CN110358219A - It is a kind of can be with the PVC interior material of formaldehyde adsorption - Google Patents
It is a kind of can be with the PVC interior material of formaldehyde adsorption Download PDFInfo
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- CN110358219A CN110358219A CN201910668875.1A CN201910668875A CN110358219A CN 110358219 A CN110358219 A CN 110358219A CN 201910668875 A CN201910668875 A CN 201910668875A CN 110358219 A CN110358219 A CN 110358219A
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- Prior art keywords
- parts
- interior material
- formaldehyde adsorption
- pvc interior
- soybean oil
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title claims abstract description 100
- 239000000463 material Substances 0.000 title claims abstract description 35
- 238000001179 sorption measurement Methods 0.000 title claims abstract description 30
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 38
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 38
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 15
- 239000003549 soybean oil Substances 0.000 claims abstract description 15
- 239000011347 resin Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000004088 foaming agent Substances 0.000 claims abstract description 12
- 239000004014 plasticizer Substances 0.000 claims abstract description 11
- 239000003381 stabilizer Substances 0.000 claims abstract description 9
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003086 colorant Substances 0.000 claims abstract description 8
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid group Chemical group C(C=1C(C(=O)O)=CC=CC1)(=O)O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011787 zinc oxide Substances 0.000 claims abstract description 8
- 239000002649 leather substitute Substances 0.000 claims abstract description 6
- -1 2- propylheptyl Chemical group 0.000 claims abstract description 4
- 150000002148 esters Chemical class 0.000 claims abstract description 4
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 4
- SUDKDSWHVLJFHP-UHFFFAOYSA-N C(=O)N.C(=O)N.[N] Chemical compound C(=O)N.C(=O)N.[N] SUDKDSWHVLJFHP-UHFFFAOYSA-N 0.000 claims 1
- 235000010469 Glycine max Nutrition 0.000 claims 1
- 244000068988 Glycine max Species 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 235000019198 oils Nutrition 0.000 claims 1
- 239000004065 semiconductor Substances 0.000 abstract description 7
- 239000003054 catalyst Substances 0.000 abstract description 5
- 239000002957 persistent organic pollutant Substances 0.000 abstract description 5
- 239000004156 Azodicarbonamide Substances 0.000 abstract description 3
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical group NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 abstract description 3
- 235000019399 azodicarbonamide Nutrition 0.000 abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 230000007704 transition Effects 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000003574 free electron Substances 0.000 description 2
- 229910021389 graphene Inorganic materials 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 230000001603 reducing effect Effects 0.000 description 2
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0023—Use of organic additives containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
- C08J9/0071—Nanosized fillers, i.e. having at least one dimension below 100 nanometers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
- D06N3/0045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers obtained by applying a ready-made foam layer; obtained by compressing, crinkling or crushing a foam layer, e.g. Kaschierverfahren für Schaumschicht
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/165—Odour absorbing, deodorizing ability
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Textile Engineering (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Nanotechnology (AREA)
- Emergency Medicine (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The invention discloses one kind can be with the PVC interior material of formaldehyde adsorption, formula material includes polyvinyl chloride resin, plasticizer, soybean oil, calcium zinc stabilizer, foaming agent, colorant and UN3077, and formula material is by weight ratio are as follows: polyvinyl chloride resin is 100 parts, plasticizer is 80 parts, soybean oil is 3 parts, calcium zinc stabilizer is 3 parts, foaming agent is 4 parts, colorant is 4 parts and UN3077 is 3 parts;The polyvinyl chloride resin average degree of polymerization is 1250~1370;The plasticizer is phthalic acid two (2- propylheptyl) ester;The soybean oil is a kind of epoxidized soybean oil;The foaming agent is azodicarbonamide;The UN3077 is a kind of nanoscale zinc oxide, and purity >=97% of the UN3077;It is described can be with the PVC interior material of formaldehyde adsorption for a kind of synthetic leather products, and described can offer several loopholes with the PVC interior material surface of formaldehyde adsorption;The present invention, can more large area the organic pollutant for being adsorbed on semiconductor catalyst surface is aoxidized, while being conducive to formaldehyde adsorption.
Description
Technical field
The present invention relates to interior trim PVC leather substance fields, and specially one kind can be with the PVC interior material of formaldehyde adsorption.
Background technique
Since formaldehyde has presence in room, the enclosed environments such as car and textile and food, in life
Each corner, seriously threatens human health.It is to use activated carbon adsorption mostly for the removal of formaldehyde on the market at present, for first
The removal of aldehyde, but active carbon PARA FORMALDEHYDE PRILLS(91,95) adsorption capacity is weaker, absorption can reach saturation, and be easy after reaching saturation by the external world
Factor influences, and is desorbed, causes secondary pollution, and common PVC interior material it is also possible to bring formaldehyde into the feed, and more
Add increase indoor and in-car formaldehyde content, while the material formaldehyde adsorption of same size and handle are adsorbed on semiconductor catalyst table
The surface area of the organic pollutant oxidation in face is small, so that adsorption effect is poor;For these defects, thus we design one kind can be with
The PVC interior material of formaldehyde adsorption is necessary.
Summary of the invention
The purpose of the present invention is to provide one kind can be with the PVC interior material of formaldehyde adsorption, can the handle absorption of more large area
Organic pollutant on semiconductor catalyst surface aoxidizes, while being conducive to formaldehyde adsorption.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of can include polyvinyl chloride resin, plasticizer, soybean oil, calcium zinc with the PVC interior material of formaldehyde adsorption, formula material
Stabilizer, foaming agent, colorant and UN3077, formula material is by weight ratio are as follows: polyvinyl chloride resin is 100 parts, plasticizer 80
Part, soybean oil are 3 parts, calcium zinc stabilizer is 3 parts, foaming agent is 4 parts, colorant is 4 parts and UN3077 is 3 parts.
As a further solution of the present invention: the polyvinyl chloride resin average degree of polymerization is 1250~1370.
As a further solution of the present invention: the plasticizer is phthalic acid two (2- propylheptyl) ester.
As a further solution of the present invention: the soybean oil is a kind of epoxidized soybean oil.
As a further solution of the present invention: the foaming agent is azodicarbonamide.
As a further solution of the present invention: the UN3077 is a kind of nanoscale zinc oxide, and the UN3077
Purity >=97%.
As a further solution of the present invention: it is described can with the PVC interior material of formaldehyde adsorption be a kind of synthetic leather products,
And described several loopholes can be offered with the PVC interior material surface of formaldehyde adsorption.
Beneficial effects of the present invention: producing synthetic leather with this formula, which plays the role of automatic absorbing formaldehyde,
UN3077 increases zinc oxide specific surface area by the way that graphene is added, urges in light as a kind of nanoscale zinc oxide in the formula
Change the lower energy that can be obtained from incident photon greater than its valence band, the electrons in semiconductor valence band occur energy level transition, generate
Have an extremely strong active free state electronics, in electron transition to conduction band after will generate corresponding hole in corresponding valence band, lead
It takes with free electron, forms so-called electron-hole pair, light induced electron has strong reducing property, and corresponding hole has
Strong oxidizing property can aoxidize the organic pollutant for being adsorbed on semiconductor catalyst surface, while be conducive to formaldehyde adsorption, PVC
Interior material surface offers several loopholes, is conducive to the contact area and contact surface area that increase light.
Specific embodiment
Technical solution of the present invention is clearly and completely described below in conjunction with embodiment, it is clear that described reality
Applying example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is general
Logical technical staff all other embodiment obtained without creative efforts belongs to what the present invention protected
Range.
A kind of can include polyvinyl chloride resin, plasticizer, soybean oil, calcium zinc with the PVC interior material of formaldehyde adsorption, formula material
Stabilizer, foaming agent, colorant and UN3077, formula material is by weight ratio are as follows: polyvinyl chloride resin is 100 parts, plasticizer 80
Part, soybean oil are 3 parts, calcium zinc stabilizer is 3 parts, foaming agent is 4 parts, colorant is 4 parts and UN3077 is 3 parts;
Wherein, polyvinyl chloride resin average degree of polymerization is 1250~1370, as main resin;
Wherein, plasticizer is phthalic acid two (2- propylheptyl) ester;
Wherein, soybean oil is a kind of epoxidized soybean oil, is used as stabilizer;
Wherein, foaming agent is azodicarbonamide;
Wherein, UN3077 is a kind of nanoscale zinc oxide, and purity >=97% of UN3077 makes as formaldehyde absorbent
With;
Wherein it is possible to which the PVC interior material of formaldehyde adsorption is a kind of synthetic leather products, and can be in the PVC of formaldehyde adsorption
Exterior material surface offers several loopholes.
The working principle of the invention: producing synthetic leather with this formula, which plays the role of automatic absorbing formaldehyde,
UN3077 increases zinc oxide specific surface area by the way that graphene is added, urges in light as a kind of nanoscale zinc oxide in the formula
Change the lower energy that can be obtained from incident photon greater than its valence band, the electrons in semiconductor valence band occur energy level transition, generate
Have an extremely strong active free state electronics, in electron transition to conduction band after will generate corresponding hole in corresponding valence band, lead
It takes with free electron, forms so-called electron-hole pair, light induced electron has strong reducing property, and corresponding hole has
Strong oxidizing property can aoxidize the organic pollutant for being adsorbed on semiconductor catalyst surface, while be conducive to formaldehyde adsorption, PVC
Interior material surface offers several loopholes, is conducive to the contact area and contact surface area that increase light.
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.There is no detailed for preferred embodiment
All details are described, are not limited the invention to the specific embodiments described.Obviously, according to the content of this specification,
It can make many modifications and variations.These embodiments are chosen and specifically described to this specification, is in order to better explain the present invention
Principle and practical application, so that skilled artisan be enable to better understand and utilize the present invention.The present invention is only
It is limited by claims and its full scope and equivalent.
Claims (7)
1. one kind can be with the PVC interior material of formaldehyde adsorption, which is characterized in that formula material includes polyvinyl chloride resin, plasticizer, big
Soya-bean oil, calcium zinc stabilizer, foaming agent, colorant and UN3077, formula material is by weight ratio are as follows: polyvinyl chloride resin is 100 parts, increases
Modeling agent is 80 parts, soybean oil is 3 parts, calcium zinc stabilizer is 3 parts, foaming agent is 4 parts, colorant is 4 parts and UN3077 is 3 parts.
2. according to claim 1 can be with the PVC interior material of formaldehyde adsorption, which is characterized in that the polyvinyl chloride resin is average
The degree of polymerization is 1250~1370.
3. according to claim 1 can be with the PVC interior material of formaldehyde adsorption, which is characterized in that the plasticizer is neighbour
Phthalic acid two (2- propylheptyl) ester.
4. according to claim 1 can be with the PVC interior material of formaldehyde adsorption, which is characterized in that the soybean oil is one
Kind epoxidized soybean oil.
5. according to claim 1 can be with the PVC interior material of formaldehyde adsorption, which is characterized in that the foaming agent is even
Nitrogen diformamide.
6. according to claim 1 can be with the PVC interior material of formaldehyde adsorption, which is characterized in that the UN3077 is one
Kind nanoscale zinc oxide, and purity >=97% of the UN3077.
7. according to claim 1 can be with the PVC interior material of formaldehyde adsorption described in -6, which is characterized in that described to adsorb
The PVC interior material of formaldehyde is a kind of synthetic leather products, and if described can be offered with the PVC interior material surface of formaldehyde adsorption
Dry loophole.
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JP2018184556A (en) * | 2017-04-27 | 2018-11-22 | 新日本理化株式会社 | Vinyl chloride resin composition in which coloring is suppressed during high-temperature use |
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2019
- 2019-07-24 CN CN201910668875.1A patent/CN110358219A/en active Pending
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CN1789321A (en) * | 2005-12-07 | 2006-06-21 | 华东师范大学 | Nano zinc oxide/polyvinyl chloride composite material and its preparation method |
CN104164788A (en) * | 2014-07-31 | 2014-11-26 | 佛山高明骏腾塑胶有限公司 | PVC calendering foaming artificial leather and preparation method thereof |
JP2018184556A (en) * | 2017-04-27 | 2018-11-22 | 新日本理化株式会社 | Vinyl chloride resin composition in which coloring is suppressed during high-temperature use |
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Application publication date: 20191022 |