CN109757510A - A kind of pumpkin plant protection agent and preparation method thereof - Google Patents
A kind of pumpkin plant protection agent and preparation method thereof Download PDFInfo
- Publication number
- CN109757510A CN109757510A CN201910026113.1A CN201910026113A CN109757510A CN 109757510 A CN109757510 A CN 109757510A CN 201910026113 A CN201910026113 A CN 201910026113A CN 109757510 A CN109757510 A CN 109757510A
- Authority
- CN
- China
- Prior art keywords
- plant protection
- protection agent
- benzimidazolyl
- pumpkin
- poly
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 240000001980 Cucurbita pepo Species 0.000 title claims abstract description 27
- 239000011814 protection agent Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 31
- 229920001661 Chitosan Polymers 0.000 claims abstract description 17
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 16
- 235000000832 Ayote Nutrition 0.000 claims abstract description 15
- 235000009854 Cucurbita moschata Nutrition 0.000 claims abstract description 15
- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 claims abstract description 15
- 235000015136 pumpkin Nutrition 0.000 claims abstract description 15
- 208000031888 Mycoses Diseases 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 7
- GTCAXTIRRLKXRU-UHFFFAOYSA-N carbamic acid methyl ester Natural products COC(N)=O GTCAXTIRRLKXRU-UHFFFAOYSA-N 0.000 claims description 18
- -1 siloxanes Chemical class 0.000 claims description 15
- 229920001577 copolymer Polymers 0.000 claims description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 4
- WEYSQARHSRZNTC-UHFFFAOYSA-N 1h-benzimidazol-2-ylcarbamic acid Chemical compound C1=CC=C2NC(NC(=O)O)=NC2=C1 WEYSQARHSRZNTC-UHFFFAOYSA-N 0.000 claims description 3
- 230000006806 disease prevention Effects 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 2
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims description 2
- 150000004702 methyl esters Chemical class 0.000 claims description 2
- 241000196324 Embryophyta Species 0.000 abstract description 16
- 201000010099 disease Diseases 0.000 abstract description 12
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 12
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 5
- 239000000575 pesticide Substances 0.000 abstract description 5
- 230000004888 barrier function Effects 0.000 abstract description 3
- TWFZGCMQGLPBSX-UHFFFAOYSA-N carbendazim Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 230000001717 pathogenic effect Effects 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000002538 fungal effect Effects 0.000 abstract 1
- 208000015181 infectious disease Diseases 0.000 abstract 1
- 239000007921 spray Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 3
- 241000221785 Erysiphales Species 0.000 description 2
- 241000233679 Peronosporaceae Species 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920000832 Cutin Polymers 0.000 description 1
- 239000005802 Mancozeb Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000006013 carbendazim Substances 0.000 description 1
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 244000053095 fungal pathogen Species 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 125000002971 oxazolyl group Chemical group 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明涉及一种南瓜叶部真菌病害防治植保剂及其制备方法，属于农业技术领域，其包含的组分及其质量体积分数分别为：0.05‑0.2%的硅氧烷聚烷基氧化物共聚物、0.01‑1%的纳米二氧化硅、0.8‑1.0%的壳聚糖和0.01‑0.1%的N‑(2‑苯并咪唑基)氨基甲酸甲酯。所述植保剂能在南瓜叶片表面形成一道天然防菌杀菌屏障，有效抑制南瓜真菌病原病对植株的浸染，整个生长过程仅需喷1‑3次，大大降低农药用量施，减少农药对环境污染。The invention relates to a plant protection agent for preventing and controlling fungal diseases of pumpkin leaves and a preparation method thereof, belonging to the technical field of agriculture. compound, 0.01-1% of nano-silica, 0.8-1.0% of chitosan and 0.01-0.1% of methyl N-(2-benzimidazolyl)carbamate. The plant protection agent can form a natural antibacterial and bactericidal barrier on the surface of the pumpkin leaves, effectively inhibit the infection of the plants by the pumpkin fungal pathogenic disease, and only needs to be sprayed 1-3 times in the entire growth process, greatly reducing the amount of pesticides applied, and reducing the environmental pollution caused by the pesticides .
Description
Technical field
The invention belongs to agricultural technology fields, and in particular, to a kind of pumpkin leaf portion fungal disease prevention and treatment plant protection agent and its
Preparation method.
Background technique
Pumpkin is a kind of public vegetable crop being fond of, and has a very high edible and medical value, but cultivation from
The fungal diseases such as powdery mildew, anthracnose, epidemic disease, downy mildew often occur to Adult plant for seedling stage, prevent at present these diseases
It controls mainly using chemical prevention method, such as triadimefon, carbendazim, Bravo, Mancozeb, although these medicaments belong to low toxicity low
Remains of pesticide, but there is timeliness, need interval just to spray within 5-7 days using primary, medicament spray in pumpkin plant pathogenic process
It spills number up to 3-5 times, control cost is high, and there are certain harm to people and animals and environment.
Summary of the invention
In order to solve deficiency in the prior art, the purpose of the present invention is to provide a kind of pumpkin plant protection agents, and further
The method for preparing the plant protection agent is provided.The plant protection agent can form natural fungi-proofing sterilization barrier together in pumpkin blade surface,
Effectively inhibit dip dyeing of the pumpkin fungal pathogen disease to plant, entire growth course only needs spray 1-3 times, substantially reduces pesticide dosage
It applies, reduces pesticide environmental pollution.
To achieve the goals above, the present invention use the specific scheme is that
A kind of pumpkin plant protection agent, it includes component and its quality volume fraction be respectively as follows: the poly- alkyl of siloxanes of 0.05-0.2%
Oxide block copolymer, the nano silica of 0.01-1%, the chitosan of 0.8-1.0% and 0.01-0.1% N- (2- benzo miaow
Oxazolyl) methyl carbamate.
As the further optimization to above scheme, the component and its quality volume fraction that the plant protection agent includes are distinguished
Are as follows: 0.1% siloxanes poly- trialkylphosphine oxide copolymer, 0.05% nano silica, 0.9% chitosan and 0.05%
N- (2- benzimidazolyl) methyl carbamate.
The present invention further provides the methods for preparing above-mentioned pumpkin plant protection agent, comprising the following steps:
Step 1: weighing chitosan and N- (2- benzimidazolyl) methyl carbamate, dissolved respectively with acetic acid, it is poly- to obtain shell
Sugar juice and N- (2- benzimidazolyl) methyl carbamate solution；
Step 2: weighing nano silica and the poly- trialkylphosphine oxide copolymer of siloxanes；Weighed nano silica is added
Enter into ethylene glycol simultaneously stirring and dissolving, add the poly- trialkylphosphine oxide copolymer of weighed siloxanes, stirs, obtain suspension；
Step 3: by chitosan solution obtained by suspension obtained by step 2 and step 1 and N- (2- benzimidazolyl) carbamic acid
The stirring of distilled water constant volume is added in methyl ester solution mixing, prepares pumpkin leaf portion fungal disease prevention and treatment plant protection agent.
The utility model has the advantages that
Plant protection agent of the present invention includes the poly- trialkylphosphine oxide copolymer of siloxanes, nano silica, chitosan and N- (2- benzene
And imidazole radicals) four kinds of components of methyl carbamate, it is preferable to the control efficiency of pumpkin disease, wherein the poly- alkyl oxidation of siloxanes
Composition copolymer avoids drug effect from being lost as a kind of emulsifier so that plant protection agent is easier to be attached to blade face cutin layer surface；Nanometer two
Silica itself has certain antibacterial effect, can act synergistically with N- (2- benzimidazolyl) methyl carbamate and inhibit disease
Evil, chitosan are primarily used to form overlay film and are attached to blade face surface layer, formed with other components collective effect in pumpkin leaf surface
One of fungi-proofing sterilization barrier, can not only prevent germ from invading, additionally it is possible to play bactericidal effect to germ, reduce fungicide
It uses, reduces blade face residual, reduce cost, reduce environmental hazard, be conducive to protect environment.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described.
Embodiment 1
A kind of pumpkin plant protection agent, it includes component and its quality volume fraction be respectively as follows: siloxanes poly- trialkylphosphine oxide copolymerization
Object 0.05%, 0.01%, 0.8% chitosan of nano silica and 0.01% N- (2- benzimidazolyl) methyl carbamate.
The preparation method of above-mentioned plant protection agent, concrete operations are as follows:
(1) N- (2- benzimidazolyl) methyl carbamate is weighed according to above-mentioned quality volume fraction, is carried out with a small amount of acetic acid molten
Solution, is configured to N- (2- benzimidazolyl) methyl carbamate solution；
(2) chitosan is weighed according to above-mentioned quality volume fraction, with a small amount of acetate dissolution, is configured to chitosan solution.
(3) nano silica and the poly- trialkylphosphine oxide copolymer of siloxanes are weighed according to above-mentioned quality volume fraction, it is first
First nano silica is added in a small amount of ethylene glycol and is stirred, adds the poly- trialkylphosphine oxide copolymer of siloxanes, is stirred,
It is configured to suspension.
(4) chitosan of N- (2- benzimidazolyl) methyl carbamate solution, step 2 preparation for step 1 being prepared
The suspension that solution and step 3 are prepared is mixed, that is, prepares pumpkin leaf portion fungal disease plant protection agent.
Embodiment 2
A kind of pumpkin plant protection agent, it includes component and its quality volume fraction be respectively as follows: siloxanes poly- trialkylphosphine oxide copolymerization
Object 0.2%, 1%, 1.0% chitosan of nano silica and 0.1% N- (2- benzimidazolyl) methyl carbamate.
Preparation method is same as Example 1.
Embodiment 3
A kind of pumpkin plant protection agent, it includes component and its quality volume fraction be respectively as follows: 0.1% siloxanes poly- alkyl oxidation
Composition copolymer, 0.05% nano silica, 0.9% chitosan and 0.05% N- (2- benzimidazolyl) carbamic acid first
Ester.
Preparation method is same as Example 1.
In order to further prove the disease-controlling effect of plant protection agent of the present invention, following tests is done: only to spray clear water
(CK1) and only it sprays 0.05%N- (2- benzimidazolyl) methyl carbamate (CK2) and does control group, benefit is prepared with embodiment 3
Pumpkin leaf portion fungal disease is prevented and treated plant protection agent and is carried out once when pumpkin is colonized 90 days as experimental group, control group and experimental group
Foliar spray.In pumpkin harvesting, to leaf portion fungal disease, the survey showed that: the powdery mildew of experimental group, anthracnose, epidemic disease,
The disease index of downy mildew is respectively 0%, 3%, 1% and 0%, and the disease index of control group CK1 is respectively 0%, 16%, 14% and 0%,
The disease index of control group CK2 is respectively 0%, 7%, 5% and 0%, and the blade of experimental group holds the green phase and relatively compares group leader.Therefore,
Plant protection agent of the present invention has preferably disease-controlling effect compared to the independent fungicide that sprays.
Similarly, it using embodiment 1 and the plant protection agent of the preparation of embodiment 2 as experimental group, shows more preferable than control group
Ground bactericidal effect and longer hold the green phase.
It should be noted that embodiment described above is interpreted as illustrative, to be not intended to limit the present invention protection
Range, protection scope of the present invention are subject to claims.To those skilled in the art, without departing substantially from of the invention real
Under the premise of matter and range, some nonessential modifications and adaptations made to the present invention still fall within protection scope of the present invention.
Claims (3)
1. a kind of pumpkin plant protection agent, it is characterised in that: the component and its quality volume fraction for including are respectively as follows: 0.05-0.2%'s
The poly- trialkylphosphine oxide copolymer of siloxanes, the nano silica of 0.01-1%, the chitosan of 0.8-1.0% and 0.01-0.1%
N- (2- benzimidazolyl) methyl carbamate.
2. a kind of pumpkin plant protection agent as described in claim 1, it is characterised in that: the component and its quality volume fraction for including point
Not are as follows: the poly- trialkylphosphine oxide copolymer of 0.1% siloxanes, 0.05% nano silica, 0.9% chitosan and 0.05%
N- (2- benzimidazolyl) methyl carbamate.
3. preparing a kind of method of pumpkin plant protection agent as claimed in claim 1 or 2, it is characterised in that: the following steps are included:
Step 1: weighing chitosan and N- (2- benzimidazolyl) methyl carbamate, dissolved respectively with acetic acid, it is poly- to obtain shell
Sugar juice and N- (2- benzimidazolyl) methyl carbamate solution；
Step 2: weighing nano silica and the poly- trialkylphosphine oxide copolymer of siloxanes；Weighed nano silica is added
Enter into ethylene glycol simultaneously stirring and dissolving, add the poly- trialkylphosphine oxide copolymer of weighed siloxanes, stirs, obtain suspension；
Step 3: by chitosan solution obtained by suspension obtained by step 2 and step 1 and N- (2- benzimidazolyl) carbamic acid
The stirring of distilled water constant volume is added in methyl ester solution mixing, prepares pumpkin leaf portion fungal disease prevention and treatment plant protection agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910026113.1A CN109757510A (en) | 2019-01-11 | 2019-01-11 | A kind of pumpkin plant protection agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910026113.1A CN109757510A (en) | 2019-01-11 | 2019-01-11 | A kind of pumpkin plant protection agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109757510A true CN109757510A (en) | 2019-05-17 |
Family
ID=66453945
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910026113.1A Pending CN109757510A (en) | 2019-01-11 | 2019-01-11 | A kind of pumpkin plant protection agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109757510A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1961668A (en) * | 2006-11-17 | 2007-05-16 | 杭州市农业科学研究院 | Seed initiator |
| CN101642099A (en) * | 2009-08-31 | 2010-02-10 | 桂林集琦生化有限公司 | Pesticide suspension concentrate with organosilicon surfactant and preparation method thereof |
-
2019
- 2019-01-11 CN CN201910026113.1A patent/CN109757510A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1961668A (en) * | 2006-11-17 | 2007-05-16 | 杭州市农业科学研究院 | Seed initiator |
| CN101642099A (en) * | 2009-08-31 | 2010-02-10 | 桂林集琦生化有限公司 | Pesticide suspension concentrate with organosilicon surfactant and preparation method thereof |
Non-Patent Citations (10)
| Title |
|---|
| VINOD KUMAR 等: "Effect of Some Fructoplane Antagonists and P ostharvest Dip Treatments on Litchi Fruit Rots and Shelf Life", 《NATIONAL ACADEMY OF AGRICULTURAL SCIENCE》 * |
| 于汉寿 等: "壳聚糖对油菜生长及油菜菌核病的影响", 《上海农业学报》 * |
| 初佳佳 等: "甲壳胺诱导辣椒抗辣椒疫病的研究", 《山东农业科学》 * |
| 赵冰: "甲壳素在保护地蔬菜上的应用 ", 《现代园艺》 * |
| 赵进成 等: "壳聚糖对8种植物病原真菌的抑制活性探讨", 《浙江农业学报》 * |
| 邢光耀: "甲壳素与杀菌剂互作对棉苗病害的防治试验 ", 《中国棉花》 * |
| 郭辉等: "二氧化硅纳米粒杀菌性能试验", 《浙江工业大学学报》 * |
| 钟一德: "叶用杀菌剂的辅助剂应用 ", 《世界农药》 * |
| 高亮 等: "壳聚糖对辣椒疫霉菌的抑制作用", 《中国植物病理学会2015年学术年会论文集》 * |
| 高亮: "壳聚糖对辣椒疫霉的抑制及转录组分析", 《山东农业大学硕士学位论文》 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101774852B (en) | Multifunctional composite seed coating agent | |
| CN1156213C (en) | Immersion type multifunctional rice seed coating agent | |
| CN106818839A (en) | A kind of corn seed coating agent and its application method | |
| CN104396974B (en) | Pesticide composition containing thifluzamide and chlorantraniliprole as well as application of pesticide composition | |
| CN104430357A (en) | Bactericide composition containing coumoxystrobin with synergistic effect | |
| CN114847282B (en) | Microcapsule suspending agent containing spinosad and preparation method thereof | |
| CN101530096A (en) | Sterilizing composition compounded by metalaxyl and teasaponin and application thereof | |
| CN107950580A (en) | Prevent the microbial bacterial agent of citrus Aleurocanthus spiniferus | |
| CN102396457B (en) | Pesticide composition containing tea saponin and amino oligosaccharin | |
| AU2021100104A4 (en) | Microcapsule suspension of pesticide and preparation method and use thereof | |
| CN109757510A (en) | A kind of pumpkin plant protection agent and preparation method thereof | |
| CN101543221B (en) | Mancozeb and tea saponin compounded sterilizing composition and application thereof | |
| CN110800739B (en) | Strawberry powdery mildew prevention and treatment medicament and preparation method and application thereof | |
| CN1726781A (en) | High-efficiency low-toxicity wheat seed coating agent | |
| CN101099469B (en) | Seed coating agent for preventing diseases and pests in cotton seedling and its preparation method | |
| CN114766517B (en) | Application of fructus viticis extract, pesticide and preparation method thereof | |
| CN101543219B (en) | Sterilizing composite compounded by diniconazole and tea saponin, preparation method and application thereof | |
| CN107743975A (en) | A kind of microcapsule suspension suspending agent containing Prochloraz and benziothiazolinone and preparation method thereof | |
| CN107372548A (en) | Composition pesticide containing captan and fluorine azoles ring bacterium amine and application thereof | |
| CN106818897A (en) | A kind of ultra low volume liquids for preventing and treating thrips and preparation method and application | |
| CN101444224B (en) | a compound insecticide | |
| CN105284815B (en) | A kind of composition pesticide containing pyraflufen-ethyl and pyrrole metsulfovax | |
| CN111955470A (en) | Inclusion compound for preventing and controlling pine cone pests, preparation method thereof and pesticide preparation | |
| CN103039492A (en) | Pesticide compound bactericide | |
| CN114946864B (en) | Synergistic bactericide containing cyprodinil, fludioxonil and terpineol and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190517 |
|
| RJ01 | Rejection of invention patent application after publication |