CN109836954A - A kind of Flame-retardant acrylic acid cold coating of slow releasing negative oxygen ion and preparation method thereof - Google Patents
A kind of Flame-retardant acrylic acid cold coating of slow releasing negative oxygen ion and preparation method thereof Download PDFInfo
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- CN109836954A CN109836954A CN201710812082.3A CN201710812082A CN109836954A CN 109836954 A CN109836954 A CN 109836954A CN 201710812082 A CN201710812082 A CN 201710812082A CN 109836954 A CN109836954 A CN 109836954A
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- retardant
- oxygen ion
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 119
- 238000002360 preparation method Methods 0.000 title claims abstract description 86
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 84
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 48
- 239000001301 oxygen Substances 0.000 title claims abstract description 48
- 238000000576 coating method Methods 0.000 title claims abstract description 45
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 239000011248 coating agent Substances 0.000 title claims abstract description 41
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 112
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 67
- 239000000839 emulsion Substances 0.000 claims abstract description 65
- 239000002270 dispersing agent Substances 0.000 claims abstract description 48
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 26
- 239000007787 solid Substances 0.000 claims abstract description 25
- 239000000049 pigment Substances 0.000 claims abstract description 18
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 14
- 239000003755 preservative agent Substances 0.000 claims abstract description 14
- 230000002335 preservative effect Effects 0.000 claims abstract description 14
- 230000009970 fire resistant effect Effects 0.000 claims abstract description 13
- 230000004048 modification Effects 0.000 claims abstract description 13
- 238000012986 modification Methods 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 9
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 5
- -1 oxygen ion Chemical class 0.000 claims description 126
- 238000006243 chemical reaction Methods 0.000 claims description 60
- 239000006210 lotion Substances 0.000 claims description 53
- 239000007788 liquid Substances 0.000 claims description 46
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 42
- 239000000178 monomer Substances 0.000 claims description 39
- 239000003995 emulsifying agent Substances 0.000 claims description 38
- 239000003973 paint Substances 0.000 claims description 37
- 239000002243 precursor Substances 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 27
- 239000003381 stabilizer Substances 0.000 claims description 25
- 238000004945 emulsification Methods 0.000 claims description 24
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 22
- 229920000877 Melamine resin Polymers 0.000 claims description 21
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical group CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims description 21
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 21
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 21
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 21
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 21
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 21
- 239000006185 dispersion Substances 0.000 claims description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 15
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 claims description 15
- 229910052799 carbon Inorganic materials 0.000 claims description 15
- 239000003999 initiator Substances 0.000 claims description 15
- 239000000084 colloidal system Substances 0.000 claims description 14
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 12
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical group O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 12
- 229910019142 PO4 Inorganic materials 0.000 claims description 12
- 229910052782 aluminium Inorganic materials 0.000 claims description 12
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 12
- 238000006757 chemical reactions by type Methods 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 12
- 239000011258 core-shell material Substances 0.000 claims description 12
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 12
- 239000010452 phosphate Substances 0.000 claims description 12
- 238000010008 shearing Methods 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 11
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 11
- 229920002125 Sokalan® Polymers 0.000 claims description 11
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical group CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 11
- 238000004040 coloring Methods 0.000 claims description 11
- 239000012975 dibutyltin dilaurate Substances 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 11
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 11
- 239000004584 polyacrylic acid Substances 0.000 claims description 11
- 239000000440 bentonite Substances 0.000 claims description 10
- 229910000278 bentonite Inorganic materials 0.000 claims description 10
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical group O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 10
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 9
- 230000000694 effects Effects 0.000 claims description 8
- 239000004417 polycarbonate Substances 0.000 claims description 8
- 229920000515 polycarbonate Polymers 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 7
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 6
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 6
- 239000004952 Polyamide Substances 0.000 claims description 6
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 6
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 6
- 239000005011 phenolic resin Substances 0.000 claims description 6
- 229920001568 phenolic resin Polymers 0.000 claims description 6
- 229920002647 polyamide Polymers 0.000 claims description 6
- 229920000388 Polyphosphate Polymers 0.000 claims description 4
- 239000001205 polyphosphate Substances 0.000 claims description 4
- 235000011176 polyphosphates Nutrition 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 239000003610 charcoal Substances 0.000 claims description 2
- UCQFCFPECQILOL-UHFFFAOYSA-N diethyl hydrogen phosphate Chemical compound CCOP(O)(=O)OCC UCQFCFPECQILOL-UHFFFAOYSA-N 0.000 claims description 2
- 230000005686 electrostatic field Effects 0.000 claims description 2
- 150000004702 methyl esters Chemical class 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims 1
- 239000004606 Fillers/Extenders Substances 0.000 claims 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical group [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims 1
- 229920006221 acetate fiber Polymers 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 230000007935 neutral effect Effects 0.000 claims 1
- 238000005979 thermal decomposition reaction Methods 0.000 claims 1
- 230000001681 protective effect Effects 0.000 abstract description 14
- 229920003023 plastic Polymers 0.000 abstract description 4
- 239000004033 plastic Substances 0.000 abstract description 4
- 239000011521 glass Substances 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 230000000979 retarding effect Effects 0.000 abstract description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 40
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 20
- 235000017557 sodium bicarbonate Nutrition 0.000 description 20
- 230000007613 environmental effect Effects 0.000 description 14
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 10
- 229940077388 benzenesulfonate Drugs 0.000 description 10
- 229910052708 sodium Inorganic materials 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- 239000002253 acid Substances 0.000 description 9
- 239000006071 cream Substances 0.000 description 9
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 150000001336 alkenes Chemical class 0.000 description 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 8
- 229920002635 polyurethane Polymers 0.000 description 8
- 239000004814 polyurethane Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 239000002904 solvent Substances 0.000 description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
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- 238000001035 drying Methods 0.000 description 3
- 239000011133 lead Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
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- 239000003513 alkali Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
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- 229910001385 heavy metal Inorganic materials 0.000 description 1
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
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Landscapes
- Paints Or Removers (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention discloses Flame-retardant acrylic acid cold coatings of a kind of slow releasing negative oxygen ion and preparation method thereof.This patent carries out functional modification to acrylic resin using organic and inorganic active molecule, and the nucleocapsid structure polyacrylic resin generated is promoted to have significant fire performance, water-fast and high film strength feature, and has high solids content (being not less than 67%).And using the fire-type polyacrylic resin water-based emulsion of preparation as film forming agent, the auxiliary materials such as dispersing agent, drier, antisettling agent, defoaming agent, preservative, anti skinning agent, levelling agent, pigment and negative oxygen ion cast charge is added to prepare the high-performance fire-resistant type water-based acrylic resin coating of releasable negative oxygen ion, the coating is environmentally protective, releasable negative oxygen ion, fire protection flame retarding, at low cost, can be in various materials field large-scale applications such as woodenware, metal, plastics, glass, building surfaces.
Description
Technical field
The invention belongs to the designs of environment protecting water-based paint and synthesis field, more particularly, to a kind of slow releasing negative oxygen ion
Flame-retardant acrylic acid cold coating and preparation method thereof, by molecular function is modified and the angle of macromolecular structure building, design and
Prepare environmentally protective water paint product, and add releasing negative oxygen ion function, can in woodenware, metal, plastics, glass, build
Build field large-scale application in the various materials such as surface.
Background technique
Indoor coating is broadly divided into water paint and two kinds of solvent reducible coatings.And the main of pollution is generated to environment at present
It is large-scale use solvent reducible coatings, and the worry to coating pollution can be altogether dispensed with using the water paint of environmental protection.Appoint
What solvent reducible coatings all can containing 50% or more organic solvent.Most of wall finiss in the market all uses water based emulsion
Paint, but the woodenware and its household, the TV of plastics, computer, air-conditioning, refrigerator, water dispenser, motorcycle, electric vehicle that are used for furniture are still
Largely use solvent borne paint.Environmental Protective Water-paint be exactly using water as diluent, without the coating of organic solvent, without benzene, toluene,
Dimethylbenzene, formaldehyde, free TDI toxic heavy metal, nontoxic non-stimulated smell is harmless, free from environmental pollution, paint film is plentiful,
It is sparkling and crystal-clear it is bright, flexibility is good and has the characteristics that water-fast, wear-resisting, ageing-resistant, color inhibition, fast drying, easy to use, can be used
In the various materials such as woodenware, metal, plastics, glass, building surface.And oil paint refers to using painting made of organic solvent
Material, containing volatile organic compound (VOC), except it is toxic to human body, pollute the environment in addition to, it is also inflammable and explosive;Certain product
Kind is also pollution environment and damage consumer health " stealthy killer " containing noxious materials such as a large amount of formaldehyde, benzene, lead.
Although aqueous woodware paint brand is numerous on Vehicles Collected from Market, the difference of its main component of argument, nothing more than be divided into
Lower three classes: (1) with acrylic acid water paint as main component, being mainly characterized by that adhesive force is good, will not deepen the color of woodenware,
But wear-resisting and chemical resistance is poor, and hardness of paint film is softer, and the test of pencil method is HB, and richness is poor, and comprehensive performance is general, applies
Work is also easy to produce defect.It is the major product that most of water paint enterprise introduces to the market because cost is relatively low and technology content is not high for it.
This is also to form most people to think the bad reason for it of water paint.Its advantage is that cheap；(2) with acrylic acid and poly- ammonia
The synthetic of ester water paint as main component, feature other than the characteristics of adhering to acrylic paint, and increase it is wear-resisting and
The strong feature of chemical resistance, some enterprises are designated as aqueous polyester paint.Hardness of paint film is preferable, and the examination of pencil rule is 1H, richness
Preferably, comprehensive performance is close to oil paint.It is domestic at present to only have several enterprises that produce.(3) polyurethane water-based paint,
Comprehensive performance is superior, and richness is high, and hardness of paint film can reach 1.5-2H, and wear-resisting property is even more than oil paint, service life,
It all has a clear superiority in terms of color conditioning, is the high-grade products in water paint, the technology is public in the whole world only several professions
Department grasps.
Water paint or solvent based coating are the building of main material with macromolecule at present simultaneously, cause it with inflammable easy
Quick-fried hidden danger causes many safety hazards or hidden danger to many industry or domestic environments.Develop fire-type Environmental Protective Water-paint
The NPD projects and trend of development are needed as current paint industry.Simultaneously with the rise of smart home, with releasable negative oxygen from
It is also trend of the times that the coating of son, which replaces traditional coating to improve the living environment of people,.
Summary of the invention
The main purpose of the invention patent is the Flame-retardant acrylic acid resin cream for overcoming traditional direct addition fire retardant to prepare
Liquid flame retardant effect is uneven, big to the Effect on Mechanical Properties of film forming rear film, and the defect of fire retardant additive amount provides a kind of production
Simple process, intensity and adhesive property be good, the preparation side of the Flame-retardant acrylic acid cold coating of water-tolerant, excellent flame retardancy
Method, while assigning the coating releasing negative oxygen ion function.
The principle of the invention lies in fire retardant and macromolecular chain are prepared into special nucleocapsid knot using macromolecular polymerization reaction
The lotion of structure, while introducing a certain proportion of hardness monomer and anti-aging function monomer, can greatly improve mechanical property with
And ageing-resistant performance, enhance the intensity and adhesive property of Flame-retardant acrylic acid resin emulsion.Firstly, preparing retardant solution
Joined in the process the nitrogen phosphorus series that can play synergistic effect fire retardant and carbon forming agent and it is fire-retardant join in a common effort agent, these are fire-retardant
Agent can trigger different fire retardants at different temperatures and work, so that effective temperature scope due to the difference of decomposition temperature
Wider, flame retardant effect is more preferable.Meanwhile the fire retardant of addition has the function of thermal expansion, can form one layer of charcoal at a certain temperature
Film is covered on body surface to completely cut off air, the addition of carbon forming agent so that this process speed faster.Meanwhile it being closed in strand
At introducing required monomer and protecting colloid in the process, so that the performance of polymerizable molecular chain increases, film-formation result
It is good, it is uniformly dispersed, it is not easily settled.The package structure for ultimately forming nucleocapsid system is steady under the action of emulsifier and dispersing agent
It is fixed to exist, the other flame retarding function of molecular level is realized, solid content is up to 50% or more Flame-retardant acrylic acid resin emulsion.It is making
The anion body that the negative oxygen ion releasing agent being added during standby coating contains has the function of significantly being excited to generate anion,
Hydrone in water or air is instantaneous " negative ionization ".Acted on by physical stimulation, such as mechanical energy, chemical energy, luminous energy,
Electrostatic field energy etc. can generate a large amount of anion.
A kind of preparation method of the Flame-retardant acrylic acid cold coating of slow releasing negative oxygen ion proposed by the present invention has work
Skill is simple, has excellent performance, is environmental-friendly, advantage at low cost, can expand it in military project, the use scope of civil field.
The purpose of invention is achieved through the following technical solutions:
(1) water (80% ~ 90%), nitrogen phosphorus system the preparation of reaction-type flame-retarding molecular modification precursor liquid: are sequentially added into reaction vessel
Column fire retardant (1% ~ 8%), flame retardancy synergists (0.1% ~ 2.5%), carbon forming agent (0.5% ~ 5%), and carry out high-speed stirred and be mixed to get
Precursor liquid；
(2) flame-retardant modified emulsion preparation process: emulsifier (0.1% ~ 2%) is added into the reaction precursor liquid of step (1) and disperses
Agent (0.1% ~ 1%), and be successively added dropwise in the emulsion process of emulsification pretreatment blender annular phosphate flame retardant (15% ~
25%), melamine (1% ~ 5%), protecting colloid (0.1% ~ 5%) can obtain the fire-retardant agent emulsion of high uniformity dispersion, and will
It is placed in heating reaction vessel and keeps temperature (50 ~ 100 DEG C), and time (1h ~ 10h) stirring is reacted；
(3) it is total that flame-retardant modified lotion completely reacted in appropriate step (2) preparation of pre- core lotion: is added in isothermal reaction container
The sample of quality 20% ~ 60%, sequentially adding required function monomer includes methyl methacrylate (8% ~ 20%), butyl acrylate
(20% ~ 40%), acrylic acid (2% ~ 8%) and after 2min is mixed, be added emulsifier (0.2% ~ 5%) and dispersing agent (0.3% ~
1.6%) it is emulsified, revolving speed is 1000 ~ 7000r, and the time is 1 ~ 10min.Required chain initiator is then added dropwise respectively
(0.01% ~ 0.5%), PH stabilizer (0.01% ~ 1.5%) and PH regulator (0.01% ~ 2.5%), so that pH value control is 10, it will be permanent
Warm pot temperature is adjusted to 30 DEG C ~ 100 DEG C, after keeping 10 ~ 80min of the temperature, completes seeded emulsion polymerization；
(4) preparation of pre- shell lotion: the sample of flame-retardant modified lotion gross mass 40%-80% completely reacted in a certain amount of step (2) is taken
Then product sequentially add emulsifier (0.1% ~ 2.5%) and dispersing agent (0.1% ~ 1.5%), add required monomer metering system
Sour methyl esters (35% ~ 45%), acrylamide (3% ~ 8%) and function monomer tertiary ethylene carbonate (1% ~ 5%), then in 1500 ~ 8000r
Emulsified 10 ~ the 160min of revolving speed adds required chain initiator (0.02% ~ 0.7%), PH stabilizer (0.02% ~ 1.8%) and PH
Regulator (0.05% ~ 3.5%), control solution pH value are 7 ~ 8；
(5) water-based emulsion core-shell structure constructs: isothermal reaction vessel temp in (4) is adjusted to 70 DEG C ~ 120 DEG C, it will be in (3)
Pre- core lotion enters dropwise in (4) in solution, and rate of addition is 0.01 ~ 10ml/min, and 1 ~ 5h is kept the temperature after dripping and obtains large arch dam
The fire-type polyacrylic resin water-based emulsion of amount；
(6) it using the high solids content fire-type polyacrylic resin water-based emulsion of step (5) preparation as film forming agent, sequentially adds point
Powder (accounting for 0.05 ~ 1.5%), drier (accounting for 0.02 ~ 1.0%), antisettling agent (accounting for 0.01 ~ 2.5%), defoaming agent (account for 0.5 ~
1.5%), preservative (accounting for 0.001 ~ 0.05%), anti skinning agent (accounting for 0.02 ~ 2.5%), levelling agent (accounting for 0.01 ~ 3.5%), pigment (account for
5 ~ 35%), negative oxygen ion releasing agent (0.5% ~ 2%), and by high-speed shearing machine high speed dispersion, it is aqueous to prepare high-performance fire-resistant type
Environmental protection coating material.
Compared with the prior art, the invention has the following advantages:
1. a kind of preparation method of the Flame-retardant acrylic acid cold coating of slow releasing negative oxygen ion of the invention has fire-retardant effect
The features such as fruit is good, and simple process is environmental-friendly, releasable negative oxygen ion.The resin solid content is up to 67% or more, intensity and glues
It ties good performance, water-tolerant, its excellent anti-flammability and can reduce production, transport the calamity source in use process, effectively protect
The safety of related personnel is protected, and expands it in military project, the use scope of civil field.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the Flame-retardant acrylic acid cold coating of slow releasing negative oxygen ion.
4 be stretching-stress curve with a thickness of the emulsion acrylic resin of 0.1mm drying rear film in Fig. 2.
In figure: 1 coating surface layer attachment negative oxygen ion cast charge, the acrylic molecules in 2 nuclear structures, in 3 shell structures
Flame retardant molecule layer.
Specific embodiment
In order to more deeply understand the present invention, below with reference to embodiment, the present invention is further illustrated, it should be noted that
The scope of protection of present invention is not limited to the scope of the embodiments.In following example, tensile strength test is used
The test of ISO7500-1 national standard；Fire protecting performance is tested according to U.S.'s UL-94 testing standard.
Embodiment 1
A kind of Flame-retardant acrylic acid cold coating of slow releasing negative oxygen ion and preparation method thereof, includes the following steps and technique item
Part:
(1) 80% water, 2% nitrogen phosphorus system the preparation of reaction-type flame-retarding molecular modification precursor liquid: are sequentially added into reaction vessel
Column fire retardant include 1% ammonium polyphosphate, 1% melamine polyphosphate, 2% flame retardancy synergists diethylphosphate aluminium, 1%
Carbon forming agent polyamide, and carry out high-speed stirred and be mixed to get precursor liquid；
(2) 0.1% emulsifier alkyl phenol polyoxy flame-retardant modified emulsion preparation process: is added into the reaction precursor liquid of step (1)
Vinethene and 0.1% dispersing agent neopelex, and in the emulsion process of emulsification pretreatment blender successively dropwise plus
Enter 25% annular phosphate flame retardant, 1% melamine, 2% protecting colloid hydroxyethyl cellulose, can obtain height
The fire-retardant agent emulsion of even dispersion, and place it in heating reaction vessel and kept for 100 DEG C of temperature, the stirring of time 5h is reacted；
(3) it is total that flame-retardant modified lotion completely reacted in appropriate step (2) preparation of pre- core lotion: is added in isothermal reaction container
The sample of quality 40%, sequentially add required function monomer include 10% methyl methacrylate, 20% butyl acrylate,
2% acrylic acid and after 2min is mixed, is added 0.5% emulsifier alkyl phenol polyoxyethylene ether and 0.5% dispersing agent 12
Sodium alkyl benzene sulfonate is emulsified, revolving speed 7000r, time 5min.0.1% required chain is then added dropwise respectively to draw
Agent ammonium persulfate, 1% PH stabilizer sodium bicarbonate and 1% PH regulator N, N- dimethylethanolamine are sent out, so that pH value controls
It is 10, constant temperature pot temperature is adjusted to 90 DEG C, after keeping temperature 60min, completes seeded emulsion polymerization；
(4) preparation of pre- shell lotion: the sample of flame-retardant modified lotion gross mass 60% completely reacted in a certain amount of step (2) is taken, so
1% emulsifier alkyl phenol polyoxyethylene ether and 0.2% dispersing agent neopelex are sequentially added afterwards, needed for adding
The methyl methacrylate of monomer 40%, 3% acrylamide and 2% function monomer tertiary ethylene carbonate, then in 7000r
The emulsified 60min of revolving speed adds the chain initiator ammonium persulfate of required 0.1%, 1% PH stabilizer sodium bicarbonate and 1%
PH regulator N, N- dimethylethanolamine, control solution pH value are 8；
(5) water-based emulsion core-shell structure constructs: isothermal reaction vessel temp in (4) being adjusted to 100 DEG C, by the pre- core in (3)
Lotion enters dropwise in (4) in solution, rate of addition 2ml/min, and the fire-type that 3h acquisition high solids content is kept the temperature after dripping is poly-
Acrylic resin water-based emulsion；
(6) using the high solids content fire-type polyacrylic resin water-based emulsion of step (5) preparation as film forming agent, 1% is sequentially added
Dispersing agent pelopon A, 0.5% drier dibutyl tin dilaurate, 0.5% antisettling agent bentonite,
1% defoaming agent poly alkyl alcohol ether compound, 0.01% preservative benzimidazole ester type compound, 0.02% anti skinning agent first
Ethyl ketone oxime compound, 0.01% levelling agent polyacrylic acid, 6% coloring pigment and 0.5% negative oxygen ion releasing agent, and lead to
High-speed shearing machine high speed dispersion is crossed, high-performance fire-resistant type Environmental Protective Water-paint is prepared.The sample drying prepared is formed a film laggard
The test of row tensile strength and flame retardant test, experiment effect are as shown in table 1 below.Coating property index is as shown in table 2 below.
The test of 1 flame retardant property of table
| Sample serial number | Film thickness (mm) | Maximum tension (MPa) | The flame self-gravitation time (s) |
| 1 | 0.11 | 60 | 5 |
| 2 | 0.13 | 58 | 6 |
| 3 | 0.11 | 65 | 5 |
2 coating property index test of table
| Project | Index | Test method |
| Coating appearance | Smooth coating | Range estimation |
| Hardness | > 0.4 | GB/T1739-89 |
| Impact, cm | 60 | GB/T1732-79 |
| Flexibility, mm | 1 | GB/T1731-93 |
| The liquid of resistance to gasoline, 2h | Appearance is without significant change | GB/T1731-93 |
| Acid resistance (0.05mol/L sulfuric acid, 7h) | It is not blistering wrinkle resistant | GB/T1763-93 |
| Alkali resistance, < 0.1mol/L | Not blistering corrugation | GB/T1763-93 |
Embodiment 2
A kind of Flame-retardant acrylic acid cold coating of slow releasing negative oxygen ion and preparation method thereof, includes the following steps and technique item
Part:
(1) 90% water, 3% nitrogen phosphorus system the preparation of reaction-type flame-retarding molecular modification precursor liquid: are sequentially added into reaction vessel
Column fire retardant include 2% ammonium polyphosphate, 1% melamine polyphosphate, 2% flame retardancy synergists diethyl hypo-aluminum orthophosphate, 1%
Carbon forming agent polyamide, and carry out high-speed stirred and be mixed to get precursor liquid；
(2) 0.1% emulsifier alkyl phenol polyoxy flame-retardant modified emulsion preparation process: is added into the reaction precursor liquid of step (1)
Vinethene and 0.2% dispersing agent neopelex, and in the emulsion process of emulsification pretreatment blender successively dropwise plus
Enter 25% annular phosphate flame retardant, 1% melamine, 2% protecting colloid hydroxyethyl cellulose, can obtain height
The fire-retardant agent emulsion of even dispersion, and place it in heating reaction vessel and kept for 100 DEG C of temperature, the stirring of time 5h is reacted；
(3) it is total that flame-retardant modified lotion completely reacted in appropriate step (2) preparation of pre- core lotion: is added in isothermal reaction container
The sample of quality 40%, sequentially add required function monomer include 10% methyl methacrylate, 20% butyl acrylate,
2% acrylic acid and after 2min is mixed, is added 0.5% emulsifier alkyl phenol polyoxyethylene ether and 0.5% dispersing agent 12
Sodium alkyl benzene sulfonate is emulsified, revolving speed 7000r, time 5min.0.1% required chain is then added dropwise respectively to draw
Agent ammonium persulfate, 1% PH stabilizer sodium bicarbonate and 1% PH regulator N, N- dimethylethanolamine are sent out, so that pH value controls
It is 10, constant temperature pot temperature is adjusted to 90 DEG C, after keeping temperature 60min, completes seeded emulsion polymerization；
(4) preparation of pre- shell lotion: the sample of flame-retardant modified lotion gross mass 60% completely reacted in a certain amount of step (2) is taken, so
1% emulsifier alkyl phenol polyoxyethylene ether and 0.2% dispersing agent neopelex are sequentially added afterwards, needed for adding
The methyl methacrylate of monomer 40%, 3% acrylamide and 2% function monomer tertiary ethylene carbonate, then in 7000r
The emulsified 60min of revolving speed adds the chain initiator ammonium persulfate of required 0.1%, 1% PH stabilizer sodium bicarbonate and 1%
PH regulator N, N- dimethylethanolamine, control solution pH value are 8；
(5) water-based emulsion core-shell structure constructs: isothermal reaction vessel temp in (4) being adjusted to 100 DEG C, by the pre- core in (3)
Lotion enters dropwise in (4) in solution, rate of addition 2ml/min, and the fire-type that 3h acquisition high solids content is kept the temperature after dripping is poly-
Acrylic resin water-based emulsion；
(6) using the high solids content fire-type polyacrylic resin water-based emulsion of step (5) preparation as film forming agent, 1% is sequentially added
Dispersing agent pelopon A, 0.5% drier dibutyl tin dilaurate, 0.5% antisettling agent bentonite,
1% defoaming agent poly alkyl alcohol ether compound, 0.01% preservative benzimidazole ester type compound, 0.02% anti skinning agent first
Ethyl ketone oxime compound, 0.01% levelling agent polyacrylic acid, 10% coloring pigment and 0.5% negative oxygen ion releasing agent, and lead to
High-speed shearing machine high speed dispersion is crossed, high-performance fire-resistant type Environmental Protective Water-paint is prepared.
Embodiment 3
A kind of Flame-retardant acrylic acid cold coating of slow releasing negative oxygen ion and preparation method thereof, includes the following steps and technique item
Part:
(1) 80% water, 2% nitrogen phosphorus system the preparation of reaction-type flame-retarding molecular modification precursor liquid: are sequentially added into reaction vessel
Column fire retardant include 1% ammonium polyphosphate, 1% melamine polyphosphate, 2% flame retardancy synergists diethyl hypo-aluminum orthophosphate, 2%
Carbon forming agent polyamide, and carry out high-speed stirred and be mixed to get precursor liquid；
(2) 0.1% emulsifier alkyl phenol polyoxy flame-retardant modified emulsion preparation process: is added into the reaction precursor liquid of step (1)
Vinethene and 0.1% dispersing agent neopelex, and in the emulsion process of emulsification pretreatment blender successively dropwise plus
Enter 25% annular phosphate flame retardant, 1% melamine, 1% protecting colloid hydroxyethyl cellulose, can obtain height
The fire-retardant agent emulsion of even dispersion, and place it in heating reaction vessel and kept for 90 DEG C of temperature, the stirring of time 3h is reacted；
(3) it is total that flame-retardant modified lotion completely reacted in appropriate step (2) preparation of pre- core lotion: is added in isothermal reaction container
The sample of quality 40%, sequentially add required function monomer include 15% methyl methacrylate, 30% butyl acrylate,
2% acrylic acid and after 2min is mixed, is added 0.5% emulsifier alkyl phenol polyoxyethylene ether and 0.5% dispersing agent 12
Sodium alkyl benzene sulfonate is emulsified, revolving speed 7000r, time 5min.0.1% required chain is then added dropwise respectively to draw
Agent ammonium persulfate, 1% PH stabilizer sodium bicarbonate and 1% PH regulator N, N- dimethylethanolamine are sent out, so that pH value controls
It is 10, constant temperature pot temperature is adjusted to 90 DEG C, after keeping temperature 60min, completes seeded emulsion polymerization；
(4) preparation of pre- shell lotion: the sample of flame-retardant modified lotion gross mass 60% completely reacted in a certain amount of step (2) is taken, so
1% emulsifier alkyl phenol polyoxyethylene ether and 0.2% dispersing agent neopelex are sequentially added afterwards, needed for adding
The methyl methacrylate of monomer 40%, 3% acrylamide and 2% function monomer tertiary ethylene carbonate, then in 7000r
The emulsified 60min of revolving speed adds the chain initiator ammonium persulfate of required 0.1%, 1% PH stabilizer sodium bicarbonate and 1%
PH regulator N, N- dimethylethanolamine, control solution pH value are 7；
(5) water-based emulsion core-shell structure constructs: isothermal reaction vessel temp in (4) being adjusted to 90 DEG C, by the pre- core cream in (3)
Liquid enters dropwise in (4) in solution, rate of addition 6ml/min, and the fire-type poly- third that 3h obtains high solids content is kept the temperature after dripping
Olefin(e) acid resin water-based emulsion；
(6) using the high solids content fire-type polyacrylic resin water-based emulsion of step (5) preparation as film forming agent, 1% is sequentially added
Dispersing agent pelopon A, 0.4% drier dibutyl tin dilaurate, 0.5% antisettling agent bentonite,
1% defoaming agent poly alkyl alcohol ether compound, 0.02% preservative benzimidazole ester type compound, 0.02% anti skinning agent first
Ethyl ketone oxime compound, 0.01% levelling agent polyacrylic acid and 15% coloring pigment and 0.5% negative oxygen ion releasing agent,
And by high-speed shearing machine high speed dispersion, high-performance fire-resistant type Environmental Protective Water-paint is prepared.
Embodiment 4
A kind of Flame-retardant acrylic acid cold coating of slow releasing negative oxygen ion and preparation method thereof, includes the following steps and technique item
Part:
(1) 85% water, 3% nitrogen phosphorus system the preparation of reaction-type flame-retarding molecular modification precursor liquid: are sequentially added into reaction vessel
Column fire retardant include 1.5% ammonium polyphosphate, 1.5% polycarbonate polyurethane, 2% flame retardancy synergists diethyl hypo-aluminum orthophosphate,
1.5% carbon forming agent polyamide, and carry out high-speed stirred and be mixed to get precursor liquid；
(2) 0.1% emulsifier alkyl phenol polyoxy flame-retardant modified emulsion preparation process: is added into the reaction precursor liquid of step (1)
Vinethene and 0.1% dispersing agent neopelex, and in the emulsion process of emulsification pretreatment blender successively dropwise plus
Enter 20% annular phosphate flame retardant, 1% melamine, 1% protecting colloid hydroxyethyl cellulose, can obtain height
The fire-retardant agent emulsion of even dispersion, and place it in heating reaction vessel and kept for 87 DEG C of temperature, the stirring of time 5h is reacted；
(3) it is total that flame-retardant modified lotion completely reacted in appropriate step (2) preparation of pre- core lotion: is added in isothermal reaction container
The sample of quality 40%, sequentially add required function monomer include 15% methyl methacrylate, 30% butyl acrylate,
2% acrylic acid and after 2min is mixed, is added 0.5% emulsifier alkyl phenol polyoxyethylene ether and 0.5% dispersing agent 12
Sodium alkyl benzene sulfonate is emulsified, revolving speed 7000r, time 5min.0.1% required chain is then added dropwise respectively to draw
Agent ammonium persulfate, 1% PH stabilizer sodium bicarbonate and 1% PH regulator N, N- dimethylethanolamine are sent out, so that pH value controls
It is 10, constant temperature pot temperature is adjusted to 90 DEG C, after keeping temperature 60min, completes seeded emulsion polymerization；
(4) preparation of pre- shell lotion: the sample of flame-retardant modified lotion gross mass 60% completely reacted in a certain amount of step (2) is taken, so
1% emulsifier alkyl phenol polyoxyethylene ether and 0.2% dispersing agent neopelex are sequentially added afterwards, needed for adding
The methyl methacrylate of monomer 40%, 3% acrylamide and 2% function monomer tertiary ethylene carbonate, then in 7000r
The emulsified 60min of revolving speed adds the chain initiator ammonium persulfate of required 0.1%, 1% PH stabilizer sodium bicarbonate and 1%
PH regulator N, N- dimethylethanolamine, control solution pH value are 7；
(5) water-based emulsion core-shell structure constructs: isothermal reaction vessel temp in (4) being adjusted to 90 DEG C, by the pre- core cream in (3)
Liquid enters dropwise in (4) in solution, rate of addition 6ml/min, and the fire-type poly- third that 3h obtains high solids content is kept the temperature after dripping
Olefin(e) acid resin water-based emulsion；
(6) using the high solids content fire-type polyacrylic resin water-based emulsion of step (5) preparation as film forming agent, 1% is sequentially added
Dispersing agent pelopon A, 0.4% drier dibutyl tin dilaurate, 0.5% antisettling agent bentonite,
1% defoaming agent poly alkyl alcohol ether compound, 0.02% preservative benzimidazole ester type compound, 0.02% anti skinning agent first
Ethyl ketone oxime compound, 0.01% levelling agent polyacrylic acid and 15% coloring pigment and 0.5% negative oxygen ion releasing agent,
And by high-speed shearing machine high speed dispersion, high-performance fire-resistant type Environmental Protective Water-paint is prepared.
Embodiment 5
A kind of Flame-retardant acrylic acid cold coating of slow releasing negative oxygen ion and preparation method thereof, includes the following steps and technique item
Part:
(1) 85% water, 2% nitrogen phosphorus system the preparation of reaction-type flame-retarding molecular modification precursor liquid: are sequentially added into reaction vessel
Column fire retardant include 1.5% ammonium polyphosphate, 0.5% polycarbonate polyurethane, 0.5% flame retardancy synergists diethyl hypophosphorous acid
Aluminium, 2% carbon forming agent polyamide, and carry out high-speed stirred and be mixed to get precursor liquid；
(2) 0.2% emulsifier alkyl phenol polyoxy flame-retardant modified emulsion preparation process: is added into the reaction precursor liquid of step (1)
Vinethene and 0.15% dispersing agent neopelex, and in the emulsion process of emulsification pretreatment blender successively dropwise
Be added 20% annular phosphate flame retardant, 1% melamine, 1% protecting colloid hydroxyethyl cellulose, can obtain height
Evenly dispersed fire-retardant agent emulsion, and place it in heating reaction vessel and kept for 90 DEG C of temperature, the stirring of time 3h is reacted；
(3) it is total that flame-retardant modified lotion completely reacted in appropriate step (2) preparation of pre- core lotion: is added in isothermal reaction container
The sample of quality 40%, sequentially add required function monomer include 15% methyl methacrylate, 30% butyl acrylate,
2% acrylic acid and after 2min is mixed, is added 0.5% emulsifier alkyl phenol polyoxyethylene ether and 0.5% dispersing agent 12
Sodium alkyl benzene sulfonate is emulsified, revolving speed 7000r, time 5min.0.1% required chain is then added dropwise respectively to draw
Agent ammonium persulfate, 1% PH stabilizer sodium bicarbonate and 1% PH regulator N, N- dimethylethanolamine are sent out, so that pH value controls
It is 10, constant temperature pot temperature is adjusted to 90 DEG C, after keeping temperature 60min, completes seeded emulsion polymerization；
(4) preparation of pre- shell lotion: the sample of flame-retardant modified lotion gross mass 60% completely reacted in a certain amount of step (2) is taken, so
1% emulsifier alkyl phenol polyoxyethylene ether and 0.2% dispersing agent neopelex are sequentially added afterwards, needed for adding
The methyl methacrylate of monomer 40%, 3% acrylamide and 2% function monomer tertiary ethylene carbonate, then in 7000r
The emulsified 60min of revolving speed adds the chain initiator ammonium persulfate of required 0.1%, 1% PH stabilizer sodium bicarbonate and 1%
PH regulator N, N- dimethylethanolamine, control solution pH value are 7；
(5) water-based emulsion core-shell structure constructs: isothermal reaction vessel temp in (4) being adjusted to 90 DEG C, by the pre- core cream in (3)
Liquid enters dropwise in (4) in solution, rate of addition 6ml/min, and the fire-type poly- third that 3h obtains high solids content is kept the temperature after dripping
Olefin(e) acid resin water-based emulsion；
(6) using the high solids content fire-type polyacrylic resin water-based emulsion of step (5) preparation as film forming agent, 1% is sequentially added
Dispersing agent pelopon A, 0.4% drier dibutyl tin dilaurate, 0.5% antisettling agent bentonite,
1% defoaming agent poly alkyl alcohol ether compound, 0.02% preservative benzimidazole ester type compound, 0.02% anti skinning agent first
Ethyl ketone oxime compound, 0.01% levelling agent polyacrylic acid and 15% coloring pigment and 0.5% negative oxygen ion releasing agent,
And by high-speed shearing machine high speed dispersion, high-performance fire-resistant type Environmental Protective Water-paint is prepared.
Embodiment 6
A kind of Flame-retardant acrylic acid cold coating of slow releasing negative oxygen ion and preparation method thereof, includes the following steps and technique item
Part:
(1) 90% water, 2% nitrogen phosphorus system the preparation of reaction-type flame-retarding molecular modification precursor liquid: are sequentially added into reaction vessel
Column fire retardant include 1.5% melamine, 0.5% polycarbonate polyurethane, 1% flame retardancy synergists diethyl hypo-aluminum orthophosphate,
2% carbon forming agent phenolic resin, and carry out high-speed stirred and be mixed to get precursor liquid；
(2) 0.2% emulsifier alkyl phenol polyoxy flame-retardant modified emulsion preparation process: is added into the reaction precursor liquid of step (1)
Vinethene and 0.15% dispersing agent neopelex, and in the emulsion process of emulsification pretreatment blender successively dropwise
Be added 20% annular phosphate flame retardant, 1% melamine, 1% protecting colloid hydroxyethyl cellulose, can obtain height
Evenly dispersed fire-retardant agent emulsion, and place it in heating reaction vessel and kept for 90 DEG C of temperature, the stirring of time 3h is reacted；
(3) it is total that flame-retardant modified lotion completely reacted in appropriate step (2) preparation of pre- core lotion: is added in isothermal reaction container
The sample of quality 40%, sequentially add required function monomer include 15% methyl methacrylate, 30% butyl acrylate,
2% acrylic acid and after 2min is mixed, is added 0.5% emulsifier alkyl phenol polyoxyethylene ether and 0.5% dispersing agent 12
Sodium alkyl benzene sulfonate is emulsified, revolving speed 7000r, time 5min.0.1% required chain is then added dropwise respectively to draw
Agent ammonium persulfate, 1% PH stabilizer sodium bicarbonate and 1% PH regulator N, N- dimethylethanolamine are sent out, so that pH value controls
It is 10, constant temperature pot temperature is adjusted to 90 DEG C, after keeping temperature 60min, completes seeded emulsion polymerization；
(4) preparation of pre- shell lotion: the sample of flame-retardant modified lotion gross mass 60% completely reacted in a certain amount of step (2) is taken, so
1% emulsifier alkyl phenol polyoxyethylene ether and 0.2% dispersing agent neopelex are sequentially added afterwards, needed for adding
The methyl methacrylate of monomer 40%, 3% acrylamide and 2% function monomer tertiary ethylene carbonate, then in 7000r
The emulsified 60min of revolving speed adds the chain initiator ammonium persulfate of required 0.1%, 1% PH stabilizer sodium bicarbonate and 1%
PH regulator N, N- dimethylethanolamine, control solution pH value are 7；
(5) water-based emulsion core-shell structure constructs: isothermal reaction vessel temp in (4) being adjusted to 90 DEG C, by the pre- core cream in (3)
Liquid enters dropwise in (4) in solution, rate of addition 6ml/min, and the fire-type poly- third that 3h obtains high solids content is kept the temperature after dripping
Olefin(e) acid resin water-based emulsion；
(6) using the high solids content fire-type polyacrylic resin water-based emulsion of step (5) preparation as film forming agent, 1% is sequentially added
Dispersing agent pelopon A, 0.4% drier dibutyl tin dilaurate, 0.5% antisettling agent bentonite,
1% defoaming agent poly alkyl alcohol ether compound, 0.02% preservative benzimidazole ester type compound, 0.02% anti skinning agent first
Ethyl ketone oxime compound, 0.01% levelling agent polyacrylic acid and 15% coloring pigment and 0.5% negative oxygen ion releasing agent,
And by high-speed shearing machine high speed dispersion, high-performance fire-resistant type Environmental Protective Water-paint is prepared.
Embodiment 7
A kind of Flame-retardant acrylic acid cold coating of slow releasing negative oxygen ion and preparation method thereof, includes the following steps and technique item
Part:
(1) 90% water, 8% nitrogen phosphorus system the preparation of reaction-type flame-retarding molecular modification precursor liquid: are sequentially added into reaction vessel
Column fire retardant include 4% melamine, 4% polycarbonate polyurethane, 2% flame retardancy synergists diethyl hypo-aluminum orthophosphate, 1.5%
Carbon forming agent phenolic resin, and carry out high-speed stirred and be mixed to get precursor liquid；
(2) 0.2% emulsifier alkyl phenol polyoxy flame-retardant modified emulsion preparation process: is added into the reaction precursor liquid of step (1)
Vinethene and 0.15% dispersing agent neopelex, and in the emulsion process of emulsification pretreatment blender successively dropwise
Be added 20% annular phosphate flame retardant, 1% melamine, 1% protecting colloid hydroxyethyl cellulose, can obtain height
Evenly dispersed fire-retardant agent emulsion, and place it in heating reaction vessel and kept for 90 DEG C of temperature, the stirring of time 3h is reacted；
(3) it is total that flame-retardant modified lotion completely reacted in appropriate step (2) preparation of pre- core lotion: is added in isothermal reaction container
The sample of quality 40%, sequentially add required function monomer include 15% methyl methacrylate, 30% butyl acrylate,
2% acrylic acid and after 2min is mixed, is added 0.5% emulsifier alkyl phenol polyoxyethylene ether and 0.5% dispersing agent 12
Sodium alkyl benzene sulfonate is emulsified, revolving speed 7000r, time 5min.0.1% required chain is then added dropwise respectively to draw
Agent ammonium persulfate, 1% PH stabilizer sodium bicarbonate and 1% PH regulator N, N- dimethylethanolamine are sent out, so that pH value controls
It is 10, constant temperature pot temperature is adjusted to 90 DEG C, after keeping temperature 60min, completes seeded emulsion polymerization；
(4) preparation of pre- shell lotion: the sample of flame-retardant modified lotion gross mass 60% completely reacted in a certain amount of step (2) is taken, so
1% emulsifier alkyl phenol polyoxyethylene ether and 0.2% dispersing agent neopelex are sequentially added afterwards, needed for adding
The methyl methacrylate of monomer 40%, 3% acrylamide and 2% function monomer tertiary ethylene carbonate, then in 7000r
The emulsified 60min of revolving speed adds the chain initiator ammonium persulfate of required 0.1%, 1% PH stabilizer sodium bicarbonate and 1%
PH regulator N, N- dimethylethanolamine, control solution pH value are 7；
(5) water-based emulsion core-shell structure constructs: isothermal reaction vessel temp in (4) being adjusted to 90 DEG C, by the pre- core cream in (3)
Liquid enters dropwise in (4) in solution, rate of addition 6ml/min, and the fire-type poly- third that 3h obtains high solids content is kept the temperature after dripping
Olefin(e) acid resin water-based emulsion；
(6) it using the high solids content fire-type polyacrylic resin water-based emulsion of step (5) preparation as film forming agent, sequentially adds
0.5% dispersing agent pelopon A, 0.4% drier dibutyl tin dilaurate, 0.5% antisettling agent are swollen
Profit soil, 1% defoaming agent poly alkyl alcohol ether compound, 0.02% preservative benzimidazole ester type compound, 0.02% anti-skinning
Agent methyl ethyl ketoxime compound, 0.01% levelling agent polyacrylic acid and 15% coloring pigment and 0.5% negative oxygen ion release
Agent, and by high-speed shearing machine high speed dispersion, prepare high-performance fire-resistant type Environmental Protective Water-paint.
Embodiment 8
A kind of Flame-retardant acrylic acid cold coating of slow releasing negative oxygen ion and preparation method thereof, includes the following steps and technique item
Part:
(1) 80% water, 2% nitrogen phosphorus system the preparation of reaction-type flame-retarding molecular modification precursor liquid: are sequentially added into reaction vessel
Column fire retardant include 1% melamine, 1% polycarbonate polyurethane, 2% flame retardancy synergists diethyl hypo-aluminum orthophosphate, 5%
Carbon forming agent phenolic resin, and carry out high-speed stirred and be mixed to get precursor liquid；
(2) 0.2% emulsifier alkyl phenol polyoxy flame-retardant modified emulsion preparation process: is added into the reaction precursor liquid of step (1)
Vinethene and 0.15% dispersing agent neopelex, and in the emulsion process of emulsification pretreatment blender successively dropwise
Be added 25% annular phosphate flame retardant, 1% melamine, 1% protecting colloid hydroxyethyl cellulose, can obtain height
Evenly dispersed fire-retardant agent emulsion, and place it in heating reaction vessel and kept for 90 DEG C of temperature, the stirring of time 3h is reacted；
(3) it is total that flame-retardant modified lotion completely reacted in appropriate step (2) preparation of pre- core lotion: is added in isothermal reaction container
The sample of quality 40%, sequentially add required function monomer include 15% methyl methacrylate, 30% butyl acrylate,
2% acrylic acid and after 2min is mixed, is added 0.5% emulsifier alkyl phenol polyoxyethylene ether and 0.5% dispersing agent 12
Sodium alkyl benzene sulfonate is emulsified, revolving speed 7000r, time 5min.0.1% required chain is then added dropwise respectively to draw
Agent ammonium persulfate, 1% PH stabilizer sodium bicarbonate and 1% PH regulator N, N- dimethylethanolamine are sent out, so that pH value controls
It is 10, constant temperature pot temperature is adjusted to 90 DEG C, after keeping temperature 60min, completes seeded emulsion polymerization；
(4) preparation of pre- shell lotion: the sample of flame-retardant modified lotion gross mass 60% completely reacted in a certain amount of step (2) is taken, so
1% emulsifier alkyl phenol polyoxyethylene ether and 0.2% dispersing agent neopelex are sequentially added afterwards, needed for adding
The methyl methacrylate of monomer 40%, 3% acrylamide and 2% function monomer tertiary ethylene carbonate, then in 7000r
The emulsified 60min of revolving speed adds the chain initiator ammonium persulfate of required 0.1%, 1% PH stabilizer sodium bicarbonate and 1%
PH regulator N, N- dimethylethanolamine, control solution pH value are 7；
(5) water-based emulsion core-shell structure constructs: isothermal reaction vessel temp in (4) being adjusted to 90 DEG C, by the pre- core cream in (3)
Liquid enters dropwise in (4) in solution, rate of addition 6ml/min, and the fire-type poly- third that 3h obtains high solids content is kept the temperature after dripping
Olefin(e) acid resin water-based emulsion；
(6) using the high solids content fire-type polyacrylic resin water-based emulsion of step (5) preparation as film forming agent, 1% is sequentially added
Dispersing agent pelopon A, 0.4% drier dibutyl tin dilaurate, 0.5% antisettling agent bentonite,
1% defoaming agent poly alkyl alcohol ether compound, 0.02% preservative benzimidazole ester type compound, 0.02% anti skinning agent first
Ethyl ketone oxime compound, 0.01% levelling agent polyacrylic acid and 15% coloring pigment and 0.5% negative oxygen ion releasing agent,
And by high-speed shearing machine high speed dispersion, high-performance fire-resistant type Environmental Protective Water-paint is prepared.
Embodiment 9
A kind of Flame-retardant acrylic acid cold coating of slow releasing negative oxygen ion and preparation method thereof, includes the following steps and technique item
Part:
(1) 85% water, 5% nitrogen phosphorus system the preparation of reaction-type flame-retarding molecular modification precursor liquid: are sequentially added into reaction vessel
Column fire retardant include 2% melamine, 3% polycarbonate polyurethane, 2% flame retardancy synergists diethyl hypo-aluminum orthophosphate, 5%
Carbon forming agent phenolic resin, and carry out high-speed stirred and be mixed to get precursor liquid；
(2) 0.2% emulsifier alkyl phenol polyoxy flame-retardant modified emulsion preparation process: is added into the reaction precursor liquid of step (1)
Vinethene and 0.15% dispersing agent neopelex, and in the emulsion process of emulsification pretreatment blender successively dropwise
Be added 25% annular phosphate flame retardant, 1% melamine, 1% protecting colloid hydroxyethyl cellulose, can obtain height
Evenly dispersed fire-retardant agent emulsion, and place it in heating reaction vessel and kept for 90 DEG C of temperature, the stirring of time 3h is reacted；
(3) it is total that flame-retardant modified lotion completely reacted in appropriate step (2) preparation of pre- core lotion: is added in isothermal reaction container
The sample of quality 40%, sequentially add required function monomer include 15% methyl methacrylate, 30% butyl acrylate,
2% acrylic acid and after 2min is mixed, is added 0.5% emulsifier alkyl phenol polyoxyethylene ether and 0.5% dispersing agent 12
Sodium alkyl benzene sulfonate is emulsified, revolving speed 7000r, time 5min.0.1% required chain is then added dropwise respectively to draw
Agent ammonium persulfate, 1% PH stabilizer sodium bicarbonate and 1% PH regulator N, N- dimethylethanolamine are sent out, so that pH value controls
It is 10, constant temperature pot temperature is adjusted to 90 DEG C, after keeping temperature 60min, completes seeded emulsion polymerization；
(4) preparation of pre- shell lotion: the sample of flame-retardant modified lotion gross mass 60% completely reacted in a certain amount of step (2) is taken, so
1% emulsifier alkyl phenol polyoxyethylene ether and 0.2% dispersing agent neopelex are sequentially added afterwards, needed for adding
The methyl methacrylate of monomer 40%, 3% acrylamide and 2% function monomer tertiary ethylene carbonate, then in 7000r
The emulsified 60min of revolving speed adds the chain initiator ammonium persulfate of required 0.1%, 1% PH stabilizer sodium bicarbonate and 1%
PH regulator N, N- dimethylethanolamine, control solution pH value are 7；
(5) water-based emulsion core-shell structure constructs: isothermal reaction vessel temp in (4) being adjusted to 90 DEG C, by the pre- core cream in (3)
Liquid enters dropwise in (4) in solution, rate of addition 6ml/min, and the fire-type poly- third that 3h obtains high solids content is kept the temperature after dripping
Olefin(e) acid resin water-based emulsion；
(6) using the high solids content fire-type polyacrylic resin water-based emulsion of step (5) preparation as film forming agent, 1% is sequentially added
Dispersing agent pelopon A, 0.4% drier dibutyl tin dilaurate, 0.5% antisettling agent bentonite,
1% defoaming agent poly alkyl alcohol ether compound, 0.02% preservative benzimidazole ester type compound, 0.02% anti skinning agent first
Ethyl ketone oxime compound, 0.01% levelling agent polyacrylic acid and 15% coloring pigment and 0.5% negative oxygen ion releasing agent,
And by high-speed shearing machine high speed dispersion, high-performance fire-resistant type Environmental Protective Water-paint is prepared.
Embodiment 10
A kind of Flame-retardant acrylic acid cold coating of slow releasing negative oxygen ion and preparation method thereof, includes the following steps and technique item
Part:
(1) 80% water, 6% nitrogen phosphorus system the preparation of reaction-type flame-retarding molecular modification precursor liquid: are sequentially added into reaction vessel
Column fire retardant include 3% melamine, 3% polycarbonate polyurethane, 2% flame retardancy synergists diethyl hypo-aluminum orthophosphate, 4%
Carbon forming agent phenolic resin, and carry out high-speed stirred and be mixed to get precursor liquid；
(2) 0.2% emulsifier alkyl phenol polyoxy flame-retardant modified emulsion preparation process: is added into the reaction precursor liquid of step (1)
Vinethene and 0.15% dispersing agent neopelex, and in the emulsion process of emulsification pretreatment blender successively dropwise
Be added 25% annular phosphate flame retardant, 1% melamine, 1% protecting colloid hydroxyethyl cellulose, can obtain height
Evenly dispersed fire-retardant agent emulsion, and place it in heating reaction vessel and kept for 90 DEG C of temperature, the stirring of time 3h is reacted；
(3) it is total that flame-retardant modified lotion completely reacted in appropriate step (2) preparation of pre- core lotion: is added in isothermal reaction container
The sample of quality 40%, sequentially add required function monomer include 15% methyl methacrylate, 30% butyl acrylate,
2% acrylic acid and after 2min is mixed, is added 0.5% emulsifier alkyl phenol polyoxyethylene ether and 0.5% dispersing agent 12
Sodium alkyl benzene sulfonate is emulsified, revolving speed 7000r, time 5min.0.1% required chain is then added dropwise respectively to draw
Agent ammonium persulfate, 1% PH stabilizer sodium bicarbonate and 1% PH regulator N, N- dimethylethanolamine are sent out, so that pH value controls
It is 10, constant temperature pot temperature is adjusted to 90 DEG C, after keeping temperature 60min, completes seeded emulsion polymerization；
(4) preparation of pre- shell lotion: the sample of flame-retardant modified lotion gross mass 60% completely reacted in a certain amount of step (2) is taken, so
1% emulsifier alkyl phenol polyoxyethylene ether and 0.2% dispersing agent neopelex are sequentially added afterwards, needed for adding
The methyl methacrylate of monomer 40%, 3% acrylamide and 2% function monomer tertiary ethylene carbonate, then in 7000r
The emulsified 60min of revolving speed adds the chain initiator ammonium persulfate of required 0.1%, 1% PH stabilizer sodium bicarbonate and 1%
PH regulator N, N- dimethylethanolamine, control solution pH value are 7；
(5) water-based emulsion core-shell structure constructs: isothermal reaction vessel temp in (4) being adjusted to 90 DEG C, by the pre- core cream in (3)
Liquid enters dropwise in (4) in solution, rate of addition 6ml/min, and the fire-type poly- third that 3h obtains high solids content is kept the temperature after dripping
Olefin(e) acid resin water-based emulsion；
(6) using the high solids content fire-type polyacrylic resin water-based emulsion of step (5) preparation as film forming agent, 1% is sequentially added
Dispersing agent pelopon A, 0.4% drier dibutyl tin dilaurate, 0.5% antisettling agent bentonite,
1% defoaming agent poly alkyl alcohol ether compound, 0.02% preservative benzimidazole ester type compound, 0.02% anti skinning agent first
Ethyl ketone oxime compound, 0.01% levelling agent polyacrylic acid and 15% coloring pigment and 0.5% negative oxygen ion releasing agent,
And by high-speed shearing machine high speed dispersion, high-performance fire-resistant type Environmental Protective Water-paint is prepared.
Claims (9)
1. a kind of Flame-retardant acrylic acid cold coating of slow releasing negative oxygen ion and preparation method thereof, it is characterised in that including as follows
Step and process conditions:
(1) water (80% ~ 90%), nitrogen phosphorus system the preparation of reaction-type flame-retarding molecular modification precursor liquid: are sequentially added into reaction vessel
Column fire retardant (1% ~ 8%), flame retardancy synergists (0.1% ~ 2.5%), carbon forming agent (0.5% ~ 5%), and carry out high-speed stirred and be mixed to get
Precursor liquid；
(2) flame-retardant modified emulsion preparation process: emulsifier (0.1% ~ 2%) is added into the reaction precursor liquid of step (1) and disperses
Agent (0.1% ~ 1%), and be successively added dropwise in the emulsion process of emulsification pretreatment blender annular phosphate flame retardant (15% ~
25%), melamine (1% ~ 5%), protecting colloid (0.1% ~ 5%) can obtain the fire-retardant agent emulsion of high uniformity dispersion, and will
It is placed in heating reaction vessel and keeps temperature (50 ~ 100 DEG C), and time (1h ~ 10h) stirring is reacted；
(3) it is total that flame-retardant modified lotion completely reacted in appropriate step (2) preparation of pre- core lotion: is added in isothermal reaction container
The sample of quality 20% ~ 60%, sequentially adding required function monomer includes methyl methacrylate (8% ~ 20%), butyl acrylate
(20% ~ 40%), acrylic acid (2% ~ 8%) and after 2min is mixed, be added emulsifier (0.2% ~ 5%) and dispersing agent (0.3% ~
1.6%) it is emulsified, revolving speed is 1000 ~ 7000r, and the time is 1 ~ 10min.
2. required chain initiator (0.01% ~ 0.5%), PH stabilizer (0.01% ~ 1.5%) and PH are then added dropwise respectively to adjust
Agent (0.01% ~ 2.5%) so that pH value control be 10, constant temperature pot temperature is adjusted to 30 DEG C ~ 100 DEG C, keep the temperature 10 ~
After 80min, seeded emulsion polymerization is completed；
(4) preparation of pre- shell lotion: the sample of flame-retardant modified lotion gross mass 40%-80% completely reacted in a certain amount of step (2) is taken
Then product sequentially add emulsifier (0.1% ~ 2.5%) and dispersing agent (0.1% ~ 1.5%), add required monomer metering system
Sour methyl esters (35% ~ 45%), acrylamide (3% ~ 8%) and function monomer tertiary ethylene carbonate (1% ~ 5%), then in 1500 ~ 8000r
Emulsified 10 ~ the 160min of revolving speed adds required chain initiator (0.02% ~ 0.7%), PH stabilizer (0.02% ~ 1.8%) and PH
Regulator (0.05% ~ 3.5%), control solution pH value are 7 ~ 8；
(5) water-based emulsion core-shell structure constructs: isothermal reaction vessel temp in (4) is adjusted to 70 DEG C ~ 120 DEG C, it will be in (3)
Pre- core lotion enters dropwise in (4) in solution, and rate of addition is 0.01 ~ 10ml/min, and 1 ~ 5h is kept the temperature after dripping and obtains large arch dam
The fire-type polyacrylic resin water-based emulsion of amount；
(6) it using the high solids content fire-type polyacrylic resin water-based emulsion of step (5) preparation as film forming agent, sequentially adds point
Powder (accounting for 0.05 ~ 1.5%), drier (accounting for 0.02 ~ 1.0%), antisettling agent (accounting for 0.01 ~ 2.5%), defoaming agent (account for 0.5 ~
1.5%), preservative (accounting for 0.001 ~ 0.05%), anti skinning agent (accounting for 0.02 ~ 2.5%), levelling agent (accounting for 0.01 ~ 3.5%), pigment (account for
5 ~ 35%) and negative oxygen ion cast charge (accounting for 0.5% ~ 2%), and by high-speed shearing machine high speed dispersion, high-performance fire-resistant is prepared
The aqueous acrylic resin paint of the releasable negative oxygen ion of type.
3. Flame-retardant acrylic acid cold coating and its preparation side of a kind of slow releasing negative oxygen ion according to claim 1
Method, it is characterised in that (1) the nitrogen phosphorus fire-retardant agent described in is that ammonium polyphosphate, melamine polyphosphate and polycarbonate are poly-
The thermal decomposition temperature of the two of them of urethane, the two is different, can achieve cooperative flame retardant effect.
4. Flame-retardant acrylic acid cold coating and its preparation side of a kind of slow releasing negative oxygen ion according to claim 1
Method, it is characterised in that the flame retardancy synergists are that diethylphosphate aluminium, the one of which of diethyl hypo-aluminum orthophosphate or two kinds are mixed
It closes, the flame retardant effect of nitrogen phosphorus fire-retardant agent can be enhanced in the case where not influencing acrylic resin performance.
5. Flame-retardant acrylic acid cold coating and its preparation side of a kind of slow releasing negative oxygen ion according to claim 1
Method, it is characterised in that the carbon forming agent be phenolic resin, the one of which of polyamide or two kinds mixing, can be in material
Surface forms protection layer of charcoal；The water of addition is common neutral water quality.
6. Flame-retardant acrylic acid cold coating and its preparation side of a kind of slow releasing negative oxygen ion according to claim 1
Method, it is characterised in that the protecting colloid is hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxybutyl cellulose, acetate fiber
The one of which of element or two kinds of mixing or two or more mixtures.
7. Flame-retardant acrylic acid cold coating and its preparation side of a kind of slow releasing negative oxygen ion according to claim 1
Method, it is characterised in that the emulsifier is alkyl phenol polyoxyethylene ether；Dispersing agent is neopelex.
8. Flame-retardant acrylic acid cold coating and its preparation side of a kind of slow releasing negative oxygen ion according to claim 1
Method, it is characterised in that the chain initiator is ammonium persulfate, and PH stabilizer is sodium bicarbonate, and PH regulator is N, N- dimethyl
Ethanol amine.
9. Flame-retardant acrylic acid cold coating and its preparation side of a kind of slow releasing negative oxygen ion according to claim 1
Method, it is characterised in that the dispersing agent is pelopon A；Drier is dibutyl tin dilaurate；Anti-settling
Agent is bentonite；Defoaming agent is poly alkyl alcohol ether compound；Preservative is benzimidazole ester type compound；Anti skinning agent is first and second
Ketoxime compounds；Levelling agent is polyacrylic acid；Pigment be coloring pigment, extender pigment, rust resisting pigment, special pigment wherein one
Kind；Negative oxygen ion releasing agent is laboratory self-control, can be by water under extraneous mechanical energy, chemical energy, luminous energy, electrostatic field energy effect
Or the hydrone in air is instantaneous " negative ionization ".
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112322132A (en) * | 2019-07-17 | 2021-02-05 | 烟台大学 | Preparation method of flame-retardant core-shell environment-friendly water-based resin coating |
| CN112831210A (en) * | 2020-12-31 | 2021-05-25 | 江苏极信环保科技有限公司 | Flame-retardant acrylic resin coating capable of slowly releasing negative oxygen ions and preparation method thereof |
| CN113321926A (en) * | 2021-06-05 | 2021-08-31 | 东莞市鼎誉新材料有限公司 | High-efficiency blended modified polyether TPU and application thereof |
| CN114293371A (en) * | 2021-12-21 | 2022-04-08 | 日华化学（中国）有限公司 | Flame retardant for continuous processing and preparation method thereof |
| CN115058182A (en) * | 2022-08-01 | 2022-09-16 | 牡丹江乾元智康环保科技有限公司 | Flame-retardant polyurethane coating capable of releasing negative oxygen ions and synthesis process thereof |
| CN116285558A (en) * | 2023-03-31 | 2023-06-23 | 湖北佰航建材科技有限公司 | Negative ion odor-removing water-based finishing paint for interior wall paint |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04100871A (en) * | 1989-10-31 | 1992-04-02 | Dainippon Ink & Chem Inc | Aqueous resin composition for coating metal |
| JP2004161894A (en) * | 2002-11-13 | 2004-06-10 | Aica Kogyo Co Ltd | Water-based low-contamination coating composition |
| CN101376812A (en) * | 2008-09-28 | 2009-03-04 | 中国科学技术大学 | A core-shell type silicon-containing synergistic flame retardant and preparation method thereof |
| JP2013185111A (en) * | 2012-03-08 | 2013-09-19 | Fuji Xerox Co Ltd | Acrylic copolymer, thermoplastic resin composition and molded article |
| CN104497768A (en) * | 2014-12-12 | 2015-04-08 | 南阳理工学院 | Preparation method of acrylic ester resin coatings and adhesives with flame retardance and waterproofness |
| CN108976977A (en) * | 2018-07-24 | 2018-12-11 | 清远粤绿新材料技术有限公司 | Graphene in-situ polymerization denatured conductive anticorrosion water-soluble latex solution and its manufacturing method |
| CN109423149A (en) * | 2017-07-04 | 2019-03-05 | 南京新莱尔材料科技有限公司 | A kind of fire-type Environmental Protective Water-paint and its manufacturing method |
| AU2020102176A4 (en) * | 2020-09-08 | 2020-11-12 | Yantai University | The method for preparing a environment-friendly flame retardant water-borne acrylic resin coating with core shell structure |
-
2017
- 2017-09-11 CN CN201710812082.3A patent/CN109836954A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04100871A (en) * | 1989-10-31 | 1992-04-02 | Dainippon Ink & Chem Inc | Aqueous resin composition for coating metal |
| JP2004161894A (en) * | 2002-11-13 | 2004-06-10 | Aica Kogyo Co Ltd | Water-based low-contamination coating composition |
| CN101376812A (en) * | 2008-09-28 | 2009-03-04 | 中国科学技术大学 | A core-shell type silicon-containing synergistic flame retardant and preparation method thereof |
| JP2013185111A (en) * | 2012-03-08 | 2013-09-19 | Fuji Xerox Co Ltd | Acrylic copolymer, thermoplastic resin composition and molded article |
| CN104497768A (en) * | 2014-12-12 | 2015-04-08 | 南阳理工学院 | Preparation method of acrylic ester resin coatings and adhesives with flame retardance and waterproofness |
| CN109423149A (en) * | 2017-07-04 | 2019-03-05 | 南京新莱尔材料科技有限公司 | A kind of fire-type Environmental Protective Water-paint and its manufacturing method |
| CN108976977A (en) * | 2018-07-24 | 2018-12-11 | 清远粤绿新材料技术有限公司 | Graphene in-situ polymerization denatured conductive anticorrosion water-soluble latex solution and its manufacturing method |
| AU2020102176A4 (en) * | 2020-09-08 | 2020-11-12 | Yantai University | The method for preparing a environment-friendly flame retardant water-borne acrylic resin coating with core shell structure |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112322132A (en) * | 2019-07-17 | 2021-02-05 | 烟台大学 | Preparation method of flame-retardant core-shell environment-friendly water-based resin coating |
| CN112322132B (en) * | 2019-07-17 | 2023-04-07 | 烟台大学 | Preparation method of flame-retardant core-shell environment-friendly water-based resin coating |
| CN112831210A (en) * | 2020-12-31 | 2021-05-25 | 江苏极信环保科技有限公司 | Flame-retardant acrylic resin coating capable of slowly releasing negative oxygen ions and preparation method thereof |
| CN113321926A (en) * | 2021-06-05 | 2021-08-31 | 东莞市鼎誉新材料有限公司 | High-efficiency blended modified polyether TPU and application thereof |
| CN114293371A (en) * | 2021-12-21 | 2022-04-08 | 日华化学（中国）有限公司 | Flame retardant for continuous processing and preparation method thereof |
| CN114293371B (en) * | 2021-12-21 | 2023-11-24 | 日华化学（中国）有限公司 | Flame retardant for continuous processing and preparation method thereof |
| CN115058182A (en) * | 2022-08-01 | 2022-09-16 | 牡丹江乾元智康环保科技有限公司 | Flame-retardant polyurethane coating capable of releasing negative oxygen ions and synthesis process thereof |
| CN116285558A (en) * | 2023-03-31 | 2023-06-23 | 湖北佰航建材科技有限公司 | Negative ion odor-removing water-based finishing paint for interior wall paint |
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Application publication date: 20190604 |