CN110006845B - A liquid refractive index measuring instrument based on electrowetting lens - Google Patents
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Abstract
本发明提出了一种基于电润湿透镜的液体折射率测量仪,它由硬质腔体、光源、准直透镜、液体测量腔体、进水口、出水口、电润湿透镜和图像传感器组成。在初始状态时,液体测量腔体中没有液体,光源经过准直透镜后形成平行光束,调节电润湿透镜外部驱动电压,光斑在图像传感器平面聚焦。加入待测液体后,光路发生变化,光斑无法在原图像传感器平面聚焦,再次调节电润湿透镜外部驱动电压,让光斑重新在图像传感器平面上聚焦。根据各元件的位置和几何光学公式可计算出待测液体的折射率。
The invention proposes a liquid refractive index measuring instrument based on an electrowetting lens, which consists of a hard cavity, a light source, a collimating lens, a liquid measuring cavity, a water inlet, a water outlet, an electrowetting lens and an image sensor . In the initial state, there is no liquid in the liquid measurement cavity, the light source forms a parallel beam after passing through the collimating lens, and the external driving voltage of the electrowetting lens is adjusted, and the light spot is focused on the image sensor plane. After adding the liquid to be tested, the optical path changes, and the light spot cannot be focused on the original image sensor plane. Adjust the external driving voltage of the electrowetting lens again to make the light spot focus on the image sensor plane again. The refractive index of the liquid to be measured can be calculated according to the position of each element and the geometrical optics formula.
Description
一、技术领域1. Technical field
本发明涉及一种液体折射率测量仪,更具体地说,本发明涉及一种基于电润湿透镜的液体折射率测量仪。The present invention relates to a liquid refractive index measuring instrument, more particularly, the present invention relates to a liquid refractive index measuring instrument based on electrowetting lenses.
二、背景技术2. Background technology
折射率是液体材料的一个重要的光学参数,对液体折射率的准确测量在化工、医药、食品、石化等工业领域都有重要的意义。液体折射测量方法从机理上大概可以分为几何光学测量法和波动光学测量法两种。几何光学测量法是利用光通过液体表面所产生的折射或反射现象,根据折射定律或反射定律进行折射率的测量,这种测量方法较为简单。基于几何光学方法的测量仪器最常见的就是阿贝折射仪,其测量所需液体量非常少,操作简单,精度高,可以直接从刻度盘上读取折射率的值。但是,阿贝折射仪是根据全反射原理来测量的,其所用棱镜的折射率限制了所能测量的范围。波动测量法则是利用光的波动性质与测量液体发生干涉或者衍射进而测量其折射率。基于波动测量法的测量仪器一般较为复杂且操作相对繁琐,对测量液体的使用量要求较多,不适用于稀有金贵液体折射率的测量,此外,该方法易受外界因素的影响,在工业生产中不易实现在线检测,实际工程应用受限。因此就亟待研制一种低成本、操作简单、测量精确和测量范围广的液体折射率测量仪。The refractive index is an important optical parameter of liquid materials, and the accurate measurement of the refractive index of liquids is of great significance in chemical, pharmaceutical, food, petrochemical and other industrial fields. The measurement methods of liquid refraction can be roughly divided into two types: geometrical optics measurement and wave optics measurement. The geometrical optics measurement method is to measure the refractive index according to the law of refraction or the law of reflection by using the phenomenon of refraction or reflection produced by light passing through the liquid surface. This measurement method is relatively simple. The most common measurement instrument based on the geometrical optics method is the Abbe refractometer, which requires a very small amount of liquid to measure, is simple to operate, and has high precision, and the value of the refractive index can be read directly from the dial. However, Abbe refractometers measure according to the principle of total reflection, and the refractive index of the prism used limits the range that can be measured. The wave measurement method is to use the wave nature of light to interfere or diffract the measuring liquid to measure its refractive index. The measurement instruments based on the wave measurement method are generally more complicated and the operation is relatively cumbersome, and the usage of the measurement liquid is more demanding, and it is not suitable for the measurement of the refractive index of rare gold and precious liquids. It is not easy to realize online detection, and the practical engineering application is limited. Therefore, it is urgent to develop a liquid refractive index measuring instrument with low cost, simple operation, accurate measurement and wide measurement range.
三、发明内容3. Content of the Invention
本发明提出一种基于电润湿透镜的液体折射率测量仪。The invention provides a liquid refractive index measuring instrument based on an electrowetting lens.
如附图1所示,该液体折射率测量仪由硬质腔体、光源、准直透镜、液体测量腔体、进水口、出水口、电润湿透镜和图像传感器组成。其中,液体测量腔体由两片光学透镜封装组成。进水口和出水口对称分布在液体测量腔体上,且进水口与出水口直径相同。准直透镜、液体测量腔体和电润湿透镜的几何中心位于同一直线上。As shown in FIG. 1 , the liquid refractive index measuring instrument consists of a hard cavity, a light source, a collimating lens, a liquid measuring cavity, a water inlet, a water outlet, an electrowetting lens and an image sensor. Among them, the liquid measurement cavity is composed of two optical lens packages. The water inlet and outlet are symmetrically distributed on the liquid measuring cavity, and the diameter of the water inlet and the water outlet are the same. The geometric centers of the collimating lens, the liquid measuring cavity and the electrowetting lens are on the same line.
基于电润湿透镜的液体折射率测量仪的测量原理如附图1和附图2所示,在初始状态时,液体测量腔体中没有液体,光源经过准直透镜后形成平行光束,通过液体测量腔体,再调节电润湿透镜外部驱动电压,让光斑在图像传感器平面聚焦。加入待测液体后,光路会发生变化,此时,光斑无法在原图像传感器平面聚焦,此时需调节电润湿透镜外部驱动电压,让光斑重新在图像传感器平面上聚焦,如附图2所示。本发明中,组成液体测量腔体的两片光学透镜之间距离为t,折射率分别为n1和n2,曲率半径分别为C1和C2;电润湿透镜两种填充液体折射率分别为n3和n4,液-液接触面曲率半径为C3;液体测量腔体中心和电润湿透镜中心之间的距离为d,整个测量系统后焦距为B。根据几何光学可推导出液体测量腔体光焦度和电润湿透镜光焦度分别为:The measurement principle of the liquid refractive index measuring instrument based on the electrowetting lens is shown in Figures 1 and 2. In the initial state, there is no liquid in the liquid measurement cavity, and the light source forms a parallel beam after passing through the collimating lens, passing through the liquid. Measure the cavity, and then adjust the external driving voltage of the electrowetting lens to focus the light spot on the image sensor plane. After adding the liquid to be tested, the optical path will change. At this time, the light spot cannot be focused on the original image sensor plane. At this time, it is necessary to adjust the external driving voltage of the electrowetting lens to make the light spot focus on the image sensor plane again, as shown in Figure 2. . In the present invention, the distance between the two optical lenses constituting the liquid measuring cavity is t, the refractive indices are n 1 and n 2 respectively, and the curvature radii are C 1 and C 2 respectively; are n 3 and n 4 respectively, the radius of curvature of the liquid-liquid contact surface is C 3 ; the distance between the center of the liquid measuring cavity and the center of the electrowetting lens is d, and the back focal length of the entire measuring system is B. The optical power of the liquid measurement cavity can be derived from geometric optics and electrowetting lens power They are:
整个测量系统后焦距为B可表示为:The back focal length of the entire measurement system is B can be expressed as:
综上几式可知待测液体折射率nx为t、d、B、n1、n2、n3和n4的函数,即:From the above formulas, it can be known that the refractive index n x of the liquid to be measured is a function of t, d, B, n 1 , n 2 , n 3 and n 4 , namely:
nx=f(t,d,B,n1,n2,n3,n4,C1,C2,C3) (4)n x = f(t,d,B,n 1 ,n 2 ,n 3 ,n 4 ,C 1 ,C 2 ,C 3 ) (4)
其中,C1、C2、n1、n2、n3和n4为已知量;t、d、B可直接测量;C3可根据电润湿透镜曲率和驱动电压测量得到。通过以上公式,可计算出待测液体的折射率。Among them, C 1 , C 2 , n 1 , n 2 , n 3 and n 4 are known quantities; t, d, and B can be measured directly; C 3 can be measured according to the curvature of the electrowetting lens and the driving voltage. Through the above formula, the refractive index of the liquid to be measured can be calculated.
在附图1中所示的液体测量腔体由两片平凸透镜组成,应该注意的是该图仅是示意性的,可根据设计需要由平凹透镜组成或平行板构成,此内容仍属于本发明的保护范围。The liquid measurement chamber shown in FIG. 1 is composed of two plano-convex lenses. It should be noted that this figure is only schematic, and can be composed of plano-concave lenses or parallel plates according to design requirements, and this content still belongs to the present invention. protected range.
优选地,组成液体测量腔体的两片光学透镜为曲率半径和材料完全相同。Preferably, the two optical lenses composing the liquid measuring cavity have the same radius of curvature and the same material.
优选地,无待测液体时,液体测量腔体填充介质为空气,折射率n0=1.000。Preferably, when there is no liquid to be measured, the liquid measuring cavity is filled with air, and the refractive index n 0 =1.000.
优选地,进水口和出水口的直径R1小于液体测量腔体的两片光学透镜之间距离t。Preferably, the diameter R 1 of the water inlet and the water outlet is smaller than the distance t between the two optical lenses of the liquid measuring cavity.
优选地,光源、准直透镜、液体测量腔体、电润湿透镜和图像传感器的光学中心均位于同一条直线上。Preferably, the optical centers of the light source, the collimating lens, the liquid measuring cavity, the electrowetting lens and the image sensor are all located on the same straight line.
四、附图说明4. Description of drawings
附图1为基于电润湿透镜的液体折射率测量仪无测量液体时的侧视图。FIG. 1 is a side view of the electrowetting lens-based liquid refractometer without measuring liquid.
附图2为基于电润湿透镜的液体折射率测量仪填充测量液体后的侧视图。FIG. 2 is a side view of the electrowetting lens-based liquid refractometer after filling with measuring liquid.
附图3为基于电润湿透镜的液体折射率测量仪的一种实施例光学仿真模拟图。FIG. 3 is an optical simulation simulation diagram of an embodiment of a liquid refractive index measuring instrument based on an electrowetting lens.
附图4为基于电润湿透镜的液体折射率测量仪的一种实施例中电润湿透镜驱动电压和焦距变化示意图。FIG. 4 is a schematic diagram illustrating the variation of the driving voltage and the focal length of the electrowetting lens in an embodiment of the liquid refractive index measuring instrument based on the electrowetting lens.
上述各附图中的图示标号为:The symbols in the above figures are:
1硬质腔体,2光源,3准直透镜,4液体测量腔体,5进水口,6出水口,7电润湿透镜,8图像传感器。1 hard cavity, 2 light source, 3 collimating lens, 4 liquid measuring cavity, 5 water inlet, 6 water outlet, 7 electrowetting lens, 8 image sensor.
应该理解上述附图只是示意性的,并没有按比例绘制。It should be understood that the above drawings are schematic only and are not drawn to scale.
五、具体实施方式Five, the specific implementation
下面详细说明本发明提出的一种基于电润湿透镜的液体折射率测量仪的实施例,对本发明进行进一步的描述。有必要在此指出的是,以下实施例只用于本发明做进一步的说明,不能理解为对本发明保护范围的限制,该领域技术熟练人员根据上述发明内容对本发明做出一些非本质的改进和调整,仍属于本发明的保护范围。The following describes an embodiment of a liquid refractive index measuring instrument based on an electrowetting lens proposed by the present invention in detail, and further describes the present invention. It is necessary to point out that the following examples are only used to further illustrate the present invention, and should not be construed as limiting the scope of protection of the present invention. Those skilled in the art make some non-essential improvements and The adjustment still belongs to the protection scope of the present invention.
基于电润湿透镜的液体折射率测量仪由硬质腔体、光源、准直透镜、液体测量腔体、进水口、出水口、电润湿透镜和图像传感器组成。其中,液体测量腔体由两片光学透镜封装组成。进水口和出水口对称分布在液体测量腔体上,且进水口与出水口直径相同。本发明的一个实施例为:液体折射率测量仪的硬质腔体由聚甲基丙烯酸甲酯(PMMA)材料制成,外径为18mm,长度为72mm,腔体内径为1mm;准直透镜为BK7光学玻璃制成,曲率半径为50mm;组成液体测量腔体的两片凸透镜为K9光学玻璃制成,曲率半径为150mm,该实施例的光学仿真模拟图如附图3所示。本实施例中的电润湿透镜型号为Varioptic公司生产的Arctic 39N0,其驱动电压和焦距变化示意图如附图4所示。在初试状态时,液体折射率测量仪的液体测量腔体内不加任何液体,光线经准直透镜、液体测量腔体,通过调节电润湿透镜的外部施加电压,使图像传感器接收到的光斑达到最小,此时,电润湿透镜外部施加的电压为48V。当加入浓度为2%的NaCl溶液,调节电润湿透镜外部施加电压,再次使图像传感器接收到的光斑达到最小。此时,电润湿透镜外部施加的电压为53V。通过电润湿透镜的电压与焦距测量表得到对应的焦距,根据ynu光线追迹法计算得到NaCl溶液的折射率为1.348。The liquid refractive index measuring instrument based on electrowetting lens is composed of a hard cavity, a light source, a collimating lens, a liquid measuring cavity, a water inlet, a water outlet, an electrowetting lens and an image sensor. Among them, the liquid measurement cavity is composed of two optical lens packages. The water inlet and outlet are symmetrically distributed on the liquid measuring cavity, and the diameter of the water inlet and the water outlet are the same. An embodiment of the present invention is: the hard cavity of the liquid refractive index measuring instrument is made of polymethyl methacrylate (PMMA) material, the outer diameter is 18mm, the length is 72mm, and the inner diameter of the cavity is 1mm; the collimating lens It is made of BK7 optical glass with a radius of curvature of 50mm; the two convex lenses forming the liquid measuring cavity are made of K9 optical glass with a radius of curvature of 150mm. The optical simulation diagram of this embodiment is shown in Figure 3. The model of the electrowetting lens in this embodiment is Arctic 39N0 produced by Varioptic Company, and a schematic diagram of the variation of the driving voltage and the focal length is shown in FIG. 4 . In the initial test state, no liquid is added to the liquid measuring cavity of the liquid refractive index measuring instrument, the light passes through the collimating lens and the liquid measuring cavity, and the external applied voltage of the electrowetting lens is adjusted, so that the light spot received by the image sensor reaches The minimum, at this time, the voltage applied outside the electrowetting lens is 48V. When NaCl solution with a concentration of 2% was added, the voltage applied outside the electro-wetting lens was adjusted to minimize the light spot received by the image sensor again. At this time, the voltage applied outside the electrowetting lens was 53V. The corresponding focal length was obtained by measuring the voltage and focal length of the electrowetting lens, and the refractive index of the NaCl solution was calculated according to the ynu ray tracing method to be 1.348.
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