CN110343381A - A kind of flame-resistant polyphenylether material - Google Patents
A kind of flame-resistant polyphenylether material Download PDFInfo
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- CN110343381A CN110343381A CN201910615033.XA CN201910615033A CN110343381A CN 110343381 A CN110343381 A CN 110343381A CN 201910615033 A CN201910615033 A CN 201910615033A CN 110343381 A CN110343381 A CN 110343381A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08L71/12—Polyphenylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
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- Health & Medical Sciences (AREA)
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- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of flame-resistant polyphenylether materials, its raw material includes: 60-80 parts of polyphenylene oxide by weight, 26-34 parts of impact resistance polystyrene, 0.4-0.6 parts of antioxidant, 0.4-0.6 parts of anti-dripping agent PTEE, 0.8-1.2 parts of crosslinking agent, 1.5-2 parts of lubricant, 2.8-3.7 parts of compatilizer, 5-7 parts of elastomer, 25-30 parts of fire retardant；Wherein, fire retardant is bisphenol-A bis- (diphenyl phosphates), polyphenyl methyl siloxane.The present invention is cooperated by each substance so that the present invention has good anti-flammability, stress crack resistance performance, melt fluidity and processability.
Description
Technical field
The present invention relates to plastics arts more particularly to a kind of flame-resistant polyphenylether materials.
Background technique
The chemical name of polyphenylene oxide is poly- 2,6- dimethyl-Isosorbide-5-Nitrae-phenylate, abbreviation PPO or PPE, also known as polyphenylene oxygen
Compound or polyphenylene ether.
PPO is mainly used for electronic apparatus, automobile, household electrical appliance, office equipment and industrial machinery etc..PPO is nontoxic,
It is transparent, relative density is small, there is excellent mechanical strength, proof stress relaxation, creep resistance, heat resistance, fire-retardant, water resistance, resistance to
Water vapour, dimensional stability.The good electrical property in very wide temperature, frequency range, major defect are that melt fluidity is poor, processing
Difficult forming, stress crack resistance performance are lower.
Currently, it is main by addition plastics, resin, elastomer etc., to improve its melt fluidity, processability and proof stress
Cracking behavior；But with the addition of plastics, resin, elastomer etc., the anti-flammability of PPO can be reduced.
Summary of the invention
Technical problems based on background technology, the invention proposes a kind of flame-resistant polyphenylether material, the present invention passes through
Each substance cooperates so that the present invention has good anti-flammability, stress crack resistance performance, melt fluidity and processability.
A kind of flame-resistant polyphenylether material proposed by the present invention, raw material include: 60-80 parts of polyphenylene oxide by weight, anti-impact
26-34 parts of hitting property polystyrene, 0.4-0.6 parts of antioxidant, 0.4-0.6 parts of anti-dripping agent PTEE, 0.8-1.2 parts of crosslinking agent, profit
1.5-2 parts of lubrication prescription, 2.8-3.7 parts of compatilizer, 5-7 parts of elastomer, 25-30 parts of fire retardant；Wherein, fire retardant is the bis- (phosphorus of bisphenol-A
Diphenyl phthalate), polyphenyl methyl siloxane.
Preferably, in the preparation process of elastomer, by ethylene-vinyl acetate copolymer, SEBS thermoplastic elastomer (TPE) and
Modified Nano kaolin mixes, and adjusting revolving speed is that 100-150 turns/min, and ball milling 7-9h obtains elastomer.
Preferably, modified Nano kaolin is γ-methacryloxypropyl trimethoxy silane modified Nano kaolinite
Soil.
Preferably, ethylene-vinyl acetate copolymer, SEBS thermoplastic elastomer (TPE) and the kaolinic weight ratio of modified Nano are
1-2:5-6:0.2-0.4.
Preferably, the weight ratio 18-24:5-10 of bisphenol-A bis- (diphenyl phosphates), polyphenyl methyl siloxane.
Preferably, polyphenylene oxide is PPO 040.
Preferably, impact resistance polystyrene is HIPS 3441.
Preferably, compatilizer is maleic anhydride graft compatilizer.
Above-mentioned PPO 040, HIPS 3441, anti-dripping agent PTEE are commercially available.
The present invention is prepared according to this field common process.
The present invention selects PPO 040 and HIPS 3441 to be used as major ingredient, is cooperated with suitable proportion, improves polyphenylene oxide
Stress crack resistance performance improves melt fluidity and processability, but is reduction of the anti-flammability of polyphenylene oxide, and appropriate amount is added in selection
Elastomer, modified Nano kaolin is contained in elastomer, can be dispersed in polyphenylene oxide, increase the anti-flammability of polyphenylene oxide, and
After suitable technique ball milling mixes, so that SEBS thermoplastic elastomer (TPE) and ethylene-vinyl acetate copolymer intercalation enter kaolinite
It between soil layer, then cooperates with polyphenylene oxide, can further improve the stress crack resistance performance of polyphenylene oxide, improve melt fluidity
And processability, and ethylene-vinyl acetate copolymer and maleic anhydride graft compatilizer cooperate, can promote PPO 040,
HIPS 3441 and elastomer compatibility, it is evenly dispersed, then cooperate the kaolin of intercalation, proof stress of the invention can be greatly increased
Cracking performance improves melt fluidity and processability；It selects bisphenol-A bis- (diphenyl phosphates), polyphenyl methyl siloxane and changes
Property nano kaoline cooperate, greatly increase anti-flammability of the invention, and polyphenyl methyl siloxane can be in polyphenylene oxide
Middle introducing Si-O chain, increases the flexibility of polyphenylene oxide, to further improve stress crack resistance performance of the invention, melt fluidity
And processability；Anti-dripping agent PTEE further increases anti-flammability of the invention；Maleic anhydride graft compatilizer is mutual with lubricant
Cooperation, so that each substance is evenly dispersed, increases mechanical performance of the invention；Above-mentioned each substance cooperates so that the present invention has
Good anti-flammability, stress crack resistance performance, melt fluidity and processability.
Specific embodiment
In the following, technical solution of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of flame-resistant polyphenylether material, raw material include: 60 parts of polyphenylene oxide by weight, impact resistance polystyrene 34
Part, 0.4 part of antioxidant, 0.6 part of anti-dripping agent PTEE, 0.8 part of crosslinking agent, 2 parts of lubricant, 2.8 parts of compatilizer, elastomer 7
Part, 25 parts of fire retardant；Wherein, fire retardant is bisphenol-A bis- (diphenyl phosphates), polyphenyl methyl siloxane.
Embodiment 2
A kind of flame-resistant polyphenylether material, raw material include: 040 80 parts of PPO by weight, 3,441 26 parts of HIPS, are resisted
0.6 part of oxygen agent, 0.4 part of anti-dripping agent PTEE, 1.2 parts of crosslinking agent, 1.5 parts of lubricant, 3.7 parts of maleic anhydride graft compatilizer,
5 parts of elastomer, 30 parts of fire retardant；Wherein, fire retardant is bisphenol-A bis- (diphenyl phosphates), polyphenyl methyl siloxane；
Wherein, in the preparation process of elastomer, by ethylene-vinyl acetate copolymer, SEBS thermoplastic elastomer (TPE) and γ-
Methacryloxypropyl trimethoxy silane modified Nano kaolin mixes, and adjusting revolving speed is 100 turns/min, and ball milling 9h is obtained
To elastomer, wherein ethylene-vinyl acetate copolymer, SEBS thermoplastic elastomer (TPE) and the kaolinic weight ratio of modified Nano are
1:6:0.2.
Embodiment 3
A kind of flame-resistant polyphenylether material, raw material include: 040 65 parts of PPO by weight, 3,441 32 parts of HIPS, are resisted
0.45 part of oxygen agent, 0.55 part of anti-dripping agent PTEE, 0.9 part of crosslinking agent, 1.8 parts of lubricant, 3 parts of maleic anhydride graft compatilizer,
6.5 parts of elastomer, 26 parts of fire retardant；Wherein, fire retardant is bisphenol-A bis- (diphenyl phosphates), polyphenyl methyl siloxane；
Wherein, in the preparation process of elastomer, by ethylene-vinyl acetate copolymer, SEBS thermoplastic elastomer (TPE) and γ-
Methacryloxypropyl trimethoxy silane modified Nano kaolin mixes, and adjusting revolving speed is 150 turns/min, and ball milling 7h is obtained
To elastomer, wherein ethylene-vinyl acetate copolymer, SEBS thermoplastic elastomer (TPE) and the kaolinic weight ratio of modified Nano are
2:5:0.4；
The weight ratio 18:10 of bisphenol-A bis- (diphenyl phosphates), polyphenyl methyl siloxane.
Embodiment 4
A kind of flame-resistant polyphenylether material, raw material include: 040 75 parts of PPO by weight, 3,441 28 parts of HIPS, are resisted
0.55 part of oxygen agent, 0.45 part of anti-dripping agent PTEE, 1.1 parts of crosslinking agent, 1.6 parts of lubricant, maleic anhydride graft compatilizer 3.5
Part, 5.5 parts of elastomer, 28 parts of fire retardant；Wherein, fire retardant is bisphenol-A bis- (diphenyl phosphates), polyphenyl methyl siloxane；
Wherein, in the preparation process of elastomer, by ethylene-vinyl acetate copolymer, SEBS thermoplastic elastomer (TPE) and γ-
Methacryloxypropyl trimethoxy silane modified Nano kaolin mixes, and adjusting revolving speed is 110 turns/min, ball milling 8.5h
Obtain elastomer, wherein ethylene-vinyl acetate copolymer, SEBS thermoplastic elastomer (TPE) and the kaolinic weight ratio of modified Nano
For 1.2:5.7:0.25；
The weight ratio 24:5 of bisphenol-A bis- (diphenyl phosphates), polyphenyl methyl siloxane.
Embodiment 5
A kind of flame-resistant polyphenylether material, raw material include: 040 70 parts of PPO by weight, 3,441 30 parts of HIPS, are resisted
0.5 part of oxygen agent, 0.5 part of anti-dripping agent PTEE, 1 part of crosslinking agent, 1.7 parts of lubricant, 3.3 parts of maleic anhydride graft compatilizer, bullet
6 parts of body, 27 parts of fire retardant of property；Wherein, fire retardant is bisphenol-A bis- (diphenyl phosphates), polyphenyl methyl siloxane；
Wherein, in the preparation process of elastomer, by ethylene-vinyl acetate copolymer, SEBS thermoplastic elastomer (TPE) and γ-
Methacryloxypropyl trimethoxy silane modified Nano kaolin mixes, and adjusting revolving speed is 125 turns/min, and ball milling 8h is obtained
To elastomer, wherein ethylene-vinyl acetate copolymer, SEBS thermoplastic elastomer (TPE) and the kaolinic weight ratio of modified Nano are
1.5:5.5:0.3；
The weight ratio 21:6 of bisphenol-A bis- (diphenyl phosphates), polyphenyl methyl siloxane.
Reference examples 1: being not added fire retardant and elastomer, other are the same as embodiment 5.
Embodiment 5, the performance of reference examples 1 are detected, as a result as follows:
As can be seen from the above table, good flame resistance of the present invention, melt flow rate (MFR) is high, and notch shock power is high.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (8)
1. a kind of flame-resistant polyphenylether material, which is characterized in that its raw material includes: 60-80 parts of polyphenylene oxide by weight, impact resistance
26-34 parts of polystyrene, 0.4-0.6 parts of antioxidant, 0.4-0.6 parts of anti-dripping agent PTEE, 0.8-1.2 parts of crosslinking agent, lubricant
1.5-2 parts, 2.8-3.7 parts of compatilizer, 5-7 parts of elastomer, 25-30 parts of fire retardant；Wherein, fire retardant is the bis- (di(2-ethylhexyl)phosphates of bisphenol-A
Phenyl ester), polyphenyl methyl siloxane.
2. flame-resistant polyphenylether material according to claim 1, which is characterized in that in the preparation process of elastomer, by ethylene-
Acetate ethylene copolymer, SEBS thermoplastic elastomer (TPE) and modified Nano kaolin mix, and adjusting revolving speed is that 100-150 turns/min,
Ball milling 7-9h obtains elastomer.
3. flame-resistant polyphenylether material according to claim 2, which is characterized in that modified Nano kaolin is γ-metering system
Acryloxypropylethoxysilane trimethoxy silane modified Nano kaolin.
4. the flame-resistant polyphenylether material according to Claims 2 or 3, which is characterized in that ethylene-vinyl acetate copolymer, SEBS
Thermoplastic elastomer (TPE) and the kaolinic weight ratio of modified Nano are 1-2:5-6:0.2-0.4.
5. any one of -4 flame-resistant polyphenylether material according to claim 1, which is characterized in that bisphenol-A bis- (diphenyl phosphates),
The weight ratio 18-24:5-10 of polyphenyl methyl siloxane.
6. any one of -5 flame-resistant polyphenylether material according to claim 1, which is characterized in that polyphenylene oxide is PPO 040.
7. any one of -6 flame-resistant polyphenylether material according to claim 1, which is characterized in that impact resistance polystyrene is
HIPS 3441。
8. any one of -7 flame-resistant polyphenylether material according to claim 1, which is characterized in that compatilizer is maleic anhydride grafting
Compatilizer.
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| CN201910615033.XA CN110343381A (en) | 2019-07-09 | 2019-07-09 | A kind of flame-resistant polyphenylether material |
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| CN201910615033.XA CN110343381A (en) | 2019-07-09 | 2019-07-09 | A kind of flame-resistant polyphenylether material |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113527860A (en) * | 2021-06-29 | 2021-10-22 | 江西岳峰集团环保新材有限公司 | Preparation method of PPO composite material with high melt flowability |
| WO2022110667A1 (en) * | 2020-11-30 | 2022-06-02 | 金发科技股份有限公司 | Kaolin-reinforced polyphenylene ether composition, preparation method thereof and use thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805508A (en) * | 2010-03-26 | 2010-08-18 | 北京化工大学 | Halogen-free fire-retardant polyphenyl ether composition capable of improving low-temperature toughness and preparation method thereof |
| CN101880451A (en) * | 2010-07-23 | 2010-11-10 | 北京化工大学 | A kind of halogen-free flame-retardant polyphenylene ether compound and its preparation method |
| CN103044894A (en) * | 2011-10-14 | 2013-04-17 | 比亚迪股份有限公司 | Modified polyphenyl ether composition and preparation method thereof |
-
2019
- 2019-07-09 CN CN201910615033.XA patent/CN110343381A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805508A (en) * | 2010-03-26 | 2010-08-18 | 北京化工大学 | Halogen-free fire-retardant polyphenyl ether composition capable of improving low-temperature toughness and preparation method thereof |
| CN101880451A (en) * | 2010-07-23 | 2010-11-10 | 北京化工大学 | A kind of halogen-free flame-retardant polyphenylene ether compound and its preparation method |
| CN103044894A (en) * | 2011-10-14 | 2013-04-17 | 比亚迪股份有限公司 | Modified polyphenyl ether composition and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 何领好 等: "《功能高分子材料》", 31 August 2016, 华中科技大学出版社 * |
| 张书华 等: "《高性能电缆材料及其应用技术》", 30 November 2015, 上海交通大学出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022110667A1 (en) * | 2020-11-30 | 2022-06-02 | 金发科技股份有限公司 | Kaolin-reinforced polyphenylene ether composition, preparation method thereof and use thereof |
| CN113527860A (en) * | 2021-06-29 | 2021-10-22 | 江西岳峰集团环保新材有限公司 | Preparation method of PPO composite material with high melt flowability |
| CN113527860B (en) * | 2021-06-29 | 2022-07-19 | 江西岳峰集团环保新材有限公司 | Preparation method of PPO composite material with high melt flowability |
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Application publication date: 20191018 |