CN109999616A - A kind of tail gas absorbing system and technique in oil extraction workshop - Google Patents
A kind of tail gas absorbing system and technique in oil extraction workshop Download PDFInfo
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- 238000000034 method Methods 0.000 title claims abstract description 27
- 238000000605 extraction Methods 0.000 title claims 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 252
- 238000001179 sorption measurement Methods 0.000 claims abstract description 122
- 239000002904 solvent Substances 0.000 claims abstract description 84
- 238000010521 absorption reaction Methods 0.000 claims abstract description 74
- 239000005662 Paraffin oil Substances 0.000 claims abstract description 50
- 238000003795 desorption Methods 0.000 claims abstract description 48
- 238000011084 recovery Methods 0.000 claims abstract description 44
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 17
- 230000008569 process Effects 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002245 particle Substances 0.000 claims abstract description 9
- 239000003595 mist Substances 0.000 claims abstract description 8
- 239000007789 gas Substances 0.000 claims description 117
- 239000003463 adsorbent Substances 0.000 claims description 16
- 230000007246 mechanism Effects 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 230000000694 effects Effects 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- 238000004880 explosion Methods 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 239000000498 cooling water Substances 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims 11
- 229910052799 carbon Inorganic materials 0.000 claims 8
- 238000004064 recycling Methods 0.000 claims 3
- 239000003610 charcoal Substances 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 238000005516 engineering process Methods 0.000 claims 2
- 230000000712 assembly Effects 0.000 claims 1
- 238000000429 assembly Methods 0.000 claims 1
- 238000009833 condensation Methods 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- 239000000428 dust Substances 0.000 claims 1
- 238000013022 venting Methods 0.000 claims 1
- 238000002386 leaching Methods 0.000 abstract description 22
- 239000004519 grease Substances 0.000 abstract description 16
- 239000000809 air pollutant Substances 0.000 abstract description 4
- 231100001243 air pollutant Toxicity 0.000 abstract description 4
- 239000003921 oil Substances 0.000 description 10
- 235000019198 oils Nutrition 0.000 description 10
- 239000003507 refrigerant Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- 238000007710 freezing Methods 0.000 description 4
- 230000008014 freezing Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000007547 defect Effects 0.000 description 3
- 239000008157 edible vegetable oil Substances 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000003673 groundwater Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000004807 desolvation Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
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- 235000012054 meals Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
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- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
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- 239000007787 solid Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 238000004148 unit process Methods 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1418—Recovery of products
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1431—Pretreatment by other processes
- B01D53/145—Pretreatment by separation of solid or liquid material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/205—Other organic compounds not covered by B01D2252/00 - B01D2252/20494
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
- B01D2259/4009—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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Abstract
本发明公开了油脂浸出车间用的尾气吸收系统及工艺,尾气吸收系统包括尾气预处理单元,其将尾气中颗粒和水雾滤除;石蜡油吸收单元;活性炭吸附单元,其包括与石蜡油吸收塔的排气端部连通的活性炭吸附塔、能够对活性炭吸附塔进行溶剂脱附的脱附组件,其中活性炭吸附塔至少有两个,并分成两组,一组为工作组,另一组为备用组,当工作组处于吸附饱和状态时,备用组与石蜡油吸收塔连通,脱附组件自动对处于饱和状态下的工作组进行脱附。本发明不仅能够将尾气的中溶剂实现95%~99.9%的回收率,而且排空时气体中的溶剂浓度控制在0.08~0.1g/m3,符合GB16297‑1996《大气污染物综合排放标准》,操作简单,成本低。
The invention discloses a tail gas absorption system and a process for a grease leaching workshop. The tail gas absorption system includes a tail gas pretreatment unit, which filters out particles and water mist in the tail gas; a paraffin oil absorption unit; The activated carbon adsorption tower connected to the exhaust end of the tower, and the desorption component capable of desorbing the solvent of the activated carbon adsorption tower. There are at least two activated carbon adsorption towers, and they are divided into two groups, one group is the working group, and the other group is the The standby group, when the working group is in the adsorption saturation state, the standby group is connected with the paraffin oil absorption tower, and the desorption component automatically desorbs the working group in the saturated state. The invention can not only realize the recovery rate of 95%-99.9% of the solvent in the tail gas, but also control the solvent concentration in the gas to be 0.08-0.1g/m 3 when emptying, which conforms to GB16297-1996 "Comprehensive Emission Standard of Air Pollutants" , Simple operation and low cost.
Description
技术领域technical field
本发明涉及一种油脂浸出车间用的尾气吸收系统,同时本发明还涉及一种油脂浸出车间用的尾气吸收工艺。The invention relates to a tail gas absorption system used in a grease leaching workshop, and also relates to a tail gas absorption process used in a grease leaching workshop.
背景技术Background technique
在食用油脂浸出车间生产过程中,浸出的油料是油料的预榨饼、油料的生坯或油料的膨化颗粒,由于这些油料有一定的空隙率,在进入浸出系统时总要带入一定量的空气;混合油汽提和湿粕脱溶时均有直接蒸汽喷入,同样要带入一部分空气进入浸出系统中;以及由于各个设备密封不好,特别是负压蒸发工艺,也有少量的空气进入。这些空气和溶剂接触,有挥发的溶剂气体分子,这类气体分子使空气饱和,形成含溶剂的空气,把这种气体称作自由气体,也称为尾气,对这种气体进行处理或回收的装置称为尾气吸收系统。In the production process of the edible oil leaching workshop, the leached oil is the pre-pressed cake of the oil, the green body of the oil or the puffed particles of the oil. Since these oils have a certain porosity, a certain amount of oil must always be brought into the leaching system. Air; direct steam is injected into the mixed oil stripping and wet meal desolvation, and a part of the air is also brought into the leaching system; and due to the poor sealing of various equipment, especially the negative pressure evaporation process, a small amount of air also enters . These air and solvent contact, there are volatile solvent gas molecules, such gas molecules saturate the air to form solvent-containing air, this gas is called free gas, also known as tail gas, the gas is treated or recovered. The device is called an exhaust gas absorption system.
由于这部份气体不能被冷凝器所冷凝,长期聚集会增加容器内的压力,若不及时排出,将会影响生产的顺利进行,甚至会引起危险事故的发生。同时,这部份气体中混有大量的溶剂,如直接排放,不但会增加溶耗,增加成本,而且会污染环境,所以,在尾气排空前一定要对其中的溶剂进行回收。Since this part of the gas cannot be condensed by the condenser, long-term accumulation will increase the pressure in the container. If it is not discharged in time, it will affect the smooth progress of production and even cause dangerous accidents. At the same time, this part of the gas is mixed with a large amount of solvent. If it is directly discharged, it will not only increase the dissolution consumption, increase the cost, but also pollute the environment. Therefore, the solvent must be recovered before the exhaust gas is emptied.
由上述所知,在油脂浸出车间各个设备排出的空气中,始终含有一定数量的溶剂蒸汽。溶剂蒸汽在自身气体中的含量,取决于溶剂馏分的组成,以及取决于冷凝器的温度。From the above knowledge, there is always a certain amount of solvent vapor in the air discharged from each equipment in the grease leaching workshop. The content of solvent vapor in the own gas depends on the composition of the solvent fraction and on the temperature of the condenser.
通常这种自由气体中的溶剂是在回收装置即尾气吸收系统中进行回收的。目前国内外吸收的方法如下:采用冷冻剂冷冻回收方法;利用石蜡油或者植物油吸收回收方法(液体吸收);利用活性炭吸附回收方法(固体吸附)。这些方法的选择有限制,取决于溶剂蒸气在它与空气的混合气体中的浓度,冷冻法回收应用于浓度170~250g/m3时;石蜡油或植物油回收应用于浓度140~170g/m3时;活性炭回收应用于浓度50~140g/m3时,如果溶剂浓度超过这些范围,则吸收溶剂的效果将大打折扣。一般情况下,石蜡油吸收回收方法利用最多。Usually the solvent in this free gas is recovered in the recovery unit, the tail gas absorption system. At present, the absorption methods at home and abroad are as follows: using refrigerant freezing recovery method; using paraffin oil or vegetable oil absorption recovery method (liquid absorption); using activated carbon adsorption recovery method (solid adsorption). The selection of these methods is limited, depending on the concentration of the solvent vapor in its mixed gas with air, when the freezing method recovery is applied to the concentration of 170-250g/m3; the recovery of paraffin oil or vegetable oil is applied to the concentration of 140-170g/m3; When activated carbon recovery is used in a concentration of 50-140g/m3, if the solvent concentration exceeds these ranges, the effect of absorbing the solvent will be greatly reduced. In general, the absorption and recovery method of paraffin oil is the most used.
具体的,采用冷冻剂冷冻回收方法分为低温水冷却回收和制冷剂冷冻回收两种。低温水采用温度为7~15℃的地下水,不循环使用,这种方法溶剂回收率较低,且大量使用地下水,故新建或改造的油脂加工厂不会采用。制冷剂主要用冷却温度为-20~-10℃的制冷剂,常用的有氨和氟里昂,存在对食用油的污染的风险,也不利于环保,操作时控制非常麻烦,最多能回收自由气体中所含溶剂的60%,效果并不理想。Specifically, the refrigerant freezing recovery method is divided into two types: low temperature water cooling recovery and refrigerant freezing recovery. Low-temperature water uses groundwater with a temperature of 7 to 15 °C, and is not recycled. This method has a low solvent recovery rate and a large amount of groundwater is used, so it will not be used in newly built or renovated oil processing plants. Refrigerants mainly use refrigerants with a cooling temperature of -20 to -10 °C. Commonly used ones are ammonia and freon, which have the risk of contaminating edible oil and are not conducive to environmental protection. The control during operation is very troublesome, and free gas can be recovered at most. 60% of the solvent contained in it, the effect is not ideal.
至于采用液体吸收方法,其以石蜡油为吸收剂,所采用的设备是吸收塔和解析塔,但是经过石蜡油吸收后,所排放的尾气溶剂含量,预计回收率为80%~90%左右,致使溶剂回收率偏低,这样一来,食用油脂浸出车间的溶剂消耗量控制在1.5~2.5kg/(t原料)之间,无法再进一步降低,同时所排放气体很难符合GB16297-1996《大气污染物综合排放标准》,在市场竞争十分激烈的今天,这对油脂加工企业造成了很大的成本压力和环保压力。As for the liquid absorption method, paraffin oil is used as the absorbent, and the equipment used is an absorption tower and a desorption tower. As a result, the solvent recovery rate is low. In this way, the solvent consumption of the edible oil leaching workshop is controlled between 1.5 and 2.5 kg/(t raw material), which cannot be further reduced. Comprehensive Pollutant Emission Standard", in today's fierce market competition, which has caused great cost pressure and environmental protection pressure on oil processing enterprises.
针对活性炭吸附回收方法,其具有很好的回收效果,但是它存在三个问题,即吸附热和解析热的产生,溶剂气体集聚达到爆炸极限,活性炭吸附和再生的操作是间歇操作的,因此它的运用因上述操作麻烦和不安全的因素而受到极大限制,实际上现在在工业上很少采用了。(活性炭的吸附热是相当大的,约每吸附1g溶剂就要产生347~695J的热量,这热量如不排除就会积聚在活性炭床上,使温度很快上升,遇空气会造成自燃。另外,自由气体进入活性炭床,它的组成就不断改变,不可避免达到爆炸极限。因此活性炭吸附虽然效果很好,但是存在局部过热和爆炸极限问题。)For the activated carbon adsorption recovery method, it has a good recovery effect, but it has three problems, namely, the generation of adsorption heat and heat of desorption, the accumulation of solvent gas reaches the explosion limit, and the operation of activated carbon adsorption and regeneration is intermittent. Its application is greatly limited due to the above-mentioned troublesome and unsafe factors, and it is rarely used in industry now. (The adsorption heat of activated carbon is quite large, about 347~695J of heat will be generated for every 1g of solvent adsorbed. If this heat is not removed, it will accumulate on the activated carbon bed, causing the temperature to rise quickly, and it will cause spontaneous combustion in the presence of air. In addition, When the free gas enters the activated carbon bed, its composition changes continuously and inevitably reaches the explosion limit. Therefore, although the adsorption effect of activated carbon is very good, there are problems of local overheating and explosion limit.)
综上所述,目前国内外所采用的三种吸收方法均存在严重的缺陷,在生产过程中为避免这些缺陷带来的麻烦甚至是事故,必须配置大量的配套设备进行控制,必须配备专门岗位人员进行监控和操作,并制订严格的管理措施,必须在浸出车间里为它设计专门的设备平台,等等,因此在投资、生产成本、吸收效果、环保、食品安全等方面,存在技术性问题和缺陷。In summary, the three absorption methods currently used at home and abroad all have serious defects. In order to avoid troubles and even accidents caused by these defects in the production process, a large number of supporting equipment must be equipped for control, and special positions must be allocated. It is necessary to design a special equipment platform for it in the leaching workshop, etc., so there are technical problems and problems in terms of investment, production cost, absorption effect, environmental protection, food safety, etc. defect.
发明内容SUMMARY OF THE INVENTION
本发明所要解决的技术问题是克服现有技术的不足,提供一种改进的油脂浸出车间用的尾气吸收系统。The technical problem to be solved by the present invention is to overcome the deficiencies of the prior art and provide an improved tail gas absorption system for grease leaching workshops.
同时,本发明还涉及一种油脂浸出车间用的尾气吸收工艺。At the same time, the invention also relates to a tail gas absorption process used in a grease leaching workshop.
为解决上述技术问题,本发明采取如下技术方案:In order to solve the above-mentioned technical problems, the present invention adopts the following technical solutions:
一种油脂浸出车间用的尾气吸收系统,其包括:A tail gas absorption system used in a grease leaching workshop, comprising:
石蜡油吸收单元,其包括与油脂浸出车间排气端部连通的石蜡油吸收塔、解析塔、第一冷凝器、以及第一溶剂回收器,其中解析塔能够将石蜡油吸收塔内石蜡油中所含有的溶剂解析出来,第一冷凝器将解析塔所解析后的气体液化,第一溶剂回收器将液化后的溶剂与石蜡油分离并回收;The paraffin oil absorption unit includes a paraffin oil absorption tower, a desorption tower, a first condenser, and a first solvent reclaimer communicated with the exhaust end of the grease leaching workshop, wherein the desorption tower can absorb the paraffin oil in the paraffin oil in the tower. The contained solvent is resolved, the first condenser liquefies the gas resolved by the analysis tower, and the first solvent recoverer separates and recovers the liquefied solvent and paraffin oil;
尾气预处理单元,其设置在所述的石蜡油吸收塔与油脂浸出车间排气端部之间且能够将尾气中颗粒和水雾滤除;A tail gas pretreatment unit, which is arranged between the paraffin oil absorption tower and the exhaust end of the grease leaching workshop and can filter out particles and water mist in the tail gas;
活性炭吸附单元,其包括与所述石蜡油吸收塔的排气端部连通的活性炭吸附塔、能够对活性炭吸附塔进行溶剂脱附的脱附组件,其中活性炭吸附塔至少有两个,并分成两组,一组为工作组,另一组为备用组,当工作组处于吸附饱和状态时,备用组与石蜡油吸收塔连通,脱附组件自动对处于饱和状态下的工作组进行脱附。The activated carbon adsorption unit includes an activated carbon adsorption tower communicating with the exhaust end of the paraffin oil absorption tower, and a desorption component capable of desorbing the solvent from the activated carbon adsorption tower, wherein the activated carbon adsorption tower has at least two and is divided into two parts. When the working group is in the adsorption saturation state, the standby group is connected with the paraffin oil absorption tower, and the desorption component automatically desorbs the working group in the saturated state.
优选地,活性炭吸附塔有两个,一个为工作组,一个为备用组;尾气吸收系统还包括用于将两个活性炭吸附塔与石蜡油吸收塔排气端部相连通的三通阀Ⅰ,当吸附时,三通阀Ⅰ将两个中的一个活性炭吸附塔与石蜡油吸收塔连通;当一个活性炭吸附塔吸附饱和状态时,处于饱和状态的活性炭吸附塔停止通入自石蜡油吸收塔排出的气体,三通阀Ⅰ切换将另一个活性炭吸附塔与石蜡油吸收塔连通。Preferably, there are two activated carbon adsorption towers, one is a working group and the other is a standby group; the tail gas absorption system also includes a three-way valve I for connecting the two activated carbon adsorption towers with the exhaust end of the paraffin oil absorption tower, When adsorbing, the three-way valve I connects one of the two activated carbon adsorption towers with the paraffin oil absorption tower; when one activated carbon adsorption tower is in a saturated state, the activated carbon adsorption tower in the saturated state stops feeding and is discharged from the paraffin oil absorption tower The three-way valve I switches to connect the other activated carbon adsorption tower with the paraffin oil adsorption tower.
根据本发明的一个具体实施和优选方面,脱附组件包括设置在每个活性炭吸附塔的排尾气通道中且用于监控排出尾气流量的监控器、与监控器连通且能够对活性炭吸附塔进行脱附的脱附机构、以及与监控器和脱附机构相连通的PLC控制器,其中监控器具有设定模块,当所监测值小于或等于设定模块所设定值时,PLC控制器驱使三通阀Ⅰ切换,且脱附机构对处于饱和状态的活性炭吸附塔进行脱附。According to a specific implementation and preferred aspect of the present invention, the desorption assembly includes a monitor arranged in the exhaust gas channel of each activated carbon adsorption tower and used for monitoring the flow rate of the exhaust gas, communicated with the monitor and capable of desorbing the activated carbon adsorption tower The attached desorption mechanism, and the PLC controller communicated with the monitor and the desorption mechanism, wherein the monitor has a setting module, and when the monitored value is less than or equal to the value set by the setting module, the PLC controller drives the tee Valve I is switched, and the desorption mechanism desorbs the activated carbon adsorption tower in a saturated state.
在此,申请人解释一下“设定值”,可以理解的活性炭吸附塔处于饱和状态下的“流量安全值”,只要等于或超过该限值,马上停止供尾气,进行脱附。Here, the applicant explains the "set value". It is understood that the "flow safety value" of the activated carbon adsorption tower in a saturated state. As long as it is equal to or exceeds the limit, the exhaust gas supply will be stopped immediately and desorption will be carried out.
优选地,脱附机构包括设置在气体管路上的三通阀Ⅱ、与三通阀Ⅱ连通的直接蒸汽加热部件、与每个活性炭吸附塔相连通的第二冷凝器、与第二冷凝器连通的第二溶剂回收器、以及能够对活性炭吸附塔的活性炭吸附剂进行干燥和冷却以恢复活性炭吸附剂的吸附能力的辅助部件。Preferably, the desorption mechanism includes a three-way valve II arranged on the gas pipeline, a direct steam heating component communicated with the three-way valve II, a second condenser communicated with each activated carbon adsorption tower, and communicated with the second condenser. The second solvent recoverer, and auxiliary components capable of drying and cooling the activated carbon adsorbent of the activated carbon adsorption tower to restore the adsorption capacity of the activated carbon adsorbent.
根据本发明的又一个具体实施和优选方面,每个活性炭吸附塔还具有一个溶剂回收通道,溶剂回收通道与第二冷凝器相连通,且在排尾气通道和溶剂回收通道上分别设有第一控制阀和第二控制阀,其中当活性炭吸附塔处于吸附状态时,第一控制阀打开,第二控制阀闭合;当处于脱附时,第二控制阀打开,第一控制阀闭合。According to another specific implementation and preferred aspect of the present invention, each activated carbon adsorption tower also has a solvent recovery channel, the solvent recovery channel is communicated with the second condenser, and the exhaust gas channel and the solvent recovery channel are respectively provided with a first solvent recovery channel A control valve and a second control valve, wherein when the activated carbon adsorption tower is in the adsorption state, the first control valve is opened and the second control valve is closed; when it is in the desorption state, the second control valve is opened and the first control valve is closed.
优选地,辅助部件包括能够加入热或冷介质的交换器、用于将交换器所加热或冷却的气体送入待脱附活性炭吸附塔中的第一风机。Preferably, the auxiliary components include an exchanger capable of adding a hot or cold medium, a first fan for feeding the gas heated or cooled by the exchanger into the activated carbon adsorption tower to be desorbed.
具体的,热介质为蒸汽,冷介质为冷却水。Specifically, the heating medium is steam, and the cooling medium is cooling water.
优选地,活性炭吸附单元还包括设置在活性炭吸附塔与石蜡油吸收塔连通管道上的第二风机。Preferably, the activated carbon adsorption unit further includes a second fan arranged on the communication pipeline between the activated carbon adsorption tower and the paraffin oil absorption tower.
优选地,尾气预处理单元包括含有过滤组件的过滤器。Preferably, the exhaust gas pretreatment unit includes a filter including a filter assembly.
此外,尾气吸收系统还包括阻火器、逆止阀、泄爆口、以及与石蜡油吸收单元和活性炭吸附单元相连通的氮气安全防护单元。In addition, the exhaust gas absorption system also includes a flame arrester, a check valve, an explosion vent, and a nitrogen safety protection unit communicated with the paraffin oil absorption unit and the activated carbon adsorption unit.
本发明的另一技术方案是:一种油脂浸出车间用的尾气吸收工艺,该工艺采用了上述的油脂浸出车间用的尾气吸收系统,其步骤如下:Another technical scheme of the present invention is: a kind of tail gas absorption process used in the grease leaching workshop, the process adopts the above-mentioned tail gas absorption system used in the grease leaching workshop, and the steps are as follows:
1)、油脂浸出车间排出的尾气由所述尾气预处理单元将尾气中颗粒和水雾滤除,并通向所述石蜡油吸收单元;1) The tail gas discharged from the grease leaching workshop is filtered by the tail gas pretreatment unit to filter out the particles and water mist in the tail gas, and leads to the paraffin oil absorption unit;
2)、由所述石蜡油吸收单元对处理后的尾气进行吸收,并通过所述解析塔、第一冷凝器、以及第一溶剂回收器实现溶剂的回收,同时排出的气体导向至所述活性炭吸附单元;2) The treated tail gas is absorbed by the paraffin oil absorption unit, and the solvent is recovered through the analytical tower, the first condenser, and the first solvent recovery device, and the discharged gas is directed to the activated carbon adsorption unit;
3)、由所述活性炭吸附单元的工作组进行尾气吸附处理,处理后的尾气自所述活性炭吸附单元的工作组排出,当工作组处于吸附饱和状态时,自所述石蜡油吸收单元排出的气体进入备用组进行吸附处理,同时所述的脱附组件自动对吸附饱和状态下的所述活性炭吸附塔进行溶剂脱附,并进行脱附后溶剂的回收,同时脱附后的所述活性炭吸附塔形成所述备用组。3) The exhaust gas adsorption treatment is carried out by the working group of the activated carbon adsorption unit. The treated exhaust gas is discharged from the working group of the activated carbon adsorption unit. When the working group is in the adsorption saturation state, the exhaust gas discharged from the paraffin oil absorption unit is discharged. The gas enters the standby group for adsorption treatment, and at the same time, the desorption component automatically desorbs the activated carbon adsorption tower under the adsorption saturation state, and recovers the solvent after desorption. At the same time, the desorbed activated carbon adsorbs The towers form the spare group.
优选地,脱附过程如下:Preferably, the desorption process is as follows:
a)、采用直接蒸汽通入活性炭吸附塔内,由蒸汽将活性炭吸附剂上的溶剂带出活性炭吸附塔,然后进行液化,以实现溶剂的回收;a), adopt direct steam to pass into the activated carbon adsorption tower, and the solvent on the activated carbon adsorbent is brought out of the activated carbon adsorption tower by steam, and then liquefies to realize the recovery of the solvent;
b)、向活性炭吸附塔内通入加热后的热空气,使得活性炭吸附剂快速干燥;b) Pass heated hot air into the activated carbon adsorption tower to dry the activated carbon adsorbent quickly;
c)、向活性炭吸附塔内通入冷却后的冷空气,使得活性炭吸附剂快速冷却,以恢复活性炭吸附剂的吸附能力。c), pass the cooled cold air into the activated carbon adsorption tower, so that the activated carbon adsorbent is rapidly cooled to restore the adsorption capacity of the activated carbon adsorbent.
也就是说,本例中的活性炭吸附单元过程分为四个:吸附、蒸发、干燥、冷却,尾气通过活性炭层时,溶剂被吸附,而尾气此时可达标(GB16297-1996《大气污染物综合排放标准》)排入大气中,当吸附塔中活性炭的吸附能力降低到一定程度后,尾气流即被转换进入到另一个吸附塔,被溶剂所饱和的活性炭,可开通直接蒸汽加热,由水蒸汽带走吸附剂中的溶剂,且一起到第二冷凝器冷凝,然后在由第二溶剂回收器进行溶剂回收,这样一来,可实现95%~99.9%的回收率。That is to say, the activated carbon adsorption unit process in this example is divided into four processes: adsorption, evaporation, drying, and cooling. When the exhaust gas passes through the activated carbon layer, the solvent is adsorbed, and the exhaust gas can reach the standard at this time (GB16297-1996 "Integrated Air Pollutants"). Emission Standard") is discharged into the atmosphere, when the adsorption capacity of the activated carbon in the adsorption tower is reduced to a certain level, the exhaust gas flow is converted into another adsorption tower, and the activated carbon saturated with the solvent can be heated by direct steam and heated by water. The steam takes away the solvent in the adsorbent and condenses in the second condenser, and then the solvent is recovered by the second solvent recovery device. In this way, a recovery rate of 95% to 99.9% can be achieved.
同时,为了在通蒸汽后恢复活性炭的吸附能力,由交换器加入的蒸汽对空气进行干燥,然后由第一风机将热空气导入吸附塔,对活性炭进行干燥;然后更换交换器内的介质,通入冷却水,由交换器对空气进行冷却,再有第一风机将冷空气导向活性炭,以求恢复活性炭的吸附能力,使吸附塔完成脱附,进而使得两个吸附塔能够交替循环使用。At the same time, in order to restore the adsorption capacity of the activated carbon after passing the steam, the steam added by the exchanger dries the air, and then the hot air is introduced into the adsorption tower by the first fan to dry the activated carbon; Into the cooling water, the air is cooled by the exchanger, and then the first fan guides the cold air to the activated carbon, in order to restore the adsorption capacity of the activated carbon, so that the adsorption tower can complete the desorption, so that the two adsorption towers can be used alternately.
由于以上技术方案的实施,本发明与现有技术相比具有如下优点:Due to the implementation of the above technical solutions, the present invention has the following advantages compared with the prior art:
本发明不仅能够将尾气的中溶剂实现95%~99.9%的回收率,而且排空时气体中的溶剂浓度控制在0.08~0.1g/m3,符合GB16297-1996《大气污染物综合排放标准》,同时操作简单,大幅度的降低成本。The invention can not only realize the recovery rate of 95%-99.9% of the solvent in the tail gas, but also control the solvent concentration in the gas to be 0.08-0.1g/m 3 when emptying, which conforms to GB16297-1996 "Comprehensive Emission Standard of Air Pollutants" , At the same time, the operation is simple and the cost is greatly reduced.
附图说明Description of drawings
下面结合附图和具体的实施例对本发明做进一步详细的说明。The present invention will be further described in detail below with reference to the accompanying drawings and specific embodiments.
图1为本发明的尾气吸收系统的结构示意图(图中的虚线表示尾气的走向);Fig. 1 is the structural schematic diagram of the exhaust gas absorption system of the present invention (the dotted line in the figure represents the direction of the exhaust gas);
其中:1、尾气预处理单元;10、过滤器;Among them: 1. Exhaust gas pretreatment unit; 10. Filter;
2、石蜡油吸收单元;20、石蜡油吸收塔;21、解析塔;22、第一冷凝器;23、第一溶剂回收器;2, paraffin oil absorption unit; 20, paraffin oil absorption tower; 21, analysis tower; 22, first condenser; 23, first solvent recovery device;
3、活性炭吸附单元;30、活性炭吸附塔;30a、排尾气通道;30b、溶剂回收通道;31、脱附组件;310、监控器;311、脱附机构;a、三通阀Ⅱ;b、直接蒸汽加热部件;c、第二冷凝器;d、第二溶剂回收器;e、辅助部件;e1、交换器;e2、第一风机;f1、第一控制阀;f2、第二控制阀;32、第二风机;3. Activated carbon adsorption unit; 30, activated carbon adsorption tower; 30a, exhaust gas channel; 30b, solvent recovery channel; 31, desorption component; 310, monitor; 311, desorption mechanism; a, three-way valve II; b, Direct steam heating part; c, second condenser; d, second solvent recovery device; e, auxiliary part; e1, exchanger; e2, first fan; f1, first control valve; f2, second control valve; 32. The second fan;
4、三通阀Ⅰ;4. Three-way valve I;
X、油脂浸出车间。X. Oil leaching workshop.
具体实施方式Detailed ways
为使本申请的上述目的、特征和优点能够更加明显易懂,下面结合附图对本申请的具体实施方式做详细的说明。在下面的描述中阐述了很多具体细节以便于充分理解本申请。但是本申请能够以很多不同于在此描述的其它方式来实施,本领域技术人员可以在不违背本申请内涵的情况下做类似改进,因此本申请不受下面公开的具体实施例的限制。In order to make the above objects, features and advantages of the present application more clearly understood, the specific embodiments of the present application will be described in detail below with reference to the accompanying drawings. In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present application. However, the present application can be implemented in many other ways different from those described herein, and those skilled in the art can make similar improvements without departing from the connotation of the present application. Therefore, the present application is not limited by the specific embodiments disclosed below.
在本申请的描述中,需要理解的是,术语“中心”、“纵向”、“横向”、“长度”、“宽度”、“厚度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”、“顺时针”、“逆时针”、“轴向”、“径向”、“周向”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本申请和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本申请的限制。In the description of this application, it should be understood that the terms "center", "longitudinal", "lateral", "length", "width", "thickness", "upper", "lower", "front", " Back, Left, Right, Vertical, Horizontal, Top, Bottom, Inner, Outer, Clockwise, Counterclockwise, Axial , "radial", "circumferential" and other indicated orientations or positional relationships are based on the orientations or positional relationships shown in the accompanying drawings, and are only for the convenience of describing the application and simplifying the description, rather than indicating or implying the indicated device or Elements must have a particular orientation, be constructed and operate in a particular orientation and are therefore not to be construed as limitations on this application.
此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括至少一个该特征。在本申请的描述中,“多个”的含义是至少两个,例如两个,三个等,除非另有明确具体的限定。In addition, the terms "first" and "second" are only used for descriptive purposes, and should not be construed as indicating or implying relative importance or implying the number of indicated technical features. Thus, a feature delimited with "first", "second" may expressly or implicitly include at least one of that feature. In the description of the present application, "plurality" means at least two, such as two, three, etc., unless expressly and specifically defined otherwise.
在本申请中,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”、“固定”等术语应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或成一体;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通或两个元件的相互作用关系,除非另有明确的限定。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本申请中的具体含义。In this application, unless otherwise expressly specified and limited, the terms "installed", "connected", "connected", "fixed" and other terms should be understood in a broad sense, for example, it may be a fixed connection or a detachable connection , or integrated; it can be a mechanical connection or an electrical connection; it can be directly connected or indirectly connected through an intermediate medium, it can be the internal connection of two elements or the interaction relationship between the two elements, unless otherwise specified limit. For those of ordinary skill in the art, the specific meanings of the above terms in this application can be understood according to specific situations.
在本申请中,除非另有明确的规定和限定,第一特征在第二特征“上”或“下”可以是第一和第二特征直接接触,或第一和第二特征通过中间媒介间接接触。而且,第一特征在第二特征“之上”、“上方”和“上面”可是第一特征在第二特征正上方或斜上方,或仅仅表示第一特征水平高度高于第二特征。第一特征在第二特征“之下”、“下方”和“下面”可以是第一特征在第二特征正下方或斜下方,或仅仅表示第一特征水平高度小于第二特征。需要说明的是,当元件被称为“固定于”或“设置于”另一个元件,它可以直接在另一个元件上或者也可以存在居中的元件。当一个元件被认为是“连接”另一个元件,它可以是直接连接到另一个元件或者可能同时存在居中元件。本文所使用的术语“垂直的”、“水平的”、“上”、“下”、“左”、“右”以及类似的表述只是为了说明的目的,并不表示是唯一的实施方式。In this application, unless otherwise expressly stated and defined, a first feature "on" or "under" a second feature may be in direct contact with the first and second features, or the first and second features indirectly through an intermediary touch. Also, the first feature being "above", "over" and "above" the second feature may mean that the first feature is directly above or obliquely above the second feature, or simply means that the first feature is level higher than the second feature. The first feature being "below", "below" and "below" the second feature may mean that the first feature is directly below or obliquely below the second feature, or simply means that the first feature has a lower level than the second feature. It should be noted that when an element is referred to as being "fixed to" or "disposed on" another element, it can be directly on the other element or an intervening element may also be present. When an element is referred to as being "connected" to another element, it can be directly connected to the other element or intervening elements may also be present. The terms "vertical", "horizontal", "upper", "lower", "left", "right" and similar expressions used herein are for the purpose of illustration only and do not represent the only embodiment.
参见图1,按照本实施例的油脂浸出车间用的尾气吸收系统,其包括尾气预处理单元1、石蜡油吸收单元2和活性炭吸附单元3。Referring to FIG. 1 , the tail gas absorption system for a grease leaching workshop according to this embodiment includes a tail gas pretreatment unit 1 , a paraffin oil absorption unit 2 and an activated carbon adsorption unit 3 .
具体的,石蜡油吸收单元2,其包括与油脂浸出车间X排气端部连通的石蜡油吸收塔20、解析塔21、第一冷凝器22、以及第一溶剂回收器23,其中解析塔21将石蜡油吸收塔20中含有溶剂解析出来,第一冷凝器22将解析塔21所解析后的气体液化,第一溶剂回收器23将液化后的溶剂与石蜡油分离并回收。Specifically, the paraffin oil absorption unit 2 includes a paraffin oil absorption tower 20, a desorption tower 21, a first condenser 22, and a first solvent recoverer 23 that are communicated with the exhaust end of the grease leaching workshop X, wherein the desorption tower 21 The solvent contained in the paraffin oil absorption tower 20 is decomposed, the first condenser 22 liquefies the decomposed gas in the desorption tower 21, and the first solvent recovery device 23 separates and recovers the liquefied solvent from the paraffin oil.
至于石蜡油吸收塔20、解析塔21、第一冷凝器22、以及第一溶剂回收器23,属于本领域常用设备,在此不对其进行一一阐述。As for the paraffin oil absorption tower 20 , the desorption tower 21 , the first condenser 22 , and the first solvent recoverer 23 , they are commonly used equipment in the art, and will not be described one by one here.
尾气预处理单元1,其设置在石蜡油吸收塔20与油脂浸出车间X排气端部之间且能够将尾气中颗粒和水雾滤除;其主要包括含有过滤组件的过滤器10,也就是说,只要达到去除尾气中的颗粒和水雾即可,也是属于本领域常用设备,在此不对其进行详细阐述。The tail gas pretreatment unit 1 is arranged between the paraffin oil absorption tower 20 and the exhaust end of the grease leaching workshop X and can filter out particles and water mist in the tail gas; it mainly includes a filter 10 containing a filter assembly, that is It is said that as long as the particles and water mist in the exhaust gas can be removed, it is also a common equipment in the field, and will not be described in detail here.
活性炭吸附单元3,其包括与石蜡油吸收塔20的排气端部连通的活性炭吸附塔30、能够对活性炭吸附塔30进行溶剂脱附的脱附组件31,其中活性炭吸附塔30有两个,并分成两组,一个为工作组,另一个为备用组,当工作组处于吸附饱和状态时,备用组与石蜡油吸收塔20连通,脱附组件31自动对处于饱和状态下的工作组进行脱附。The activated carbon adsorption unit 3 includes an activated carbon adsorption tower 30 communicated with the exhaust end of the paraffin oil absorption tower 20, and a desorption assembly 31 capable of desorbing the solvent from the activated carbon adsorption tower 30, wherein there are two activated carbon adsorption towers 30, And divided into two groups, one is the working group and the other is the standby group. When the working group is in the adsorption saturation state, the standby group is communicated with the paraffin oil absorption tower 20, and the desorption component 31 automatically desorbs the working group in the saturated state. attached.
尾气吸收系统还包括用于将两个活性炭吸附塔30与石蜡油吸收塔20排气端部相连通的三通阀Ⅰ4,当吸附时,三通阀Ⅰ4将两个中的一个活性炭吸附塔30与石蜡油吸收塔20连通;当一个活性炭吸附塔30吸附饱和状态时,处于饱和状态的活性炭吸附塔30停止通入自石蜡油吸收塔20排出的气体,三通阀Ⅰ4切换将另一个活性炭吸附塔30与石蜡油吸收塔20连通。The tail gas absorption system also includes a three-way valve I4 for connecting the two activated carbon adsorption towers 30 with the exhaust ends of the paraffin oil absorption tower 20. When adsorbing, the three-way valve I4 connects one of the two activated carbon adsorption towers 30. Connected with the paraffin oil absorption tower 20; when one activated carbon adsorption tower 30 is in a saturated state, the activated carbon adsorption tower 30 in the saturated state stops feeding the gas discharged from the paraffin oil absorption tower 20, and the three-way valve I4 is switched to adsorb another activated carbon. The tower 30 communicates with the paraffin oil absorption tower 20 .
脱附组件31包括设置在每个活性炭吸附塔30的排尾气通道30a中且用于监控排出尾气流量的监控器310、与监控器310连通且能够对活性炭吸附塔30进行脱附的脱附机构311、以及与监控器310和脱附机构311相连通的PLC控制器(图中未显示,但不难想到),其中监控器310具有设定模块,当所监测值小于或等于设定模块所设定值时,PLC控制器驱使三通阀Ⅰ4切换,且脱附机构311对处于饱和状态的活性炭吸附塔30进行脱附。The desorption assembly 31 includes a monitor 310 arranged in the exhaust gas channel 30a of each activated carbon adsorption tower 30 and used for monitoring the flow rate of the exhaust gas, and a desorption mechanism communicated with the monitor 310 and capable of desorbing the activated carbon adsorption tower 30 311, and a PLC controller (not shown in the figure, but not difficult to imagine) communicated with the monitor 310 and the desorption mechanism 311, wherein the monitor 310 has a setting module, when the monitored value is less than or equal to the setting module When the value is fixed, the PLC controller drives the three-way valve I4 to switch, and the desorption mechanism 311 desorbs the activated carbon adsorption tower 30 in a saturated state.
在此,申请人解释一下“设定值”,可以理解的活性炭吸附塔处于饱和状态下的“流量安全值”,只要等于或超过该限值,马上停止供尾气,进行脱附。Here, the applicant explains the "set value". It is understood that the "flow safety value" of the activated carbon adsorption tower in a saturated state. As long as it is equal to or exceeds the limit, the exhaust gas supply will be stopped immediately and desorption will be carried out.
脱附机构311包括设置在气体管路上的三通阀Ⅱa、与三通阀Ⅱa连通的直接蒸汽加热部件b、与每个活性炭吸附塔30相连通的第二冷凝器c、与第二冷凝器c连通的第二溶剂回收器d、以及能够对活性炭吸附塔30的活性炭吸附剂进行干燥和冷却以恢复活性炭吸附剂的吸附能力的辅助部件e。The desorption mechanism 311 includes a three-way valve IIa arranged on the gas pipeline, a direct steam heating component b communicated with the three-way valve IIa, a second condenser c communicated with each activated carbon adsorption tower 30, and a second condenser c communicated with a second solvent recovery device d, and an auxiliary component e capable of drying and cooling the activated carbon adsorbent of the activated carbon adsorption tower 30 to restore the adsorption capacity of the activated carbon adsorbent.
本例中,每个活性炭吸附塔30还具有一个溶剂回收通道30b,溶剂回收通道30b与第二冷凝器c相连通,且在排尾气通道30a和溶剂回收通道30b上分别设有第一控制阀f1和第二控制阀f2,其中当活性炭吸附塔30处于吸附状态时,第一控制阀f1打开,第二控制阀f2闭合;当处于脱附时,第二控制阀f2打开,第一控制阀f1闭合。In this example, each activated carbon adsorption tower 30 also has a solvent recovery channel 30b, the solvent recovery channel 30b is communicated with the second condenser c, and the exhaust gas channel 30a and the solvent recovery channel 30b are respectively provided with a first control valve f1 and the second control valve f2, wherein when the activated carbon adsorption tower 30 is in the adsorption state, the first control valve f1 is opened, and the second control valve f2 is closed; when it is in the desorption state, the second control valve f2 is opened, and the first control valve f1 is closed.
辅助部件e包括能够加入热或冷介质的交换器e1、用于将交换器e1所加热或冷却的气体(空气)送入待脱附活性炭吸附塔30中的第一风机e2。The auxiliary component e includes an exchanger e1 capable of adding hot or cold medium, and a first fan e2 for feeding the gas (air) heated or cooled by the exchanger e1 into the activated carbon adsorption tower 30 to be desorbed.
具体的,热介质为蒸汽,冷介质为冷却水。Specifically, the heating medium is steam, and the cooling medium is cooling water.
本例中,活性炭吸附单元3过程分为四个:吸附、蒸发、干燥、冷却,尾气通过活性炭层时,溶剂被吸附,而尾气此时可达标(GB16297-1996《大气污染物综合排放标准》)排入大气中,当吸附塔中活性炭的吸附能力降低到一定程度后,尾气流即被转换进入到另一个吸附塔,被溶剂所饱和的活性炭,可开通直接蒸汽加热,由水蒸汽带走吸附剂中的溶剂,且一起到第二冷凝器冷凝,然后在由第二溶剂回收器进行溶剂回收,这样一来,可实现95%~99.9%的回收率。In this example, activated carbon adsorption unit 3 has four processes: adsorption, evaporation, drying, and cooling. When the exhaust gas passes through the activated carbon layer, the solvent is adsorbed, and the exhaust gas can reach the standard at this time (GB16297-1996 "Comprehensive Emission Standard of Air Pollutants" ) into the atmosphere, when the adsorption capacity of the activated carbon in the adsorption tower is reduced to a certain level, the tail gas flow is converted into another adsorption tower, and the activated carbon saturated by the solvent can be heated by direct steam and taken away by water vapor The solvent in the adsorbent is condensed in the second condenser, and then the solvent is recovered by the second solvent recovery device. In this way, a recovery rate of 95% to 99.9% can be achieved.
此外,活性炭吸附单元3还包括设置在活性炭吸附塔30与石蜡油吸收塔20连通管道上的第二风机32。In addition, the activated carbon adsorption unit 3 further includes a second fan 32 arranged on the communication pipeline between the activated carbon adsorption tower 30 and the paraffin oil absorption tower 20 .
与此同时,本例中的尾气吸收系统还包括阻火器、逆止阀、泄爆口、以及与石蜡油吸收单元和活性炭吸附单元相连通的氮气安全防护单元。At the same time, the exhaust gas absorption system in this example also includes a flame arrester, a check valve, an explosion vent, and a nitrogen safety protection unit communicated with the paraffin oil absorption unit and the activated carbon adsorption unit.
本例中,阻火器、逆止阀、泄爆口、氮气安全防护装置均与PLC控制器连通,最终的目的就是形成完善的安全控制系统(虽然这些都没在图中显示,但对于本领域人员来说,是十分常用的,在此不对其进行详细阐述)。In this example, the flame arrester, check valve, explosion vent, and nitrogen safety protection device are all connected to the PLC controller, and the ultimate purpose is to form a complete safety control system (although these are not shown in the figure, but for the field For personnel, it is very commonly used and will not be elaborated here).
综上所述,本实施例不仅能够将尾气的中溶剂实现95%~99.9%的回收率,而且排空时气体中的溶剂浓度控制在0.08~0.1g/m3,符合GB16297-1996《大气污染物综合排放标准》,同时操作简单,大幅度的降低成本。To sum up, this embodiment can not only achieve a recovery rate of 95% to 99.9% for the solvent in the exhaust gas, but also control the solvent concentration in the gas to be 0.08 to 0.1 g/m 3 during emptying, which is in line with GB16297-1996 "Atmosphere". Integrated Pollutant Emission Standard", at the same time, it is simple to operate and greatly reduces the cost.
同时,本实施例的实施过程如下:Meanwhile, the implementation process of this embodiment is as follows:
1)、油脂浸出车间排出的尾气由尾气预处理单元将尾气中颗粒和水雾滤除,并通向石蜡油吸收单元;1) The tail gas discharged from the grease leaching workshop is filtered by the tail gas pretreatment unit to filter out the particles and water mist in the tail gas, and leads to the paraffin oil absorption unit;
2)、由石蜡油吸收单元对处理后的尾气进行吸收,并通过所述解析塔、第一冷凝器、以及第一溶剂回收器实现溶剂的回收,同时排出的气体导向至活性炭吸附单元,其中所排出的气体中溶剂的含量占10%~20%;2), the treated tail gas is absorbed by the paraffin oil absorption unit, and the recovery of the solvent is realized through the analytical tower, the first condenser, and the first solvent recovery device, and the discharged gas is directed to the activated carbon adsorption unit, wherein The content of solvent in the discharged gas accounts for 10%~20%;
3)、由活性炭吸附单元的工作组进行尾气吸附处理,处理后的尾气自活性炭吸附单元的工作组排出,其中所排出的气体中溶剂的含量占0.1%~5%,同时,当工作组处于吸附饱和状态时,自石蜡油吸收单元排出的气体进入备用组进行吸附处理,同时脱附组件自动对吸附饱和状态下的活性炭吸附塔进行溶剂脱附,并进行脱附后溶剂的回收,同时脱附后的活性炭吸附塔形成备用组,如此交替循环使用,可不间断的实现尾气的吸收。3) The exhaust gas adsorption treatment is carried out by the working group of the activated carbon adsorption unit, and the treated exhaust gas is discharged from the working group of the activated carbon adsorption unit, and the solvent content in the discharged gas accounts for 0.1%~5%. When the adsorption is saturated, the gas discharged from the paraffin oil absorption unit enters the standby group for adsorption treatment. At the same time, the desorption component automatically desorbs the solvent from the activated carbon adsorption tower in the adsorption saturation state, and recovers the solvent after desorption. The attached activated carbon adsorption tower forms a spare group, which can be used alternately and circularly to achieve continuous exhaust gas absorption.
同时,上述的脱附过程如下:Meanwhile, the above-mentioned desorption process is as follows:
a)、采用直接蒸汽通入活性炭吸附塔内,由蒸汽将活性炭吸附剂上的溶剂带出活性炭吸附塔,然后进行液化,以实现溶剂的回收;a), adopt direct steam to pass into the activated carbon adsorption tower, and the solvent on the activated carbon adsorbent is brought out of the activated carbon adsorption tower by steam, and then liquefies to realize the recovery of the solvent;
b)、向活性炭吸附塔内通入加热后的热空气,使得活性炭吸附剂快速干燥;b) Pass heated hot air into the activated carbon adsorption tower to dry the activated carbon adsorbent quickly;
c)、向活性炭吸附塔内通入冷却后的冷空气,使得活性炭吸附剂快速冷却,以恢复活性炭吸附剂的吸附能力。c), pass the cooled cold air into the activated carbon adsorption tower, so that the activated carbon adsorbent is rapidly cooled to restore the adsorption capacity of the activated carbon adsorbent.
以上对本发明做了详尽的描述,其目的在于让熟悉此领域技术的人士能够了解本发明的内容并加以实施,并不能以此限制本发明的保护范围,且本发明不限于上述的实施例,凡根据本发明的精神实质所作的等效变化或修饰,都应涵盖在本发明的保护范围。The present invention has been described in detail above, and its purpose is to enable those skilled in the art to understand the content of the present invention and implement it, and cannot limit the scope of protection of the present invention by this, and the present invention is not limited to the above-mentioned embodiments, All equivalent changes or modifications made according to the spirit of the present invention shall be included in the protection scope of the present invention.
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