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CN110408247A - A kind of underwater structures spraying repair materials and preparation method thereof - Google Patents

A kind of underwater structures spraying repair materials and preparation method thereof Download PDF

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Publication number
CN110408247A
CN110408247A CN201910740396.6A CN201910740396A CN110408247A CN 110408247 A CN110408247 A CN 110408247A CN 201910740396 A CN201910740396 A CN 201910740396A CN 110408247 A CN110408247 A CN 110408247A
Authority
CN
China
Prior art keywords
repair materials
underwater structures
water
added
ethyl cellulose
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201910740396.6A
Other languages
Chinese (zh)
Inventor
周立涛
张赓
张扬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin Sea Star Underwater Robot Co Ltd
Original Assignee
Tianjin Sea Star Underwater Robot Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin Sea Star Underwater Robot Co Ltd filed Critical Tianjin Sea Star Underwater Robot Co Ltd
Priority to CN201910740396.6A priority Critical patent/CN110408247A/en
Publication of CN110408247A publication Critical patent/CN110408247A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)
  • Paints Or Removers (AREA)
  • Sealing Material Composition (AREA)

Abstract

The present invention relates to repair materials technical fields, and disclose a kind of underwater structures spraying repair materials, in percentage include following component: acrylate 15~20%;Ethyl cellulose 5~10%;Buffer 5~10%;Water-reducing agent 2~5%;Polyurethane grouting liquid 5~15%;Admixture 5~10%;Surfactant 10~20%;Methyl methacrylate 15~20%;Butyl acrylate 3~10%;Super absorbent resin 5~10%;Emulsifier 5~10%;Cyclohexanone and formaldehyde mixture 20~30%;Castor oil 5~10%.The underwater structures spray repair materials and preparation method thereof, can improve its adhesion property under the premise of guaranteeing waterproof performance.

Description

A kind of underwater structures spraying repair materials and preparation method thereof
Technical field
The present invention relates to repair materials technical field, specially a kind of underwater structures spraying repair materials and its preparation side Method.
Background technique
Underwater structures are mounted in the underwater support construction used, and underwater structures need waterproof with higher anti- Corrosive nature, underwater structures are under water using because extraneous factor leads to the surface damage of underwater structures, displacement is kept often Its structure is slight and Corrosion Protection, needs to spray repair materials to be repaired.
Existing spraying repair materials cause the adhesiveness of sprayed on material poor, spraying is repaired to pursue waterproof performance Adhesion strength between material and underwater structures is insufficient, causes spraying repair materials that can not be adhered to underwater structures for a long time On, it needs regularly to spray again, increases cost, and it is slight to increase work.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of underwater structures spraying repair materials and its preparation sides Method has the advantages of adhesion property that can be improved spraying repair materials, and the spraying repair materials solved now on the market are viscous The poor problem of attached performance.
(2) technical solution
For the purpose for realizing the above-mentioned adhesion property that can be improved spraying repair materials, the present invention provides following technical side Case: a kind of underwater structures spraying repair materials, include following component: acrylate 15~20% in percentage;
Ethyl cellulose 5~10%;
Buffer 5~10%;
Water-reducing agent 2~5%;
Polyurethane grouting liquid 5~15%;
Admixture 5~10%;
Surfactant 10~20%;
Methyl methacrylate 15~20%;
Butyl acrylate 3~10%;
Super absorbent resin 5~10%;
Emulsifier 5~10%;
Cyclohexanone and formaldehyde mixture 20~30%;
Castor oil 5~10%.
Preferably, the polyurethane grouting liquid is specially oil soluble polyurethane grouting liquid.
Preferably, the water-reducing agent is polycarboxylate water-reducer, and water-reducing rate is not less than 12%.
Preferably, the admixture be silicon ash, microlith ash, mountain flour and miberal powder mixture.
Preferably, the emulsifier is specially petroleum sulfonate.
Preferably, the surfactant is specially cetyl benzene polyethers sodium sulfonate.
Preferably, comprising the following steps: ethyl cellulose is put into container, the water that temperature is 65-75 DEG C is added, is used Mechanical stirring equipment, which is stirred, makes it at liquid, obtains ethyl cellulose aqueous solution;Successively add to ethyl cellulose aqueous solution Enter acrylate, buffer, water-reducing agent, surfactant and butyl acrylate, is sufficiently stirred using mechanical stirring equipment; Polyurethane grouting liquid is added in being easy, emulsifier is added to polyurethane grouting liquid, is emulsified, is gathered using emulsifying device Urethane emulsion;Ethyl cellulose aqueous solution is mixed with polyurethane emulsion and is quickly stirred, obtains mixed liquor, and to mixing Liquid is rapidly cooled to room temperature;Admixture, methyl methacrylate, super absorbent resin and cyclohexanone are added into mixed liquor It with formaldehyde mixture and is quickly stirred, castor oil is added after stirring 25min, finally obtains spraying repair materials.
(3) beneficial effect
Compared with prior art, the present invention provides a kind of underwater structures spraying repair materials and preparation method thereof, tools It is standby following the utility model has the advantages that
The underwater structures spray repair materials and preparation method thereof, by the acrylate of setting, ethyl cellulose, delay Electuary, water-reducing agent, polyurethane grouting liquid, admixture, surfactant, methyl methacrylate, butyl acrylate, high-hydroscopicity Resin, emulsifier, cyclohexanone and formaldehyde mixture and castor oil, emulsifier, surfactant, acrylate, cyclohexanone and first Aldehyde mixture, methyl methacrylate and butyl acrylate can effectively raise the adhesiveness of spraying repair materials, thus Enable to spray repair materials and be adsorbed on the surfaces of underwater structures for a long time, avoid that spraying repair materials are easy to fall off asks Topic, improving spraying repair materials and using is stability, and buffer, water-reducing agent, castor oil, super absorbent resin and surface are living Property agent can guarantee to spray the waterproof performance of repair materials, this spraying repair materials can mention under the premise of guaranteeing waterproof performance Its high adhesion property.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
A kind of underwater structures spraying repair materials, include following component: acrylate 15~20% in percentage;
Ethyl cellulose 5~10%;
Buffer 5~10%;
Water-reducing agent 2~5%;
Polyurethane grouting liquid 5~15%;
Admixture 5~10%;
Surfactant 10~20%;
Methyl methacrylate 15~20%;
Butyl acrylate 3~10%;
Super absorbent resin 5~10%;
Emulsifier 5~10%;
Cyclohexanone and formaldehyde mixture 20~30%;
Castor oil 5~10%.
Polyurethane grouting liquid is specially oil soluble polyurethane grouting liquid.
Water-reducing agent is polycarboxylate water-reducer, and water-reducing rate is not less than 12%.
Admixture be silicon ash, microlith ash, mountain flour and miberal powder mixture.
Emulsifier is specially petroleum sulfonate, and petroleum sulfonate is petroleum and its fraction is raw material, with sulfonating agent sulfonation, then The manufactured product with alkali neutralization is a kind of super-active agent, can be improved the emulsifying power of polyurethane grouting liquid.
Surfactant is specially cetyl benzene polyethers sodium sulfonate, and cetyl benzene polyethers sodium sulfonate is a kind of water solubility Good anionic surfactant has good wetting, emulsification, dispersion, foam and dirt-removing power in hard water, has preferable Foam performance can be improved the foam performance of spraying repair materials, convenient for spraying repair materials forming.
The following steps are included: ethyl cellulose is put into container, the water that temperature is 65-75 DEG C is added, is stirred using machinery Mixing equipment, which is stirred, makes it at liquid, obtains ethyl cellulose aqueous solution;Propylene is sequentially added to ethyl cellulose aqueous solution Acid esters, buffer, water-reducing agent, surfactant and butyl acrylate, are sufficiently stirred using mechanical stirring equipment;By poly- ammonia Ester grouting liquid is added in easy, and emulsifier is added to polyurethane grouting liquid, is emulsified using emulsifying device, obtains polyurethane cream Change liquid;Ethyl cellulose aqueous solution is mixed with polyurethane emulsion and is quickly stirred, obtains mixed liquor, and carry out to mixed liquor It is quickly cooled to room temperature;Admixture, methyl methacrylate, super absorbent resin and cyclohexanone and formaldehyde are added into mixed liquor Mixture is simultaneously quickly stirred, and castor oil is added after stirring 25min, finally obtains spraying repair materials.
In conclusion underwater structures spraying repair materials and preparation method thereof, emulsifier, surfactant, propylene Acid esters, cyclohexanone and formaldehyde mixture, methyl methacrylate and butyl acrylate can effectively raise spraying and repair material The adhesiveness of material avoids spraying and repairs material to enable to spray the surface that repair materials are adsorbed on underwater structures for a long time Material the problem of being easy to fall off, improves spraying repair materials and uses as stability, and buffer, water-reducing agent, castor oil, high water absorption Property resin and surfactant can guarantee spray repair materials waterproof performance, this spraying repair materials can guarantee waterproof Its adhesion property is improved under the premise of performance.
It should be noted that term " includes ", so that including the process, methods of a series of elements, article or setting Standby includes not only those elements, but also including other elements that are not explicitly listed, or further includes for this process, side Method, article or the intrinsic element of equipment.In the absence of more restrictions, limited by sentence "including a ..." Element, it is not excluded that there is also other identical elements in the process, method, article or apparatus that includes the element.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (7)

1. a kind of underwater structures spray repair materials, which is characterized in that in percentage include following component: acrylate 15 ~20%;
Ethyl cellulose 5~10%;
Buffer 5~10%;
Water-reducing agent 2~5%;
Polyurethane grouting liquid 5~15%;
Admixture 5~10%;
Surfactant 10~20%;
Methyl methacrylate 15~20%;
Butyl acrylate 3~10%;
Super absorbent resin 5~10%;
Emulsifier 5~10%;
Cyclohexanone and formaldehyde mixture 20~30%;
Castor oil 5~10%.
2. a kind of underwater structures according to claim 1 spray repair materials, it is characterised in that: the polyurethane grouting Liquid is specially oil soluble polyurethane grouting liquid.
3. a kind of underwater structures according to claim 1 spray repair materials, it is characterised in that: the water-reducing agent is poly- Carboxylic acid water reducer, water-reducing rate are not less than 12%.
4. a kind of underwater structures according to claim 1 spray repair materials, it is characterised in that: the admixture is Silicon ash, microlith ash, mountain flour and miberal powder mixture.
5. a kind of underwater structures according to claim 1 spray repair materials, it is characterised in that: the emulsifier is specific For petroleum sulfonate.
6. a kind of underwater structures according to claim 1 spray repair materials, it is characterised in that: the surfactant Specially cetyl benzene polyethers sodium sulfonate.
7. a kind of preparation method of underwater structures spraying repair materials, it is characterised in that: the following steps are included: by ethyl cellulose Element is put into container, the water that temperature is 65-75 DEG C is added, being stirred using mechanical stirring equipment makes it at liquid, obtains second Base cellulose aqueous solution;To ethyl cellulose aqueous solution sequentially add acrylate, buffer, water-reducing agent, surfactant and Butyl acrylate is sufficiently stirred using mechanical stirring equipment;Polyurethane grouting liquid is added in being easy, is in the milk to polyurethane Emulsifier is added in liquid, is emulsified using emulsifying device, obtains polyurethane emulsion;By ethyl cellulose aqueous solution and polyurethane Emulsion is mixed and is quickly stirred, and obtains mixed liquor, and be rapidly cooled mixed liquor to room temperature;It is added and mixes into mixed liquor It closes material, methyl methacrylate, super absorbent resin and cyclohexanone and formaldehyde mixture and is quickly stirred, stir 25min After castor oil is added, finally obtain spraying repair materials.
CN201910740396.6A 2019-08-12 2019-08-12 A kind of underwater structures spraying repair materials and preparation method thereof Withdrawn CN110408247A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910740396.6A CN110408247A (en) 2019-08-12 2019-08-12 A kind of underwater structures spraying repair materials and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910740396.6A CN110408247A (en) 2019-08-12 2019-08-12 A kind of underwater structures spraying repair materials and preparation method thereof

Publications (1)

Publication Number Publication Date
CN110408247A true CN110408247A (en) 2019-11-05

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CN201910740396.6A Withdrawn CN110408247A (en) 2019-08-12 2019-08-12 A kind of underwater structures spraying repair materials and preparation method thereof

Country Status (1)

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CN (1) CN110408247A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4855184A (en) * 1988-02-02 1989-08-08 Minnesota Mining And Manufacturing Company Radiation-curable protective coating composition
CN102863192A (en) * 2012-09-08 2013-01-09 芜湖沃多福新材料有限责任公司 Waterproof leaking stoppage material with self-repairing function
CN103254403A (en) * 2013-05-24 2013-08-21 淄博德信联邦化学工业有限公司 Preparation method of oil-soluble polyurethane grouting liquid
CN104211354A (en) * 2014-08-29 2014-12-17 上海龙洲新型建材有限公司 Self-closing repairing coating enhanced waterproof material
CN106010188A (en) * 2016-06-29 2016-10-12 浙江鲁班建筑防水有限公司 Self-repaired polyurethane waterproof coating and preparation method thereof
KR101720037B1 (en) * 2016-07-11 2017-03-27 임펙트디엔씨 주식회사 An anti-wash non-shrinkage cement concrete composition having the improved durability for road pavement and a repairing method of concrete structure using the same
CN106833343A (en) * 2015-12-04 2017-06-13 江苏省电力公司南京供电公司 A kind of selfcurable insulative anti-corrosive and waterproof paint repaired for distribution net equipment insulation

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4855184A (en) * 1988-02-02 1989-08-08 Minnesota Mining And Manufacturing Company Radiation-curable protective coating composition
CN102863192A (en) * 2012-09-08 2013-01-09 芜湖沃多福新材料有限责任公司 Waterproof leaking stoppage material with self-repairing function
CN103254403A (en) * 2013-05-24 2013-08-21 淄博德信联邦化学工业有限公司 Preparation method of oil-soluble polyurethane grouting liquid
CN104211354A (en) * 2014-08-29 2014-12-17 上海龙洲新型建材有限公司 Self-closing repairing coating enhanced waterproof material
CN106833343A (en) * 2015-12-04 2017-06-13 江苏省电力公司南京供电公司 A kind of selfcurable insulative anti-corrosive and waterproof paint repaired for distribution net equipment insulation
CN106010188A (en) * 2016-06-29 2016-10-12 浙江鲁班建筑防水有限公司 Self-repaired polyurethane waterproof coating and preparation method thereof
KR101720037B1 (en) * 2016-07-11 2017-03-27 임펙트디엔씨 주식회사 An anti-wash non-shrinkage cement concrete composition having the improved durability for road pavement and a repairing method of concrete structure using the same

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Application publication date: 20191105