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CN110028706A - A kind of rubber and its manufacturing method with infrared energy reflection - Google Patents

A kind of rubber and its manufacturing method with infrared energy reflection Download PDF

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Publication number
CN110028706A
CN110028706A CN201910281468.5A CN201910281468A CN110028706A CN 110028706 A CN110028706 A CN 110028706A CN 201910281468 A CN201910281468 A CN 201910281468A CN 110028706 A CN110028706 A CN 110028706A
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CN
China
Prior art keywords
rubber
infrared
energy reflection
infrared energy
powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910281468.5A
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Chinese (zh)
Inventor
叶逸仁
胡晓东
邓杰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenzhen Yuan Fang Science And Technology New Material Co Ltd
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Shenzhen Yuan Fang Science And Technology New Material Co Ltd
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Priority to CN201910281468.5A priority Critical patent/CN110028706A/en
Publication of CN110028706A publication Critical patent/CN110028706A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Radiation-Therapy Devices (AREA)

Abstract

The present invention relates to a kind of rubber with infrared energy reflection, it is made of function powder and rubber raw materials mixing, function powder includes a variety of inorganic oxide powders, the component ratio of inorganic oxide powder are as follows: titanium dioxide 10-40%, infrared ray powder 20-50%, activated zinc oxide 5-10%, aluminium oxide 5-10%, iron oxide 5-20%, carbon black 10-20%, silica 5-10%, graphite 5-10%, rubber made of the present invention has effects that infrared energy reflection, its infrared ray reflected can act directly on human body, it is used for curable product, clothing, the articles for daily use such as mattress or cushion, since IR wavelength is longer, fuel factor can be generated, with excellent thermal effect, long-time service can also promote body metabolism, improve cell viability and Regenerated energy Power enhances human body constitution;And can be applied to physics catalysis use, so that the refinement of the substances such as fuel oil, combustion gas, air is improved activity.

Description

A kind of rubber and its manufacturing method with infrared energy reflection
Technical field
The present invention relates to rubber production preparation field, espespecially a kind of rubber and its manufacturer with infrared energy reflection Method.
Background technique
Infrared ray (Infrared) is electromagnetic wave of the wavelength between microwave and visible light, and wavelength is at 760 nanometers (nm) To between 1mm, the non-visible light longer than feux rouges.
After infrared radiation body surface, a part is reflected, and another part is absorbed by the skin.Reflection journey of the skin to infrared ray Spend it is related with pigmented situation, when with 0.9 micron of wavelength of infrared radiation, its energy of non-pigmented skin reflex About 60%;And there is pigmented skin reflex its energy about 40%.When (1.5 microns of wavelength or more) irradiations of long-wave infrared, absolutely Major part is reflected and is that shallow-layer skin histology absorbs, and only up to 0.05 ~ 2 millimeter of depth of skin is penetrated, thus can only be applied to The textura epidermoidea of skin;The near infrared ray part of short infrared (within 1.5 microns of wavelength) and red light penetrates tissue most Deep, penetration depth can be applied directly to blood vessel, lymphatic vessel, nerve endings and the other subcutaneous tissues of skin up to 10 millimeters.
In infrared spectral range, to human body, most beneficial wave band is exactly 4 to 14 microns of this wavelength bands, this infrared ray Wave band plays the role of promotion to the growth of life, and to activating cell tissue, blood circulation has good effect, can be improved people's Immunity reinforces the metabolism of human body.
Rubber is widely used, and be can be used as raw material and is woven into staple fibre, and then clothing is made, in addition it can conduct The raw material of the articles for daily use such as curable product or mattress, cushion, Lumbar.Existing clothing, can be in clothing in order to enhance warming effect Interior addition animal down, but it is expensive and more thick and heavy, it has not been convenient to it washs.And some curable products can coat on surface Infrared-reflecting layers carry out medical recovery to patient using infrared ray, but this curable product infrared ray after prolonged use Reflecting effect can fade, and service life is short.
Summary of the invention
To solve the above problems, the present invention provides a kind of rubber and its manufacturing method with infrared energy reflection.
To achieve the above object, the present invention, which adopts the following technical scheme that, is: a kind of rubber with infrared energy reflection Glue is made of function powder and rubber raw materials mixing, and the function powder is a variety of inorganic oxide powder/particle mixtures, the nothing The component ratio of machine oxide powder are as follows: titanium dioxide 10-40%, infrared ray powder 20-50%, activated zinc oxide 5-10%, aluminium oxide 5-10%, iron oxide 5-20%, carbon black 10-20%, silica 5-10%, graphite 5-10%.
Preferably, the rubber raw materials are natural rubber or artificial rubber.
A kind of manufacturing method of the rubber with infrared energy reflection, includes the following steps:
Step 1: Step 1: selecting titanium dioxide, infrared ray powder, activated zinc oxide, aluminium oxide, iron oxide, carbon black, titanium dioxide Silicon, graphite, are mixed to form function powder;
Step 2: function powder and rubber raw materials are put into togerther in mixing facilities, it is uniformly mixed;
Step 3: Cure of Rubber agent is added in the mixture of step 3, high temperature and pressure curing process is carried out.
Preferably, the Cure of Rubber agent is vulcanizing agent.
A kind of application of the rubber with infrared energy reflection, is applied in health care, medical, industrial, clothes, physics catalysis Device or furniture (such as desk, chair) field.
The utility model has the advantages that infrared ray can change wavelength length because of temperature height and reflectivity is strong and weak, in a variety of different materials Under the background of mixture, infrared ray can in response to temperature variation and have a certain range of reflectivity stability or strengthen property. The beneficial effects of the present invention are: the present invention selects titanium dioxide, infrared ray powder, activated zinc oxide, aluminium oxide, iron oxide, carbon The inorganic oxides powder such as black, silica, graphite is mixed to form function powder, stablizes and strengthen the rubber by the function powder The infrared energy of reflectivity (between 0.40~0.99), infrared reflection effect is unattenuated after long-time service, and what is distributed is red Outside line can act directly on human body, the articles for daily use such as curable product, clothing, mattress or cushion are used for, due to infrared Line wavelength is longer, can generate fuel factor, has excellent thermal effect, and long-time service can also promote body metabolism, improves thin Born of the same parents' vigor and power of regeneration enhance human body constitution.
Detailed description of the invention
Fig. 1 is infrared reflectivity experimental data table possessed by function powder of the present invention.
Specific embodiment
The present invention is made about a kind of rubber with infrared energy reflection of function powder and rubber raw materials mixing, The function powder is a variety of inorganic oxide powder/particle mixtures, the component ratio of the function powder are as follows: titanium dioxide 10- 40%, infrared ray powder 20-50%, activated zinc oxide 5-10%, aluminium oxide 5-10%, iron oxide 5-20%, carbon black 10-20%, titanium dioxide Silicon 5-10%, graphite 5-10%.
Preferably, the rubber raw materials are natural rubber or artificial rubber.
A kind of manufacturing method of the rubber with infrared energy reflection, includes the following steps:
Step 1: Step 1: selecting titanium dioxide, infrared ray powder, activated zinc oxide, aluminium oxide, iron oxide, carbon black, titanium dioxide Silicon, graphite, are mixed to form function powder;
Step 2: the function powder of 5-65% weight ratio and rubber raw materials are put into togerther in mixing facilities, it is uniformly mixed;
Step 3: Cure of Rubber agent is added in the mixture of step 3, high temperature and pressure curing process is carried out.
Preferably, the Cure of Rubber agent is vulcanizing agent.
It is a kind of with infrared energy reflection rubber application, apply health care, medical, clothes, physics catalyst converter or The fields such as furniture.
Embodiment one:
A kind of rubber with infrared energy reflection is made, wherein the function powder of function powder and rubber raw materials mixing The component ratio of body are as follows: 30% titanium dioxide, 40% infrared ray powder, 5% activated zinc oxide, 5% aluminium oxide, 5% iron oxide, 5% carbon black, 5% silica, 5% graphite.Rubber produced by the present invention with infrared energy reflection, is made rubber using the rubber raw materials Piece measures laboratory test through infrared ray, under the test environment conditions that temperature is 20 degree Celsius and humidity is 60%, according to The specification of ASTM-E 1933 tests the sheet rubber with the measuring instrument of FLIR-SC2000, obtains as shown in Figure 1 Test result, show that the sheet rubber its infrared ray under low-temperature condition is released is to the infrared reflectivity of 1 mum wavelength 63.125%, the infrared reflectivity of 8 ~ 14 mum wavelengths is 64.125%, after hundreds of secondary uses, is detected the silica gel piece infrared external reflection Rate does not decay.
Embodiment two:
A kind of rubber with infrared energy reflection is made, wherein the function powder of function powder and rubber raw materials mixing The component ratio of body are as follows: 10% titanium dioxide, 30% infrared ray powder, 9% activated zinc oxide, 9% aluminium oxide, 15% iron oxide, 9% carbon Black, 9% silica, 9% graphite.Rubber produced by the present invention with infrared energy reflection, is made of the rubber raw materials Sheet rubber measures laboratory test through infrared ray, under the test environment conditions that temperature is 20 degree Celsius and humidity is 60%, root The sheet rubber is tested with the measuring instrument of FLIR-SC2000 according to the specification of ASTM-E 1933, is obtained as shown in Figure 1 Test result, show that the sheet rubber its infrared ray under low-temperature condition is released is to the infrared reflectivity of 1 mum wavelength 66.875%, the infrared reflectivity of 8 ~ 14 mum wavelengths is 68.675%, after hundreds of secondary uses, is detected the silica gel piece infrared external reflection Rate does not decay.
Embodiment three:
A kind of rubber with infrared energy reflection is made, wherein the function powder of function powder and rubber raw materials mixing The component ratio of body are as follows: 16% titanium dioxide, 37% infrared ray powder, 7% activated zinc oxide, 6% aluminium oxide, 11% iron oxide, 6% carbon Black, 8% silica, 9% graphite.Rubber produced by the present invention with infrared energy reflection, is made of the rubber raw materials Sheet rubber measures laboratory test through infrared ray, under the test environment conditions that temperature is 20 degree Celsius and humidity is 60%, root The sheet rubber is tested with the measuring instrument of FLIR-SC2000 according to the specification of ASTM-E 1933, is obtained as shown in Figure 1 Test result, show that the sheet rubber its infrared ray under low-temperature condition releases the infrared reflectivity of 1 mum wavelength and is 66.125%, the infrared reflectivity of 8 ~ 14 mum wavelengths is 67.325%, after hundreds of secondary uses, is detected the silica gel piece infrared external reflection Rate does not decay.
Human body still includes macroelement and microelement two major classes mainly in addition to being made of water and protein etc., In all element for accounting for human total weight's a ten thousandth or more, such as carbon, hydrogen, oxygen, nitrogen, calcium, phosphorus, magnesium, sodium etc. be known as constant member Element, and human total weight's a ten thousandth element below is accounted for, such as iron, zinc, copper, manganese, chromium, selenium, molybdenum, cobalt, fluorine etc. are referred to as micro Element;Microelement is very little in the intracorporal content of people, as zinc only account for human total weight 33/1000000ths, iron also only Have 60/1000000ths, although and microelement is few in the intracorporal content of people, play important role, they mostly with Complex form is present among human body, transmits various substances necessary to life, to adjust the metabolism of human body;It is micro Element deposits each position in human body, maintains the health of entire body with oneself distinctive effect, allows each device of body Official can normally operate;In addition, the infrared energy that the intracorporal microelement of people can issue 5~30 microns (it is excellent to position wavelength It is selected as 9.36 microns), according to physics theory, human body can largely absorb 5~30 microns of infrared ray, using function powder of the present invention Made rubber has the function of infrared reflection, using rubber made of the present invention as raw material, produces and processes as curable product, clothing Object, mattress or other articles for daily use, can worn for long periods or use, generated infrared ray can act directly on human body, Energy is absorbed by biological cell, is caused sympathetic response, resonance, is increased the vibration of intramolecular, and then is activated histocyte, promoted Blood circulation, and the infrared ray that ought be released can be absorbed into depths under skin, keep intracellular water subactivity more active, into And promote capillary expansion, with reach promote blood circulation and metabolism function and effect, make subcutaneous deep skin Temperature rises, and expands capilary, promotes blood circulation, and strengthens blood and cell tissue metabolism, excludes the tired object accumulated in vivo The agings waste such as matter and lactic acid has warming and improvement constitution effect.
It can be applied to physics catalysis use, so that the refinement of the substances such as fuel oil, combustion gas, air is improved activity and improve combustion rate, Reduce exhaust gas discharge capacity.
Embodiment of above be only preferred embodiments of the present invention will be described, not to the scope of the present invention into Row limits, and without departing from the spirit of the design of the present invention, this field ordinary engineering and technical personnel is to technical side of the invention The various changes and improvements that case is made, should fall within the scope of protection determined by the claims of the present invention.

Claims (6)

1. a kind of rubber with infrared energy reflection, it is characterised in that: the rubber is by 5-65% function powder and surplus rubber The mixing of collagen material is made, the component ratio of the function powder are as follows: titanium dioxide 10-40%, infrared ray powder 20-50%, active oxygen Change zinc 5-10%, aluminium oxide 5-10%, iron oxide 5-20%, carbon black 10-20%, silica 5-10%, graphite 5-10%.
2. a kind of rubber with infrared energy reflection according to claim 1, it is characterised in that: the rubber raw materials For natural rubber.
3. a kind of rubber with infrared energy reflection according to claim 1, it is characterised in that: the rubber raw materials For artificial rubber.
4. a kind of manufacturing method of the rubber with infrared energy reflection, includes the following steps:
Step 1: titanium dioxide, infrared ray powder, activated zinc oxide, aluminium oxide, iron oxide, carbon black, silica, graphite are selected, It is mixed to form function powder;
Step 2: function powder and rubber raw materials are put into togerther in mixing facilities, it is uniformly mixed;
Step 3: Cure of Rubber agent is added in the mixture of step 3, high temperature and pressure curing process is carried out.
5. a kind of manufacturing method of rubber with infrared energy reflection according to claim 4, it is characterised in that: institute Stating Cure of Rubber agent is vulcanizing agent.
6. a kind of rubber according to claim 1 with infrared energy reflection, it is characterised in that: the rubber applications In health care, medical, industrial, clothes, physics catalyst converter or field of furniture.
CN201910281468.5A 2019-04-09 2019-04-09 A kind of rubber and its manufacturing method with infrared energy reflection Pending CN110028706A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111073263A (en) * 2019-12-26 2020-04-28 南通纳科达聚氨酯科技有限公司 Infrared reflection TPU (thermoplastic polyurethane) automobile paint protective film

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0364316B2 (en) * 1987-09-25 1991-10-04 Nissha Printing
JP2010150780A (en) * 2008-12-24 2010-07-08 Nitto Kako Kk Heat shield rubber mat
CN102473824A (en) * 2009-06-26 2012-05-23 株式会社朝日橡胶 White color reflecting material and process for production thereof
CN106366461A (en) * 2016-08-30 2017-02-01 广东丰能科技有限公司 Light reflecting and heat insulating rubber granules

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0364316B2 (en) * 1987-09-25 1991-10-04 Nissha Printing
JP2010150780A (en) * 2008-12-24 2010-07-08 Nitto Kako Kk Heat shield rubber mat
CN102473824A (en) * 2009-06-26 2012-05-23 株式会社朝日橡胶 White color reflecting material and process for production thereof
CN106366461A (en) * 2016-08-30 2017-02-01 广东丰能科技有限公司 Light reflecting and heat insulating rubber granules

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
裘炳毅: "《化妆品化学与工艺技术大全(上册)》", 30 January 2000, 中国轻工业出版社 *
韩欣: "《走进科学》", 30 June 2006, 内蒙古人民出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111073263A (en) * 2019-12-26 2020-04-28 南通纳科达聚氨酯科技有限公司 Infrared reflection TPU (thermoplastic polyurethane) automobile paint protective film

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Inventor after: Hu Xiaodong

Inventor after: Ye Yiren

Inventor after: Deng Jie

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Inventor before: Hu Xiaodong

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Application publication date: 20190719

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