CN110395781A - Salt eluriates Processes and apparatus, salt making apparatus and high slat-containing wastewater processing system - Google Patents
Salt eluriates Processes and apparatus, salt making apparatus and high slat-containing wastewater processing system Download PDFInfo
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- 150000003839 salts Chemical class 0.000 title claims abstract description 358
- 238000000034 method Methods 0.000 title claims abstract description 54
- 239000002351 wastewater Substances 0.000 title claims description 9
- 230000008569 process Effects 0.000 title abstract description 43
- 239000002002 slurry Substances 0.000 claims abstract description 133
- 239000007788 liquid Substances 0.000 claims description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 9
- 239000012047 saturated solution Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 238000002386 leaching Methods 0.000 claims 12
- 239000002689 soil Substances 0.000 claims 12
- 239000013078 crystal Substances 0.000 claims 2
- 230000008676 import Effects 0.000 claims 2
- 238000002360 preparation method Methods 0.000 claims 2
- 238000007599 discharging Methods 0.000 claims 1
- 238000009955 starching Methods 0.000 claims 1
- 239000012267 brine Substances 0.000 abstract description 9
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 abstract description 9
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 238000004065 wastewater treatment Methods 0.000 abstract description 4
- 239000002245 particle Substances 0.000 description 36
- 239000000243 solution Substances 0.000 description 32
- 239000012535 impurity Substances 0.000 description 13
- 230000005484 gravity Effects 0.000 description 10
- 238000002425 crystallisation Methods 0.000 description 8
- 230000008025 crystallization Effects 0.000 description 8
- 239000012452 mother liquor Substances 0.000 description 8
- 238000005406 washing Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- 238000001704 evaporation Methods 0.000 description 6
- 230000008020 evaporation Effects 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 230000008719 thickening Effects 0.000 description 6
- 238000012824 chemical production Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 229910001410 inorganic ion Inorganic materials 0.000 description 4
- 239000002562 thickening agent Substances 0.000 description 4
- 238000009434 installation Methods 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 238000002306 biochemical method Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
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Abstract
本申请实施例提供一种盐淘洗工艺及设备、制盐装置及高含盐废水处理系统。所述盐淘洗工艺包括利用盐腿对盐浆进行一级淘洗;以及将由所述盐腿中流出的盐浆引流至洗盐器内,利用所述洗盐器对所述盐浆进行二级淘洗,并在二级淘洗过程中同时对所述盐浆进行稠厚。本申请中的盐淘洗工艺及设备采用盐腿和洗盐器相结合的两级强化淘洗,能够显著提高分离出的盐的品质。
The embodiments of the present application provide a salt elutriation process and equipment, a salt production device, and a high-salt wastewater treatment system. The salt elutriation process includes using a salt leg to perform primary elutriation on the salt slurry; stage elutriation, and simultaneously thicken the brine slurry during the secondary elutriation. The salt elutriation process and equipment in this application adopts two-stage enhanced elutriation combining a salt leg and a salt washer, which can significantly improve the quality of the separated salt.
Description
技术领域technical field
本申请涉及化工技术领域,具体而言,涉及一种盐淘洗工艺及设备、制盐装置及高含盐废水处理系统。The application relates to the technical field of chemical industry, specifically, to a salt elutriation process and equipment, a salt making device and a high-salt wastewater treatment system.
背景技术Background technique
随着高盐废水零排放行业要求的不断提高,高盐废水零排放也从早期的杂盐技术向分盐技术发展。相较于传统的盐化工生产,高盐废水中往往含有大量杂质无机离子和有机物质,传统的生化技术难以将这些杂质从盐水中去除。With the continuous improvement of high-salt wastewater zero-discharge industry requirements, the zero-discharge of high-salt wastewater has also developed from the early miscellaneous salt technology to the salt separation technology. Compared with traditional salt chemical production, high-salt wastewater often contains a large number of impurities, inorganic ions and organic substances, and traditional biochemical techniques are difficult to remove these impurities from brine.
盐淘洗技术被广泛应用在盐化工生产上,然而对于高盐废水零排放而言,利用盐淘洗技术难以将盐水中的大量杂质无机离子和有机物质去除,从而导致通过蒸发结晶过程生成出来的盐品质不达标,无法满足需要。Salt elutriation technology is widely used in salt chemical production. However, for zero discharge of high-salt wastewater, it is difficult to use salt elutriation technology to remove a large number of impurity inorganic ions and organic substances in brine, resulting in the formation of The salt quality is not up to standard and cannot meet the needs.
因此,对于高盐废水,采用蒸发结晶过程进行零排放分盐的工艺,如何提高盐的品质是其工程化遇到的重要问题。Therefore, for high-salt wastewater, how to improve the quality of salt is an important problem encountered in the engineering of the zero-discharge salt separation process using the evaporation crystallization process.
发明内容Contents of the invention
本申请实施例的目的在于提供一种盐淘洗工艺及与该工艺对应的盐淘洗设备,其能够在高盐废水采用蒸发结晶过程以实现零排放分盐工艺中提高分离出的盐的品质。The purpose of the embodiments of the present application is to provide a salt elutriation process and salt elutriation equipment corresponding to the process, which can improve the quality of the separated salt in the zero discharge salt separation process by using the evaporation crystallization process in high-salt wastewater .
本申请实施例提供了一种盐淘洗设备,包括:The embodiment of the present application provides a salt elutriation equipment, including:
利用盐腿对盐浆进行一级淘洗;Use salt legs to perform primary elutriation on salt slurry;
将由所述盐腿中流出的盐浆引流至洗盐器内,利用所述洗盐器对所述盐浆进行二级淘洗,并在二级淘洗过程中同时对所述盐浆进行稠厚。Drain the salt slurry flowing out of the salt leg into the salt washer, use the salt washer to perform secondary elutriation on the salt slurry, and simultaneously thicken the salt slurry during the secondary elutriation process thick.
在上述实现过程中,首先利用盐腿对盐浆进行一级淘洗,该步骤中的淘洗与传统盐化工生产过程相似,即通过盐腿首先对盐浆进行淘洗。将盐浆淘洗过的盐浆引流至一个洗盐器中,在该洗盐器中对盐浆进行二次淘洗,为了不增加设备,使该洗盐器具有稠厚器的结构特点,即在利用洗盐器对盐浆进行二次淘洗时可同时对盐浆进行稠厚。采用盐腿和洗盐器相结合的两级强化淘洗,可显著提高分离出的盐的品质。In the above implementation process, firstly, the salt slurry is firstly elutriated by using the salt leg. The elutriation in this step is similar to the traditional salt chemical production process, that is, the salt slurry is firstly elutriated by the salt leg. The salt slurry washed by salt slurry is drained into a salt washing device, and the salt slurry is washed twice in the salt washing device. In order not to increase equipment, the salt washing device has the structural characteristics of a thickener. That is to say, when the salt slurry is washed twice by the salt washer, the salt slurry can be thickened at the same time. Two-stage intensive elutriation using a combination of salt legs and salt scrubbers can significantly improve the quality of the separated salt.
在一种可能的实现方式中,所述利用盐腿对盐浆进行一级淘洗包括:In a possible implementation manner, performing primary elutriation on salt slurry by using salt legs includes:
在所述盐腿的底部向盐腿内通入第一淘洗液,利用第一淘洗液对盐腿中的盐浆进行一级淘洗;Pass the first elutriation solution into the salt leg at the bottom of the salt leg, and use the first elutriation solution to perform primary elutriation on the salt slurry in the salt leg;
所述利用所述洗盐器对所述盐浆进行二级淘洗包括:Said utilizing said salt washer to carry out secondary elutriation to said salt slurry comprises:
在洗盐器的底部向洗盐器内通入第二淘洗液,并利用第二淘洗液对所述盐浆进行二级淘洗。Pass the second elutriation solution into the salt washer at the bottom of the salt washer, and use the second elutriation solution to perform secondary elutriation on the salt slurry.
在上述实现过程中,第一淘洗液自盐腿的底部通入盐腿内,盐腿内的盐浆受重力作用,盐浆中的结晶盐颗粒逐渐富集在盐腿的底部,第一淘洗液自盐腿底部进入盐腿后,与富集的结晶盐颗粒进行对冲,第一淘洗液与结晶盐颗粒充分混合,将结晶盐颗粒表面的含有高浓度杂质的母液进行替换,进而实现对盐浆的淘洗。In the above realization process, the first elutriation solution is passed into the salt leg from the bottom of the salt leg, and the salt slurry in the salt leg is subjected to gravity, and the crystallized salt particles in the salt slurry are gradually enriched at the bottom of the salt leg. After the elutriation solution enters the salt leg from the bottom of the salt leg, it is flushed with the enriched crystallized salt particles, the first elutriation solution is fully mixed with the crystallized salt particles, and the mother liquor containing high-concentration impurities on the surface of the crystallized salt particles is replaced, and then Realize the elutriation of salt slurry.
与之相似地,第二淘洗液自洗盐器的底部通入洗盐器内,洗盐器内的盐浆受重力作用亦富集在洗盐器的底部,第二淘洗液自洗盐器底部进入洗盐器后,与富集的结晶盐颗粒进行对冲,第二淘洗液与结晶盐颗粒充分混合,将结晶盐颗粒表面的含有高浓度杂质的母液进行替换,进而实现对盐浆的强化淘洗。Similarly, the second elutriation liquid is passed into the salt washer from the bottom of the salt washer, and the salt slurry in the salt washer is also enriched at the bottom of the salt washer by gravity, and the second elutriation liquid is self-washed. After the bottom of the salt tank enters the salt washer, it is flushed with the enriched crystallized salt particles, and the second elutriation liquid is fully mixed with the crystallized salt particles to replace the mother liquor containing high-concentration impurities on the surface of the crystallized salt particles, thereby realizing the salt Enhanced elutriation of pulp.
作为一种实施方式,所述第一淘洗液与进入所述盐腿的盐浆的流量体积比为0.2~4;As an embodiment, the flow volume ratio of the first elutriation solution to the salt slurry entering the salt leg is 0.2-4;
所述第二淘洗液与进入所述洗盐器内的盐浆的流量体积比为0.1~4。The flow volume ratio of the second elutriation solution to the salt slurry entering the salt washer is 0.1-4.
在上述实现过程中,在采用蒸发结晶过程进行零排放分盐的工艺中,对盐浆进行淘洗是整个制盐过程中的必要步骤,淘洗设备与其上游设备和下游设备均相互连通。淘洗设备中输入第一淘洗液和第二淘洗液的量,与制盐系统中的蒸发量和热量均有直接关系。若为达到淘洗的效果而不考虑淘洗液的用量,则会影响整个制盐系统的物料平衡和热平衡。而第一淘洗液与进入盐腿的盐浆的流量体积比在0.2~4;第二淘洗液与进入洗盐器内的盐浆的流量体积比在0.1~4之间时,能够保证制盐系统的热平衡和物料平衡。In the above implementation process, in the zero-emission salt separation process using the evaporation crystallization process, elutriation of the salt slurry is a necessary step in the entire salt production process, and the elutriation equipment is connected to its upstream equipment and downstream equipment. The amount of the first elutriation solution and the second elutriation solution input into the elutriation equipment is directly related to the evaporation and heat in the salt making system. If the amount of elutriation solution is not considered in order to achieve the effect of elutriation, it will affect the material balance and heat balance of the entire salt making system. And the flow volume ratio of the first elutriation liquid and the salt slurry entering the salt leg is 0.2~4; when the flow volume ratio of the second elutriation liquid and the salt slurry entering the salt washer is between 0.1~4, it can ensure Heat balance and material balance of salt production system.
在一种可能的实现方式中,在所述洗盐器对所述盐浆进行二级淘洗时,还包括:对所述盐浆进行搅拌。通过对盐浆进行搅拌,淘洗液与盐浆充分混合,能够增强待淘洗盐颗粒表面流体的流速,加快淘洗效率。In a possible implementation manner, when the salt washer performs secondary elutriation on the salt slurry, it further includes: stirring the salt slurry. By stirring the salt slurry, the elutriation solution and the salt slurry are fully mixed, which can enhance the flow rate of the fluid on the surface of the salt particles to be elutriated, and accelerate the elutriation efficiency.
在一种可能的实现方式中,所述第一淘洗液为盐结晶系统进料、蒸馏液、清水、配制的饱和溶液中的一种或者一种以上的组合液;In a possible implementation manner, the first elutriation solution is one or more combinations of the salt crystallization system feed, distillate, clear water, and prepared saturated solution;
所述第二淘洗液为盐结晶系统进料、蒸馏液、清水、配制的饱和溶液中的一种或者一种以上的组合液。The second elutriation solution is one or more combinations of the salt crystallization system feed, distillate, clear water, and prepared saturated solution.
在一种可能的实现方式中,进入所述盐腿的盐浆固含量为2~20%,进入所述洗盐器的盐浆固含量为5~40%,经所述洗盐器二级淘洗后的盐浆固含量为5~50%。In a possible implementation manner, the solid content of the salt slurry entering the salt leg is 2-20%, and the solid content of the salt slurry entering the salt washer is 5-40%. The solid content of the salt slurry after elutriation is 5-50%.
根据本发明的另一个方面,提供了一种盐淘洗设备,包括:According to another aspect of the present invention, a kind of salt elutriation equipment is provided, comprising:
盐腿,用于对盐浆进行一级淘洗;Salt legs for primary elutriation of brine slurry;
洗盐器,对由所述盐腿中流出的盐浆进行二级淘洗,并在二级淘洗过程中同时对所述盐浆进行稠厚。The salt washer is used to perform secondary elutriation on the salt slurry flowing out of the salt leg, and simultaneously thicken the salt slurry during the secondary elutriation process.
在上述实现过程中,采用盐腿对盐浆进行一级淘洗,将盐浆淘洗过的盐浆引流至兼具淘洗和稠厚功能的洗盐器中,该洗盐器中对盐浆进行二次淘洗,同时对盐浆进行稠厚。采用盐腿和洗盐器相结合的两级强化淘洗,可显著提高分离出的盐的品质。In the above realization process, the salt leg is used to carry out one-stage elutriation on the salt slurry, and the salt slurry that has been elutriated by the salt slurry is drained into the salt washing device with both elutriation and thickening functions. The slurry is subjected to secondary elutriation, and the salt slurry is thickened at the same time. Two-stage intensive elutriation using a combination of salt legs and salt scrubbers can significantly improve the quality of the separated salt.
在一种可能的实现方式中,所述洗盐器包括:In a possible implementation manner, the salt scrubber includes:
淘洗筒,包括上下布置的溢流部和淘洗部;所述溢流部的截面面积大于所述淘洗部的截面面积;所述溢流部设有溢流出口;所述淘洗部设置有第二淘洗液进口和盐浆出口;The elutriation cylinder includes an overflow part and an elutriation part arranged up and down; the cross-sectional area of the overflow part is larger than that of the elutriation part; the overflow part is provided with an overflow outlet; the elutriation part It is equipped with a second elutriation solution inlet and a brine slurry outlet;
进浆管,其进口端位于所述溢流部上方并与所述盐腿的出料口连通,所述进浆管出口端穿过所述溢流部并延伸至所述淘洗部内。The inlet end of the slurry inlet pipe is located above the overflow part and communicates with the discharge port of the salt leg, and the outlet end of the slurry inlet pipe passes through the overflow part and extends into the elutriation part.
在上述实现过程中,盐浆从进浆管的进口端进入并沿着进浆管下降到淘洗筒的淘洗部,与淘洗部内盛装的淘洗液混合,淘洗液将盐浆中附着在结晶盐表面的含有高浓度杂质的母液进行冲洗替换。同时,溢流部的截面面积大于淘洗部的截面面积,截面较大的溢流部流速低,水向上的推力不足以克服盐颗粒自身的重力,所以溢流部能够悬浮的颗粒较少。在重力作用下,结晶盐颗粒在淘洗部逐渐富集,实现增稠的作用。In the above realization process, the salt slurry enters from the inlet end of the pulp inlet pipe and descends to the elutriation part of the elutriation cylinder along the pulp inlet pipe, and mixes with the elutriation liquid contained in the elutriation part, and the elutriation liquid will The mother liquor with high concentration of impurities attached to the surface of the crystallized salt is flushed and replaced. At the same time, the cross-sectional area of the overflow part is larger than that of the elutriation part, and the flow velocity of the overflow part with a larger cross-section is low, and the upward thrust of the water is not enough to overcome the gravity of the salt particles themselves, so the overflow part can suspend fewer particles. Under the action of gravity, the crystalline salt particles are gradually enriched in the elutriation section to achieve the thickening effect.
在一种可能的实现方式中,所述洗盐器还包括:搅拌器,设置于所述淘洗部内。搅拌器对盐浆进行搅拌,淘洗液与盐浆充分混合,能够增强待淘洗盐颗粒表面流体的流速,加快淘洗效率。In a possible implementation manner, the salt washer further includes: an agitator disposed in the elutriation part. The agitator stirs the salt slurry, and the elutriation liquid and the salt slurry are fully mixed, which can enhance the flow rate of the fluid on the surface of the salt particles to be elutriated, and accelerate the elutriation efficiency.
在一种可能的实现方式中,所述溢流部和淘洗部通过自上而下渐缩的缓冲部连接。In a possible implementation manner, the overflow part and the elutriation part are connected by a buffer part that tapers from top to bottom.
在一种可能的实现方式中,所述盐腿包括自上而下依次设置的倒圆台筒、中间筒和锥形筒;In a possible implementation manner, the salt leg includes a rounded table cylinder, an intermediate cylinder and a conical cylinder arranged sequentially from top to bottom;
所述锥形筒底部设置第一淘洗液进口;A first elutriation solution inlet is provided at the bottom of the conical cylinder;
所述中间筒设置至少一个出料口。The intermediate cylinder is provided with at least one discharge port.
在上述实现过程中,倒圆台筒的截面面积大于中间筒的截面面积,主要用于滤除不含或少含结晶盐颗粒的清液,为清液的上浮提供通道。结晶盐颗粒在中间筒内向下运动并逐渐富集,进入中间筒内的淘洗液与结晶盐表面的含有高浓度杂质的母液进行冲洗替换,实现对盐浆的一次淘洗。锥形筒的截面积由下至上依次增大,淘洗液由锥形筒底部通入,淘洗液的扩散面积逐步增大,有利于淘洗液与盐浆进行充分混合,淘洗效果更优。In the above implementation process, the cross-sectional area of the inverted table cylinder is larger than that of the intermediate cylinder, which is mainly used to filter out the clear liquid containing no or little crystalline salt particles and provide a channel for the clear liquid to float. The crystallized salt particles move downward in the intermediate cylinder and are gradually enriched. The elutriation solution entering the intermediate cylinder is flushed and replaced with the mother liquor containing high concentration of impurities on the surface of the crystallized salt to realize one-time elutriation of the salt slurry. The cross-sectional area of the conical cylinder increases sequentially from bottom to top, and the elutriation liquid enters from the bottom of the conical cylinder, and the diffusion area of the elutriation liquid gradually increases, which is conducive to the full mixing of the elutriation liquid and the salt slurry, and the elutriation effect is better. excellent.
在一种可能的实现方式中,所述出料口为多个时,多个出料口位于不同的设置高度处。In a possible implementation manner, when there are multiple discharge ports, the multiple discharge ports are located at different installation heights.
在上述实现过程中,中间筒内不同高度富集的结晶盐颗粒的粒径不同,出料口位于不同的设置高度,则可以获得不同粒径的结晶盐颗粒。In the above implementation process, the particle diameters of the crystalline salt particles enriched at different heights in the intermediate cylinder are different, and the discharge ports are located at different setting heights, so that crystalline salt particles with different particle sizes can be obtained.
在一种可能的实现方式中,所述出料口的设置高度高于所述进浆管的进口端的设置高度;或In a possible implementation manner, the setting height of the discharge port is higher than the setting height of the inlet end of the slurry inlet pipe; or
所述出料口的设置高度低于所述进浆管的进口端的设置高度,所述出料口流出的盐浆通过泵输入至所述进浆管中。The setting height of the discharge port is lower than that of the inlet end of the slurry inlet pipe, and the salt slurry flowing out of the discharge port is input into the slurry feed pipe through a pump.
在上述实现过程中,出料口的设置高度高于进浆管的进口端的设置高度,则盐腿中的盐浆可通过重力自流至洗盐器的进浆管中。In the above implementation process, the setting height of the discharge port is higher than that of the inlet end of the slurry inlet pipe, so the salt slurry in the salt leg can flow into the slurry inlet pipe of the salt washer by gravity.
根据本发明的另一方面,还提供了一种制盐装置,包括如上述的盐淘洗设备。According to another aspect of the present invention, a salt production device is also provided, including the above-mentioned salt elutriation equipment.
根据本发明的再一方面,还提供了一种高含盐废水处理系统,包括如上所述的盐淘洗设备。According to yet another aspect of the present invention, a high-salt wastewater treatment system is also provided, including the above-mentioned salt elutriation equipment.
由以上技术方案可知,本申请中的盐淘洗工艺及设备采用盐腿和洗盐器相结合的两级强化淘洗,能够显著提高分离出的盐的品质。It can be known from the above technical solutions that the salt elutriation process and equipment in this application adopts two-stage enhanced elutriation combining salt legs and salt washers, which can significantly improve the quality of the separated salt.
附图说明Description of drawings
为了更清楚地说明本申请实施例的技术方案,下面将对本申请实施例中所需要使用的附图作简单地介绍,应当理解,以下附图仅示出了本申请的某些实施例,因此不应被看作是对范围的限定,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他相关的附图。In order to more clearly illustrate the technical solutions of the embodiments of the present application, the accompanying drawings that need to be used in the embodiments of the present application will be briefly introduced below. It should be understood that the following drawings only show some embodiments of the present application, so It should not be regarded as a limitation on the scope, and those skilled in the art can also obtain other related drawings according to these drawings without creative work.
图1为本申请实施例提供的一种盐淘洗工艺的流程图;Fig. 1 is the flowchart of a kind of salt elutriation process that the embodiment of the application provides;
图2为本申请实施例提供的一种盐淘洗设备的结构示意图。Fig. 2 is a schematic structural diagram of a salt elutriation equipment provided in the embodiment of the present application.
图标:100-盐腿;200-洗盐器;110-倒圆台筒;120-中间筒;121-出料口;130-锥形筒;131-第一淘洗液进口;210-淘洗筒;220-进浆管;230-搅拌器;211-溢流部;212-淘洗部;213-溢流出口;214-第二淘洗液进口;215-盐浆出口;216-缓冲部。Icons: 100-salt leg; 200-salt washer; 110-inversion table cylinder; 120-intermediate cylinder; 121-discharge port; 130-conical cylinder; ; 220-slurry inlet pipe; 230-stirrer; 211-overflow part; 212-elution part; 213-overflow outlet;
具体实施方式Detailed ways
下面将结合本申请实施例中的附图,对本申请实施例中的技术方案进行描述。The technical solutions in the embodiments of the present application will be described below with reference to the drawings in the embodiments of the present application.
应注意到:相似的标号和字母在下面的附图中表示类似项,因此,一旦某一项在一个附图中被定义,则在随后的附图中不需要对其进行进一步定义和解释。同时,在本申请的描述中,术语“第一”、“第二”等仅用于区分描述,而不能理解为指示或暗示相对重要性。It should be noted that like numerals and letters denote similar items in the following figures, therefore, once an item is defined in one figure, it does not require further definition and explanation in subsequent figures. Meanwhile, in the description of the present application, the terms "first", "second" and the like are only used to distinguish descriptions, and cannot be understood as indicating or implying relative importance.
本申请的发明人发现,现有盐化工生产过程中的盐浆较为纯净,在分盐工艺中,通常将盐浆进行淘洗后直接进入增稠器中进行增稠,而高盐废水中往往含有大量杂质无机离子和有机物质,利用传统盐化工中的淘洗设备及淘洗工艺进行淘洗后进入增稠器,并不能将盐水中的大量杂质无机离子和有机物质去除。为了提高分离盐的品质,本申请中的发明人创造性地提出,在基于传统盐化工中的淘洗基础上,对淘洗后的盐浆再次进行淘洗,且该次淘洗尽量不占用单独的淘洗设备,而是再次淘洗与增稠同时进行,基于该思路,本申请的发明人还提供了一套与该想法对应的盐淘洗设备。The inventors of the present application found that the salt slurry in the existing salt chemical production process is relatively pure. In the salt separation process, the salt slurry is usually washed and directly entered into the thickener for thickening, while the high-salt wastewater often Contains a large amount of impurity inorganic ions and organic substances. Using the elutriation equipment and elutriation process in the traditional salt chemical industry to wash and enter the thickener, it cannot remove a large amount of impurity inorganic ions and organic substances in the brine. In order to improve the quality of the separated salt, the inventors in this application creatively proposed that on the basis of elutriation in traditional salt chemical industry, the elutriated salt slurry should be elutriated again, and this elutriation should not occupy a separate unit as much as possible. Instead, elutriation and thickening are carried out at the same time. Based on this idea, the inventor of the present application also provides a set of salt elutriation equipment corresponding to this idea.
下面通过具体的实施例对本申请中的盐淘洗工艺和盐淘洗设备进行详细介绍。The salt elutriation process and salt elutriation equipment in this application will be described in detail below through specific examples.
图1为本申请实施例提供的一种盐淘洗工艺的流程图。由图1所示,盐淘洗工艺包括如下步骤:Fig. 1 is a flow chart of a salt elutriation process provided by the embodiment of the present application. Shown in Figure 1, the salt elutriation process comprises the following steps:
S101:利用盐腿对盐浆进行一级淘洗;S101: using salt legs to perform primary elutriation on the salt slurry;
S102:将由所述盐腿中流出的盐浆引流至洗盐器内,利用所述洗盐器对所述盐浆进行二级淘洗,并在二级淘洗过程中同时对所述盐浆进行稠厚。S102: Drain the salt slurry flowing out of the salt leg into a salt washer, use the salt washer to perform secondary elutriation on the salt slurry, and simultaneously wash the salt slurry during the secondary elutriation process To thicken.
在上述实现过程中,首先利用盐腿对盐浆进行一级淘洗,该步骤中的淘洗与传统盐化工生产过程相似,即通过盐腿首先对盐浆进行淘洗。将盐浆淘洗过的盐浆引流至一个洗盐器中,在该洗盐器中对盐浆进行二次淘洗,为了不增加设备,使该洗盐器具有稠厚器的结构特点,即在利用洗盐器对盐浆进行二次淘洗时可同时对盐浆进行稠厚。采用盐腿和洗盐器相结合的两级强化淘洗,可显著提高分离出的盐的品质。In the above implementation process, firstly, the salt slurry is firstly elutriated by using the salt leg. The elutriation in this step is similar to the traditional salt chemical production process, that is, the salt slurry is firstly elutriated by the salt leg. The salt slurry washed by salt slurry is drained into a salt washing device, and the salt slurry is washed twice in the salt washing device. In order not to increase equipment, the salt washing device has the structural characteristics of a thickener. That is to say, when the salt slurry is washed twice by the salt washer, the salt slurry can be thickened at the same time. Two-stage intensive elutriation using a combination of salt legs and salt scrubbers can significantly improve the quality of the separated salt.
在一种可能的实现方式中,利用盐腿对盐浆进行一级淘洗包括:In one possible implementation, primary elutriation of salt slurry using salt legs includes:
在盐腿的底部向盐腿内通入第一淘洗液,利用第一淘洗液对盐腿中的盐浆进行一级淘洗;Pass the first elutriation liquid into the salt leg at the bottom of the salt leg, and use the first elutriation liquid to carry out primary elutriation to the salt slurry in the salt leg;
利用洗盐器对盐浆进行二级淘洗包括:Secondary elutriation of brine slurry using a salt scrubber includes:
在洗盐器的底部向洗盐器内通入第二淘洗液,并利用第二淘洗液对盐浆进行二级淘洗。The second elutriation liquid is passed into the salt washer at the bottom of the salt washer, and the salt slurry is subjected to secondary elutriation by using the second elutriation liquid.
在上述实现过程中,第一淘洗液自盐腿的底部通入盐腿内,盐腿内的盐浆受重力作用,盐浆中的结晶盐颗粒逐渐富集在盐腿的底部,第一淘洗液自盐腿底部进入盐腿后,与富集的结晶盐颗粒进行对冲,第一淘洗液与结晶盐颗粒充分混合,将结晶盐颗粒表面的含有高浓度杂质的母液进行替换,进而实现对盐浆的淘洗。In the above realization process, the first elutriation solution is passed into the salt leg from the bottom of the salt leg, and the salt slurry in the salt leg is subjected to gravity, and the crystallized salt particles in the salt slurry are gradually enriched at the bottom of the salt leg. After the elutriation solution enters the salt leg from the bottom of the salt leg, it is flushed with the enriched crystallized salt particles, the first elutriation solution is fully mixed with the crystallized salt particles, and the mother liquor containing high-concentration impurities on the surface of the crystallized salt particles is replaced, and then Realize the elutriation of salt slurry.
与之相似地,第二淘洗液自洗盐器的底部通入洗盐器内,洗盐器内的盐浆受重力作用亦富集在洗盐器的底部,第二淘洗液自洗盐器底部进入洗盐器后,与富集的结晶盐颗粒进行对冲,第二淘洗液与结晶盐颗粒充分混合,将结晶盐颗粒表面的含有高浓度杂质的母液进行替换,进而实现对盐浆的强化淘洗。Similarly, the second elutriation liquid is passed into the salt washer from the bottom of the salt washer, and the salt slurry in the salt washer is also enriched at the bottom of the salt washer by gravity, and the second elutriation liquid is self-washed. After the bottom of the salt tank enters the salt washer, it is flushed with the enriched crystallized salt particles, and the second elutriation liquid is fully mixed with the crystallized salt particles to replace the mother liquor containing high-concentration impurities on the surface of the crystallized salt particles, thereby realizing the salt Enhanced elutriation of pulp.
作为一种实施方式,第一淘洗液与进入盐腿的盐浆的流量体积比为0.2~4;第二淘洗液与进入洗盐器内的盐浆的流量体积比为0.1~4。As an embodiment, the flow volume ratio of the first elutriation liquid to the salt slurry entering the salt leg is 0.2-4; the flow volume ratio of the second elutriation liquid to the salt slurry entering the salt washer is 0.1-4.
在采用蒸发结晶过程进行零排放分盐的工艺中,对盐浆进行淘洗是整个制盐过程中的必要步骤,淘洗设备与其上游设备和下游设备均相互连通。淘洗设备中输入第一淘洗液和第二淘洗液的量,与制盐系统中的蒸发量和热量均有直接关系。若为达到淘洗的效果而不考虑淘洗液的用量,则会影响整个制盐系统的物料平衡和热平衡。而第一淘洗液与进入盐腿的盐浆的流量体积比在0.2~4;第二淘洗液与进入洗盐器内的盐浆的流量体积比在0.1~4之间时,能够保证制盐系统的热平衡和物料平衡。In the zero-emission salt separation process using the evaporation crystallization process, elutriation of the salt slurry is a necessary step in the entire salt production process, and the elutriation equipment is connected to its upstream equipment and downstream equipment. The amount of the first elutriation solution and the second elutriation solution input into the elutriation equipment is directly related to the evaporation and heat in the salt making system. If the amount of elutriation solution is not considered in order to achieve the effect of elutriation, it will affect the material balance and heat balance of the entire salt making system. And the flow volume ratio of the first elutriation liquid and the salt slurry entering the salt leg is 0.2~4; when the flow volume ratio of the second elutriation liquid and the salt slurry entering the salt washer is between 0.1~4, it can ensure Heat balance and material balance of salt production system.
在一种可能的实现方式中,在洗盐器对盐浆进行二级淘洗时,还包括对盐浆进行搅拌。通过对盐浆进行搅拌,淘洗液与盐浆充分混合,能够增强待淘洗盐颗粒表面流体的流速,加快淘洗效率。In a possible implementation manner, when the salt washer performs secondary elutriation on the salt slurry, stirring the salt slurry is also included. By stirring the salt slurry, the elutriation solution and the salt slurry are fully mixed, which can enhance the flow rate of the fluid on the surface of the salt particles to be elutriated, and accelerate the elutriation efficiency.
在一种可能的实现方式中,第一淘洗液为盐结晶系统进料、蒸馏液、清水、配制的饱和溶液中的一种或者一种以上的组合液;In a possible implementation manner, the first elutriation solution is one or more than one combination of the salt crystallization system feed, distillate, clear water, and prepared saturated solution;
第二淘洗液为盐结晶系统进料、蒸馏液、清水、配制的饱和溶液中的一种或者一种以上的组合液。The second elutriation solution is one or more than one combination of the salt crystallization system feed, distillate, clear water, and prepared saturated solution.
在一种可能的实现方式中,进入盐腿的盐浆固含量为2~20%,进入洗盐器的盐浆固含量为5~40%,经洗盐器二级淘洗后的盐浆固含量为5~50%。In a possible implementation, the solid content of the salt slurry entering the salt leg is 2-20%, the solid content of the salt slurry entering the salt washer is 5-40%, and the salt slurry after secondary elutriation in the salt washer The solid content is 5-50%.
根据本发明的另一个方面,提供了一种盐淘洗设备。图2为本申请实施例提供的一种盐淘洗设备的结构示意图。由图2所示,盐淘洗设备包括盐腿100和洗盐器200。According to another aspect of the present invention, a salt elutriation apparatus is provided. Fig. 2 is a schematic structural diagram of a salt elutriation equipment provided in the embodiment of the present application. As shown in FIG. 2 , the salt elutriation equipment includes a salt leg 100 and a salt washer 200 .
盐腿100用于对盐浆进行一级淘洗;洗盐器200对由盐腿100中流出的盐浆进行二级淘洗,并在二级淘洗过程中同时对盐浆进行稠厚。The salt leg 100 is used for primary elutriation of the salt slurry; the salt washer 200 is used for secondary elutriation of the brine slurry flowing out of the salt leg 100, and simultaneously thickens the salt slurry during the secondary elutriation process.
在上述实现过程中,采用盐腿100对盐浆进行一级淘洗,将盐浆淘洗过的盐浆引流至兼具淘洗和稠厚功能的洗盐器200中,该洗盐器200中对盐浆进行二次淘洗,同时对盐浆进行稠厚。采用盐腿100和洗盐器200相结合的两级强化淘洗,可显著提高分离出的盐的品质。In the above implementation process, the salt leg 100 is used to perform primary elutriation on the salt slurry, and the salt slurry elutriated by the salt slurry is drained into the salt washer 200 which has both elutriation and thickening functions. The salt washer 200 In the middle, the salt slurry is washed twice, and the salt slurry is thickened at the same time. The two-stage enhanced elutriation combined with the salt leg 100 and the salt washer 200 can significantly improve the quality of the separated salt.
在一种可能的实现方式中,参见图2,洗盐器200包括淘洗筒210和进浆管220。In a possible implementation manner, referring to FIG. 2 , the salt washer 200 includes an elutriation cylinder 210 and a slurry feeding pipe 220 .
淘洗筒210包括上下布置的溢流部211和淘洗部212。溢流部211设有溢流出口213;淘洗筒210还设置有第二淘洗液进口214和盐浆出口215。The elutriation cylinder 210 includes an overflow portion 211 and an elutriation portion 212 arranged up and down. The overflow part 211 is provided with an overflow outlet 213 ; the elutriation cylinder 210 is also provided with a second elutriation solution inlet 214 and a brine slurry outlet 215 .
进浆管220,其进口端位于溢流部211上方,出口端穿过溢流部211并延伸至淘洗部212内。The inlet end of the slurry inlet pipe 220 is located above the overflow portion 211 , and the outlet end passes through the overflow portion 211 and extends into the elutriation portion 212 .
在上述实现过程中,盐浆从进浆管220的进口端进入并沿着进浆管220下降到淘洗筒210的淘洗部212,与淘洗部212内盛装的淘洗液混合,淘洗液将盐浆中附着在结晶盐表面的含有高浓度杂质的母液进行冲洗替换。同时,溢流部211的截面面积大于淘洗部212的截面面积,截面较大的溢流部211流速低,水向上的推力不足以克服盐颗粒自身的重力,所以溢流部211能够悬浮的颗粒较少。在重力作用下,结晶盐颗粒在淘洗部212逐渐富集,实现增稠的作用。In the above implementation process, the salt slurry enters from the inlet end of the pulp inlet pipe 220 and descends to the elutriation part 212 of the elutriation cylinder 210 along the pulp inlet pipe 220, mixes with the elutriation liquid contained in the elutriation part 212, and elutriates The washing liquid washes and replaces the mother liquor containing high concentration of impurities attached to the surface of the crystallized salt in the salt slurry. Simultaneously, the cross-sectional area of the overflow part 211 is greater than the cross-sectional area of the elutriation part 212, and the overflow part 211 with a larger cross-section has a low flow rate, and the upward thrust of the water is not enough to overcome the gravity of the salt particles themselves, so the overflow part 211 can be suspended Less grainy. Under the action of gravity, the crystallized salt particles are gradually enriched in the elutriation part 212 to realize the effect of thickening.
在一种可能的实现方式中,洗盐器200还包括设置于淘洗部212内的搅拌器230。搅拌器230对盐浆进行搅拌,淘洗液与盐浆充分混合,能够增强待淘洗盐颗粒表面流体的流速,加快淘洗效率。In a possible implementation manner, the salt washer 200 further includes an agitator 230 disposed in the elutriation part 212 . The stirrer 230 stirs the salt slurry, and the elutriation solution is fully mixed with the salt slurry, which can increase the flow rate of the fluid on the surface of the salt particles to be elutriated, and accelerate the elutriation efficiency.
在一种可能的实现方式中,溢流部211和淘洗部212通过自上而下渐缩的缓冲部216连接。In a possible implementation manner, the overflow part 211 and the elutriation part 212 are connected by a buffer part 216 that tapers from top to bottom.
在上述实现过程中,溢流部211的截面面积大于淘洗部212的截面面积,溢流部211中水流的流速较慢,淘洗部212的流速相对溢流部211较快,缓冲部216的截面逐渐变小,可对溢流部211和淘洗部212交接处的水流进行缓冲,使溢流区尽可能少地存在悬浮颗粒,为清液的上浮提供通道。In the above implementation process, the cross-sectional area of the overflow portion 211 is larger than the cross-sectional area of the elutriation portion 212, the flow velocity of the water flow in the overflow portion 211 is relatively slow, and the flow velocity of the elutriation portion 212 is faster than the overflow portion 211, and the buffer portion 216 The cross section of the cross section gradually becomes smaller, which can buffer the water flow at the junction of the overflow part 211 and the elutriation part 212, so that there are as few suspended particles as possible in the overflow area, and provide a channel for the supernatant to float up.
在一种可能的实现方式中,盐腿100包括自上而下依次设置的倒圆台筒110、中间筒120和锥形筒130。锥形筒130底部设置第一淘洗液进口131;中间筒120设置至少一个出料口121。In a possible implementation manner, the salt leg 100 includes a rounded table cylinder 110 , a middle cylinder 120 and a conical cylinder 130 arranged sequentially from top to bottom. The bottom of the conical cylinder 130 is provided with a first elutriation liquid inlet 131 ; the middle cylinder 120 is provided with at least one discharge port 121 .
在上述实现过程中,倒圆台筒110的截面面积大于中间筒120的截面面积,主要用于滤除不含或少含结晶盐颗粒的清液,为清液的上浮提供通道。结晶盐颗粒在中间筒120内向下运动并逐渐富集,进入中间筒120内的淘洗液与结晶盐表面的含有高浓度杂质的母液进行冲洗替换,实现对盐浆的一次淘洗。锥形筒130的截面积由下至上依次增大,淘洗液由锥形筒130底部通入,淘洗液的扩散面积逐步增大,有利于淘洗液与盐浆进行充分混合,淘洗效果更优。In the above implementation process, the cross-sectional area of the rounded table cylinder 110 is larger than that of the intermediate cylinder 120, and is mainly used to filter out the clear liquid containing no or little crystallized salt particles and provide a channel for the clear liquid to float up. The crystallized salt particles move downward in the intermediate cylinder 120 and are gradually enriched. The elutriation liquid entering the intermediate cylinder 120 is flushed and replaced with the mother liquor containing high concentration of impurities on the surface of the crystallized salt, realizing one-time elutriation of the salt slurry. The cross-sectional area of the conical cylinder 130 increases sequentially from bottom to top, and the elutriation liquid is introduced from the bottom of the conical cylinder 130, and the diffusion area of the elutriation liquid gradually increases, which is conducive to the full mixing of the elutriation liquid and the salt slurry, and the elutriation The effect is better.
在一种可能的实现方式中,出料口为多个时,多个出料口位于不同的设置高度处。In a possible implementation manner, when there are multiple discharge ports, the multiple discharge ports are located at different installation heights.
在上述实现过程中,中间筒120内不同高度富集的结晶盐颗粒的粒径不同,出料口位于不同的设置高度,则可以获得不同粒径的结晶盐颗粒。In the above implementation process, the particle diameters of the crystalline salt particles enriched at different heights in the intermediate cylinder 120 are different, and the outlets are located at different installation heights, so that crystalline salt particles with different particle sizes can be obtained.
在一种可能的实现方式中,出料口的设置高度高于进浆管220的进口端的设置高度。In a possible implementation manner, the setting height of the discharge port is higher than the setting height of the inlet end of the pulp inlet pipe 220 .
在上述实现过程中,出料口的设置高度高于进浆管220的进口端的设置高度,则盐腿100中的盐浆可通过重力自流至洗盐器200的进浆管220中。In the above implementation process, the setting height of the discharge port is higher than that of the inlet end of the slurry inlet pipe 220 , so the salt slurry in the salt leg 100 can flow into the slurry inlet pipe 220 of the salt washer 200 by gravity.
需要说明的是,出料口的设置高度也可不高于进浆管220的进口端的设置高度。在出料口的设置高度低于进浆管220进口端的设置高度时,可通过泵送的方式将盐腿100中的盐浆输入至洗盐器200的进浆管220中。It should be noted that the setting height of the discharge port may not be higher than the setting height of the inlet end of the pulp inlet pipe 220 . When the setting height of the discharge port is lower than the setting height of the inlet end of the slurry inlet pipe 220 , the salt slurry in the salt leg 100 can be input into the slurry inlet pipe 220 of the salt washer 200 by means of pumping.
根据本发明的另一方面,提供了一种包括上述盐淘洗设备的制盐装置。According to another aspect of the present invention, a salt production device comprising the above-mentioned salt elutriation equipment is provided.
根据本发明的再一方面,提供了一种包括上述盐淘洗设备的高含盐废水处理系统。According to yet another aspect of the present invention, a high-salt wastewater treatment system comprising the above-mentioned salt elutriation equipment is provided.
在本申请所提供的几个实施例中,应该理解到,所揭露的装置和方法,也可以通过其它的方式实现。以上所述仅为本申请的实施例而已,并不用于限制本申请的保护范围,对于本领域的技术人员来说,本申请可以有各种更改和变化。凡在本申请的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本申请的保护范围之内。应注意到:相似的标号和字母在下面的附图中表示类似项,因此,一旦某一项在一个附图中被定义,则在随后的附图中不需要对其进行进一步定义和解释。In the several embodiments provided in this application, it should be understood that the disclosed devices and methods may also be implemented in other ways. The above descriptions are only examples of the present application, and are not intended to limit the scope of protection of the present application. For those skilled in the art, various modifications and changes may be made to the present application. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of this application shall be included within the protection scope of this application. It should be noted that like numerals and letters denote similar items in the following figures, therefore, once an item is defined in one figure, it does not require further definition and explanation in subsequent figures.
需要说明的是,在本文中,诸如第一和第二等之类的关系术语仅仅用来将一个实体或者操作与另一个实体或操作区分开来,而不一定要求或者暗示这些实体或操作之间存在任何这种实际的关系或者顺序。而且,术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素,而且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、物品或者设备所固有的要素。在没有更多限制的情况下,由语句“包括一个……”限定的要素,并不排除在包括所述要素的过程、方法、物品或者设备中还存在另外的相同要素。It should be noted that in this article, relational terms such as first and second are only used to distinguish one entity or operation from another entity or operation, and do not necessarily require or imply that there is a relationship between these entities or operations. There is no such actual relationship or order between them. Furthermore, the term "comprises", "comprises" or any other variation thereof is intended to cover a non-exclusive inclusion such that a process, method, article or apparatus comprising a set of elements includes not only those elements, but also includes elements not expressly listed. other elements of or also include elements inherent in such a process, method, article, or device. Without further limitations, an element defined by the phrase "comprising a ..." does not exclude the presence of additional identical elements in the process, method, article or apparatus comprising said element.
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