设在氢气喷管的外侧,并与燃烧室连接,用于在预热阶段向燃烧室喷射水蒸气;一次风喷管套设在第一水蒸气喷管的外侧,并与燃烧室连接,用于在预热阶段向燃烧室喷射一次风;二次风喷管与燃烧室连接,用于在无焰燃烧阶段向燃烧室喷射二次风;燃烧室用于为氢气进行富氧燃烧提供空间。本发明利用水蒸气将一次风与氢气分隔,能够有效降低氢气的燃烧速率,从而提高燃烧器的安全性,待达到预设温度后,切换为二次风喷管提供氧气以此实现氢气的无焰燃烧,能够保证燃烧器内的温度分布较为均匀,从而避免了氢气燃烧产生的安全隐患。

The invention belongs to the field of flameless burners, and specifically discloses a hydrogen water vapor oxygen-enriched flameless burner, wherein a hydrogen nozzle is connected to a combustion chamber; the first water vapor nozzle is sleeved on the outside of the hydrogen nozzle, and Connected to the combustion chamber, used to inject water vapor into the combustion chamber during the preheating stage; the primary air nozzle is sleeved on the outside of the first steam nozzle, and connected to the combustion chamber, used to inject water vapor into the combustion chamber during the preheating stage The primary air and secondary air nozzles are connected to the combustion chamber for injecting secondary air into the combustion chamber during the flameless combustion stage; the combustion chamber is used to provide space for oxygen-enriched combustion of hydrogen. The invention uses water vapor to separate the primary air from the hydrogen, which can effectively reduce the combustion rate of hydrogen, thereby improving the safety of the burner. After reaching the preset temperature, switch to the secondary air nozzle to provide oxygen to realize the hydrogen without Flame combustion can ensure a relatively uniform temperature distribution in the burner, thus avoiding the safety hazards caused by hydrogen combustion.

Description

一种氢气水蒸气富氧无焰燃烧器A hydrogen water vapor oxygen-enriched flameless burner

技术领域technical field

本发明属于无焰燃烧器领域,更具体地,涉及一种氢气水蒸气富氧无焰燃烧器。The invention belongs to the field of flameless burners, and more specifically relates to a hydrogen-water vapor oxygen-enriched flameless burner.

背景技术Background technique

近年来,随着人类对化石能源的快速消费,环境问题日趋严重,其中化石能源燃烧产生的氮氧化物是形成酸雨和PM2.5的主要原因之一,同时化石燃料燃烧产生的CO2也会加剧温室气体效应,对环境造成极大的影响。氢气作为一种新型燃料因其具有诸多优点而备受关注,例如氢气因燃烧热值高,故燃烧氢气产生的能量较高;氢气燃烧之后的产物只有水,因此氢气燃烧具有清洁无污染的特点;此外,氢气可以直接由水获得,可以循环使用。然而,氢气燃烧也有难以克服的缺点:氢气热值高,相应的燃烧温度高,导致伴随着氢气燃烧的氮氧化物(NOx)排放也较高;氢气的燃烧速率极快又极易爆炸,所以氢气燃烧的安全隐患也限制了氢气的大规模使用。In recent years, with the rapid consumption of fossil energy by human beings, environmental problems have become increasingly serious. Nitrogen oxides produced by fossil energy combustion are one of the main causes of acid rain and PM2.5. At the same time, CO 2 produced by fossil fuel combustion will also Exacerbate the greenhouse gas effect and have a great impact on the environment. As a new type of fuel, hydrogen has attracted much attention because of its many advantages. For example, because hydrogen has a high combustion calorific value, the energy generated by burning hydrogen is relatively high; the product after hydrogen combustion is only water, so hydrogen combustion is clean and pollution-free. ; In addition, hydrogen can be obtained directly from water and can be recycled. However, hydrogen combustion also has insurmountable disadvantages: the high calorific value of hydrogen, and the corresponding high combustion temperature, resulting in high emissions of nitrogen oxides (NOx) accompanying hydrogen combustion; the combustion rate of hydrogen is extremely fast and easy to explode, so The safety hazard of hydrogen combustion also limits the large-scale use of hydrogen.

此外,寻找一种新的燃烧技术也是降低污染物排放的另一条途径,富氧燃烧和无焰燃烧近年来受到持续关注,传统富氧燃烧是以二氧化碳代替氮气稀释氧气,使得烟气中含有大量的二氧化碳,从而有利于对二氧化碳的捕集和封存,同时二氧化碳相对于氮气具有更高的热容,因此燃烧温度相对较低,进而NOx的排放量会在一定程度上降低。无焰燃烧作为一种新兴技术具有如下优点:反应速率低、局部释热少、热流分布均匀、燃烧温度低且分布均匀、无火焰锋面、噪音极小,且NOx排放极低。富氧燃烧和无焰燃烧结合起来的技术被称为富氧无焰燃烧技术,该技术综合了富氧燃烧和无焰燃烧的优点,能够更大程度的降低氮氧化物的排放。In addition, finding a new combustion technology is another way to reduce pollutant emissions. Oxygen-enriched combustion and flameless combustion have received continuous attention in recent years. Traditional oxy-enriched combustion uses carbon dioxide instead of nitrogen to dilute oxygen, making the flue gas contain a large amount of carbon dioxide, which is beneficial to the capture and storage of carbon dioxide, and carbon dioxide has a higher heat capacity than nitrogen, so the combustion temperature is relatively low, and NOx emissions will be reduced to a certain extent. As an emerging technology, flameless combustion has the following advantages: low reaction rate, less local heat release, uniform heat flow distribution, low and uniform combustion temperature, no flame front, minimal noise, and extremely low NOx emissions. The technology that combines oxygen-enriched combustion and flameless combustion is called oxygen-enriched flameless combustion technology. This technology combines the advantages of oxygen-enriched combustion and flameless combustion, and can reduce the emission of nitrogen oxides to a greater extent.

目前对无焰燃烧技术的研究已取得较大进展,例如CN201310624080.3提出了一种煤粉富氧无焰燃烧方法及其系统,该发明在富氧燃烧富集二氧化碳的基础上通过无焰燃烧提高其稳定性、燃尽率和辐射换热;CN201410528106.9提出了一种富氧燃气无焰燃烧器,该发明可将无焰燃烧和富氧燃烧有机结合,实现了无焰燃烧,优化了炉内温度分布同时降低了NOx排放。然而,目前现有的富氧燃烧器均是以二氧化碳作为氧化剂稀释剂,而针对氢气燃料采用水蒸气作为稀释剂可以获得高纯度的水蒸气烟气,利于烟气捕水和降低NOx生成;同时,对于氢气这种燃烧速率极快的燃料,目前还没有相关无焰燃烧器的发明专利,这使得氢气这种清洁能源的利用受到一定限制。At present, the research on flameless combustion technology has made great progress. For example, CN201310624080.3 proposes a method and system for pulverized coal oxygen-enriched flameless combustion. Improve its stability, burnout rate and radiation heat transfer; CN201410528106.9 proposes an oxygen-enriched gas flameless burner, which can organically combine flameless combustion and oxygen-enriched combustion to realize flameless combustion and optimize The temperature distribution in the furnace also reduces NOx emissions. However, the existing oxygen-enriched burners all use carbon dioxide as the oxidant diluent, while using water vapor as the diluent for hydrogen fuel can obtain high-purity water vapor flue gas, which is beneficial to trapping water in the flue gas and reducing NOx formation; at the same time However, for hydrogen, a fuel with an extremely fast combustion rate, there is currently no invention patent for a flameless burner, which limits the utilization of hydrogen, a clean energy source.

发明内容Contents of the invention

针对现有技术的以上缺陷或改进需求,本发明提供了一种氢气水蒸气富氧无焰燃烧器,其中结合富氧燃烧和无焰燃烧自身的特征,对其关键组件如第一水蒸气喷管、一次风喷管和二次风喷管的结构及其具体设置方式进行研究和设计,相应的可实现氢气的富氧无焰燃烧,并有效解决燃料燃烧过程产生大量氮氧化物的问题,且能直接实现烟气捕水,因而尤其适用于氢气燃烧的应用场合。Aiming at the above defects or improvement needs of the prior art, the present invention provides a hydrogen-water vapor oxygen-enriched flameless burner, which combines the characteristics of oxygen-enriched combustion and flameless combustion itself, and its key components such as the first water vapor injection The structure and specific arrangement of the pipe, the primary air nozzle and the secondary air nozzle are researched and designed, which can realize the oxygen-enriched flameless combustion of hydrogen and effectively solve the problem of a large amount of nitrogen oxides produced during the fuel combustion process. And it can directly realize the water capture of flue gas, so it is especially suitable for the application of hydrogen combustion.

为实现上述目的,本发明提出了一种氢气水蒸气富氧无焰燃烧器,包括氢气喷管、第一水蒸气喷管、一次风喷管、二次风喷管、第一保温管道、第二保温管道和燃烧室,其中:In order to achieve the above object, the present invention proposes a hydrogen water vapor oxygen-enriched flameless burner, comprising a hydrogen nozzle, a first water vapor nozzle, a primary air nozzle, a secondary air nozzle, a first heat preservation pipe, a second 2. Insulated pipes and combustion chambers, of which:

所述氢气喷管与所述燃烧室连接,用于向所述燃烧室喷射氢气;The hydrogen nozzle is connected to the combustion chamber for injecting hydrogen into the combustion chamber;

所述第一水蒸气喷管套设在所述氢气喷管的外侧,并与所述燃烧室连接,用于在预热阶段向所述燃烧室喷射水蒸气,进而降低所述氢气的燃烧速率;所述一次风喷管套设在所述第一水蒸气喷管的外侧,并与所述燃烧室连接,用于在预热阶段向所述燃烧室喷射水蒸气与氧气的混合气体作为一次风,从而为所述氢气进行富氧有焰燃烧提供氧气;同时所述第一水蒸气喷管和一次风喷管的出口分别沿周向方向均匀布置有第一旋流叶片和第二旋流叶片,用于带动所述水蒸气和一次风以相同的旋流度沿所述氢气喷管的轴线旋转;The first water vapor nozzle is sleeved on the outside of the hydrogen nozzle and connected to the combustion chamber for injecting water vapor into the combustion chamber during the preheating stage, thereby reducing the combustion rate of the hydrogen The primary air nozzle is sleeved on the outside of the first water vapor nozzle and connected to the combustion chamber for injecting a mixture of water vapor and oxygen into the combustion chamber during the preheating stage as a primary wind, so as to provide oxygen for the oxygen-enriched flaming combustion of the hydrogen; at the same time, the outlets of the first water vapor nozzle and the primary air nozzle are respectively uniformly arranged with first swirl blades and second swirl blades along the circumferential direction blades, used to drive the water vapor and the primary wind to rotate along the axis of the hydrogen nozzle with the same degree of swirl;

所述二次风喷管与所述燃烧室连接,用于在无焰燃烧阶段向所述燃烧室喷射水蒸气与氧气的混合气体作为二次风,从而为所述氢气进行富氧无焰燃烧提供氧气;The secondary air nozzle is connected to the combustion chamber, and is used to inject a mixture of water vapor and oxygen into the combustion chamber as secondary air during the flameless combustion stage, so as to perform oxygen-enriched flameless combustion for the hydrogen provide oxygen;

所述第一保温管道套设在所述氢气喷管、第一水蒸气喷管和一次风喷管的外侧,用于预热所述氢气、水蒸气和一次风,同时避免所述水蒸气发生冷凝;所述第二保温管道套设在所述二次风喷管的外侧,用于预热所述二次风;The first insulation pipe is sleeved on the outside of the hydrogen nozzle, the first water vapor nozzle and the primary air nozzle to preheat the hydrogen, water vapor and primary air while avoiding the occurrence of the water vapor Condensation; the second thermal insulation pipe is sleeved on the outside of the secondary air nozzle for preheating the secondary air;

所述燃烧室用于为所述氢气进行富氧燃烧提供空间。The combustion chamber is used to provide a space for the oxygen-enriched combustion of the hydrogen.

作为进一步优选地,所述氢气喷管的进口设置有防回火腔,用于稳定所述氢气的进气压力,从而保证燃烧过程的安全性,所述防回火腔的数量为1个~3个。As a further preference, the inlet of the hydrogen nozzle is provided with an anti-temper chamber, which is used to stabilize the intake pressure of the hydrogen, thereby ensuring the safety of the combustion process, and the number of the anti-temper chamber is 1- 3.

作为进一步优选地,所述氢气水蒸气富氧无焰燃烧器还包括第二水蒸气管道,所述第二水蒸气管道与二次风喷管连接,用于将烟气中的水蒸气通入所述二次风中,进而稀释所述二次风中氧气的浓度。As further preferably, the hydrogen water vapor oxygen-enriched flameless burner also includes a second water vapor pipeline, which is connected with the secondary air nozzle for passing the water vapor in the flue gas into the In the secondary air, the concentration of oxygen in the secondary air is further diluted.

作为进一步优选地,将燃烧产生的烟气通入所述第一保温管道和第二保温管道中,从而实现所述烟气的余热回收利用。As a further preference, the flue gas produced by combustion is passed into the first heat preservation pipe and the second heat preservation pipe, so as to realize waste heat recovery and utilization of the flue gas.

作为进一步优选地,所述水蒸气和一次风的旋流度优选为0.7~0.9。As a further preference, the swirl degree of the water vapor and the primary air is preferably 0.7-0.9.

作为进一步优选地,所述一次风喷管的直径为所述氢气喷管直径的1.5倍~3倍,所述二次风喷管的直径为所述氢气喷管直径的1倍~5倍。As a further preference, the diameter of the primary air nozzle is 1.5 to 3 times the diameter of the hydrogen nozzle, and the diameter of the secondary air nozzle is 1 to 5 times the diameter of the hydrogen nozzle.

作为进一步优选地,所述一次风和二次风中氧气的浓度优选为10%~50%,无焰燃烧阶段,所述燃烧室中氧气的浓度优选为2%~10%。As a further preference, the oxygen concentration in the primary air and the secondary air is preferably 10%-50%, and in the flameless combustion stage, the oxygen concentration in the combustion chamber is preferably 2%-10%.

作为进一步优选地,所述燃烧室内设置有喷水减温管,用于向所述燃烧室内喷水,从而降低局部高温区的温度。As a further preference, a water spraying desuperheating pipe is provided in the combustion chamber for spraying water into the combustion chamber, thereby reducing the temperature of a local high temperature area.

作为进一步优选地,所述氢气水蒸气富氧无焰燃烧器还包括设置在所述燃烧室内的钝体,所述钝体内设置有冷却水管道,用于降低所述钝体的温度,预热阶段,所述钝体位于所述氢气喷管的出口,用于形成稳定火焰,无焰燃烧阶段,所述钝体贴紧所述燃烧室内壁,从而实现无焰燃烧。As a further preference, the hydrogen water vapor oxygen-enriched flameless burner also includes a blunt body arranged in the combustion chamber, and a cooling water pipeline is arranged in the blunt body for reducing the temperature of the blunt body and preheating stage, the blunt body is located at the outlet of the hydrogen nozzle to form a stable flame, and in the flameless combustion stage, the blunt body is close to the inner wall of the combustion chamber, thereby realizing flameless combustion.

作为进一步优选地,所述二次风喷管的出口设置有1~5个喷口,通过改变所述喷口的数量调节所述二次风喷管的出口流速。As a further preference, the outlet of the secondary air nozzle is provided with 1 to 5 nozzles, and the outlet flow rate of the secondary air nozzle is adjusted by changing the number of nozzles.

总体而言,通过本发明所构思的以上技术方案与现有技术相比,主要具备以下的技术优点:Generally speaking, compared with the prior art, the above technical solution conceived by the present invention mainly has the following technical advantages:

1.本发明通过在氢气喷管外侧依次套设第一水蒸气喷管和一次风喷管,能够在预热阶段实现氢气的有焰燃烧,同时利用水蒸气将一次风与氢气分隔,能够有效降低氢气的燃烧速率,从而提高燃烧器的安全性,待达到预设温度后,切换为二次风喷管提供氧气以此实现氢气的无焰燃烧,能够保证燃烧器内的温度分布较为均匀,从而避免了氢气燃烧产生的安全隐患,同时本发明利用水蒸气稀释氧气,使得燃烧产生的烟气主要为水,因而有利于进行捕集再利用,实现近零排放;1. The present invention can realize the flaming combustion of hydrogen in the preheating stage by sequentially setting the first water vapor nozzle and the primary air nozzle on the outside of the hydrogen nozzle, and simultaneously utilize water vapor to separate the primary air from the hydrogen, which can effectively Reduce the combustion rate of hydrogen, thereby improving the safety of the burner. After reaching the preset temperature, switch to the secondary air nozzle to provide oxygen to achieve flameless combustion of hydrogen, which can ensure a relatively uniform temperature distribution in the burner. Thereby, the potential safety hazard caused by hydrogen combustion is avoided. At the same time, the present invention uses water vapor to dilute oxygen, so that the flue gas generated by combustion is mainly water, which is beneficial to capture and reuse, and realizes near-zero emissions;

2.尤其是,本发明通过优化一次风喷管和二次风喷管的直径,能够保证有焰燃烧的安全性和无焰燃烧的均匀性;2. In particular, the present invention can ensure the safety of flaming combustion and the uniformity of flameless combustion by optimizing the diameters of the primary air nozzle and the secondary air nozzle;

3.同时,针对氢气燃烧速率过快、容易发生爆炸的特点,本发明通过控制一次风和二次风中氧气的浓度,并优化燃烧室内的氧气浓度,能够有效控制氢气的燃烧速率,同时本发明在氢气喷管的进口设置防回火腔,能够稳定氢气的进气压力,避免因回火造成爆炸,此外本发明在燃烧室内设置减温管,能够有效降低局部高温区的温度,保证燃烧室内温度分布较为均匀。3. At the same time, aiming at the characteristics of the hydrogen combustion rate being too fast and prone to explosion, the present invention can effectively control the combustion rate of hydrogen by controlling the concentration of oxygen in the primary air and secondary air and optimizing the oxygen concentration in the combustion chamber. The invention sets up an anti-tempering chamber at the inlet of the hydrogen nozzle, which can stabilize the intake pressure of hydrogen and avoid explosions caused by tempering. In addition, the invention sets a desuperheating tube in the combustion chamber, which can effectively reduce the temperature in the local high-temperature area and ensure combustion. The indoor temperature distribution is relatively uniform.

附图说明Description of drawings

图1是按照本发明优选实施例构建的氢气水蒸气富氧无焰燃烧器的剖视图;Fig. 1 is the cross-sectional view of the hydrogen water vapor oxygen-enriched flameless burner constructed according to the preferred embodiment of the present invention;

图2是图1中A-A面的剖视图;Fig. 2 is the sectional view of A-A plane among Fig. 1;

图3是利用本发明提供的氢气水蒸气富氧无焰燃烧器构建的燃烧系统示意图。Fig. 3 is a schematic diagram of a combustion system constructed using the hydrogen-water vapor oxygen-enriched flameless burner provided by the present invention.

在所有附图中,相同的附图标记用来表示相同的元件或结构,其中:Throughout the drawings, the same reference numerals are used to designate the same elements or structures, wherein:

1-氢气喷管,2-一次风喷管,3-二次风喷管,4-第一保温管道,5-第一水蒸气喷管,6-钝体,7-第一旋流叶片,7’-第二旋流叶片,8-喷水减温管,9-第二保温管道,10-第二水蒸气喷管,11-燃烧室,12-防回火腔,13-氢气水蒸气富氧无焰燃烧器,14-氧气流量计,15-氧气瓶,16-氢气流量计,17-氢气瓶,18-第三增压风机,19-第一增压风机,20-捕水箱,21-氢气管路,22-第一氧气进气管路,23-二次风进气管路,24-第一水蒸气进气管路,25-第三水蒸气进气管路,26-第二水蒸气进气管路,27-烟气循环管路,28-一次风进气管路,29-第二氧气进气管路,30-烟气管路,31-捕水管路,32-第二增压风机。1-hydrogen nozzle, 2-primary air nozzle, 3-secondary air nozzle, 4-first heat preservation pipe, 5-first water vapor nozzle, 6-blunt body, 7-first swirl blade, 7'-the second swirl vane, 8-the water spray desuperheating pipe, 9-the second heat preservation pipe, 10-the second water vapor nozzle, 11-combustion chamber, 12-anti-temper chamber, 13-hydrogen water vapor Oxygen-enriched flameless burner, 14-Oxygen flow meter, 15-Oxygen cylinder, 16-Hydrogen gas flowmeter, 17-Hydrogen gas cylinder, 18-The third booster fan, 19-The first booster fan, 20-Water catcher, 21-Hydrogen pipeline, 22-First oxygen intake pipeline, 23-Secondary air intake pipeline, 24-First water vapor intake pipeline, 25-Third water vapor intake pipeline, 26-Second water vapor Intake pipeline, 27-flue gas circulation pipeline, 28-primary air intake pipeline, 29-second oxygen intake pipeline, 30-flue gas pipeline, 31-water catch pipeline, 32-second booster fan.

具体实施方式Detailed ways

为了使本发明的目的、技术方案及优点更加清楚明白,以下结合附图及实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。此外,下面所描述的本发明各个实施方式中所涉及到的技术特征只要彼此之间未构成冲突就可以相互组合。In order to make the object, technical solution and advantages of the present invention more clear, the present invention will be further described in detail below in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described here are only used to explain the present invention, not to limit the present invention. In addition, the technical features involved in the various embodiments of the present invention described below can be combined with each other as long as they do not constitute a conflict with each other.

如图1~2所示,本发明优选实施例提供了一种氢气水蒸气富氧无焰燃烧器,包括氢气喷管1、第一水蒸气喷管5、一次风喷管2、二次风喷管3、第二水蒸气管道10、第一保温管道4、第二保温管道9和燃烧室11,其中:As shown in Figures 1 to 2, a preferred embodiment of the present invention provides a hydrogen water vapor oxygen-enriched flameless burner, including a hydrogen nozzle 1, a first water vapor nozzle 5, a primary air nozzle 2, a secondary air Nozzle 3, the second water vapor pipeline 10, the first insulation pipeline 4, the second insulation pipeline 9 and the combustion chamber 11, wherein:

氢气喷管1与燃烧室11连接,用于向燃烧室11喷射氢气,氢气喷管1的进口设置有防回火腔12,用于稳定氢气的进气压力,并防止回火现象的发生,从而保证燃烧过程的安全性,防回火腔12的数量为1个~3个;The hydrogen nozzle 1 is connected to the combustion chamber 11 for injecting hydrogen into the combustion chamber 11. The inlet of the hydrogen nozzle 1 is provided with an anti-temper chamber 12 for stabilizing the intake pressure of hydrogen and preventing the occurrence of tempering. In order to ensure the safety of the combustion process, the number of anti-tempering chambers 12 is 1 to 3;

第一水蒸气喷管5套设在氢气喷管1的外侧,并与燃烧室11连接,用于在预热阶段向燃烧室11喷射水蒸气,从而降低氢气的燃烧速率,第一水蒸气喷管5的出口沿周向方向均匀布置有第一旋流叶片7,用于带动水蒸气沿氢气喷管1的轴线进行旋转;The first water vapor nozzle 5 is sleeved on the outside of the hydrogen nozzle 1 and connected to the combustion chamber 11 for injecting water vapor into the combustion chamber 11 during the preheating stage, thereby reducing the combustion rate of hydrogen. The outlet of the tube 5 is evenly arranged with first swirl blades 7 along the circumferential direction, which are used to drive the water vapor to rotate along the axis of the hydrogen nozzle 1;

一次风喷管2套设在第一水蒸气喷管5的外侧,并与燃烧室11连接,用于在预热阶段向燃烧室11喷射水蒸气与氧气的混合气体作为一次风,从而为氢气进行富氧有焰燃烧提供氧气,一次风喷管2的出口沿周向方向均匀布置有第二旋流叶片7’,用于带动一次风沿氢气喷管1的轴线进行旋转,以在预热阶段产生旋流有焰火焰,从而预热燃烧室11;The primary air nozzle 2 is sleeved on the outside of the first water vapor nozzle 5 and is connected to the combustion chamber 11 for injecting a mixture of water vapor and oxygen into the combustion chamber 11 during the preheating stage as the primary air to generate hydrogen gas. Oxygen-enriched flaming combustion is carried out to provide oxygen, and the outlet of the primary air nozzle 2 is evenly arranged with second swirl blades 7' along the circumferential direction, which are used to drive the primary air to rotate along the axis of the hydrogen nozzle 1 to preheat stage produces a swirling flaming flame, thereby preheating the combustion chamber 11;

二次风喷管3与燃烧室11连接,用于在无焰燃烧阶段向燃烧室11喷射水蒸气与氧气的混合气体作为二次风,从而为氢气进行富氧无焰燃烧提供氧气,二次风喷管3的出口设置有1~5个喷口,通过改变喷口的数量调节二次风喷管3的出口流速,图2是喷口数量为5个的分布示意图;The secondary air nozzle 3 is connected to the combustion chamber 11, and is used to inject a mixture of water vapor and oxygen into the combustion chamber 11 as secondary air during the flameless combustion stage, so as to provide oxygen for the oxygen-enriched flameless combustion of hydrogen. The outlet of the air nozzle 3 is provided with 1 to 5 nozzles, and the outlet flow rate of the secondary air nozzle 3 is adjusted by changing the number of nozzles. Fig. 2 is a schematic diagram showing the distribution of 5 nozzles;

第二水蒸气管道10与二次风喷管3连接,用于将烟气中的水蒸气通入二次风中,进而稀释二次风中氧气的浓度;The second water vapor pipeline 10 is connected with the secondary air nozzle 3, and is used to pass the water vapor in the flue gas into the secondary air, thereby diluting the concentration of oxygen in the secondary air;

第一保温管道4套设在氢气喷管1、第一水蒸气喷管5和一次风喷管2的外侧,用于预热氢气、水蒸气和一次风,同时避免水蒸气发生冷凝,第二保温管道9套设在二次风喷管3和第二水蒸气喷管10的外侧,用于预热二次风和水蒸气,同时避免水蒸气发生冷凝,将燃烧产生的烟气通入第一保温管道和第二保温管道中,从而实现烟气的余热回收利用;The first thermal insulation pipe 4 is set on the outside of the hydrogen nozzle 1, the first water vapor nozzle 5 and the primary air nozzle 2, and is used to preheat the hydrogen, water vapor and primary air while avoiding condensation of the water vapor. The thermal insulation pipe 9 is set on the outside of the secondary air nozzle 3 and the second water vapor nozzle 10 to preheat the secondary air and water vapor while avoiding the condensation of the water vapor and passing the flue gas generated by combustion into the first In the first insulation pipeline and the second insulation pipeline, so as to realize the waste heat recovery and utilization of flue gas;

燃烧室11为氢气进行富氧燃烧提供空间,燃烧室11内设置有喷水减温管8,用于向燃烧室11内喷水,从而降低局部高温区的温度,以减少氢气燃烧过程中NOx的生成。Combustion chamber 11 provides a space for oxygen-enriched combustion of hydrogen, and a water spray desuperheating pipe 8 is arranged in combustion chamber 11, which is used to spray water into combustion chamber 11, thereby reducing the temperature of local high temperature area, so as to reduce NOx in the process of hydrogen combustion generation.

进一步,水蒸气和一次风以相同的旋流度沿氢气喷管的轴线旋转,能够推迟氢气与氧气的混合,从而实现氢气清洁中温燃烧,同时水蒸气和一次风的旋流度优选为0.7~0.9,能够在预热阶段产生旋流有焰燃烧,以进行燃烧室预热,同时还能够延迟氢气与氧气的混合,降低燃烧速率与火焰温度。Further, water vapor and primary air rotate along the axis of the hydrogen nozzle with the same swirl degree, which can delay the mixing of hydrogen and oxygen, thereby realizing clean and medium-temperature combustion of hydrogen gas. At the same time, the swirl degree of water vapor and primary air is preferably 0.7- 0.9, it can produce swirling flame combustion in the preheating stage to preheat the combustion chamber, and at the same time, it can delay the mixing of hydrogen and oxygen, reduce the combustion rate and flame temperature.

进一步,一次风喷管2的直径为氢气喷管1直径的1.5倍~3倍,以此使得一次风进气速度接近氢气进气速度,并在进入燃烧室后与氢气充分混合实现旋流燃烧;二次风喷管3的直径为氢气喷管1直径的1倍~5倍,同时保证二次风中的氧化剂能够充分被水蒸气稀释并且其速度达到50m/s~150m/s,从而使得二次风进入燃烧室后能够大量卷吸烟气,以实现水蒸气富氧无焰燃烧。Further, the diameter of the primary air nozzle 2 is 1.5 to 3 times the diameter of the hydrogen nozzle 1, so that the primary air intake velocity is close to the hydrogen intake velocity, and after entering the combustion chamber, it is fully mixed with hydrogen to achieve swirling combustion The diameter of the secondary air nozzle 3 is 1 to 5 times the diameter of the hydrogen nozzle 1, while ensuring that the oxidant in the secondary air can be fully diluted by water vapor and its speed reaches 50m/s~150m/s, so that After the secondary air enters the combustion chamber, it can entrain a large amount of smoke to realize the oxygen-enriched flameless combustion of water vapor.

为降低氢气的燃烧速率,从而提高燃烧器的安全性,一次风和二次风中氧气的浓度优选为10%~50%,无焰燃烧阶段,燃烧室11中氧气的浓度优选为2%~10%,从而保证无焰燃烧阶段燃烧室内能够达到均匀低氧氛围,以便于实现水蒸气富氧无焰燃烧。In order to reduce the combustion rate of hydrogen, thereby improving the safety of the burner, the concentration of oxygen in the primary air and secondary air is preferably 10% to 50%, and in the flameless combustion stage, the concentration of oxygen in the combustion chamber 11 is preferably 2% to 50%. 10%, so as to ensure that the combustion chamber can achieve a uniform low-oxygen atmosphere in the flameless combustion stage, so as to realize the oxygen-enriched flameless combustion of water vapor.

进一步,氢气水蒸气富氧无焰燃烧器还包括设置在燃烧室11内的钝体6,因氢气燃烧温度较高,钝体6的内部设置有冷却水管道,从而降低其温度,预热阶段,钝体6位于氢气喷管1的出口,用于形成稳定火焰,无焰燃烧阶段,钝体6贴紧燃烧室11内壁,从而实现无焰燃烧。Further, the hydrogen water vapor oxygen-enriched flameless burner also includes a blunt body 6 arranged in the combustion chamber 11. Due to the high combustion temperature of hydrogen, a cooling water pipe is arranged inside the blunt body 6 to reduce its temperature. In the preheating stage , the blunt body 6 is located at the outlet of the hydrogen nozzle 1, and is used to form a stable flame. In the flameless combustion stage, the blunt body 6 is close to the inner wall of the combustion chamber 11, thereby realizing flameless combustion.

利用本发明提供的氢气水蒸气富氧无焰燃烧器构建的燃烧系统如图3所示,其中氢气水蒸气富氧无焰燃烧器13的氢气喷管1与氢气管路21连接,并通过氢气流量计16控制氢气瓶17提供氢气;一次风进气管路28与一次风喷管2连接,用于为其提供一次风,同时一次风进气管路28分别与第一氧气进气管路22和第一水蒸气进气管路24连接,通过氧气和水蒸气混合后获得一次风;二次风进气管路23与二次风喷管3连接,用于为其提供二次风,同时二次风进气管路23分别与第二氧气进气管路29和第二水蒸气进气管路26连接,通过氧气和水蒸气混合获得二次风;氧气瓶15为第一氧气进气管路22和第二氧气进气管路29提供氧气,并通过氧气流量计14监测其流量值;第三水蒸气进气管路25与第一水蒸气喷管5连接,用于向燃烧室11提供水蒸气作为稀释剂;燃烧室11产生的烟气通过烟气管路30和烟气循环管路27进入第一水蒸气进气管路24、第二水蒸气进气管路26和第三水蒸气进气管路25,并由第一增压风机19、和第二增压风机32和第三增压风机18进行增压从而为燃烧室11提供水蒸气,而燃烧室11内剩余的烟气通过捕水管路31进入捕水箱20进行捕水。Utilize the combustion system that the hydrogen water vapor oxygen-enriched flameless burner provided by the present invention is constructed as shown in Figure 3, wherein the hydrogen nozzle 1 of the hydrogen water vapor oxygen-enriched flameless burner 13 is connected with the hydrogen pipeline 21, and passes hydrogen The flow meter 16 controls the hydrogen cylinder 17 to provide hydrogen; the primary air intake pipeline 28 is connected with the primary air nozzle 2 for providing primary air, while the primary air intake pipeline 28 is connected with the first oxygen intake pipeline 22 and the first oxygen intake pipeline 22 respectively. A water vapor intake pipeline 24 is connected to obtain the primary air after mixing oxygen and water vapor; the secondary air intake pipeline 23 is connected to the secondary air nozzle 3 to provide secondary air for it, while the secondary air enters The air pipeline 23 is connected with the second oxygen intake pipeline 29 and the second water vapor intake pipeline 26 respectively, and obtains secondary air by mixing oxygen and water vapor; the oxygen bottle 15 is the first oxygen intake pipeline 22 and the second oxygen intake pipeline. Gas line 29 provides oxygen, and monitors its flow value by oxygen flow meter 14; The third water vapor inlet line 25 is connected with the first water vapor nozzle 5, and is used to provide water vapor as diluent to combustion chamber 11; Combustion chamber 11, the flue gas produced enters the first water vapor intake pipeline 24, the second water vapor intake pipeline 26 and the third water vapor intake pipeline 25 through the flue gas pipeline 30 and the flue gas circulation pipeline 27, and is fed by the first The booster fan 19, the second booster fan 32 and the third booster fan 18 are pressurized to provide water vapor for the combustion chamber 11, and the remaining flue gas in the combustion chamber 11 enters the water catcher 20 through the water catcher pipeline 31 to carry out catch water.

下面对本发明提供的氢气水蒸气富氧无焰燃烧器的具体工作过程作进一步说明。The specific working process of the hydrogen-water vapor oxygen-enriched flameless burner provided by the present invention will be further described below.

预热阶段,分别向氢气喷管1、第一水蒸气喷管5、一次风喷管2内通入氢气、水蒸气和一次风,同时将钝体6靠近氢气喷管1的出口,水蒸气和一次风以旋流的方式进入燃烧室11内,与氢气快速燃烧并在钝体6形成稳定火焰,待燃烧室11的温度高于氢气自燃点后,逐渐减少第一水蒸气喷管5和一次风喷管2中的流量直至关闭,并逐渐增大第二水蒸气喷管10和二次风喷管3中的流量直至达到预设目标,同时将钝体6远离氢气喷管1的出口使其靠近燃烧器11的壁面,二次风经过喷口高速喷出后进入燃烧室11,卷吸大量烟气并与氢气混合从而实现无焰燃烧,燃烧过程中产生的烟气具有较高热量,因此可以通入第一保温管道4和第二保温管道9中,用于预热水蒸气、一次风和二次风,同时因烟气中的主要成分为水蒸气,故可将烟气通入第一水蒸气喷管5、第二水蒸气喷管10中,还可将烟气与氧气混合获得一次风和二次风,从而实现烟气中水蒸气的富集,最后利用捕水箱20将烟气中的水进行捕集。In the preheating stage, hydrogen, water vapor and primary air are respectively introduced into the hydrogen nozzle 1, the first water vapor nozzle 5, and the primary air nozzle 2, and the blunt body 6 is placed close to the outlet of the hydrogen nozzle 1, and the water vapor And the primary wind enters the combustion chamber 11 in the form of swirling flow, burns rapidly with the hydrogen and forms a stable flame at the blunt body 6, after the temperature of the combustion chamber 11 is higher than the hydrogen self-ignition point, gradually reduce the first water vapor nozzle 5 and The flow in the primary air nozzle 2 is until closed, and the flow in the second steam nozzle 10 and the secondary air nozzle 3 is gradually increased until reaching the preset target, while the blunt body 6 is kept away from the outlet of the hydrogen nozzle 1 Make it close to the wall of the burner 11, the secondary air is jetted out at high speed through the nozzle and then enters the combustion chamber 11, entraining a large amount of smoke and mixing it with hydrogen to achieve flameless combustion. The smoke generated during the combustion process has high heat, Therefore, it can be passed into the first thermal insulation pipeline 4 and the second thermal insulation pipeline 9 for preheating hot water vapor, primary air and secondary air. In the first water vapor nozzle 5 and the second water vapor nozzle 10, the flue gas can also be mixed with oxygen to obtain primary air and secondary air, thereby realizing the enrichment of water vapor in the flue gas, and finally using the water catcher 20 to The water in the flue gas is captured.

本领域的技术人员容易理解,以上仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明的保护范围之内。Those skilled in the art can easily understand that the above are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modifications, equivalent replacements and improvements made within the spirit and principles of the present invention should be Included within the protection scope of the present invention.

Claims (10)

1. a kind of oxygen-enriched flameless burner of hydrogen vapor, which is characterized in that including hydrogen jet pipe (1), the first vapor jet pipe (5), First air jet pipe (2), Secondary Air jet pipe (3), the first utilidor (4), the second utilidor (9) and combustion chamber (11), Wherein:
The hydrogen jet pipe (1) connect with the combustion chamber (11), for spraying hydrogen to the combustion chamber (11);
The first vapor jet pipe (5) is set in the outside of the hydrogen jet pipe (1), and connect with the combustion chamber (11), For spraying vapor to the combustion chamber (11) in warm-up phase, and then reduce the burn rate of the hydrogen;It is described primary Wind jet pipe (2) is set in the outside of the first vapor jet pipe (5), and connect with the combustion chamber (11), for preheating Stage sprays the mixed gas of vapor and oxygen as First air, to carry out richness for the hydrogen to the combustion chamber (11) Oxygen flaming combustion provides oxygen;The outlet of the first vapor jet pipe (5) and First air jet pipe (2) simultaneously is circumferentially square respectively To the first swirl vane (7) and the second swirl vane (7 ') has been evenly arranged, for driving the vapor and First air with phase Same eddy flow degree is rotated along the axis of the hydrogen jet pipe (1);
The Secondary Air jet pipe (3) connect with the combustion chamber (11), in the flameless combustion stage to the combustion chamber (11) The mixed gas of vapor and oxygen is sprayed as Secondary Air, so that carrying out oxygen-enriched flameless combustion for the hydrogen provides oxygen;
First utilidor (4) is set in the hydrogen jet pipe (1), the first vapor jet pipe (5) and First air jet pipe (2) Outside, for preheating the hydrogen, vapor and First air, while the vapor being avoided to condense;Described second protects Warm pipeline (9) is set in the outside of the Secondary Air jet pipe (3), for preheating the Secondary Air;
The combustion chamber (11) is used to carry out oxygen-enriched combusting for the hydrogen to provide space.
2. the oxygen-enriched flameless burner of hydrogen vapor as described in claim 1, which is characterized in that the hydrogen jet pipe (1) Import is provided with anti-backfire chamber (12), for stablizing the admission pressure of the hydrogen, thus guarantee the safety of combustion process, institute The quantity for stating anti-backfire chamber (12) is 1~3.
3. the oxygen-enriched flameless burner of hydrogen vapor as claimed in claim 1 or 2, which is characterized in that the hydrogen vapor Oxygen-enriched flameless burner further includes the second vapor pipeline (10), the second vapor pipeline (10) and Secondary Air jet pipe (3) Connection for the vapor in flue gas to be passed through in the Secondary Air, and then dilutes the concentration of oxygen in the Secondary Air.
4. the oxygen-enriched flameless burner of hydrogen vapor as claimed in any one of claims 1 to 3, which is characterized in that produce burning Raw flue gas is passed through in first utilidor (4) and the second utilidor (9), to realize the waste heat recycling of the flue gas It utilizes.
5. the oxygen-enriched flameless burner of hydrogen vapor as described in claim 1, which is characterized in that the vapor and First air Eddy flow degree be preferably 0.7~0.9.
6. the oxygen-enriched flameless burner of hydrogen vapor as described in claim 1, which is characterized in that the First air jet pipe (2) Diameter be 1.5 times~3 times of hydrogen jet pipe (1) diameter, the diameter of the Secondary Air jet pipe (3) is the hydrogen jet pipe (1) 1 times of diameter~5 times.
7. the oxygen-enriched flameless burner of hydrogen vapor as described in claim 1, which is characterized in that the First air and Secondary Air The concentration of middle oxygen is preferably 10%~50%, the flameless combustion stage, and the concentration of oxygen is preferably 2% in the combustion chamber (11) ~10%.
8. the oxygen-enriched flameless burner of hydrogen vapor as described in claim 1, which is characterized in that set in the combustion chamber (11) Spray desuperheating pipe (8) are equipped with, for the water spray into the combustion chamber (11), to reduce the temperature of local high temperature zone.
9. the oxygen-enriched flameless burner of hydrogen vapor as described in claim 1, which is characterized in that the hydrogen vapor is oxygen-enriched Flameless burner further includes the bluff body (6) being arranged in the combustion chamber (11), is provided with cooling water pipe in the bluff body (6) Road, for reducing the temperature of the bluff body (6), warm-up phase, the bluff body (6) is located at the outlet of the hydrogen jet pipe (1), uses Stablize flame, flameless combustion stage in being formed, the bluff body (6) is adjacent to the combustion chamber (11) inner wall, to realize that nonflame fires It burns.
10. the oxygen-enriched flameless burner of hydrogen vapor as described in any one of claims 1 to 9, which is characterized in that described secondary The outlet of wind jet pipe (3) is provided with 1~5 spout, and the quantity by changing the spout adjusts the Secondary Air jet pipe (3) Exit velocity.
CN201910666886.6A 2019-07-23 2019-07-23 Hydrogen and steam oxygen-enriched flameless combustor Active CN110410787B (en)

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CN116060574A (en) * 2023-04-07 2023-05-05 山西金瑞高压环件有限公司 Chamber type natural gas energy-saving emission-reducing forging heating furnace
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