CN109778265A - A kind of metallic copper electroplate liquid containing epoxychloropropane - Google Patents
A kind of metallic copper electroplate liquid containing epoxychloropropane Download PDFInfo
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- CN109778265A CN109778265A CN201711102704.XA CN201711102704A CN109778265A CN 109778265 A CN109778265 A CN 109778265A CN 201711102704 A CN201711102704 A CN 201711102704A CN 109778265 A CN109778265 A CN 109778265A
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- epoxychloropropane
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Abstract
A kind of metallic copper electroplate liquid containing epoxychloropropane, in parts by weight, comprising: 30-50 parts of epoxychloropropane, 40-50 parts of aluminum sulfate, 30-60 parts of sldium lauryl sulfate, 15-20 parts of nickel hydroxide cobaltous sulfate, 10-20 parts of cobalt chloride, 15-30 parts of ferric sulfate, 10-20 parts of frerrous chloride, 10-15 parts of cuprous oxide, 15-20 parts of hydrochloric acid, 3-5 parts of acetic acid, 10-15 parts of dibastic sodium phosphate, 15-20 parts of sodium nitrite, 20-30 parts of potassium cyanide, 20-50 parts of sodium stannate, 20-50 parts of potassium hydroxide, 50-80 parts of ferroso-ferric oxide, 1000-3000 parts of deionized water.It joined ferroso-ferric oxide in electroplate liquid of the present invention, can effectively realize anti-corrosion effect.
Description
Technical field
The present invention relates to electroplate liquids, and in particular to a kind of metallic copper electroplate liquid containing epoxychloropropane.
Background technique
In mechanical processing process, the anti-corrosive grease of component surface adherency, cutting fluid, machinery oil, lubricant grease, grinding
Liquid, release agent etc. are mixed and are sticked together with dust, polishing dust, form thicker dirt.If the above dirt is not removed before heat treatment
It goes, then degreasing and rust removal is difficult to clean up after its quenching sinters obstinate solid grease into, and bubble attachment makes to plate thereon when plating
Layer forms gas detention type pin hole.Heat treated part surface inevitably adheres to one layer of greasy dirt, when dust is fallen on the surface,
And mix and stick together with grease, it is difficult to clean up over time, so that workpiece surface be made to form unconspicuous tiny oil mark, applies
Bubble residence forms pin hole thereon when plating.When in addition using mesh band type resistor furnace quenching, the greasy dirt and dust etc. of workpiece surface are miscellaneous
Matter particle is mixed to stick together, and sinters obstinate solid grease into, and when salt made from earth containing a comparatively high percentage of sodium chloride is tempered, the above grease forms with nitro salt obstinate again
Thermopolymer, when plating, are difficult that the above dirt is thoroughly cleared, and bubble hydrogen is easily adhered to above dirt, it is difficult to is discharged, to make
Coating generates pin hole and point phenomenon, and as bubble is gradually grown up, coating can be burst automatically, decortication phenomenon is generated, to lead
Send a telegraph the disadvantage of plating solution difference of hardness, dispersion performance and covering power difference.
In view of the above shortcomings, the designer, is actively subject to research and innovation, to found a kind of new structural metal
Copper electroplate liquid makes it with more the utility value in industry.
Summary of the invention
In order to solve the above technical problems, the object of the present invention is to provide a kind of, the metallic copper containing epoxychloropropane is electroplated
Liquid.
Technical scheme is as follows:
A kind of metallic copper electroplate liquid containing epoxychloropropane, which is characterized in that in parts by weight, comprising:
30-50 parts of epoxychloropropane, 40-50 parts of aluminum sulfate, 30-60 parts of sldium lauryl sulfate, nickel hydroxide cobaltous sulfate 15-
20 parts, 10-20 parts of cobalt chloride, 15-30 parts of ferric sulfate, 10-20 parts of frerrous chloride, 10-15 parts of cuprous oxide, 15-20 parts of hydrochloric acid,
3-5 parts of acetic acid, 10-15 parts of dibastic sodium phosphate, 15-20 parts of sodium nitrite, 20-30 parts of potassium cyanide, 20-50 parts of sodium stannate, hydroxide
20-50 parts of potassium, 50-80 parts of ferroso-ferric oxide, 1000-3000 parts of deionized water.
Further, in parts by weight, comprising: 40 parts of epoxychloropropane, 44 parts of aluminum sulfate, sldium lauryl sulfate 34
Part, 18 parts of nickel hydroxide cobaltous sulfate, 15 parts of cobalt chloride, 20 parts of ferric sulfate, 15 parts of frerrous chloride, 12 parts of cuprous oxide, hydrochloric acid 18
Part, 4 parts of acetic acid, 12 parts of dibastic sodium phosphate, 18 parts of sodium nitrite, 25 parts of potassium cyanide, 30 parts of sodium stannate, 35 parts of potassium hydroxide, four oxygen
Change 60 parts of three-iron, 2000 parts of deionized water.
A kind of preparation method of the metallic copper electroplate liquid containing epoxychloropropane, it is characterised in that: by epoxychloropropane, sulphur
Sour aluminium, sldium lauryl sulfate, nickel hydroxide cobaltous sulfate, cobalt chloride, ferric sulfate, frerrous chloride, cuprous oxide, hydrochloric acid, acetic acid, phosphorus
After sour hydrogen sodium, sodium nitrite, potassium cyanide, sodium stannate, potassium hydroxide, ferroso-ferric oxide are mixed, then pass through dispersion machine dispersion
After be add to deionized water, the electroplate liquid is obtained after stirring by high-speed mixer.
According to the above aspect of the present invention, the present invention has at least the following advantages:
It joined ferroso-ferric oxide in electroplate liquid of the present invention, can effectively realize anti-corrosion effect.
Specific embodiment
With reference to embodiment, the embodiment of the present invention is furthur described in detail.Following embodiment is used for
Illustrate the present invention, but is not intended to limit the scope of the invention.
A kind of preparation method of the metallic copper electroplate liquid containing epoxychloropropane, by epoxychloropropane, aluminum sulfate, laruyl alcohol
Sodium sulphate, nickel hydroxide cobaltous sulfate, cobalt chloride, ferric sulfate, frerrous chloride, cuprous oxide, hydrochloric acid, acetic acid, dibastic sodium phosphate, nitrous
Sour sodium, potassium cyanide, sodium stannate, potassium hydroxide, ferroso-ferric oxide be mixed after, then by dispersion machine dispersion after be added to from
In sub- water, the electroplate liquid is obtained after stirring by high-speed mixer.
Embodiment 1
A kind of metallic copper electroplate liquid containing epoxychloropropane, in parts by weight, comprising:
30 parts of epoxychloropropane, 40 parts of aluminum sulfate, 30 parts of sldium lauryl sulfate, 15 parts of nickel hydroxide cobaltous sulfate, cobalt chloride
10 parts, 15 parts of ferric sulfate, 10 parts of frerrous chloride, 10 parts of cuprous oxide, 15 parts of hydrochloric acid, 3 parts of acetic acid, 10 parts of dibastic sodium phosphate, nitrous
15 parts of sour sodium, 20 parts of potassium cyanide, 20 parts of sodium stannate, 20 parts of potassium hydroxide, 50 parts of ferroso-ferric oxide, 1000 parts of deionized water.
Embodiment 2
A kind of metallic copper electroplate liquid containing epoxychloropropane, in parts by weight, comprising:
40 parts of epoxychloropropane, 45 parts of aluminum sulfate, 45 parts of sldium lauryl sulfate, 18 parts of nickel hydroxide cobaltous sulfate, cobalt chloride
15 parts, 20 parts of ferric sulfate, 15 parts of frerrous chloride, 12 parts of cuprous oxide, 18 parts of hydrochloric acid, 4 parts of acetic acid, 12 parts of dibastic sodium phosphate, nitrous
18 parts of sour sodium, 25 parts of potassium cyanide, 30 parts of sodium stannate, 30 parts of potassium hydroxide, 30 parts of ferroso-ferric oxide, 2000 parts of deionized water.
Embodiment 3
A kind of metallic copper electroplate liquid containing epoxychloropropane, in parts by weight, comprising:
50 parts of epoxychloropropane, 50 parts of aluminum sulfate, 60 parts of sldium lauryl sulfate, 20 parts of nickel hydroxide cobaltous sulfate, cobalt chloride
20 parts, 30 parts of ferric sulfate, 20 parts of frerrous chloride, 15 parts of cuprous oxide, 20 parts of hydrochloric acid, 5 parts of acetic acid, 15 parts of dibastic sodium phosphate, nitrous
20 parts of sour sodium, 30 parts of potassium cyanide, 50 parts of sodium stannate, 50 parts of potassium hydroxide, 80 parts of ferroso-ferric oxide, 3000 parts of deionized water.
It joined ferroso-ferric oxide in electroplate liquid of the present invention, can effectively realize anti-corrosion effect.
The above is only a preferred embodiment of the present invention, it is not intended to restrict the invention, it is noted that for this skill
For the those of ordinary skill in art field, without departing from the technical principles of the invention, can also make it is several improvement and
Modification, these improvements and modifications also should be regarded as protection scope of the present invention.
Claims (3)
1. a kind of metallic copper electroplate liquid containing epoxychloropropane, which is characterized in that in parts by weight, comprising:
30-50 parts of epoxychloropropane, 40-50 parts of aluminum sulfate, 30-60 parts of sldium lauryl sulfate, nickel hydroxide cobaltous sulfate 15-20
Part, 10-20 parts of cobalt chloride, 15-30 parts of ferric sulfate, 10-20 parts of frerrous chloride, 10-15 parts of cuprous oxide, 15-20 parts of hydrochloric acid, second
3-5 parts sour, 10-15 parts of dibastic sodium phosphate, 15-20 parts of sodium nitrite, 20-30 parts of potassium cyanide, 20-50 parts of sodium stannate, potassium hydroxide
20-50 parts, 50-80 parts of ferroso-ferric oxide, 1000-3000 parts of deionized water.
2. a kind of metallic copper electroplate liquid containing epoxychloropropane according to claim 1, which is characterized in that according to weight
Number meter, comprising: 40 parts of epoxychloropropane, 44 parts of aluminum sulfate, 34 parts of sldium lauryl sulfate, 18 parts of nickel hydroxide cobaltous sulfate, chlorine
Change 15 parts of cobalt, 20 parts of ferric sulfate, 15 parts of frerrous chloride, 12 parts of cuprous oxide, 18 parts of hydrochloric acid, 4 parts of acetic acid, 12 parts of dibastic sodium phosphate,
18 parts of sodium nitrite, 25 parts of potassium cyanide, 30 parts of sodium stannate, 35 parts of potassium hydroxide, 60 parts of ferroso-ferric oxide, deionized water 2000
Part.
3. a kind of preparation method of metallic copper electroplate liquid containing epoxychloropropane according to claim 2, feature exist
In: by epoxychloropropane, aluminum sulfate, sldium lauryl sulfate, nickel hydroxide cobaltous sulfate, cobalt chloride, ferric sulfate, frerrous chloride, oxygen
Change cuprous, hydrochloric acid, acetic acid, dibastic sodium phosphate, sodium nitrite, potassium cyanide, sodium stannate, potassium hydroxide, ferroso-ferric oxide to be mixed
Afterwards, then after being dispersed by dispersion machine it is add to deionized water, the electroplate liquid is obtained after stirring by high-speed mixer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711102704.XA CN109778265A (en) | 2017-11-10 | 2017-11-10 | A kind of metallic copper electroplate liquid containing epoxychloropropane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711102704.XA CN109778265A (en) | 2017-11-10 | 2017-11-10 | A kind of metallic copper electroplate liquid containing epoxychloropropane |
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| CN109778265A true CN109778265A (en) | 2019-05-21 |
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| CN201711102704.XA Pending CN109778265A (en) | 2017-11-10 | 2017-11-10 | A kind of metallic copper electroplate liquid containing epoxychloropropane |
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4554061A (en) * | 1982-10-18 | 1985-11-19 | E. I. Du Pont De Nemours And Company | Anodic electrodeposition of charged aqueous powder slurry |
| CN101942684A (en) * | 2010-10-09 | 2011-01-12 | 济南德锡科技有限公司 | Alkaline electroplating Zn-Ni alloy additive, electroplating solution and preparation method |
| CN102031547A (en) * | 2010-11-05 | 2011-04-27 | 天津市飞荣达科技有限公司 | Device and method for continuously compounding plating metal and nano-particles on surface of carbon fiber |
| CN104294325A (en) * | 2014-10-10 | 2015-01-21 | 张志良 | Formula of electroplate liquid for automobile front cover |
| CN104911656A (en) * | 2015-06-13 | 2015-09-16 | 梁胜光 | Metal alloy electroplating liquid |
| CN105543759A (en) * | 2015-12-18 | 2016-05-04 | 合肥中澜新材料科技有限公司 | High-hardness corrosion-resistant wear-resistant engine cylinder inner-wall coating and preparation method thereof |
| CN106065486A (en) * | 2016-06-10 | 2016-11-02 | 太原工业学院 | A kind of non-cyanide copper electroplating compound additive and production technology thereof |
| CN106119911A (en) * | 2016-08-21 | 2016-11-16 | 无锡瑾宸表面处理有限公司 | Stable type electroplate liquid |
-
2017
- 2017-11-10 CN CN201711102704.XA patent/CN109778265A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4554061A (en) * | 1982-10-18 | 1985-11-19 | E. I. Du Pont De Nemours And Company | Anodic electrodeposition of charged aqueous powder slurry |
| CN101942684A (en) * | 2010-10-09 | 2011-01-12 | 济南德锡科技有限公司 | Alkaline electroplating Zn-Ni alloy additive, electroplating solution and preparation method |
| CN102031547A (en) * | 2010-11-05 | 2011-04-27 | 天津市飞荣达科技有限公司 | Device and method for continuously compounding plating metal and nano-particles on surface of carbon fiber |
| CN104294325A (en) * | 2014-10-10 | 2015-01-21 | 张志良 | Formula of electroplate liquid for automobile front cover |
| CN104911656A (en) * | 2015-06-13 | 2015-09-16 | 梁胜光 | Metal alloy electroplating liquid |
| CN105543759A (en) * | 2015-12-18 | 2016-05-04 | 合肥中澜新材料科技有限公司 | High-hardness corrosion-resistant wear-resistant engine cylinder inner-wall coating and preparation method thereof |
| CN106065486A (en) * | 2016-06-10 | 2016-11-02 | 太原工业学院 | A kind of non-cyanide copper electroplating compound additive and production technology thereof |
| CN106119911A (en) * | 2016-08-21 | 2016-11-16 | 无锡瑾宸表面处理有限公司 | Stable type electroplate liquid |
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Application publication date: 20190521 |