Disclosure of Invention
Aiming at the defects in the prior art, the invention provides the cable tube plugging agent and the use method thereof.
In order to achieve the purpose, the invention adopts the technical scheme that:
the component A comprises the following components in parts by weight:
the component B is prepared from diphenylmethane diisocyanate and polyphenyl polymethylene polyisocyanate in a mass ratio of 90: (8-10) mixing;
A. the proportion of the two components is as follows by mass ratio: 100: (70-80).
In order to achieve the flame retardant effect, the cable tube plugging agent further comprises a component C, wherein the component C is a composite efficient flame retardant; A. b, C the proportion of the three components is as follows by mass ratio: 100 (70-80): (25-30).
In order to further improve the flame retardant effect, the composite efficient flame retardant is preferably expanded graphite powder with the mesh number of 200-300.
Preferably, the dihydroxy polyether is at least one of N-210, N-220 and N-240.
Preferably, the chain extender is 3,3 '-dichloro-4, 4' -diaminodiphenylmethane. 3,3 '-dichloro-4, 4' -diaminodiphenylmethane is an elastomer chain extender, and has a high hydroxyl value and a low viscosity.
Preferably, the cross-linking agent is polyether polyol DV-125. The crosslinking agent can increase the foaming hardness and the curing speed.
Preferably, the amine trimerization catalyst is at least one of DMP-30, DABCO TMR and polycat 41.
A using method of a cable tube plugging agent comprises the following steps:
s1, preparing A, B two components into a W material and a B material respectively, and filling the W material and the B material into plastic bags respectively; or preparing the material A into a material W, mixing the B, C components in proportion to prepare a material B, and filling the material W and the material B into plastic bags respectively;
s2, sleeving the first plugging plate on the cable in a ring mode, and plugging the first plugging plate into the cable pipe to be 7-10 cm deep;
s3, sleeving a second plugging plate on the cable in a ring mode, and plugging the second plugging plate into the cable tube to a depth of 1-4 cm; the first plugging plate, the cable and the second plugging plate enclose an injection molding space, and the second plugging plate is provided with an injection molding opening communicated with the injection molding space;
s4, mixing the material W and the material B in a plastic bag according to a set proportion, quickly kneading the mixed liquid for 15-90 seconds, and injecting the mixed liquid into an injection molding space through an insertion pipe; after standing for several minutes, the mixed liquid is expanded and solidified and is bonded with the cable tube into a whole.
Preferably, the first blocking plate and the second blocking plate are soft sponge plates or pearl cotton plates with the thickness of 7-9 cm.
Preferably, the volume of the mixed liquid injected into the injection space is 1/5-1/7 of the injection space.
The invention has the beneficial effects that:
1. the problem of the ageing of current anti-blocking product is solved, permanent sealing can be realized.
2. The plugging agent has the advantages of small usage amount, high oil resistance, water resistance and corrosion resistance, and superior cost performance to the existing product, and is bonded with a cable pipe into a whole after expansion.
3. The plugging agent can meet plugging of various cable tube holes and cable sections, and is high in flexibility and wide in applicability.
4. The application of the plugging agent has the advantages of convenient use, strong operability and high efficiency, and the plugging agent can be expanded to coat fireproof mud on the outermost layer of the cable pipe or coat a layer of fireproof coating to realize the fireproof function.
Detailed Description
In order to further illustrate how the present invention may be carried out, the following examples are provided to illustrate the preparation and use of the anti-blocking agent of the present invention, but it should be understood that the scope of the present invention is not limited by these examples.
In the following examples, water impermeability was tested using the GB 4208-; the method for measuring the compatibility and the corrosivity of the cable skin adopts a GB/T1690-2010 method; the GB/T528-; the fire resistance is detected by GB/T8625-.
The weak acid condition refers to that the anti-blocking agent obtained in the embodiment is soaked in 5% hydrochloric acid for 24 hours, and then the mechanical strength of the anti-blocking agent is detected, so that the acid and alkali resistance of the preservative is measured.
The weak base condition means that the mechanical strength of the anti-blocking agent obtained in the example is tested after the anti-blocking agent is soaked in 5% sodium hydroxide for 24 hours, and the weak base resistance of the preservative is measured.
The starting materials used in the following examples are all commercially available.
Example 1
The cable tube plugging agent consists of A, B components, and comprises the following raw materials in parts by weight:
component A
B component
0.507kg of diphenylmethane diisocyanate (MDI)
0.045kg of polyphenyl polymethylene polyisocyanate (PAPI)
A, B is prepared into a material W and a material B respectively, and the preparation method comprises the following steps:
(1) preparing a W material: and weighing the component A in parts by weight, and uniformly stirring in a stainless steel reaction kettle to obtain the composition. Stirring at a speed of 3000-4000 n/min; the stirring time is 1-2 min. And filling the W material into a plastic bag with a discharge port, and sealing and storing.
(2) Preparation of material B: and weighing the component B according to the parts by weight, and uniformly stirring in a stainless steel reaction kettle to obtain the composition. Stirring at a speed of 3000-4000 n/min; the stirring time is 1-2 min. And filling the material B into a plastic bag with a discharge port, and sealing and storing.
The method for using the cable pipe plugging agent prepared in the embodiment 1 comprises the following steps:
step one, preparing a plugging structure: ginseng radix (Panax ginseng C.A. Meyer)Referring to fig. 1, a black pearl cotton plate with the thickness of 8cm is sleeved on a cable with the diameter of 160mm and is stuffed into a cable tube with the inner diameter of 200mm to be 8cm deep, and another black pearl cotton plate with the thickness of 8cm is sleeved on the cable and is stuffed into the cable tube to be 1cm deep; the first black pearl cotton plate, the cable and the second black pearl cotton plate are enclosed into a volume: (0.1. pi.)2-π·0.082)·0.07=7.9168×10-4m3The second black pearl cotton plate is provided with an injection molding opening communicated with the injection molding space;
secondly, referring to fig. 2, taking out the black W material and the brown B material in the packaging box, and pouring the W material into the B material, wherein the mass ratio of the W material to the B material is 100: 80;
thirdly, referring to fig. 3, rapidly kneading the mixed liquid for 15-90 seconds;
a fourth step, referring to fig. 4, of injecting the mixed liquid into the injection space through the cannula; the volume of the injected mixed liquid is 1.13X 10-4m3=113ml;
And fifthly, referring to fig. 5, after standing for several minutes, the mixed liquid expands and solidifies and is bonded with the cable pipe into a whole.
The physical and chemical properties of the blocking agent obtained in example 1 were measured and shown in Table 1.
TABLE 1 physical and chemical Properties of the blocking agent obtained in example 1
Example 2
The cable tube plugging agent consists of A, B components, and comprises the following raw materials in parts by weight:
component A
B component
0.5432kg of diphenylmethane diisocyanate (MDI)
0.048kg of polyphenyl polymethylene polyisocyanate (PAPI)
The preparation and use of the blocking agent of example 2 was substantially the same as example 1, except that A, B was mixed together in a mass ratio of 100: 70. The physical and chemical properties of the blocking agent obtained in example 2 are shown in Table 2.
TABLE 2 physical and chemical Properties of the blocking agent obtained in example 2
Example 3
The cable tube plugging agent consists of A, B components, and comprises the following raw materials in parts by weight:
component A
B component
0.579kg of diphenylmethane diisocyanate (MDI)
0.0514kg of polyphenyl polymethylene polyisocyanate (PAPI)
The preparation and use of the blocking agent of example 3 was substantially the same as example 1, except that A, B was mixed together in a mass ratio of 100: 75. The physical and chemical properties of the blocking agent obtained in example 3 are shown in Table 3 below.
TABLE 3 physical and chemical Properties of the blocking agent obtained in example 1
EXAMPLE 4
The cable tube plugging agent consists of A, B, C components, and comprises the following raw materials in parts by weight:
component A
B component
0.507kg of diphenylmethane diisocyanate (MDI)
0.05635kg of polyphenyl polymethylene polyisocyanate (PAPI)
0.2kg of expanded graphite powder with the mesh number of the component C being 200
A, B is prepared into a material W and a material B respectively, and the preparation method comprises the following steps:
(1) w material: the preparation and packaging method is the same as in example 1.
(2) B, material B: and weighing the component B and the component C according to the parts by weight, and uniformly stirring in a stainless steel reaction kettle to obtain the high-performance polyurethane resin. Stirring at a speed of 3000-4000 n/min; the stirring time is 1-2 min. And filling the material B into a plastic bag with a discharge port, and sealing and storing.
The method for using the cable duct plugging agent of the embodiment 4 comprises the following steps:
step one, preparing a plugging structure: referring to fig. 1, a soft sponge plate ring with the thickness of 8cm is sleeved on a cable with the diameter of 160mm and is plugged into a cable tube with the inner diameter of 200mm to a depth of 8cm, and another soft sponge plate ring with the thickness of 8cm is sleeved on the cable and is plugged into the cable tube to a depth of 1 cm; the first soft sponge board, the cable and the second soft sponge board are enclosed into a volume as follows: (0.1. pi.)2-π·0.082)·0.07=7.9168×10-4m3The second black pearl cotton plate is provided with an injection molding opening communicated with the injection molding space;
secondly, referring to fig. 2, taking out the black W material and the brown B material in the packaging box, pouring the W material into the B material, wherein A, B, C comprises the following three components in a mass ratio of 100: 70: 25;
thirdly, referring to fig. 3, rapidly kneading the mixed liquid for 15-90 seconds;
a fourth step, referring to fig. 4, of injecting the mixed liquid into the injection space through the cannula; the volume of the injected mixed liquid is 1.13X 10-4m3=113ml;
And fifthly, referring to fig. 5, after standing for several minutes, the mixed liquid expands and solidifies and is bonded with the cable pipe into a whole.
The physical and chemical properties of the blocking agent obtained in test example 4 are shown in Table 4 below.
Table 4 table of physico-chemical properties of the blocking agents obtained in example 4
EXAMPLE 5
The cable tube plugging agent consists of A, B, C components, and comprises the following raw materials in parts by weight:
component A
B component
0.579kg of diphenylmethane diisocyanate (MDI)
0.0514kg of polyphenyl polymethylene polyisocyanate (PAPI)
0.2kg of expanded graphite powder with 300 mesh of C component
The preparation and use of the blocking agent of example 5 are the same as in example 4, and the physical and chemical properties of the blocking agent obtained in example 5 are shown in Table 5 below.
TABLE 5 physical and chemical Properties of the blocking agent obtained in example 5
The embodiment shows that the blocking agent prepared by the method has excellent mechanical property, good acid-base corrosion resistance and water flow impact resistance, and the strength retention rate of the blocking agent in an acid-base environment can reach more than 97%; the sealing performance is good, and the sealing index can reach more than 8 grades.