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CN109809803A - A kind of fish torpedo ladle permanent layer coating - Google Patents

A kind of fish torpedo ladle permanent layer coating Download PDF

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Publication number
CN109809803A
CN109809803A CN201711164675.XA CN201711164675A CN109809803A CN 109809803 A CN109809803 A CN 109809803A CN 201711164675 A CN201711164675 A CN 201711164675A CN 109809803 A CN109809803 A CN 109809803A
Authority
CN
China
Prior art keywords
torpedo ladle
fish torpedo
permanent layer
coating
ladle permanent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711164675.XA
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Chinese (zh)
Inventor
洪建国
宋旭飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Meishan Iron and Steel Co Ltd
Original Assignee
Shanghai Meishan Iron and Steel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Meishan Iron and Steel Co Ltd filed Critical Shanghai Meishan Iron and Steel Co Ltd
Priority to CN201711164675.XA priority Critical patent/CN109809803A/en
Publication of CN109809803A publication Critical patent/CN109809803A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a kind of fish torpedo ladle permanent layer coatings, mainly solve the big technical problem of thermal coefficient height, the transport molten iron process hot metal temperature drop of existing fish torpedo ladle.Fish torpedo ladle permanent layer coating provided by the invention, the weight percent of raw material components are as follows: lightweight alumina 55%~65%, microballon 5%~10%, pure calcium aluminate cement 13%~24%, magnesia 4-5%, silicon powder 3%~8%, the sum of weight percent of the raw material components are 100%.Fish torpedo ladle permanent layer made of coating of the present invention is 0.232-0.245W/ (mK) in 600 DEG C of thermal coefficients, and fish torpedo ladle permanent layer preparation cost is low.

Description

A kind of fish torpedo ladle permanent layer coating
Technical field
The present invention relates to a kind of fish torpedo ladle refractory material, in particular to a kind of fish torpedo ladle permanent layer coating belongs to Steel and iron industry Thermal Equipment technical field of refractory materials.
Background technique
Fish torpedo ladle is a kind of large-scale Molten Iron Transportation equipment, for storing, transporting molten iron, is given birth to coordinating ironmaking production and steel-making The molten iron temporarily occurred, molten steel non-equilibrium state are produced, the molten iron temperature of fish torpedo ladle transport is 1300 DEG C -1500 DEG C, this is to torpedo Refractoriness, compressive resistance, the anti-erosion of the resistance to material of tank have very high requirement.It is brick that the working lining of fish torpedo ladle generallys use silicon carbide It builds, the permanent layer of fish torpedo ladle generallys use clay brick masonry and forms, and the thermal coefficient of clay brick is 0.732W/ (mK), It is relatively higher;This combination of fish torpedo ladle, during the molten iron for causing fish torpedo ladle to transport, hot metal temperature drop is big in fish torpedo ladle, high Up to 150 DEG C or so, lead to a large amount of heat-energy losses.
The Chinese patent application of publication number CN1459345A discloses a kind of novel dry working lining, the patent with Magnesia, olivine sand, synthetic magnesia-calcium clinker, passivation dolomite sand, passive lime stone sand, calcining olivine sand are base stock, with Aluminum sulfate (Al2(SO4)3·18H2O), aluminium polychloride (AlCl36H2O), halogen (MgCl2·6H2It O is) bonding agent, with iron Squama, clay, silicon powder are sintering aid, are uniformly mixed to prepare dry type lining material;It is constructed at the scene by tundish mould tire, and With 150~350 DEG C toast 1~3 hour, take off mould tire, working lining.This liner in dundish and wet type spray material (or Coating) working lining is compared to having the characteristics that easy construction, low energy consumption, the service life is high;Have compared with heat-insulating shield working lining not dirty Contaminate molten steel, the features such as service life is high;Have compared with the dry-type working lining of resinous bonding agent it is free from environmental pollution, do not pollute molten steel etc. Feature.
The Chinese patent application of publication number CN101284736A discloses steel-making anti-sticking coating and preparation method thereof, The quality percentage composition for being characterized in that the coating is 0-3mm waste magnesia carbon brick powder 65-80%, and waste magnesia carbon brick powder is 10- 30%, electric smelting magnesium powder 5-30%;Fine silica powder 1-4%, α-Al2O3 micro mist 1-4%, calgon 0.1- 1%, calcium lignosulfonate 0.1-0.8%, mild-clay 1-5%, coating provided by the invention is using in waste magnesia carbon brick The lubrication property of graphite can prevent slag penetration, and surface is not easy dross, not only efficiently use waste magnesia carbon bricks but also extend painting again The service life of skinning loam, reduces costs.
Lack the coating for being exclusively used in fish torpedo ladle permanent layer in the prior art.
Summary of the invention
The object of the present invention is to provide a kind of fish torpedo ladle permanent layer coatings, mainly solve the thermally conductive system of existing fish torpedo ladle The technical problem that number is high, transport molten iron process hot metal temperature drop is big.
The technical scheme is that a kind of fish torpedo ladle permanent layer coating, the weight percent of raw material components are as follows: Lightweight alumina 55%~65%, microballon 5%~10%, pure calcium aluminate cement 13%~24%, magnesia 4-5%, silicon powder 3%~8%, the sum of weight percent of the raw material components is 100%.
The reasons why component of fish torpedo ladle permanent layer coating of the present invention limits within the above range is as follows:
Because the permanent layer of fish torpedo ladle, working lining are all made of Al-Si Refractory Materials and are made, fish torpedo ladle permanent layer of the present invention is used Coating is using based on aluminium silicon matter, to prevent reacting for alkaline matter and acidic materials.
Lightweight alumina: using lightweight alumina as coating aggregate, the chemical component of lightweight alumina is the present invention Al2O3·H2O, Al2O3·3H2O and a small amount of Fe2O3·SiO2, it is commonly used for manufacturing refractory material, elevated temperature strength is high, resists molten Scouring ability is strong, is widely used in the industries such as steel, coloured, the bulk density 2.7-2.9g/cm of common alumina3, the present invention The bulk density used is 2.0-2.2g/cm3Therefore referred to as lightweight alumina.
Lightweight alumina is the oxide of aluminium silicon systems, and fusing point is 1800 DEG C, and price is relatively cheap.Due to common alumina Thermal conductivity is high, and present invention employs lightweight alumina, bulk density 2.0-2.2g/cm3If excessively high in coating, Constructional difficulties;If content is too low, material property changes, and cannot effectively support working lining and compress to its intensity.It is ground for many years Study carefully, the weight percentage that the present invention controls lightweight alumina in coating is 55%~65%;For the ease of constructing and guaranteeing Construction quality, the present invention control partial size≤5mm of lightweight alumina.
Microballon: cenosphere is used in order to further decrease the thermal coefficient of invention material, the chemical component of microballon is Sodium silicoaluminate (Na2O·Al2O3·2SiO2·H2It O), is a kind of global shape, the fine microballon of continuous ionic exchange, particle size is not Together, the present invention is less than or equal to 10 μm using partial size, and microballon forming process is that silica, aluminum oxide are reacted with sodium hydroxide The sodium silicoaluminate of indissoluble is generated, chemical equation is 2SiO2+Al2O3+ 2NaOH=Na2O·Al2O3·2SiO2·H2O, it is hollow The effect for reducing thermal coefficient is not had if microballon additional amount is very little, is added too much, material intensity after molding, which is not achieved, to be wanted It asks, is studied for many years, the weight percentage that the present invention controls microballon in coating is 5%~10%;For the ease of construction and Guarantee that construction quality, the present invention control partial size≤10 μm of microballon.
Magnesia: having gelling characteristic using magnesia (MgO), with addition of a certain amount be conducive to enhance its adhesion from And its rebound rate is reduced, and additional amount cannot be excessive, excessively then destroys original ingredient, and it is too low, due effect is not had, is passed through It studies for many years, the weight percentage that the present invention controls magnesia is 4-5%.
Pure calcium aluminate cement: the set strength in order to enhance coating is combined using pure calcium aluminate cement in the material Agent is studied for many years, and the weight percentage that the present invention controls pure calcium aluminate cement is 13%~24%.
Silicon powder: the combination of coating of the present invention is by the way of Coagulating binding, by fine aluminium when the Coagulating binding of coating Sour calcium cement and silicon powder are realized jointly, in order to enable coating, which quickly adheres to, forms an entirety with torpedo tank liner original brick, Using silicon powder, the aluminum oxide contained in the silicon powder and raw material in instant component, which reacts, generates aluminium silicon spinel (2Al2O3·3SiO2), chemical equation is 3SiO2+2Al2O3=2Al2O3·3SiO2
Further coating and torpedo tank liner is promoted to form entirety, since silicon powder has been catalytic action, content It should not be too high;It is studied for many years, the weight percentage that the present invention controls silicon powder is 3%~8%.
The preparation method of coating of the present invention, comprising:
1) by coating with comparing lightweight alumina and pure calcium aluminate cement carries out weighing ingredient, with kolleroang by light weight Change alumina and pure calcium aluminate cement carries out mixing 5~10 minutes;
2) weighing ingredient is carried out with comparison microballon, magnesia, silicon powder by coating;
3) microballon, magnesia, silicon powder and lightweight alumina and pure calcium aluminate cement are mixed 15~20 points with kolleroang Clock obtains coating finished product, is packed into finished bag.
The construction method of coating of the present invention is:
Fraction of water is added in coating, is advisable in order to smear, amount of water is controlled 2~3%, in fish torpedo ladle slack tank In the state of, coating is applied in fish torpedo ladle steel by the common anchoring piece for the 10cm long that burn-ons on fish torpedo ladle slack tank inner wall At wall, smeared using multilayer, until smear the bed of material with a thickness of 210cm, rest 14 hours, the permanent layer of fish torpedo ladle be made;Afterwards The working lining of fish torpedo ladle is built in the permanent layer surface of fish torpedo ladle.
The present invention uses fish torpedo ladle permanent layer made of coating in 600 DEG C of thermal coefficients for 0.232-0.245W/ (m K), fish torpedo ladle permanent layer made of existing clay brick is the left and right 0.732W/ (mK), the use of the two in 600 DEG C of thermal coefficients Service life is suitable.
Coating bulk density of the present invention is 1.0~1.2g/cm3It is 1.7~1.9g/ compared to existing clay brick bulk density cm3It reduces obviously, reduces the weight of fish torpedo ladle, save transportation power sources.
Fish torpedo ladle permanent layer of the present invention is made of low thermally conductive coating, realizes existing fish torpedo ladle permanent layer fire resisting The great-leap-forward progress of material and construction method, improves the thermal insulation property of fish torpedo ladle.
The present invention has following good effect compared with prior art: 1, fish torpedo ladle permanent layer made of coating of the present invention exists 600 DEG C of thermal coefficients are 0.232-0.245W/ (mK), improve the thermal insulation property of fish torpedo ladle.2, coating of the present invention is applied The cost of work simple process, manufactured fish torpedo ladle permanent layer is low.3, coating bulk density of the present invention is 1.0~1.2g/cm3Phase It is 1.7~1.9g/cm than existing clay brick bulk density3It reduces obviously, reduces the weight of fish torpedo ladle, save transportation power sources.
Specific embodiment
Below with reference to Examples 1 to 5, the present invention will be further described, as shown in table 1.
A kind of fish torpedo ladle permanent layer coating, the weight percent of raw material components are as follows: lightweight alumina 55%~ 65%, microballon 5%~10%, pure calcium aluminate cement 13%~24%, magnesia 4-5%, silicon powder 3%~8%, the raw material The sum of weight percent of component is 100%.
The raw material components of 1 coating of the embodiment of the present invention of table, unit: weight percent.
Fish torpedo ladle permanent layer is made using coating of the present invention, embodiment 1-5 is respectively in 600 DEG C of thermal coefficients 0.232W/ (mK), 0.232W/ (mK), 0.245W/ (mK), 0.235W/ (mK), 0.232W/ (mK).
In addition to the implementation, the present invention can also have other embodiments.It is all to use equivalent substitution or equivalent transformation shape At technical solution, fall within the scope of protection required by the present invention.

Claims (6)

1. a kind of fish torpedo ladle permanent layer coating, characterized in that the weight percent of its raw material components are as follows: lightweight alumina 55%~65%, microballon 5%~10%, pure calcium aluminate cement 13%~24%, magnesia 4-5%, silicon powder 3%~8%, institute Stating the sum of weight percent of raw material components is 100%;The bulk density of the lightweight alumina is 2.0-2.2g/cm3;It is described Microballon is sodium silicoaluminate cenosphere.
2. fish torpedo ladle permanent layer coating as described in claim 1, characterized in that the weight percent of its raw material components Are as follows: lightweight alumina 55%, microballon 10%, pure calcium aluminate cement 24%, magnesia 5%, silicon powder 6%.
3. fish torpedo ladle permanent layer coating as described in claim 1, characterized in that the weight percent of its raw material components Are as follows: lightweight alumina 60%, microballon 10%, pure calcium aluminate cement 23%, magnesia 4%, silicon powder 3%.
4. fish torpedo ladle permanent layer coating as described in claim 1, characterized in that the weight percent of its raw material components Are as follows: lightweight alumina 65%, microballon 10%, pure calcium aluminate cement 13%, magnesia 5%, silicon powder 7%.
5. the fish torpedo ladle permanent layer coating as described in claim 1-4 is any, characterized in that the grain of the lightweight alumina Diameter≤5mm.
6. the fish torpedo ladle permanent layer coating as described in claim 1-4 is any, characterized in that partial size≤10 of the microballon μm。
CN201711164675.XA 2017-11-21 2017-11-21 A kind of fish torpedo ladle permanent layer coating Pending CN109809803A (en)

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CN109809803A true CN109809803A (en) 2019-05-28

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113024264A (en) * 2019-12-09 2021-06-25 上海梅山钢铁股份有限公司 Heat-insulating coating for permanent layer of torpedo ladle
CN115710116A (en) * 2022-12-15 2023-02-24 河南宏兴炉料有限公司 Method for manufacturing heat-insulation coating
CN115872729A (en) * 2021-09-26 2023-03-31 上海梅山钢铁股份有限公司 Repair material for torpedo ladle working layer

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101293777A (en) * 2008-06-25 2008-10-29 河南省耕生耐火材料有限公司 High-strength light weight castable refractory

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101293777A (en) * 2008-06-25 2008-10-29 河南省耕生耐火材料有限公司 High-strength light weight castable refractory

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
姜立伟等 主编: "《土木工程概论》", 31 October 2006, 哈尔滨地图出版社 *
林宗寿主编: "《无机非金属材料工学》", 31 August 2014, 武汉理工大学出版社 *
薛正良 主编: "《钢铁冶金概论》", 30 April 2016, 冶金工业出版社 *
袁林等 主编: "《绿色耐火材料》", 31 January 2015, 中国建材工业出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113024264A (en) * 2019-12-09 2021-06-25 上海梅山钢铁股份有限公司 Heat-insulating coating for permanent layer of torpedo ladle
CN115872729A (en) * 2021-09-26 2023-03-31 上海梅山钢铁股份有限公司 Repair material for torpedo ladle working layer
CN115872729B (en) * 2021-09-26 2023-12-05 上海梅山钢铁股份有限公司 Repair material for working layer of torpedo tank
CN115710116A (en) * 2022-12-15 2023-02-24 河南宏兴炉料有限公司 Method for manufacturing heat-insulation coating

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Application publication date: 20190528