CN109824944A - A kind of rubber adhesive and preparation method thereof - Google Patents
A kind of rubber adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN109824944A CN109824944A CN201910132270.0A CN201910132270A CN109824944A CN 109824944 A CN109824944 A CN 109824944A CN 201910132270 A CN201910132270 A CN 201910132270A CN 109824944 A CN109824944 A CN 109824944A
- Authority
- CN
- China
- Prior art keywords
- parts
- rubber adhesive
- bisphenol
- white carbon
- rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 45
- 239000005060 rubber Substances 0.000 title claims abstract description 45
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 43
- 239000000853 adhesive Substances 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000006229 carbon black Substances 0.000 claims abstract description 23
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims abstract description 20
- 229940106691 bisphenol a Drugs 0.000 claims abstract description 14
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229960004011 methenamine Drugs 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 235000019241 carbon black Nutrition 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 230000000505 pernicious effect Effects 0.000 abstract 1
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 12
- 239000000463 material Substances 0.000 description 7
- 238000004073 vulcanization Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 238000010058 rubber compounding Methods 0.000 description 4
- 238000004513 sizing Methods 0.000 description 4
- XQJMXPAEFMWDOZ-UHFFFAOYSA-N 3exo-benzoyloxy-tropane Natural products CN1C(C2)CCC1CC2OC(=O)C1=CC=CC=C1 XQJMXPAEFMWDOZ-UHFFFAOYSA-N 0.000 description 3
- QQXLDOJGLXJCSE-UHFFFAOYSA-N N-methylnortropinone Natural products C1C(=O)CC2CCC1N2C QQXLDOJGLXJCSE-UHFFFAOYSA-N 0.000 description 3
- QIZDQFOVGFDBKW-DHBOJHSNSA-N Pseudotropine Natural products OC1C[C@@H]2[N+](C)[C@H](C1)CC2 QIZDQFOVGFDBKW-DHBOJHSNSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- CYHOMWAPJJPNMW-JIGDXULJSA-N tropine Chemical compound C1[C@@H](O)C[C@H]2CC[C@@H]1N2C CYHOMWAPJJPNMW-JIGDXULJSA-N 0.000 description 3
- 229910001369 Brass Inorganic materials 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of rubber adhesives, it is made including following raw materials according according to following mass parts, HMMM45-55 parts, 10-15 parts of bisphenol-A, 24-42 parts of white carbon black, 3-6 parts of methenamine, the preparation method of the rubber adhesive includes the following steps, HMMM is placed in reactor, bisphenol-A, white carbon black and methenamine is sequentially added to be mixed and stirred for uniformly, obtained rubber adhesive have it is high temperature vulcanized non-discolouring, production process does not generate pernicious gas, does not pollute the good feature of light-colour rubber product, bond properties.
Description
Technical field
The present invention relates to adhesive manufacturing field, a kind of rubber adhesive and preparation method thereof is related in particular to.
Background technique
Rubber product, especially automobile tire, engine rubber damper, sebific duct, adhesive tape etc. are not single rubber
Material is formed by framework material of fibre, metal product such as steel, brass plating, zinc-plated steel and steel wire with rubber mostly
Composite material.With the development of modern industry, the requirement to this kind of composite material is higher and higher, and not requiring nothing more than product can reach
Conventional requirement and technical standard, also requires that transnormal demand, such as automobile can be met in some special cases
Tire still is able to be safely operated in the case where hypervelocity and overload.This requires in addition to reasonable sizing compound formula and suitable skeleton
Outside material, the bond properties of the two also wants sufficiently high.Product is set to remain framework material and rubber under harsh use condition
Gluing is integrated, and rubber adhesive comes into being.
Resorcinol is most common, most basic adhesive in traditional m- first-lean type system.But resorcinol is deposited
In problems, first is that it is expensive, second is that resorcinol easily distils in mixing process, a large amount of irritating smog is generated,
The health for not only seriously affecting operator, also causes the pollution of environment, and resorcinol content is easy to cause to decline,
Influence bonding effect.Therefore, we develop it is a kind of new resorcinol is substituted with bisphenol-A, to prepare the side of rubber adhesive
Method.
Summary of the invention
For various deficiencies of the prior art, it is proposed that a kind of method that can substitute resorcinol with bisphenol-A.
To achieve the above object, the invention provides the following technical scheme:
A kind of rubber adhesive, including following raw materials according are made according to following mass parts, HMMM45-55 parts, bisphenol-A 10-15
Part, 24-42 parts of white carbon black, 3-6 parts of methenamine.
Further, HMMM45 parts, 10 parts of bisphenol-A, 42 parts of white carbon black, 3 parts of methenamine.
Further, HMMM50 parts, 12 parts of bisphenol-A, 34 parts of white carbon black, 4 parts of methenamine.
Further, HMMM55 parts, 15 parts of bisphenol-A, 24 parts of white carbon black, 6 parts of methenamine.
The present invention also provides a kind of preparation method of rubber adhesive, the preparation method of the rubber adhesive includes following
Step:
S1: HMMM is placed in reactor；
S2: bisphenol-A, white carbon black and methenamine are sequentially added and is mixed and stirred for uniformly, the rubber adhesive being made.
Further, 45 parts of HMMM are placed in reactor, sequentially add 10 parts of bisphenol-As, 42 parts of white carbon blacks, 3 parts of black Lip rivers
Tropine stirs evenly to obtain the rubber adhesive.
Further, 50 parts of HMMM are placed in reactor, sequentially add 12 parts of bisphenol-As, 34 parts of white carbon blacks, 4 parts of black Lip rivers
Tropine stirs evenly to obtain the rubber adhesive.
Further, 55 parts of HMMM are placed in reactor, sequentially add 15 parts of bisphenol-As, 24 parts of white carbon blacks, 6 parts of black Lip rivers
Tropine stirs evenly to obtain the rubber adhesive.
Beneficial effects of the present invention:
1, natural rubber and various synthetic rubber and fabric or brass plating cord can be made to obtain good bonding, it can also
The bonding for improving PVC and fabric, has a wide range of application.
2, sizing material can directly be added in mixing process, crosslink reaction in vulcanization and generate adhesive effect, use
It is convenient.
3, high temperature vulcanized non-discolouring, light-colour rubber product is not polluted.
4, bond properties is good, and especially after aging, adhesiveness keeps good.
5, the plasticity of glue stuff compounding is effectively improved, heat is reduced, improves processing technology, extends time of scorch, to vulcanization
It has no adverse effects, improves vulcanization security reliability, high comprehensive performance.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
A kind of rubber adhesive, including following raw materials according are made according to following mass parts, HMMM (2,4,6- tri- [bis- (methoxyl groups
Methyl) amino] -1,3,5-triazines) 45-55 parts, 10-15 parts of bisphenol-A, 24-42 parts of white carbon black, 3-6 parts of methenamine.
Preparation method are as follows: HMMM is placed in reactor, sequentially adds bisphenol-A, white carbon black and methenamine mixing simultaneously
It stirs evenly, can be prepared by the rubber adhesive.
Embodiment one:
45 parts of HMMM are placed in reactor, 10 parts of bisphenol-As, 42 parts of white carbon blacks, 3 parts of methenamines is sequentially added, stirs
Mix uniform the rubber adhesive.
Embodiment two:
50 parts of HMMM are placed in reactor, 12 parts of bisphenol-As, 34 parts of white carbon blacks, 4 parts of methenamines is sequentially added, stirs
Mix uniform the rubber adhesive.
Embodiment three:
55 parts of HMMM are placed in reactor, 15 parts of bisphenol-As, 24 parts of white carbon blacks, 6 parts of methenamines is sequentially added, stirs
Mix uniform the rubber adhesive.
Test case:
It is kneaded using the rubber adhesive that embodiment one obtains, and is labeled as X-1, formula 1 is added.Original formulation is (no
Add rubber adhesive) as a comparison, labeled as formula 2.
Formula is as shown in table 1.
The rubber compounding that table one is kneaded
The technological parameter of rubber compounding process is as shown in table 2.
The technological parameter of 2 rubber compounding process of table
The results are shown in Table 3 for rubber compounding vulcanization.
The test result of 3 rubber compound of table vulcanization
It can be seen that being not much different after adhesive is added in formula with original formulation cure data, illustrate the adhesive to sizing material
Vulcanization characteristics has no adverse effect, and is significantly improved using H extraction performance after adhesive, illustrates to take out the H of sizing material after adhesive is added
Performance has facilitation out.
Automobile tire hose lining has been made, and has been tested using formula 1, formula 2, as a result as follows:
4 tyres durable of table and adhesion test
From table 4, it can be seen that the finished tire interlayer adhesion of rubber adhesive of the present invention on probation is higher than regular convention formula.It says
Bright rubber adhesive of the present invention has facilitation to rubber adhesion.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (8)
1. a kind of rubber adhesive, it is characterised in that: be made including following raw materials according according to following mass parts, HMMM45-55 parts, double
A10-15 parts of phenol, 24-42 parts of white carbon black, 3-6 parts of methenamine.
2. a kind of rubber adhesive according to claim 1, it is characterised in that: HMMM45 parts, 10 parts of bisphenol-A, white carbon black
42 parts, 3 parts of methenamine.
3. a kind of rubber adhesive according to claim 1, it is characterised in that: HMMM50 parts, 12 parts of bisphenol-A, white carbon black
34 parts, 4 parts of methenamine.
4. a kind of rubber adhesive according to claim 1, it is characterised in that: HMMM55 parts, 15 parts of bisphenol-A, white carbon black
24 parts, 6 parts of methenamine.
5. a kind of method for preparing any rubber adhesive of claim 1-4, it is characterised in that: the following steps are included:
S1: HMMM is placed in reactor；
S2: bisphenol-A, white carbon black and methenamine are sequentially added and is mixed and stirred for uniformly, the rubber adhesive being made.
6. a kind of preparation method of rubber adhesive according to claim 5, it is characterised in that: be placed in 45 parts of HMMM instead
It answers in device, sequentially adds 10 parts of bisphenol-As, 42 parts of white carbon blacks, 3 parts of methenamines, stir evenly to obtain the rubber adhesive.
7. a kind of rubber adhesive according to claim 5, it is characterised in that: 50 parts of HMMM are placed in reactor, then
12 parts of bisphenol-As, 34 parts of white carbon blacks, 4 parts of methenamines are sequentially added, the rubber adhesive is stirred evenly to obtain.
8. a kind of rubber adhesive according to claim 5, it is characterised in that: 55 parts of HMMM are placed in reactor, then
15 parts of bisphenol-As, 24 parts of white carbon blacks, 6 parts of methenamines are sequentially added, the rubber adhesive is stirred evenly to obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910132270.0A CN109824944A (en) | 2019-02-22 | 2019-02-22 | A kind of rubber adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910132270.0A CN109824944A (en) | 2019-02-22 | 2019-02-22 | A kind of rubber adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109824944A true CN109824944A (en) | 2019-05-31 |
Family
ID=66864000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910132270.0A Pending CN109824944A (en) | 2019-02-22 | 2019-02-22 | A kind of rubber adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109824944A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115232377A (en) * | 2021-04-23 | 2022-10-25 | 北京化工大学 | Non-pneumatic tire shear layer material and preparation method and application thereof |
| TWI880693B (en) * | 2024-03-29 | 2025-04-11 | 厚生股份有限公司 | Composite leather made of natural rubber and fiber cloth, and method for producing the same |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1330905A (en) * | 1970-02-26 | 1973-09-19 | Dunlop Holdings Ld | Vulcanizable compositions |
| US4338263A (en) * | 1979-05-04 | 1982-07-06 | The General Tire & Rubber Company | Tire cord adhesives |
| RO93229B1 (en) * | 1985-12-03 | 1987-12-31 | îNTREPRINDEREA DE MEDICAMENTE SI COLORANTI "SINTOFARM" | Adhesive composition |
| JPH111672A (en) * | 1997-06-12 | 1999-01-06 | Nok Corp | Vulcanizable adhesive composition |
| CN105008449A (en) * | 2012-12-14 | 2015-10-28 | 倍耐力轮胎股份公司 | Tyre for vehicle wheels |
| CN108751726A (en) * | 2018-08-09 | 2018-11-06 | 苏州华龙化工有限公司 | A kind of preparation method of high-strength high temperature-resistant mineral wool |
-
2019
- 2019-02-22 CN CN201910132270.0A patent/CN109824944A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1330905A (en) * | 1970-02-26 | 1973-09-19 | Dunlop Holdings Ld | Vulcanizable compositions |
| US4338263A (en) * | 1979-05-04 | 1982-07-06 | The General Tire & Rubber Company | Tire cord adhesives |
| RO93229B1 (en) * | 1985-12-03 | 1987-12-31 | îNTREPRINDEREA DE MEDICAMENTE SI COLORANTI "SINTOFARM" | Adhesive composition |
| JPH111672A (en) * | 1997-06-12 | 1999-01-06 | Nok Corp | Vulcanizable adhesive composition |
| CN105008449A (en) * | 2012-12-14 | 2015-10-28 | 倍耐力轮胎股份公司 | Tyre for vehicle wheels |
| CN108751726A (en) * | 2018-08-09 | 2018-11-06 | 苏州华龙化工有限公司 | A kind of preparation method of high-strength high temperature-resistant mineral wool |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115232377A (en) * | 2021-04-23 | 2022-10-25 | 北京化工大学 | Non-pneumatic tire shear layer material and preparation method and application thereof |
| CN115232377B (en) * | 2021-04-23 | 2024-03-26 | 北京化工大学 | A kind of non-pneumatic tire shear layer material and its preparation method and application |
| TWI880693B (en) * | 2024-03-29 | 2025-04-11 | 厚生股份有限公司 | Composite leather made of natural rubber and fiber cloth, and method for producing the same |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190531 |
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| RJ01 | Rejection of invention patent application after publication |