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CN109778375A - A kind of reflective silk thread of section surrounding tool reflective function - Google Patents

A kind of reflective silk thread of section surrounding tool reflective function Download PDF

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Publication number
CN109778375A
CN109778375A CN201910214750.1A CN201910214750A CN109778375A CN 109778375 A CN109778375 A CN 109778375A CN 201910214750 A CN201910214750 A CN 201910214750A CN 109778375 A CN109778375 A CN 109778375A
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CN
China
Prior art keywords
refractive index
reflective
fiber
adhesive layer
high refractive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910214750.1A
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Chinese (zh)
Inventor
任旭林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Lianghong New Materials Co Ltd
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Zhejiang Lianghong New Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Zhejiang Lianghong New Materials Co Ltd filed Critical Zhejiang Lianghong New Materials Co Ltd
Priority to CN201910214750.1A priority Critical patent/CN109778375A/en
Publication of CN109778375A publication Critical patent/CN109778375A/en
Pending legal-status Critical Current

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  • Ropes Or Cables (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Abstract

The present invention relates to reflectorized material more particularly to a kind of reflective silk threads.A kind of reflective silk thread of section surrounding tool reflective function, it includes common fiber, and the fiber periphery is coated with adhesive layer, and the adhesive layer adheres to high refractive index glass micro pearl.Reflective silk thread of the invention can be used to replace or part replaces ordinary lines to carry out woven fabric, has expanded the purposes of reflective silk thread.

Description

A kind of reflective silk thread of section surrounding tool reflective function
Technical field
The present invention relates to reflectorized material more particularly to a kind of reflective silk threads of section surrounding tool reflective function.
Background technique
Currently, people pay more attention to traffic safety.Reflective fabric, due to its special retroreflective energy, traffic-police, Sanitationman, clothes for student are ridden and shoes and hats dress ornament etc. is widely used.But it is limited to product characteristic and processing work Skill, either high refractive index glass micro pearl type reflective fabric or micro-prism type reflective strip, more highlight reflective function, And ignore the fashion of apparel industry.
In the market, the plastic sense and sealing of the grey of high refractive index glass micro pearl type reflective fabric and prism-type reflective strip Item, appearance all allow people that dare not flatter, therefore also all can be only applied on the retroreflective garments of some special occasions operations or personnel, and More daily dress ornaments can not be extended to.Also having and microbead type reflective fabric is cut into reflective strip, 3-5mm wide is band-like in flat strips, The section of cutting does not adhere to high refractive index glass micro pearl, therefore also without reflective function.Such reflective strip, though in city It is also referred to as reflecting thread on field, has for some reflective rope bands, but for weaving, the width of reflective strip is excessive, can not weave More exquisite fabric affects its use occasion.Narrower reflective strip can not cutting then due to the limitation of processing technology.
Summary of the invention
The purpose of the present invention is to solve the above problem of the existing technology, provide it is a kind of can be used for weaving it is reflective Silk.Reflective silk thread of the invention can be used to replace or part replaces ordinary lines to be woven into cloth, has expanded reflective silk thread.
What the object of the invention was realized in: a kind of section surrounding has the reflective silk thread of reflective function, it includes common Fiber, the fiber periphery is coated with adhesive layer, and the adhesive layer adheres to high refractive index glass micro pearl.
A kind of reflective silk thread of described section surrounding tool reflective function, it is the adhesive layer on fiber, through photocuring, After baking-curing or baking drying process, adherency high refractive index glass micro pearl is formed;Or adhesive layer is applied on fiber, first adherency is high Then refractive index glass microballon is formed through photocuring, baking-curing or baking drying.
A kind of reflective silk thread of section surrounding tool reflective function, the fiber include chemical fibre, plant fibre The combination of one or more of dimension, animal origin, inorganic non-metallic fiber, wire.
The chemical fibre includes but unlimited spandex, terylene, aramid fiber, polypropylene fibre, acrylic fibers, one or more of in vinylon material Combination.
The plant fiber includes the combination of one or more of cotton fiber, various flaxen fibers.
The animal origin includes the combination of one or more of wool, camel hair, the rabbit hair, silk.
The inorfil includes the combination of the one or more such as carbon fiber, asbestos.
A kind of reflective silk thread of described section surrounding tool reflective function, the wire include but unlimited copper wire, aluminium The combination of the one or more such as silk, steel wire.
A kind of reflective silk thread of section surrounding tool reflective function, the fibre section is converted into circular diameter range It is 5-5000 microns.
A kind of reflective silk thread of section surrounding tool reflective function, adhesive layer are made of high molecular material, including But unlimited polyacrylate resin, polyurethane resin, polyester resin, polyamide, Corvic, polyvinyl alcohol contracting fourth Urea formaldehyde, acrylic resin, epoxy resin, vinyl chloride-vinyl acetate resin, chlorinated polyether resin, amino resins, isocyanate resin etc. are a kind of or several The combination of kind resin.
A kind of section surrounding has the reflective silk thread of reflective, and the adhesive layer on fiber is passed through by fiber and applied The gluing of the method for inflammatory blepharoedema or felt device for painting.
A kind of reflective silk thread of section surrounding tool reflective function, which is characterized in that fiber filament tie layer surface High refractive index glass micro pearl, adhered to by the following two kinds mode: one is the fiber filaments with adhesive layer to rush across ball-planting device, from And surrounding adheres to high refractive index glass micro pearl;Another kind is that by way of fitting transfer, high refractive index glass micro pearl is shifted To adhesive layer, i.e. []: the fiber filament with adhesive layer rushes across two layers and is stained with the film of high refractive index glass micro pearl, and is bonded, thin Film walks that film direction is consistent with fiber filament, and the up-down rollers of fitting move back and forth along moving towards 90 ° of clipping speed limits with fiber filament, then remove thin High refractive index glass micro pearl on film is transferred on the adhesive layer of filament surface by film.
A kind of reflective silk thread of section surrounding tool reflective function, the refractive index of the high refractive index glass micro pearl For 1.90-1.93, partial size is 5-100 microns.
A kind of reflective silk thread of section surrounding tool reflective function, the high refractive index glass micro pearl is surface element Point or all did processing, what process face accounted for entire glass microballoon area is more than or equal to 0%, is less than or equal to 100%, material packet Include aluminium, zinc sulphide.Aluminium and zinc sulphide are attached to the surface of glass microballoon by way of vacuum evaporation.
A kind of reflective silk thread of section surrounding tool reflective function, the high refractive index glass micro pearl is embedded in bonding In layer, the height of insertion adhesive layer part accounts for the 10%-90% of Glass Bead Diameter.
The reflecting thread of a kind of reflective function that section surrounding has, which is characterized in that described is embedded in bonding The spacing between high refractive index glass micro pearl in layer is less than the partial size of high refractive index glass micro pearl.
The present invention adheres to reflective layer on common animal and plant fiber, and can be obtained after cured described can be used for weaving Reflecting thread.Ordinary lines can be partly or entirely replaced to carry out knitted or woven fabrics, so as to obtain the cloth with reflecting power, with Make various clothes, footgear, scarf, cap etc..It not only has reflection function, and beautiful.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention.
Specific embodiment
Referring to a kind of reflective silk thread of section surrounding tool reflective function of Fig. 1, it includes fiber 1, adhesive layer 2, high refraction Rate glass microballoon 3.It is realized by technique once: the adhesive layer on fiber, after photocuring, baking-curing or baking drying etc. After process, high refractive index glass micro pearl is adhered to;Adhesive layer can also be applied on fiber, first adhere to high refractive index glass micro pearl, so It is formed by photocuring, baking-curing or baking drying.
Fiber includes the combination of the one or more such as chemical fibre, plant fiber, animal origin, inorfil, wire.
It is 5-5000 microns that different fibre sections, which are converted into circular diameter range,.
Chemical fibre includes but one or more of groups such as unlimited spandex, terylene, aramid fiber, polypropylene fibre, acrylic fibers, vinylon material It closes;
Plant fiber includes but unlimited material includes but unlimited particularized below: cotton fiber, flaxen fiber etc. are one or more of Combination;
Animal origin includes the combination of the one or more such as wool, camel hair, the rabbit hair, silk;
Inorganic non-metallic fiber includes the combination of the one or more such as carbon fiber, asbestos;
Wire includes but the combination of the one or more such as unlimited copper wire, aluminium wire, steel wire.
Adhesive layer is made of high molecular material, including but unlimited polyacrylate resin, polyurethane resin, polyester resin, Polyamide, Corvic, polyvinyl butyral resin, acrylic resin, epoxy resin, vinyl chloride-vinyl acetate resin, chlorine ether The combination of the one or more resin such as resin, amino resins, isocyanate resin.
Adhesive layer on fiber passes through the method gluing of coating cup or felt device for painting by fiber.
The high refractive index glass micro pearl of fiber filament tie layer surface is adhered to by the following two kinds mode: one is bands to bond The fiber filament of layer rushes across ball-planting device, thus surrounding adherency high refractive index glass micro pearl;Another kind is to pass through the side of fitting transfer High refractive index glass micro pearl is transferred to adhesive layer by formula.Method particularly includes: the fiber filament with adhesive layer rushes across two layers and is stained with height The PET film of refractive index glass microballon, and being bonded, film walk that film direction is consistent with fiber filament, the up-down rollers of fitting along and fiber Silk moves towards 90 ° of clipping speed limits and moves back and forth, then stripping film, and the high refractive index glass micro pearl on film is transferred to fiber silk table On the adhesive layer in face.
The refractive index of high refractive index glass micro pearl is 1.90-1.93, and partial size is 5-100 microns.
High refractive index glass micro pearl can be surface portion or all do processing, and process face accounts for entire glass microballoon The 0%-100% of area, material include aluminium, zinc sulphide etc..Aluminium and zinc sulphide are adhered to high refraction by way of vacuum evaporation The surface of rate glass microballoon.
For high refractive index glass micro pearl in adhesive layer, the height of insertion adhesive layer part accounts for Glass Bead Diameter 10%-90%.
The spacing between high refractive index glass micro pearl in adhesive layer is less than the partial size of high refractive index glass micro pearl.
Below with drawings and examples, the present invention will be further described, but protection scope of the present invention is not limited to It is as described below.
[embodiment 1]:
Referring to a kind of reflective silk thread of section surrounding tool reflective function of Fig. 1, it includes fiber 1, adhesive layer 2, high refraction Rate glass microballoon 3.
The fiber 1 is terylene, and diameter is 70-150 μm.
The adhesive layer 2 is the mixture of polyacrylate resin, isocyanates, and coated cup is adhered to terylene silk table Face, drying, with a thickness of 10-15 μm.
The high refractive index glass micro pearl 3, refractive index 1.90-1.93, diameter are 30-45 μm, surface without aluminizing or Zinc sulphide processing is plated, adheres to high refractive index glass micro pearl by planting pearl equipment.
This reflective silk thread, bead planting technique is simple, and at low cost, retro-reflecting coefficient is low, meets low-end product requirement.
[embodiment 2]:
The fiber 1 is terylene, and diameter is 70-150 μm.
The adhesive layer 2 is the mixture of polyacrylate resin, isocyanates, and coated cup is adhered to terylene silk table Face, drying, with a thickness of 18-25 μm.
The high refractive index glass micro pearl 3, refractive index 1.90-1.93, diameter are 45-75 μm, and surface 50% is aluminized Or 50% plating zinc sulphide processing, pass through plant pearl equipment adhere to high refractive index glass micro pearl.
This reflective silk thread, bead planting technique is simple, and each angle retro-reflecting coefficient is balanced, non-directional.
[embodiment 3]:
The fiber 1 is terylene, and diameter is 200-250 μm.
The adhesive layer 2 is the mixture of polyacrylate resin, isocyanates, is adhered to and washs through felt device for painting Synthetic fibre silk table face, drying, with a thickness of 18-25 μm.
The high refractive index glass micro pearl 3, refractive index 1.90-1.93, diameter are 45-75 μm, and surface 100% is aluminized Or 100% plating zinc sulphide processing, pass through plant pearl equipment adhere to high refractive index glass micro pearl.
This reflective silk thread, bead planting technique is simple, need after post treatment by wire surface glass microballoon aluminium coated or Zinc sulfide layer removal is plated, retro-reflecting coefficient is high.
[embodiment 4]:
The fiber 1 is terylene, and diameter is 200-250 μm.
The adhesive layer 2 is the mixture of polyacrylate resin, isocyanates, is adhered to and washs through felt device for painting Synthetic fibre silk table face, drying, with a thickness of 18-25 μm.
The high refractive index glass micro pearl 3, refractive index 1.90-1.93, diameter are 45-75 μm, and surface 50% is aluminized Or 50% plating zinc sulphide processing, fitting transfer by way of, high refractive index glass micro pearl is transferred to adhesive layer.
This reflective silk thread, retro-reflecting coefficient are high.
[embodiment 5]:
The fiber 1 is spandex, and diameter is 200-250 μm.
The adhesive layer 2 is the mixture of polyacrylate resin, polyurethane resin, isocyanates, is painted through felt Device is adhered to spandex thread surface, drying, with a thickness of 18-25 μm.
The high refractive index glass micro pearl 3, refractive index 1.90-1.93, diameter are 45-75 μm, and surface 50% is aluminized Or 50% plating zinc sulphide processing, fitting transfer by way of, high refractive index glass micro pearl is transferred to adhesive layer.
This reflective silk thread, retro-reflecting coefficient is high, and has elasticity.
[embodiment 6]:
The fiber 1 is aramid fiber, and diameter is 200-250 μm.
The adhesive layer 2 is polyamide, is adhered to aramid fiber yarn surface through felt device for painting, is dried, with a thickness of 18-25μm。
The high refractive index glass micro pearl 3, refractive index 1.90-1.93, diameter are 45-75 μm, and surface 50% is aluminized Or 50% plating zinc sulphide processing, fitting transfer by way of, high refractive index glass micro pearl is transferred to adhesive layer.
This reflective silk thread retro-reflecting coefficient is high, and dry cleaning resistance has preferable anti-flammability.
[embodiment 7]:
The fiber 1 is spandex, and diameter is 200-250 μm.
The adhesive layer 2 is polyacrylate resin, polyurethane resin mixture, is adhered to ammonia through felt device for painting Pearl, photocuring, with a thickness of 18-25 μm are planted by ball-planting device in synthetic fibre silk table face.
The high refractive index glass micro pearl 3, refractive index 1.90-1.93, diameter are 45-75 μm, surface without aluminizing or Without plating zinc sulphide processing.
This reflective silk thread, speed of production is fast, adhesive layer process environmental protection, at low cost.Retro-reflecting coefficient is low, and has elasticity.
[embodiment 8]:
The fiber 1 is terylene, and diameter is 250-450 μm.
The adhesive layer 2 is the mixture of polyacrylate resin, polyurethane resin, and coated cup device, which is adhered to, to be washed Synthetic fibre silk table face, photocuring, with a thickness of 18-25 μm.
The high refractive index glass micro pearl 3, refractive index 1.90-1.93, diameter are 45-75 μm, and surface 50% is aluminized Or 50% plating zinc sulphide processing, fitting transfer by way of, high refractive index glass micro pearl is transferred to adhesive layer.
This reflective silk thread, retro-reflecting coefficient is high, high production efficiency, and environmental protection.
[embodiment 9]:
The fiber 1 is cotton and blend polyester, and diameter is 500-700 μm.
The adhesive layer 2 is the mixture of polyacrylate resin, polyurethane resin, and coated cup device is adhered to mixed Spinning surface, photocuring, with a thickness of 18-25 μm.
The high refractive index glass micro pearl 3, refractive index 1.90-1.93, diameter are 45-75 μm, and surface 50% is aluminized Or 50% plating zinc sulphide processing, fitting transfer by way of, high refractive index glass micro pearl is transferred to adhesive layer.
This reflective silk thread, retro-reflecting coefficient is high, high production efficiency, and environmental protection.
[embodiment 10]:
The fiber 1 is copper wire, and diameter is 800-1000 μm.
The adhesive layer 2 is the mixture of polyacrylate resin, polyurethane resin, and coated cup device is adhered to copper Silk table face, photocuring, with a thickness of 18-25 μm.
The high refractive index glass micro pearl 3, refractive index 1.90-1.93, diameter are 45-75 μm, and surface 50% is aluminized Or 50% plating zinc sulphide processing, fitting transfer by way of, high refractive index glass micro pearl is transferred to adhesive layer.
This reflective silk thread, retro-reflecting coefficient is high, and fixed effect is good, can be applied to headwear etc., and high production efficiency, environmental protection.
[embodiment 11]:
The fiber 1 is flax silk, and diameter is 500-850 μm.
The adhesive layer 2 is the mixture of polyacrylate resin, isocyanates, is adhered to fiber crops through felt painting installation Silk table face, drying, with a thickness of 18-25 μm.
The high refractive index glass micro pearl 3, refractive index 1.90-1.93, diameter are 45-75 μm, and surface 50% is aluminized Or 50% plating zinc sulphide processing, fitting transfer by way of, high refractive index glass micro pearl is transferred to adhesive layer.
This reflective silk thread, retro-reflecting coefficient are high.

Claims (11)

1. a kind of reflective silk thread of section surrounding tool reflective function, it includes common fiber, which is characterized in that the fiber Periphery is coated with adhesive layer, and the adhesive layer adheres to high refractive index glass micro pearl.
2. a kind of reflective silk thread of section surrounding tool reflective function according to claim 1, it is characterised in that: it be Adhesive layer on fiber, after photocuring, baking-curing or baking drying process, adherency high refractive index glass micro pearl is formed;Or Adhesive layer is applied on fiber, first adheres to high refractive index glass micro pearl, is then formed through photocuring, baking-curing or baking drying.
3. a kind of reflective silk thread of section surrounding tool reflective function according to claim 1, which is characterized in that the fibre Dimension includes the combination of one or more of chemical fibre, plant fiber, animal origin, inorganic non-metallic fiber, wire;
The chemical fibre includes but one or more of unlimited spandex, terylene, aramid fiber, polypropylene fibre, acrylic fibers, vinylon material group It closes;
The plant fiber includes the combination of one or more of cotton fiber, various flaxen fibers;The animal origin includes sheep The combination of one or more of hair, camel hair, the rabbit hair, silk;
The inorfil includes the combination of one or more of carbon fiber, asbestos;
The wire includes the combination of one or more of copper wire, aluminium wire, steel wire.
4. a kind of reflective silk thread of section surrounding tool reflective function according to claim 1 or 3, which is characterized in that institute Stating fibre section and being converted into circular diameter range is 5-5000 microns.
5. a kind of reflective silk thread of section surrounding tool reflective function according to claim 1, it is characterised in that adhesive layer It is made of high molecular material, including polyacrylate resin, polyurethane resin, polyester resin, polyamide, polyvinyl chloride tree Rouge, polyvinyl butyral resin, acrylic resin, epoxy resin, vinyl chloride-vinyl acetate resin, chlorinated polyether resin, amino resins, isocyanates The combination of one or more of resin resin.
6. the reflective silk thread that a kind of section surrounding according to claim 1 has reflective function, which is characterized in that described Adhesive layer on fiber passes through the method gluing of coating cup or felt device for painting by fiber.
7. a kind of reflective silk thread of section surrounding tool reflective function according to claim 1, which is characterized in that fiber filament The high refractive index glass micro pearl of tie layer surface is adhered to by the following two kinds mode: one is the fiber filaments with adhesive layer to rush across Ball-planting device, thus surrounding adherency high refractive index glass micro pearl;Another kind is by way of fitting transfer, by high refractive index glass Glass microballon, which is transferred to the adhesive layer i.e. fiber filament with adhesive layer, to be rushed across two layers and is stained with the film of high refractive index glass micro pearl, and is pasted It closing, film walks that film direction is consistent with fiber filament, and the up-down rollers edge of fitting is moved towards 90 ° of clipping speed limits with fiber filament and moved back and forth, then High refractive index glass micro pearl on film is transferred on the adhesive layer of filament surface by stripping film.
8. a kind of reflective silk thread of section surrounding tool reflective function according to claim 1, which is characterized in that the height The refractive index of refractive index glass microballon is 1.90-1.93, and partial size is 5-100 microns.
9. a kind of reflective silk thread of section surrounding tool reflective function according to claim 8, which is characterized in that the height Refractive index glass microballon is surface portion or all did processing, and processing area accounts for being more than or equal to for entire glass microballoon area 0%, it is less than or equal to 100%, processing material includes aluminium and zinc sulphide, and aluminium and zinc sulphide are attached to glass by way of vacuum evaporation The surface of glass microballon.
10. a kind of reflective silk thread of section surrounding tool reflective function according to claim 8, which is characterized in that described For high refractive index glass micro pearl in adhesive layer, the height of insertion adhesive layer part accounts for the 10%-90% of Glass Bead Diameter.
11. a kind of reflecting thread of reflective function that section surrounding has according to claim 10, which is characterized in that institute The spacing between the high refractive index glass micro pearl in adhesive layer stated is less than the partial size of high refractive index glass micro pearl.
CN201910214750.1A 2019-03-20 2019-03-20 A kind of reflective silk thread of section surrounding tool reflective function Pending CN109778375A (en)

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Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001248081A (en) * 2000-03-03 2001-09-14 Keiwa Kogyo:Kk Reflection rope for boundary line of motor pool, etc.
US20030215631A1 (en) * 2002-05-17 2003-11-20 Kyung-Joong Kang Reflective yarn and method of producing the same
JP2004054147A (en) * 2002-07-24 2004-02-19 Unitika Sparklite Kk Retroreflective material
JP2004184646A (en) * 2002-12-03 2004-07-02 Unitika Sparklite Kk Retro-reflective material
KR20120116117A (en) * 2011-04-12 2012-10-22 디에스알 주식회사 Rope that the fuction of identification function is improved under the water
CN203630382U (en) * 2014-02-26 2014-06-04 台州市万创夜光明工贸有限公司 Reflective fabric with high washing durability
CN203930103U (en) * 2014-02-26 2014-11-05 台州市万创夜光明工贸有限公司 A kind of highlighted level color reflective cloth
JP2015191144A (en) * 2014-03-28 2015-11-02 ユニチカスパークライト株式会社 Retroreflective material
CA2983803A1 (en) * 2015-04-28 2016-11-03 C.R.Y. Sas Retroreflective, elongated, filamentous product, process for making the same, uses thereof and products made therefrom
CN106707388A (en) * 2017-03-23 2017-05-24 浙江海川安全防护用品有限公司 Colorful high-brightness hot-sticking reflective cloth and manufacturing process
CN206863262U (en) * 2017-03-23 2018-01-09 浙江海川安全防护用品有限公司 A kind of colorful reflection beads formed film
CN108562960A (en) * 2018-06-20 2018-09-21 上海清研新材料科技有限公司 Silk-screen printing reflective membrane and preparation method thereof
CN208293166U (en) * 2018-01-16 2018-12-28 福建益明纺织有限公司 A kind of luminescent and reflecting silk

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001248081A (en) * 2000-03-03 2001-09-14 Keiwa Kogyo:Kk Reflection rope for boundary line of motor pool, etc.
US20030215631A1 (en) * 2002-05-17 2003-11-20 Kyung-Joong Kang Reflective yarn and method of producing the same
JP2004054147A (en) * 2002-07-24 2004-02-19 Unitika Sparklite Kk Retroreflective material
JP2004184646A (en) * 2002-12-03 2004-07-02 Unitika Sparklite Kk Retro-reflective material
KR20120116117A (en) * 2011-04-12 2012-10-22 디에스알 주식회사 Rope that the fuction of identification function is improved under the water
CN203930103U (en) * 2014-02-26 2014-11-05 台州市万创夜光明工贸有限公司 A kind of highlighted level color reflective cloth
CN203630382U (en) * 2014-02-26 2014-06-04 台州市万创夜光明工贸有限公司 Reflective fabric with high washing durability
JP2015191144A (en) * 2014-03-28 2015-11-02 ユニチカスパークライト株式会社 Retroreflective material
CA2983803A1 (en) * 2015-04-28 2016-11-03 C.R.Y. Sas Retroreflective, elongated, filamentous product, process for making the same, uses thereof and products made therefrom
CN106707388A (en) * 2017-03-23 2017-05-24 浙江海川安全防护用品有限公司 Colorful high-brightness hot-sticking reflective cloth and manufacturing process
CN206863262U (en) * 2017-03-23 2018-01-09 浙江海川安全防护用品有限公司 A kind of colorful reflection beads formed film
CN208293166U (en) * 2018-01-16 2018-12-28 福建益明纺织有限公司 A kind of luminescent and reflecting silk
CN108562960A (en) * 2018-06-20 2018-09-21 上海清研新材料科技有限公司 Silk-screen printing reflective membrane and preparation method thereof

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Application publication date: 20190521