CN109911911A - A kind of method of whitening and talcum of impure talcum mud - Google Patents
A kind of method of whitening and talcum of impure talcum mud Download PDFInfo
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- CN109911911A CN109911911A CN201910288308.3A CN201910288308A CN109911911A CN 109911911 A CN109911911 A CN 109911911A CN 201910288308 A CN201910288308 A CN 201910288308A CN 109911911 A CN109911911 A CN 109911911A
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- talcum
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- 235000012222 talc Nutrition 0.000 title claims abstract description 89
- 239000000454 talc Substances 0.000 title claims abstract description 87
- 229910052623 talc Inorganic materials 0.000 title claims abstract description 87
- 238000000034 method Methods 0.000 title claims abstract description 31
- 230000002087 whitening effect Effects 0.000 title claims abstract description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 67
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 14
- 229920002907 Guar gum Polymers 0.000 claims abstract description 10
- 239000000665 guar gum Substances 0.000 claims abstract description 10
- 229960002154 guar gum Drugs 0.000 claims abstract description 10
- 235000010417 guar gum Nutrition 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 10
- 239000013049 sediment Substances 0.000 claims abstract description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical class O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 3
- 239000007787 solid Substances 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 3
- RYYXDZDBXNUPOG-UHFFFAOYSA-N 4,5,6,7-tetrahydro-1,3-benzothiazole-2,6-diamine;dihydrochloride Chemical compound Cl.Cl.C1C(N)CCC2=C1SC(N)=N2 RYYXDZDBXNUPOG-UHFFFAOYSA-N 0.000 claims description 15
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 15
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 15
- 239000005708 Sodium hypochlorite Substances 0.000 claims description 15
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 15
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 15
- 238000001354 calcination Methods 0.000 claims description 9
- 239000011550 stock solution Substances 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 239000003153 chemical reaction reagent Substances 0.000 claims description 4
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims 2
- 241000790917 Dioxys <bee> Species 0.000 claims 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 239000002002 slurry Substances 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 22
- 239000011707 mineral Substances 0.000 abstract description 22
- 238000004061 bleaching Methods 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 6
- 239000003814 drug Substances 0.000 abstract description 5
- 238000000746 purification Methods 0.000 abstract description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 24
- 229910052742 iron Inorganic materials 0.000 description 13
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- -1 iron ion Chemical class 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000011085 pressure filtration Methods 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910001608 iron mineral Inorganic materials 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 238000007885 magnetic separation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229910052683 pyrite Inorganic materials 0.000 description 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
- 239000011028 pyrite Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
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- Cosmetics (AREA)
Abstract
The present invention provides the method for whitening and talcum of a kind of impure talcum mud, are related to mineral purification technique field, to promote talcum (talcum mud) whiteness of impure yellow mud.Method obtains being stirred ore pulp comprising steps of S1, at least calgon, sodium hydroxide, guar gum are added in the ore pulp of impure talcum mud and stir;S2, the above-mentioned ore pulp that is stirred is staticly settled, obtains sediment;S3, the sediment is washed into 2 to 3 times heel row solid carbon dioxides with clear water get talcum.Talcum is prepared using the above method.The method of whitening of impure talcum mud of the invention, breach the technical bottleneck that original chemical bleaching can not brighten the talcum (talcum mud) of impure yellow mud, low-grade, rich reserves talcums (talcum mud) are purified as high-grade talcum (talcum mud) using medicament, the added value of mineral products is improved, there is huge market value.
Description
[technical field]
The present invention relates to mineral purification technique field, the especially a kind of method of whitening and talcum of impure talcum mud.
[background technique]
With the rapid development of social economy, talcum is widely used to papermaking, ceramics, plastics, paint, cosmetics, electricity
A industrial department of cable, pesticide etc. more than 30 proposes increasingly higher demands to the purity and whiteness of talcum (talcum mud) both at home and abroad.
Although the talcum in China finds out that resource reserve is larger, but talcum (talcum mud) resource of high-quality high-grade is fewer and fewer, this kind of
Talcum accounts for Chinese talc total output less than 20%.Liaoning, Shandong, the big place of production in Guangxi three will all enter dry spells at present.Mainly
Reason: first is that part Medium and smaller mines pass through the exploitation of many years, resource is exhausted;Second is that with development in science and technology, especially newly
The application field of the rise of material industry, China top grade talcum resource is constantly widened.
High-order talcum enumerated with the index parameter of low-grade talcum in table 1 come compared with facilitating.
1 talcum of table (talcum mud) index parameter
Low-grade talcum reserves are very big, therefore have the purification of low-grade talcum with huge economic value.
General mineral method of whitening is physics except brightening after iron or chemical bleaching method brightens, and physics mainly passes through except iron
High-gradient magnetic separation machine equipment is carried out except iron, and chemical bleaching, which mainly passes through medicament, carries out iron ion complexing except iron.At present this two
Kind method: one, physics is bleached except iron can only remove Armco magnetic iron mineral, and be mingled in most talcum (talcum mud) at present
The very high yellow mud of iron-content, for the iron dust in this yellow mud in nonmagnetic iron, magnetic plant can not carry out de_ironing refinement, while general
Pyrite containing part in talcum (talcum mud), this part iron can not equally be screened by magnetic plant, simultaneously for
The concentration of crude ore pulp requires, and it is lower that this allows for specific yield;Two, chemical bleaching method brightens, mainly by will be in mineral
Iron ion complexing after be discharged again with solution, chemical bleaching for pulp density require it is not high, can be mass-produced, but chemistry
Bleaching is equally faced with impure yellow mud in existing talcum (talcum mud), and the iron ion in yellow mud is present in lattice, if not
Yellow mud is discharged in advance, then mineral can not be bleached.
[summary of the invention]
The present invention provides the method for whitening and talcum of a kind of impure talcum mud, to by the talcum of impure yellow mud
(talcum mud) whiteness is promoted.
A kind of method of whitening of impure talcum mud of the invention, comprising steps of S1, at least by calgon, hydrogen-oxygen
Change sodium, guar gum are added in the ore pulp of impure talcum mud and stir, and obtain being stirred ore pulp;S2, it is stirred above-mentioned
Ore pulp staticly settles, and obtains sediment;S3, the sediment is washed into 2 to 3 times heel row solid carbon dioxides with clear water get talcum.
Further, also thiourea dioxide, sodium hypochlorite, disodium ethylene diamine tetraacetate are added containing miscellaneous in the step S1
In the ore pulp of matter talcum mud.
Preferably, step is specifically included in step S1: calgon, sodium hydroxide, guar gum being added impure
It is stirred in the ore pulp of talcum mud;It is added in aqueous solution thiourea dioxide, sodium hydroxide to obtain stock solution;By sodium hypochlorite
Stirring in ore pulp is added to stock solution and adds disodium ethylene diamine tetraacetate, obtains being stirred ore pulp.
Preferably, step is specifically included in step S1: specifically including step in step S1: by calgon, hydroxide
Sodium, guar gum are added in the ore pulp of impure talcum mud and stir;Impure talcum is added in thiourea dioxide and sodium hydroxide
It is stirred in the ore pulp of mud, adds sodium hypochlorite and disodium ethylene diamine tetraacetate.
Specifically, the mass parts that chemical reagent is added are as follows: using calgon 0.1wt%-5wt%, sodium hydroxide
0.1wt%-5wt%, disodium ethylene diamine tetraacetate 0.1wt%-5wt%, thiourea dioxide 0.1wt%-5wt%, sodium hypochlorite
0.1wt%-5wt%.
Specifically, the purity that chemical reagent is added is as follows: the content of the calgon is containing for 99%, sodium hydroxide
Measure 99%, the content 99% of disodium ethylene diamine tetraacetate, the content of thiourea dioxide 99%, the content of sodium hypochlorite 10%.
Specifically, treated, talcum flexural strength is 3MPa.
Specifically, treated, talcum calcining whiteness is 89-91, and the flow velocity of calcination of talc is in 22s-27s.
A kind of talcum of the invention, is prepared using the above method.
The method of whitening of impure talcum mud of the invention, breaches original chemical bleaching for the cunning of impure yellow mud
The technical bottleneck that stone (talcum mud) can not brighten is purified low-grade, rich reserves talcums (talcum mud) for height using medicament
The talcum (talcum mud) of grade, improves the added value of mineral products, has huge market value.
[Detailed description of the invention]
Fig. 1 is the method flow diagram of the embodiment of the present invention 1;
Fig. 2 is the method flow diagram of the embodiment of the present invention 2;
Fig. 3 is the method flow diagram of the embodiment of the present invention 3.
[specific embodiment]
It is described in detail by the following examples.
Embodiment 1, the present embodiment a kind of impure yellow mud talcum (talcum mud) method of whitening, the inclined phosphorus of the six of use
The content of sour sodium is that the 99%, content 99% of sodium hydroxide, the content of disodium ethylene diamine tetraacetate 99%, thiourea dioxide contain
Amount 99%, the content 10% of sodium hypochlorite, comprising the following steps:
S101: mineral pretreatment: by 1000kg mineral it is agitated at mud after, calgon, the 10kg of 50kg is added
Sodium hydroxide, the stirring of 3kg guar gum precipitate and obtain pretreatment mud after yellow mud is discharged;
S102: 10kg thiourea dioxide and 10kg sodium hydroxide medicament pretreatment: are prepared into aqueous solution as spare;
S103: mineral processing: prepared stock solution in 100kg sodium hypochlorite and step 2 is added in ore pulp
It stirs and 5kg disodium ethylene diamine tetraacetate is added;
S104: pressure filtration molding: ore pulp is drained using filter press, obtains required mineral, i.e. talcum.
The mineralogical property index of acquisition are as follows: plasticity, flexural strength 3MPa, iron content 0.2%-0.3%:
Performance indicator after the calcination of minerals of acquisition are as follows: calcining whiteness 89-91, flow velocity 22s-26s.
Embodiment 2, the present embodiment a kind of impure yellow mud talcum (talcum mud) method of whitening, the inclined phosphorus of the six of use
The content of sour sodium is that the 99%, content 99% of sodium hydroxide, the content of disodium ethylene diamine tetraacetate 99%, thiourea dioxide contain
Amount 99%, the content 10% of sodium hypochlorite, comprising the following steps:
S201: mineral pretreatment: by 1000kg mineral it is agitated at mud after, calgon, the 10kg of 30kg is added
Sodium hydroxide, the stirring of 2kg guar gum precipitate and obtain pretreatment mud after yellow mud is discharged;
S202: 8kg thiourea dioxide and 8kg sodium hydroxide medicament pretreatment: are prepared into aqueous solution as spare;
S203: mineral processing: prepared stock solution in 50kg sodium hypochlorite and step 2 is added in ore pulp
It stirs and 3kg disodium ethylene diamine tetraacetate is added;
S204: pressure filtration molding: ore pulp is drained using filter press, obtains required mineral, i.e. talcum.
The mineralogical property index of acquisition are as follows: plasticity, flexural strength 3MPa, iron content 0.2%-0.3%:
Performance indicator after the calcination of minerals of acquisition are as follows: calcining whiteness 89-91, flow velocity 23s-26s.
Embodiment 3, the present embodiment a kind of impure yellow mud talcum (talcum mud) method of whitening, the inclined phosphorus of the six of use
The content of sour sodium is that the 99%, content 99% of sodium hydroxide, the content of disodium ethylene diamine tetraacetate 99%, thiourea dioxide contain
Amount 99%, the content 10% of sodium hypochlorite, comprising the following steps:
S301: mineral pretreatment: by 1000kg mineral it is agitated at mud after, calgon, the 10kg of 30kg is added
Sodium hydroxide, the stirring of 2kg guar gum precipitate and obtain pretreatment mud after yellow mud is discharged;
S302: mineral processing: 8kg thiourea dioxide being added in ore pulp with 8kg sodium hydroxide and is stirred, and is added 50kg times
Sodium chlorate and 3kg disodium ethylene diamine tetraacetate;
S303 pressure filtration molding: ore pulp is drained using filter press, obtains required mineral, i.e. talcum.
The mineralogical property index of acquisition are as follows: plasticity, flexural strength 3MPa, iron content 0.2%-0.35%;
Performance indicator after the calcination of minerals of acquisition are as follows: calcining whiteness 89-91, flow velocity 22s-27s.
Here description of the invention and application are all only illustrative and exemplary, are not intended to the scope of the present invention
Limitation is in the above-described embodiments.The deformation and change of embodiments disclosed herein be it is entirely possible, for those this fields
Those of ordinary skill for, embodiment replacement and equivalent various parts be well known.Those skilled in the art also answer
Should it is clear that without departing from the spirit or essential characteristics of the invention, the present invention can in other forms, structure,
Arrangement, ratio, and realized with other components, material and component, and the case where not departing from scope and spirit of the present invention
Under, other deformations and change can be carried out to embodiments disclosed herein.
Claims (9)
1. a kind of method of whitening of impure talcum mud, which is characterized in that comprising steps of
S1, at least calgon, sodium hydroxide, guar gum are added in the ore pulp of impure talcum mud and stirred, stirred
Mix mixed ore pulp;
S2, the above-mentioned ore pulp that is stirred is staticly settled, obtains sediment;
S3, the sediment is washed into 2 to 3 times heel row solid carbon dioxides with clear water get talcum.
2. the method for whitening of impure talcum mud as described in claim 1, which is characterized in that also by dioxy in the step S1
Change thiocarbamide, sodium hypochlorite, disodium ethylene diamine tetraacetate to be added in the ore pulp of impure talcum mud.
3. the method for whitening of impure talcum mud as claimed in claim 2, which is characterized in that specifically include step in step S1
It is rapid:
Calgon, sodium hydroxide, guar gum are added in the ore pulp of impure talcum mud and are stirred;
It is added in aqueous solution thiourea dioxide, sodium hydroxide to obtain stock solution;
Sodium hypochlorite and stock solution are added to stirring in ore pulp and add disodium ethylene diamine tetraacetate, obtains being stirred mine
Slurry.
4. the method for whitening of impure talcum mud as claimed in claim 2, which is characterized in that specifically include step in step S1
It is rapid:
Calgon, sodium hydroxide, guar gum are added in the ore pulp of impure talcum mud and are stirred;
Thiourea dioxide is added in the ore pulp of impure talcum mud with sodium hydroxide and is stirred, sodium hypochlorite and ethylenediamine are added
Tetraacethyl disodium.
5. the method for whitening of the impure talcum mud as described in claim 2,3 or 4, which is characterized in that chemical reagent is added
Mass parts are as follows: using calgon 0.1wt%-5wt%, sodium hydroxide 0.1wt%-5wt%, disodium ethylene diamine tetraacetate
0.1wt%-5wt%, thiourea dioxide 0.1wt%-5wt%, sodium hypochlorite 0.1wt%-5wt%.
6. the method for whitening of the impure talcum mud as described in claim 2,3 or 4, which is characterized in that chemical reagent is added
Purity is as follows: the content of the calgon is 99%, the content 99% of sodium hydroxide, the content of disodium ethylene diamine tetraacetate
99%, the content 99%, the content of sodium hypochlorite 10% of thiourea dioxide.
7. the method for whitening of impure talcum mud as described in claim 1, which is characterized in that treated talcum flexural strength
For 3MPa.
8. the method for whitening of impure talcum mud as described in claim 1, which is characterized in that treated, and talcum calcines whiteness
For 89-91, and the flow velocity of calcination of talc is in 22s-27s.
9. a kind of talcum, which is characterized in that be prepared using the method for any one of the claims 1 to 8.
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WO1998008585A1 (en) * | 1996-08-26 | 1998-03-05 | Geochem Technologies, Inc. | Leaching of metal chalcogenide (sulfide-type) minerals with oxidizing and chelating agents |
CN1544535A (en) * | 2003-11-11 | 2004-11-10 | 赵路军 | Method for purifying and whitening calcium carbonate |
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CN101602898A (en) * | 2009-07-24 | 2009-12-16 | 厦门大学 | Whitening method for washing iron-dyed kaolin |
CN106563576A (en) * | 2016-10-27 | 2017-04-19 | 江西理工大学 | Method for flotation separation of chalcopyrite and talc by using locust bean gum |
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-
2019
- 2019-04-11 CN CN201910288308.3A patent/CN109911911A/en active Pending
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WO1998008585A1 (en) * | 1996-08-26 | 1998-03-05 | Geochem Technologies, Inc. | Leaching of metal chalcogenide (sulfide-type) minerals with oxidizing and chelating agents |
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