CN1099047A - Compositions of ultraviolet curing type - Google Patents
Compositions of ultraviolet curing type Download PDFInfo
- Publication number
- CN1099047A CN1099047A CN 94107281 CN94107281A CN1099047A CN 1099047 A CN1099047 A CN 1099047A CN 94107281 CN94107281 CN 94107281 CN 94107281 A CN94107281 A CN 94107281A CN 1099047 A CN1099047 A CN 1099047A
- Authority
- CN
- China
- Prior art keywords
- acrylate
- composition
- monomer
- methyl
- double methacrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 30
- 239000000178 monomer Substances 0.000 claims abstract description 23
- -1 (methyl) Hydroxyethyl Chemical group 0.000 claims description 20
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 20
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 6
- 230000001588 bifunctional effect Effects 0.000 claims description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 4
- 230000000694 effects Effects 0.000 claims description 4
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 4
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 claims description 3
- GZBSIABKXVPBFY-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)CO GZBSIABKXVPBFY-UHFFFAOYSA-N 0.000 claims description 3
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 3
- 238000007865 diluting Methods 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- VETIYACESIPJSO-UHFFFAOYSA-N 2-[2-(2-hydroxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound OCCOCCOCCOC(=O)C=C VETIYACESIPJSO-UHFFFAOYSA-N 0.000 claims description 2
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims description 2
- UHFFVFAKEGKNAQ-UHFFFAOYSA-N 2-benzyl-2-(dimethylamino)-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=CC=C1 UHFFVFAKEGKNAQ-UHFFFAOYSA-N 0.000 claims description 2
- NLGDWWCZQDIASO-UHFFFAOYSA-N 2-hydroxy-1-(7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-yl)-2-phenylethanone Chemical compound OC(C(=O)c1cccc2Oc12)c1ccccc1 NLGDWWCZQDIASO-UHFFFAOYSA-N 0.000 claims description 2
- LWRBVKNFOYUCNP-UHFFFAOYSA-N 2-methyl-1-(4-methylsulfanylphenyl)-2-morpholin-4-ylpropan-1-one Chemical compound C1=CC(SC)=CC=C1C(=O)C(C)(C)N1CCOCC1 LWRBVKNFOYUCNP-UHFFFAOYSA-N 0.000 claims description 2
- RIWRBSMFKVOJMN-UHFFFAOYSA-N 2-methyl-1-phenylpropan-2-ol Chemical compound CC(C)(O)CC1=CC=CC=C1 RIWRBSMFKVOJMN-UHFFFAOYSA-N 0.000 claims description 2
- QXIQCNFSNJEMOD-UHFFFAOYSA-N 3-hydroxybutan-2-yl prop-2-enoate Chemical compound CC(O)C(C)OC(=O)C=C QXIQCNFSNJEMOD-UHFFFAOYSA-N 0.000 claims description 2
- RYAIMSPHUVXLQI-UHFFFAOYSA-N 4-(aminomethyl)-2-(benzotriazol-2-yl)phenol Chemical compound NCC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 RYAIMSPHUVXLQI-UHFFFAOYSA-N 0.000 claims description 2
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- 239000004258 Ethoxyquin Substances 0.000 claims description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 2
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical group C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 claims description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 2
- 239000012965 benzophenone Substances 0.000 claims description 2
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 claims description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 2
- 229940093500 ethoxyquin Drugs 0.000 claims description 2
- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 claims description 2
- 235000019285 ethoxyquin Nutrition 0.000 claims description 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 2
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims description 2
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 claims description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 239000011521 glass Substances 0.000 abstract description 6
- 239000000758 substrate Substances 0.000 abstract description 4
- 239000004744 fabric Substances 0.000 abstract description 3
- 229920003023 plastic Polymers 0.000 abstract description 3
- 239000004033 plastic Substances 0.000 abstract description 3
- 239000010985 leather Substances 0.000 abstract description 2
- 239000003085 diluting agent Substances 0.000 abstract 1
- 229920000058 polyacrylate Polymers 0.000 abstract 1
- 239000012752 auxiliary agent Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000010076 replication Effects 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
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- Macromonomer-Based Addition Polymer (AREA)
Abstract
The ultraviolet-ray solidified composition is made of polyacrylate, active diluent monomer, opticalt rigger and other assistants. The composition is used to copy relief-style hologram onto glass, plastics, leather and fabrics to show colour and stereo pattern on substrate.
Description
The invention relates to a kind of compositions of ultraviolet curing type, said composition can make the relief type hologram replication on substrates such as glass, plastics, leather and fabric, thereby makes these substrates have splendid color or solid pattern.
Photocurable composition of the prior art is two-pack normally, light curing agent wherein (or light trigger) goes in the matrix resin owing to be matrix resin and light curing agent two components to be mixed use by a certain amount of joining before use as another component, so mixing uniformity directly affects the quality of product.And generally be difficult for mixing; Aforementioned body resin and light curing agent can not be put after mixing for a long time in addition, otherwise can be not easy to operate because of curing; Be exactly to influence quality product because two component blended " criticize " different in addition, in a word, Photocurable composition of the prior art is extremely inconvenient in use, is unsuitable for suitability for industrialized production.
The invention provides a kind of compositions of ultraviolet curing type of single component, said composition has overcome deficiency of the prior art, and is easy to use, period of storage is long, laser curing velocity is fast, can enhance productivity.
The composition of compositions of ultraviolet curing type of the present invention and weight percent are:
A. polymeric acrylate 10～60%
B. the rare monomer 20～80% of active alkene
C. light trigger 0.5～10%
Above-mentioned composition also can comprise other auxiliary agents, and as stopper, photostabilizer etc., the weight ratio of these auxiliary agents is lower than 10% of composition total weight.
A. polymeric acrylate:
Polymeric acrylate is the most important component of compositions of ultraviolet curing type, and the final performance of decision product is as intensity, wear resistance etc.Spendable polymeric acrylate comprises: Synolac acrylate, polyester acrylate, polyether acrylate, bisphenol A epoxy acrylate, phenolic aldehyde acrylate and/or urethane acrylate, wherein urethane acrylate and/or polyester acrylate are preferred.
B. activity diluting monomer:
The molecular weight of polymeric acrylate is generally all bigger, very thickness, be difficult for to flow, thereby the reactive monomer that must add small molecular weight regulates viscosity, with the satisfied requirement that is coated with, improves the hardness, flexibility of material etc.
The activity diluting monomer that is adopted comprises simple function group monomer, bifunctional monomer and/or polyfunctional monomer.Though, can cause material brittle because polyfunctional monomer can increase the intensity of cross-linking set, increase material; And single, double monomer's cross-linking set is few, a little less than the rigidity, therefore should regulate each monomeric ratio as required.
Described simple function group monomer comprises: (methyl) Hydroxyethyl acrylate, (methyl) Propylene glycol monoacrylate, (methyl) butyl acrylate, (methyl) Isooctyl acrylate monomer, (methyl) vinylformic acid tetrahydrofuran ester, (methyl) vinylformic acid norborneol ester, N-vinyl pyrrolidone, acrylamide and/or vinyl acetate etc.
Described bifunctional monomer comprises: a condensed ethandiol double methacrylate, tirethylene glycol double methacrylate, triethylene Glycol acrylate, four condensed ethandiol acrylate, 1,4-butyleneglycol double methacrylate, neopentyl glycol double methacrylate, 1,6-hexylene glycol double methacrylate, Phthalic acid, diallyl ester and/or phthalic acid one condensed ethandiol double methacrylate etc.
Described polyfunctional monomer comprises: Viscoat 295, pentaerythritol triacrylate, tetramethylol methane tetraacrylate, Dipentaerythritol five acrylate and/or ethoxyquin tri methylol alkane triacrylate etc.
C. light trigger:
Only under the light trigger existence condition, polymeric acrylate could react with reactive monomer generation cross-linking chemistry under action of ultraviolet light.Initiator by cracking or hydrogen abstraction reaction, produces free radical, the polymerization of trigger monomer under the irradiation of light.Spendable initiator comprises: benzophenone, dibenzoyl, benzoin ether, Michler's keton, thioxanthone, Irgacure 184, Irgacure 500, Irgacure 907, Irgacure 369 and/or Darocur 1173
D. other auxiliary agents:
In order to prevent polymerization reaction take place in the storage process, can add stopper, as Resorcinol, alkylphenol and/or alkoxyl group phenol.
In order to improve the stability of holographic copy composition, can add photostabilizer, photostabilizer energy shielding ultraviolet rays light wave reduces ultraviolet transmission effect.The spendable stablizer ammonia photostabilizer that is obstructed, as three (1,2,2 ', 6,6 '-the pentamethyl-piperidinyl) phosphorous acid ester, two (2,2 ', 6,6 '-the tetramethyl-piperidinyl) sebate; Hydroxy benzophenone class uv-absorbing agent is as 2-hydroxyl-4-methoxy benzophenone; Benzotriazole UV absorbers, as 2-(2 '-hydroxyl-5 '-aminomethyl phenyl) benzotriazole.
Compositions of ultraviolet curing type of the present invention can be that blade coating, roller coating, spraying etc. are applied on the substrates such as glass, plastics, fabric with coating process commonly used, and coat-thickness is 10～30 microns.
Coating can be used ultraviolet light polymerization, and according to the power of exposure energy, the time shutter can be from several seconds to 10 minutes.The ultraviolet source that is suitable for has sunlight, high voltage mercury lamp, low pressure mercury lamp, xenon lamp, halogen lamp etc., and light intensity can be 100W to 5000W.
The present invention can obtain further instruction by following embodiment.Embodiment is as follows:
Form weight (gram)
Urethane acrylate 545
Tetramethylol methane tetraacrylate 97.5
(methyl) vinylformic acid norborneol ester 223.6
Irgacure 184 81.5
Resorcinol 52.5
The composition of this embodiment such as above-mentioned adds each component in the 2000ml beaker, and 60 ℃ of heating in water bath obtain light yellow transparent liquid to dissolving fully.Liquid is coated on glass, covers the embossed holographic masterplate again, get rid of bubble, exposure is 2 minutes under sunlight, opens masterplate, and hologram pattern is just all transferred on glass, handles through plated film, spraying protective layer again, just can obtain beautiful Grating glass.
Claims (8)
1, a kind of compositions of ultraviolet curing type, the composition of said composition and weight percent are:
A. polymeric acrylic acid fat 10～60%
B. activity diluting monomer 20～80%
C. light trigger 0.5～10%
2, according to the composition of claim 1, it is characterized in that said composition can comprise stopper, photostabilizer, its weight ratio is lower than 10% of composition total weight.
3, according to the composition of claim 1, described polymeric acrylate comprises Synolac acrylate, polyester acrylate, polyether acrylate, bisphenol A epoxy acrylate, phenolic aldehyde acrylate and/or urethane acrylate.
4, according to the composition of claim 1, described reactive monomer can be simple function group monomer, bifunctional monomer and/or polyfunctional monomer.
5, according to the composition of claim 4, described simple function group monomer comprises (methyl) Hydroxyethyl acrylate, (methyl) Propylene glycol monoacrylate, (methyl) butyl acrylate, (methyl) Isooctyl acrylate monomer, (methyl) vinylformic acid tetrahydrofuran ester, (methyl) vinylformic acid norborneol ester, N-vinyl pyrrolidone, acrylamide and/or vinyl acetate; Described bifunctional monomer comprises a condensed ethandiol double methacrylate, tirethylene glycol double methacrylate, triethylene Glycol acrylate, four condensed ethandiol acrylate, 1,4-butyleneglycol double methacrylate, neopentyl glycol double methacrylate, 1,6-hexylene glycol double methacrylate, Phthalic acid, diallyl ester and/or phthalic acid one condensed ethandiol double methacrylate; Described polyfunctional monomer comprises Viscoat 295, pentaerythritol triacrylate, tetramethylol methane tetraacrylate, Dipentaerythritol five acrylate and/or ethoxyquin Viscoat 295.
6, according to the composition of claim 1, described light trigger comprises benzophenone, dibenzoyl, benzoin ether, Michler's keton, thioxanthone, Irgacure 184, Irgacure 500, Irgacure 907, Irgacure 369 and/or Darocur 1173.
7, according to the composition of claim 2, described stopper comprises Resorcinol, alkylphenol and/or alkoxyl group phenol.
8, according to the composition of claim 2, described photostabilizer comprises three (1,2,2 ', 6,6 '-the pentamethyl-piperidinyl) phosphorous acid ester, two (2,2 ', 6,6 '-the tetramethyl-piperidinyl) sebate, 2-hydroxyl-4-methoxy benzophenone and/or 2-(2 '-hydroxyl-5 '-aminomethyl phenyl) benzotriazole
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94107281 CN1099047A (en) | 1994-06-27 | 1994-06-27 | Compositions of ultraviolet curing type |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94107281 CN1099047A (en) | 1994-06-27 | 1994-06-27 | Compositions of ultraviolet curing type |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1099047A true CN1099047A (en) | 1995-02-22 |
Family
ID=5032909
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 94107281 Pending CN1099047A (en) | 1994-06-27 | 1994-06-27 | Compositions of ultraviolet curing type |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1099047A (en) |
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| CN102120908A (en) * | 2010-12-30 | 2011-07-13 | 浙江工业大学 | Paper package surface cold-transfer type gold blocking UV oil polish and application thereof |
| CN102344704A (en) * | 2010-07-28 | 2012-02-08 | 中钞特种防伪科技有限公司 | Light-cured composition |
| CN102774222A (en) * | 2011-05-10 | 2012-11-14 | 上海协承昌化工有限公司 | Forming process for pattern layer on surface of aluminum-plastic substrate |
| CN102786839A (en) * | 2012-07-31 | 2012-11-21 | 佛山市三求电子材料有限公司 | Glass protecting ink and preparation method thereof |
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-
1994
- 1994-06-27 CN CN 94107281 patent/CN1099047A/en active Pending
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