CN110040963A - A kind of precious metal stove enamel tooth ivory white glaze and its application method - Google Patents
A kind of precious metal stove enamel tooth ivory white glaze and its application method Download PDFInfo
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- CN110040963A CN110040963A CN201910251695.3A CN201910251695A CN110040963A CN 110040963 A CN110040963 A CN 110040963A CN 201910251695 A CN201910251695 A CN 201910251695A CN 110040963 A CN110040963 A CN 110040963A
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- parts
- precious metal
- tooth
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- oxide
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- 210000003298 dental enamel Anatomy 0.000 title claims abstract description 46
- 239000010970 precious metal Substances 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims abstract description 19
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 47
- 239000000919 ceramic Substances 0.000 claims abstract description 45
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 42
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 38
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 23
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000010453 quartz Substances 0.000 claims abstract description 20
- 229910001928 zirconium oxide Inorganic materials 0.000 claims abstract description 20
- 239000011787 zinc oxide Substances 0.000 claims abstract description 19
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910001887 tin oxide Inorganic materials 0.000 claims abstract description 18
- 239000000454 talc Substances 0.000 claims abstract description 16
- 229910052623 talc Inorganic materials 0.000 claims abstract description 16
- 235000012222 talc Nutrition 0.000 claims abstract description 16
- 229910001649 dickite Inorganic materials 0.000 claims abstract description 15
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 235000012239 silicon dioxide Nutrition 0.000 claims description 21
- 230000001590 oxidative effect Effects 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 239000004575 stone Substances 0.000 claims description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 229910000510 noble metal Inorganic materials 0.000 claims description 6
- 238000007747 plating Methods 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 5
- 239000013078 crystal Substances 0.000 claims description 5
- 230000009965 odorless effect Effects 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 230000009967 tasteless effect Effects 0.000 claims description 5
- 239000006004 Quartz sand Substances 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 239000007822 coupling agent Substances 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- IVORCBKUUYGUOL-UHFFFAOYSA-N 1-ethynyl-2,4-dimethoxybenzene Chemical compound COC1=CC=C(C#C)C(OC)=C1 IVORCBKUUYGUOL-UHFFFAOYSA-N 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims description 2
- DDWBIQIJOKOKOT-UHFFFAOYSA-J [OH-].[Zr+4].Cl.[OH-].[OH-].[OH-] Chemical compound [OH-].[Zr+4].Cl.[OH-].[OH-].[OH-] DDWBIQIJOKOKOT-UHFFFAOYSA-J 0.000 claims description 2
- 238000010306 acid treatment Methods 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 2
- 239000000908 ammonium hydroxide Substances 0.000 claims description 2
- 229910052681 coesite Inorganic materials 0.000 claims description 2
- 229910052906 cristobalite Inorganic materials 0.000 claims description 2
- 238000002425 crystallisation Methods 0.000 claims description 2
- 230000008020 evaporation Effects 0.000 claims description 2
- 238000001704 evaporation Methods 0.000 claims description 2
- -1 half white frit Chemical compound 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 238000002386 leaching Methods 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- 235000010755 mineral Nutrition 0.000 claims description 2
- 239000004576 sand Substances 0.000 claims description 2
- ORVGYTXFUWTWDM-UHFFFAOYSA-N silicic acid;sodium Chemical group [Na].O[Si](O)(O)O ORVGYTXFUWTWDM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 2
- 229910052682 stishovite Inorganic materials 0.000 claims description 2
- XIFFNSGJZPAYQJ-UHFFFAOYSA-N sulfuric acid;zirconium Chemical compound [Zr].OS(O)(=O)=O XIFFNSGJZPAYQJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052905 tridymite Inorganic materials 0.000 claims description 2
- 239000011667 zinc carbonate Substances 0.000 claims description 2
- 235000004416 zinc carbonate Nutrition 0.000 claims description 2
- 229910000010 zinc carbonate Inorganic materials 0.000 claims description 2
- 235000010215 titanium dioxide Nutrition 0.000 claims 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 3
- 239000010936 titanium Substances 0.000 claims 3
- 229910052719 titanium Inorganic materials 0.000 claims 3
- 241000790917 Dioxys <bee> Species 0.000 claims 2
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 229910052845 zircon Inorganic materials 0.000 claims 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 claims 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims 1
- 229910052573 porcelain Inorganic materials 0.000 abstract description 12
- 230000007774 longterm Effects 0.000 abstract description 5
- 210000000214 mouth Anatomy 0.000 abstract description 5
- 230000005855 radiation Effects 0.000 abstract description 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract description 3
- 206010044038 Tooth erosion Diseases 0.000 abstract description 3
- 230000002378 acidificating effect Effects 0.000 abstract description 3
- 235000013361 beverage Nutrition 0.000 abstract description 3
- 230000035622 drinking Effects 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- 239000004411 aluminium Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- WGKMWBIFNQLOKM-UHFFFAOYSA-N [O].[Cl] Chemical compound [O].[Cl] WGKMWBIFNQLOKM-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 210000004513 dentition Anatomy 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000011022 opal Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000036346 tooth eruption Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Cosmetics (AREA)
- Dental Preparations (AREA)
Abstract
The invention discloses a kind of precious metal stove enamel tooth ivory white glaze and its application method, component and the weight item composition of the ivory white glaze of the precious metal stove enamel tooth include: 40-52 parts of changbaiite, 15-25 parts of quartz, 10-17 parts of calcite, 7-15 parts of dickite, 0.5-1.5 parts of zinc oxide, 5-10 parts of talcum, 1.3-3.5 parts of zirconium oxide, half white frit 4-10 parts, 0.7-2.1 parts of aluminium oxide, 0.5-1.2 parts of titanium dioxide, tin oxide 0.4-0.9.The present invention can increase ivory white whiteness; and exposed instead give birth to the sulfide in air in air of ceramic tooth is avoided to react flavescence; it can prevent ivory white baking-ceramic tooth from changing colour after long-term use; prevent user's long-term drinking acidic beverages from leading to porcelain erosion of teeth; increase the service life of baking-ceramic tooth; the wear resistance of baking-ceramic tooth can be increased; the titanium dioxide that raw material is added is nontoxic; there is preferable whiteness; and titanium dioxide adhesive force is strong; it is not easy to fall off from baking-ceramic tooth, it is possible to reduce radiation of the ultraviolet light to oral cavity has oral cavity certain protective effect.
Description
Technical field
The present invention relates to plating glaze precious metal stove enamel tooth field more particularly to a kind of ivory white glaze of precious metal stove enamel tooth and
Its application method.
Background technique
Baking-ceramic tooth is to be made into metal cap with high-strength alloy on natural teeth or planting body, its surface coat one layer with it is natural
The consistent porcelain powder in creamy white pool, is finally bonded in natural teeth, and baking-ceramic tooth can both repair single defect of teeth, can also be used as solid
Position body repairs defect of dentition, has appearance beauty true to nature, firm wear-resisting, wears with comfortable advantage, can restore the function of tooth
Can, and playing the role of beauty, precious metal stove enamel tooth is one of baking-ceramic tooth, and in general it is expensive to be divided into gold for precious metal stove enamel tooth
Metal-porcelain and Polarium precious metal stove enamel, both precious metal stove enamel tooth prices have the characteristics of their own, and metal is roasting
The interior hat of porcelain tooth is stable gold, and platinum, palldium alloy is non-stimulated to gum, and the good biocompatibility with human body, color is forced naturally
It is very tightly combined with tooth body, and has certain bactericidal effect, the outer hat of precious metal stove enamel tooth is porcelain, the knot of porcelain and noble metal
Conjunction property is very high, is not easy to collapse porcelain, ivory white glaze is the colorless or colored glassy thin layer for being covered on ceramic tooth surface, is to use mine
Raw material and raw material cooperate by a certain percentage is made glaze slip by grinding, imposes on billet surface, calcines through certain temperature, as
The surface that creamy white glaze is plated in baking-ceramic tooth can not only increase the aesthetics of baking-ceramic tooth, but also the machinery that can increase ceramic tooth is strong
Degree, it is wear-resistant, so that ceramic toilet article is had longer service life.
It is above-mentioned to prepare precious metal stove enamel tooth and there are certain drawbacks when in use with ivory white glaze, porcelain ivory white first
Tooth is easy to react with the sulfide in air after being used for a long time, and causes ivory white baking-ceramic tooth to turn yellow, secondly, not can be reduced purple
Radiation of the outside line to oral cavity, in addition, the hardness of baking-ceramic tooth is inadequate, user's long-term drinking acidic beverages can by porcelain erosion of teeth,
Reduce the service life of baking-ceramic tooth.
Summary of the invention
The object of the present invention is to provide a kind of precious metal stove enamel tooth ivory white glaze and its application methods, solve tradition
Ivory white precious metal stove enamel tooth be easy discoloration, cannot absorb radiation, be used for a long time be easy the problem of being corroded.
In order to achieve the above object, the present invention is achieved by the following technical solutions:
The present invention provides a kind of precious metal stove enamel tooth ivory white glaze and its application method, and the precious metal stove enamel tooth is with ivory white
Component and the weight item composition of glaze include: 40-52 parts of changbaiite, 15-25 parts of quartz, 10-17 parts of calcite, dickite
7-15 parts, 0.5-1.5 parts of zinc oxide, 5-10 parts of talcum, 1.3-3.5 parts of zirconium oxide, half white frit 4-10 parts, aluminium oxide 0.7-
2.1 parts, 0.5-1.2 parts of titanium dioxide, tin oxide 0.4-0.9.
Preferably, the ivory white glaze of the precious metal stove enamel tooth component and weight item composition include: 50 parts of changbaiite,
15 parts of quartz, 10 parts of calcite, 8 parts of dickite, 0.7 part of zinc oxide, 5 parts of talcum, 2 parts of zirconium oxide, half 6 parts of white frit, oxygen
Change 2.1 parts of aluminium, 0.8 part of titanium dioxide, 0.4 part of tin oxide.
Preferably, the ivory white glaze of the precious metal stove enamel tooth component and weight item composition include: 48 parts of changbaiite,
20 parts of quartz, 9 parts of calcite, 7 parts of dickite, 0.8 part of zinc oxide, 6 parts of talcum, 1.5 parts of zirconium oxide, half 5 parts of white frit, oxygen
Change 0.9 part of aluminium, 1.2 parts of titanium dioxide, 0.6 part of tin oxide.
Preferably, the ivory white glaze of the precious metal stove enamel tooth component and weight item composition include: 47 parts of changbaiite,
18 parts of quartz, 7 parts of calcite, 9 parts of dickite, 0.6 part of zinc oxide, 8 parts of talcum, 1.3 parts of zirconium oxide, half 7 parts of white frit, oxygen
Change 0.7 part of aluminium, 0.7 part of titanium dioxide, 0.7 part of tin oxide.
Preferably, the changbaiite is sub-translucent to translucent, refractive index about 1.56~1.60.
Preferably, the quartz ingredient is mainly SiO2, and varied quartz color is often milky, nothing
Color, grey are deployed by quartz sand, resin, coupling agent, curing agent, titanium dioxide by formula rate, first deployed in proportion
Resin, coupling agent, titanium dioxide are mixed in the stirring carried out in agitator 2 minutes, while the quartz sand weighed up, curing agent sand being poured into
It stirs in bucket, heating is stirred even with an ancient unit of weight, quartz is obtained after cooling, the calcite is colourless or white, the calcite crystal
For sheet, crystalline aggregate is usually very tiny.
Preferably, the dickite is a kind of aluminium silicate mineral of hydroxyl, colourless, or with faint yellow, the oxidation
Zinc is a kind of oxide of zinc, and the zinc oxide is white powder or hexaplanar crystalline solid, and odorless tasteless, no grittiness is heated
Become yellow, the zinc oxide is calcined by zinc carbonate and obtained, and the talcum is in bulk, foliaceous, threadiness or radial, color
For white, canescence.
Preferably, the zirconium oxide is the main oxides of zirconium, is white odorless, tasteless crystal under usual condition, passes through zirconium
Diamond stone and caustic soda are melted at 650 DEG C, hot water leaching molten mass, and silicon is separated in silicic acid sodium form with sodium zirconate, then with sulfuric acid treatment,
Sulfuric acid zirconium solution is obtained, further except ammonium hydroxide is added after impurity, zirconium hydroxide is settled out, adds dissolving with hydrochloric acid zirconium hydroxide, obtain chlorine oxygen
Change zirconium, through evaporation and concentration, crystallisation by cooling, crushing, roasting to get zirconium oxide finished product.
The present invention also provides a kind of ivory white glaze of precious metal stove enamel tooth and its processing methods of application method, specific to wrap
Include following steps:
(1) by specific component and weight item composition prepare changbaiite, quartz, calcite, dickite, zinc oxide, talcum,
Zirconium oxide, half white frit, aluminium oxide, titanium dioxide, tin oxide raw material；
(2) each raw material is mixed, adds the abundant ball milling of water, is uniformly mixing to obtain ivory white glaze slip；
(3) precious metal stove enamel tooth is placed on the wheel of rotation, glaze slip in (2) is poured in the center of precious metal stove enamel tooth, by
Centrifugal force makes glaze slip uniformly scatter, to obtain the baking-ceramic tooth of glazing completion；
(4) temperature is made to be ramped up 330-440 DEG C in 1.5-2.8h under oxidizing atmosphere the baking-ceramic tooth after glazing in (3), after
Continue makes temperature be ramped up 880-980 DEG C in 2.3-3.4h under oxidizing atmosphere, then so that temperature is existed under reducing atmosphere
7.8-12h is ramped up 1250-11300 DEG C, is finally cooled to room temperature baking-ceramic tooth, both the ivory white noble metal of available plating glaze
Baking-ceramic tooth.
Half white frit is made of nitre, borax, silicate, and half white frit is first made before preparing glaze slip, with dyke these
Raw material melts in water when preparing glair, and coloring agent is put into half white frit and is melted in advance, it can be made to be distributed in color glaze
It is more average, transfer dyeing efficiency half white frit should with must component fat clay mixing fine grinding, manufactured glair is
Possessing the suspension relatively stabilized and the tackness to green body, half white frit whiteness is higher, make ground coat enamel covering power with higher,
The color of precious metal stove enamel tooth can be completely covered.
Aluminium oxide is the white solid for being insoluble in water, odorless, tasteless, matter is extremely hard, and aluminium oxide is by bauxite and hard water aluminium
Made of stones standby, in glaze, aluminium oxide can make brightening agent use.
Titanium dioxide is a kind of white inorganic pigment, has nontoxic, optimal opacity, best whiteness and brightness,
It is usually reacted under conditions of being constantly passed through air and stirring with levigate ilmenite and sulfuric acid, soluble sulphate is made,
Then the sulfuric acid salt hydrolysis of preparation is obtained into titanium dioxide.
Tin oxide be it is white, faint yellow or light gray is cubic, six sides or orthorhombic system powder, tin oxide be usually used in enamel with
Electromagnetic material, and the polishing for manufacturing opal glass, pink salt, porcelain colorant, fabric mordant and weighting agent, steel and glass
Agent, tin oxide are usually burnt by tin in air, or are acted on by tetravalence solubility pink salt and alkali, can also be by metallic tin and dense HNO3
Effect generates β-stannic acid precipitating, then heated, dehydration and tin oxide.
Beneficial effects of the present invention: zinc oxide, which is added, in the present invention can increase ivory white whiteness, and avoid ceramic tooth sudden and violent
Anti- flavescence is reacted in life to dew with the sulfide in air in air, can prevent ivory white baking-ceramic tooth from changing colour after long-term use,
Keep baking-ceramic tooth more attractive, zirconium oxide secondly, which is added, in glaze can protect porcelain dentification, other by baking-ceramic tooth are easy to acid
The raw material of reaction wraps up, and prevents user's long-term drinking acidic beverages from leading to porcelain erosion of teeth, increases the service life of baking-ceramic tooth,
And zirconium oxide comparatively robust, the wear resistance of baking-ceramic tooth can be increased, the titanium dioxide that raw material is added is nontoxic, has preferable white
Degree, and titanium dioxide adhesive force is strong, is not easy to fall off from baking-ceramic tooth, keeps baking-ceramic tooth more durable, titanium dioxide property is stablized,
It is not easy to change, ceramic tooth is used for a long time, ultraviolet light can be absorbed additionally by titanium dioxide, it is possible to reduce ultraviolet light pair
The radiation in oral cavity has certain protective effect to oral cavity.
Specific embodiment
With reference to embodiment, the specific embodiment of the present invention is further described.Following embodiment is only used for more
Add and clearly demonstrate technical solution of the present invention, and not intended to limit the protection scope of the present invention.
Embodiment 1
Specific step is as follows for production method:
(1) according to component and weight item composition prepare: 50 parts of changbaiite, 15 parts of quartz, 10 parts of calcite, 8 parts of dickite,
0.7 part of zinc oxide, 5 parts of talcum, 2 parts of zirconium oxide, half 6 parts of white frit, 2.1 parts of aluminium oxide, 0.8 part of titanium dioxide, tin oxide 0.4
Part；
(2) each raw material is mixed, adds the abundant ball milling of water, is uniformly mixing to obtain ivory white glaze slip；
(3) precious metal stove enamel tooth is placed on the wheel of rotation, glaze slip in (2) is poured in the center of precious metal stove enamel tooth, by
Centrifugal force makes glaze slip uniformly scatter, to obtain the baking-ceramic tooth of glazing completion；
(4) temperature is made to be ramped up 330-440 DEG C in 1.5-2.8h under oxidizing atmosphere the baking-ceramic tooth after glazing in (3), after
Continue makes temperature be ramped up 880-980 DEG C in 2.3-3.4h under oxidizing atmosphere, then so that temperature is existed under reducing atmosphere
7.8-12h is ramped up 1250-11300 DEG C, is finally cooled to room temperature baking-ceramic tooth, both the ivory white noble metal of available plating glaze
Baking-ceramic tooth.
Embodiment 2
Specific step is as follows for production method:
(1) according to component and weight item composition prepare: 48 parts of changbaiite, 20 parts of quartz, 9 parts of calcite, 7 parts of dickite,
0.8 part of zinc oxide, 6 parts of talcum, 1.5 parts of zirconium oxide, half 5 parts of white frit, 0.9 part of aluminium oxide, 1.2 parts of titanium dioxide, tin oxide
0.6 part；
(2) each raw material is mixed, adds the abundant ball milling of water, is uniformly mixing to obtain ivory white glaze slip；
(3) precious metal stove enamel tooth is placed on the wheel of rotation, glaze slip in (2) is poured in the center of precious metal stove enamel tooth, by
Centrifugal force makes glaze slip uniformly scatter, to obtain the baking-ceramic tooth of glazing completion；
(4) temperature is made to be ramped up 330-440 DEG C in 1.5-2.8h under oxidizing atmosphere the baking-ceramic tooth after glazing in (3), after
Continue makes temperature be ramped up 880-980 DEG C in 2.3-3.4h under oxidizing atmosphere, then so that temperature is existed under reducing atmosphere
7.8-12h is ramped up 1250-11300 DEG C, is finally cooled to room temperature baking-ceramic tooth, both the ivory white noble metal of available plating glaze
Baking-ceramic tooth.
Embodiment 3
Specific step is as follows for production method:
(1) according to component and weight item composition prepare: 47 parts of changbaiite, 18 parts of quartz, 7 parts of calcite, 9 parts of dickite,
0.6 part of zinc oxide, 8 parts of talcum, 1.3 parts of zirconium oxide, half 7 parts of white frit, 0.7 part of aluminium oxide, 0.7 part of titanium dioxide, tin oxide
0.7 part；
(2) each raw material is mixed, adds the abundant ball milling of water, is uniformly mixing to obtain ivory white glaze slip；
(3) precious metal stove enamel tooth is placed on the wheel of rotation, glaze slip in (2) is poured in the center of precious metal stove enamel tooth, by
Centrifugal force makes glaze slip uniformly scatter, to obtain the baking-ceramic tooth of glazing completion；
(4) temperature is made to be ramped up 330-440 DEG C in 1.5-2.8h under oxidizing atmosphere the baking-ceramic tooth after glazing in (3), after
Continue makes temperature be ramped up 880-980 DEG C in 2.3-3.4h under oxidizing atmosphere, then so that temperature is existed under reducing atmosphere
7.8-12h is ramped up 1250-11300 DEG C, is finally cooled to room temperature baking-ceramic tooth, both the ivory white noble metal of available plating glaze
Baking-ceramic tooth.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (9)
1. a kind of precious metal stove enamel tooth ivory white glaze and its application method, which is characterized in that the precious metal stove enamel tooth with as
Creamy white glaze component and weight item composition include: 40-52 parts of changbaiite, 15-25 parts of quartz, 10-17 parts of calcite,
Open 7-15 parts of stone, 0.5-1.5 parts of zinc oxide, 5-10 parts of talcum, 1.3-3.5 parts of zirconium oxide, half white frit 4-10 parts, aluminium oxide
0.7-2.1 parts, 0.5-1.2 parts of titanium dioxide, tin oxide 0.4-0.9.
2. a kind of precious metal stove enamel tooth ivory white glaze and its application method according to claim 1, which is characterized in that
Component and the weight item composition of the ivory white glaze of the precious metal stove enamel tooth include: 50 parts of changbaiite, 15 parts of quartz, Fang Xie
10 parts of stone, 8 parts of dickite, 0.7 part of zinc oxide, 5 parts of talcum, 2 parts of zirconium oxide, half 6 parts of white frit, 2.1 parts of aluminium oxide, titanium dioxide
0.8 part of titanium, 0.4 part of tin oxide.
3. a kind of precious metal stove enamel tooth ivory white glaze and its application method according to claim 1, which is characterized in that
Component and the weight item composition of the ivory white glaze of the precious metal stove enamel tooth include: 48 parts of changbaiite, 20 parts of quartz, Fang Xie
9 parts of stone, 7 parts of dickite, 0.8 part of zinc oxide, 6 parts of talcum, 1.5 parts of zirconium oxide, half 5 parts of white frit, 0.9 part of aluminium oxide, dioxy
Change 1.2 parts of titanium, 0.6 part of tin oxide.
4. a kind of precious metal stove enamel tooth ivory white glaze and its application method according to claim 1, which is characterized in that
Component and the weight item composition of the ivory white glaze of the precious metal stove enamel tooth include: 47 parts of changbaiite, 18 parts of quartz, Fang Xie
7 parts of stone, 9 parts of dickite, 0.6 part of zinc oxide, 8 parts of talcum, 1.3 parts of zirconium oxide, half 7 parts of white frit, 0.7 part of aluminium oxide, dioxy
Change 0.7 part of titanium, 0.7 part of tin oxide.
5. a kind of precious metal stove enamel tooth ivory white glaze and its application method according to claim 1, which is characterized in that
The changbaiite is sub-translucent to translucent, refractive index about 1.56~1.60.
6. a kind of precious metal stove enamel tooth ivory white glaze and its application method according to claim 1, which is characterized in that
The quartz ingredient is mainly SiO2, and varied quartz color is often milky, colourless, grey, passes through quartz
Sand, resin, coupling agent, curing agent, titanium dioxide are deployed by formula rate, first resin deployed in proportion, coupling agent, titanium white
Powder is mixed in the stirring carried out in agitator 2 minutes, while the quartz sand weighed up, curing agent sand being poured into and stirred in bucket, and heating is stirred
It is even with an ancient unit of weight, obtain quartz after cooling, the calcite be it is colourless or white, the calcite crystal is sheet, crystal set
Body is usually very tiny.
7. a kind of precious metal stove enamel tooth ivory white glaze and its application method according to claim 1, which is characterized in that
The dickite is a kind of aluminium silicate mineral of hydroxyl, colourless, or with faint yellow, and the zinc oxide is a kind of oxidation of zinc
Object, the zinc oxide are white powder or hexaplanar crystalline solid, and odorless tasteless, no grittiness is heated to become yellow, the oxidation
Zinc is calcined by zinc carbonate and is obtained, and the talcum is in bulk, foliaceous, threadiness or radial, and color is white, canescence.
8. a kind of precious metal stove enamel tooth ivory white glaze and its application method according to claim 1, which is characterized in that
The zirconium oxide is the main oxides of zirconium, is white odorless, tasteless crystal under usual condition, by zircon and caustic soda 650
DEG C melting, hot water leaching molten mass, silicon are separated with sodium zirconate in silicic acid sodium form, then with sulfuric acid treatment, obtain sulfuric acid zirconium solution, into
One step adds ammonium hydroxide after removing impurity, is settled out zirconium hydroxide, adds dissolving with hydrochloric acid zirconium hydroxide, obtain basic zirconium chloride, be concentrated by evaporation,
Crystallisation by cooling, crushing, roasting are to get zirconium oxide finished product.
9. a kind of ivory white glaze of precious metal stove enamel tooth according to claim 1-8 and its application method plus
Work method, which is characterized in that specifically includes the following steps:
(1) component described in -4 any one and weight item composition prepare changbaiite, quartz, Fang Xie according to claim 1
Stone, dickite, zinc oxide, talcum, zirconium oxide, half white frit, aluminium oxide, titanium dioxide, tin oxide raw material；
(2) each raw material is mixed, adds the abundant ball milling of water, is uniformly mixing to obtain ivory white glaze slip；
(3) precious metal stove enamel tooth is placed on the wheel of rotation, glaze slip in (2) is poured in the center of precious metal stove enamel tooth, by
Centrifugal force makes glaze slip uniformly scatter, to obtain the baking-ceramic tooth of glazing completion；
(4) temperature is made to be ramped up 330-440 DEG C in 1.5-2.8h under oxidizing atmosphere the baking-ceramic tooth after glazing in (3), after
Continue makes temperature be ramped up 880-980 DEG C in 2.3-3.4h under oxidizing atmosphere, then so that temperature is existed under reducing atmosphere
7.8-12h is ramped up 1250-11300 DEG C, is finally cooled to room temperature baking-ceramic tooth, both the ivory white noble metal of available plating glaze
Baking-ceramic tooth.
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|---|---|---|---|---|
| CN112028488A (en) * | 2020-09-04 | 2020-12-04 | 福建省春秋陶瓷实业有限公司 | Ivory white glaze ceramic product with light brown ground glaze and preparation method thereof |
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