CN110108381A - LC passive wireless sensor that is a kind of while detecting temperature, humidity - Google Patents
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- 239000000758 substrate Substances 0.000 claims abstract description 21
- 239000003990 capacitor Substances 0.000 claims abstract description 19
- 238000002161 passivation Methods 0.000 claims abstract description 19
- 238000001514 detection method Methods 0.000 claims abstract description 17
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims abstract description 8
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- 229910021389 graphene Inorganic materials 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
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- 229910052759 nickel Inorganic materials 0.000 claims description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 3
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- 230000035945 sensitivity Effects 0.000 abstract description 2
- 238000005516 engineering process Methods 0.000 description 9
- 230000008859 change Effects 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
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Abstract
本发明公开了一种同时检测温度、湿度的LC无源无线传感器,包括衬底,衬底上方设置有叉指正电极、叉指负电极、电感线圈,衬底与叉指正电极、叉指负电极、电感线圈之间存在一个空腔;叉指负电极表面覆有一层敏感介质,叉指正电极和叉指负电极形成叉指结构,叉指正电极和叉指负电极之间有空气层,构成检测电容;电感线圈位于叉指正电极和叉指负电极的外围,电感线圈的尾部通过引线与叉指负电极连接,电感线圈与检测电容构成LC传感器谐振回路单元;所述空腔的四周设置有自下而上的氧化层、底层钝化层、顶层钝化层,氧化层位于衬底上。本发明可以实现对温度和湿度的同时检测,具有灵敏度高,响应快,结构简单、体积小、成本低、寿命长的优点。
The invention discloses an LC passive wireless sensor for simultaneously detecting temperature and humidity, which comprises a substrate, on which a fork positive electrode, a fork negative electrode, and an inductance coil are arranged, and the substrate is connected with the fork positive electrode and the fork negative electrode. 1. There is a cavity between the inductance coils; the surface of the negative electrode of the fork is covered with a layer of sensitive medium, the positive electrode of the fork and the negative electrode of the fork form an interdigital structure, and there is an air layer between the positive electrode of the fork and the negative electrode of the fork, forming a detection Capacitance; the inductance coil is located on the periphery of the positive electrode of the fork and the negative electrode of the fork, the tail of the inductance coil is connected with the negative electrode of the fork through a lead wire, and the inductance coil and the detection capacitor constitute the LC sensor resonant circuit unit; Bottom-up oxide layer, bottom passivation layer, top passivation layer, oxide layer on the substrate. The invention can realize simultaneous detection of temperature and humidity, and has the advantages of high sensitivity, fast response, simple structure, small volume, low cost and long service life.
Description
技术领域technical field
本发明涉及一种基于微电子机械系统(Micro-Electro-Mechanical-System,MEMS)技术加工的电感-电容谐振回路式(Inductor–Capacitor,LC)无源无线传感器,尤其是一种能够同时遥测温度和湿度两个参数的无源无线传感器。The invention relates to an inductance-capacitor resonant circuit (Inductor-Capacitor, LC) passive wireless sensor processed based on Micro-Electro-Mechanical-System (MEMS) technology, especially a kind of sensor capable of remote temperature measurement at the same time A passive wireless sensor for two parameters, and humidity.
背景技术Background technique
物联网(Internet of Things,IOT),是一种物物相连的网络。它是新一代信息技术的高度集成和综合运用,对新一轮产业变革和经济社会绿色、智能、可持续发展具有重要意义,被称作是继计算机、互联网之后,世界信息产业的第三次浪潮。传感器是物联网感知层最主要的组成部分,是数据的采集入口。传感器性能将直接影响后续控制系统和信息系统中数据的准确性,决定着整个物联网系统特性和整体的性能指标,而且传感器性能的提高和种类的增多,对智能装备的应用也起着技术牵引和场景升级的作用。无源无线传感器研究属于面向物联网应用的传感器前沿研究领域。LC无源无线传感器,即传感器谐振回路由无源元件构成,结构简单,价格便宜,理论上工作温度不受限制,而且传感器结构设计灵活,加工材料可多样化,采集到的传感器信号的频谱信息丰富,使其在功能设计以及多参数设计研究等方面具有很大的潜力。温度、湿度是与人们日常生活最为密切相关的两个物理量,同时也是在科学实验和生产活动中需要测量和控制的重要物理量。特别是随着工业、农业等行业对智能化水平的需求的不断提高以及物联网技术的发展,环境温湿度检测的需求量急剧增加,结合新兴技术,独立创新,开发包括温湿度传感器在内的具有自主知识产权的无源无线传感器迫在眉睫。The Internet of Things (IOT) is a network in which things are connected. It is a highly integrated and comprehensive application of the new generation of information technology, which is of great significance to the new round of industrial transformation and the green, intelligent and sustainable development of the economy and society. wave. Sensors are the most important part of the perception layer of the Internet of Things, and they are the entrances for data collection. Sensor performance will directly affect the accuracy of data in subsequent control systems and information systems, and determine the characteristics and overall performance indicators of the entire Internet of Things system. Moreover, the improvement of sensor performance and the increase in types also play a technical role in the application of smart equipment. and the role of scene upgrades. Passive wireless sensor research belongs to the frontier research field of sensors for Internet of Things applications. LC passive wireless sensor, that is, the sensor resonant circuit is composed of passive components, the structure is simple, the price is cheap, the working temperature is not limited in theory, and the sensor structure design is flexible, the processing materials can be diversified, and the spectrum information of the collected sensor signal It has great potential in functional design and multi-parameter design research. Temperature and humidity are two physical quantities most closely related to people's daily life, and they are also important physical quantities that need to be measured and controlled in scientific experiments and production activities. Especially with the continuous improvement of the demand for intelligence in industry, agriculture and other industries and the development of Internet of Things technology, the demand for environmental temperature and humidity detection has increased sharply. Combined with emerging technologies, independent innovation, and development of temperature and humidity sensors. Passive wireless sensors with independent intellectual property rights are imminent.
发明内容Contents of the invention
本发明的目的是提供一种同时检测温度、湿度的LC无源无线传感器,以实现对温度和湿度的同时检测。The object of the present invention is to provide an LC passive wireless sensor for simultaneously detecting temperature and humidity, so as to realize simultaneous detection of temperature and humidity.
为实现上述目的,本发明采用的技术方案为:To achieve the above object, the technical solution adopted in the present invention is:
一种同时检测温度、湿度的LC无源无线传感器,包括衬底,衬底上方设置有叉指正电极、叉指负电极、电感线圈,衬底与叉指正电极、叉指负电极、电感线圈之间存在一个空腔;所述叉指负电极表面覆有一层敏感介质,叉指正电极和叉指负电极形成叉指结构,叉指正电极和叉指负电极之间有空气层,构成检测电容;所述电感线圈位于叉指正电极和叉指负电极的外围,电感线圈的尾部通过引线与叉指负电极连接,电感线圈与检测电容构成LC传感器谐振回路单元;所述空腔的四周设置有自下而上的氧化层、底层钝化层、顶层钝化层,氧化层位于衬底上。An LC passive wireless sensor for detecting temperature and humidity at the same time, comprising a substrate, a positive electrode, a negative electrode, and an inductance coil are arranged above the substrate, and the connection between the substrate and the positive electrode, the negative electrode, and the inductance coil There is a cavity between them; the surface of the negative interdigital electrode is covered with a layer of sensitive medium, the positive interdigital electrode and the negative interdigital electrode form an interdigital structure, and there is an air layer between the positive interdigital electrode and the negative interdigital electrode to form a detection capacitance; The inductance coil is located on the periphery of the positive electrode of the fork and the negative electrode of the fork, the tail of the inductance coil is connected with the negative electrode of the fork through a lead wire, and the inductance coil and the detection capacitor form an LC sensor resonant circuit unit; Bottom-up oxide layer, bottom passivation layer, top passivation layer, oxide layer on substrate.
所述引线的一端位于顶层钝化层内,并通过金属层连接锚区固定。One end of the lead wire is located in the top passivation layer and fixed through the metal layer connection anchor area.
所述引线为多晶硅层或电极金属层。The lead is a polysilicon layer or an electrode metal layer.
所述衬底的材质为硅。The material of the substrate is silicon.
所述底层钝化层和顶层钝化层的材质均为氮化硅。Both the bottom passivation layer and the top passivation layer are made of silicon nitride.
所述敏感介质的材质为氧化石墨烯,氧化石墨烯由选择性生长的方式得到,如通过CVD生长而成。The material of the sensitive medium is graphene oxide, and the graphene oxide is obtained by selective growth, such as by CVD.
所述叉指正电极、叉指负电极及电感线圈的材质为镍。The material of the interdigitated positive electrode, the interdigitated negative electrode and the inductance coil is nickel.
所述叉指正电极、叉指负电极、电感线圈由电镀工艺加工得到。The interdigitated positive electrode, the interdigitated negative electrode and the inductance coil are processed by electroplating process.
所述电感线圈为平面螺旋线圈。The inductance coil is a planar spiral coil.
本发明的原理是:本发明的LC无源无线传感器包括检测电容和电感线圈,其中,检测电容是由正负电极、敏感介质以及空气层构成叉指结构状的敏感电容,当温度及湿度发生变化,会引起电容的混合介电常数发生变化,而温度变化又会引起整个LC谐振回路的Q值变化,即变化的温湿度会引起LC谐振回路的谐振频率和阻抗最大值发生变化,检测LC谐振回路的谐振频率和阻抗最大值就可以实现对于环境温度和湿度的检测。The principle of the present invention is: the LC passive wireless sensor of the present invention includes a detection capacitor and an inductance coil, wherein the detection capacitor is a sensitive capacitor with an interdigital structure formed by positive and negative electrodes, a sensitive medium, and an air layer. The change will cause the mixed dielectric constant of the capacitor to change, and the temperature change will cause the Q value of the entire LC resonant circuit to change, that is, the changing temperature and humidity will cause the resonant frequency and the maximum impedance of the LC resonant circuit to change, and the detection of LC The resonant frequency and the maximum value of the impedance of the resonant circuit can realize the detection of the ambient temperature and humidity.
有益效果:本发明的LC无源无线传感器可以实现对温度和湿度的同时检测,具有灵敏度高,响应快,结构简单、体积小、成本低、寿命长的优点。LC结构中的敏感电容和电感线圈为由电镀工艺加工的具有高深宽比的MEMS结构。综合其材料的加工成本、制作工艺的实现方式以及敏感电容的大小来说,MEMS加工工艺加工的传感器具有成本低、制作工艺成熟、器件尺寸小的优点。敏感电容和电感线圈为同一电镀工艺加工,使得LC传感器的加工的可重复性和一致性得到了提高。采用多晶硅层(或电极金属层)用来实现电感线圈回路的闭合,能够简化LC传感器MEMS加工的步骤。衬底的材质为硅,敏感电容和电感线圈与硅衬底之间有空气腔,空气腔可以实现电隔离和热隔离,减少寄生电容,减少测试过程中的电磁损耗的。Beneficial effects: the LC passive wireless sensor of the present invention can realize simultaneous detection of temperature and humidity, and has the advantages of high sensitivity, fast response, simple structure, small volume, low cost and long life. The sensitive capacitor and inductor coils in the LC structure are MEMS structures with high aspect ratio processed by electroplating process. In terms of the processing cost of its materials, the realization of the manufacturing process, and the size of the sensitive capacitor, the sensor processed by the MEMS processing process has the advantages of low cost, mature manufacturing process, and small device size. The sensitive capacitor and inductor coil are processed by the same electroplating process, which improves the repeatability and consistency of the processing of the LC sensor. The polysilicon layer (or electrode metal layer) is used to close the loop of the inductance coil, which can simplify the steps of MEMS processing of the LC sensor. The substrate is made of silicon, and there is an air cavity between the sensitive capacitor and inductance coil and the silicon substrate. The air cavity can realize electrical isolation and thermal isolation, reduce parasitic capacitance, and reduce electromagnetic loss during the test.
附图说明Description of drawings
图1是本发明提供的基于MEMS工艺的电感-电容谐振回路式温湿度传感器的截面图;Fig. 1 is the sectional view of the inductance-capacitance resonant circuit type temperature and humidity sensor based on MEMS technology provided by the present invention;
图2是本发明提供的基于MEMS工艺的电感-电容谐振回路式温湿度传感器的截面图;Fig. 2 is the sectional view of the inductance-capacitance resonant circuit type temperature and humidity sensor based on MEMS technology provided by the present invention;
图3是本发明提供的LC无源无线温湿度传感器系统的结构示意图;Fig. 3 is the structural representation of LC passive wireless temperature and humidity sensor system provided by the present invention;
图中,1-衬底,2-氧化层,3-底层钝化层,4-顶层钝化层,5-金属层连接锚区,6-引线,7-电感线圈,8-1-叉指正电极,8-2-叉指负电极,9-敏感介质,10-空腔,11-空气层。In the figure, 1-substrate, 2-oxide layer, 3-bottom passivation layer, 4-top passivation layer, 5-metal layer connection anchor area, 6-lead, 7-inductance coil, 8-1-fork Electrode, 8-2-interdigitated negative electrode, 9-sensitive medium, 10-cavity, 11-air layer.
具体实施方式Detailed ways
下面结合附图对本发明做更进一步的解释。The present invention will be further explained below in conjunction with the accompanying drawings.
如图1和图2,本发明的一种同时检测温度、湿度的LC无源无线传感器,包括衬底1,衬底1位于传感器的底部,起基座作用;衬底1上方设置有叉指正电极8-1、叉指负电极8-2、电感线圈7,衬底1与叉指正电极8-1、叉指负电极8-2、电感线圈7之间存在一个空腔10;叉指负电极8-2表面覆有一层敏感介质9,叉指正电极8-1和叉指负电极8-2形成叉指结构,叉指正电极8-1和叉指负电极8-2之间有空气层11,构成检测电容;电感线圈7为平面螺旋线圈,电感线圈7位于叉指正电极8-1和叉指负电极8-2的外围,电感线圈7的尾部通过引线6与叉指负电极8-2连接,电感线圈7与检测电容构成LC传感器谐振回路单元;所述空腔10的四周设置有自下而上的氧化层2、底层钝化层3、顶层钝化层4,氧化层2位于衬底1上。As shown in Fig. 1 and Fig. 2, an LC passive wireless sensor for simultaneously detecting temperature and humidity of the present invention includes a substrate 1, which is located at the bottom of the sensor and acts as a base; Electrode 8-1, fork finger negative electrode 8-2, inductance coil 7, there is a cavity 10 between the substrate 1 and fork finger positive electrode 8-1, fork finger negative electrode 8-2, and inductance coil 7; The surface of the electrode 8-2 is covered with a layer of sensitive medium 9, the interdigitated positive electrode 8-1 and the interdigitated negative electrode 8-2 form an interdigitated structure, and there is an air layer between the interdigitated positive electrode 8-1 and the interdigitated negative electrode 8-2 11. Constitute a detection capacitor; the inductance coil 7 is a planar spiral coil, the inductance coil 7 is located on the periphery of the fork positive electrode 8-1 and the fork negative electrode 8-2, and the tail of the inductance coil 7 is connected to the fork negative electrode 8- through the lead wire 6. 2 connected, the inductance coil 7 and the detection capacitor constitute the LC sensor resonant circuit unit; the cavity 10 is surrounded by an oxide layer 2, a bottom passivation layer 3, and a top passivation layer 4, and the oxide layer 2 is located at on substrate 1.
其中,引线6的一端位于顶层钝化层4内,并通过金属层连接锚区5固定。引线6为多晶硅层或电极金属层。Wherein, one end of the lead wire 6 is located in the top passivation layer 4 and fixed through the metal layer connection anchor region 5 . The lead 6 is a polysilicon layer or an electrode metal layer.
衬底1的材质为硅。The material of the substrate 1 is silicon.
底层钝化层3和顶层钝化层4的材质均为氮化硅。Both the bottom passivation layer 3 and the top passivation layer 4 are made of silicon nitride.
敏感介质9的材质为氧化石墨烯。氧化石墨烯是实现较宽温湿度感测的最佳敏感介质材料。氧化石墨烯表面及边缘拥有大量含氧基团,使氧化石墨烯具有极强的亲水性,使其具有灵敏的感湿特性;含氧官能团同时使得氧化石墨烯丧失了原有的导电能力,使得其具有半导体或者绝缘体的特性;温度变化影响含氧官能团的结构及氢键的强弱,进而影响温敏特性。The sensitive medium 9 is made of graphene oxide. Graphene oxide is the best sensitive dielectric material for wide temperature and humidity sensing. There are a large number of oxygen-containing groups on the surface and edge of graphene oxide, which makes graphene oxide extremely hydrophilic and sensitive to moisture; the oxygen-containing functional groups also make graphene oxide lose its original conductivity. It has the characteristics of a semiconductor or an insulator; temperature changes affect the structure of the oxygen-containing functional group and the strength of the hydrogen bond, thereby affecting the temperature-sensitive characteristics.
叉指正电极8-1、叉指负电极8-2及电感线圈7的材质为镍。The positive interdigitated electrode 8-1, the negative interdigitated electrode 8-2 and the inductance coil 7 are made of nickel.
本发明的LC无源无线传感器由如下方法制作得到:首先,无源无线温湿度传感器的检测电容及电感线圈结构都是由MEMS片上金属加工工艺(如MetalMumps加工工艺或自设计的金属片上加工工艺)中的金属结构层加工而成;叉指负电极上的氧化石墨烯层的可控制备可以采用在叉指负电极上通过选择性生长的方式得到氧化石墨烯薄膜,如CVD生长而成。The LC passive wireless sensor of the present invention is made by the following method: first, the detection capacitor and the inductance coil structure of the passive wireless temperature and humidity sensor are all processed by the MEMS on-chip metal processing technology (such as MetalMumps processing technology or self-designed metal sheet processing technology) ) in the metal structure layer; the controllable preparation of the graphene oxide layer on the interdigital negative electrode can be obtained by selective growth on the interdigital negative electrode, such as CVD growth.
在本发明中,正负电极、敏感介质层以及空气层构成叉指结构状的检测电容,该检测电容与电感线圈串联形成LC谐振回路,等效电路图如图3右侧所示。当温度和湿度发生变化时,会引起LC谐振回路的阻抗容抗发生变化,进而引起检测端的频谱阻抗(如图3中左侧)的幅度Re(Z)和谐振频率f0点发生变化,从而实现温度和湿度的同时无源无线检测。In the present invention, the positive and negative electrodes, the sensitive medium layer and the air layer form an interdigitated detection capacitor, and the detection capacitor is connected in series with the inductance coil to form an LC resonant circuit. The equivalent circuit diagram is shown on the right side of FIG. 3 . When the temperature and humidity change, the impedance and capacitance reactance of the LC resonant tank will change, which will cause the amplitude Re(Z) and resonance frequency f 0 of the spectral impedance at the detection end (as shown on the left in Figure 3) to change, thus Enables simultaneous passive wireless detection of temperature and humidity.
以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。The above is only a preferred embodiment of the present invention, it should be pointed out that, for those of ordinary skill in the art, without departing from the principle of the present invention, some improvements and modifications can also be made, and these improvements and modifications can also be made. It should be regarded as the protection scope of the present invention.
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