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CN109837756A - A kind of preparation method of flame retardant type flocking yarn - Google Patents

A kind of preparation method of flame retardant type flocking yarn Download PDF

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Publication number
CN109837756A
CN109837756A CN201910138265.0A CN201910138265A CN109837756A CN 109837756 A CN109837756 A CN 109837756A CN 201910138265 A CN201910138265 A CN 201910138265A CN 109837756 A CN109837756 A CN 109837756A
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China
Prior art keywords
yarn
flocking
flame retardant
preparation
parts
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Pending
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CN201910138265.0A
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Chinese (zh)
Inventor
姜林强
蔡国明
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Zhejiang Jiuda Textile Technology Co Ltd
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Zhejiang Jiuda Textile Technology Co Ltd
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Priority to CN201910138265.0A priority Critical patent/CN109837756A/en
Publication of CN109837756A publication Critical patent/CN109837756A/en
Pending legal-status Critical Current

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  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a kind of preparation methods of flame retardant type flocking yarn, preparation process includes that yarn, pretreatment decontamination, first time drying and processing, spray treatment, flocking processing, the processing of second of drying and processing, bristle and winding are sent in charging, wherein in spray treatment, it can assign yarn excellent flame retardant property by spraying one layer of environmental-protection flame-retardant water paint with caking property.Continuous production may be implemented in the production technology that the present invention prepares flocking yarn, it ensure that the quality of flocking yarn, a large amount of time and cost have been saved for postorder woven fabric process, improve production efficiency, and the implanted article prepared has excellent flame retardant property, the performance requirement for fully meeting high-grade flocked fabric meets the developing direction in implanted article future.

Description

A kind of preparation method of flame retardant type flocking yarn
Technical field
The invention belongs to Textile Engineering field more particularly to a kind of preparation methods of flame retardant type flocking yarn.
Background technique
Flocking is using charge identical charges repel each other the principle that there is a natural attraction between the sexes, so that negative electrical charge on staple fiber villus band, by flocking Material is placed under zero potential or grounding requirement, and villus accelerates vertically to fly to flocked material surface under the action of electric field, due to planting Down material is pre-coated with the reason of binder, and villus is just vertically adhered on material, is dried or dried in the air after flocking It is dry to obtain finished product.In flocking field, flocked material is usually cloth, in the entirely process of production implanted article, cloth warp The processes such as pretreatment, gluing, flocking and bristle are crossed, a large amount of villus, glue and pretreatment fluid are consumed, production is caused and plants The rising of flannelette material cost, in order to save cost, can choose yarn is that raw material produces flocking yarn, is finally woven into cloth.And And need to carry out degumming process in the gluing treatment process before flocking, it is therefore an objective to remove extra glue to keep certain glue Thickness of feed layer will cause holiday or thick the phenomenon that applying, seriously affect flocking quality, need rationally to control sizing material if degumming is improper Thickness degree can take spraying technology to control the thickness of dope layer and realize above-mentioned purpose.In addition, mentioning with living standard Height, demand of the people to properties of textile are not limited to the performances such as decorative appearance, wear-resisting, stretching, need under certain special occasions Want textile fabric that there are the performances such as sterilization, hydrophobic, conductive, fire-retardant, uvioresistant.In field of textiles, nano material has spy Different uvioresistant absorbs visible light and infrared ray, anti-aging, high-intensitive and toughness, good conductive and electrostatic screening effect, Stronger antibacterial and deodorizing function and adsorption capacity etc., therefore, by nano material and flocking with these specific functions Fabric or yarn progress are compound, can prepare fabric and new textile material with various functions.Such as nano-aluminum hydroxide is Good inorganic anti-flaming material, because it can be decomposited chemical bonding water (about 34.6%) at high temperature, this decomposition reaction is heat absorption Reaction, thus the thermal degradation speed of high polymer can be delayed, slow down or inhibit the burning of high polymer, inhibits the temperature rise of high polymer, and Promote charing and suppression cigarette.And the surface-active of nano-aluminum hydroxide is more much higher than micron-sized, improves chemical reaction speed Rate, so that decomposition reaction is easier to carry out.Nano-aluminum hydroxide can be used as flame retardant and be added in other flame-retardant compositions, rise To preferable flame retardant effect.
Summary of the invention
The purpose of the invention is to provide a kind of preparation method of flame retardant type flocking yarn, the continuous of yarn may be implemented Production, and the implanted article prepared possesses good flame retardant property.
The present invention is of the existing technology in order to overcome the problems, such as, using following technical scheme:
A kind of preparation method of flame retardant type flocking yarn, comprising the following specific steps
(1) yarn is sent in charging: 60 groups of spindles being previously charged into creel device, 60 groups of yarns are then passed through dividing sinker pipeline, are used in combination Gripping means grips yarn group, yarn group are completed charging and are prepared using Yarn tension balancer;
(2) pre-process decontamination: yarn group immerses preprocessing solution, clears up the spot on yarn and miscellaneous hair, cleans out rear yarn Group is then passed through in the gap of multipair power roller and squeezes out extra preprocessing solution;
(3) first time drying and processing: the yarn group after pretreated is dried by infrared-ray dryer, evaporates pretreatment fluid;
(4) spray treatment: by the environmental-protection flame-retardant water paint of prior deployed viscosity, the feeding device being added in flush coater In, so that coating atomization is sprayed onto yam surface by compressed air, complete spraying process, paint ingredient is based on parts by weight, comprising: 30 ~ 50 parts of polyurethane-modified polyacrylate lotion, 10 ~ 20 parts of KH560 silane coupling agent, 0.5 ~ 5 part of defoaming agent, titanium dioxide 1 ~ 10 Part, 0.5 ~ 3 part of levelling agent, 1 ~ 5 part of antioxidant amounting, triazines nitrogen -10 ~ 15 parts of silicon carbon forming agent, 1 ~ 5 part of amine borate, zinc borate 1 ~ 5 parts, 1 ~ 5 part of nano-aluminum hydroxide and 20 ~ 52 parts of deionized water;
(5) flocking is handled: yarn group passes through electrostatic flocking apparatus, and staple fiber villus is adsorbed on spray treatment under the action of electric field On yarn afterwards;
(6) second of drying and processing: yarn group passes through infrared-ray dryer, heated baking, so that paint solidification forms a film;
(7) bristle is handled: yarn group is by the power roller in bristle system, by controlling vacuum-control(led) system, by yarn group On residual villus remove and recycle in dust collecting sleeve.
(8) it winds.
Further, it is that 20 ~ 50 s(apply 4 glasss of viscometer methods that the technological parameter in the spray treatment, which includes: viscosity of the coating, Measurement), air pressure is 0.35 ~ 0.45 MPa, and spraying effective distance is 20 ~ 30 cm, and coating spray volume is 0.04 ~ 0.08L/ min。
Further, coating used in the spray treatment is the environmental-protection flame-retardant water paint with caking property, resistance Combustion agent ingredient is triazines nitrogen-silicon carbon forming agent, amine borate, zinc borate and nano-aluminum hydroxide.
Further, the flame retardant constituent in the environmental-protection flame-retardant water paint can be replaced the nothing with fire retardation Machine object or organic matter and their combination.
Further, villus is uniformly trickled down in yarn group by metallic sieve in the flocking processing, flocking room medium staple Hair falling weight should control between 0.5 ~ 3kg/min.
Further, the range that vacuum-control(led) system vacuumizes in the bristle processing is 10-1~105 Pa。
Further, the preparation method of flocking yarn is suitable for cotton, fiber crops, silk, wool, acrylic, terylene, viscous fine and each Yarn made of the blended material of kind.
Further, the yarn includes thread layers, flame retardant coating and flocking layer from inside to outside.
Using technical solution provided by the invention, can get it is following the utility model has the advantages that
(1) continuous production may be implemented in the production technology that the present invention prepares flocking yarn, has saved greatly for postorder woven fabric process The time of amount and cost, improve production efficiency.
(2) the spray treatment technique in the present invention can accurately control coating instead of traditional gluing treatment process The thickness of layer, ensure that the quality of implanted article.
(3) flocking yarn prepared by the present invention has excellent flame retardant property, if spinning fully meets high-grade plant at cloth The flame retardant property demand of velvet fabric.
Detailed description of the invention
Fig. 1 is the schematic diagram of the section structure of flame retardant type flocking yarn of the present invention from inside to outside.
1, thread layers in Fig. 1;2, flame retardant coating;3, flocking layer.
Specific embodiment:
The present invention is further explained in the light of specific embodiments.
Embodiment 1:
A kind of preparation method of flame retardant type flocking yarn, comprising the following specific steps
(1) yarn is sent in charging: 60 groups of spindles are previously charged into creel device on rotatable guide ontology,
Then 60 groups of yarns are passed through into dividing sinker pipeline under the action of tractive force, and is moved by motor driven clamping device level It is dynamic, it adjusts and clamps yarn group in position, yarn group adjusts yarn tension using Yarn tension balancer, completes charging Prepare;
(2) pre-process decontamination: under the action of tractive force, power roller wheel drive yarn group immerses in preprocessing solution, clears up yarn Spot and miscellaneous hair on line accelerate cleaning effect using the bubble that 2400W supersonic generator generates in pretreatment fluid, and temperature is It 50 ~ 80 DEG C, cleans out rear yarn group and is then passed through in the gap of multipair power roller and squeeze out extra preprocessing solution;
(3) first time drying and processing.Yarn group after pretreated is dried by infrared-ray dryer, and heating temperature is 100 ~ 120 DEG C, evaporate pretreatment fluid;
(4) spray treatment: by environmental-protection flame-retardant water paint and deionized water (diluent) according to the ratio of mass parts ratio 1:3 It is deployed, so that its viscosity is reached 20 ~ 50 s(and apply 4 glasss of viscometer method measurements), deployed coating is then added to flush coater In feeding device in, so that coating atomization is sprayed onto yam surface by compressed air, complete spraying process, specific process parameter is such as Under: air pressure is 0.35 ~ 0.45 MPa, and spraying effective distance is 20 ~ 30 cm, and coating spray volume is 0.04 ~ 0.08L/min. Paint ingredient is based on parts by weight, comprising: 30 parts of polyurethane-modified polyacrylate lotion, 10 parts of KH560 silane coupling agent, defoaming 0.5 part of agent, 1 part of titanium dioxide, 0.5 part of levelling agent, 1 part of antioxidant amounting, triazines nitrogen -10 parts of silicon carbon forming agent, 1 part of amine borate, 1 part of zinc borate, 1 part of nano-aluminum hydroxide and 20 parts of deionized water;
(5) flocking is handled: yarn group passes through electrostatic flocking apparatus, and staple fiber villus is equal by metallic sieve under the action of electric field Even to trickle down in yarn group, in order to guarantee the flocking quality of yarn, electrostatic pressure should be maintained between 40 ~ 60KV, between two pole plates Within for 10cm.It can change the size of electric field force by the size and villus carried charge that control electric field strength, and then control The falling weight of villus, villus falling weight can be fallen with villus in the metering device unit of account time subsidiary in flocking system Weight, should control between 0.5 ~ 3kg/min;
(6) second of drying and processing: yarn group passes through infrared-ray dryer, the heated baking at 80 ~ 100 DEG C, so that coating is solid It is melted into film;
(7) bristle is handled: yarn group starts mechanical pump by the power roller in bristle system, control vacuum-control(led) system, will Vacuum degree is extracted into 7Pa and collects in dust collecting sleeve hereinafter, will remain villus using vacuum suction principle, while collecting villus, takes out Gas out is filtered by filter, and ozone is discharged outside bristle system.
(8) it winds.
Coating used in the spray treatment is the environmental-protection flame-retardant water paint with caking property, and flame retardant constituent is Triazines nitrogen-silicon carbon forming agent, amine borate, zinc borate and nano-aluminum hydroxide.
Flame retardant constituent in the environmental-protection flame-retardant water paint can be replaced the inorganic matter with fire retardation or have Machine object and their combination.
The range that vacuum-control(led) system vacuumizes in the bristle processing is 10-1~105 Pa。
The preparation method of flocking yarn of the present invention is suitable for cotton, fiber crops, silk, wool, acrylic, terylene, viscous fine and various Yarn made of blended material.
The yarn includes thread layers, flame retardant coating and flocking layer from inside to outside.
Embodiment 2: the difference from embodiment 1 is that, in the spray treatment of step (4) paint ingredient based on parts by weight, It include: 50 parts of polyurethane-modified polyacrylate lotion, 20 parts of KH560 silane coupling agent, 5 parts of defoaming agent, 10 parts of titanium dioxide, levelling 3 parts of agent, 5 parts of antioxidant amounting, triazines nitrogen -15 parts of silicon carbon forming agent, 5 parts of amine borate, 5 parts of zinc borate, 5 parts of nano-aluminum hydroxide And 52 parts of deionized water.
Embodiment 3: the difference with embodiment 1 and embodiment 2 is that paint ingredient is in the spray treatment of step (4) with weight Measure number meter, comprising: 40 parts of polyurethane-modified polyacrylate lotion, 15 parts of KH560 silane coupling agent, 3 parts of defoaming agent, titanium dioxide 5 parts, 1.7 parts of levelling agent, 3 parts of antioxidant amounting, triazines nitrogen -12 parts of silicon carbon forming agent, 3 parts of amine borate, zinc borate 3 part, nanometer 3 parts of aluminium hydroxide and 36 parts of deionized water.
Comparative example 1: the difference with embodiment 3 is, in the spray treatment of step (4) paint ingredient based on parts by weight, It include: 40 parts of polyurethane-modified polyacrylate lotion, 15 parts of KH560 silane coupling agent, 3 parts of defoaming agent, 5 parts of titanium dioxide, levelling 1.7 parts of agent, 3 parts of antioxidant amounting and 36 parts of deionized water.
By flocking yarn prepared by embodiment 1 ~ 3 and comparative example 1, according to GB/T 5454-1997 using oxygen index instrument into The test of row anti-flammability, data result are as shown in table 1.
1 embodiment 1 ~ 3 of table and the flame retardant property of comparative example 1 compare
Compared to comparative example 1 it can be seen from the performance test results of table 1, the flame retardant property of the flocking yarn in embodiment 1 ~ 3 It is excellent, due to being added without effective flame-retardant composition in comparative example 1, including triazines nitrogen-silicon carbon forming agent, amine borate, zinc borate and Nano-aluminum hydroxide, LOI value are below embodiment 1 ~ 3, and anti-flammability is poor, illustrate to add effective flame-retardant composition in flocking yarn It can assign yarn excellent anti-flammability.
The present invention provides a kind of preparation method of flame retardant type flocking yarn, can get it is following the utility model has the advantages that
Continuous production may be implemented in the production technology that the present invention prepares flocking yarn, ensure that the quality of flocking yarn, after being Sequence woven fabric process has saved a large amount of time and cost, improves production efficiency, and the implanted article prepared is with excellent Flame retardant property fully meets the flame retardant property demand of high-grade flocked fabric, meets the developing direction in implanted article future.
Finally it should be noted that the above content is merely illustrative of the technical solution of the present invention, rather than the present invention is protected The limitation of range, the simple modification or equivalent replacement that those skilled in the art carry out technical solution of the present invention, All without departing from the spirit and scope of technical solution of the present invention.

Claims (8)

1. a kind of preparation method of flame retardant type flocking yarn, which is characterized in that comprising the following specific steps
(1) yarn is sent in charging: 60 groups of spindles being previously charged into creel device, 60 groups of yarns are then passed through dividing sinker pipeline, are used in combination Gripping means grips yarn group, yarn group are completed charging and are prepared using Yarn tension balancer;
(2) pre-process decontamination: yarn group immerses preprocessing solution, clears up the spot on yarn and miscellaneous hair, cleans out rear yarn Group is then passed through in the gap of multipair power roller and squeezes out extra preprocessing solution;
(3) first time drying and processing: the yarn group after pretreated is dried by infrared-ray dryer, evaporates pretreatment fluid;
(4) spray treatment: by the environmental-protection flame-retardant water paint of prior deployed viscosity, the feeding device being added in flush coater In, so that coating atomization is sprayed onto yam surface by compressed air, complete spraying process, paint ingredient is based on parts by weight, comprising: 30 ~ 50 parts of polyurethane-modified polyacrylate lotion, 10 ~ 20 parts of KH560 silane coupling agent, 0.5 ~ 5 part of defoaming agent, titanium dioxide 1 ~ 10 Part, 0.5 ~ 3 part of levelling agent, 1 ~ 5 part of antioxidant amounting, triazines nitrogen -10 ~ 15 parts of silicon carbon forming agent, 1 ~ 5 part of amine borate, zinc borate 1 ~ 5 parts, 1 ~ 5 part of nano-aluminum hydroxide and 20 ~ 52 parts of deionized water;
(5) flocking is handled: yarn group passes through electrostatic flocking apparatus, and staple fiber villus is adsorbed on spray treatment under the action of electric field On yarn afterwards;
(6) second of drying and processing: yarn group passes through infrared-ray dryer, heated baking, so that paint solidification forms a film;
(7) bristle is handled: yarn group is by the power roller in bristle system, by controlling vacuum-control(led) system, by yarn group On residual villus remove and recycle in dust collecting sleeve;
(8) it winds.
2. the preparation method of flame retardant type flocking yarn according to claim 1, which is characterized in that in the spray treatment Technological parameter includes: that viscosity of the coating is 20 ~ 50 s, and air pressure is 0.35 ~ 0.45 MPa, and spraying effective distance is 20 ~ 30 Cm, coating spray volume are 0.04 ~ 0.08L/min.
3. the preparation method of flame retardant type flocking yarn according to claim 1 or 2, which is characterized in that the spray treatment Used in coating be the environmental-protection flame-retardant water paint with caking property, flame retardant constituent is triazines nitrogen-silicon carbon forming agent, boron Acid amide, zinc borate and nano-aluminum hydroxide.
4. the preparation method of flame retardant type flocking yarn according to claim 3, which is characterized in that the environmental-protection flame-retardant water Flame retardant constituent in property coating can be replaced inorganic matter with fire retardation or organic matter or their combination.
5. the preparation method of flame retardant type flocking yarn according to claim 1, which is characterized in that the flocking handles medium staple Hair is uniformly trickled down in yarn group by metallic sieve, and villus falling weight should control between 0.5 ~ 3kg/min in flocking room.
6. the preparation method of flame retardant type flocking yarn according to claim 1, which is characterized in that true in the bristle processing The range that empty control system vacuumizes is 10-1~105 Pa。
7. the preparation method of flame retardant type flocking yarn according to claim 1, which is characterized in that the preparation side of flocking yarn Method is suitable for using natural fiber or chemical fibre through pure spinning or blended manufactured yarn.
8. a kind of using the method flame retardant type flocked yarn obtained for preparing flame retardant type flocking yarn as described in claim 1 Line, which is characterized in that the yarn includes thread layers, flame retardant coating and flocking layer from inside to outside.
CN201910138265.0A 2019-02-25 2019-02-25 A kind of preparation method of flame retardant type flocking yarn Pending CN109837756A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117845388A (en) * 2024-03-07 2024-04-09 德州彩诗禾纺织有限公司 A kind of textile equipment and textile process of flame retardant acrylic yarn

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CN109355927A (en) * 2018-11-20 2019-02-19 东莞市亿兆布料制品有限公司 A kind of flocking processing technology of felt cloth

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CN101307512A (en) * 2007-05-18 2008-11-19 上海德福伦化纤有限公司 Bamboo charcoal flocked pile preparation method
CN101215742A (en) * 2008-01-07 2008-07-09 曾得华 Flocked yarn and preparing method thereof
CN201362933Y (en) * 2009-02-19 2009-12-16 马朝军 Flocking fire-proof wall fabric
WO2013100123A1 (en) * 2011-12-28 2013-07-04 東洋紡株式会社 Insulating and thermally conductive sheet
CN107266890A (en) * 2017-07-11 2017-10-20 济南泰星精细化工有限公司 A kind of unsaturated polyester resin halogen-free flame retardants and its preparation method and application
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117845388A (en) * 2024-03-07 2024-04-09 德州彩诗禾纺织有限公司 A kind of textile equipment and textile process of flame retardant acrylic yarn
CN117845388B (en) * 2024-03-07 2024-05-31 德州彩诗禾纺织有限公司 Spinning equipment and spinning process for flame-retardant acrylic yarns

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Application publication date: 20190604