CN110387097A - A kind of hybrid alloys formula of ABS, PVC - Google Patents
A kind of hybrid alloys formula of ABS, PVC Download PDFInfo
- Publication number
- CN110387097A CN110387097A CN201910771655.1A CN201910771655A CN110387097A CN 110387097 A CN110387097 A CN 110387097A CN 201910771655 A CN201910771655 A CN 201910771655A CN 110387097 A CN110387097 A CN 110387097A
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- parts
- abs
- pvc
- formula
- hybrid alloys
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- 239000000956 alloy Substances 0.000 title claims abstract description 27
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 26
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 39
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 39
- 239000003063 flame retardant Substances 0.000 claims abstract description 28
- 239000000463 material Substances 0.000 claims abstract description 14
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 13
- 239000012745 toughening agent Substances 0.000 claims abstract description 13
- 239000004793 Polystyrene Substances 0.000 claims abstract description 12
- 229920002223 polystyrene Polymers 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims description 12
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 5
- 239000002313 adhesive film Substances 0.000 claims description 5
- 238000012662 bulk polymerization Methods 0.000 claims description 5
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 5
- 239000000314 lubricant Substances 0.000 claims description 5
- 238000007342 radical addition reaction Methods 0.000 claims description 5
- -1 styrene monomer free radical Chemical class 0.000 claims description 5
- 239000000725 suspension Substances 0.000 claims description 5
- QNNXEUPKHFCUKS-UHFFFAOYSA-J [Ca+2].[Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O Chemical compound [Ca+2].[Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O QNNXEUPKHFCUKS-UHFFFAOYSA-J 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 229920006389 polyphenyl polymer Polymers 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000035939 shock Effects 0.000 abstract description 3
- 238000005406 washing Methods 0.000 abstract description 3
- 238000005267 amalgamation Methods 0.000 abstract description 2
- 229920002521 macromolecule Polymers 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 238000002464 physical blending Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses the hybrid alloys formula of a kind of ABS, PVC, the formula includes polyvinyl chloride 20-40 parts, 10-30 parts of polystyrene, 10-15 parts of fire retardant, 10-20 parts of toughener and 1-10 parts of other auxiliary agents.There is higher anti-flammability in the present invention with the hybrid alloys that ABS, PVC is made in polyvinyl chloride, polystyrene, fire retardant, toughener and other auxiliary agents, there is the shock resistance relatively done, there are good amalgamation and impact resistance, the prices of raw materials are lower compared to the prices of raw materials of other materials, it reduces costs, suitable for the production of the electrical appliances shell such as computer, router, TV and washing machine and the production of its nonmetallic accessory, application range is wider.
Description
Technical field
The present invention relates to a kind of hybrid alloys formula, the hybrid alloys formula of specially a kind of ABS, PVC, belong to ABS,
PVC Alloyapplication technical field.
Background technique
PVC alloy is the composite material that the various kinds of resin blending and modifying based on PVC obtains, herein " alloy " two word with
Metal is simultaneously irrelevant, and PVC alloy is the high-performance obtained using physical blending or chemical grafting method, functionalization, dedicated
A kind of new material of change.PVC alloy product can be widely used for automobile, electronics, precision instrument, office equipment, packaging material, building
The fields such as material.It can improve or improve the performance of existing plastics and reduce cost, it has also become the most active in plastics industry
One of kind increases very rapid.
The prices of raw materials of traditional PVC alloy material are higher, result in its higher cost, for the material application and
Promote band inconvenience.Therefore, the hybrid alloys formula of a kind of ABS, PVC are proposed regarding to the issue above.
Summary of the invention
The object of the invention is that providing the hybrid alloys formula of a kind of ABS, PVC to solve the above-mentioned problems.
The present invention is achieved through the following technical solutions above-mentioned purpose, and a kind of hybrid alloys formula of ABS, PVC is described to match
Side includes polyvinyl chloride 20-40 parts, 10-30 parts of polystyrene, 10-15 parts of fire retardant, 10-20 parts of toughener and other auxiliary agents
1-10 parts.
Preferably, the polyvinyl chloride is poly- using bulk polymerization, suspension polymerisation, emulsion polymerization, microsuspension polymerization and solution
A kind of mode is obtained in conjunction.
Preferably, the polystyrene refers to the polymer by styrene monomer free radical addition polymerization.
Preferably, the toughener, which refers to, can increase the flexible substance of adhesive film layer.
Preferably, other described auxiliary agents are by one of lubricant, age resister or calcium stearate zinc stabilizer or a variety of
It constitutes.
Preferably, the fire retardant assigns the functional aid of combustible polymers flame retardancy, primarily directed to macromolecule material
The Principle And Method of Flame Retardation Design of material；There are many types for fire retardant, are divided into additive flame retardant and reactive flame retardant by application method.
The beneficial effects of the present invention are: in the present invention with polyvinyl chloride, polystyrene, fire retardant, toughener and other
The hybrid alloys that ABS, PVC is made in auxiliary agent have higher anti-flammability, there is the shock resistance relatively done, and have good amalgamation
And impact resistance, the prices of raw materials are lower compared to the prices of raw materials of other materials, reduce costs, be suitable for computer,
The production of the electrical appliances shell such as router, TV and washing machine and the production of its nonmetallic accessory, application range are wider.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment one:
A kind of hybrid alloys formula of ABS, PVC, the formula includes 40 parts of polyvinyl chloride, 20 parts of polystyrene, fire-retardant
10 parts of 10 parts of agent, 10 parts of toughener and other auxiliary agents.
Preferably, the polyvinyl chloride is poly- using bulk polymerization, suspension polymerisation, emulsion polymerization, microsuspension polymerization and solution
A kind of mode is obtained in conjunction.
Preferably, the polystyrene refers to the polymer by styrene monomer free radical addition polymerization.
Preferably, the toughener, which refers to, can increase the flexible substance of adhesive film layer.
Preferably, other described auxiliary agents are made of lubricant and age resister.
Preferably, the fire retardant assigns the functional aid of combustible polymers flame retardancy, primarily directed to macromolecule material
The Principle And Method of Flame Retardation Design of material；There are many types for fire retardant, are divided into additive flame retardant and reactive flame retardant by application method.
The hybrid alloys of ABS, PVC made from above-mentioned formula have higher shock resistance, are suitable for the families such as washing machine
Electricity.
Embodiment two:
A kind of hybrid alloys formula of ABS, PVC, the formula includes 30 parts of polyvinyl chloride, 30 parts of polystyrene, fire-retardant
5 parts of 15 parts of agent, 20 parts of toughener and other auxiliary agents.
Preferably, the polyvinyl chloride is poly- using bulk polymerization, suspension polymerisation, emulsion polymerization, microsuspension polymerization and solution
A kind of mode is obtained in conjunction.
Preferably, the polystyrene refers to the polymer by styrene monomer free radical addition polymerization.
Preferably, the toughener, which refers to, can increase the flexible substance of adhesive film layer.
Preferably, other described auxiliary agents are made of lubricant, age resister and calcium stearate zinc stabilizer.
Preferably, the fire retardant assigns the functional aid of combustible polymers flame retardancy, primarily directed to macromolecule material
The Principle And Method of Flame Retardation Design of material；There are many types for fire retardant, are divided into additive flame retardant and reactive flame retardant by application method.
The hybrid alloys of ABS, PVC made from above-mentioned formula have stronger anti-flammability.
Embodiment three:
A kind of hybrid alloys formula of ABS, PVC, the formula includes 30 parts of polyvinyl chloride, 20 parts of polystyrene, fire-retardant
10 parts of 10 parts of agent, 15 parts of toughener and other auxiliary agents.
Preferably, the polyvinyl chloride is poly- using bulk polymerization, suspension polymerisation, emulsion polymerization, microsuspension polymerization and solution
A kind of mode is obtained in conjunction.
Preferably, the polystyrene refers to the polymer by styrene monomer free radical addition polymerization.
Preferably, the toughener, which refers to, can increase the flexible substance of adhesive film layer.
Preferably, other described auxiliary agents are lubricant and age resister.
Preferably, the fire retardant assigns the functional aid of combustible polymers flame retardancy, primarily directed to macromolecule material
The Principle And Method of Flame Retardation Design of material；There are many types for fire retardant, are divided into additive flame retardant and reactive flame retardant by application method.
The hybrid alloys of ABS, PVC made from above-mentioned formula have higher anti-aging property.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (6)
1. the hybrid alloys formula of a kind of ABS, PVC, it is characterised in that: the formula includes polyvinyl chloride 20-40 parts, polyphenyl second
10-30 parts of alkene, 10-15 parts of fire retardant, 10-20 parts of toughener and 1-10 parts of other auxiliary agents.
2. the hybrid alloys formula of a kind of ABS, PVC according to claim 1, it is characterised in that: the polyvinyl chloride is adopted
It is made with mode a kind of in bulk polymerization, suspension polymerisation, emulsion polymerization, microsuspension polymerization and polymerisation in solution.
3. the hybrid alloys formula of a kind of ABS, PVC according to claim 1, it is characterised in that: the polystyrene is
Refer to the polymer by styrene monomer free radical addition polymerization.
4. the hybrid alloys formula of a kind of ABS, PVC according to claim 1, it is characterised in that: the toughener refers to
It can increase the flexible substance of adhesive film layer.
5. the hybrid alloys formula of a kind of ABS, PVC according to claim 1, it is characterised in that: other described auxiliary agents by
One of lubricant, age resister or calcium stearate zinc stabilizer or a variety of compositions.
6. the hybrid alloys formula of a kind of ABS, PVC according to claim 1, it is characterised in that: the fire retardant assigns
The functional aid of combustible polymers flame retardancy, primarily directed to the Principle And Method of Flame Retardation Design of high molecular material；There are many classes for fire retardant
Type is divided into additive flame retardant and reactive flame retardant by application method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910771655.1A CN110387097A (en) | 2019-08-21 | 2019-08-21 | A kind of hybrid alloys formula of ABS, PVC |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910771655.1A CN110387097A (en) | 2019-08-21 | 2019-08-21 | A kind of hybrid alloys formula of ABS, PVC |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110387097A true CN110387097A (en) | 2019-10-29 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910771655.1A Pending CN110387097A (en) | 2019-08-21 | 2019-08-21 | A kind of hybrid alloys formula of ABS, PVC |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110387097A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0295982B1 (en) * | 1987-06-04 | 1994-11-02 | Elf Atochem S.A. | Compatibilisation agent and use therof in preparing thermoplastic polymer alloys |
| CN102477206A (en) * | 2010-11-29 | 2012-05-30 | 合肥杰事杰新材料股份有限公司 | Flame-retardant antistatic ABS/PVC alloy material and preparation method thereof |
| CN102731936A (en) * | 2012-07-20 | 2012-10-17 | 西安科技大学 | PVC (polyvinyl chloride)/styrene polymer alloy and preparation method thereof |
-
2019
- 2019-08-21 CN CN201910771655.1A patent/CN110387097A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0295982B1 (en) * | 1987-06-04 | 1994-11-02 | Elf Atochem S.A. | Compatibilisation agent and use therof in preparing thermoplastic polymer alloys |
| CN102477206A (en) * | 2010-11-29 | 2012-05-30 | 合肥杰事杰新材料股份有限公司 | Flame-retardant antistatic ABS/PVC alloy material and preparation method thereof |
| CN102731936A (en) * | 2012-07-20 | 2012-10-17 | 西安科技大学 | PVC (polyvinyl chloride)/styrene polymer alloy and preparation method thereof |
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| PB01 | Publication | ||
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Application publication date: 20191029 |