CN109789430A

CN109789430A - During clothes are pure and fresh and relative improvement

Info

Publication number: CN109789430A
Application number: CN201780044477.1A
Authority: CN
Inventors: G·P·罗伯茨; R·L·图米斯
Original assignee: Unilever NV
Current assignee: Unilever PLC; Unilever NV
Priority date: 2016-08-05
Filing date: 2017-08-02
Publication date: 2019-05-21
Also published as: EP3493918A1; WO2018024798A1; BR112019002314A2; US20200181833A1; ZA201808564B

Abstract

The present invention relates to the pure and fresh products of a kind of clothes (1) comprising: the pure and fresh composition of clothes (12)；And Handheld spraying device, it is manually operable to generate being sprayed for the composition in the form of thin aerosol (29)；The composition (12) includes at least one of anti-peculiar smell agent, anti wrinkling agent and fragrance；And the spraying device includes the reservoir (2) containing the composition (12) and the humidifier (15) that is contained in shield (3), the shield is substantially aligned with the longitudinal axis (8) of the reservoir (2)；The humidifier (15) is manually operable and the composition (12) in the form of thin aerosol (29) and along spray direction (5) from product (1) discharging doses, which is substantially perpendicular to the longitudinal axis (8) of reservoir (2).The invention further relates to generate the pure and fresh spraying method of clothes.

Description

During clothes are pure and fresh and relative improvement

Technical field

It is pure and fresh (garment refreshment) that the present invention relates to clothes.

Background technique

Pure and fresh product, such as " air freshener " or carpet and upholstery freshener has previously been proposed, and The manually operable spray bottle containing liquid composition is generally included, the liquid composition may include anti-malodorous compound And/or fragrance.In these products, spray bottle is commonly used in being sprayed for composition to be directed on surface or in air, in With and/or cover offensive odour.

It has proposed to carry out pure and fresh apparel article using this product in " rifle " type bottle that trigger operates, to extend it Acceptable use time between washing.

Applicant have determined that the problem of relevant to the pure and fresh product of the routine of the above-mentioned type some perception and disadvantage.

It is fine enough that the pure and fresh issuable problem of product of tradition of the above-mentioned type is that they will not usually be generated Liquid spray and avoid generating ugly spot on clothes when being deposited on clothes by spraying.In some cases, this may Cause to dye, and this is unacceptable for the user of product.Even if in the case where no dyeing, the wet patch in part It is also inaesthetic and inconvenient for generating for a user, especially if the clothes will be worn immediately.Certainly, for Such as be intended for for the product of carpet or upholstery, this is not problem.

In some cases, it is believed that even if liquid composition itself is prepared as so that when the fabric with clothes contacts Actual spot is not generated, and some users only feel that relatively wet being sprayed containing big drop may cause the certain customers Misgivings, and therefore prevent frequently using these products come clothes pure and fresh between washing.

It has also been determined that (many potential consumers usually may for the true form of even conventional spray bottle or configuration sometimes It is associated with relatively wet spray product such as domestic cleaning product etc. with by it) user can be can increase to the load of dyeing possibility Sorrow, and it is therefore prevented to use the conventional pure and fresh product of fabric.

Above-mentioned some problems can be can solve although needing so-called " aerosol spray " product of pressurized propellant type, it Be typically considered to be unfavorable to environment now, and therefore to a certain extent not by the welcome of consumer.

Summary of the invention

Therefore, it is an object of the present invention to provide a kind of improved pure and fresh products of clothes.Another object of the present invention It is pure and fresh spraying to be to provide a kind of improved fabric.And it is pure and fresh spraying that a further object of the present invention is to provide a kind of generation clothes Improved method.

In a first aspect, the present invention provides a kind of pure and fresh product of clothes comprising: the pure and fresh composition of clothes；And hand-held Spraying device is manually operable to generate being sprayed for the composition of thin aerosol form；The composition includes following At least one of: anti-peculiar smell agent, anti wrinkling agent and fragrance；With the spraying device include the reservoir containing the composition and Humidifier.

In aspects described herein, adapted to realize clothes to the maximum extent so as to user one or more of below Pure and fresh event: the configuration of humidifier；Specific spray characteristics are provided；And the pure and fresh composition of clothes.

In an arrangement, the shield of humidifier is surrounded by providing, spraying device is adapted to more effective and convenient Operation, the shield are aligned with the reservoir of device.

In another scheme, spraying device is adapted to more effectively make by providing around the shield of humidifier With wherein the shield is the longitudinal axis that elongated and device spray direction is substantially perpendicular to shield.

In another scheme, there is the humidifier of discharge orifice by providing, spraying device is adapted to more effectively make With the humidifier is configured to generate the thin aerosol spray with sizable cone angle (suitably in the range of 55 to 80 degree) Mist.

In another scheme, by providing humidifier, spraying device is adapted to more efficiently use, the humidifier It is configured to generate the thin aerosol with small average droplet size (suitably in the range of 20 to 200 μm).

Each of these schemes all solve the above problem, and the combination of these schemes is realizing to include consumer It perceives and especially effective to the expected result aspect of the satisfaction of product.

In this regard, each and every kind of combination of scheme is disclosed.

By providing the spraying device for being suitable for Consumer Preferences and being the pure and fresh customization of clothes, the pure and fresh composition of clothes Using will increase, and preferably become to be accustomed to, to reduce the frequency of washing.Therefore water, detersive active may be implemented The reduction used with energy.This is a valuable contribution, is especially considering that a large amount of water used in washing machine.

In addition, the pure and fresh composition of the clothes of per unit dose realizes improved " clothes freshness effect ".Therewith, this can be with Allow using less " the pure and fresh active material of clothes ", such as anti-peculiar smell, crease-resistant and fragrance active.

Suitably, humidifier is contained in shield.Advantageously, the shield can have basic with the longitudinal axis of the reservoir The longitudinal axis of upper alignment.

Suitably, the humidifier be manually operable with from the product with the institute of thin aerosol form discharging doses State composition.

Suitably, the spraying spray direction with the longitudinal axis basically perpendicular to reservoir.

Suitably, shield is elongated, and the spraying spray direction with the longitudinal axis for being substantially perpendicular to shield.

Easily, the humidifier may include the nozzle in the shield, and the nozzle has discharge orifice.Cause This, nozzle is not prominent from shield.

These features can help to improve user's acceptance, such as by avoiding and generally producing have related dyeing/weight " rifle " type spraying device of the ejection-type output of degree deposition is associated.By avoiding this relevance, consumer can connect completely By the practice that is pure and fresh and dressing again of anti-peculiar smell/crease-resistant/fragrance component is used, so that it is acceptable between washing to extend clothes It uses.This can reduce water consumption, to bring environmental benefit.

It can be also used for that the device is prevented to be hooked on clothes.It can also contribute to it is duplicate using and/or There is provided in given injection events it is consistent spraying because the discharge orifice of nozzle is by shield shielding/protection.

Optionally, the shield is substantially columnar and is installed to the reservoir to prolong upwards from it in form It stretches.

Suitably, the diameter of shield is substantially constant along its length.Suitably, the diameter of container is basic along its length On be constant.Suitably, the diameter of shield and container is substantially constant along its respective length.Suitably, shield The diameter of diameter and container is substantially the same.

Suitably, and with conventional pure and fresh spray product on the contrary, container does not include constriction/neck.

Suitably, the cross-sectional shape of shield along its longitudinal axis is substantially constant.For example, shield can have along its length Circular cross section.

Suitably, at least part of shield along its longitudinal axis, suitably along its longitudinal axis be substantially all substantially diameter To symmetrical.For example, shield can have circular cross section along its length.

The coaxially arranged holding and operation for facilitating spraying device of shield and reservoir, this is conducive to the steady of actuator again Consistency between operation and continuous operation.Advantageous ergonomics, which may also help in, provides more comfortably making for a long time for device With, such as in the case where the pure and fresh composition of clothes to be applied on the big clothes or more than one piece clothes of such as winter coat.

Coaxial shield, especially elongated and/or eneral cylindrical shape shape, help to provide it is a kind of can be with for user The device of the position relative insensitivity of gripping.The hand of user holds/and the direction of grip device is same.For example, user can be with The device is cosily held behind the outlet opening of shield with palm or thumb.Conversely, because " constriction " shape of container and spray The shape of mist mechanism, " rifle " type spraying device force user to hold device along a specific orientation.

Coaxial shield additionally aids the device center of gravity for providing and being located on (common) longitudinal axis, this facilitates comfortable, consistent again And extended use.In fact, center of gravity may remain on the axis and unrelated with the filling level of container.

Coaxial shield also allows humidifier relative to a series of orientations of reservoir/container.This allows again in container and spray There is greater flexibility and tolerance in connection/coupling of mist mechanism.It (such as is refilled when wherein container will dismantle every now and then Container), or when the replaceable reservoir of use, this may be particularly advantageous.

Reservoir (strictly speaking, limiting the container of reservoir) may be used as user and " grab in manipulation with what is held when operating device Hold " component.

Easily, the shield can be combined with the humidifier therein removes from the reservoir.

Advantageously, the shield and the reservoir can be configured for releasably engageable with each other.

Optionally, the shield and the reservoir are threadedly engaged.

Optionally, the shield and the reservoir can be used as interference engagement and be engaged with each other.

According to further aspect related with the first aspect of the present invention, a kind of pure and fresh product of clothes is provided, is wrapped It includes: the pure and fresh composition of clothes；And Handheld spraying device, it is manually operable to generate the composition of thin aerosol form Be sprayed；The composition includes at least one of the following: anti-peculiar smell agent, anti wrinkling agent and fragrance；And the spraying device packet The humidifier for including the reservoir containing the composition and being contained in shield, the longitudinal axis of the shield substantially with the reservoir Alignment；The humidifier is manually operable and from the product discharging doses in the form of thin aerosol and along spray direction The composition, the spray direction be basically perpendicular to reservoir the longitudinal axis.

Suitably, which includes nozzle and can operate and certain agent is discharged from nozzle in the form of thin aerosol The composition of amount.

Suitably, which has tap, which is configured to the spraying generation thin gas to have wide cone angle Colloidal sol, this is conducive to for composition being applied uniformly on clothes.

Suitably, the cone angle by spraying at least 50 degree, preferably at least 55 degree, more preferably at least 60 degree.

Suitably, this has the cone angle no more than 90 degree, preferably no greater than 85 degree, more preferably no more than 80 degree by spraying.

Suitable cone angle is selected from the range of 50 to 90 degree, suitably 55 to 80 degree, suitably 60 to 80 degree.

Advantageously, the discharge orifice can be configured to generate the thin aerosol with substantially circular jet mode.

As described below, it has been suggested that the composition can provide in fluid form, so that generated thin aerosol Suitably use the form of mist.Drop size is discussed below.

By configuring humidifier to deliver as characterized above be sprayed, it is possible to make the pure and fresh composition of clothes of injection The highest percentage being deposited on clothes.Suitably, the dosage of at least 50% weight is trapped on clothes, suitably at least 60wt%, suitably at least 70wt%, suitably at least 80wt%；Suitably at least 90wt%.

According to further aspect related with the first aspect of the present invention, a kind of pure and fresh product of fabric is provided, is wrapped It includes: the pure and fresh composition of clothes；And Handheld spraying device, it is manually operable to generate the composition of thin aerosol form Be sprayed；The composition includes at least one of the following: anti-peculiar smell agent, anti wrinkling agent and fragrance；With the spraying device packet Include reservoir and humidifier containing the composition；The humidifier includes nozzle and is manually operable and molten with thin gas The form of glue is from the composition of nozzle discharging doses, wherein the nozzle has discharge orifice, the discharge orifice is configured At the spraying generation thin aerosol to have cone angle in the range of 55 to 80 degree.

Easily, the pure and fresh composition of the clothes is provided as liquid, and the humidifier can be operated to be discharged at least 0.1ml, preferably at least 0.2ml, more preferably at least 0.25ml, more preferably at least 0.3ml, more preferably at least 0.35ml, more preferably At least 0.35ml, more preferably at least 0.4ml, more preferably at least 0.45ml, and the dosage of most preferably at least 0.5ml.

Suitably, which is no more than 2ml, preferably more than 1.8ml, preferably more than 1.6ml, more preferably no more than 1.5ml, more preferably no more than 1.4ml, more preferably no more than 1.3ml, and most preferably not more than 1.2ml.

Suitably, the pure and fresh composition of liquid clothes which is 0.1 to 2ml, preferably 0.2 to 1.8ml, more preferably 0.25 to 1.6ml, more preferable 0.25 to 1.5ml, and most preferably 0.25 to 1.2ml.

It has been found that these dosage realize required clothes in the case where not ugly and waste big droplet formation It is especially effective in terms of freshness effect (such as crease-resistant).

According to further aspect related with the first aspect of the present invention, a kind of pure and fresh product of clothes is provided, is wrapped It includes: the pure and fresh composition of clothes；And Handheld spraying device, it is manually operable with and thin aerosol form generates the composition Be sprayed；The composition includes at least one of the following: anti-peculiar smell agent, anti wrinkling agent and fragrance；And the spraying device packet The humidifier for including the reservoir containing the composition and being contained in shield, the longitudinal axis of the shield substantially with the reservoir Alignment；The humidifier is manually operable and from product discharging doses in the form of thin aerosol and along spray direction The composition, the spray direction are substantially perpendicular to the longitudinal axis of reservoir, wherein the dosage is 0.5 to 1.5ml combination Object.

Suitably, it is not more than 250 μm comprising average diameter by spraying, is suitably not more than 200 μm, is suitably not more than 150 μ M is suitably not more than 125 μm, is suitably not more than 100 μm of drop.

Suitably, by spraying comprising average diameter be at least 5 μm, suitably at least 10 μm, suitably at least 20 μm, suitably At least 30 μm, suitably at least 40 μm, suitably at least 50 μm of drop.

Suitably, spraying comprising having average diameter is 20 to 200 μm, is suitably 40 to 150 μm, suitably for 40 to 125 μm of drop.

By providing improved aerosol (especially mist), the pure and fresh composition of the clothes can be more efficiently used.No Only can be by the pure and fresh composition deposition of the spraying clothes of greater proportion on the fabric, and the clothes that can improve deposition are pure and fresh The effect of composition.Particularly, the drop size in range disclosed herein can be realized comparable uniformly or equal on clothes The active material of phase is distributed, this optimizes clothes freshness effect therewith.

In multiple embodiments, the pure and fresh composition of a large amount of clothes can be applied to the clothes of large area by spraying device On, there is uniform cover and without visible wetting or label.This is larger for such as housing, jacket and other coats Clothes are particularly advantageous.

The measurement of drop size is discussed below with reference to the experiment that inventor carries out.

According to further aspect related with the first aspect of the present invention, a kind of pure and fresh product of clothes is provided, is wrapped It includes: the pure and fresh composition of clothes；And Handheld spraying device, it is manually operable to generate the composition of thin aerosol form Be sprayed；The composition includes at least one of the following: anti-peculiar smell agent, anti wrinkling agent and fragrance；With the spraying device packet The humidifier for including the reservoir containing the composition and being contained in shield, the longitudinal axis of the shield substantially with the reservoir Alignment；The humidifier is manually operable and from product discharging doses in the form of thin aerosol and along spray direction The composition, the spray direction are substantially perpendicular to the longitudinal axis of reservoir, wherein by spraying comprising average diameter 20 to 200 Drop in the range of μm.

Easily, the pure and fresh composition of the clothes is provided as liquid, and the humidifier may include atomizer, institute It states atomizer to be configured to resolving into the liquid dosages into drop, and thereby promotes the generation thin gas in the form of mist molten Glue.

Easily, the atomizer may include at least one of the following: minor air cell and lateral dispersing chamber.

Suitably, atomizer is for mixing air with the pure and fresh composition of clothes.

Suitably, size/capacity of the internal capacity of container, i.e. reservoir is selected from: at least 100ml, at least 200ml, at least 300ml and at least 400ml.Expediently, volume/size of reservoir is selected from: no more than 1000ml, no more than 800ml, be no more than 600ml, it is no more than 500ml, is no more than 400ml and is no more than 300ml.Suitable range is selected from: 100 to 300ml and 100 to 200ml.Other suitable ranges are selected from 200 to 600ml, 200 to 500ml and 300 to 500ml.

These values are also applied for the detachable/reservoir that can refill, this is discussed below.

Suitably, spraying device humidifier is manually operable with the composition from nozzle discharging doses and Speech is manually operable spraying device.

The humidifier may include manual pump.

Optionally, the pump is following one: positive-displacement pump；Self priming pump；Reciprocating pump.

Suitably, humidifier is operated by actuator.Actuator, which can be, pushes actuator or pulling actuator.

Easily, the Handheld spraying device can be operated in the case where not using pressurized propellant.In fact it is preferred to Spraying device without propellant.

The pure and fresh composition of clothes can be any physical form, such as solid, such as powder or particle；Or as liquid Such as waterborne liquid.

Before the spraying, solid form can be mixed with water.

Liquid is preferred.

The pure and fresh composition of clothes includes at least one of anti-peculiar smell agent, anti wrinkling agent and fragrance.Suitably, there are in these At least two, that is, anti-peculiar smell agent and anti wrinkling agent；Or anti-peculiar smell agent and fragrance；Or anti wrinkling agent and fragrance.Expediently, in the presence of All three, anti wrinkling agent, anti-peculiar smell agent and fragrance.

As described below, the pure and fresh composition of the clothes uitably includes carrier, is convenient to as water.

As described below, the pure and fresh composition of the clothes suitably contains encapsulation object, such as fragrance encapsulation object, for example, fragrance is micro- Capsule.

The composition may include have rupturable melamine-formaldehyde polymer wall microcapsules it is water-soluble serous, Containing for example anti-peculiar smell agent and/or fragrance, wherein microcapsules are contacted with one or more polymerizing silicone phosphatide, such as International Flavors&Fragrances disclosed in US2005/0113282, is being incorporated herein by ginseng It examines.

Suitably, the pure and fresh composition of the clothes includes thickener and/or structural agent.These components can be with following amount In the presence of: 0.1 to 60%, 0.1 to 50%, 0.1 to 40%, 0.1 to 30%, 0.1 of the weight based on the pure and fresh composition of clothes to 20%, 0.1 to 10%, 0.1 to 5% and 0.1 to 2% weight.This can permit control the pure and fresh composition of clothes viscosity and/or Rheological property.

The pure and fresh composition of the clothes is suitably the pure and fresh composition of aqueous clothes.

Aqueous solution is preferred for smell control.Diluted aqueous solution provide on the fabric anti-peculiar smell agent (such as ring paste Smart molecule) farthest separation, and maximization a possibility that make scent molecule and anti-peculiar smell agent interact.

Preferred vector of the invention is water.The water used can be distilled water, deionized water or tap water.Water is not only used as The liquid-carrier of anti-peculiar smell agent (such as cyclodextrin), but also promote appointing on anti-peculiar smell agent (such as cyclodextrin molecular) and clothes Complex reaction between what odor molecules.

Suitably, the amount of water present in the pure and fresh composition of clothes is selected from the pure and fresh composition weight of the clothes at least 50%, at least 75%, at least 85%, at least 90%, at least 95% and at least 97%.

Preferably, carrier also includes emulsifier.Emulsifier may include surfactant as described herein.

In multiple embodiments, one of pure and fresh composition of the clothes or various ingredients (such as it is anti-peculiar smell agent, crease-resistant Agent and fragrance) it is provided as encapsulation object.Microcapsules are preferred.

The fragrance particularly preferably encapsulated, especially fragrance microcapsule (PMC).

Suitable microcapsules are described in US2005/0113282, are incorporated herein by reference.Particularly, microcapsules can To be made of rupturable melamine-formaldehyde polymer wall, and the composition may include the aqueous slurry of the microcapsules Liquid.

Effective deposition of anti-peculiar smell agent enables smell to be neutralized rather than only be blanked.Spraying dress through the invention The mist for setting acquisition helps to realize effective deposition of " activity " anti-peculiar smell agent, and therefore effectively neutralizes peculiar smell.

Anti- peculiar smell agent horizontal can exist by selected from the following: based on the weight of the pure and fresh composition of clothes, less than 20%, small In 10% and less than 5%.Suitably amount of the anti-peculiar smell agent in the pure and fresh composition of clothes is selected from, by the pure and fresh composition of clothes Poidometer, from about 0.01% to about 5%, preferably from about 0.1% to about 3%, more preferably from about 0.5% to about 2%.

Any suitable anti-peculiar smell agent can be used.Indeed, it is possible to pass through any effectively " capture ", " absorption " or " broken It is bad " scent molecule is from clothes to separate or remove the compound of smell or product realizes anti-peculiar smell effect.

Odor control agent may include the peculiar smell counteractant as described in US2005/0113282A1, be incorporated by reference into this Wen Zhong.Particularly, which may include the mixed of zinc ricinate or its solution and substituted monocycle organic compound Close object, as described in the 17th section of page 2, thus substituted monocycle organic compound substitution one of below or it is a variety of or and its Combination:

1- cyclohexyl second -1- base butyrate；

1- cyclohexyl second -1- yl acetate；

1- cyclohexyl second -1- alcohol；

1- (4'- Methylethyl) cyclohexyl second -1- base propionic ester；With

2'- hydroxyl -1'- ethyl (2- phenoxy group) acetic acid esters.

The synergistic combination of peculiar smell counteractant disclosed in 38-49 sections is suitably, for example, the composition includes:

(i) material containing at least one substituted monocycle organic compound of from about 10 to about 90 parts by weight is:

(a) the 1- cyclohexyl second -1- base butyrate having following structure:

(b) the 1- cyclohexyl second -1- yl acetate having following structure:

(c) the 1- cyclohexyl second -1- alcohol having following structure:

(d) 1- (4'- Methylethyl) cyclohexyl second -1- base propionic ester having following structure:

With

(e) 2'- hydroxyl -1'- ethyl (2- phenoxy group) acetic acid esters having following structure:

The composition containing zinc ricinate of (ii) about 90 to about 10 parts by weight for zinc ricinate and/or contains The greater than about zinc ricinoleate solution of the zinc ricinate of 30% weight.Preferably, the above-mentioned composition containing zinc ricinate is The mixture of the zinc ricinate of about 50% weight and at least one 1- hydroxyl -2- ethoxyethyl group ether of about 50% weight.More Specifically, for be with the preferred composition of zinc ricinate group subassembly following substance mixture:

(A) 1- cyclohexyl second -1- base butyrate；

(B) 1- cyclohexyl second -1- yl acetate；With

(C) 1- (4'- Methylethyl) cyclohexyl second -1- base propionic ester.

It is highly preferred that the weight ratio of the component of the above-mentioned mixture containing zinc ricinate is wherein group containing zinc ricinate Close object: 1- cyclohexyl second -1- base butyrate: 1- cyclohexyl second -1- yl acetate: 1- (4'- Methylethyl) cyclohexyl second -1- base The ratio that propionic ester is about 2:1:1:1.

The preferred composition of the another kind that can be used for combining with zinc ricinate component or solution is mixture below:

(A) 1- cyclohexyl second -1- yl acetate；With

(B) 1- (4'- Methylethyl) cyclohexyl second -1- base propionic ester.

It is highly preferred that the weight ratio of the component of above-mentioned zinc ricinate mixture is wherein to combine containing zinc ricinate Object: 1- cyclohexyl second -1- yl acetate: 1- (4'- Methylethyl) cyclohexyl second -1- base propionic ester is the ratio of about 3:1:1.

Any material for being described herein as odor control agent can also be classified as another component as described herein In the case of, for the present invention, this material should be classified as odor control agent.

Compatibly, the pure and fresh composition of clothes contains solvent and/or plasticizer.Solvent and plasticizer, which play, helps water plasticizing fine The effect of the native abilities of dimension.Acceptable solvent and plasticizer include having 1-10 carbon compound.It is non-limiting below Classes of compounds is suitable: single methanol class, glycols (dials), polyalcohol, ethers, ketone, esters, organic acid and alkyl Glycerin ether and hydro carbons.Preferred solvent it is water-soluble and/or in the presence of optional surfactant it is miscible.Example includes first Alcohol, ethyl alcohol, isopropanol, hexanol, 1,2- hexylene glycol, hexylene glycol (such as 2- methyl -2,4-PD), Isopropanediol (3- methyl - 1,3 butylene glycol), 1,2- butanediol, 2,3- butanediol, 1,3 butylene glycol, 1,4- butanediol, 1,3- propylene glycol, 1,2- the third two Alcohol, the isomers of cyclohexanedimethanol, the isomers of propylene glycol, the isomers of butanediol, the isomers of trimethylpentanediol, second The isomers of ylmethyl pentanediol, the alcohol ethoxylate of 2- ethyl -1,3- hexylene glycol, 2,2,4- trimethyl -1,3- pentanediol, Alcohol ethoxylate, ethylene glycol, diethylene glycol (DEG), dipropylene glycol, the D-sorbite, fourth of 2,2,4- trimethyl -1,3- pentanediol glycerol Oxygroup ethoxy ethanol, 3- methyl -3- methoxybutanol, 3- methoxybutanol, 1- ethyoxyl -2- propyl alcohol, diethylene glycol monoethyl ether, Diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, triethylene glycol list ether, antierythrite and solvent and plasticizer mixture.When making At least 0.5%, at least 1%, at least 2%, at least 3% and when with solvent, usually to be selected from the pure and fresh composition weight of clothes At least 4% horizontal presence.Suitably, it is existing horizontal selected from the pure and fresh composition weight of clothes less than 30%, be less than 25%, less than 20% and less than 15%.

Suitably, the pure and fresh composition of the clothes includes surfactant.

Surfactant can help water (and therefore pure and fresh composition of clothes) to penetrate into fiber.Surfactant mentions For low surface tension, allow the pure and fresh composition of clothes easily and more uniformly in expanding on hydrophobic surface such as polyester and nylon It dissipates.The diffusion of the pure and fresh composition of clothes also dries it faster.Surfactant additionally aid water penetration with tend to repel water Water-repellent fabrics finishing agent processing fabric in.Remaining surfactant, which additionally aids, keeps small fiber to recline (fiat Against) fiber surface, to make smooth surface and facilitate smoothing wrinkle.It is fine that remaining surfactant can also play hardening The effect of dimension, to help to prevent to wrinkle again.

In multiple embodiments, the pure and fresh composition of clothes contains a effective amount of of the performance for improving the pure and fresh composition of clothes Surfactant is appropriately selected from 0.001%, 0.01%, 0.03%, 0.05% and the 0.1% of the pure and fresh composition weight of clothes.

Suitably, the amount of surfactant be selected from the pure and fresh composition weight of clothes less than 20%, less than 15%, it is small In 10%, less than 5%, less than 2%, less than 1%, less than 0.5% and less than 0.3%.

The OK range of the amount of surfactant is as follows: 0.001 to 20%, the 0.001% of the pure and fresh composition weight of clothes To 5%, 0.01 to 5%, 0.01 to 2%.

Suitably, which is compatible with anti-peculiar smell agent (such as cyclodextrin) so that it should substantially not with Anti- peculiar smell dosage form is at compound, to reduce the performance of the reagent and/or surfactant.Compound formation reduces reagent suction The ability and surfactant of getter taste reduce the ability of the surface tension of the pure and fresh composition of aqueous clothes.

The surface that suitable anti-peculiar smell agent compatible surfactants can be provided by anti-peculiar smell agent Surfactant The shortage of the effect of tension and easily identify.This is by existing in the solution and there is no about 1% specific anti-peculiar smell agent In the case where measure aqueous surfactant solution surface tension (dynes per centimeter²) Lai Shixian.Aqueous solution contains concentration 0.5%, 0.1%, 0.01% and 0.005% surfactant.Anti- peculiar smell agent can pass through the table of raising surfactant solution Face tension influences the surface-active of surfactant.If giving 1% of the surface tension and anti-peculiar smell agent under concentration in water The surface tension of similar face activating agent differs by more than about 10% in solution, then shows to deposit between surfactant and anti-peculiar smell agent In strong interaction.Possessed surface tension should be with the phase containing 1% anti-peculiar smell agent in aqueous solution for preferred surfactant (reduction) is differed compared with the surface tension of strength solution is less than about 10%, preferably less than about 5% and more preferably less than about 1%.

The example of compatible nonionic surfactant includes ethylene oxide and epoxy with anti-peculiar smell agent (such as cyclodextrin) The block copolymer of propane.Compatible suitable Block polyoxyethylene-polyoxypropylene is poly- with many reagents (especially cyclodextrin) Closing object surfactant includes being hydrogenated based on ethylene glycol, propylene glycol, glycerol, trimethylolpropane and ethylenediamine as initial activity Close those of object.It is prepared by the sequential ethoxylation and propoxylation of the precursor compound with single hydrogen atoms poly- Polymerisable compounds, such as C12-18 aliphatic alcohol, usually not with such as cyclodextrin-compatible.By BASF-Wyandotte Corp., Wyandotte, Mich are named asWithCertain block polymer surfactant compounds It is easy to get.

Silicone surfactant can be used, because these compounds generally give to fibre lubrication and slickness, make it It is easy to slide or slide past each other and therefore enhance the process of smoothing wrinkle or wrinkle control.

A kind of useful surfactant is nonionic silicone surfactant.Wherein, the kind of polyalkyleneoxide polysiloxane Class is suitable.In general, polyalkyleneoxide polysiloxane has dimethyl silicone polymer hydrophobic part and one or more hydrophilies Polyalkylene chain.The hydrophilic polyalkylene chain can be used as side chain (side section) or as block copolymer part and poly- silicon oxygen Alkane hydrophobic part combines.The non-limiting example of the surfactant of these types isSurfactant, can be from Crompton is obtained.Other non-limiting examples of polyalkyleneoxide polysiloxane include following being available from Dow The compound of 193,190, FF-400Fluid, Q2-5220, Q4-3667, Q2-5211, and can be from Toray Dow Coming Silicone Co., the compound that Ltd is obtained.

A kind of useful glass or plastic containers.For example, the non-ionic surface active of suitable type Agent is alkyl ethoxylated surfactant, such as the addition product of ethylene oxide and fatty alcohol, fatty acid, fatty amine etc..Second Oxygroup surfactant includes the compound with general formula:

R⁸-Z-(CH₂CH₂O)_sB

Wherein R⁸It is alkyl or alkylaryl, selected from primary, secondary and branched alkyl hydrocarbon, primary, secondary and branched-chain alkenyl alkyl, And/or the phenol alkyl that primary, secondary and branched alkyl-and alkenyl replace, there are about 6 to about 20 carbon atoms, preferably from about 8 to about 18 A carbon atom, more preferably from about 10 to about 15 carbon atoms；S is the integer of about 2 to about 45, preferably from about 2 to about 20, more preferably from about 2 To about 15；B is hydrogen, carboxylate or sulfate group；It is selected from linking group Z :-O- ,-N (R)_x、-C(O)O-、-C(O)N (R)-,-C (O) N (R)-and its mixture, wherein R (when it is present) is R⁸, the low alkyl group with about 1 to about 4 carbon, polycyclic Oxygen alkane or hydrogen and x are 1 or 2.

Suitably, these surfactants have from about 5 to about 20, and (Hydrophile-Lipophile is flat by the HLB of preferably from about 6 to about 15 Weighing apparatus).The example of commercial surfactant is Neodol 91-2.5 (C9-C10, s=2.7, HLB=8.5), Neodol 23-3 (C12-C13, s=2.9, HLB=7.9) and Neodol 25-3 (C12-C15, s=2.8, HLB=7.5).

A kind of useful surfactant is ionic surface active agent.Anionic surfactant is particularly useful, because it Most unlikely leave residue.Ionic surface active agent is also selected from cation and zwitterionic surfactant.

Suitable surfactant can in Surfactants and Interfacial Phenomena, 2nd Ed., It is found in Milton J.Rosen, 1989, John Wiley&Sons, Inc., pp.7-16, passes through reference herein and introduce. Suitable anionic surfactant can also in Handbook of Surfactants, M.R.Porter, 1991, It is found in Blackie&Son Ltd, pp.54-115 and bibliography therein, the disclosure of which passes through reference herein and introduces.It closes Suitable surfactant includesWAC,40(Stepan Co.,Northfield,III.).Yin Ionic surface active agent can also be generated by the sulphation or sulfonation of animal or plant base oil.The surface-active of these types The example of agent includes sulphation rapeseed oil and sulfated castor oil (Freedom SCO-75), can be from Freedom Chemical Co., Charlotte N.C. (BF Goodrich possesses) is obtained.

Suitable cation and zwitterionic surfactant are found in above-mentioned Handbook of Surfactants, Pp.179-202 and above-mentioned Surfactants and Interfacial Phenomena, pp.17-20 and pp.28-31 and Bibliography therein, the disclosure of which are hereby incorporated by reference.

A kind of useful surfactant is fluorine based surfactant.Fluorocarbon surfactant includes such surface Activating agent, wherein the hydrophobic part of amphiphile at least partly includes carbon-based linear or cyclic group certain parts, wherein institute Stating group has the fluorine connecting with carbon, and wherein hydrogen is usually connected to carbon together with hydrophilic head.It is some typical non-limiting Fluorocarbon surfactant includes fluorinated alkyl polyoxyalkylene and fluorinated alkyl esters and ionic surface active agent.Suitable example packet It includes9075, FSO, FSN, FS-300, FS-310, FSN-100, FS0-100,65FTS, TBC, from DuPont and Fluorad^TMSurfactant FC-430, FC-431, FC-740, FC-99, FC-120, FC-754, FC170C and FC-171 come From St.Paul, the 3M of Minn^TMCompany.

In some embodiments, the pure and fresh composition of clothes contains effective quantity to kill or reduce the water-soluble of microorganism growth Property anti-microbial active matter, about the 0.001% to about 0.8% of the pure and fresh composition weight of preferred garment, more preferably from about 0.002% To about 0.3%, even more preferably about 0.003% to about 0.2%, and it is preferably selected from halogenated compound, cyclic nitrogen compound, season Compound and phenolic compound.

Extensive quaternary compound also is used as anti-microbial active matter.The non-limiting example packet of useful quaternary compound It includes: (1) benzalkonium chloride class and/or substituted benzalkonium chloride class, for example (,) it is commercially available(can be obtained from Lonza),(can be obtained from Mason),(can be obtained from Witco/Sherex) andIt (can It is obtained from Lonza)；Short chain (the C1-4 alkyl and/or hydroxyalkyl) quaternary compound of (2) two (C6-C14) alkyl two, such as LonzaProduct, six ammonia chloride of (3) N- (3- chlorallyl), as that can be obtained from DowWith(4) benzethonium chloride, as from Rohm&Haas1622；(5) it is provided by Rohm&Haas Pass throughThe methyl benzethonium chloride that 10X is represented；(6) cetylpyridinium chloride, such as derived from Merrell The Cepacol chloride of Labs.The example of preferred Dialkyl quats is two (C8-C12) dialkyl dimethyl ammonium chlorides, Such as dimercaptodimethyl ammonium chloride (Bardac 22) and Quaternium 24 (Bardac 2050).These quaternary conjunctions The typical concentration range of object biocidal efficacy is about the 0.001% to about 0.8% of the pure and fresh composition weight of clothes, preferably from about 0.005% to about 0.3%, more preferably from about 0.01% to about 0.2%, and even more preferably about 0.03% to about 0.1%.

When antimicrobial is used together with surfactant, they can provide improved anti-microbial effect.This It is especially true for silicone surfactant, and especially when silicone surfactant and Chlorhexidine antimicrobial acivity When substance combines.

In multiple embodiments, the pure and fresh composition of clothes contains in terms of the pure and fresh composition weight of clothes about 0.01% to about 3%, more preferably from about 0.05% to about 1%, and the low molecular weight polyols of even more preferably about 0.1% to about 0.5%.

There are relatively high boiling low molecular weight polyols, such as ethylene glycol, diethylene glycol (DEG), triethylene glycol, the third two compared with water Alcohol, dipropylene glycol and/or glycerol are the preferred optional members for improving the odor control of the pure and fresh composition of clothes.

It is believed that the ability that polyalcohol is able to maintain the time longer than water allow it with anti-peculiar smell agent (such as cyclodextrin) and Some odor molecules form ternary complex.In the case where cyclodextrin, it is believed that glycol, which is added, to fill in cyclodextrin cavity Void space, which cannot be filled up completely by some odor molecules of relative small size.It is preferable to use glycol It is or mixtures thereof glycerol, ethylene glycol, propylene glycol, dipropylene glycol, more preferable ethylene glycol and propylene glycol.It is this polynary by generating The cyclodextrin of the method preparation of alcohol level is height needs, because they can be used in the case where not removing polyalcohol.

Some polyalcohols, such as dipropylene glycol, it can also be used to promote some fragrance components at of the invention pure and fresh group of clothes Close the dissolution in object.

In embodiments, the pure and fresh composition of clothes contains in terms of the pure and fresh composition weight of clothes about 0.001% to about 0.3%, preferably from about 0.01% to about 0.1%, the aminocarboxylic acid ester chelating agent of more preferably from about 0.02% to about 0.05%.

Chelating agent, such as ethylenediamine tetra-acetic acid (EDTA), hydroxy ethylene ethylenediamine triacetic acid, diethylene-triamine pentaacetic acid With other aminocarboxylic acid ester chelating agents and its mixture and their salt and their mixture, can be optionally used for increasing Add the antimicrobial and anti-corrosion effect of anti-gramnegative bacterium (especially pseudomonad species).Although to EDTA and other ammonia The sensibility of yl carboxylic acid ester chelating agent is mainly the characteristic of pseudomonad species, but thin to susceptible other of chelating agent height Fungus kind includes achromobacter (Achromobacter), alcaligenes (Alcaligenes), azotobacter, Escherichia Category, Salmonella, spiral Pseudomonas and vibrio.Other biological group (including fungi and yeast) also shows that these chelating agents Sensibility increase.In addition, aminocarboxylic acid ester chelating agent can help for example to keep product clarification, protection fragrance and fragrance group Point, and prevent rancid and peculiar smell.

In embodiments, the pure and fresh composition of clothes contains a effective amount of metal salt, preferably with the pure and fresh composition weight of clothes Meter about 0.1% to about 10%, more preferably from about 0.2% to about 8%, even more preferably about 0.3% to about 5%, it is especially water-soluble Property copper and/or zinc salt, for improving smell benefit；

Optionally, the pure and fresh composition of clothes may include metal salt to increase odor adsorption and/or antimicrobial benefit.Metal Salt is selected from mantoquita, zinc salt and its mixture.

Mantoquita has some antimicrobial benefits.Specifically, copper abietinate plays the role of fungicide, copper acetate is risen The effect of mould inhibitor, copper chloride play fungicide, and copper lactate plays fungicide and copper sulphate plays fungicide Effect.Mantoquita also has some peculiar smell control abilities.Referring to the 3rd, 172, No. 817 United States Patent (USP) of Leupold et al., wherein The deodorant compositions for handling disposable product are disclosed, it includes the acyl group acetone salt of at least water-slight soluble, including copper Salt and zinc salt, all these patents are all incorporated herein by reference.

Preferred zinc salt has peculiar smell control ability.Zinc is most often used since it alleviates the ability of peculiar smell, such as The 4th, 325, No. 939 United States Patent (USP) authorized in rinse product such as 20 days April nineteen eighty-two and the authorize for nineteen eighty-three September 4th the 4th, Disclosed in 469, No. 674 United States Patent (USP)s (licensing to N.B.Shah etc.), all these documents are incorporated herein by reference. Highly ionized and soluble zinc salt, such as zinc chloride provide the best source of zinc ion.Zinc borate plays fungistat and mould inhibitor Effect, zinc octoate plays the role of fungicide, and zinc chloride has the benefit of anti-corrosion and deodorization, and zinc ricinate rises antifungal Agent effect, Zinc vitriol play the role of fungicide, and Zinc Undecyenate plays fungistat.Institute as above It states, zinc ricinate can be used as the acquisition of the TEGO Sorb A30 from Evonik.

It is preferred that metal salt is or mixtures thereof water-soluble zinc salt, mantoquita, and more preferably zinc salt, especially ZnCl₂.These Salt, which is preferably in the present invention, to be mainly used for absorbing amine and sulfur-containing compound.Particularly, for the composition containing cyclodextrin, it For absorb molecular dimension it is too small and cannot be with cyclodextrin molecular effectively compound this kind of compound.Low molecular weight sulfur-bearing object Matter, such as sulfide and thio-alcohol are peculiar smell (such as the food odors (garlic, onion), body/stink with perspiration, breathing of many types Smell etc.) ingredient.Low molecular weight amine is also the ingredient of many peculiar smell (such as food odors, body odour, urine etc.).

It can be by water soluble alkali metal carbonate and/or bicarbonate such as sodium bicarbonate, saleratus, potassium carbonate, carbonic acid Caesium, sodium carbonate and its mixture are added in the pure and fresh composition of clothes to help to control certain acid-type odors.Preferred salt is carbon Sour sodium-hydrate, potassium carbonate, sodium bicarbonate, saleratus and their mixture.It is clear when these salt are added to clothes When in new compositions, they there are level be usually with about the 0.1% to about 5% of the pure and fresh composition method poidometer of clothes, it is excellent Choosing about 0.2% to about 3%, more preferably from about 0.3% to about 2%.

In embodiments, the pure and fresh composition of clothes contains a effective amount of enzyme, in terms of the pure and fresh composition weight of clothes about 0.0001% to about 0.5%, preferably from about 0.001% to about 0.3%, more preferably from about 0.005% to about 0.2%, for improving gas Taste controls benefit.Protease is particularly useful.Suitable water-solubility protein enzyme be pepsin, trypsase, ficin, Bromelain, papain and renin.Commercially available enzyme includes Novo Industries NS (Denmark)WithAnd International Bio- Synthetics, Inc.'s (Holland)

In embodiments, the pure and fresh composition of clothes contains a effective amount of dissolution, water-soluble anti-microbial preservative, It is preferred that in terms of the pure and fresh composition weight of clothes about 0.0001% to about 0.5%, more preferably from about 0.0002% to about 0.2%, it is optimal Choosing about 0.0003% to about 0.1%.

The pure and fresh composition of clothes uitably includes fabric care polysaccharide.

Suitable fabric care polysaccharide is that have those of spherical conformation in dilute aqueous solution by random coil structure.Institute Stating polysaccharide includes the homotype and/or abnormal shape polysaccharide with simple helical structure with or without branching, such as is with or without Isosorbide-5-Nitrae-α-connection skeleton structure (such as Isosorbide-5-Nitrae-alpha-glucans, Isosorbide-5-Nitrae-α-xylan) of branching, is with or without the 1,3- of branching β-connection skeleton (for example, galactan), and be with or without all 1,6- connections of branching skeleton (for example, glucan, Amylopectin, pustulan), and have about 5,000 to about 500,000, preferably from about 8,000 to about 250,000, more preferably from about 10,000 to about 150,000 weight average molecular weight, general size range is from 2nm to about 300nm, and preferably from about 3nm is to about 100nm, more preferably from about 4nm are to about 30nm.Size is defined as the revolution length that molecule occupies in dilute aqueous solution.

The proper level of fabric care polysaccharide with chondritic be selected from the pure and fresh composition weight of clothes 0.01% to 5%, 0.05% to 2%, 0.1% to 1%.

Preferably, fabric care polysaccharide is selected from arabogalactan, pachymaran, curdlan, callose (callose), paramylum, scleroglucan (sceleroglucan), lentinan, lichenin, laminarin, schizophyllum commune Polysaccharide (szhizophyllan), grifolan, sclerotinite glucan (SSG), Ompharia lapidescence glucan (OL-2), pustulan, dextran, amylopectin replace form and its derivative form.

Suitable fabric nursing branched polysaccharides with 1,3- β-connection skeleton are arabogalactans (also referred to as half Lactose araban or ε-galactan).Other fabric care polysaccharides of the part of skeleton are connected to 1,3- β- Example includes: 1,3- β-xylan (from such as Pencillus dumetosus)；Curdlan (curdlen), one kind 1,3- Beta glucan (from for example, Bacillus foecalis alkaligenes (Alcaligenes faecalis))；β-the Portugal paramylum B, 1,3- of one kind is poly- Sugar (comes from such as euglena gracilis (Euglena gracilis))；Lichenin, a kind of (1,3), (Isosorbide-5-Nitrae)-beta glucan is (from each Kind source, including Iceland's lichens (Cetraria islandica))；Scleroglucan, a kind of (1,3), (1,6)-beta glucan (come From such as Sclerotium rolfsii (Sclerotium rolfii)) and lentinan (lentinen), a kind of (1,3), (1,6) Portugal-β- Glycan (comes from, for example, edible Xianggu-mushroom (Lentinus edodes)).About these and other with 1,3- β-connection skeleton Polysaccharide more details in " Chemistry and Biology of (1 → 3)-β-Glucans ", B.A Stone and A In E.Clarke, La Trobe University Press, Victoria, Australia, 1992, pp.68-71 and 82-83 It provides, is hereby incorporated by reference.

Crease-resistant includes the function of removing or reducing wrinkle, and small using the consumer of spraying device of the invention This " going to wrinkle " or " smoothing wrinkle " are demonstrated in group research.

Suitably, amount of the anti wrinkling agent in the pure and fresh composition of clothes is selected from the pure and fresh composition weight of clothes at least 0.01%, at least 0.1% and at least 0.5%.Suitably, amount of the anti wrinkling agent in the pure and fresh composition of clothes is selected from: clothes Pure and fresh composition weight is no more than 10%, is no more than 8%, is no more than 6%, is no more than 5%, is no more than 4%, is no more than 3% Be no more than 2.5%.Suitable range can be selected from: 0.01 to 10%, 0.01 to 5%, the 0.1 of the pure and fresh composition weight of clothes To 5%, 0.1 to 3% and 0.1 to 2.5%.

Suitably, the pure and fresh composition of clothes contains silicone anti wrinkling agent.

Suitable silicone polymer is emulsified silicone, under being disclosed as having in the 34th section of US20050113282A1 Formula: (CH₃)₃SiO[(CH₃)₂SiO]mSi(CH₃)₂, wherein m is in the range of 1 to 8.Disclosed other useful silicone polymers It is the dimethyl silicone polymer class as disclosed in No. 6,001,343 29 column 1-25 row of U.S. Patent No..

Suitably, the composition includes silicone phospholipid polyalcohol additive, such as United States Patent (USP) No.5,237,035, and embodiment 56-85 is enumerated in the 12nd column, and ratio is 0.05% to 0.8%, preferably 0.1-0.3%, and most preferably 0.2%.

The composition may include water-soluble silicone, as disclosed in the US2002148994 of Giuvudan, by drawing With being incorporated herein.Silicone has Formulas I:

It is 0 to 20 and R1 is polyethylene or polypropylene ether that wherein M, which is 40 to 200, N,.

Suitably, silicone is dimethicone copolyol.Suitably, silicone be as with polyoxyethylene and/or The dimethicone copolyol of the dimethylsiloxane polymer of polyoxypropylene side chains.

Water-soluble silicone can contain at least one, preferably at least two kinds of dimethicone copolyols.Poly dimethyl silicon Oxygen alkane copolyol suitably has the surface-active that can be soaked with permeable fiber.Preferred polymer is that have to be greater than The ratio between 20/80, preferably greater than 40/60 ethylene oxide and propylene oxide (" EO/PO "), and in 25 DEG C of 0.1% aqueous solution In less than 25mN/m surface tension polymer.The example of dimethicone copolyol for use in the present invention include by TEGOPREN (R) nonionic series of Goldschmidt Corporation (Hopewell, VA) sale.

Suitably, the pure and fresh composition of clothes contains fragrance.Suitably, the amount of fragrance is selected from: the pure and fresh composition of clothes 0.001 to 5%, 0.001 to 2%, 0.01 to 1%, 0.001 to 1% and the 0.003% to 1% of weight.

For example, the pure and fresh composition of clothes can provide " scent signal " in the form of pleasant smell, for processing The fabric crossed provides feeling of freshness.Scent signal can be designed to provide transient fragrance smell.It is smelt when addition fragrance is used as When feeling signal, only added with extremely low level, for example, about 0% to about 0.5% in terms of the pure and fresh composition weight of clothes, it is excellent Choosing about 0.003% to about 0.3%, more preferably from about 0.005% to about 0.2%.Fragrance can also be used as in product and fabric on more Strong smell addition.When preferred higher levels of fragrance, relatively high-caliber fragrance can be added.It is particularly suitable for application In No. 5,445,747 United States Patent (USP)s that the example of the fragrance component of clothes authorized Kvietok et al. at nineteen ninety-five August 29th to Out, it is incorporated herein by reference.

When needing has lasting aromatic odor on clothes, it is preferable to use at least a effective amount of boiling point is about 300 DEG C Or higher fragrance component.The example of these preferred components authorizes the 5,500,138th of Bacon et al. on March 19th, 1996 It provides, is incorporated herein by reference in number United States Patent (USP).It further preferably uses after through the pure and fresh compositions-treated clothes of clothes It is capable of the material of slow release fragrance component.The Severns etc. that the example of such material was authorized on July 2nd, 1996 It is provided in the 5th, 531, No. 910 United States Patent (USP) of people, which is incorporated herein by reference.

Preferably, fragrance is hydrophilic and mainly by being grouped as, i.e., (a) ClogP is less than about selected from two groups of ingredients 3.5, more preferably less than about 3.0 hydrophilic composition, and ingredient and its mixture (b) with significant low detection threshold value.It is logical Often, at least about 50 weight %, preferably at least about 60 weight %, more preferably at least about 70 weight %, and most preferably at least about 80 weights The fragrance for measuring % is made of the fragrance component in above-mentioned (a) and (b) group.

About (a) hydrophilic perfume ingredients, which is more soluble in water, has lesser multiple with cyclodextrin The tendency of conjunction, and can more be obtained in the pure and fresh composition of clothes than the ingredient of conventional perfumes.The hydrophobic degree of fragrance component can be with it Octanol/water Partition Coefficients P is related.The Octanol/water Partition Coefficients of fragrance component are its equilibrium concentrations in octanol and in water Between ratio.Fragrance component with larger distribution coefficient P is considered more hydrophobic.On the contrary, having smaller distribution coefficient P Fragrance component be considered more hydrophilic.Due to the distribution coefficient of fragrance component value usually with higher, they are more square Just logP is provided in the form of their denary logarithms.Therefore, currently preferred fragrance hydrophilic perfume ingredients LogP is about 3.5 or smaller, preferably from about 3.0 or smaller.

It has been reported that the logP of many fragrance components；For example, can be from Daylight Chemical Information Systems, Inc. (Daylight CIS), the Pomona92 database that Irvine, Calif. are obtained include many, and to original The reference of beginning document.But logP value most conveniently passes through the calculating of " CLOGP " program, which can also be from Daylight CIS It obtains.The program also lists experimental logP values (when it can get in Pomona92 database)." logp of calculating " (ClogP) it is determined by the fragment method of Hansch and Leo (referring to A Leo, in Comprehensive Medicinal Chemistry, Vol.4, C.Hansch, P.G.Sammens, J.B.Taylor and C.A.Ramsden, Eds., p.295, Pergamon Press, 1990, be incorporated herein by reference).Chemical structure of the fragment method based on every kind of fragrance component, and examine Consider number amount and type, atom connectivity and the chemical bonding of atom.In the selection of the fragrance component of this paper, ClogP value is used (it is the most reliable and widely used estimated value of the physicochemical properties) rather than experimental logP values.

About the fragrance component of (b) low odor detection threshold, the odor detection threshold of odorous material is can be examined with smell The lowest vapor concentration for the material surveyed.Odor detection threshold and some odor detection thresholds are in such as " Standardized Human Olfactory Thresholds ", M.Devos etc., IRL Press at Oxford University Press, 1990 and " Compilation of Odour and Taste Threshold Values Data ", F.A Fazzalari, editor,ASTM Data Series DS 48A,American Society for Testing and Materials, It is discussed in 1978, two publications are both incorporated herein by reference.Use a small amount of fragrance with low odor detection threshold Ingredient can improve fragrance scent feature, even if they are hydrophilic not as good as given above group (a) of fragrance component.It can be used for taking Fill being not belonging to above-mentioned group (a) but there is the fragrance component of significant low detection threshold value to be selected from ambrox for pure and fresh composition (ambrox), bacdanol, benzyl salicylate, butyl anthranilate, ambrox (cetalox), damascenone (damascenone), α-damascone (damascone), γ-dodecalactone, Ebanol (ebanol), herbavert, suitable Formula -3- hexenyl salicylate, α-ionone, alpha, beta-lonone, α-daphnone, lilial (lilial), first Base nonyl ketone, gamma-undecalactone, undecylene aldehyde and its mixture.Other than the hydrophilic composition of group (a), these materials are excellent Choosing exists with low-level, and about the 20% of usually less than total perfume composition Weight, preferably less than about 15%, more preferably less than about 10%.However, only need to which very low level provides effect.

As described above, suitably fragrance is provided with encapsulated form, such as fragrance microcapsule (PMC).

Other than component listed above (such as polymer), the pure and fresh composition of clothes can optionally contain other auxiliary Odour controlling materials, chelating agent, antistatic agent (if necessary to more Electrostatic Controls), expelling parasite and drive moth agent in addition (insect and moth repelling agents), colorant (especially blueing agent), viscosity-control additive and they Mixture.The total level of optional member is preferably smaller than about the 10% of the pure and fresh composition weight of clothes, and more preferably less than about 5%, very To more preferably less than about 3%, still more preferably less than about 2%.These optional members do not include the other compositions being specifically mentioned above. Other optional materials be antistatic agent, expelling parasite and drive moth agent, optional colorant, optional plugging inhibitor, and its optionally The mixture of ingredient.

Suitably, the pure and fresh composition of clothes is substantially free of being suitably substantially free of, suitably using without any Under the conditions of can make or pollute the material of garment fabric dirty.

Clothes can be any clothing.

Applicant have observed that causing the reagent of peculiar smell and smell, and the actually this examination for causing peculiar smell and smell The accumulation mode of agent is garment feature, and is different from other materials, such as hard surface and Household ornament product.It is washed with clothes That washs benefits from cleaning formulation and cleaning process for custom made clothing (with the system for example differently customized for upholstery Agent and method are opposite) identical mode, it is clear that the pure and fresh composition of clothes (and its relevant spraying device) can be customized for clothes Newly.

According to the second aspect of the invention, a kind of replacement storage for the pure and fresh product of clothes according to above-mentioned aspect is provided Device, the replacement reservoir are pre-filled with the pure and fresh composition of the clothes for product supply of certain volume.

Replacement reservoir can be rigid or flexible.Replacing reservoir may include one or more rigid walls and/or one Or multiple flexible walls.In the case where flexible reservoir, reservoir can use the form of pouch.

Suitably, replacement reservoir is that bonding part elongated and that there is the longitudinal axis along elongated reservoir axially to extend is used It is engaged in the reception of spraying device or mating part.Easily, shield includes the reception or mating part.Suitably, may be used The bonding part for discharging reservoir includes the threaded portion being spirally connected for the receiving portion with spraying device.For example, replaceable storage Device may include vertical annular lip, which is provided with the external screw thread being spirally connected for the recessed area with shield, should Recessed area includes internal thread pockets.

Easily, replacement reservoir can provide in suit.In fact, relevant to the second aspect of the present invention further Aspect be include replace reservoir suit.

" refilling suit " appropriate includes one or more reservoirs.In the case where more than one reservoir, such as two, The content (the pure and fresh composition of clothes) of three, four, five or more reservoirs, each reservoir can be identical as other reservoirs Or it is different.For example, suit may include multiple reservoirs, each reservoir have different anti-peculiar smell agent and/or different anti wrinkling agents and/ Or fragrance.

The suit may include specification, such as be detached from related explanation with by reservoir and humidifier/shield is connect/.

In the case where suit is comprising having the reservoir of the pure and fresh composition of different garment (such as including different fragrance), explanation Book can also provide the guidance about selection reservoir to match with desired use (for example, types of garments to be updated).

In embodiments, spraying device of the suit comprising any of aforementioned aspects and at least one, suitably two Or more replacement reservoir.

According to the third aspect of the invention we, it is pure and fresh spraying that a kind of clothes are provided, it includes formed by the pure and fresh composition of clothes Mist, the pure and fresh composition of clothes include at least one of the following: anti-peculiar smell agent；Crease-resistant compound；And fragrance；Wherein The spraying cone angle is in the range of 55 to 80 degree；And the mist is by 0.25 to the 1.5ml clothes pure and fresh composition Dosage is formed, and includes the drop that average diameter range is 20 to 200 μm.

According to the fourth aspect of the invention, a kind of pure and fresh spraying method of clothes generated according to above-mentioned aspect is provided, This method includes according to the offer of any one of aforementioned aspects and operated products (spraying device).

According to the fifth aspect of the invention, a kind of method of pure and fresh clothes is provided comprising grasp according to any preceding aspect The step of making product (spraying device), to guide the spraying output of device to clothes.

According to the sixth aspect of the invention, a kind of method of pure and fresh clothes is provided, including the clothes of above-mentioned aspect are pure and fresh The step being applied on clothes by spraying.

According to the seventh aspect of the invention, it provides and is used to incite somebody to action according to the product (spraying device) of any one of aforementioned aspects The pure and fresh composition of clothes is administered on clothes so that the pure and fresh purposes of clothes.

According to the eighth aspect of the invention, the pure and fresh use for being used for pure and fresh clothes by spraying of clothes according to above-mentioned aspect is provided On the way.

As used herein, " aerosol " refers to that (the pure and fresh composition of clothes) dry particle or suspending drops are aerial Colloid.Drop is particularly interesting.Aerosol can be used propellant (in this case, spraying device can with it is non-just Formula term " aerosol-type device " refers to) or without propellant generation.As described in elsewhere, the present invention is more particularly directed to non-propulsion Agent device.

As used herein, " clothes " refer to clothes/clothing.It does not include the part as home furnishings, carpet, curtain etc. Material or fabric.Therefore, unless otherwise indicated, " fabric " being otherwise mentioned above refers to " garment fabric ".

Scheme and each of related fields and optional feature can be with other schemes and its related fields and optional spy The combination of any one or more of sign.

Detailed description of the invention

In order to which the present invention can be more easily to understand, and it is understood that its further feature, with reference to the drawings Embodiments of the present invention are described by way of example, in which:

Fig. 1 is lateral elevational view, shows the pure and fresh product of fabric of a possible embodiment according to the present invention；

Fig. 2 is lateral elevational view, shows the liquid reservoir of product shown in Fig. 1, wherein removing the shield and phase of product The humidifier of pass.

Fig. 3 is show in schematic partial sections, shows the shield and related humidifier of product；

Fig. 4 is show in schematic partial sections, is approximately similar to Fig. 3, but it illustrates the substitutions of shield and humidifier Construction；With

Fig. 5 is lateral elevational view, shows the exemplary fine mist that can be generated by product.

Fig. 6 A is the schematic diagram of Clothing Sample imaging device, including camera, shell, Clothing Sample and incident light.

Fig. 6 B shows image and its relevant folding line scoring (its assessment from sense organ group) of Clothing Sample.

Fig. 6 C shows the image of Clothing Sample before and after crease-resistant (removal wrinkle) clothes of application pure and fresh composition, And relevant folding line scoring.

Fig. 7 shows the droplets size distribution figure for measuring and obtaining from Malvern Spraytec instrument, has and corresponds to The peak maximum of average droplet size.

Specific embodiment

Turning now to considering that attached drawing, Fig. 1 show the exemplary reality of the pure and fresh product of fabric according to the present invention in more detail Mode is applied, imagination provides the form of spraying device in a handheld.In general, product 1 includes container 2, on the top of container 2 Shield 3 is provided in portion.Container 2 can be provided in the form of bottle, and be limited pure and fresh for receiving the clothes of certain volume The reservoir of composition, as will be described in more detail.The plan of shield 3 accommodates humidifier, which is configured to calmly Device 2 extracts the pure and fresh composition of clothes of doses, is atomized the dosage, and the side outlet hole 4 by being arranged in shield 3 is discharged The dosage of atomization, the atomization dosage are discharged in the form of thin aerosol and along the spray direction generally indicated with 5.

Although in the broadest sense, the present invention is interpreted as dry with the aerial pure and fresh composition of clothes that suspends The form of the colloid of dry particle or drop generates thin aerosol correlation, and description is particularly configured for use in generation in air with liquid The thin aerosol of the form of the mist of drop, so that dry powder form provides the pure and fresh composition 12 of clothes in liquid form rather than for example Embodiment of the present invention.

Reservoir/container

Turning now to Fig. 2 is considered, illustrates in greater detail illustrative reservoir and limit container 2, wherein removing shield 3. As that will point out, the specific structure of shown container 2 is shown, is mentioned in the form of elongated and substantially straight flange cylindrical bottles For there are the upper shoulder regions 6 being inwardly tapered, which, which narrows, limits upright ring with the top in container Shape antelabium 7, and centered on the longitudinal axis of container 8.Antelabium 7 is shown as with external screw thread 9 in order between container 2 and shield 3 Releasable engagement.It will be apparent, however, that the releasable engagement of other forms is possible between container 2 and shield 3.

It is understood that the reservoir, which limits container 2, defines the internal capacity for receiving the pure and fresh composition 12 of clothes 10.The plan of product 1 is supplied to end user with initial pre-filled state, and wherein reservoir has been substantially filled with proper volume The pure and fresh composition 12 of clothes.

Imagine in some embodiments, container 2 will be by the plastic material for the suitable type for becoming known for consumer product area It is molded.However, container 2 may also be formed by glass, or include at least glass.

Although should also be understood that the reservoir containing the pure and fresh composition of clothes of embodiments disclosed herein by container 2 itself It limits, it is contemplated however that other variants, wherein reservoir can be used as the offer of independent container comprising the pure and fresh composition 12 of clothes, should Container is simply accommodated and is supported in container 2.

The pure and fresh composition of clothes

The illustrative aqueous pure and fresh composition of clothes of spraying device suitable for Fig. 1 to 4 includes one or more of.

0.01 to 5wt% anti-odorous compound (such as zinc ricinate)

0.01 to 2% surfactant

0.001 to 0.8% antimicrobial

0.01 to 3% low molecular weight polyols

0.001 to 0.3% aminocarboxylic acid ester chelating agent

0.1 to 10% metal salt

0.0001 to 0.5% enzyme

0.0001 to 0.5% antibiotic antiseptic

0.1 to 2.5wt% crease-resistant compound (such as the crease-resistant compound of silicone)

0.001 to 5wt% fragrance (fragrance especially encapsulated, such as PMC)

The water of surplus

Shield

Diagrammatically illustrate the various aspects of shield 3 in more detail in Fig. 3.

Shown in shield 3 particular configuration be some it is elongated and be it is columnar, have the longitudinal axis 12.Imagine some In embodiment, shield 3 is molded by suitable plastic material.Specific shield 3 shown in more specifically, is configured to its diameter It is substantially equal to the diameter of container 2, so that shield 3 and the combination of container 1 are total to be formed when being installed on container 2 as shown in Figure 1 Body straight flange and elongated product 1.

The bottom of shield 3 be provided with it is recessed construction 13, this it is recessed construction 13 be configured to receive and engagement container 2 it is most upper End.Particularly, recessed area 13 includes internal thread pockets 14, and size and construction are configured to be threadedly engaged container in a usual manner The antelabium 7 of 2 correspondence screw thread, to provide so that the convenient means that shield 3 and container 2 are releasedly interconnected.It should manage Solution, especially consideration Fig. 1, when shield 3 and container 2 are interconnected in this way, shield will be installed on container 2 so as to by It upwardly extends and is aligned with the longitudinal axis of container 28.In fact, the longitudinal axis 8 with container 2 is overlapped by the longitudinal axis 13 of shield 3.

However, it should be noted that although above-mentioned shield 3 and container 2 are configured to be connected through a screw thread and be releasably engaged, The connection that other forms can be used replaces.For example, it is contemplated to which wherein shield 3 and container 2 can be configured for as interference A kind of variant of the releasable engagement of cooperation.This arrangement can be come real by adjusting the size of the non-threaded recess portion 14 of shield It is existing, so that it is as the non-threaded antelabium 7 for receiving simultaneously engagement container that is closely slidably matched, so that recess portion 14 and/or antelabium 7 will be Flexible deformation is when they are slidably engaged with each other to provide fastening but releasable interconnection.

Because container 2 and shield 3 can discharge each other as described above, work as the initial provision of the pure and fresh composition 12 of its clothes When having exhausted, container 2 can be removed from shield 3 and its relevant humidifier, consequently facilitating the supplement of product 1.This can pass through Original container 2 is replaced with the replacement container filled with the pure and fresh composition 12 of clothes, or simply by refilling original appearance Device 2 is realized.

Humidifier

Referring again to FIGS. 3, it should be noted that the receiving humidifier of shield 3, is generally indicated with 15.It is clear that humidifier 15 be disposed for it is in person hand-manipulated by the user of product 1, and include allow it without using it is so-called " aerosol spray The humidifier operated in the case where that pressurized propellant used in mist ".

Therefore, humidifier 15 may include manually operable pump 16, can use any convenient form, such as Positive-displacement pump, self priming pump or reciprocating pump.Pump 16 is mechanically connected to actuator, uses and presses in specific arrangements shown in Fig. 3 The form of button 17, button 17 is contained in the aperture 18 of the upper end of shield 3 setting, in order to while holding product 1 It is pressed by the finger of user.Button 17 is shown as being installed to the end of plunger 19, and plunger 19 extends to the inner shell of pump 16 Pump 16 is activated in body and when driving downwards by the operation of button 17.

The entrance 20 of pump 16 is shown as connected to inlet tube 21, and inlet tube 21 can use the form of one section of flexible duct. It is appreciated that inlet tube (" is drawn when shield 3 and its relevant humidifier 15 are installed in the manner shown in fig. 1 on container 2 Take pipe ") 21 it will extend downwardly and terminate at from the mechanism the pure and fresh combination of clothes that is limited by container 2 is located at its open end 22 The bottom of object reservoir.Therefore, inlet tube 21 is convenient for aspirating the pure and fresh composition 12 of clothes from reservoir when operating humidifier 15.

Humidifier 15 further includes nozzle 23, and nozzle 23 is fluidly connected to the outlet of pump 16, and substantially completely closes In shield 3, so as to terminate at discharge end 24, discharge end 24 be positioned adjacent to shield 3 outlet opening 4 and substantially with its Alignment.Small discharge orifice 25 is formed in nozzle 23, and is configured to when operating humidifier 15, by outlet opening 4 along spray The aerosol of the form of fine mist of the pure and fresh composition 12 of the outside guide garments in mist direction 5.As should be noted that, spray direction 5 is preferably It is substantially perpendicular to the respective longitudinal axis 8,12 of container 2 and shield 3, so that the user of product 1 is easily directed toward fabric clothes Etc..

In order to ensure generating the appropriate fine mist of the pure and fresh composition of clothes, humidifier 15 may include atomizer.It can With understanding, in the embodiment that the pure and fresh composition 12 of wherein clothes is provided as liquid, atomizer will be configured to by The liquid of the doses extracted by inlet tube 21 resolves into a large amount of droplet and thus generates pure and fresh group of required clothes The mist of object 12 is closed for being discharged from product 1.It is contemplated that in some embodiments, atomizer is by one as nozzle 23 The feature of body provides.Atomizer may include minor air cell and/or lateral dispersing chamber.

Fig. 4 shows the form of shield 3 shown in Fig. 3 and related humidifier 15 slightly improved.Shown in Fig. 4 Form is identical as many aspects of form shown in Fig. 3, and therefore identical or equivalent component is identified by identical Ref. No., And it will not be described in detail further.However, alternative configuration shown in Fig. 4 does not have the humidifier actuator of button form, but Instead of have can finger manipulation 26 form of trigger or lever actuator.As will be noted, trigger or lever 26 pass through pivot Axis connection 27 is installed relative to pump 16, so that trigger or lever can be by the operations that moves pivotally with transfer tube 16.Trigger or lever 26 from the protrusion of humidifier 15, the elongated slot 28 formed in the side wall in shield 3 (and optionally under outlet opening 4 Side), and terminate at the free terminal 29 being spaced apart with shield 3.Slit 28 be dimensioned to adapt at the time of activation trigger or The range of pivotal motion of lever.

It is understood that (perhaps being arranged by the button 17 under Fig. 3 deployment scenarios or by Fig. 4 in the starting of pump 16 Trigger or lever 26) when, pump is 16 by the pure and fresh composition 12 of the clothes for extracting doses from reservoir, and thus atomizer will make this Dosed nebulization.Then the aerosol by tap 25 as 29 form of mist is discharged the dosage being atomized, as shown in Figure 5.Such as It is already indicated above, mist 29 will be discharged along spray direction 5, which is substantially perpendicular to the longitudinal axis 8 of container 2.

It is considered advantageously, the discharge orifice 25 of nozzle 23 is configured to generate the sum of basic cone distribution in 55 to 80 degree The spraying mist 29 of cone angle A in range.It has been found that such spraying distribution is used in product 1 by pure and fresh group of clothes It closes when object 12 is sprayed onto clothes etc. above and extraordinary covering is provided, the regional area without generating excessive moisture.More specifically, In some embodiments, nozzle 23 and its related atomizer can be configured to generate with flat in 20 to 200 μ ms Drop in the mist 29 of equal diameter.

In some embodiments, it is contemplated that humidifier 15 will be configured to extract the clothes of doses in each actuating Pure and fresh composition 12 (its volume is 0.25 to 1.5ml) is filled, for being atomized and being discharged in the form of mist 29.Therefore, by product 1 The pure and fresh composition of clothes of the mist 29 of generation being sprayed every time by therefore containing 0.25 to 1.5ml.In other embodiments, Humidifier 15 can be configured to extract 0.5 to 1.2ml dosage in each actuating.

Average droplet size

(Malvern is come from using Malvern Spraytec particle and spray droplet dimension measuring device Instruments Ltd, UK) measure average droplet size and droplets size distribution.Using laser diffraction measurement spray droplet and The size of spraying granule.Measurement when laser beam by it is spraying when the intensity of light that scatters.Then the data are analyzed by measuring device To calculate the size for the drop for generating scattering pattern.Spraying device is located in appliance stand so that laser beam (diameter 1cm) from Across the center of spray plume (spray plume) at nozzle discharge orifices about 15cm.

The measurement of 5 second time is carried out while repeated priming (driving) is spraying.The process is repeated 3 times.

Average droplet size is taken as peak value/maximum value of the curve of liquid-drop diameter relative volume fraction.Example distribution figure is such as Shown in Fig. 7.

Spray cone angle

Spray cone angle measurement is carried out by the way that camera to be located in the side of spraying device.Spraying device is operated (for example, pressing Hydraulic actuator) and capture image quickly to record the image of spray plume.Then image is analyzed to identify spray plume Coboundary and lower boundary and with the line annotating images for corresponding to these boundaries, these lines from the discharge orifice of nozzle along boundary to Outer extension.Angle of the cone angle measuring between upper and lower line, as shown in Figure 5.

About Fig. 6 A to 6C, folding line removal experiment is carried out to assess and is configured to delivering with the spraying of feature described herein The effect of spraying device.

Garment fabric sample is the gambroon washed with Persil Non-Bio.Restore to test using industrial standard folding line Instrument wrinkles sample.It is put into sample wetness in folding line tester, top-heavness 1kg, and places 10 minutes.Sample is existed It is hung under 20 DEG C/65%RH 2-3 hours, then imaging is horizontal as " before " wrinkle.

Sample is atomized and from 1 pound of fabric bottom hung weight 5 seconds.Sample is suspended under 20 DEG C/65%RH and 2 Hour after and reimaging after 24+ hours.

It is imaged as follows using the imaging device schematically shown in Fig. 6 A.Sample is lain in side illumination In box.Image is shot right above from fabric.Due to side illumination, folding line is shown as high light and shade in the picture.Pass through screen Sense organ group on curtain scores to determine the level of the wrinkle in image.

The scoring of image folding line is given by being compared with reference scale.In a large amount of JND (Just Noticeable Difference scale is created after test) with the size of determination significant difference and difference.Score is 0-10 continuously linear mark Degree.

The pure and fresh composition of clothes includes silicone anti wrinkling agent.

Significant folding line removal is realized, folding line score reduces several integers.

Fig. 6 C shows the instructional images obtained before and after the treatments from sample.

Drop size

One example of drop size measurement result is as shown in Figure 7.Use Malvern Spraytec as described herein Instrument obtains data.Average droplet size is the peak maximum in liquid-drop diameter-volume fraction curve graph, in this case About 75 μm.

Composition

Carry out a series of experiments with test for a series of pure and fresh compositions of different clothes (including with different viscosities/ The pure and fresh composition of the clothes of rheological behaviour) above-mentioned drop and cone angle feature whether may be implemented.

Test result shows adjustable a certain range of viscosity/rheological behaviour, while keeping " spray applicability ".

When in the present specification and claims in use, term " includes " and "comprising" and its modification mean include Specified feature, step or integer.These terms are not construed as excluding the presence of other features, step or integer.

The feature disclosed in aforementioned specification or following claims or attached drawing, optionally with its particular form or with It is expressed for executing the disclosed means of function or the mode of method or process for obtaining disclosed result, Ke Yidan It is used to solely or with any combination of these features realize the present invention in the form of its multiplicity.

It is many etc. when providing the disclosure although having been combined above-mentioned example embodiment describes the present invention Same modifications and variations will be apparent those skilled in the art.Therefore, described above of the invention exemplary Embodiment is considered illustrative and not restrictive.It without departing from the scope of the invention, can be to being retouched The embodiment stated carries out various changes.

Claims

1. a kind of pure and fresh product of clothes (1), the pure and fresh product of clothes includes: the pure and fresh composition of clothes (12)；It is sprayed with hand-held Mist device is manually operable to generate being sprayed for the composition in the form of thin aerosol (29)；Composition (12) packet Containing at least one of anti-peculiar smell agent, anti wrinkling agent and fragrance；And the spraying device includes containing the composition (12) Reservoir (2) and the humidifier (15) being contained in shield (3), the longitudinal axis of the shield (3) substantially with the reservoir (2) (8) it is aligned；The humidifier (15) is manually operable and in the form of thin aerosol (29) and along spray direction (5) from product (1) composition (12) of discharging doses, the spray direction are substantially perpendicular to the longitudinal axis of reservoir (2) in (8)。

2. the pure and fresh product of clothes according to claim 1, wherein the humidifier (15) includes being located at the shield (3) Interior nozzle (23), the nozzle (23) have discharge orifice (25), and the discharge orifice is configured to have and spend range 55 to 80 The spraying and/or drop comprising average diameter in 20 to 200 μ ms of interior cone angle (A) is sprayed to generate the thin gas Colloidal sol (29).

3. the pure and fresh product of clothes according to claim 2, wherein it includes anti-that the pure and fresh composition of the clothes (12), which is selected from (A), The pure and fresh composition of the clothes of peculiar smell agent, anti wrinkling agent and fragrance；(B) includes the clothes of the fragrance of anti-peculiar smell agent, anti wrinkling agent and encapsulating Fill pure and fresh composition.

4. according to the pure and fresh product of clothes described in any one of aforementioned claim, wherein the anti wrinkling agent includes silicone.

5. according to the pure and fresh product of clothes described in any one of aforementioned claim, wherein the silicone includes one or more poly- two Methylsiloxane copolyol.

6. according to the pure and fresh product of clothes described in any one of aforementioned claim, wherein the anti-peculiar smell agent includes zinc ricinate Or its solution and substituted monocycle organic compound.

7. a kind of pure and fresh spraying method of generation clothes, the method includes providing and operate according to claim 1 to any in 6 Product (1) described in.