CN110055143B - Composition containing natural active components and preparation method and application thereof - Google Patents
Composition containing natural active components and preparation method and application thereof Download PDFInfo
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- CN110055143B CN110055143B CN201910468597.5A CN201910468597A CN110055143B CN 110055143 B CN110055143 B CN 110055143B CN 201910468597 A CN201910468597 A CN 201910468597A CN 110055143 B CN110055143 B CN 110055143B
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38636—Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/261—Alcohols; Phenols
- C11D7/262—Alcohols; Phenols fatty or with at least 8 carbon atoms in the alkyl or alkenyl chain
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/40—Products in which the composition is not well defined
- C11D7/44—Vegetable products
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- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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- Health & Medical Sciences (AREA)
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- Detergent Compositions (AREA)
Abstract
The invention relates to the field of detergents, and provides a composition containing natural active components, which at least comprises, by weight, 50-100 parts of the natural active components, 0.5-5 parts of polyhydroxy long-chain alkane and 1-5 parts of biological enzyme. Also provides a preparation method and application of the composition containing the natural active components.
Description
Technical Field
The invention relates to the field of detergents, in particular to a composition containing natural active components and a preparation method and application thereof.
Background
The pesticide residue of fruits and vegetables refers to the general term of pesticide, toxic metabolites, degradation conversion products and reaction impurities remained on the surface of vegetables after pesticide spraying. In the modern society, excessive pursuit of economic benefits by people leads to irregular use of pesticides, and although the use of a large amount of pesticides improves the yield of fruits and vegetables, the residual pesticides seriously harm human health. With the improvement of the living standard of people and the enhancement of people's consciousness on food safety and environmental protection, the problem of pesticide residue on the surface of agricultural products is increasingly concerned by people. At present, a powerful cleaning agent which can effectively remove pesticide residues, microorganisms and soil and sand on the surface of agricultural products and does not pollute the environment is developed, and the cleaning is quick and convenient to achieve, so that the focus of worldwide attention is formed. Therefore, there is a need to develop a cleaning composition having high safety which can be applied to various cleaning agents or detergents and has a multifunctional effect.
Disclosure of Invention
In order to solve the above technical problems, the first aspect of the present invention provides a composition containing a natural active ingredient, wherein the raw materials at least comprise, by weight, 50 to 100 parts of the natural active ingredient, 0.5 to 5 parts of polyhydroxy long chain alkane, and 1 to 5 parts of a biological enzyme.
As a preferred embodiment, the natural active ingredient in the present invention comprises a plant extract; the plant extract is selected from one or more of flos Lonicerae extract, fructus Gleditsiae Abnormalis extract, folium Artemisiae Argyi extract, maca extract, and fructus Citri Limoniae extract.
As a preferred embodiment, the polyhydroxy long chain alkane of the present invention has 2 to 6 hydroxyl groups; the polyhydroxy long chain alkane has 5-12 methylene groups.
In a preferred embodiment, the biological enzyme is selected from the group consisting of xylanase, lipase, phytase, amylase, protease, cutinase, cellulase, pectinase, mannanase, arabinase, galactanase, and oxidase.
As a preferable technical scheme, the raw material also comprises 5-20 parts of water-soluble chitosan.
As a preferred technical scheme, the plant extract in the invention is a combination of folium artemisiae argyi extract, maca extract and lemon extract; the weight ratio of the folium artemisiae argyi extract to the maca extract to the lemon extract is 1: (1-5): (0.1-1).
As a preferred technical solution, the biological enzyme in the invention is a combination of lipase, phytase and xylanase; the weight ratio of the phytase to the lipase to the xylanase is 1: (0.05-0.5): (0.5-1.5).
As a preferred technical solution, the natural active ingredients in the present invention further include one or more of shea butter extract, aloe extract, citrus fruit extract, lilium brownii extract, rose extract, purslane extract, tremella extract, tea extract, centella asiatica extract, chamomile flower extract, and rosemary leaf extract.
According to a second aspect of the present invention, there is provided a method for preparing a composition comprising a natural active ingredient, comprising at least the steps of, (1) weighing the raw materials of the composition for use; (2) firstly, uniformly stirring natural active components and polyhydroxy long-chain alkane; adding biological enzyme, stirring, pouring into a clean container, and sealing with a cover.
The third aspect of the invention provides an application of the composition containing the natural active components in cleaning fruits and vegetables.
Has the advantages that:
the invention provides a composition containing natural active components, which has the obvious effect of reducing the residual amount of pesticides, microorganisms and bacteria on fruit and vegetable products, and has the excellent characteristics of high pesticide removal efficiency and high removal rate; the main components of the invention contain natural active components, so the invention is safe and environment-friendly, and can not cause skin damage and condition the skin after long-term use.
Detailed Description
Unless otherwise indicated, implied from the context, or customary in the art, all parts and percentages herein are by weight and the testing and characterization methods used are synchronized with the filing date of the present application. To the extent that a definition of a particular term disclosed in the prior art is inconsistent with any definitions provided herein, the definition of the term provided herein controls.
The technical features of the technical solutions provided by the present invention are further clearly and completely described below with reference to the specific embodiments, and the scope of protection is not limited thereto.
The words "preferred", "preferably", "more preferred", and the like, in the present invention, refer to embodiments of the invention that may provide certain benefits, under certain circumstances. However, other embodiments may be preferred, under the same or other circumstances. Furthermore, the recitation of one or more preferred embodiments does not imply that other embodiments are not useful, nor is it intended to exclude other embodiments from the scope of the invention. The sources of components not mentioned in the present invention are all commercially available.
The first aspect of the invention provides a composition containing natural active components, and the raw materials at least comprise, by weight, 50-100 parts of the natural active components, 0.5-5 parts of polyhydroxy long-chain alkane and 1-5 parts of biological enzyme.
In some preferred embodiments, the raw material of the natural active ingredient-containing composition at least comprises, by weight, 60 to 90 parts of the natural active ingredient, 1 to 4 parts of polyhydroxy long-chain alkane, and 2 to 4 parts of biological enzyme.
In some preferred embodiments, the raw material of the natural active ingredient-containing composition at least comprises, by weight, 80 parts of the natural active ingredient, 2.5 parts of polyhydroxy long chain alkane and 3 parts of biological enzyme.
In some embodiments, the natural active component comprises a plant extract; the plant extract is selected from one or more of honeysuckle extract, gleditsia sinensis lam extract, folium artemisiae argyi extract, maca extract and lemon extract; preferably, the plant extract is selected from one or more of fructus Gleditsiae Abnormalis extract, folium Artemisiae Argyi extract, maca extract, and fructus Citri Limoniae extract; more preferably, the plant extract is selected from one or more of folium artemisiae argyi extract, maca extract and lemon extract.
In some embodiments, the plant extract is a combination of mugwort extract, maca extract, lemon extract; the weight ratio of the folium artemisiae argyi extract to the maca extract to the lemon extract is 1: (1-5): (0.1-1); preferably, the weight ratio of the folium artemisiae argyi extract to the maca extract to the lemon extract is 1: (2-3): (0.3-0.7); more preferably, the weight ratio of the folium artemisiae argyi extract to the maca extract to the lemon extract is 1: 2.5: 0.5.
the CAS number of the folium artemisiae argyi extract is 94-24-6; the CAS number of the maca extract is 138-59-0; the CAS number of the lemon extract is 84929-31-7.
In some embodiments, the polyhydroxy long chain alkane has from 2 to 6 hydroxyl groups; 5-12 methylene groups in the polyhydroxy long chain alkane; preferably, the polyhydroxy long chain alkane has 3 to 5 hydroxyl groups; 7-10 methylene groups in the polyhydroxy long chain alkane; more preferably, the polyhydroxy long chain alkane has 4 hydroxyl groups; the polyhydroxy long chain alkane has 9 methylene groups.
In some embodiments, the polyhydroxy long chain alkane is an alkyl glycoside.
In some embodiments, the polyhydroxy long chain alkane is selected from the group consisting of lauryl glucoside, undecyl glucoside, n-decyl glucoside, butyl glucoside, or combinations thereof; preferably, the polyhydroxy long alkane is selected from one or more of lauryl glucoside, undecyl glucoside and n-decyl glucoside; more preferably, the long chain length polyhydroxylated alkane is n-decyl glucoside.
In some embodiments, the biological enzyme is selected from the group consisting of xylanase, lipase, phytase, amylase, protease, cutinase, cellulase, pectinase, mannanase, arabinase, galactanase, oxidase; preferably, the biological enzyme is selected from one or more of xylanase, lipase, phytase, amylase and protease; more preferably, the biological enzyme is selected from one or more of xylanase, lipase and phytase.
CAS number of the xylanase 9025-57-4; the CAS number of the lipase is 9001-62-1; the CAS number of the phytase is 37288-11-2.
In some embodiments, the biological enzyme is a combination of lipase, phytase, xylanase; the weight ratio of the phytase to the lipase to the xylanase is 1: (0.05-0.5): (0.5-1.5); preferably, the weight ratio of the phytase to the lipase to the xylanase is 1: (0.1-0.3): (0.8-1.2); more preferably, the weight ratio of the phytase to the lipase to the xylanase is 1: 0.2: 1.
the applicant finds that the chitosan, the natural plant extract, the alkyl glycoside, the phytase and the protease are compounded for use, so that the removal rate of pesticides can be improved, the residual quantity of the pesticides, microorganisms and bacteria on fruits and vegetables can be obviously reduced, and the residual pesticides on the fruits and vegetables can be thoroughly eliminated; presumably, the reason why the alkylglycoside can reduce the surface tension of the solution, increase the contact area between the natural plant extract and the chitosan and phytase and help the natural active components in the plant extract to promote the degradation reaction of the biological enzyme on the pesticide, and the active components in the artemisia leaf extract, the maca extract and the lemon extract in the plant extract can exert excellent cooperativity to further promote the removal of the pesticide, the microorganism and the bacteria is probably because the maca extract simultaneously has a large amount of various amino acids and is rich in glucosinolate and taurine components, and the glucosinolate can be complexed with the chitosan to the degraded pesticide component under the cooperation of the active components in the lemon extract to further promote the forward reaction direction of the degradation reaction, and the taurine is cooperated with the active components in the artemisia leaf extract, the osmotic pressure around the cells of the microorganism and bacteria is regulated, so that the biological active enzyme can damage the phospholipid of the cell membrane, thereby killing the microorganism such as bacteria.
In some embodiments, the feedstock further comprises 5-20 parts water-soluble chitosan; preferably, the raw materials also comprise 10-18 parts of water-soluble chitosan; more preferably, the raw material further comprises 16 parts of water-soluble chitosan.
The applicant finds that when the plant extract and the biological enzyme are used together, the plant extract and the biological enzyme have excellent pesticide and microorganism removal effects, the degradation activity of the biological enzyme on pesticide, microorganism and the like can be further improved by adding a certain amount of xylanase and chitosan, the removal efficiency is obviously improved, the purpose of quick cleaning can be realized, the condition that the pesticide and the like cannot be cleaned thoroughly due to the fast-paced life style of people at present is avoided, no degradation product and detergent components are left on the surfaces of fruits and vegetables and the contact part of a human body, and the effects of no residue, safety and environmental protection in the true sense are realized; presumably, the chitosan can not only adsorb metal ions and other particles in fruits and vegetables, but also adsorb degraded residues due to active hydroxyl and amino in chitosan macromolecules, and can take away the residues on the surfaces of the fruits and vegetables, and the electropositivity of the chitosan and the mustard glycerol in the maca extract have a complexing reaction, so that the degradation rate of pesticides in the whole process is greatly improved. In addition, the xylanase reduces the acting force of detergent components on fruit and vegetable products by acting on the cell walls of plants, reduces the tension action of the surfaces of the plants, is beneficial to the flowing away of chitosan macromolecules and biological enzymes, further improves the speed of removing pesticides, and can be free of residues.
The water-soluble chitosan purchasing manufacturer does not make special restrictions, and the water-soluble chitosan generally purchased in the market can be applied to the invention; preferably, the product is purchased from Hunan Tan Jia leaf source Biotechnology Co., Ltd, and the model is 2277-92-1.
In some embodiments, the natural active component further comprises a combination of one or more of avocado extract, aloe extract, citrus fruit extract, lilium brownii extract, rose extract, purslane extract, tremella extract, tea extract, centella asiatica extract, chamomile extract, rosemary leaf extract; preferably, the natural active component further comprises one or more of avocado extract, aloe extract, rose extract, purslane extract, and centella extract; more preferably, the natural active component further comprises one or more of shea butter extract and aloe extract.
In some embodiments, the natural active component further comprises a combination of avocado extract, aloe extract; preferably, the weight ratio of the avocado extract to the maca extract to the aloe extract is 1: (1-5): (0.5-2); more preferably, the weight ratio of the avocado extract to the maca extract to the aloe extract is 1: (2-4): (1-1.6); further preferably, the weight ratio of the avocado extract, the maca extract and the aloe extract is 1: 3: 1.4.
the applicant finds that the fruit and vegetable cleaning agent has the effect of conditioning the skin state after being used for a long time, and probably because the natural active components and the biological enzyme are adopted, the fruit and vegetable cleaning agent does not cause any damage to the skin; in particular, the synergy can be achieved by adding a small amount of avocado extract and aloe extract, and compounding with maca extract and alkyl glycoside, presumably because the avocado extract and aloe extract have moisturizing factors, the alkyl glycoside can reduce the surface tension of the skin, and the maca extract can promote the absorption of the moisturizing factors by the skin by regulating osmotic pressure.
The CAS number of the avocado extract is 84695-98-7.
The CAS number of the aloe extract is 85507-69-3.
The CAS number of the citrus fruit extract is 94266-47-4.
The CAS number of the lilium candidum extract is 84776-67-0.
The CAS number of the rose extract is 90106-38-0.
The CAS number of the purslane extract is 90083-07-1.
The CAS number of the tremella extract is 778577-37-0.
The CAS number of the tea extract is 84650-60-2.
The said centella asiatica extract has CAS number 84696-21-9.
The CAS number of the chamomile extract is 84082-60-0.
The CAS number of the rosemary leaf extract is 84604-14-8.
According to a second aspect of the present invention, there is provided a method for preparing a composition comprising a natural active ingredient, comprising at least the steps of, (1) weighing the raw materials of the composition for use; (2) firstly, uniformly stirring natural active components and polyhydroxy long-chain alkane; adding biological enzyme, stirring, pouring into a clean container, and sealing with a cover.
In some preferred embodiments, the method of preparing the natural active ingredient-containing composition comprises at least the steps of,
(1) weighing each raw material in the composition for later use;
(2) firstly, putting natural active components and polyhydroxy long-chain alkane into a stirrer, and uniformly stirring; adding biological enzyme, continuously stirring uniformly, and finally adding the rest raw materials, and continuously stirring uniformly;
(3) pouring into a clean container, and sealing with a cover.
The third aspect of the invention provides an application of the composition containing the natural active components in cleaning fruits and vegetables.
In some embodiments, the composition containing the natural active components can be used for preparing fruit and vegetable cleaning agents.
In some embodiments, the fruit and vegetable cleaning agent comprises, by weight, 20-40 parts of a composition containing a natural active component, 0.1-0.5 part of a dispersing agent, 0.1-0.5 part of a pH regulator, 5-10 parts of sodium chloride, 0.1-1 part of a light stabilizer, 5-15 parts of ethanol, and 80-100 parts of deionized water.
In some preferred embodiments, the fruit and vegetable cleaning agent comprises, by weight, 30 parts of a composition containing a natural active component, 0.25 part of a dispersing agent, 0.3 part of a pH regulator, 8 parts of sodium chloride, 0.5 part of a light stabilizer, 10 parts of ethanol and 90 parts of deionized water.
In some embodiments, the preparation method of the fruit and vegetable cleaning agent is not particularly limited, and preferably, the fruit and vegetable cleaning agent is prepared according to the preparation method of the fruit and vegetable cleaning agent provided by the invention.
The preparation method of the fruit and vegetable cleaning agent comprises the following steps:
s1: weighing and preparing raw materials in the fruit and vegetable cleaning agent;
s2: adding sodium chloride, ethanol, a composition containing a natural active component and water into a stirrer, and stirring at the temperature of 30-60 ℃ for 10-30 minutes at the stirring speed of 200-;
s3: adding a dispersing agent and a pH regulator into the mixed solution A, stirring for 5-20 minutes at a stirring speed of 100-.
Preferably, the preparation method of the fruit and vegetable cleaning agent comprises the following steps:
s1: weighing and preparing raw materials in the fruit and vegetable cleaning agent:
s2: adding sodium chloride, ethanol, a composition containing natural active components and water into a stirrer, and stirring at 40 ℃ for 15 minutes at a stirring speed of 300r/min to obtain a mixed solution A;
s3: and adding a dispersing agent and a pH regulator into the mixed solution A, stirring for 10 minutes at a stirring speed of 200r/min, heating to 50 ℃, adding a light stabilizer into the stirred mixed solution, and continuously stirring for 15 minutes at a stirring speed of 500r/min to obtain the fruit and vegetable cleaning agent.
The present invention is described in detail below with reference to examples, which are provided for the purpose of further illustration only and are not to be construed as limiting the scope of the present invention, and the insubstantial modifications and adaptations thereof by those skilled in the art based on the teachings of the present invention will still fall within the scope of the present invention.
The fruit and vegetable cleaning agent method described in the following examples 1-16 is as follows:
s1: weighing and preparing raw materials in the fruit and vegetable cleaning agent;
s2: adding 8 parts of sodium chloride, 10 parts of ethanol, 30 parts of a composition containing natural active components and 90 parts of water into a stirrer, and stirring for 15 minutes at the temperature of 40 ℃ and the stirring speed of 300r/min to obtain a mixed solution A;
s3: and adding 0.25 dispersant and 0.3pH regulator into the mixed solution A, stirring for 10 minutes at a stirring speed of 200r/min, heating to 50 ℃, adding 0.5 light stabilizer into the stirred mixed solution, continuously stirring for 15 minutes at a stirring speed of 500r/min, and thus obtaining the fruit and vegetable cleaning agent.
Example 1
A composition containing natural active components comprises, by weight, 80 parts of natural active components, 2.5 parts of polyhydroxy long chain alkane, 3 parts of biological enzyme and 16 parts of water-soluble chitosan;
the natural active components comprise plant extracts, the plant extracts are a combination of folium artemisiae argyi extracts, maca extracts and lemon extracts, and the weight ratio is 1: 2.5: 0.5; the polyhydroxy long-chain alkane is n-decyl glucoside; the biological enzyme is a combination of phytase, lipase and xylanase, and the weight ratio is 1: 0.2: 1; the natural active components also comprise a combination of avocado extract and aloe extract, wherein the weight ratio of the avocado extract to the maca extract to the aloe extract is 1: 3: 1.4;
the preparation method of the composition containing the natural active components comprises the following steps,
(1) weighing each raw material in the composition for later use;
(2) firstly, putting natural active components and polyhydroxy long-chain alkane into a stirrer, and uniformly stirring; adding biological enzyme, continuously stirring uniformly, and finally adding the rest raw materials, and continuously stirring uniformly;
(3) pouring into a clean container, and sealing with a cover.
A fruit and vegetable cleaning agent prepared from the composition containing natural active ingredients is provided.
Example 2
A composition containing natural active components comprises, by weight, 50 parts of natural active components, 0.5 part of polyhydroxy long-chain alkane, 1 part of biological enzyme and 5 parts of water-soluble chitosan;
the natural active components comprise plant extracts, the plant extracts are a combination of folium artemisiae argyi extracts, maca extracts and lemon extracts, and the weight ratio is 1: 1: 0.1; the polyhydroxy long alkane is undecyl glucoside; the biological enzyme is a combination of phytase, lipase and xylanase, and the weight ratio is 1: 0.05: 0.5; the natural active components also comprise a combination of avocado extract and aloe extract, wherein the weight ratio of the avocado extract to the maca extract to the aloe extract is 1: 1: 0.5;
the preparation method of the composition containing the natural active components comprises the following steps,
(1) weighing each raw material in the composition for later use;
(2) firstly, putting natural active components and polyhydroxy long-chain alkane into a stirrer, and uniformly stirring; adding biological enzyme, continuously stirring uniformly, and finally adding the rest raw materials, and continuously stirring uniformly;
(3) pouring into a clean container, and sealing with a cover.
Example 3
A composition containing natural active components comprises, by weight, 100 parts of natural active components, 5 parts of polyhydroxy long chain alkane, 5 parts of biological enzyme and 20 parts of water-soluble chitosan;
the natural active components comprise plant extracts, the plant extracts are a combination of folium artemisiae argyi extracts, maca extracts and lemon extracts, and the weight ratio is 1: 5: 1; the polyhydroxy long alkane is undecyl glucoside; the biological enzyme is a combination of phytase, lipase and xylanase, and the weight ratio is 1: 0.5: 1.5; the natural active components also comprise a combination of avocado extract and aloe extract, wherein the weight ratio of the avocado extract to the maca extract to the aloe extract is 1: 5: 2;
the preparation method of the composition containing the natural active components comprises the following steps,
(1) weighing each raw material in the composition for later use;
(2) firstly, putting natural active components and polyhydroxy long-chain alkane into a stirrer, and uniformly stirring; adding biological enzyme, continuously stirring uniformly, and finally adding the rest raw materials, and continuously stirring uniformly;
(3) pouring into a clean container, and sealing with a cover.
Example 4
A composition containing natural active components comprises, by weight, 60 parts of natural active components, 1 part of long-chain polyhydroxyalkane, 2 parts of biological enzyme and 10 parts of water-soluble chitosan;
the natural active components comprise plant extracts, the plant extracts are a combination of folium artemisiae argyi extracts, maca extracts and lemon extracts, and the weight ratio is 1: 2: 0.3; the polyhydroxy long alkane is undecyl glucoside; the biological enzyme is a combination of phytase, lipase and xylanase, and the weight ratio is 1: 0.1: 0.8; the natural active components also comprise a combination of avocado extract and aloe extract, wherein the weight ratio of the avocado extract to the maca extract to the aloe extract is 1: 2: 1;
the preparation method of the composition containing the natural active components comprises the following steps,
(1) weighing each raw material in the composition for later use;
(2) firstly, putting natural active components and polyhydroxy long-chain alkane into a stirrer, and uniformly stirring; adding biological enzyme, continuously stirring uniformly, and finally adding the rest raw materials, and continuously stirring uniformly;
(3) pouring into a clean container, and sealing with a cover.
Example 5
A composition containing natural active components comprises, by weight, 90 parts of natural active components, 4 parts of polyhydroxy long chain alkane, 4 parts of biological enzyme and 18 parts of water-soluble chitosan;
the natural active components comprise plant extracts, the plant extracts are a combination of folium artemisiae argyi extracts, maca extracts and lemon extracts, and the weight ratio is 1: 3: 0.7; the polyhydroxy long alkane is undecyl glucoside; the biological enzyme is a combination of phytase, lipase and xylanase, and the weight ratio is 1: 0.3: 1.2; the natural active components also comprise a combination of avocado extract and aloe extract, wherein the weight ratio of the avocado extract to the maca extract to the aloe extract is 1: 4: 1.6;
the preparation method of the composition containing the natural active components comprises the following steps,
(1) weighing each raw material in the composition for later use;
(2) firstly, putting natural active components and polyhydroxy long-chain alkane into a stirrer, and uniformly stirring; adding biological enzyme, continuously stirring uniformly, and finally adding the rest raw materials, and continuously stirring uniformly;
(3) pouring into a clean container, and sealing with a cover.
Example 6
A composition containing natural active components comprises, by weight, 80 parts of natural active components, 2.5 parts of polyhydroxy long chain alkane, 3 parts of biological enzyme and 16 parts of water-soluble chitosan;
the natural active component comprises a plant extract, wherein the plant extract is a combination of a folium artemisiae argyi extract and a lemon extract, and the weight ratio of the plant extract to the folium artemisiae argyi extract is 1: 0.5; the polyhydroxy long-chain alkane is n-decyl glucoside; the biological enzyme is a combination of phytase, lipase and xylanase, and the weight ratio is 1: 0.2: 1; the natural active components also comprise a combination of avocado extract and aloe extract, wherein the weight ratio of the avocado extract to the maca extract to the aloe extract is 1: 3: 1.4;
the preparation method of the composition containing the natural active components comprises the following steps,
(1) weighing each raw material in the composition for later use;
(2) firstly, putting natural active components and polyhydroxy long-chain alkane into a stirrer, and uniformly stirring; adding biological enzyme, continuously stirring uniformly, and finally adding the rest raw materials, and continuously stirring uniformly;
(3) pouring into a clean container, and sealing with a cover.
A fruit and vegetable cleaning agent prepared from the composition containing natural active ingredients is provided.
Example 7
A composition containing natural active components comprises, by weight, 80 parts of natural active components, 2.5 parts of polyhydroxy long chain alkane, 3 parts of biological enzyme and 16 parts of water-soluble chitosan;
the natural active components comprise plant extracts, the plant extracts are a combination of maca extracts and lemon extracts, and the weight ratio is 5: 1; the polyhydroxy long-chain alkane is n-decyl glucoside; the biological enzyme is a combination of phytase, lipase and xylanase, and the weight ratio is 1: 0.2: 1; the natural active components also comprise a combination of avocado extract and aloe extract, wherein the weight ratio of the avocado extract to the maca extract to the aloe extract is 1: 3: 1.4;
the preparation method of the composition containing the natural active components comprises the following steps,
(1) weighing each raw material in the composition for later use;
(2) firstly, putting natural active components and polyhydroxy long-chain alkane into a stirrer, and uniformly stirring; adding biological enzyme, continuously stirring uniformly, and finally adding the rest raw materials, and continuously stirring uniformly;
(3) pouring into a clean container, and sealing with a cover.
A fruit and vegetable cleaning agent prepared from the composition containing natural active ingredients is provided.
Example 8
A composition containing natural active components comprises, by weight, 80 parts of natural active components, 2.5 parts of polyhydroxy long chain alkane, 3 parts of biological enzyme and 16 parts of water-soluble chitosan;
the natural active components comprise plant extracts, the plant extracts are a combination of folium artemisiae argyi extracts, maca extracts and lemon extracts, and the weight ratio is 1: 0.5: 1; the polyhydroxy long-chain alkane is n-decyl glucoside; the biological enzyme is a combination of phytase, lipase and xylanase, and the weight ratio is 1: 0.2: 1; the natural active components also comprise a combination of avocado extract and aloe extract, wherein the weight ratio of the avocado extract to the maca extract to the aloe extract is 1: 3: 1.4;
the preparation method of the composition containing the natural active components comprises the following steps,
(1) weighing each raw material in the composition for later use;
(2) firstly, putting natural active components and polyhydroxy long-chain alkane into a stirrer, and uniformly stirring; adding biological enzyme, continuously stirring uniformly, and finally adding the rest raw materials, and continuously stirring uniformly;
(3) pouring into a clean container, and sealing with a cover.
A fruit and vegetable cleaning agent prepared from the composition containing natural active ingredients is provided.
Example 9
A composition containing natural active components comprises, by weight, 80 parts of natural active components, 2.5 parts of polyhydroxy long chain alkane, 3 parts of biological enzyme and 16 parts of water-soluble chitosan;
the natural active components comprise plant extracts, the plant extracts are a combination of folium artemisiae argyi extracts, maca extracts and lemon extracts, and the weight ratio is 1: 10: 0.5; the polyhydroxy long-chain alkane is n-decyl glucoside; the biological enzyme is a combination of phytase, lipase and xylanase, and the weight ratio is 1: 0.2: 1; the natural active components also comprise a combination of avocado extract and aloe extract, wherein the weight ratio of the avocado extract to the maca extract to the aloe extract is 1: 3: 1.4;
the preparation method of the composition containing the natural active components comprises the following steps,
(1) weighing each raw material in the composition for later use;
(2) firstly, putting natural active components and polyhydroxy long-chain alkane into a stirrer, and uniformly stirring; adding biological enzyme, continuously stirring uniformly, and finally adding the rest raw materials, and continuously stirring uniformly;
(3) pouring into a clean container, and sealing with a cover.
A fruit and vegetable cleaning agent prepared from the composition containing natural active ingredients is provided.
Example 10
A composition containing natural active components comprises, by weight, 80 parts of natural active components, 2.5 parts of polyhydroxy long chain alkane, and 3 parts of biological enzyme;
the natural active components comprise plant extracts, the plant extracts are a combination of folium artemisiae argyi extracts, maca extracts and lemon extracts, and the weight ratio is 1: 2.5: 0.5; the polyhydroxy long-chain alkane is n-decyl glucoside; the biological enzyme is a combination of phytase, lipase and xylanase, and the weight ratio is 1: 0.2: 1; the natural active components also comprise a combination of avocado extract and aloe extract, wherein the weight ratio of the avocado extract to the maca extract to the aloe extract is 1: 3: 1.4;
the preparation method of the composition containing the natural active components comprises the following steps,
(1) weighing each raw material in the composition for later use;
(2) firstly, putting natural active components and polyhydroxy long-chain alkane into a stirrer, and uniformly stirring; adding biological enzyme, continuously stirring uniformly, and finally adding the rest raw materials, and continuously stirring uniformly;
(3) pouring into a clean container, and sealing with a cover.
A fruit and vegetable cleaning agent prepared from the composition containing natural active ingredients is provided.
Example 11
A composition containing natural active components comprises, by weight, 80 parts of natural active components, 2.5 parts of polyhydroxy long chain alkane, 3 parts of biological enzyme and 1 part of water-soluble chitosan;
the natural active components comprise plant extracts, the plant extracts are a combination of folium artemisiae argyi extracts, maca extracts and lemon extracts, and the weight ratio is 1: 2.5: 0.5; the polyhydroxy long-chain alkane is n-decyl glucoside; the biological enzyme is a combination of phytase, lipase and xylanase, and the weight ratio is 1: 0.2: 1; the natural active components also comprise a combination of avocado extract and aloe extract, wherein the weight ratio of the avocado extract to the maca extract to the aloe extract is 1: 3: 1.4;
the preparation method of the composition containing the natural active components comprises the following steps,
(1) weighing each raw material in the composition for later use;
(2) firstly, putting natural active components and polyhydroxy long-chain alkane into a stirrer, and uniformly stirring; adding biological enzyme, continuously stirring uniformly, and finally adding the rest raw materials, and continuously stirring uniformly;
(3) pouring into a clean container, and sealing with a cover.
A fruit and vegetable cleaning agent prepared from the composition containing natural active ingredients is provided.
Example 12
A composition containing natural active components comprises, by weight, 80 parts of natural active components, 2.5 parts of polyhydroxy long chain alkane, 3 parts of biological enzyme and 16 parts of water-soluble chitosan;
the natural active components comprise plant extracts, the plant extracts are a combination of folium artemisiae argyi extracts, maca extracts and lemon extracts, and the weight ratio is 1: 2.5: 0.5; the polyhydroxy long-chain alkane is n-decyl glucoside; the biological enzyme is a combination of phytase and lipase, and the weight ratio is 1: 0.2; the natural active components also comprise a combination of avocado extract and aloe extract, wherein the weight ratio of the avocado extract to the maca extract to the aloe extract is 1: 3: 1.4;
the preparation method of the composition containing the natural active components comprises the following steps,
(1) weighing each raw material in the composition for later use;
(2) firstly, putting natural active components and polyhydroxy long-chain alkane into a stirrer, and uniformly stirring; adding biological enzyme, continuously stirring uniformly, and finally adding the rest raw materials, and continuously stirring uniformly;
(3) pouring into a clean container, and sealing with a cover.
A fruit and vegetable cleaning agent prepared from the composition containing natural active ingredients is provided.
Example 13
A composition containing natural active components comprises, by weight, 80 parts of natural active components, 2.5 parts of polyhydroxy long chain alkane, 3 parts of biological enzyme and 16 parts of water-soluble chitosan;
the natural active components comprise plant extracts, the plant extracts are a combination of folium artemisiae argyi extracts, maca extracts and lemon extracts, and the weight ratio is 1: 2.5: 0.5; the polyhydroxy long-chain alkane is n-decyl glucoside; the biological enzyme is a combination of protease, lipase and xylanase, and the weight ratio is 1: 0.2: 1; the natural active components also comprise a combination of avocado extract and aloe extract, wherein the weight ratio of the avocado extract to the maca extract to the aloe extract is 1: 3: 1.4;
the preparation method of the composition containing the natural active components comprises the following steps,
(1) weighing each raw material in the composition for later use;
(2) firstly, putting natural active components and polyhydroxy long-chain alkane into a stirrer, and uniformly stirring; adding biological enzyme, continuously stirring uniformly, and finally adding the rest raw materials, and continuously stirring uniformly;
(3) pouring into a clean container, and sealing with a cover.
A fruit and vegetable cleaning agent prepared from the composition containing natural active ingredients is provided.
Example 14
A composition containing natural active components comprises, by weight, 80 parts of natural active components, 2.5 parts of polyhydroxy long chain alkane, 3 parts of biological enzyme and 16 parts of water-soluble chitosan;
the natural active components comprise plant extracts, the plant extracts are a combination of folium artemisiae argyi extracts, maca extracts and lemon extracts, and the weight ratio is 1: 2.5: 0.5; the polyhydroxy long-chain alkane is n-decyl glucoside; the biological enzyme is a combination of phytase, lipase and xylanase, and the weight ratio is 1: 0.2: 1; the natural active components also comprise a combination of avocado extract and aloe extract, wherein the weight ratio of the avocado extract to the maca extract to the aloe extract is 0.5: 3: 1.4;
the preparation method of the composition containing the natural active components comprises the following steps,
(1) weighing each raw material in the composition for later use;
(2) firstly, putting natural active components and polyhydroxy long-chain alkane into a stirrer, and uniformly stirring; adding biological enzyme, continuously stirring uniformly, and finally adding the rest raw materials, and continuously stirring uniformly;
(3) pouring into a clean container, and sealing with a cover.
A fruit and vegetable cleaning agent prepared from the composition containing natural active ingredients is provided.
Example 15
A composition containing natural active components comprises, by weight, 80 parts of natural active components, 2.5 parts of polyhydroxy long chain alkane, 3 parts of biological enzyme and 16 parts of water-soluble chitosan;
the natural active components comprise plant extracts, the plant extracts are a combination of folium artemisiae argyi extracts, maca extracts and lemon extracts, and the weight ratio is 1: 2.5: 0.5; the polyhydroxy long-chain alkane is n-decyl glucoside; the biological enzyme is a combination of phytase, lipase and xylanase, and the weight ratio is 1: 0.2: 1; the natural active components also comprise a combination of avocado extract and aloe extract, wherein the weight ratio of the avocado extract to the maca extract to the aloe extract is 0.5: 3: 0.1;
the preparation method of the composition containing the natural active components comprises the following steps,
(1) weighing each raw material in the composition for later use;
(2) firstly, putting natural active components and polyhydroxy long-chain alkane into a stirrer, and uniformly stirring; adding biological enzyme, continuously stirring uniformly, and finally adding the rest raw materials, and continuously stirring uniformly;
(3) pouring into a clean container, and sealing with a cover.
A fruit and vegetable cleaning agent prepared from the composition containing natural active ingredients is provided.
Example 16
A composition containing natural active components comprises, by weight, 80 parts of natural active components, 2.5 parts of polyhydroxy long chain alkane, 3 parts of biological enzyme and 16 parts of water-soluble chitosan;
the natural active components comprise plant extracts, the plant extracts are a combination of folium artemisiae argyi extracts, maca extracts and lemon extracts, and the weight ratio is 1: 2.5: 0.5; the polyhydroxy long alkane is butyl glucoside; the biological enzyme is a combination of phytase, lipase and xylanase, and the weight ratio is 1: 0.2: 1; the natural active components also comprise a combination of avocado extract and aloe extract, wherein the weight ratio of the avocado extract to the maca extract to the aloe extract is 1: 3: 1.4;
the preparation method of the composition containing the natural active components comprises the following steps,
(1) weighing each raw material in the composition for later use;
(2) firstly, putting natural active components and polyhydroxy long-chain alkane into a stirrer, and uniformly stirring; adding biological enzyme, continuously stirring uniformly, and finally adding the rest raw materials, and continuously stirring uniformly;
(3) pouring into a clean container, and sealing with a cover.
A fruit and vegetable cleaning agent prepared from the composition containing natural active ingredients is provided.
Performance testing
1. The performance tests of the fruit and vegetable cleaning agents prepared in examples 1-13 of the present invention were as follows, wherein two commercially available fruit and vegetable cleaning agents of different brands A, B were selected as control groups; the washing and removing effect of the fruit and vegetable cleaning agent on the residual pesticide is determined by adopting the method for washing and removing the residual pesticide in appendix A in the fruit and vegetable cleaning agent of the national standard GB/T-24691; the cleaning is carried out in three groups, and the cleaning time of the three groups is 30 seconds, 1 minute and 3 minutes respectively, and the residual rates (%) of the cypermethrin and the propoxur after only one time of cleaning are obtained.
TABLE 1 test results for pesticide removal by fruit and vegetable cleaners
2. Skin conditioning effect test:
300 persons were randomly selected and divided into 10 groups of 30 persons, no hand care product was used during the test period, household vegetable and fruit were hand washed with the fruit and vegetable detergent prepared in examples 1-6 and 14-16 of the present invention every day, and a commercially available brand a fruit and vegetable detergent was selected as a control group. And continuously using for 2 months, and calculating the difference value between the area on the back of the hand and the initial basic value after continuously using for 1 month and after continuously using for 2 months as the moisture content increment of the skin stratum corneum, wherein the larger the moisture content increment of the skin stratum corneum indicates that the conditioning effect of the hand is better. The water content of the skin cuticle is measured by a skin water content tester CM825, and the test environment of the test is 20.0-21.5 ℃ of temperature and 48.0-56.0% of relative humidity, which meets the requirement of scheme design.
Table 2 skin conditioning effect test results
The foregoing examples are illustrative only, and serve to explain some of the features of the present disclosure. The appended claims are intended to claim as broad a scope as is contemplated, and the examples presented herein are merely illustrative of selected implementations in accordance with all possible combinations of examples. Accordingly, it is applicants' intention that the appended claims are not to be limited by the choice of examples illustrating features of the invention. And that advances in science and technology will result in possible equivalents or sub-substitutes not currently contemplated for reasons of inaccuracy in language representation, and such changes should also be construed where possible to be covered by the appended claims.
Claims (3)
1. The composition containing natural active components is characterized by comprising the raw materials of, by weight, 50-100 parts of the natural active components, 0.5-5 parts of polyhydroxy long-chain alkane, 1-5 parts of biological enzyme and 5-20 parts of water-soluble chitosan; the natural active components are the combination of plant extracts, avocado extracts and aloe extracts; the plant extract is a combination of folium artemisiae argyi extract, maca extract and lemon extract; the weight ratio of the folium artemisiae argyi extract to the maca extract to the lemon extract is 1: (1-5): (0.1-1); the weight ratio of the avocado extract to the maca extract to the aloe extract is 1: 3: 1.4;
the polyhydroxy long-chain alkane is alkyl glycoside;
the biological enzyme is a combination of lipase, phytase and xylanase; the weight ratio of the phytase to the lipase to the xylanase is 1: (0.05-0.5): (0.5-1.5).
2. A method for preparing a composition containing a natural active ingredient as claimed in claim 1, comprising at least the steps of:
(1) weighing each raw material in the composition for later use;
(2) firstly, putting natural active components and polyhydroxy long-chain alkane into a stirrer, and uniformly stirring; adding biological enzyme, continuously stirring uniformly, and finally adding the rest raw materials, and continuously stirring uniformly;
(3) pouring into a clean container, and sealing with a cover.
3. Use of a composition comprising natural active ingredients according to claim 1 for cleaning fruits and vegetables.
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CN103122280A (en) * | 2011-11-19 | 2013-05-29 | 大连得达科技发展有限公司 | Pesticide residue scavenger |
CN103255007A (en) * | 2012-02-16 | 2013-08-21 | 上海植晶生物科技有限公司 | Pesticide residue cleaner |
CN102827709B (en) * | 2012-09-04 | 2014-11-05 | 北京中科梦成生物技术有限公司 | Enzyme preparation for removing pesticide residual on surfaces of vegetables and fruits and preparation method thereof |
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CN103820229A (en) * | 2014-03-20 | 2014-05-28 | 祝一鸣 | Natural antibacterial mould proofing detergent without petrochemical components |
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CN104232362A (en) * | 2014-08-29 | 2014-12-24 | 王晓伟 | Fruit/vegetable detergent containing aloe extract and preparation method of fruit/vegetable detergent |
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