CN109824270A - A kind of decorative brick of diamond flash effect, colored dry granular and preparation method thereof - Google Patents
A kind of decorative brick of diamond flash effect, colored dry granular and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a kind of decorative bricks of diamond flash effect, colored dry granular and preparation method thereof, the present invention pre-processes link by increasing crystallization to diamond flash of light frit, frit itself is set to contain a great deal of and size crystal, and using the form glazing of dry granular glaze, substantially reduce crystalline glaze crystal nucleation growth required time and temperature condition, it is more suitable for current Wall or floor tile roller kilns and is rapidly fired to periodic condition in 50-90 minutes, increases use occasion.And using the decorative brick of the colour dry granular, color clear-cut individuality, the starlight as diamond is glittering, dazzling under light-illuminating, and is accompanied by that shape size is different, and the silver color oil droplet shape fine crystals speckle of clear-cut has much ornamental sense.
Description
Technical field
The present invention relates to ceramic technology field, more particularly to a kind of decorative brick of diamond flash effect, colored dry granular and
Preparation method.
Background technique
With the increasingly raising of people's living standard, to the colour system pattern of ceramic tile ornament materials, grain details, sense of touch texture
Etc. individual decorations demand it is higher and higher.
Ceramic tile is in addition to being traditional decoration material, it is also desirable to be the personalized art work.Diamond flash effect glaze belongs to crystallization
Stellar scintillation, dazzling effect is presented, with light irradiating angle and visual angle in one of glaze under the irradiation of light
Change color pattern change multiplicity, the silver color oil droplet shape fine crystals speckle of clear-cut different with shape size.
A kind of production method of placer gold glaze material of CN100537487C, describes with Fe2O3For crystallization colorant, part frit adds life
Material is prepared into glaze slip according to a certain ratio.Half fritted glaze by firing temperature, firing atmosphere, firing period, the conditions such as soaking time
Limitation influence is big more than dry granular glaze, and use scope is narrow, not with sharp industrialized production.A kind of verdigris crystalline glaze of CN100381384C and
Preparation method provides one kind with ZnO, TiO2For seed content, MnO2, CuO be colour former artistic crystallization glaze prepare, roasting
Temperature is 1150-1220 DEG C, firing period 3-4 hour, and Wall or floor tile firing period is burnt into all generally at 50-90 minute at present
Phase is partially long, greatly limits its use occasion.So far, the crystallization artistic glaze research report that really can be used to be rapidly fired to is not
It is more, and for being suitble to be rapidly fired to have diamond flash effect dry granular glaze in terms of research with regard to less.
Summary of the invention
The invention mainly solves the technical problem of providing a kind of decorative brick of diamond flash effect for being suitble to be rapidly fired to,
Colored dry granular and preparation method thereof.
In order to solve the above technical problems, the embodiment of the present invention in a first aspect, to provide a kind of diamond flash effect colour dry
Grain, the diamond flash effect colour dry granular include following component: SiO255-65%, Al2O35-15%, CaO 8-12%,
MgO 2-5%, K2O 1-3%, Na2O 3-5%, BaO 8-12%, B2O31-3%, Cr2O31.5-3%, CuO 2.5-4%,
CaF20-2%, P2O50-2%, TiO20-2%, particle size range are 12-40 mesh, 30-60 mesh, 60-120 mesh or 120-250
One of which in mesh.
In order to solve the above technical problems, the second aspect of the embodiment of the present invention, it is color to provide a kind of above-mentioned diamond flash effect
The preparation method of color dry granular, the preparation method include: the raw material for weighing following proportion: 0-15 parts of potassium albite, quartz 35-52
Part, 5-12 parts of calcite, 6-20 parts of dolomite, talcum 0-6 parts of burning, 4-14 parts of commercial alumina, 2-8 parts of borax, potassium nitrate 0-5
Part, 6-12 parts of barium carbonate, 1-8 parts of soda ash, 1-5 parts of potassium bichromate, 2-5 parts of industrial oxidation copper, 0-4 parts of fluorite, calcium phosphate 0-6
Part, 0-3 parts of titanium dioxide, 0-4 parts of chromium oxide；The above raw material is mixed, and is homogenized through 1450-1550 DEG C of melting, then
Through 1350-1400 DEG C of heat preservation Crystallizing treatment, water quenching, drying obtains frit；The frit is obtained into different mesh through different international sieves
The colored dry granular of the diamond flash effect of number range.
Wherein, the coloured silk of the diamond flash effect that the frit is obtained to different meshes range through different international sieves
Color dry granular includes: that the frit is obtained 12-40 mesh, 30-60 mesh, 60-120 mesh, 4 kinds of 120-250 mesh not through different international sieves
The colored dry granular of the diamond flash effect of same specification.
In order to solve the above technical problems, third aspect present invention, provides a kind of decorative brick of diamond flash effect, the dress
Adoring brick includes diamond flash effect colour dry granular described above.
Wherein, the decorative brick is dry by being applied with the diamond flash effect colour on the ceramic tile blank surface for having drenched overglaze
It after grain, is fired, is not thrown, half throws or throw and obtain entirely in roller kilns 1150-1200 DEG C, firing period 50-90 minutes.
Existing beneficial effect is technical solution provided by the invention compared with prior art: the feelings being different from the prior art
Condition, the present invention increase crystallization to diamond flash of light frit and pre-process link, and frit itself is made to contain a great deal of and size crystal,
And using the form glazing of dry granular glaze, crystalline glaze crystal nucleation growth required time and temperature condition are substantially reduced, it is more suitable
It closes current Wall or floor tile roller kilns and is rapidly fired to periodic condition in 50-90 minutes, increase use occasion.Diamond provided by the invention dodges
Light effect dry granular glaze improves the appreciation effect of decorative brick decoration, so that decorative brick color clear-cut individuality, as boring under light-illuminating
The same starlight of stone is glittering, dazzling, and different with shape size, the silver color oil droplet shape fine crystals spot of clear-cut
Line has much ornamental sense, decorates demand for consumer personalization and provides a kind of new selection.
Detailed description of the invention
Fig. 1 is dry granular brick glaze face effect picture prepared by the embodiment of the present invention 1；
Fig. 2 is dry granular brick glaze face effect picture prepared by the embodiment of the present invention 2；
Fig. 3 is dry granular brick glaze face effect picture prepared by the embodiment of the present invention 3；
Fig. 4 is dry granular brick glaze face effect picture prepared by the embodiment of the present invention 4.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to the accompanying drawings and embodiments, right
The present invention is further elaborated.
In being described below, for illustration and not for limitation, give many technical characteristics illustrates schematic diagram, so as to
It cuts thoroughly and understands the embodiment of the present invention.However, it will be clear to one skilled in the art that in the other realities for not having these details
It applies and the present invention also may be implemented in example.In other situations, the detailed description to well-known method is omitted, so as not to it is unnecessary
Details interfere description of the invention.
Firstly, the present invention provides a kind of diamond flash effect colour dry granular, the diamond flash effect colour dry granular include with
Lower chemical component: SiO255-65%, Al2O35-15%, CaO 8-12%, MgO 2-5%, K2O 1-3%, Na2O 3-5%,
BaO 8-12%, B2O31-3%, Cr2O31.5-3%, CuO 2.5-4%, CaF20-2%, P2O50-2%, TiO2 0-
2%, particle size range is the one of which in 12-40 mesh, 30-60 mesh, 60-120 mesh or 120-250 mesh.
Wherein, in chemical component, CaF2、P2O5、TiO2One of or it is a variety of be used as crystallization promotor.
Among these, the chemical composition and particle size range of diamond flash effect colour dry granular have diamond flash effect larger
It influences.In the case where keeping other conditions constant in chemical component, the ratio of Si/Al in adjusting component influences the color development of glaze, begins
Melt temperature, speckle size, the coefficient of expansion and shining point quantity and size.
B in formula2O3Frit beginning melting temperature is influenced greatly, to influence obviously on oil droplet shape silver color glass mark is formed.CaF2、
P2O5、TiO2Influence all reapective features of several crystallization promotors to flash of light amount of crystals and size, CaF2Promote the nucleation of crystal
Effect is obvious, so a considerable amount of tiny flash of light crystal, TiO can be obtained2Promote the effect of the growth of crystal obvious, so energy
Obtain large-sized flash of light crystal, and P2O5Then therebetween, it can promote to be nucleated but also promote growth, but also be easy to lead
Otherwise defect problem is caused, therefore the characteristics of the present invention is according to 3 kinds of crystal promotors, it introduces and controls its dosage.
Further, the embodiment of the present invention provides a kind of preparation side for preparing above-mentioned diamond flash effect colour dry granular
Method, the preparation method mainly comprise the steps that
1, the raw material of following proportion: 0-15 parts of potassium albite, 35-52 parts of quartz is weighed, 5-12 parts of calcite, dolomite 6-
20 parts, talcum 0-6 parts of burning, 4-14 parts of commercial alumina, 2-8 parts of borax, 0-5 parts of potassium nitrate, 6-12 parts of barium carbonate, soda ash 1-8
Part, 1-5 parts of potassium bichromate, 2-5 parts of industrial oxidation copper, 0-4 parts of fluorite, 0-6 parts of calcium phosphate, 0-3 parts of titanium dioxide, chromium oxide 0-
4 parts；
2, the above raw material is mixed, and is homogenized through 1450-1550 DEG C of melting, it is then brilliant through 1350-1400 DEG C of heat preservation
Change processing, water quenching, drying obtain frit；
3, the frit is obtained to the colored dry granular of the diamond flash effect of different meshes range through different international sieves.
It should be noted that in the present invention, composition of raw materials, glass melting temperature, crystallization temperature and soaking time, dry granular mesh number model
It encloses, glaze volume, firing temperature and firing period have a great impact to final diamond flash effect.The present invention by allotment with
The proportion and preparation process condition parameter of upper raw material adjust, so that it is guaranteed that the frit being prepared meets its chemical component demand,
And the color development of dry granular glaze can be reached, the beginning melts temperature, speckle size, the coefficient of expansion and shining point quantity and size and all reaches most
Excellent effect.
Wherein, it should be noted that in actual application, crystallization soaking time is longer, and final products effect is better,
But in embodiments of the present invention, production cycle and cost needs, controlling crystallizing soaking time are 15 minutes to half in order to balance
A hour.
Wherein, temperature of the frit in melting, Crystallizing treatment influences big, this hair to the size dimension of flash of light crystal and quantity
It is bright to be adjusted by constantly test, it is final to determine that melting homogenization temperature scope control at 1450-1550 DEG C, keeps the temperature Crystallizing treatment temperature
Scope control is at 1350-1400 DEG C.
On the basis of the diamond flash effect colour dry granular and preparation method thereof that above embodiments provide, the present invention is implemented
Example further provides for a kind of decorative brick of diamond flash effect, which includes the above diamond flash effect colour dry granular.
More specifically, the decorative brick is by drenching overglaze glaze slip on ceramic body, the above-mentioned diamond flash effect of cloth is color
It after color dry granular, is fired, is not thrown, partly throwing or full throwing etc. are thrown in roller kilns 1150-1200 DEG C, firing period 50-90 minutes
Light technique for grinding and obtain.
Wherein, overglaze formula and spray process can be carried out according to common process.
In order to further illustrate that technical solution of the present invention, following present invention will be carried out in conjunction with several specific embodiments
It is described in detail, but this is specific implementation means cited by the present invention, protection scope of the present invention is not limited thereto.
Embodiment 1:
Diamond flash effect colour dry granular glaze implementation steps and technological parameter:
1) frit formula composition are as follows: 47.5 parts of 325 mesh quartz, 8 parts of calcite, 8.5 parts of dolomite, 9 parts of commercial alumina,
5 parts of borax, 0.2 part of potassium nitrate, 10 parts of barium carbonate, 3.5 parts of soda ash, 3 parts of potassium bichromate, 2.5 parts of industrial oxidation copper, fluorite 1.3
Part, 1.5 parts of calcium phosphate；
2) melted homogenization temperature: 1500 DEG C；
3) crystallization temperature: 1400 DEG C；
4) dry granular granulometric range and glaze volume: 12-40 mesh, the disk of 400g/300 × 600；
5) overglaze glaze slip: overglaze glaze slip formula composition used are as follows: 30 parts of potassium feldspar, 15 parts of albite, 20 parts of quartz, kaolinite
Native 14 parts of 8 calcined alumina, 5 parts of calcite, wollastonite 3,12 parts of zirconium silicate, suitable sodium carboxymethylcellulose, tripolyphosphate
Sodium, preservative and water.Overglaze technological parameter are as follows: the specific gravity of 1.85-1.92 drenches the disk of 90g/300 × 600；
6) ceramic body is through drenching overglaze glaze slip, after the processes such as cloth diamond flash effect dry granular glaze, enters in roller kilns and is burnt into,
Firing temperature is 1185 DEG C, and firing period 62min obtains decorative brick finished product.
Embodiment 2:
Diamond flash effect dry granular glaze implementation steps and technological parameter:
1) frit formula composition are as follows: 48 parts of 325 mesh quartz, 10 parts of calcite, 10 parts of dolomite, 8.5 parts of commercial alumina,
4 parts of borax, 0.2 part of potassium nitrate, 8 parts of barium carbonate, 3.5 parts of soda ash, 3.5 parts of potassium bichromate, 3 parts of industrial oxidation copper, fluorite 0.5
Part, 1 part of titanium dioxide；
2) melted homogenization temperature: 1530 DEG C；
3) crystallization temperature: 1380 DEG C；
4) dry granular granulometric range and glaze volume: 30-60 mesh, the disk of 265g/300 × 600；
5) overglaze glaze slip: overglaze glaze slip formula composition used are as follows: 25 parts of potassium feldspar, 20 parts of albite, 18 parts of quartz, kaolinite
Native 14 parts of 8 calcined alumina, 3 parts of calcite, wollastonite 3, dolomite 2,12 parts of zirconium silicate, suitable sodium carboxymethylcellulose,
Sodium tripolyphosphate, preservative and water.Overglaze technological parameter are as follows: the specific gravity of 1.85-1.92, leaching, the disk of 85g/300 × 600；
6) ceramic body is through drenching overglaze glaze slip, after the processes such as cloth diamond flash effect dry granular glaze, enters in roller kilns and is burnt into,
Firing temperature is 1185 DEG C, and firing period 62min obtains decorative brick finished product.
Embodiment 3:
Diamond flash effect dry granular glaze implementation steps and technological parameter:
1) frit formula composition are as follows: 48.5 parts of 325 mesh quartz, 9.5 parts of calcite, 9 parts of dolomite, commercial alumina 8.5
Part, 2.5 parts of borax, 0.2 part of potassium nitrate, 10.5 parts of barium carbonate, 3.5 parts of soda ash, 3 parts of potassium bichromate, 2.5 parts of industrial oxidation copper,
1.3 parts of fluorite, 1.5 parts of calcium phosphate；
2) melted homogenization temperature: 1530 DEG C；
3) crystallization temperature: 1400 DEG C；
4) dry granular granulometric range and glaze volume: 60-120 mesh, the disk of 50g/300 × 600；
5) overglaze glaze slip: overglaze glaze slip formula composition used are as follows: 18 parts of potassium feldspar, 25 parts of albite, 18 parts of quartz, kaolinite
Native 14 parts of 8 calcined alumina, 3 parts of calcite, wollastonite 3, dolomite 2,12 parts of zirconium silicate, suitable sodium carboxymethylcellulose,
Sodium tripolyphosphate, preservative and water.Overglaze technological parameter are as follows: the specific gravity of 1.85-1.92, leaching, the disk of 85g/300 × 600；
6) ceramic body is through drenching overglaze glaze slip, after the processes such as cloth diamond flash effect dry granular glaze, enters in roller kilns and is burnt into,
Firing temperature is 1180 DEG C, and firing period 65min obtains decorative brick finished product.
Embodiment 4:
Diamond flash effect dry granular glaze implementation steps and technological parameter:
1) frit formula composition are as follows: 50 parts of 325 mesh quartz, 8.5 parts of calcite, 9 parts of dolomite, 6.5 parts of commercial alumina,
3 parts of borax, 0.2 part of potassium nitrate, 10 parts of barium carbonate, 3.5 parts of soda ash, 3 parts of potassium bichromate, 2.5 parts of industrial oxidation copper, chromium oxide
0.8 part, 1.2 parts of fluorite, 1.8 parts of titanium dioxide；
2) melted homogenization temperature: 1500 DEG C；
3) crystallization temperature: 1360 DEG C；
4) dry granular granulometric range and glaze volume: 60-120 mesh, the disk of 50g/300 × 600；
5) overglaze glaze slip: overglaze glaze slip formula composition used are as follows: 18 parts of potassium feldspar, 25 parts of albite, 18 parts of quartz, kaolinite
Native 14 parts of 8 calcined alumina, 3 parts of calcite, wollastonite 3, dolomite 2,12 parts of zirconium silicate, suitable sodium carboxymethylcellulose,
Sodium tripolyphosphate, preservative and water.Overglaze technological parameter are as follows: the specific gravity of 1.85-1.92, leaching, the disk of 85g/300 × 600；
6) ceramic body is through drenching overglaze glaze slip, after the processes such as cloth diamond flash effect dry granular glaze, enters in roller kilns and is burnt into,
Firing temperature is 1180 DEG C, and firing period 65min obtains decorative brick finished product.
Mohs' hardness, surface abrasion resistance detect reference standard BS6431:Part:13:1986；GB/T3810.7-2016
The finished product parameters test result of above 4 embodiments see the table below 1:
It and is the glazing effect figure of finished product obtained by the several embodiments of the present invention or more, from these referring to Figure 1 to Fig. 4
Effect picture can be seen that the decorative brick that method through the embodiment of the present invention is prepared, and shade is with distinct contrast, diamond dodges
Luminous point quantity is more, and size is big, and distribution is different, dazzling under light-illuminating, is accompanied by the oil droplet shape figure of clear-cut often
Case.
The above present invention is in conjunction with specific embodiments to the detailed description of technical solution of the present invention, it will be understood that the present invention mentions
Made for a kind of diamond flash effect colour dry granular for being suitble to be rapidly fired to by deploying the different formulations and preparation process of raw material
It obtains frit itself and contains a great deal of and size crystal, and using the form glazing of dry granular glaze, reach and shorten crystalline glaze crystalline substance
With temperature condition the time required to body nucleating growth, it is more suitable for current Wall or floor tile roller kilns and is rapidly fired to periodic condition in 50-90 minutes,
Increase use occasion.Decorative brick, color clear-cut individuality, as diamond one under light-illuminating are used for using colored dry granular of the invention
Sample starlight is glittering, dazzling, different with shape size, the silver color oil droplet shape fine crystals speckle of clear-cut, quite
The ornamental sense of tool.
The foregoing is merely in conjunction with specific embodiments to made by the principle of the invention and embodiment further specifically
It is bright, and it cannot be said that specific implementation of the invention is only limited to these instructions, be merely used to help understand method of the invention and its
Core concept；Meanwhile for general technical staff of the technical field of the invention, before not departing from present inventive concept
It puts, it is all using equivalent structure or equivalent flow shift made by description of the invention and accompanying drawing content, directly or indirectly
Other related technical areas are used in, all shall be regarded as belonging to scope of patent protection of the invention.
Claims (5)
1. a kind of diamond flash effect colour dry granular, which is characterized in that the diamond flash effect colour dry granular include below at
Point: SiO255-65%, Al2O35-15%, CaO 8-12%, MgO 2-5%, K2O 1-3%, Na2O 3-5%, BaO 8-
12%, B2O31-3%, Cr2O31.5-3%, CuO 2.5-4%, CaF20-2%, P2O50-2%, TiO20-2%, grain
Diameter range is the one of which in 12-40 mesh, 30-60 mesh, 60-120 mesh or 120-250 mesh.
2. the preparation method of diamond flash effect colour dry granular described in a kind of claim 1, which is characterized in that the preparation method
Include:
Weigh the raw material of following proportion: 0-15 parts of potassium albite, 35-52 parts of quartz, 5-12 parts of calcite, 6-20 parts of dolomite,
Talcum 0-6 parts of burning, 4-14 parts of commercial alumina, 2-8 parts of borax, 0-5 parts of potassium nitrate, 6-12 parts of barium carbonate, 1-8 parts of soda ash, weight
1-5 parts of potassium chromate, 2-5 parts of industrial oxidation copper, 0-4 parts of fluorite, 0-6 parts of calcium phosphate, 0-3 parts of titanium dioxide, 0-4 parts of chromium oxide；
The above raw material is mixed, and is homogenized through 1450-1550 DEG C of melting, then through 1350-1400 DEG C of heat preservation Crystallizing treatment,
Water quenching, drying obtain frit；
The frit is obtained to the colored dry granular of the diamond flash effect of different meshes range through different international sieves.
3. the preparation method of diamond flash effect colour dry granular according to claim 2, which is characterized in that it is described will be described
The colored dry granulars for the diamond flash effect that frit obtains different meshes range through different international sieves include:
The frit is obtained into 4 kinds of 12-40 mesh, 30-60 mesh, 60-120 mesh, 120-250 mesh different sizes through different international sieves
The colored dry granular of diamond flash effect.
4. a kind of decorative brick of diamond flash effect, which is characterized in that the decorative brick includes the flash of light of diamond described in claim 1
Effect colour dry granular.
5. decorative brick according to claim 4, which is characterized in that the decorative brick passes through in the ceramic tile blank for having drenched overglaze
After surface is applied with the diamond flash effect colour dry granular, through in 50-90 minutes 1150-1200 DEG C, firing period roller kilns
It fires, is not thrown, half throws or throw and obtain entirely.
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Application publication date: 20190531 |