CN109912758A - A kind of high-performance floor-cleaning machine water suction adhesive tape and preparation method thereof - Google Patents
A kind of high-performance floor-cleaning machine water suction adhesive tape and preparation method thereof Download PDFInfo
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- CN109912758A CN109912758A CN201711324206.XA CN201711324206A CN109912758A CN 109912758 A CN109912758 A CN 109912758A CN 201711324206 A CN201711324206 A CN 201711324206A CN 109912758 A CN109912758 A CN 109912758A
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- Prior art keywords
- adhesive tape
- antioxidant
- parts
- cleaning machine
- catalyst
- Prior art date
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- 239000002390 adhesive tape Substances 0.000 title claims abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 238000004140 cleaning Methods 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims description 11
- 239000003054 catalyst Substances 0.000 claims abstract description 34
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 23
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 22
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 239000012948 isocyanate Substances 0.000 claims abstract description 12
- 239000004014 plasticizer Substances 0.000 claims abstract description 12
- 239000004970 Chain extender Substances 0.000 claims abstract description 10
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 9
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000006096 absorbing agent Substances 0.000 claims description 17
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 15
- 238000005266 casting Methods 0.000 claims description 15
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 150000002148 esters Chemical class 0.000 claims description 11
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- HILAULICMJUOLK-UHFFFAOYSA-N 1,3-diethyl-5-methylbenzene Chemical compound CCC1=CC(C)=CC(CC)=C1 HILAULICMJUOLK-UHFFFAOYSA-N 0.000 claims description 6
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 6
- -1 phenylenedimethylidyne Chemical group 0.000 claims description 6
- 229920005862 polyol Polymers 0.000 claims description 6
- 150000003077 polyols Chemical class 0.000 claims description 6
- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 claims description 5
- 229940106691 bisphenol a Drugs 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 claims description 4
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 238000005520 cutting process Methods 0.000 claims description 4
- 230000018044 dehydration Effects 0.000 claims description 4
- 238000006297 dehydration reaction Methods 0.000 claims description 4
- 125000005442 diisocyanate group Chemical group 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- ZXHZWRZAWJVPIC-UHFFFAOYSA-N 1,2-diisocyanatonaphthalene Chemical compound C1=CC=CC2=C(N=C=O)C(N=C=O)=CC=C21 ZXHZWRZAWJVPIC-UHFFFAOYSA-N 0.000 claims description 3
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 claims description 3
- DHTGRDDBCWWKQJ-UHFFFAOYSA-N 2-(2,2-dihydroxyethoxy)ethane-1,1-diol Chemical compound OC(O)COCC(O)O DHTGRDDBCWWKQJ-UHFFFAOYSA-N 0.000 claims description 3
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 claims description 3
- HCILJBJJZALOAL-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)-n'-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyl]propanehydrazide Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 HCILJBJJZALOAL-UHFFFAOYSA-N 0.000 claims description 3
- YHHRETYFTSZELQ-UHFFFAOYSA-N 4-ethenoxyphenol Chemical class OC1=CC=C(OC=C)C=C1 YHHRETYFTSZELQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000005711 Benzoic acid Substances 0.000 claims description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 3
- UDSFAEKRVUSQDD-UHFFFAOYSA-N Dimethyl adipate Chemical compound COC(=O)CCCCC(=O)OC UDSFAEKRVUSQDD-UHFFFAOYSA-N 0.000 claims description 3
- OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 claims description 3
- INWVTRVMRQMCCM-UHFFFAOYSA-N N=C=O.N=C=O.C=1C=CC=CC=1C(C)(C)C1=CC=CC=C1 Chemical compound N=C=O.N=C=O.C=1C=CC=CC=1C(C)(C)C1=CC=CC=C1 INWVTRVMRQMCCM-UHFFFAOYSA-N 0.000 claims description 3
- CFXCGWWYIDZIMU-UHFFFAOYSA-N Octyl-3,5-di-tert-butyl-4-hydroxy-hydrocinnamate Chemical compound CCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 CFXCGWWYIDZIMU-UHFFFAOYSA-N 0.000 claims description 3
- 235000019482 Palm oil Nutrition 0.000 claims description 3
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 235000010233 benzoic acid Nutrition 0.000 claims description 3
- 235000010290 biphenyl Nutrition 0.000 claims description 3
- 239000004305 biphenyl Substances 0.000 claims description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 3
- 229910052797 bismuth Inorganic materials 0.000 claims description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 3
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims description 3
- 239000004359 castor oil Substances 0.000 claims description 3
- 235000019438 castor oil Nutrition 0.000 claims description 3
- 238000007334 copolymerization reaction Methods 0.000 claims description 3
- 229940100539 dibutyl adipate Drugs 0.000 claims description 3
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 claims description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- AYLRODJJLADBOB-QMMMGPOBSA-N methyl (2s)-2,6-diisocyanatohexanoate Chemical compound COC(=O)[C@@H](N=C=O)CCCCN=C=O AYLRODJJLADBOB-QMMMGPOBSA-N 0.000 claims description 3
- 150000002780 morpholines Chemical class 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002540 palm oil Substances 0.000 claims description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 3
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 3
- 150000004885 piperazines Chemical class 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 229920005906 polyester polyol Polymers 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 229910052704 radon Inorganic materials 0.000 claims description 3
- SYUHGPGVQRZVTB-UHFFFAOYSA-N radon atom Chemical compound [Rn] SYUHGPGVQRZVTB-UHFFFAOYSA-N 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 3
- 229940066771 systemic antihistamines piperazine derivative Drugs 0.000 claims description 3
- CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 claims description 2
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 claims description 2
- BEVJGIXXCOCLMC-UHFFFAOYSA-N 3-ethenoxyphenol Chemical class OC1=CC=CC(OC=C)=C1 BEVJGIXXCOCLMC-UHFFFAOYSA-N 0.000 claims description 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 2
- 230000002745 absorbent Effects 0.000 claims description 2
- 239000002250 absorbent Substances 0.000 claims description 2
- 150000004985 diamines Chemical class 0.000 claims description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 2
- 229940051250 hexylene glycol Drugs 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 229940100573 methylpropanediol Drugs 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims 2
- REMJYSCJWCSURO-UHFFFAOYSA-N CC(C)(C1=CC=CC=C1)C1=CC=CC=C1.N=C=O.N=C=O.N=C=O Chemical compound CC(C)(C1=CC=CC=C1)C1=CC=CC=C1.N=C=O.N=C=O.N=C=O REMJYSCJWCSURO-UHFFFAOYSA-N 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 claims 1
- 235000011037 adipic acid Nutrition 0.000 claims 1
- 239000001361 adipic acid Substances 0.000 claims 1
- HSUIVCLOAAJSRE-UHFFFAOYSA-N bis(2-methoxyethyl) benzene-1,2-dicarboxylate Chemical compound COCCOC(=O)C1=CC=CC=C1C(=O)OCCOC HSUIVCLOAAJSRE-UHFFFAOYSA-N 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 2
- 230000000845 anti-microbial effect Effects 0.000 abstract description 2
- 230000002708 enhancing effect Effects 0.000 abstract description 2
- 239000003344 environmental pollutant Substances 0.000 abstract 1
- 231100000719 pollutant Toxicity 0.000 abstract 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 3
- MILSYCKGLDDVLM-UHFFFAOYSA-N 2-phenylpropan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)C1=CC=CC=C1 MILSYCKGLDDVLM-UHFFFAOYSA-N 0.000 description 2
- BEJQXBXPRXFJDP-UHFFFAOYSA-N 3-(3,3-dihydroxypropoxy)propane-1,1-diol Chemical compound OC(O)CCOCCC(O)O BEJQXBXPRXFJDP-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- KPTLPIAOSCGETM-UHFFFAOYSA-N benzene 1,2-diisocyanatoethane Chemical compound O=C=NCCN=C=O.c1ccccc1 KPTLPIAOSCGETM-UHFFFAOYSA-N 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- DNXHEGUUPJUMQT-CBZIJGRNSA-N Estrone Chemical compound OC1=CC=C2[C@H]3CC[C@](C)(C(CC4)=O)[C@@H]4[C@@H]3CCC2=C1 DNXHEGUUPJUMQT-CBZIJGRNSA-N 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- GHMLBKRAJCXXBS-UHFFFAOYSA-N Resorcinol Natural products OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-N anhydrous cyanic acid Natural products OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- BSDQITJYKQHXQR-UHFFFAOYSA-N methyl prop-2-eneperoxoate Chemical compound COOC(=O)C=C BSDQITJYKQHXQR-UHFFFAOYSA-N 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of high-performance floor-cleaning machine water suction adhesive tape, it is characterized in that, being made of the raw material of following parts by weight: 100 parts of polyalcohol, 5-50 parts of isocyanates, 0.5-20 parts of chain extender, 5-50 parts of plasticizer, 0.5-30 parts of nano-titanium dioxide, 0.1-10 parts of catalyst, 0.1-10 parts of antioxidant, 0.1-10 parts of anti-UV agent.The present invention effectively avoids floor-cleaning machine water suction adhesive tape from occurring to be broken because of contacting with moisture and pollutant for a long time and fail using the nanometer enhancing of nano-titanium dioxide and antibacterial characteristics, the mechanical property and anti-microbial property of Lai Gaishan polyurethane-type water suction adhesive tape.
Description
Technical field
The present invention relates to Material Fields, and in particular to a kind of high-performance floor-cleaning machine water suction adhesive tape and preparation method thereof.
Background technique
The main function of floor-cleaning machine water suction adhesive tape is to cooperate the vacuum dehydration motor in floor-cleaning machine, with ground formation negative pressure
Chamber, the sewage before collecting and absorbing after brush cleaning on stand-down.Due to floor-cleaning machine water suction adhesive tape at work with ground
It rubs for a long time, floor-cleaning machine is higher to the mechanical property requirements of water suction adhesive tape, simultaneously because water suction adhesive tape long-time and water and powder
Dirt, greasy dirt, rubbish contact, absorb water adhesive tape surface bacterium easy to breed, goes mouldy, and leads to the adhesive tape fracture failure that absorbs water.
Summary of the invention
The purpose of the present invention is to solve the above problem, provides a kind of high-performance floor-cleaning machine water suction adhesive tape and its preparation side
Method, the adhesive tape have the characteristics that mechanical property is good, antibiotic property is excellent.
In order to achieve the above object, the present invention is achieved by the following technical solutions:
A kind of high-performance floor-cleaning machine water suction adhesive tape, which is characterized in that be made of the raw material of following parts by weight: polyalcohol 100
Part, 5-50 parts of isocyanates, 0.5-20 parts of chain extender, 5-50 parts of plasticizer, 0.5-30 parts of nano-titanium dioxide, catalyst 0.1-
10 parts, 0.1-10 parts of antioxidant, 0.1-10 parts of anti-UV agent.
Further, the polyalcohol includes molecular weight 300-8000, and the polyester polyol of degree of functionality 2-4, polyethers are more
It is first alcohol, polyolefin polyhydric alcohol, polyacrylate polyol, copolymerization ethoxylated polyhydric alcohol, castor oil polyhydric alcohol, palm oil polyalcohol, big
One of soya-bean oil polyalcohol or a variety of mixtures.
Further, the isocyanates includes toluene di-isocyanate(TDI), methyl diphenylene diisocyanate, liquefaction
MDI, hexamethylene diisocyanate, dicyclohexyl methyl hydride diisocyanate, naphthalene diisocyanate, paraphenylene diisocyanate, 1,
4- cyclohexane diisocyanate, benzene dimethylene diisocyanate, cyclohexanedimethyleterephthalate diisocyanate, trimethyl -1,6-
The different radon acid esters of hexa-methylene two, dimethyl diphenyl diisocyanate, Methylcyclohexyl diisocyanate, dimethyl diphenylmethane
One of triisocyanate, dimethyl diphenylmethane diisocyanate, lysine diisocyanate or a variety of mixtures.
Further, the chain extender includes 3,3 '-two chloro- 4,4 '-diphenylmethanediamiands, 3,5- dimethyl sulphur-based first
Phenylenediamine, 3,5- diethyl toluene diamine, ethylene glycol, butanediol, diglycol, propylene glycol, neopentyl glycol, methyl-prop two
Alcohol, hexylene glycol, Glycerin, glycerol, king's hydroxyl ethane, pentaerythrite, hydroquinone vinyl ethers, resorcinol vinyl
One of ether, bisphenol-A dihydroxyethyl ether, bisphenol-A dihydroxypropyl ether or a variety of mixtures.
Further, the plasticizer includes dioctyl phthalate, dibutyl phthalate, phthalic acid two
Methoxy acrylate, dimethyl adipate, adipic acid dibutyl ester, dibutyl adipate, dioctyl sebacate, benzoic acid glycol, phosphorus
One of acid ester plasticizer or a variety of mixtures.
Further, the nano-titanium dioxide includes the rutile-type and Detitanium-ore-type dioxy of partial size 0.1-1000nm
Change titanium powder.
Further, the catalyst includes amines catalyst, bridged piperazine derivatives catalyst, morpholine class catalyst, miaow
Zole derivatives catalyst, organotin catalysts, carboxylic acid potassium class catalyst, organozinc catalyst, organic bismuth catalyst, titanate ester
One of catalyst or a variety of compounds.
Further, the antioxidant includes antioxidant 245, antioxidant 1010, antioxidant 1035, antioxidant 1076,
One of antioxidant 1098, antioxidant 1135, antioxidant 1330, antioxidant 3114, antioxidant 1024, antioxidant 5057 are more
Kind compound.
Further, the anti-UV agent includes ultraviolet absorbing agent UV-1, ultraviolet absorbing agent UV-320, ultraviolet radiation absorption
Agent UV-326, ultraviolet absorbing agent UV-327, ultraviolet absorbing agent UV-328, ultraviolet absorbing agent UV-571, ultraviolet radiation absorption
One of agent UV-1130 or a variety of compounds.
A kind of preparation method of high-performance floor-cleaning machine water suction adhesive tape, which is characterized in that the described method comprises the following steps:
(1) prepared by performed polymer
Polyalcohol is added in reaction kettle, heats 100-130 DEG C, dehydration is vacuumized to moisture less than 0.03%, is added
Isocyanates reacts 0.5-5 hours at 30-100 DEG C of reaction temperature of control, obtains performed polymer；
(2) preparation for the adhesive tape that absorbs water
Above-mentioned performed polymer is added in casting machine A tank, then by chain extender, plasticizer, antioxidant, anti-UV agent, catalysis
Agent is proportionally added into casting machine B tank, is opened A, B tank respectively and is opened the heating of A, B tank again after mixing evenly, reaches material temperature
70-100℃；A, B tank discharging ratio are set, casting machine casting is opened, casting machine discharging is added to the gold of 50-130 DEG C of temperature
Belong in mold, keep the temperature shaping and demoulding after 0.5-2h, then the product after demoulding is placed into room temperature environment and is vulcanized 1-15 days, passes through
Cross that guillotine or cutting machine are cut, deburring absorbs water adhesive tape to get to high-performance floor-cleaning machine.
The beneficial effects of the present invention are: the present invention utilizes the nanometer enhancing of nano-titanium dioxide and antibacterial characteristics, Lai Gaishan
Polyurethane-type absorb water adhesive tape mechanical property and anti-microbial property, effectively avoid floor-cleaning machine water suction adhesive tape because for a long time with moisture and dirt
It contaminates object contact and fracture and failure occurs.
Specific embodiment
Technical solution of the present invention is clearly and completely described below in conjunction with embodiment, it is clear that described reality
Applying example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is general
Logical technical staff every other embodiment obtained without creative efforts belongs to what the present invention protected
Range.
A kind of high-performance floor-cleaning machine water suction adhesive tape, which is characterized in that be made of the raw material of following parts by weight: polyalcohol 100
Part, resists 25 parts of isocyanates, 10 parts of chain extender, 15 parts of plasticizer, 18 parts of nano-titanium dioxide, 5 parts of catalyst, 5 parts of antioxidant
5 parts of UV agent.
The polyalcohol includes molecular weight 300-8000, the polyester polyol of degree of functionality 2-4, polyether polyol, polyene
Hydrocarbon polyalcohol, polyacrylate polyol, copolymerization ethoxylated polyhydric alcohol, castor oil polyhydric alcohol, palm oil polyalcohol, soybean oil polyol
One of or a variety of mixtures.
The isocyanates includes toluene di-isocyanate(TDI), methyl diphenylene diisocyanate, liquefied mdi, six methylenes
Group diisocyanate, dicyclohexyl methyl hydride diisocyanate, naphthalene diisocyanate, paraphenylene diisocyanate, 1,4- hexamethylene two
Isocyanates, benzene dimethylene diisocyanate, cyclohexanedimethyleterephthalate diisocyanate, trimethyl -1,6- hexa-methylene two
Different radon acid esters, dimethyl diphenyl diisocyanate, Methylcyclohexyl diisocyanate, three isocyanic acid of dimethyl diphenylmethane
One of ester, dimethyl diphenylmethane diisocyanate, lysine diisocyanate or a variety of mixtures.
The chain extender includes 3,3 '-two chloro- 4,4 '-diphenylmethanediamiands, 3,5- dimethythiotoluene diamine, 3,
5- diethyl toluene diamine, ethylene glycol, butanediol, diglycol, propylene glycol, neopentyl glycol, methyl propanediol, oneself two
Alcohol, Glycerin, glycerol, king's hydroxyl ethane, pentaerythrite, hydroquinone vinyl ethers, resorcinol vinyl ethers, bis-phenol
One of A dihydroxyethyl ether, bisphenol-A dihydroxypropyl ether or a variety of mixtures.
The plasticizer includes dioctyl phthalate, dibutyl phthalate, phthalic acid dimethoxy second
Ester, dimethyl adipate, adipic acid dibutyl ester, dibutyl adipate, dioctyl sebacate, benzoic acid glycol, phosphate plasticising
One of agent or a variety of mixtures.
The nano-titanium dioxide includes the rutile-type and anatase titanium dioxide powder of partial size 0.1-1000nm.
The catalyst includes that amines catalyst, bridged piperazine derivatives catalyst, morpholine class catalyst, imdazole derivatives are urged
Agent, organotin catalysts, carboxylic acid potassium class catalyst, organozinc catalyst, organic bismuth catalyst, in titanate ester catalyst
One or more compounds.
The antioxidant includes antioxidant 245, antioxidant 1010, antioxidant 1035, antioxidant 1076, antioxidant
1098, one of antioxidant 1135, antioxidant 1330, antioxidant 3114, antioxidant 1024, antioxidant 5057 or a variety of compound
Object.
The anti-UV agent include ultraviolet absorbing agent UV-1, ultraviolet absorbing agent UV-320, ultraviolet absorbent uv-326,
Ultraviolet absorbing agent UV-327, ultraviolet absorbing agent UV-328, ultraviolet absorbing agent UV-571, ultraviolet absorbing agent UV-1130
One of or a variety of compounds.
A kind of preparation method of high-performance floor-cleaning machine water suction adhesive tape, which is characterized in that the described method comprises the following steps:
(1) prepared by performed polymer
Polyalcohol is added in reaction kettle, heats 120 DEG C, dehydration is vacuumized to moisture less than 0.03%, isocyanide is added
Acid esters reacts 4 hours at 70 DEG C of reaction temperature of control, obtains performed polymer；
(2) preparation for the adhesive tape that absorbs water
Above-mentioned performed polymer is added in casting machine A tank, then by chain extender, plasticizer, antioxidant, anti-UV agent, catalysis
Agent is proportionally added into casting machine B tank, is opened A, B tank respectively and is opened the heating of A, B tank again after mixing evenly, material temperature is made to reach 80
℃；A, B tank discharging ratio are set, casting machine casting is opened, casting machine discharging is added in the metal die of 90 DEG C of temperature, is protected
Then product after demoulding is placed into room temperature environment and vulcanizes 8 days, by guillotine or cutting by shaping and demoulding after warm 1.5h
Machine cut, deburring to get to high-performance floor-cleaning machine absorb water adhesive tape.
According to the adhesive tape that above-mentioned formula and preparation method manufacture, by test, properties and polyurethane adhesive tape is not improved
It compares, data are as shown in the table:
Can be seen that high-performance adhesive tape of the present invention performances more various than traditional adhesive tape from obtained Experimental comparison's data has
Very big promotion.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (10)
- The adhesive tape 1. a kind of high-performance floor-cleaning machine absorbs water, which is characterized in that be made of the raw material of following parts by weight: 100 parts of polyalcohol, 5-50 parts of isocyanates, 0.5-20 parts of chain extender, 5-50 parts of plasticizer, 0.5-30 parts of nano-titanium dioxide, catalyst 0.1-10 Part, 0.1-10 parts of antioxidant, 0.1-10 parts of anti-UV agent.
- The adhesive tape 2. a kind of high-performance floor-cleaning machine according to claim 1 absorbs water, it is characterised in that: the polyalcohol includes Molecular weight 300-8000, the polyester polyol of degree of functionality 2-4, polyether polyol, polyolefin polyhydric alcohol, polyacrylate are polynary One of alcohol, copolymerization ethoxylated polyhydric alcohol, castor oil polyhydric alcohol, palm oil polyalcohol, soybean oil polyol or a variety of mixtures.
- The adhesive tape 3. a kind of high-performance floor-cleaning machine according to claim 1 absorbs water, it is characterised in that: the isocyanates packet Include toluene di-isocyanate(TDI), methyl diphenylene diisocyanate, liquefied mdi, hexamethylene diisocyanate, dicyclohexyl methyl hydride Diisocyanate, naphthalene diisocyanate, paraphenylene diisocyanate, 1,4- cyclohexane diisocyanate, two isocyanide of phenylenedimethylidyne Acid esters, cyclohexanedimethyleterephthalate diisocyanate, the different radon acid esters of trimethyl -1,6- hexa-methylene two, two isocyanide of dimethyl diphenyl Acid esters, Methylcyclohexyl diisocyanate, dimethyl diphenylmethane triisocyanate, dimethyl diphenylmethane diisocyanate One of ester, lysine diisocyanate or a variety of mixtures.
- The adhesive tape 4. a kind of high-performance floor-cleaning machine according to claim 1 absorbs water, it is characterised in that: the chain extender includes 3,3 '-two chloro- 4,4 '-diphenylmethanediamiands, 3,5- dimethythiotoluene diamine, 3,5- diethyl toluene diamine, ethylene glycol, Butanediol, diglycol, propylene glycol, neopentyl glycol, methyl propanediol, hexylene glycol, Glycerin, glycerol, king's hydroxyl Ethane, pentaerythrite, hydroquinone vinyl ethers, resorcinol vinyl ethers, bisphenol-A dihydroxyethyl ether, bisphenol-A dihydroxypropyl One of ether or a variety of mixtures.
- The adhesive tape 5. a kind of high-performance floor-cleaning machine according to claim 1 absorbs water, it is characterised in that: the plasticizer includes neighbour Dioctyl phthalate, dibutyl phthalate, dimethoxyethyl phthalate, dimethyl adipate, adipic acid two One of pungent rouge, dibutyl adipate, dioctyl sebacate, benzoic acid glycol, phosphate plasticizer or a variety of mixtures.
- The adhesive tape 6. a kind of high-performance floor-cleaning machine according to claim 1 absorbs water, it is characterised in that: the nanometer titanium dioxide Titanium includes the rutile-type and anatase titanium dioxide powder of partial size 0.1-1000nm.
- The adhesive tape 7. a kind of high-performance floor-cleaning machine according to claim 1 absorbs water, it is characterised in that: the catalyst includes Amines catalyst, bridged piperazine derivatives catalyst, morpholine class catalyst, imdazole derivatives catalyst, organotin catalysts, carboxylic acid potassium One of class catalyst, organozinc catalyst, organic bismuth catalyst, titanate ester catalyst or a variety of compounds.
- The adhesive tape 8. a kind of high-performance floor-cleaning machine according to claim 1 absorbs water, it is characterised in that: the antioxidant includes Antioxidant 245, antioxidant 1010, antioxidant 1035, antioxidant 1076, antioxidant 1098, antioxidant 1135, antioxidant 1330, One of antioxidant 3114, antioxidant 1024, antioxidant 5057 or a variety of compounds.
- The adhesive tape 9. a kind of high-performance floor-cleaning machine according to claim 1 absorbs water, it is characterised in that: the anti-UV agent includes purple It is ultraviolet absorbers UV-1, ultraviolet absorbing agent UV-320, ultraviolet absorbent uv-326, ultraviolet absorbing agent UV-327, ultraviolet One of light absorbers UV-328, ultraviolet absorbing agent UV-571, ultraviolet absorbing agent UV-1130 or a variety of compounds.
- 10. a kind of preparation method of high-performance floor-cleaning machine water suction adhesive tape, which is characterized in that the described method comprises the following steps:(1) prepared by performed polymerPolyalcohol is added in reaction kettle, heats 100-130 DEG C, dehydration is vacuumized to moisture less than 0.03%, isocyanide is added Acid esters reacts 0.5-5 hours at 30-100 DEG C of reaction temperature of control, obtains performed polymer；(2) preparation for the adhesive tape that absorbs waterAbove-mentioned performed polymer is added in casting machine A tank, is then pressed chain extender, plasticizer, antioxidant, anti-UV agent, catalyst Ratio is added in casting machine B tank, is opened A, B tank respectively and is opened the heating of A, B tank again after mixing evenly, material temperature is made to reach 70-100 ℃；A, B tank discharging ratio are set, casting machine casting is opened, casting machine discharging is added to the metal die of 50-130 DEG C of temperature It is interior, shaping and demoulding after 0.5-2h is kept the temperature, then the product after demoulding is placed into room temperature environment and is vulcanized 1-15 days, by cutting Machine or cutting machine cut, deburring absorbs water adhesive tape to get to high-performance floor-cleaning machine.
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