CN110405217A - Functionally graded porous energy-absorbing material and its manufacturing method - Google Patents
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- B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
- B22F7/002—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of porous nature
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
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Abstract
本发明属于多孔材料技术领域,尤其涉及一种功能梯度多孔吸能材料及其制造方法。功能梯度多孔吸能材料包括若干吸能材料层,各吸能材料层沿空间正交三维方向中的至少一个方向层叠连接;各吸能材料层均包括若干相互连接且中空的立方单元胞体,各吸能材料层的各立方单元胞体的结构沿各吸能材料层的层叠方向呈梯度式排列。本发明材料的每一层吸能材料层均通过若干中空的立方单元胞体相互连接形成,立方单元胞体沿空间正交三维方向中的一个或多个方向的呈梯度式的排列和分布,使其沿该方向在缓冲或冲击能量吸收上呈现功能梯度式的效果,不但多孔材料尺寸易控制,且具有功能梯度效果导致以及能够有效抵受单向冲击。
The invention belongs to the technical field of porous materials, and in particular relates to a functional gradient porous energy-absorbing material and a manufacturing method thereof. The functionally graded porous energy-absorbing material includes several energy-absorbing material layers, and each energy-absorbing material layer is stacked and connected along at least one direction in the space orthogonal three-dimensional direction; each energy-absorbing material layer includes several interconnected and hollow cubic unit cells, each The structure of each cubic unit cell of the energy-absorbing material layer is arranged in a gradient manner along the stacking direction of each energy-absorbing material layer. Each layer of energy-absorbing material layer of the material of the present invention is formed by interconnecting several hollow cubic unit cells, and the cubic unit cells are arranged and distributed in a gradient manner along one or more directions in the orthogonal three-dimensional direction of space, making it Along this direction, there is a functional gradient effect on cushioning or impact energy absorption. Not only is the size of the porous material easy to control, but it also has a functional gradient effect and can effectively withstand unidirectional impact.
Description
技术领域technical field
本发明属于多孔材料技术领域,尤其涉及一种功能梯度多孔吸能材料及其制造方法。The invention belongs to the technical field of porous materials, and in particular relates to a functional gradient porous energy-absorbing material and a manufacturing method thereof.
背景技术Background technique
多孔材料是一种由相互贯通或封闭的孔洞构成网络结构材料。典型的孔结构有:由大量多边形孔在平面上聚集形成的二维结构,由于其形状类似于蜂房的六边形结构而被称为“蜂窝”材料;更为普遍的是由大量有序或无序(即规则或不规则)的孔洞在空间聚集形成的三维结构。若这些孔洞为无序(即不规则)的,则通常称之为“泡沫”材料,典型的如泡沫铝。另外,如果孔洞之间是相通的,则称为开孔多孔材料;如果孔洞之间不连通,即每个孔洞与周围孔洞完全隔开,则称为闭孔多孔材料;当然,也有一些孔洞是半开孔半闭孔的。Porous material is a kind of network structure material composed of interpenetrating or closed pores. Typical pore structures are: a two-dimensional structure formed by the aggregation of a large number of polygonal pores on a plane, which is called a "honeycomb" material because its shape is similar to the hexagonal structure of a honeycomb; more commonly, it is composed of a large number of ordered or A three-dimensional structure formed by the aggregation of disordered (regular or irregular) pores in space. When the cells are disordered (ie, irregular), the material is often referred to as a "foamed" material, typically aluminum foam. In addition, if the pores are connected, it is called an open-pore porous material; if the pores are not connected, that is, each hole is completely separated from the surrounding pores, it is called a closed-cell porous material; of course, there are also some pores that are Half open and half closed.
相对连续介质材料而言,多孔材料一般具有相对密度低、比强度高、比表面积高、重量轻、隔音、隔热、渗透性好等优点。另外,多孔材料通常具有非常高的阻尼减振和冲击能量吸收的能力,因此常被用于制造缓冲或吸能器和元配件。Compared with continuum materials, porous materials generally have the advantages of low relative density, high specific strength, high specific surface area, light weight, sound insulation, heat insulation, and good permeability. In addition, porous materials usually have a very high ability to damp vibration and absorb impact energy, so they are often used to manufacture cushioning or energy absorbers and components.
多孔金属材料是一种典型的多孔材料。目前广泛使用在吸能器中的多孔金属材料为蜂窝式和泡沫式的结构(较为典型的是泡沫铝)。在汽车工业中,采用多孔金属夹芯板结构可制造汽车盖板、卡车盖与滑动顶板等,从而减轻结构件的质量和提高结构件的刚度。多孔金属夹芯板还具有高的吸收冲击与声能的效果。在航空航天工业中,多孔金属已被研究用于航天飞机着陆架中的冲击能吸收元件在造船工业中。在铁道机车行业,多孔金属芯材大型镶板已用于现代化客轮中的许多部件的建造,多孔金属夹芯结构已在船舶机舱减振降噪中得到应用。Porous metal material is a typical porous material. At present, the porous metal materials widely used in energy absorbers are honeycomb and foam structures (typically aluminum foam). In the automotive industry, the porous metal sandwich panel structure can be used to manufacture car covers, truck covers and sliding roofs, etc., thereby reducing the quality of the structural parts and improving the rigidity of the structural parts. The porous metal sandwich panel also has a high effect of absorbing impact and sound energy. In the aerospace industry, porous metals have been investigated for impact energy absorbing elements in the landing gear of the space shuttle and in the shipbuilding industry. In the railway locomotive industry, large panels of porous metal core materials have been used in the construction of many parts in modern passenger ships, and porous metal sandwich structures have been applied in the vibration and noise reduction of ship engine rooms.
目前的多孔材料在缓冲吸能场合中的应用主要存在以下两点问题:The current application of porous materials in buffering and energy-absorbing applications mainly has the following two problems:
(1)用于冲击减振和缓冲吸能场合的多孔材料以多孔金属材料为主,主要分为三维结构的“泡沫铝”和二维结构的“铝蜂窝”材料。一方面,泡沫铝的孔形、孔径、孔隙等晶胞要素不易控制,导致组织不均匀,从而吸能效果难以预测与控制;另一方面,二维蜂窝金属只能抵受单向冲击,对多方位多角度的冲击无能为力。(1) The porous materials used for shock absorption and energy absorption are mainly porous metal materials, which are mainly divided into three-dimensional structure "foam aluminum" and two-dimensional structure "aluminum honeycomb" materials. On the one hand, the unit cell elements such as cell shape, pore size, and pores of aluminum foam are not easy to control, resulting in uneven structure, so that the energy absorption effect is difficult to predict and control; on the other hand, two-dimensional honeycomb metal can only withstand one-way impact Impact from multiple directions and angles is powerless.
(2)用于冲击减振和缓冲吸能场合的多孔材料的结构形态均比较单一,不具备沿某一方向或多个方向的功能梯度效果。(2) The structure of the porous material used for shock vibration reduction and energy absorption is relatively simple, and it does not have a functional gradient effect along a certain direction or multiple directions.
发明内容Contents of the invention
本发明的目的在于提供一种功能梯度多孔吸能材料及其制造方法,旨在解决现有技术中的多孔材料尺寸不易控制,且不具有功能梯度效果导致以及只能够抵受单向冲击的技术问题。The purpose of the present invention is to provide a functionally graded porous energy-absorbing material and its manufacturing method, aiming to solve the problems in the prior art that the size of the porous material is not easy to control, does not have a functional gradient effect and can only withstand one-way impact question.
为实现上述目的,本发明采用的技术方案是:一种功能梯度多孔吸能材料,包括若干吸能材料层,各所述吸能材料层沿空间正交三维方向中的至少一个方向层叠连接;In order to achieve the above object, the technical solution adopted by the present invention is: a functionally graded porous energy-absorbing material, including several energy-absorbing material layers, each of which is stacked and connected along at least one of the spatially orthogonal three-dimensional directions;
各所述吸能材料层均包括若干相互连接且中空的立方单元胞体,各所述吸能材料层的各所述立方单元胞体的结构沿各所述吸能材料层的层叠方向呈梯度式排列。Each of the energy-absorbing material layers includes a number of interconnected and hollow cubic unit cells, and the structure of each of the cubic unit cells in each of the energy-absorbing material layers is arranged in a gradient manner along the stacking direction of each of the energy-absorbing material layers. .
优选地,沿各所述吸能材料层的层叠方向连接的各所述立方单元胞体的体积呈梯度式的递增或递减排列。Preferably, the volumes of the cubic unit cells connected along the stacking direction of the energy-absorbing material layers are arranged in a gradient-like increasing or decreasing manner.
优选地,沿各所述吸能材料层的层叠方向连接的各所述立方单元胞体的壁厚呈梯度式的递增或递减排列。Preferably, the wall thickness of each of the cubic unit cells connected along the stacking direction of each of the energy-absorbing material layers is arranged in a gradient-like increasing or decreasing manner.
优选地,沿各所述吸能材料层的层叠方向连接的各所述立方单元胞体的材质呈梯度式的变化排列。Preferably, the materials of the cubic unit cells connected along the lamination direction of the energy-absorbing material layers are arranged in a gradient manner.
优选地,沿各所述吸能材料层的层叠方向连接的各所述立方单元胞体的体积和壁厚均呈梯度式的递增或递减排列。Preferably, the volume and wall thickness of each of the cubic unit cells connected along the stacking direction of each of the energy-absorbing material layers are arranged in a gradient-like increasing or decreasing manner.
优选地,沿各所述吸能材料层的层叠方向连接的各所述立方单元胞体的壁厚呈梯度式的递增或递减排列以及材质均梯度式的变化排列。Preferably, the wall thickness of each of the cubic unit cells connected along the stacking direction of each energy-absorbing material layer is arranged in a gradient-like increasing or decreasing manner, and the material is arranged in a gradient-like changing arrangement.
优选地,沿各所述吸能材料层的层叠方向连接的各所述立方单元胞体的体积呈梯度式的递增或递减排列以及材质呈梯度式的变化排列。Preferably, the cubic unit cells connected along the stacking direction of each energy-absorbing material layer are arranged in a gradient-like increasing or decreasing volume and their materials are arranged in a gradient-like changing arrangement.
优选地,叠层连接的各所述吸能材料层以至少一层相同的所述吸能材料层为一个梯度。Preferably, each of the energy-absorbing material layers connected by lamination uses at least one same energy-absorbing material layer as a gradient.
优选地,叠层连接的各所述吸能材料层的各所述立方单元胞体的沿空间正交三维方向中的两个相反的方向呈梯度式排列。Preferably, the cubic unit cells of each of the energy-absorbing material layers connected by lamination are arranged in a gradient manner along two opposite directions among the spatially orthogonal three-dimensional directions.
本发明的有益效果:本发明的功能梯度多孔吸能材料,其每一层吸能材料层均通过若干中空的立方单元胞体相互连接形成,这些立方单元胞体沿空间正交三维方向中的一个或多个方向的呈梯度式的排列和分布,使其沿该方向在缓冲或冲击能量吸收上呈现功能梯度式的效果。由于立方单元胞体及整体梯度结构上的独特性,该功能梯度多孔吸能材料在力学性能(尤其是冲击动力学性能)方面,拥有其它各类多孔材料所无法比拟的优势。与二维的蜂窝材料相比,该功能梯度多孔吸能材料可以抵受来自空间正交三维方向中一个或多个方向的冲击(二维蜂窝材料只能抵受单向冲击),且冲击能量的吸收具有功能梯度式的效果;与三维的泡沫金属相比,该功能梯度多孔吸能材料的结构相对均匀,整体材料的晶胞(立方单元胞体)沿空间正交三维方向中的一个方向或多个方向均匀地、梯度式地整齐排列,使得材料的力学性能(包括静力学和动力学性能)在该方向上呈现稳定的功能梯度特性。另外,相比于蜂窝材料,该功能梯度多孔吸能材料的晶胞(立方单元胞体)尺寸可控,通过控制该立方单元胞体的大小和数量,生成体积不一的、各种规格的功能梯度多孔吸能材料,从而更有利于把其填充到被保护的部位内,因此功能梯度多孔吸能材料的相对密度和孔隙率也就可控,进而可根据实际情况来制备不同规格的材料,满足不同的应用需求。Beneficial effects of the present invention: In the functionally graded porous energy-absorbing material of the present invention, each layer of the energy-absorbing material layer is formed by interconnecting several hollow cubic unit cells, and these cubic unit cells are formed along one or more of the spatially orthogonal three-dimensional directions. The gradient-like arrangement and distribution in multiple directions makes it have a functional gradient effect in cushioning or impact energy absorption along the direction. Due to the uniqueness of the cubic unit cell body and the overall gradient structure, the functionally graded porous energy-absorbing material has advantages incomparable to other types of porous materials in terms of mechanical properties (especially impact dynamic properties). Compared with two-dimensional honeycomb materials, this functionally graded porous energy-absorbing material can withstand impacts from one or more directions in three-dimensional orthogonal directions (two-dimensional honeycomb materials can only withstand one-way impacts), and the impact energy The absorption has a functional gradient effect; compared with the three-dimensional foam metal, the structure of the functional gradient porous energy-absorbing material is relatively uniform, and the unit cell (cubic unit cell body) of the overall material is along one of the three-dimensional orthogonal directions in space or Multiple directions are uniformly and gradiently arranged, so that the mechanical properties (including static and dynamic properties) of the material present a stable functional gradient characteristic in this direction. In addition, compared with honeycomb materials, the size of the unit cell (cubic unit cell body) of the functionally graded porous energy-absorbing material is controllable. By controlling the size and quantity of the cubic unit cell body, functional gradients of different sizes and specifications can be generated. Porous energy-absorbing materials, which are more conducive to filling them into the protected parts, so the relative density and porosity of functionally gradient porous energy-absorbing materials can be controlled, and materials of different specifications can be prepared according to actual conditions to meet different application requirements.
本发明采用的另一技术方案是:一种功能梯度多孔吸能材料的制造方法,包括如下步骤:Another technical solution adopted by the present invention is: a method for manufacturing a functionally graded porous energy-absorbing material, comprising the following steps:
制备若干层结构不同的吸能材料层,其中各所述吸能材料层均包括若干相互连接且中空的立方单元胞体;Prepare several layers of energy-absorbing material with different structures, wherein each of the energy-absorbing material layers includes several interconnected and hollow cubic unit cells;
将各所述吸能材料层沿空间正交三维方向中的至少一个方向层叠连接,且使得各所述立方单元胞体的结构沿各所述吸能材料层的层叠方向呈梯度式排列。Each of the energy-absorbing material layers is stacked and connected along at least one of the spatially orthogonal three-dimensional directions, and the structure of each of the cubic unit cells is arranged in a gradient manner along the stacking direction of each of the energy-absorbing material layers.
本发明的功能梯度多孔吸能材料的制造方法,其制造出的功能梯度多孔吸能材料的每一层吸能材料层均通过若干中空的立方单元胞体相互连接形成,这些立方单元胞体沿空间正交三维方向中的一个或多个方向的呈梯度式的排列和分布,使其沿该方向在缓冲或冲击能量吸收上呈现功能梯度式的效果,由于立方单元胞体及整体梯度结构上的独特性,该功能梯度多孔吸能材料在力学性能(尤其是冲击动力学性能)方面,拥有其它各类多孔材料所无法比拟的优势,即不但多孔材料尺寸易控制,且具有功能梯度效果导致以及能够有效抵受单向冲击。In the manufacturing method of the functionally graded porous energy-absorbing material of the present invention, each layer of the energy-absorbing material layer of the functionally graded porous energy-absorbing material produced is formed by interconnecting several hollow cubic unit cells. The gradient arrangement and distribution of one or more directions in the intersecting three-dimensional direction makes it present a functional gradient effect in cushioning or impact energy absorption along this direction, due to the uniqueness of the cubic unit cell body and the overall gradient structure , this functionally graded porous energy-absorbing material possesses incomparable advantages over other types of porous materials in terms of mechanical properties (especially impact dynamics), that is, not only the size of the porous material is easy to control, but also has a functional gradient effect and can effectively Withstand one-way impact.
附图说明Description of drawings
为了更清楚地说明本发明实施例中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动性的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions in the embodiments of the present invention, the following will briefly introduce the accompanying drawings that need to be used in the descriptions of the embodiments or the prior art. Obviously, the accompanying drawings in the following description are only of the present invention. For some embodiments, those of ordinary skill in the art can also obtain other drawings based on these drawings without paying creative efforts.
图1为本发明实施例提供的功能梯度多孔吸能材料的第一种实施方式的立体结构示意图。Fig. 1 is a schematic three-dimensional structure diagram of a first embodiment of a functionally graded porous energy-absorbing material provided by an embodiment of the present invention.
图2为本发明实施例提供的功能梯度多孔吸能材料的第一种实施方式的平面结构示意图。Fig. 2 is a schematic plan view of the first embodiment of the functionally graded porous energy-absorbing material provided by the embodiment of the present invention.
图3为沿图2中A-A线的剖切视图。Fig. 3 is a sectional view along line A-A in Fig. 2 .
图4为本发明实施例提供的功能梯度多孔吸能材料的第二种实施方式的立体结构示意图。Fig. 4 is a schematic three-dimensional structure diagram of the second embodiment of the functionally graded porous energy-absorbing material provided by the embodiment of the present invention.
图5为本发明实施例提供的功能梯度多孔吸能材料的第二种实施方式的平面结构示意图。Fig. 5 is a schematic plan view of the second embodiment of the functionally graded porous energy-absorbing material provided by the embodiment of the present invention.
图6为沿图5中B-B线的剖切视图。Fig. 6 is a sectional view along line B-B in Fig. 5 .
图7为本发明实施例提供的功能梯度多孔吸能材料的第三种实施方式的立体结构示意图。Fig. 7 is a schematic perspective view of the three-dimensional structure of the third embodiment of the functionally graded porous energy-absorbing material provided by the embodiment of the present invention.
图8为本发明实施例提供的功能梯度多孔吸能材料的第三种实施方式的平面结构示意图。Fig. 8 is a schematic plan view of the third embodiment of the functionally graded porous energy-absorbing material provided by the embodiment of the present invention.
图9为沿图8中C-C线的剖切视图。Fig. 9 is a sectional view along line C-C in Fig. 8 .
其中,图中各附图标记:Wherein, each reference sign in the figure:
10—吸能材料层 11—立方单元胞体 L—梯度。10—energy-absorbing material layer 11—cubic unit cell body L—gradient.
具体实施方式Detailed ways
下面详细描述本发明的实施例,所述实施例的示例在附图中示出,其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图1~9描述的实施例是示例性的,旨在用于解释本发明,而不能理解为对本发明的限制。Embodiments of the present invention are described in detail below, examples of which are shown in the drawings, wherein the same or similar reference numerals designate the same or similar elements or elements having the same or similar functions throughout. The embodiments described below by referring to the accompanying drawings 1 to 9 are exemplary and are intended to explain the present invention, but should not be construed as limiting the present invention.
在本发明的描述中,需要理解的是,术语“长度”、“宽度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。In describing the present invention, it should be understood that the terms "length", "width", "upper", "lower", "front", "rear", "left", "right", "vertical", The orientation or positional relationship indicated by "horizontal", "top", "bottom", "inner", "outer", etc. are based on the orientation or positional relationship shown in the drawings, and are only for the convenience of describing the present invention and simplifying the description, rather than Nothing indicating or implying that a referenced device or element must have a particular orientation, be constructed, and operate in a particular orientation should therefore not be construed as limiting the invention.
此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者更多个该特征。在本发明的描述中,“多个”的含义是两个或两个以上,除非另有明确具体的限定。In addition, the terms "first" and "second" are used for descriptive purposes only, and cannot be interpreted as indicating or implying relative importance or implicitly specifying the quantity of indicated technical features. Thus, a feature defined as "first" and "second" may explicitly or implicitly include one or more of these features. In the description of the present invention, "plurality" means two or more, unless otherwise specifically defined.
在本发明中,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”、“固定”等术语应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或成一体;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通或两个元件的相互作用关系。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本发明中的具体含义。In the present invention, unless otherwise clearly specified and limited, terms such as "installation", "connection", "connection" and "fixation" should be understood in a broad sense, for example, it can be a fixed connection or a detachable connection , or integrated; it can be mechanically connected or electrically connected; it can be directly connected or indirectly connected through an intermediary, and it can be the internal communication of two components or the interaction relationship between two components. Those of ordinary skill in the art can understand the specific meanings of the above terms in the present invention according to specific situations.
如图1~9所示,本发明实施例提供的一种功能梯度多孔吸能材料,其可应用作各种行业的冲击吸能原件。功能梯度多孔吸能材料包括若干吸能材料层10,各所述吸能材料层10沿空间正交三维方向中的至少一个方向层叠连接,例如,空间正交三维方向中的方向可以是X轴向、Y轴向或者Z轴向;各所述吸能材料层10均包括若干相互连接且中空的立方单元胞体11,各所述吸能材料层10的各所述立方单元胞体11的结构沿各所述吸能材料层10的层叠方向呈梯度式排列。As shown in Figures 1 to 9, the embodiment of the present invention provides a functionally graded porous energy-absorbing material, which can be used as impact energy-absorbing components in various industries. The functionally graded porous energy-absorbing material includes several energy-absorbing material layers 10, and each of the energy-absorbing material layers 10 is stacked and connected along at least one direction in the spatially orthogonal three-dimensional direction, for example, the direction in the spatially orthogonal three-dimensional direction can be the X axis direction, Y axis or Z axis; each of the energy-absorbing material layers 10 includes a number of interconnected and hollow cubic unit cells 11, and the structure of each of the cubic unit cells 11 of each of the energy-absorbing material layers 10 is along the The lamination direction of each energy-absorbing material layer 10 is arranged in a gradient manner.
具体地,本发明实施例的功能梯度多孔吸能材料,其每一层吸能材料层10均通过若干中空的立方单元胞体11相互连接形成,这些立方单元胞体11沿空间正交三维方向中的一个或多个方向的呈梯度式的排列和分布,使其沿该方向在缓冲或冲击能量吸收上呈现功能梯度式的效果。由于立方单元胞体11及整体梯度结构上的独特性,该功能梯度多孔吸能材料在力学性能(尤其是冲击动力学性能)方面,拥有其它各类多孔材料所无法比拟的优势。与二维的蜂窝材料相比,该功能梯度多孔吸能材料可以抵受来自空间正交三维方向中一个或多个方向的冲击(二维蜂窝材料只能抵受单向冲击),且冲击能量的吸收具有功能梯度式的效果;与三维的泡沫金属相比,该功能梯度多孔吸能材料的结构相对均匀,整体材料的晶胞(立方单元胞体11)沿空间正交三维方向中的一个方向或多个方向均匀地、梯度式地整齐排列,使得材料的力学性能(包括静力学和动力学性能)在该方向上呈现稳定的功能梯度特性。另外,相比于蜂窝材料,该功能梯度多孔吸能材料的晶胞(立方单元胞体11)尺寸可控,通过控制该立方单元胞体11的大小和数量,生成体积不一的、各种规格的功能梯度多孔吸能材料,从而更有利于把其填充到被保护的部位内,因此功能梯度多孔吸能材料的相对密度和孔隙率也就可控,进而可根据实际情况来制备不同规格的材料,满足不同的应用需求。Specifically, in the functionally graded porous energy-absorbing material of the embodiment of the present invention, each layer of energy-absorbing material layer 10 is formed by interconnecting several hollow cubic unit cells 11. Gradient arrangement and distribution in one or more directions makes it have a functional gradient effect in cushioning or impact energy absorption along the direction. Due to the uniqueness of the cubic unit cell body 11 and the overall gradient structure, the functionally graded porous energy-absorbing material has advantages incomparable to other porous materials in terms of mechanical properties (especially impact dynamic properties). Compared with two-dimensional honeycomb materials, this functionally graded porous energy-absorbing material can withstand impacts from one or more directions in three-dimensional orthogonal directions (two-dimensional honeycomb materials can only withstand one-way impacts), and the impact energy The absorption has a functionally gradient effect; compared with the three-dimensional foam metal, the structure of the functionally gradient porous energy-absorbing material is relatively uniform, and the unit cell (cubic unit cell body 11) of the overall material is along one of the three-dimensional orthogonal directions in space. Or multiple directions are uniformly and gradiently arranged, so that the mechanical properties (including static and dynamic properties) of the material present a stable functional gradient characteristic in this direction. In addition, compared with the honeycomb material, the size of the unit cell (cubic unit cell body 11) of the functionally graded porous energy-absorbing material is controllable. By controlling the size and quantity of the cubic unit cell body 11, different sizes and specifications of Functionally graded porous energy-absorbing material, which is more conducive to filling it into the protected part, so the relative density and porosity of the functionally graded porous energy-absorbing material can also be controlled, and then materials of different specifications can be prepared according to actual conditions , to meet different application requirements.
更具体地,本实施例的功能梯度多孔吸能材料在具体应用时,当其受到压缩或者冲击时,材料内部的孔隙和组织就会发生坍塌,材料通过自身的内部变形,把压缩或冲击的能量转化为材料的应变能来吸收掉。对于具有立方单元胞体11的内部结构的多孔材料而言,其力学性能(包括静力学和动力学性能)则由立方单元胞体11的材质、体积(边长)和壁厚,以及这些立方单元胞体11的排列分布这些因素所决定。因此,可以通过复合具有不同材质、体积或者壁厚的立方单元,且在材料内部按一定的规律排列这些立方单元来实现整块多孔材料具有功能梯度式的力学性能。More specifically, when the functionally graded porous energy-absorbing material of this embodiment is used in a specific application, when it is compressed or impacted, the pores and tissues inside the material will collapse, and the material will transform the compressed or impacted material through its own internal deformation. The energy is converted into strain energy of the material to absorb. For the porous material with the internal structure of cubic unit cells 11, its mechanical properties (comprising statics and dynamics properties) are then determined by the material, volume (side length) and wall thickness of the cubic unit cells 11, and these cubic unit cells The permutation distribution of 11 is determined by these factors. Therefore, the functionally graded mechanical properties of the whole porous material can be realized by combining cubic units with different materials, volumes or wall thicknesses, and arranging these cubic units according to certain rules inside the material.
进一步地,本发明实施例的功能梯度多孔吸能材料是由大量的立方单元胞体11组成。即该功能梯度多孔材料的内部组织结构可划分为一个个的立方单元胞体11,每个立方单元胞体11为中空、全封闭(也可以通过小孔连通)的结构,一般为毫米量级(但不限于)。并且,各个立方单元胞体11之间是相互连接的,就制备工艺而言,可以由事先制备大量的立方单元胞体11,然后通过胶粘、激光焊或者钎焊等手段把这些立方单元胞体11堆砌拼接成整体的功能梯度多孔材料的方法来生成;也可以通过3D打印、粉末冶金等方式直接制备而成。Furthermore, the functionally graded porous energy-absorbing material of the embodiment of the present invention is composed of a large number of cubic unit cells 11 . That is, the internal tissue structure of the functionally graded porous material can be divided into cubic unit cells 11 one by one, and each cubic unit cell body 11 is a hollow and fully closed structure (which can also be connected through small holes), generally on the order of millimeters (but not limited to). Moreover, the cubic unit cells 11 are interconnected. As far as the preparation process is concerned, a large number of cubic unit cells 11 can be prepared in advance, and then these cubic unit cells 11 can be stacked by means of gluing, laser welding or brazing. It can be produced by splicing into a whole functionally graded porous material; it can also be directly prepared by 3D printing, powder metallurgy and other methods.
在本实施例中,功能梯度多孔吸能材料的其中一种实施方式是:如图1~6所示,沿各所述吸能材料层10的层叠方向连接的各所述立方单元胞体11的体积呈梯度式的递增或递减排列。具体地,同一层的吸能材料层10的各所述立方单元胞体11的结构相同,并且不同层的吸能材料层10的立方单元胞体11沿着层叠方向以立方单元胞体11的体积的递增或递减呈梯度排列,从而现实材料的功能梯度效果。In this embodiment, one implementation of the functionally graded porous energy-absorbing material is: as shown in FIGS. The volumes are arranged in a gradient-like ascending or descending order. Specifically, the cubic unit cells 11 of the energy-absorbing material layer 10 of the same layer have the same structure, and the cubic unit cells 11 of the energy-absorbing material layers 10 of different layers increase with the volume of the cubic unit cells 11 along the lamination direction. Or descending and arranged in a gradient, so as to realize the functional gradient effect of the material.
在本实施例中,功能梯度多孔吸能材料的其中一种实施方式是:如图7~9所示,沿各所述吸能材料层10的层叠方向连接的各所述立方单元胞体11的壁厚呈梯度式的递增或递减排列。具体地,同一层的吸能材料层10的各所述立方单元胞体11的结构相同,并且不同层的吸能材料层10的立方单元胞体11沿着层叠方向以立方单元胞体11的壁厚的递增或递减呈梯度排列,从而现实材料的功能梯度效果。In this embodiment, one implementation of the functionally graded porous energy-absorbing material is: as shown in FIGS. The wall thickness is arranged in a gradient increasing or decreasing manner. Specifically, the cubic unit cells 11 of the energy-absorbing material layers 10 of the same layer have the same structure, and the cubic unit cells 11 of the energy-absorbing material layers 10 of different layers have the same wall thickness of the cubic unit cells 11 along the stacking direction. Incremental or decremental gradient arrangement, so as to realize the functional gradient effect of the material.
在本实施例中,功能梯度多孔吸能材料的其中一种实施方式是:沿各所述吸能材料层10的层叠方向连接的各所述立方单元胞体11的材质呈梯度式的变化排列。具体地,同一层的吸能材料层10的各所述立方单元胞体11的结构相同,并且不同层的吸能材料层10的立方单元胞体11沿着层叠方向以立方单元胞体11的材质的变化呈梯度排列,从而现实材料的功能梯度效果。In this embodiment, one implementation of the functionally graded porous energy-absorbing material is that the materials of the cubic unit cells 11 connected along the stacking direction of the energy-absorbing material layers 10 are arranged in a gradient manner. Specifically, the cubic unit cells 11 of the energy-absorbing material layer 10 of the same layer have the same structure, and the cubic unit cells 11 of the energy-absorbing material layers 10 of different layers change according to the material of the cubic unit cells 11 along the stacking direction. Arranged in a gradient to realize the functional gradient effect of the material.
在本实施例中,功能梯度多孔吸能材料的其中一种实施方式是:沿各所述吸能材料层10的层叠方向连接的各所述立方单元胞体11的体积和壁厚均呈梯度式的递增或递减排列。具体地,同一层的吸能材料层10的各所述立方单元胞体11的结构相同,并且不同层的吸能材料层10的立方单元胞体11沿着层叠方向以立方单元胞体11的体积和壁厚的递增或递减呈梯度排列,从而现实材料的功能梯度效果。In this embodiment, one implementation of the functionally graded porous energy-absorbing material is: the volume and wall thickness of each cubic unit cell 11 connected along the lamination direction of each energy-absorbing material layer 10 are gradient in ascending or descending order. Specifically, the cubic unit cells 11 of the energy-absorbing material layer 10 of the same layer have the same structure, and the cubic unit cells 11 of the energy-absorbing material layers 10 of different layers have the volume and wall of the cubic unit cells 11 along the stacking direction. Thick increasing or decreasing gradients are arranged to realize the functional gradient effect of the material.
在本实施例中,功能梯度多孔吸能材料的其中一种实施方式是:沿各所述吸能材料层10的层叠方向连接的各所述立方单元胞体11的壁厚呈梯度式的递增或递减排列以及材质均梯度式的变化排列。具体地,同一层的吸能材料层10的各所述立方单元胞体11的结构相同,并且不同层的吸能材料层10的立方单元胞体11沿着层叠方向以立方单元胞体11的壁厚的递增或递减以及材质的变化呈梯度排列,从而现实材料的功能梯度效果。In this embodiment, one implementation of the functionally graded porous energy-absorbing material is: the wall thickness of each of the cubic unit cells 11 connected along the stacking direction of each of the energy-absorbing material layers 10 increases gradually or gradually. Decreasing arrangement and gradient arrangement of materials. Specifically, the cubic unit cells 11 of the energy-absorbing material layers 10 of the same layer have the same structure, and the cubic unit cells 11 of the energy-absorbing material layers 10 of different layers have the same wall thickness of the cubic unit cells 11 along the stacking direction. Incremental or decremental and material changes are arranged in gradients to realize the functional gradient effect of materials.
在本实施例中,功能梯度多孔吸能材料的其中一种实施方式是:沿各所述吸能材料层10的层叠方向连接的各所述立方单元胞体11的体积呈梯度式的递增或递减排列以及材质呈梯度式的变化排列。具体地,同一层的吸能材料层10的各所述立方单元胞体11的结构相同,并且不同层的吸能材料层10的立方单元胞体11沿着层叠方向以立方单元胞体11的体积的递增或递减以及材质的变化呈梯度排列,从而现实材料的功能梯度效果。In this embodiment, one implementation of the functionally graded porous energy-absorbing material is: the volume of each of the cubic unit cells 11 connected along the stacking direction of each of the energy-absorbing material layers 10 increases or decreases in a gradient manner Arrangements and materials are arranged in gradients. Specifically, the cubic unit cells 11 of the energy-absorbing material layer 10 of the same layer have the same structure, and the cubic unit cells 11 of the energy-absorbing material layers 10 of different layers increase with the volume of the cubic unit cells 11 along the lamination direction. Or decreasing and material changes are arranged in gradients, so as to realize the functional gradient effect of materials.
进一步地,上述实施方式为沿一个方向呈现功能梯度的情况,但实际上,本发明实施例的功能梯度多孔材料,通过对其内部的立方单元胞体11的适当排列,可呈现沿空间正交三维方向的一个、两个甚至三个方向功能梯度效果。用户可根据实际情况对材料内部的立方单元进行灵活排列组合,使材料展示多种多样、功能强大的功能梯度性能。Further, the above-mentioned embodiment is a case where a functional gradient is presented along one direction, but in fact, the functionally graded porous material of the embodiment of the present invention can present an orthogonal three-dimensional Directional one, two or even three direction function gradient effect. Users can flexibly arrange and combine the cubic units inside the material according to the actual situation, so that the material can display various and powerful functional gradient properties.
当然,除了上述的六种立方单元胞体11的排列组合方式外,还有:同一层的吸能材料层10的各所述立方单元胞体11的结构不同并以一定的方向呈梯度排列。Of course, in addition to the arrangement and combination of the six cubic unit cells 11 mentioned above, there are also: the cubic unit cells 11 of the energy-absorbing material layer 10 in the same layer have different structures and are arranged in gradients in a certain direction.
本发明实施例的功能梯度多孔材料具有非常大的优势:第一,材料内部的立方单元胞体11的组织结构尺寸可控,整个多孔材料的一致性非常高,使得材料具备非常优良的性能;第二,材料内部的立方单元胞体11具有多种排列组合方式,内部结构变化多样,使其能呈现多种多样、功能强大的多孔功能梯度式的效果;第三,材料的外形结构均为立方体,可以很方便地填充到被保护的位置(非常方便的作为吸能的填充材料),适用性广。The functionally graded porous material of the embodiment of the present invention has great advantages: first, the size of the cubic unit cell body 11 inside the material is controllable, and the consistency of the entire porous material is very high, so that the material has very good performance; Second, the cubic unit cells 11 inside the material have multiple arrangements and combinations, and the internal structure is varied, so that it can present a variety of powerful porous functional gradient effects; third, the external structure of the material is cubic, It can be easily filled to the protected position (very convenient as an energy-absorbing filling material), and has wide applicability.
在本实施例中,如图1~2、图4~5和图8~9所示,叠层连接的各所述吸能材料层10以至少一层相同的所述吸能材料层10为一个梯度L。具体地,呈梯度排列的功能梯度多孔吸能材料中,如图4~5所示,可以以一层相同的所述吸能材料层10为一个梯度L,如图8~9所示,也可以以两层相同的所述吸能材料层10为一个梯度L,如图1~2所示,还可以以三层相同的所述吸能材料层10为一个梯度L,或者三层以上的相同的所述吸能材料层10为一个梯度L,根据功能梯度多孔吸能材料整体体积的大小进行适应性选择。例如,沿着一个方向,每间隔一层或者两层或者三层的吸能材料层10中,立方单元胞体11的体积或者壁厚呈梯度式的递增或递减排列或者材质呈梯度式的变化排列。In this embodiment, as shown in Figures 1-2, Figures 4-5 and Figures 8-9, each of the energy-absorbing material layers 10 that are laminated and connected is at least one of the same energy-absorbing material layers 10. A gradient L. Specifically, among functionally graded porous energy-absorbing materials arranged in gradients, as shown in Figures 4-5, one layer of the same energy-absorbing material layer 10 can be used as a gradient L, as shown in Figures 8-9, also Two layers of the same energy-absorbing material layer 10 can be used as a gradient L, as shown in Figures 1-2, and three layers of the same energy-absorbing material layer 10 can also be used as a gradient L, or more than three layers The same energy-absorbing material layer 10 is a gradient L, which is adaptively selected according to the overall volume of the functionally graded porous energy-absorbing material. For example, along one direction, in every one, two or three layers of energy-absorbing material layers 10, the volume or wall thickness of the cubic unit cells 11 is arranged in a gradient-like increasing or decreasing manner, or the material is arranged in a gradient-like changing arrangement. .
在本实施例中,如图7~9所示,叠层连接的各所述吸能材料层10的各所述立方单元胞体11的沿空间正交三维方向中的两个相反的方向呈梯度式排列。例如,各所述吸能材料层10的各所述立方单元胞体11的沿空间正交三维方向中的X轴的正负两个方向呈梯度式排列。又例如,各所述吸能材料层10的各所述立方单元胞体11的沿空间正交三维方向中的Y轴的正负两个方向呈梯度式排列。又例如,各所述吸能材料层10的各所述立方单元胞体11的沿空间正交三维方向中的Z轴的正负两个方向呈梯度式排列。In this embodiment, as shown in Figures 7 to 9, the cubic unit cells 11 of each of the energy-absorbing material layers 10 that are laminated and connected have a gradient in two opposite directions in the orthogonal three-dimensional directions in space. arrangement. For example, each of the cubic unit cells 11 of each of the energy-absorbing material layers 10 is arranged in a gradient manner along the positive and negative directions of the X-axis in three-dimensional orthogonal directions in space. For another example, the cubic unit cells 11 of each energy-absorbing material layer 10 are arranged in gradients along the positive and negative directions of the Y-axis in the three-dimensional orthogonal directions in space. For another example, the cubic unit cells 11 of each energy-absorbing material layer 10 are arranged in a gradient manner along the positive and negative directions of the Z-axis in the three-dimensional orthogonal directions in space.
本发明实施例的功能梯度多孔材料主要用于缓冲或冲击能量吸收,但该材料的功能不限于此。因此多孔材料具有其它方面的优良性能,如轻质结构、隔音、隔热等,对于多孔金属材料,还具有很好的电磁波吸收(电磁屏蔽)特性,所以在通讯工程,环保工程等领域有广泛的应途。而本发明实施例的功能梯度多孔材料,同样适用于这些功能用途的领域。The functionally graded porous material in the embodiment of the present invention is mainly used for cushioning or impact energy absorption, but the function of the material is not limited thereto. Therefore, porous materials have excellent properties in other aspects, such as lightweight structure, sound insulation, heat insulation, etc. For porous metal materials, they also have good electromagnetic wave absorption (electromagnetic shielding) characteristics, so they are widely used in communication engineering, environmental protection engineering and other fields. should be used. However, the functionally graded porous material of the embodiment of the present invention is also applicable to the fields of these functional applications.
图1~3所示的是所有立方单元胞体11的材质和壁厚相同,但立方单元胞体11的体积沿某一方向增减所形成的功能梯度多孔材料的实施方式。如图1所示,该实施方式沿垂直方向每隔三层(L为三层相同的吸能材料层10)立方单元胞体11的体积和数量就呈梯度式变化,但每三层内的立方单元胞体11的体积和数量是相同的。这样,当该实施方式受到压缩或者冲击时,底下三层的立方单元胞体11会首先发生变形坍塌,吸收一部分压缩或冲击能量;当压缩或者冲击能量持续且不断增加,倒数第三层会接着发生变形坍塌,继续吸收增加的这一部分压缩或冲击能量;当压缩或者冲击能量再持续且不断增加,那么,从下往上,每三层的立方单元胞体11就先后地发生变形坍塌,梯度式地不断吸收压缩或冲击的能量,对被保护的对象起到持续性的保护。Figures 1 to 3 show an embodiment of a functionally graded porous material in which all the cubic unit cells 11 have the same material and wall thickness, but the volume of the cubic unit cells 11 increases or decreases along a certain direction. As shown in Figure 1, in this embodiment, the volume and number of cubic unit cells 11 change in a gradient manner every three layers (L is three layers of the same energy-absorbing material layer 10) along the vertical direction, but the cubic unit cells in every three layers The volume and number of unit cell bodies 11 are the same. In this way, when the embodiment is compressed or impacted, the cubic unit cells 11 of the bottom three layers will deform and collapse first, absorbing part of the compression or impact energy; when the compression or impact energy continues and increases continuously, the penultimate layer will then undergo deformation and collapse. deformation and collapse, continue to absorb the increased compression or impact energy; when the compression or impact energy continues and continues to increase, then, from bottom to top, the cubic unit cells 11 of every three layers are deformed and collapsed successively, in a gradient manner Continuously absorb the energy of compression or impact, and provide continuous protection for the protected object.
图4~6所示的是功能梯度多孔材料与图1相类似,所不同的是图2所示的材料的立方单元胞体11的体积沿垂直方向每层均发生梯度式的变化(即L为一层相同的吸能材料层10)。Shown in Figures 4 to 6 is that the functionally graded porous material is similar to Figure 1, and the difference is that the volume of the cubic unit cell body 11 of the material shown in Figure 2 changes in a gradient manner in each layer along the vertical direction (that is, L is One layer of the same energy-absorbing material layer 10).
图7~9所示的是所有立方单元胞体11的材质和体积均相同,但立方单元胞体11的壁厚沿某一方向增减所形成的功能梯度多孔材料。该实施方式以每两层为一梯度L(L为两层相同的吸能材料层10),即每两层内的立方单元胞体11的材质和体积均相同,但每隔两层立方单元胞体11的壁厚就发生递增或递减。另外,图3所示的立方单元胞体11的壁厚,沿垂直方向的两端均发生变化,这样的情况同样适用于其它实施方式。Figures 7 to 9 show functionally graded porous materials in which all the cubic unit cells 11 have the same material and volume, but the wall thickness of the cubic unit cells 11 increases or decreases along a certain direction. In this embodiment, every two layers is a gradient L (L is two layers of the same energy-absorbing material layer 10), that is, the cubic unit cells 11 in every two layers have the same material and volume, but every two layers of cubic unit cells 11, the wall thickness increases or decreases. In addition, the wall thickness of the cubic unit cell body 11 shown in FIG. 3 changes at both ends along the vertical direction, and this situation is also applicable to other embodiments.
本发明实施例还提供一种功能梯度多孔吸能材料的制造方法,包括如下步骤:The embodiment of the present invention also provides a method for manufacturing a functionally graded porous energy-absorbing material, including the following steps:
S01:制备若干层结构不同的吸能材料层10,其中各所述吸能材料层10均包括若干相互连接且中空的立方单元胞体11;S01: Prepare several energy-absorbing material layers 10 with different layer structures, wherein each energy-absorbing material layer 10 includes several interconnected and hollow cubic unit cells 11;
S02:将各所述吸能材料层10沿空间正交三维方向中的至少一个方向层叠连接,且使得各所述立方单元胞体11的结构沿各所述吸能材料层10的层叠方向呈梯度式排列。S02: stack and connect each of the energy-absorbing material layers 10 along at least one of the spatially orthogonal three-dimensional directions, and make the structure of each of the cubic unit cells 11 present a gradient along the stacking direction of each of the energy-absorbing material layers 10 arrangement.
本发明实施例的功能梯度多孔吸能材料的制造方法,其制造出的功能梯度多孔吸能材料的每一层吸能材料层10均通过若干中空的立方单元胞体11相互连接形成,这些立方单元胞体11沿空间正交三维方向中的一个或多个方向的呈梯度式的排列和分布,使其沿该方向在缓冲或冲击能量吸收上呈现功能梯度式的效果,由于立方单元胞体11及整体梯度结构上的独特性,该功能梯度多孔吸能材料在力学性能(尤其是冲击动力学性能)方面,拥有其它各类多孔材料所无法比拟的优势,即不但多孔材料尺寸易控制,且具有功能梯度效果导致以及能够有效抵受单向冲击。In the manufacturing method of the functionally graded porous energy-absorbing material according to the embodiment of the present invention, each energy-absorbing material layer 10 of the functionally graded porous energy-absorbing material produced is formed by interconnecting several hollow cubic unit cells 11, and these cubic units The cell body 11 is arranged and distributed in a gradient manner along one or more directions in the spatially orthogonal three-dimensional direction, so that it presents a functional gradient effect in cushioning or impact energy absorption along this direction, because the cubic unit cell body 11 and the overall The uniqueness of the gradient structure, the functionally graded porous energy-absorbing material has advantages incomparable to other types of porous materials in terms of mechanical properties (especially impact dynamics), that is, not only the size of the porous material is easy to control, but also has functional The gradient effect results in and can effectively withstand unidirectional impacts.
以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modifications, equivalent replacements and improvements made within the spirit and principles of the present invention should be included in the protection of the present invention. within range.
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