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CN110358219A - It is a kind of can be with the PVC interior material of formaldehyde adsorption - Google Patents

It is a kind of can be with the PVC interior material of formaldehyde adsorption Download PDF

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Publication number
CN110358219A
CN110358219A CN201910668875.1A CN201910668875A CN110358219A CN 110358219 A CN110358219 A CN 110358219A CN 201910668875 A CN201910668875 A CN 201910668875A CN 110358219 A CN110358219 A CN 110358219A
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CN
China
Prior art keywords
parts
interior material
formaldehyde adsorption
pvc interior
soybean oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910668875.1A
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Chinese (zh)
Inventor
张金晖
丁磊
王元鑫
王汝武
唐炯辉
黄俊斌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUZHOU BEISITE DECORATION NEW MATERIAL Co Ltd
Original Assignee
SUZHOU BEISITE DECORATION NEW MATERIAL Co Ltd
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Publication date
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Priority to CN201910668875.1A priority Critical patent/CN110358219A/en
Publication of CN110358219A publication Critical patent/CN110358219A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0023Use of organic additives containing oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
    • C08J9/0071Nanosized fillers, i.e. having at least one dimension below 100 nanometers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102Azo-compounds
    • C08J9/103Azodicarbonamide
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0043Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
    • D06N3/0045Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers obtained by applying a ready-made foam layer; obtained by compressing, crinkling or crushing a foam layer, e.g. Kaschierverfahren für Schaumschicht
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/04N2 releasing, ex azodicarbonamide or nitroso compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2491/00Characterised by the use of oils, fats or waxes; Derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/16Properties of the materials having other properties
    • D06N2209/165Odour absorbing, deodorizing ability
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/12Decorative or sun protection articles
    • D06N2211/28Artificial leather

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Textile Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Nanotechnology (AREA)
  • Emergency Medicine (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

The invention discloses one kind can be with the PVC interior material of formaldehyde adsorption, formula material includes polyvinyl chloride resin, plasticizer, soybean oil, calcium zinc stabilizer, foaming agent, colorant and UN3077, and formula material is by weight ratio are as follows: polyvinyl chloride resin is 100 parts, plasticizer is 80 parts, soybean oil is 3 parts, calcium zinc stabilizer is 3 parts, foaming agent is 4 parts, colorant is 4 parts and UN3077 is 3 parts;The polyvinyl chloride resin average degree of polymerization is 1250~1370;The plasticizer is phthalic acid two (2- propylheptyl) ester;The soybean oil is a kind of epoxidized soybean oil;The foaming agent is azodicarbonamide;The UN3077 is a kind of nanoscale zinc oxide, and purity >=97% of the UN3077;It is described can be with the PVC interior material of formaldehyde adsorption for a kind of synthetic leather products, and described can offer several loopholes with the PVC interior material surface of formaldehyde adsorption;The present invention, can more large area the organic pollutant for being adsorbed on semiconductor catalyst surface is aoxidized, while being conducive to formaldehyde adsorption.

Description

It is a kind of can be with the PVC interior material of formaldehyde adsorption
Technical field
The present invention relates to interior trim PVC leather substance fields, and specially one kind can be with the PVC interior material of formaldehyde adsorption.
Background technique
Since formaldehyde has presence in room, the enclosed environments such as car and textile and food, in life Each corner, seriously threatens human health.It is to use activated carbon adsorption mostly for the removal of formaldehyde on the market at present, for first The removal of aldehyde, but active carbon PARA FORMALDEHYDE PRILLS(91,95) adsorption capacity is weaker, absorption can reach saturation, and be easy after reaching saturation by the external world Factor influences, and is desorbed, causes secondary pollution, and common PVC interior material it is also possible to bring formaldehyde into the feed, and more Add increase indoor and in-car formaldehyde content, while the material formaldehyde adsorption of same size and handle are adsorbed on semiconductor catalyst table The surface area of the organic pollutant oxidation in face is small, so that adsorption effect is poor;For these defects, thus we design one kind can be with The PVC interior material of formaldehyde adsorption is necessary.
Summary of the invention
The purpose of the present invention is to provide one kind can be with the PVC interior material of formaldehyde adsorption, can the handle absorption of more large area Organic pollutant on semiconductor catalyst surface aoxidizes, while being conducive to formaldehyde adsorption.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of can include polyvinyl chloride resin, plasticizer, soybean oil, calcium zinc with the PVC interior material of formaldehyde adsorption, formula material Stabilizer, foaming agent, colorant and UN3077, formula material is by weight ratio are as follows: polyvinyl chloride resin is 100 parts, plasticizer 80 Part, soybean oil are 3 parts, calcium zinc stabilizer is 3 parts, foaming agent is 4 parts, colorant is 4 parts and UN3077 is 3 parts.
As a further solution of the present invention: the polyvinyl chloride resin average degree of polymerization is 1250~1370.
As a further solution of the present invention: the plasticizer is phthalic acid two (2- propylheptyl) ester.
As a further solution of the present invention: the soybean oil is a kind of epoxidized soybean oil.
As a further solution of the present invention: the foaming agent is azodicarbonamide.
As a further solution of the present invention: the UN3077 is a kind of nanoscale zinc oxide, and the UN3077 Purity >=97%.
As a further solution of the present invention: it is described can with the PVC interior material of formaldehyde adsorption be a kind of synthetic leather products, And described several loopholes can be offered with the PVC interior material surface of formaldehyde adsorption.
Beneficial effects of the present invention: producing synthetic leather with this formula, which plays the role of automatic absorbing formaldehyde, UN3077 increases zinc oxide specific surface area by the way that graphene is added, urges in light as a kind of nanoscale zinc oxide in the formula Change the lower energy that can be obtained from incident photon greater than its valence band, the electrons in semiconductor valence band occur energy level transition, generate Have an extremely strong active free state electronics, in electron transition to conduction band after will generate corresponding hole in corresponding valence band, lead It takes with free electron, forms so-called electron-hole pair, light induced electron has strong reducing property, and corresponding hole has Strong oxidizing property can aoxidize the organic pollutant for being adsorbed on semiconductor catalyst surface, while be conducive to formaldehyde adsorption, PVC Interior material surface offers several loopholes, is conducive to the contact area and contact surface area that increase light.
Specific embodiment
Technical solution of the present invention is clearly and completely described below in conjunction with embodiment, it is clear that described reality Applying example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is general Logical technical staff all other embodiment obtained without creative efforts belongs to what the present invention protected Range.
A kind of can include polyvinyl chloride resin, plasticizer, soybean oil, calcium zinc with the PVC interior material of formaldehyde adsorption, formula material Stabilizer, foaming agent, colorant and UN3077, formula material is by weight ratio are as follows: polyvinyl chloride resin is 100 parts, plasticizer 80 Part, soybean oil are 3 parts, calcium zinc stabilizer is 3 parts, foaming agent is 4 parts, colorant is 4 parts and UN3077 is 3 parts;
Wherein, polyvinyl chloride resin average degree of polymerization is 1250~1370, as main resin;
Wherein, plasticizer is phthalic acid two (2- propylheptyl) ester;
Wherein, soybean oil is a kind of epoxidized soybean oil, is used as stabilizer;
Wherein, foaming agent is azodicarbonamide;
Wherein, UN3077 is a kind of nanoscale zinc oxide, and purity >=97% of UN3077 makes as formaldehyde absorbent With;
Wherein it is possible to which the PVC interior material of formaldehyde adsorption is a kind of synthetic leather products, and can be in the PVC of formaldehyde adsorption Exterior material surface offers several loopholes.
The working principle of the invention: producing synthetic leather with this formula, which plays the role of automatic absorbing formaldehyde, UN3077 increases zinc oxide specific surface area by the way that graphene is added, urges in light as a kind of nanoscale zinc oxide in the formula Change the lower energy that can be obtained from incident photon greater than its valence band, the electrons in semiconductor valence band occur energy level transition, generate Have an extremely strong active free state electronics, in electron transition to conduction band after will generate corresponding hole in corresponding valence band, lead It takes with free electron, forms so-called electron-hole pair, light induced electron has strong reducing property, and corresponding hole has Strong oxidizing property can aoxidize the organic pollutant for being adsorbed on semiconductor catalyst surface, while be conducive to formaldehyde adsorption, PVC Interior material surface offers several loopholes, is conducive to the contact area and contact surface area that increase light.
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.There is no detailed for preferred embodiment All details are described, are not limited the invention to the specific embodiments described.Obviously, according to the content of this specification, It can make many modifications and variations.These embodiments are chosen and specifically described to this specification, is in order to better explain the present invention Principle and practical application, so that skilled artisan be enable to better understand and utilize the present invention.The present invention is only It is limited by claims and its full scope and equivalent.

Claims (7)

1. one kind can be with the PVC interior material of formaldehyde adsorption, which is characterized in that formula material includes polyvinyl chloride resin, plasticizer, big Soya-bean oil, calcium zinc stabilizer, foaming agent, colorant and UN3077, formula material is by weight ratio are as follows: polyvinyl chloride resin is 100 parts, increases Modeling agent is 80 parts, soybean oil is 3 parts, calcium zinc stabilizer is 3 parts, foaming agent is 4 parts, colorant is 4 parts and UN3077 is 3 parts.
2. according to claim 1 can be with the PVC interior material of formaldehyde adsorption, which is characterized in that the polyvinyl chloride resin is average The degree of polymerization is 1250~1370.
3. according to claim 1 can be with the PVC interior material of formaldehyde adsorption, which is characterized in that the plasticizer is neighbour Phthalic acid two (2- propylheptyl) ester.
4. according to claim 1 can be with the PVC interior material of formaldehyde adsorption, which is characterized in that the soybean oil is one Kind epoxidized soybean oil.
5. according to claim 1 can be with the PVC interior material of formaldehyde adsorption, which is characterized in that the foaming agent is even Nitrogen diformamide.
6. according to claim 1 can be with the PVC interior material of formaldehyde adsorption, which is characterized in that the UN3077 is one Kind nanoscale zinc oxide, and purity >=97% of the UN3077.
7. according to claim 1 can be with the PVC interior material of formaldehyde adsorption described in -6, which is characterized in that described to adsorb The PVC interior material of formaldehyde is a kind of synthetic leather products, and if described can be offered with the PVC interior material surface of formaldehyde adsorption Dry loophole.
CN201910668875.1A 2019-07-24 2019-07-24 It is a kind of can be with the PVC interior material of formaldehyde adsorption Pending CN110358219A (en)

Priority Applications (1)

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CN201910668875.1A CN110358219A (en) 2019-07-24 2019-07-24 It is a kind of can be with the PVC interior material of formaldehyde adsorption

Applications Claiming Priority (1)

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CN201910668875.1A CN110358219A (en) 2019-07-24 2019-07-24 It is a kind of can be with the PVC interior material of formaldehyde adsorption

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CN110358219A true CN110358219A (en) 2019-10-22

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1789321A (en) * 2005-12-07 2006-06-21 华东师范大学 Nano zinc oxide/polyvinyl chloride composite material and its preparation method
CN104164788A (en) * 2014-07-31 2014-11-26 佛山高明骏腾塑胶有限公司 PVC calendering foaming artificial leather and preparation method thereof
CN107190521A (en) * 2017-05-24 2017-09-22 贝内克-长顺汽车内饰材料(张家港)有限公司 A kind of low smell PVC artificial leather and preparation method thereof
CN107310231A (en) * 2017-06-28 2017-11-03 江门市大丰皮革有限公司 A kind of automotive trim PVC artificial leather of noise control anti-soil environmental protection
CN107903535A (en) * 2017-12-08 2018-04-13 广东技塑新材料股份有限公司 Low smell has the PVC automotive interior materials and preparation method of sterilizing function
JP2018184556A (en) * 2017-04-27 2018-11-22 新日本理化株式会社 Vinyl chloride resin composition in which coloring is suppressed during high-temperature use

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1789321A (en) * 2005-12-07 2006-06-21 华东师范大学 Nano zinc oxide/polyvinyl chloride composite material and its preparation method
CN104164788A (en) * 2014-07-31 2014-11-26 佛山高明骏腾塑胶有限公司 PVC calendering foaming artificial leather and preparation method thereof
JP2018184556A (en) * 2017-04-27 2018-11-22 新日本理化株式会社 Vinyl chloride resin composition in which coloring is suppressed during high-temperature use
CN107190521A (en) * 2017-05-24 2017-09-22 贝内克-长顺汽车内饰材料(张家港)有限公司 A kind of low smell PVC artificial leather and preparation method thereof
CN107310231A (en) * 2017-06-28 2017-11-03 江门市大丰皮革有限公司 A kind of automotive trim PVC artificial leather of noise control anti-soil environmental protection
CN107903535A (en) * 2017-12-08 2018-04-13 广东技塑新材料股份有限公司 Low smell has the PVC automotive interior materials and preparation method of sterilizing function

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
天津市第二塑料制品厂 天津轻工业学院编: "《塑料挤出成型工艺及设备》", 30 November 1971, 天津人民出版社 *
李玲 等: "甲醛气体在ZnO表面光降解的机理研究", 《影像科学与光化学》 *

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Application publication date: 20191022