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CN110038391A - Powdered activated coke moving bed desulfurizer - Google Patents

Powdered activated coke moving bed desulfurizer Download PDF

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Publication number
CN110038391A
CN110038391A CN201910373226.9A CN201910373226A CN110038391A CN 110038391 A CN110038391 A CN 110038391A CN 201910373226 A CN201910373226 A CN 201910373226A CN 110038391 A CN110038391 A CN 110038391A
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activated coke
powdered activated
moving bed
section
outlet
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CN110038391B (en
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杨春振
杨超玉
赵剑
吴华
马鸿良
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CHINA ENERGY SAVING REDUCTION Co Ltd
China Energy Investment Corp Ltd
Shandong Shenhua Shanda Energy and Environment Co Ltd
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CHINA ENERGY SAVING REDUCTION Co Ltd
China Energy Investment Corp Ltd
Shandong Shenhua Shanda Energy and Environment Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/02Particle separators, e.g. dust precipitators, having hollow filters made of flexible material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • B01D53/08Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds according to the "moving bed" method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)

Abstract

本发明提供了一种粉状活性焦移动床脱硫装置。该装置包括移动床脱硫单元,移动床脱硫单元包括:移动床本体,移动床本体具有空腔,移动床本体上还设置有待脱硫气体进口和与待脱硫气体进口相对设置的脱硫气体出口,按照气体流动方向,空腔依次被分割为气流进入段、填料填充段及气流排出段,气流进入段设置有待脱硫气体进口和粉状活性焦喷入口,脱硫气体出口设置在气流排出段,填料填充段中填充有惰性床料和/或颗粒活性焦,且惰性床料及颗粒活性焦的粒径均大于粉状活性焦。利用该装置对气体进行粉状活性焦移动床脱硫处理,能够显著增加粉状活性焦在系统中的停留时间,从而能够更充分地利用粉状活性焦的硫容,提高脱硫效率。

The invention provides a powder active coke moving bed desulfurization device. The device includes a moving bed desulfurization unit, and the moving bed desulfurization unit includes: a moving bed body, the moving bed body has a cavity, and the moving bed body is also provided with a gas inlet to be desulfurized and a desulfurization gas outlet arranged opposite to the gas inlet to be desulfurized. In the flow direction, the cavity is divided into an airflow entry section, a filler filling section and an airflow discharge section in turn. The airflow entry section is provided with a gas inlet to be desulfurized and a powder activated coke injection port, and the desulfurized gas outlet is set in the airflow discharge section. Filled with inert bed material and/or granular activated coke, and the particle size of both inert bed material and granular activated coke is larger than that of powdery activated coke. Using the device to desulfurize the gas in a moving bed of powdered activated coke can significantly increase the residence time of powdered activated coke in the system, so that the sulfur content of powdered activated coke can be more fully utilized, and the desulfurization efficiency can be improved.

Description

粉状活性焦移动床脱硫装置Powder activated coke moving bed desulfurization device

技术领域technical field

本发明涉及气体脱硫技术领域,具体而言,涉及一种粉状活性焦移动床脱硫装置。The present invention relates to the technical field of gas desulfurization, in particular to a powder activated coke moving bed desulfurization device.

背景技术Background technique

半干法脱硫技术是电厂减少水消耗、解决石灰石-石膏法脱硫技术脱硫废水零排的重要技术。与颗粒状活性焦相比,粉状活性焦(粒径小于等于200μm)具有比表面积大、生产工艺简单、成本低等优势。针对颗粒活性焦,采用移动床脱硫工艺能够保证活性焦的停留时间,但是该技术活性焦初装量大;针对粉状活性焦,采用循环流化床半干法脱硫工艺能够保证气固充分接触,对于提高脱硫效率是有益的,但是该技术无法有效保证活性焦在系统内的停留时间,造成活性焦硫容无法充分被应用。Semi-dry desulfurization technology is an important technology for power plants to reduce water consumption and solve zero discharge of desulfurization wastewater from limestone-gypsum desulfurization technology. and Compared with granular activated coke, powdered activated coke (particle size less than or equal to 200 μm) has the advantages of large specific surface area, simple production process and low cost. For granular activated coke, the moving bed desulfurization process can ensure the residence time of the activated coke, but the initial charge of the activated coke is large; for powdery activated coke, the circulating fluidized bed semi-dry desulfurization process can ensure sufficient gas-solid contact , it is beneficial to improve the desulfurization efficiency, but this technology cannot effectively guarantee the residence time of the activated coke in the system, resulting in that the activated coke sulfur capacity cannot be fully used.

充分保证粉状活性焦在脱硫系统内的停留时间成为推广粉状活性焦脱硫技术的关键,基于以上原因,有必要提供一种新的粉状活性焦脱硫工艺,以提高粉状活性焦在系统内的停留时间。Fully ensuring the residence time of powdered activated coke in the desulfurization system has become the key to popularizing powdered activated coke desulfurization technology. residence time within.

发明内容SUMMARY OF THE INVENTION

本发明的主要目的在于提供一种粉状活性焦移动床脱硫装置,以解决现有技术中粉状活性焦在脱硫系统中停留时间较短导致的无法充分利用其硫容的问题。The main purpose of the present invention is to provide a powdered activated coke moving bed desulfurization device to solve the problem that the powdery activated coke cannot make full use of its sulfur capacity due to the short residence time of the powdered activated coke in the desulfurization system in the prior art.

为了实现上述目的,根据本发明的一个方面,提供了一种粉状活性焦移动床脱硫装置,其包括移动床脱硫单元,移动床脱硫单元包括:移动床本体,移动床本体具有空腔,移动床本体上还设置有待脱硫气体进口和与待脱硫气体进口相对设置的脱硫气体出口,按照气体流动方向,空腔依次被分割为气流进入段、填料填充段及气流排出段,气流进入段设置有待脱硫气体进口和粉状活性焦喷入口,脱硫气体出口设置在气流排出段,填料填充段中填充有惰性床料和/或颗粒活性焦,且惰性床料及颗粒活性焦的粒径均大于粉状活性焦。In order to achieve the above object, according to one aspect of the present invention, a powder activated coke moving bed desulfurization device is provided, which includes a moving bed desulfurization unit, and the moving bed desulfurization unit includes: a moving bed body, the moving bed body has a cavity, and the moving bed The bed body is also provided with a gas inlet to be desulfurized and a desulfurized gas outlet opposite to the inlet of the gas to be desulfurized. According to the gas flow direction, the cavity is divided into an airflow entry section, a packing filling section and an airflow discharge section in turn. The desulfurization gas inlet and the powdery active coke spray inlet, the desulfurization gas outlet is arranged in the gas flow discharge section, and the filler filling section is filled with inert bed material and/or granular activated coke, and the particle size of the inert bed material and granular activated coke is larger than that of the powdery active coke Active coke.

进一步地,按照气体流动方向,气流进入段包括靠近待脱硫气体进口设置的气流入口段和与其相连并靠近填料填充段设置的气流渐扩段。Further, according to the gas flow direction, the gas flow inlet section includes a gas flow inlet section arranged close to the inlet of the gas to be desulfurized and a gas flow expanding section connected to it and arranged near the filler filling section.

进一步地,气流入口段设置有至少一个粉状活性焦喷入口。Further, the airflow inlet section is provided with at least one powder activated coke spray inlet.

进一步地,移动床脱硫单元还包括粉状活性焦喷射装置,粉状活性焦喷射装置穿过移动床本体的外壁延伸至气流渐扩段内部,且粉状活性焦喷射装置设置有多个粉状活性焦喷入口。Further, the moving bed desulfurization unit also includes a powdery active coke spray device, the powdery active coke spray device extends through the outer wall of the moving bed body to the inside of the airflow gradually expanding section, and the powdery active coke spray device is provided with a plurality of powdery active coke spray devices. Active coke injection port.

进一步地,气流渐扩段的底部还设置有粉状活性焦落料仓,用于承接气流渐扩段内部因重力落下的粉状活性焦。Further, the bottom of the airflow gradually expanding section is also provided with a powdery active coke dropping bin for receiving the powdery active coke falling from the inside of the airflow gradually expanding section due to gravity.

进一步地,按照气体流动方向,气流排出段包括靠近填料填充段设置的气流渐缩段和靠近脱硫气体出口设置的气流出口段。Further, according to the gas flow direction, the gas flow discharge section includes a gas flow constriction section arranged near the filler filling section and a gas flow outlet section arranged near the desulfurized gas outlet.

进一步地,移动床脱硫单元还包括:第一气流均布板,设置在气流进入段和填料填充段之间;第二气流均布板,设置在填料填充段和气流排出段之间。Further, the moving bed desulfurization unit further includes: a first airflow uniform distribution plate, which is arranged between the airflow entry section and the packing filling section; and a second airflow uniform distribution board, which is arranged between the packing filling section and the airflow discharge section.

进一步地,填料填充段顶部设置有惰性床料和/或颗粒活性焦的入口,底部设置有惰性床料和/或颗粒活性焦的出口。Further, an inlet for inert bed material and/or granular activated coke is provided at the top of the packing section, and an outlet for inert bed material and/or granular activated coke is provided at the bottom.

进一步地,移动床脱硫单元还包括:第一布水增湿单元,设置在填料填充段中靠近顶部的位置;第二布水增湿单元,设置在气流入口段中。Further, the moving bed desulfurization unit further includes: a first water distribution and humidification unit, which is arranged in a position close to the top of the filler filling section; and a second water distribution and humidification unit, which is arranged in the airflow inlet section.

进一步地,移动床脱硫单元还包括第一布袋除尘器,第一布袋除尘器的入口与脱硫气体出口相连,第一布袋除尘器还具有第一气相出口和第一固相出口。Further, the moving bed desulfurization unit further includes a first bag filter, the inlet of the first bag filter is connected to the desulfurization gas outlet, and the first bag filter also has a first gas phase outlet and a first solid phase outlet.

进一步地,粉状活性焦移动床脱硫装置还包括分离单元,分离单元包括:分离床,具有床料进口、流化气进口、流化气出口和床料出口,床料进口与填料填充段的出口相连;第二布袋除尘器,其进口与流化气出口相连,且第二布袋除尘器还具有第二气相出口和第二固相出口,第二气相出口与流化气进口相连;床料储仓,与床料出口相连。Further, the powder activated coke moving bed desulfurization device also includes a separation unit, and the separation unit includes: a separation bed, which has a bed material inlet, a fluidization gas inlet, a fluidization gas outlet and a bed material outlet, and the bed material inlet and the filler filling section are connected. The outlet is connected to the second bag filter, the inlet of which is connected to the fluidizing gas outlet, and the second bag filter also has a second gas phase outlet and a second solid phase outlet, and the second gas phase outlet is connected to the fluidizing gas inlet; bed material Storage bin, connected to the bed material outlet.

进一步地,气流渐扩段的底部还设置有粉状活性焦落料仓,用于承接气流渐扩段内部因重力落下的粉状活性焦;粉状活性焦落料仓底部还设置有排料口,分离床的床料进口还与排料口及第一布袋除尘器的第一固相出口相连。Further, the bottom of the airflow gradually expanding section is also provided with a powdery active coke blanking bin, which is used to receive the powdery active coke that falls due to gravity inside the airflow gradually expanding section; the bottom of the powdery active coke blanking bin is also provided with a discharge material. The bed material inlet of the separation bed is also connected with the discharge port and the first solid phase outlet of the first bag filter.

进一步地,移动床脱硫单元还包括至少一个粉状活性焦供应仓,粉状活性焦供应仓的出口与粉状活性焦喷入口相连,粉状活性焦供应仓的入口与第二布袋除尘器的第二固相出口相连。Further, the moving bed desulfurization unit also includes at least one powdery active coke supply bin, the outlet of the powdery active coke supply bin is connected to the powdery active coke spray inlet, and the inlet of the powdery active coke supply bin is connected to the second bag filter. The second solid phase outlet is connected.

进一步地,移动床脱硫单元还包括床料供应仓,床料供应仓的入口与床料储仓的出口相连,床料供应仓的出口与填料填充段顶部的入口。Further, the moving bed desulfurization unit further includes a bed material supply bin, the inlet of the bed material supply bin is connected with the outlet of the bed material storage bin, and the outlet of the bed material supply bin is connected with the inlet at the top of the packing section.

进一步地,粉状活性焦移动床脱硫装置还包括粉状活性焦退出装置,其与粉状活性焦供应仓的入口和第二固相出口之间的管路相连。Further, the powdered activated coke moving bed desulfurization device further includes a powdered activated coke withdrawal device, which is connected with the pipeline between the inlet of the powdered activated coke supply bin and the second solid phase outlet.

进一步地,分离单元还包括循环风机,其设置在第二气相出口与流化气进口相连的管路上。Further, the separation unit further includes a circulating fan, which is arranged on the pipeline connecting the second gas phase outlet with the fluidizing gas inlet.

利用本发明提供的粉状活性焦移动床脱硫装置对气体进行粉状活性焦移动床脱硫处理,能够显著增加粉状活性焦在系统中的停留时间,从而能够更充分地利用粉状活性焦的硫容,提高脱硫效率。Using the powder activated coke moving bed desulfurization device provided by the present invention to carry out the powder activated coke moving bed desulfurization treatment on the gas can significantly increase the residence time of the powder activated coke in the system, so that the powder activated coke can be more fully utilized. Sulfur capacity, improve desulfurization efficiency.

附图说明Description of drawings

构成本申请的一部分的说明书附图用来提供对本发明的进一步理解,本发明的示意性实施例及其说明用于解释本发明,并不构成对本发明的不当限定。在附图中:The accompanying drawings forming a part of the present application are used to provide further understanding of the present invention, and the exemplary embodiments of the present invention and their descriptions are used to explain the present invention and do not constitute an improper limitation of the present invention. In the attached image:

图1示出了根据本发明一种实施例中的粉状活性焦移动床脱硫装置的结构示意图;以及FIG. 1 shows a schematic structural diagram of a powdered activated coke moving bed desulfurization device according to an embodiment of the present invention; and

图2示出了仿真计算得到的图1中的粉状活性焦移动床脱硫装置在实际脱硫工作中移动床内部的粉状活性焦的分布图。FIG. 2 shows the distribution diagram of powdery active coke inside the moving bed of the powdery active coke moving bed desulfurization device in FIG. 1 obtained by simulation calculation during the actual desulfurization work.

其中,上述附图包括以下附图标记:Wherein, the above-mentioned drawings include the following reference signs:

1、移动床脱硫单元;2、分离单元;3、粉状活性焦退出装置;1. Moving bed desulfurization unit; 2. Separation unit; 3. Powder activated coke exit device;

10、移动床本体;11、气流进入段;111、气流入口段;112、气流渐扩段;113、粉状活性焦落料仓;12、填料填充段;13、气流排出段;131、气流渐缩段;132、气流出口段;14、第一气流均布板;15、第二气流均布板;16、第一布水增湿单元;17、第二布水增湿单元;18、第一布袋除尘器;19、粉状活性焦供应仓;20、粉状活性焦喷射装置;30、床料供应仓;21、分离床;22、第二布袋除尘器;23、床料储仓;24、循环风机;31、粉状活性焦退出仓;10. Moving bed body; 11. Air flow entry section; 111, Air flow inlet section; 112, Air flow gradually expanding section; 113, Powder activated coke blanking bin; 12, Filler filling section; 13, Air flow discharge section; 131, Air flow Tapering section; 132, air outlet section; 14, first air distribution plate; 15, second air distribution plate; 16, first water distribution humidification unit; 17, second water distribution humidification unit; 18, The first bag filter; 19, the powder active coke supply bin; 20, the powder active coke injection device; 30, the bed material supply bin; 21, the separation bed; 22, the second bag filter; 23, the bed material storage bin ; 24. Circulating fan; 31. Powdered active coke exits the warehouse;

101、第一阀门;102、第二阀门;103、第三阀门;104、第四阀门;105、第五阀门;106、第六阀门;107、第七阀门;108、第八阀门;109、第九阀门;201、第十阀门;202、第十一阀门;203、第十二阀门;301、第十三阀门;302、第十四阀门。101, the first valve; 102, the second valve; 103, the third valve; 104, the fourth valve; 105, the fifth valve; 106, the sixth valve; 107, the seventh valve; 108, the eighth valve; 109, The ninth valve; 201, the tenth valve; 202, the eleventh valve; 203, the twelfth valve; 301, the thirteenth valve; 302, the fourteenth valve.

具体实施方式Detailed ways

需要说明的是,在不冲突的情况下,本申请中的实施例及实施例中的特征可以相互组合。下面将参考附图并结合实施例来详细说明本发明。It should be noted that the embodiments in the present application and the features of the embodiments may be combined with each other in the case of no conflict. The present invention will be described in detail below with reference to the accompanying drawings and in conjunction with the embodiments.

正如背景技术部分所描述的,现有技术中粉状活性焦在脱硫系统中停留时间较短,其硫容无法充分利用,影响了脱硫效率。As described in the background art section, the residence time of powdered activated coke in the desulfurization system is short in the prior art, and its sulfur capacity cannot be fully utilized, which affects the desulfurization efficiency.

为了解决上述问题,本发明提供了一种粉状活性焦移动床脱硫装置,如图1所示,其包括移动床脱硫单元1,移动床脱硫单元1包括:移动床本体10,移动床本体10具有空腔,移动床本体10上还设置有待脱硫气体进口和与待脱硫气体进口相对设置的脱硫气体出口,按照气体流动方向,空腔依次被分割为气流进入段11、填料填充段12及气流排出段13,气流进入段11设置有待脱硫气体进口和粉状活性焦喷入口,脱硫气体出口设置在气流排出段13,填料填充段12中填充有惰性床料和/或颗粒活性焦,且惰性床料及颗粒活性焦的粒径均大于粉状活性焦。In order to solve the above problems, the present invention provides a powder activated coke moving bed desulfurization device, as shown in FIG. 1 , which includes a moving bed desulfurization unit 1 , and the moving bed desulfurization unit 1 includes: a moving bed body 10 , a moving bed body 10 It has a cavity, and the moving bed body 10 is also provided with a gas inlet to be desulfurized and a desulfurized gas outlet arranged opposite to the gas inlet to be desulfurized. According to the gas flow direction, the cavity is divided into an air flow entry section 11, a filler filling section 12 and an air flow in turn. The discharge section 13, the gas flow inlet section 11 is provided with a gas inlet to be desulfurized and a powdery active coke spray inlet, the desulfurization gas outlet is set in the gas flow discharge section 13, and the filler filling section 12 is filled with inert bed material and/or granular active coke, and inert The particle size of the bed material and granular activated coke is larger than that of the powdered activated coke.

在实际运行过程中,如图1所示,待脱硫气体A通过待脱硫气体进口进入气流进入段11,在气流进入段11中与粉状活性焦喷入口喷入的粉状活性焦相接触并进行脱硫过程。与此同时,随气流的流动,粉状活性焦被夹带在气体中一并进入填料填充段12,在该阶段,粉状活性焦一边继续进行脱硫过程,一边逐渐被填充的惰性床料和/或颗粒活性焦拦截,完成气固分离。分离后的脱硫气体通过气流排出段13排出。而拦截粉状活性焦后的惰性床料和/或颗粒活性能够缓慢排出移动床本体10。In the actual operation process, as shown in Figure 1, the gas A to be desulfurized enters the gas flow entry section 11 through the gas inlet to be desulfurized, and in the gas flow entry section 11, it contacts with the powdery activated coke sprayed into the powdery active coke injection port, and Carry out the desulfurization process. At the same time, with the flow of the gas flow, the powdery activated coke is entrained in the gas and enters the filler filling section 12. At this stage, the powdery activated coke continues the desulfurization process while gradually being filled with the inert bed material and/or Or particle active coke interception to complete gas-solid separation. The separated desulfurized gas is discharged through the gas flow discharge section 13 . The inert bed material and/or particle activity after intercepting the powdered activated coke can be slowly discharged from the moving bed body 10 .

利用本发明提供的粉状活性焦移动床脱硫装置对气体进行粉状活性焦移动床脱硫处理,能够显著增加粉状活性焦在系统中的停留时间,从而能够更充分地利用粉状活性焦的硫容,提高脱硫效率。Using the powder activated coke moving bed desulfurization device provided by the present invention to carry out the powder activated coke moving bed desulfurization treatment on the gas can significantly increase the residence time of the powder activated coke in the system, so that the powder activated coke can be more fully utilized. Sulfur capacity, improve desulfurization efficiency.

除此之外,当填料填充段12填充有颗粒活性焦时,这些颗粒活性焦能够与粉状活性焦一起进行气体脱硫,能够进一步改善脱硫效率。且拦截脱硫后的粉状活性焦后,颗粒活性焦缓慢排出,出装量小、较慢的移动速度可以降低颗粒活性焦的磨损量,使之能够重复利用。In addition, when the filler filling section 12 is filled with granular activated coke, these granular activated cokes can perform gas desulfurization together with the powdered activated coke, which can further improve the desulfurization efficiency. And after intercepting the powdery activated coke after desulfurization, the granular activated coke is slowly discharged, the small output and the slow moving speed can reduce the wear amount of the granular activated coke, so that it can be reused.

在一种典型的实施例中,如图1所示,按照气体流动方向,气流进入段11包括靠近待脱硫气体进口设置的气流入口段111和与其相连并靠近填料填充段12设置的气流渐扩段112。这样,待脱硫气体进入气流入口段111和气流渐扩段112后逐渐扩散开来,与喷入的粉状活性焦更充分地接触。In a typical embodiment, as shown in FIG. 1 , according to the gas flow direction, the gas flow inlet section 11 includes a gas flow inlet section 111 arranged close to the inlet of the gas to be desulfurized and a gas flow expanding section connected to it and arranged near the filler filling section 12 paragraph 112. In this way, the to-be-desulfurized gas enters the gas flow inlet section 111 and the gas flow gradually expanding section 112 and gradually spreads out, so as to more fully contact the injected powdery activated coke.

在一种典型的实施例中,气流入口段111设置有至少一个粉状活性焦喷入口。这样,粉状活性焦能够第一时间与待脱硫气体接触,有助于进一步提高脱硫效率,并继续增加粉状活性焦在系统中的停留时间,充分利用其硫容。In a typical embodiment, the airflow inlet section 111 is provided with at least one powder activated coke spray inlet. In this way, the powdered activated coke can be contacted with the gas to be desulfurized for the first time, which helps to further improve the desulfurization efficiency, and continues to increase the residence time of the powdered activated coke in the system, making full use of its sulfur capacity.

在一种优选的实施例中,如图1所示,移动床脱硫单元1还包括粉状活性焦喷射装置20,粉状活性焦喷射装置20穿过移动床本体10的外壁延伸至气流渐扩段112内部,且粉状活性焦喷射装置20设置有多个粉状活性焦喷入口。这样可以将粉状活性焦更分散更均匀地喷入气流进入段11中与气体接触。In a preferred embodiment, as shown in FIG. 1 , the moving bed desulfurization unit 1 further includes a powdery active coke spray device 20 , and the powdery active coke spray device 20 extends through the outer wall of the moving bed body 10 to the point where the gas flow gradually expands. Inside the section 112, and the powdery active coke injection device 20 is provided with a plurality of powdery active coke injection ports. In this way, the powdered activated coke can be more dispersed and more uniformly sprayed into the airflow entry section 11 to contact with the gas.

在一种优选的实施例中,如图1所示,气流渐扩段112的底部还设置有粉状活性焦落料仓113,用于承接气流渐扩段112内部因重力落下的粉状活性焦。在粉状活性焦被喷入的过程中,难免有一小部分会因重力落下,利用粉状活性焦落料仓113可以将这部分粉状活性焦收集起来重复利用。In a preferred embodiment, as shown in FIG. 1 , the bottom of the airflow gradually expanding section 112 is further provided with a powdery activated coke dropping bin 113 for receiving the powdery active coke falling from the inside of the airflow gradually expanding section 112 due to gravity coke. During the process of being sprayed into the powdery activated coke, a small part of the powdery activated coke will inevitably fall down due to gravity, and the powdery activated coke dropping bin 113 can be used to collect this part of the powdery activated coke and reuse it.

在一种优选的实施例中,按照气体流动方向,气流排出段13包括靠近填料填充段12设置的气流渐缩段131和靠近脱硫气体出口设置的气流出口段132。这样,经填料填充段12分离出来的脱硫气体逐渐收缩并从移动床本体10中排出。In a preferred embodiment, according to the gas flow direction, the gas flow discharge section 13 includes a gas flow tapering section 131 disposed near the packing section 12 and a gas flow outlet section 132 disposed near the desulfurized gas outlet. In this way, the desulfurized gas separated by the packing section 12 is gradually contracted and discharged from the moving bed body 10 .

需要说明的是,本发明中的移动床本体10可以是多段式结构,比如可以由上至下分为多级脱硫单元,每一级脱硫单元均包括有气流进入段11、填料填充段12及气流排出段13结构,只需将多级填料填充段12相连设置即可。待脱硫气体可以从每一级气流进入段11中进入,并与喷入其中的粉状活性焦进行接触并脱硫。本发明图1中仅示出了一段式结构,多段式结构也应在本发明的范围之内,这是本领域技术人员都应理解的,在此不再赘述。It should be noted that the moving bed body 10 in the present invention can be a multi-stage structure, for example, it can be divided into multi-stage desulfurization units from top to bottom. As for the structure of the airflow discharge section 13, it is only necessary to connect the multi-stage filler filling sections 12 to each other. The gas to be desulfurized can enter from each stage gas flow entry section 11, and be contacted with the powdered activated coke injected into it and desulfurized. FIG. 1 of the present invention only shows a one-segment structure, and a multi-segment structure should also be within the scope of the present invention, which should be understood by those skilled in the art, and will not be repeated here.

在一种优选的实施例中,如图1所示,移动床脱硫单元1还包括:第一气流均布板14,设置在气流进入段11和填料填充段12之间;第二气流均布板15,设置在填料填充段12和气流排出段13之间。利用第一气流均布板14可以使气流进入段11中的气流更均匀地进入填料填充段12中进行气固分离,当使用颗粒活性焦作为床料时也可以增加气体与颗粒活性焦的接触面。利用第二气流均布板15可以更充分地将脱硫气体收集至气流排出段13中排出。In a preferred embodiment, as shown in FIG. 1 , the moving bed desulfurization unit 1 further includes: a first air distribution plate 14, which is arranged between the air inlet section 11 and the packing section 12; the second air distribution is uniform The plate 15 is arranged between the filler filling section 12 and the airflow discharge section 13 . The use of the first air distribution plate 14 can make the air flow entering the section 11 enter the packing section 12 more uniformly for gas-solid separation, and when using granular activated coke as bed material, the contact between the gas and granular activated coke can also be increased noodle. The desulfurized gas can be more fully collected into the gas flow discharge section 13 and discharged by using the second gas distribution plate 15 .

基于以上移动床本体10结构,粉状活性焦能够更充分地分布在气流进入段11中参与气体脱硫,图2示出了仿真计算得到的上述粉状活性焦移动床脱硫装置在实际脱硫工作中移动床内部的粉状活性焦的分布图,也可以证明这一点。Based on the structure of the moving bed body 10 above, the powdered activated coke can be more fully distributed in the gas flow inlet section 11 to participate in the gas desulfurization. Fig. 2 shows that the above-mentioned powdered activated coke moving bed desulfurization device obtained by simulation calculation moves during the actual desulfurization work. The distribution map of powdered active coke inside the bed can also prove this.

在一种实施例中,填料填充段12顶部设置有惰性床料和/或颗粒活性焦的入口,底部设置有惰性床料和/或颗粒活性焦的出口。随着气固分离的进行,混有粉状活性焦的床料缓慢移除,同时使新的床料不断进入,保证了脱硫处理和气固分离的持续进行。In one embodiment, the top of the packing section 12 is provided with an inlet for the inert bed material and/or granular activated coke, and the bottom is provided with an outlet for the inert bed material and/or granular activated coke. With the progress of gas-solid separation, the bed material mixed with powdered activated coke is slowly removed, and at the same time, new bed material is continuously entered, which ensures the continuous progress of desulfurization treatment and gas-solid separation.

在一种优选的实施例中,如图1所示,移动床脱硫单元1还包括:第一布水增湿单元16,设置在填料填充段12中靠近顶部的位置;第二布水增湿单元17,设置在气流入口段111中。这样可以通入工艺水D对待脱硫气体和床料进行增湿,由于高温烟气作用,工艺水D蒸发随达标后的烟气排出。具体地,第一布水增湿单元16是为了将粉状活性焦表面增湿,有利于烟气中SO2向覆盖在活性焦表面的液膜中渗透;第二布水增湿单元17是为了给待脱硫气体A增湿降温,使烟气温度达到最佳脱硫温度。In a preferred embodiment, as shown in FIG. 1 , the moving bed desulfurization unit 1 further includes: a first water distribution humidification unit 16 , which is arranged at a position close to the top of the packing section 12 ; a second water distribution humidification unit 16 ; The unit 17 is arranged in the airflow inlet section 111 . In this way, the process water D can be introduced to humidify the desulfurized gas and the bed material. Due to the effect of the high temperature flue gas, the process water D evaporates and is discharged with the flue gas after reaching the standard. Specifically, the first water distribution humidification unit 16 is to humidify the surface of the powdery active coke, which is beneficial to the penetration of SO 2 in the flue gas into the liquid film covering the surface of the active coke; the second water distribution humidification unit 17 is In order to humidify and cool down the gas A to be desulfurized, the temperature of the flue gas can reach the optimum desulfurization temperature.

为了对脱硫气体进行除尘处理,在一种优选的实施例中,如图1所示,移动床脱硫单元1还包括第一布袋除尘器18,第一布袋除尘器18的入口与脱硫气体出口相连,第一布袋除尘器18还具有第一气相出口和第一固相出口。经床料拦截后的气体中难免还携带有少量粉状活性焦,利用第一布袋除尘器18可以将这部分粉状活性焦分离出来,使分离后的净化气体B排放,收集到的粉状活性焦可以重复利用。In order to dedust the desulfurized gas, in a preferred embodiment, as shown in FIG. 1 , the moving bed desulfurization unit 1 further includes a first bag filter 18, and the inlet of the first bag filter 18 is connected to the desulfurization gas outlet , the first bag filter 18 also has a first gas phase outlet and a first solid phase outlet. A small amount of powdery active coke is inevitably carried in the gas intercepted by the bed material. The first bag filter 18 can be used to separate this part of the powdery active coke, so that the separated purified gas B is discharged, and the collected powdery active coke is discharged. Active coke can be reused.

在一种优选的实施例中,如图1所示,粉状活性焦移动床脱硫装置还包括分离单元2,分离单元2包括:分离床21,具有床料进口、流化气进口、流化气出口和床料出口,床料进口与填料填充段12的出口相连;第二布袋除尘器22,其进口与流化气出口相连,且第二布袋除尘器22还具有第二气相出口和第二固相出口,第二气相出口与流化气进口相连;床料储仓23,与床料出口相连。In a preferred embodiment, as shown in FIG. 1 , the powder activated coke moving bed desulfurization device further includes a separation unit 2, and the separation unit 2 includes: a separation bed 21, which has a bed material inlet, a fluidization gas inlet, a fluidization The gas outlet and the bed material outlet, the bed material inlet is connected with the outlet of the filler filling section 12; the second bag filter 22, its inlet is connected with the fluidizing gas outlet, and the second bag filter 22 also has a second gas phase outlet and a first Two solid phase outlets, the second gas phase outlet is connected with the fluidization gas inlet; the bed material storage bin 23 is connected with the bed material outlet.

在分离床21中,经过脱硫处理的粉状活性焦被流化气“吹”离床料并从流化气出口排出,进入第二布袋除尘器22进一步进行气固分离。床料则从床料出口排出并进入床料储仓23。在实际分离粉状活性焦时,也可以向流化气进口额外通入新鲜流化气C进行吹扫。In the separation bed 21, the desulfurized powdered activated coke is "blown" out of the bed material by the fluidizing gas and discharged from the fluidizing gas outlet, and enters the second bag filter 22 for further gas-solid separation. The bed material is discharged from the bed material outlet and enters the bed material storage bin 23 . When actually separating the powdered activated coke, it is also possible to additionally introduce fresh fluidizing gas C to the fluidizing gas inlet for purging.

在一种优选的实施例中,气流渐扩段112的底部还设置有粉状活性焦落料仓113,用于承接气流渐扩段112内部因重力落下的粉状活性焦;粉状活性焦落料仓113底部还设置有排料口,分离床21的床料进口还与排料口及第一布袋除尘器18的第一固相出口相连。这样可以利用分离床21一并处理粉状活性焦落料仓113和第一布袋除尘器18收集到的粉状活性焦。In a preferred embodiment, the bottom of the airflow gradually expanding section 112 is also provided with a powdery active coke dropping bin 113, which is used to receive the powdery active coke falling from the inside of the airflow gradually expanding section 112 due to gravity; The bottom of the blanking bin 113 is also provided with a discharge port, and the bed material inlet of the separation bed 21 is also connected to the discharge port and the first solid phase outlet of the first bag filter 18 . In this way, the powdery activated coke dropping bin 113 and the powdery activated coke collected by the first bag filter 18 can be processed together with the separation bed 21 .

在一种优选的实施例中,如图1所示,移动床脱硫单元1还包括至少一个粉状活性焦供应仓19,粉状活性焦供应仓19的出口与粉状活性焦喷入口相连,粉状活性焦供应仓19的入口与第二布袋除尘器22的第二固相出口相连。这样可以将第二布袋除尘器22分离后的粉状活性焦进一步返回至粉状活性焦供应仓19中,并进一步通过粉状活性焦喷入口喷入系统继续参与气体脱硫过程。In a preferred embodiment, as shown in FIG. 1, the moving bed desulfurization unit 1 further includes at least one powder activated coke supply bin 19, and the outlet of the powder activated coke supply bin 19 is connected to the powder activated coke spray inlet, The inlet of the powder activated coke supply bin 19 is connected with the second solid phase outlet of the second bag filter 22 . In this way, the powdery activated coke separated by the second bag filter 22 can be further returned to the powdery activated coke supply bin 19, and further injected into the system through the powdery activated coke injection port to continue to participate in the gas desulfurization process.

在一种优选的实施例中,移动床脱硫单元1还包括床料供应仓30,床料供应仓30的入口与床料储仓23的出口相连,床料供应仓30的出口与填料填充段12顶部的入口。这样可以将床料返回重复利用。In a preferred embodiment, the moving bed desulfurization unit 1 further includes a bed material supply bin 30, the inlet of the bed material supply bin 30 is connected to the outlet of the bed material storage bin 23, and the outlet of the bed material supply bin 30 is connected with the filler filling section 12 Entrance at the top. This allows the bed material to be returned for reuse.

在一种优选的实施例中,如图1所示,粉状活性焦移动床脱硫装置还包括粉状活性焦退出装置3,其与粉状活性焦供应仓19的入口和第二固相出口之间的管路相连。这样,当粉状活性焦硫容完全充满时可以利用粉状活性焦退出装置3将其输出系统,可以进入后续的再生等过程。具体地,上述粉状活性焦退出装置3包括粉状活性焦退出仓31,其进口与粉状活性焦供应仓19的入口和第二固相出口之间的管路相连。In a preferred embodiment, as shown in FIG. 1 , the powdered activated coke moving bed desulfurization device further includes a powdered activated coke withdrawal device 3 , which is connected to the inlet of the powdered activated coke supply bin 19 and the second solid phase outlet. pipes between them. In this way, when the powdered activated coke is completely filled with sulfur, the powdered activated coke can be output from the system by using the powdered activated coke exiting device 3, and can be used for subsequent regeneration and other processes. Specifically, the above-mentioned powdered activated coke withdrawal device 3 includes a powdered activated coke withdrawal bin 31, the inlet of which is connected to the pipeline between the inlet of the powdered activated coke supply bin 19 and the second solid phase outlet.

在一种优选的实施例中,分离单元2还包括循环风机24,其设置在第二气相出口与流化气进口相连的管路上。In a preferred embodiment, the separation unit 2 further includes a circulating fan 24, which is arranged on the pipeline connecting the second gas phase outlet with the fluidizing gas inlet.

本发明提供的装置中还设置有各种阀门,在一种实施例中,阀门包括:The device provided by the present invention is also provided with various valves. In one embodiment, the valves include:

第一阀门101,设置在床料供应仓30的出口与填料填充段12顶部入口相连的管路上;The first valve 101 is arranged on the pipeline connecting the outlet of the bed material supply bin 30 with the inlet of the top of the packing section 12;

第二阀门102,设置在工艺水D的供应管路上,该供应管路包括主供应管路和与第一布水增湿单元16相连的第一支管及与第二布水增湿单元17相连的第二支管;第三阀门103,设置在第一支管上;第四阀门104,设置在第二支管上;The second valve 102 is arranged on the supply pipeline of the process water D. The supply pipeline includes a main supply pipeline, a first branch pipe connected to the first water distribution and humidification unit 16 and connected to the second water distribution and humidification unit 17 the second branch pipe; the third valve 103 is arranged on the first branch pipe; the fourth valve 104 is arranged on the second branch pipe;

至少一个第五阀门105,一一对应设置在粉状活性焦供应仓19的供料管路上;第六阀门106,设置在粉状活性焦供应仓19的进口管路上;At least one fifth valve 105 is arranged on the feeding pipeline of the powdery active coke supply bin 19 in a one-to-one correspondence; the sixth valve 106 is arranged on the inlet pipeline of the powdery active coke supply bin 19;

第七阀门107,设置在第一固相出口所在的管路上;The seventh valve 107 is arranged on the pipeline where the first solid phase outlet is located;

第八阀门108,设置在填料填充段12底部的出口管路上;第九阀门109,设置在粉状活性焦落料仓113的排料口所在管路上;The eighth valve 108 is arranged on the outlet pipeline at the bottom of the filler filling section 12; the ninth valve 109 is arranged on the pipeline where the discharge port of the powder activated coke blanking bin 113 is located;

第十阀门201,设置在第二固相出口所在的管路上;The tenth valve 201 is arranged on the pipeline where the second solid phase outlet is located;

第十一阀门202,设置在床料储仓23的出料管路上;The eleventh valve 202 is arranged on the discharge pipeline of the bed material storage bin 23;

第十二阀门203,设置在新鲜流化气C的供应管路上;The twelfth valve 203 is arranged on the supply pipeline of the fresh fluidizing gas C;

第十三阀门301,设置在粉状活性焦退出仓31的进料管路上;第十四阀门302,设置在粉状活性焦退出仓31的出料管路上。The thirteenth valve 301 is arranged on the feeding pipeline of the powdery active coke exiting bin 31 ; the fourteenth valve 302 is arranged on the discharging pipeline of the powdery active coke exiting the bin 31 .

在具体操作过程中,可以采用以下工艺进行脱硫处理:In the specific operation process, the following processes can be used for desulfurization treatment:

移动床脱硫单元1中的体系温度小于等于150℃,阻力小于等于2000Pa;The temperature of the system in the moving bed desulfurization unit 1 is less than or equal to 150°C, and the resistance is less than or equal to 2000Pa;

惰性床料、颗粒活性焦的粒径大于等于1mm;The particle size of inert bed material and granular active coke is greater than or equal to 1mm;

填料填充段12内床料温度小于等于100℃;The temperature of the bed material in the packing section 12 is less than or equal to 100°C;

填料填充段12内床料向下移动速度小于等于1.0m/s;The downward moving speed of the bed material in the packing section 12 is less than or equal to 1.0m/s;

填料填充段12采用一段或多段装置(图1中显示的是1段);The filler filling section 12 adopts a one-stage or multi-stage device (shown in FIG. 1 is 1 stage);

总之,利用本发明提供的装置进行粉状活性焦移动床脱硫处理,具有以下优点:In a word, using the device provided by the present invention to carry out powdery active coke moving bed desulfurization treatment has the following advantages:

1)本发明利用大粒径惰性床料或颗粒活性焦同时实现了粉状活性焦与烟气的分离、烟气中SO2的去除。1) The present invention utilizes large particle size inert bed material or granular activated coke to simultaneously realize the separation of powdery activated coke and flue gas, and the removal of SO 2 in flue gas.

2)优选地,本发明在不同位置设有粉状活性焦喷入点,保证粉状活性焦与烟气的充分均匀混合,保证脱硫效率。2) Preferably, the present invention is provided with powder activated coke injection points at different positions to ensure sufficient and uniform mixing of powder activated coke and flue gas, and to ensure desulfurization efficiency.

3)优选地,本发明移动床内设置颗粒活性焦,可与粉状活性焦同时对烟气中SO2进行去除,系统颗粒活性焦出装量小、较慢的移动速度可降低磨损量。3) Preferably, granular activated coke is arranged in the moving bed of the present invention, which can remove SO 2 in the flue gas simultaneously with the powder activated coke. The system has a small output of granular activated coke and a slow moving speed can reduce the amount of wear.

4)本发明增加了粉状活性焦在系统内的停留时间,充分利用粉状活性焦的硫容。4) The present invention increases the residence time of the powdery active coke in the system, and makes full use of the sulfur content of the powdery active coke.

5)本发明粉状活性焦脱硫装置可进行模块化设计。5) The powder activated coke desulfurization device of the present invention can be modularized.

以上所述仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and changes. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention shall be included within the protection scope of the present invention.

Claims (16)

1. a kind of powdered activated coke moving bed desulfurizer, which is characterized in that including moving bed desulfurization unit (1), the movement Bed desulfurization unit (1) include:
Moving bed ontology (10), the moving bed ontology (10) have cavity, be additionally provided on the moving bed ontology (10) to Processed gas import and the desulfurized gas outlet being oppositely arranged with the gas feed to be desulfurization, according to gas flow direction, institute It states cavity and is successively divided into air-flow approach section (11), filler filled section (12) and air-flow discharge section (13), the air-flow enters Section (11) is provided with the gas feed to be desulfurization and powdered activated coke entrance, and the desulfurized gas outlet is arranged in the gas Section (13) are discharged in stream, burnt filled with inert bed material and/or seed activity in the filler filled section (12), and the inert bed material And the partial size of the seed activity coke is all larger than powdered activated coke.
2. powdered activated coke moving bed desulfurizer according to claim 1, which is characterized in that according to gas flowing side To, the air-flow approach section (11) include close to the gas feed setting to be desulfurization air flow inlet section (111) and with its phase Even and close to the air-flow divergent segment (112) of the filler filled section (12) setting.
3. powdered activated coke moving bed desulfurizer according to claim 2, which is characterized in that the air flow inlet section (111) it is provided at least one described powdered activated coke entrance.
4. powdered activated coke moving bed desulfurizer according to claim 2, which is characterized in that the moving bed desulfurization list First (1) further includes powdered activated coke injection apparatus (20), and the powdered activated coke injection apparatus (20) passes through the moving bed sheet It is internal that the outer wall of body (10) extends to the air-flow divergent segment (112), and the powdered activated coke injection apparatus (20) is provided with Multiple powdered activated coke entrances.
5. powdered activated coke moving bed desulfurizer according to claim 4, which is characterized in that the air-flow divergent segment (112) bottom is additionally provided with powdered activated coke blanking storehouse (113), internal because of weight for accepting the air-flow divergent segment (112) The powdered activated coke that power is fallen.
6. powdered activated coke moving bed desulfurizer according to claim 2, which is characterized in that according to gas flowing side To air-flow discharge section (13) includes close to the air-flow converging transition (131) of the filler filled section (12) setting and close to institute State the air stream outlet section (132) of desulfurized gas outlet setting.
7. powdered activated coke moving bed desulfurizer according to any one of claim 1 to 6, which is characterized in that described Moving bed desulfurization unit (1) further include:
First airflow uniform distribution plate (14) is arranged between the air-flow approach section (11) and the filler filled section (12);
Second airflow uniform distribution plate (15), setting is between the filler filled section (12) and air-flow discharge section (13).
8. the powdered activated coke moving bed desulfurizer according to any one of claim 2 to 6, which is characterized in that described The entrance of the inert bed material and/or seed activity coke is provided at the top of filler filled section (12), bottom is provided with described The outlet of inert bed material and/or seed activity coke.
9. powdered activated coke moving bed desulfurizer according to claim 8, which is characterized in that the moving bed desulfurization list First (1) further include:
First water distribution humidification unit (16) is arranged in the filler filled section (12) close to the position at top;
Second water distribution humidification unit (17) is arranged in the air flow inlet section (111).
10. powdered activated coke moving bed desulfurizer according to claim 8, which is characterized in that the moving bed desulfurization Unit (1) further includes the first bag filter (18), and the entrance of first bag filter (18) goes out with the processed gas Mouth is connected, and first bag filter (18) also has the first gaseous phase outlet and the first solid-phase outlet.
11. powdered activated coke moving bed desulfurizer according to claim 10, which is characterized in that the powdered activated coke Moving bed desulfurizer further includes separative unit (2), and the separative unit (2) includes:
Separation bed (21) has bed material import, inlet for fluidization air, fluidized gas outlet and bed material outlet, the bed material import and institute The outlet for stating filler filled section (12) is connected;
Second bag filter (22), import are connected with fluidized gas outlet, and second bag filter (22) is also It is exported with the second gaseous phase outlet and second solid phase, second gaseous phase outlet is connected with the inlet for fluidization air;
Bed material warehouse (23) is connected with bed material outlet.
12. powdered activated coke moving bed desulfurizer according to claim 11, which is characterized in that the air-flow divergent segment (112) bottom is additionally provided with powdered activated coke blanking storehouse (113), internal because of weight for accepting the air-flow divergent segment (112) The powdered activated coke that power is fallen;Powdered activated coke blanking storehouse (113) bottom is additionally provided with discharge gate, the separation bed (21) The bed material import be also connected with first solid-phase outlet of the discharge gate and first bag filter (18).
13. powdered activated coke moving bed desulfurizer according to claim 11, which is characterized in that the moving bed desulfurization Unit (1) further includes at least one powdered activated coke supply storehouse (19), the outlet of powdered activated coke supply storehouse (19) and institute It states powdered activated coke entrance to be connected, the entrance of powdered activated coke supply storehouse (19) and second bag filter (22) The second solid phase outlet be connected.
14. powdered activated coke moving bed desulfurizer according to claim 11, which is characterized in that the moving bed desulfurization Unit (1) further includes bed material supply storehouse (30), the entrance of bed material supply storehouse (30) and the outlet of the bed material warehouse (23) It is connected, the outlet of bed material supply storehouse (30) and the entrance at the top of the filler filled section (12).
15. powdered activated coke moving bed desulfurizer according to claim 13, which is characterized in that the powdered activated coke Moving bed desulfurizer further includes powdered activated coke extractor (3), the entrance with powdered activated coke supply storehouse (19) Pipeline between the second solid phase outlet is connected.
16. powdered activated coke moving bed desulfurizer according to claim 11, which is characterized in that the separative unit (2) further include circulating fan (24), be arranged on the pipeline that second gaseous phase outlet is connected with the inlet for fluidization air.
CN201910373226.9A 2019-05-06 2019-05-06 Powder active coke moving bed desulfurizing device Active CN110038391B (en)

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