[go: up one dir, main page]

CN109749685A - A kind of glued board adhesive composition and its preparation process - Google Patents

A kind of glued board adhesive composition and its preparation process Download PDF

Info

Publication number
CN109749685A
CN109749685A CN201711092134.0A CN201711092134A CN109749685A CN 109749685 A CN109749685 A CN 109749685A CN 201711092134 A CN201711092134 A CN 201711092134A CN 109749685 A CN109749685 A CN 109749685A
Authority
CN
China
Prior art keywords
parts
adhesive composition
kilograms
glued board
acidity regulator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711092134.0A
Other languages
Chinese (zh)
Inventor
胡友莉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Danyang Yitong Safety Technology Service Co Ltd
Original Assignee
Danyang Yitong Safety Technology Service Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Danyang Yitong Safety Technology Service Co Ltd filed Critical Danyang Yitong Safety Technology Service Co Ltd
Priority to CN201711092134.0A priority Critical patent/CN109749685A/en
Publication of CN109749685A publication Critical patent/CN109749685A/en
Pending legal-status Critical Current

Links

Landscapes

  • Adhesives Or Adhesive Processes (AREA)

Abstract

The present invention relates to technical field of adhesive, especially a kind of glued board adhesive composition and its preparation process.Described adhesive composition is made of following substance by following mass fraction: 100~120 parts of water, 20~25 parts of polyvinyl alcohol, 20~25 parts of poly- isocyanide ester, 40~45 parts of paraffin, 100~120 parts of 42% urea liquid, 10~16 parts of bentonite, 10~20 parts of thickener, 10~15 parts of preservative, 0.3~0.6 part of antimildew disinfectant, the dosage of acidity regulator, the acidity regulator is so that the pH value of adhesive composition is 2~6.Beneficial effect is: plywood adhesive composition of the invention avoids making the noxious materials such as formaldehyde, benzene, toluene, it can satisfy the demand of green building material and top-grade furniture that people decorate for household, it is suitble to the needs of people, it is harmless, environmentally protective that totally nontoxic may be implemented using the wood-based plate that this product produces.And the curing time end of the adhesive composition, Acceptable life are long.

Description

A kind of glued board adhesive composition and its preparation process
Technical field
The present invention relates to technical field of adhesive, especially a kind of glued board adhesive composition and its preparation process.
Background technique
The adhesive of plywood production is still based on formaldehyde system adhesive at present, and wherein phenolic resin glue is chiefly used in producing Outdoor version type Ⅰ plywood, urea-formaldehyde resin adhesive is chiefly used in producing II class glued board of indoor type, due to the production of formaldehyde system adhesive bonding Product have free formaldehyde release in the production and use process, endanger the health of people, increasingly increase in consumer's environmental consciousness In the case where strong, formaldehyde system adhesive is especially bonded the production of the urea-formaldehyde resin adhesive of interior products by being increasingly stringenter Limitation.By improving to urea-formaldehyde resin adhesive production technology, or the product being bonded to it can using post-processing means appropriate The release of harmful formaldehyde gas is reduced, but this not only adds costs, and cannot thoroughly solve the problems, such as that free formaldehyde discharges.
Published in Journal of northeast Forestry university 2008-7 " the starch-based aqueous isocyanate wood adhesive of hot pressing type Develop " to describe in a text " be the timber gluing that primary raw material prepares that dosage is huge, comprehensive performance is high using annual cornstarch Agent ", but the preparation process of this adhesive is complicated, and production cost can not be greatly reduced.Patent No. 200410017054.5 In, describe it is a kind of using vegetable protein as based Wood Adhesives of primary raw material and preparation method thereof, but it is this formula and method system Standby based Wood Adhesives poor water resistance, there are the unstability of product quality in industrial production, and plate is required to produce Hot pressing temperature meter pressure is higher, and the board quality of production is difficult to ensure.
Summary of the invention
The technical problem to be solved by the present invention is overcome deficiency in the prior art, a kind of simple process, green ring are provided Guarantor, the glued board adhesive composition of water-tolerant and its manufacture craft.
In order to solve the above technical problems, The technical solution adopted by the invention is as follows:
A kind of glued board adhesive composition, described adhesive composition press following mass parts array by following substance At: 100~120 parts of water, 20~25 parts of polyvinyl alcohol, 20~25 parts of poly- isocyanide ester, 40~45 parts of paraffin, 42% urea is molten 100~120 parts of liquid, 10~16 parts of bentonite, 10~20 parts of thickener, 10~15 parts of preservative, antimildew disinfectant 0.3~0.6 Part, the dosage of acidity regulator, the acidity regulator is so that the pH value of adhesive composition is 2~6.
Further, the thickener is selected from: sodium alginate, seaweed propylene glycol ester, carragheen, gum arabic, carboxylic first At least one of base sodium cellulosate.
Further, the preservative is selected from: sorbic acid, potassium sorbate, sodium propionate, sodium hydrogensulfite, in sodium sulphate It is at least one.
Further, the antimildew disinfectant is antimildew disinfectant KL-303.
Further, the acidity regulator is selected from: a kind of in citric acid, acetic acid and lactic acid.
Further, the pH value of described adhesive composition is 3~5.
Further, described adhesive composition is made of following substance by following mass fraction: 110 parts of water, polyethylene 22 parts of alcohol, 23 parts of poly- isocyanide ester, 43 parts of paraffin, 110 parts of 42% urea liquid, 23 parts of bentonite, 15 parts of thickener, anti-corrosion 22 parts of agent, 0.4 part of antimildew disinfectant, the dosage of acidity regulator, the acidity regulator is the pH so that adhesive composition Value is 2~6.
A kind of method of glued board adhesive composition as described in claim 1 is prepared, the method includes following Step: 100~120 kilograms of water are added in a kettle, is heated to 45 DEG C, the side Bian Jiare is slowly added to polyvinyl alcohol 20~25,000 Gram, it is warming up to 95~100 DEG C and stops heating after polyvinyl alcohol all dissolution, keep the temperature 1.5h, be cooled to 65 DEG C of addition paraffin 40 ~45 kilograms, 100~120 kilograms of 42% urea liquid, 10~16 kilograms of bentonite, 10~20 kilograms of thickener, preservative 10~15 kilograms, 0.3~0.6 kilogram of antimildew disinfectant, after stirring 30min, 20~25 kilograms of poly- isocyanide ester is added, mixing is equal After even, acidity regulator is added, the pH value for adjusting adhesive composition is 2~6.
Be using the beneficial effect of technical solution of the present invention: plywood adhesive composition of the invention avoids making first The noxious materials such as aldehyde, benzene, toluene can satisfy the demand of green building material and top-grade furniture that people decorate for household, be suitble to It is harmless, environmentally protective that totally nontoxic may be implemented using the wood-based plate that this product produces in the needs of people.Moreover, the present invention exists No pollution to the environment in production process, and the curing time end of the adhesive composition, Acceptable life are long.
Specific embodiment
The present invention will be further described combined with specific embodiments below.
Embodiment 1
A kind of glued board adhesive composition, described adhesive composition are made of following substance by following mass number: 100 parts of water, 20 parts of polyvinyl alcohol, 20 parts of poly- isocyanide ester, 40 parts of paraffin, 100 parts of 42% urea liquid, 10 parts of bentonite, 10 parts of sodium alginate, 5 parts of sorbic acid, 5 parts of potassium sorbate, 0.3 part of antimildew disinfectant KL-303, adding citric acid adjusts adhesive The dosage of the acidity of composition, the citric acid is so that the pH value of adhesive composition is 2~3.
The method of above-mentioned adhesive composition is prepared the following steps are included: water double centner is added in a kettle, is heated to 45 DEG C, the side Bian Jiare is slowly added to 20 kilograms of polyvinyl alcohol, is warming up to 95~100 DEG C and stops adding after polyvinyl alcohol all dissolution Heat keeps the temperature 1.5h, is cooled to 40 kilograms of paraffin of 65 DEG C of additions, 42% urea liquid double centner, and 10 kilograms of bentonite, seaweed 10 kilograms of sour sodium, 5 kilograms of potassium sorbate, 0.3 kilogram of antimildew disinfectant KL-303, after stirring 30min, adds by 5 kilograms of sorbic acid Enter 20 kilograms of poly- isocyanide ester, after mixing, adding citric acid adjusts the acidity of adhesive composition, adjusts adhesive composition PH value be 2~3.
Embodiment 2
A kind of glued board adhesive composition, described adhesive composition press following mass parts array by following substance At: 110 parts of water, 22 parts of polyvinyl alcohol, 23 parts of poly- isocyanide ester, 43 parts of paraffin, 110 parts of 42% urea liquid, bentonite 23 Part, 7.5 parts of seaweed propylene glycol ester, 7.5 parts of carragheen, 22 parts of sodium propionate, 0.4 part of antimildew disinfectant KL-303, acetic acid is added to adjust The dosage of the acidity of adhesive composition, the acetic acid is so that the pH value of adhesive composition is 3~5.
The method of above-mentioned adhesive composition is prepared the following steps are included: 110 kilograms of water are added in a kettle, is heated to 45 DEG C, the side Bian Jiare is slowly added to 22 kilograms of polyvinyl alcohol, is warming up to 95~100 DEG C and stops adding after polyvinyl alcohol all dissolution Heat keeps the temperature 1.5h, is cooled to 43 kilograms of paraffin of 65 DEG C of additions, 110 kilograms of 42% urea liquid, and 23 kilograms of bentonite, seaweed 7.5 kilograms of propylene glycol ester, 7.5 kilograms of carragheen, 22 kilograms of sodium propionate, 0.4 kilogram of antimildew disinfectant KL-303, stir 30min Afterwards, 23 kilograms of poly- isocyanide ester is added, after mixing, acetic acid is added to adjust the acidity of adhesive composition, adjusts adhesive group The pH value for closing object is 3~5.
Embodiment 3
A kind of glued board adhesive composition, described adhesive composition press following mass parts array by following substance At: 120 parts of water, 25 parts of polyvinyl alcohol, 25 parts of poly- isocyanide ester, 45 parts of paraffin, 120 parts of 42% urea liquid, bentonite 16 Part, 10 parts of gum arabic, 10 parts of sodium carboxymethylcellulose, 7.5 parts of sodium hydrogensulfite, 7.5 parts of sodium sulphate, antimildew disinfectant 0.6 part of KL-303, the dosage of lactic acid, the lactic acid is so that the pH value of adhesive composition is 5~6.
The method of above-mentioned adhesive composition is prepared the following steps are included: 120 kilograms of water are added in a kettle, is heated to 45 DEG C, the side Bian Jiare is slowly added to 25 kilograms of polyvinyl alcohol, is warming up to 95~100 DEG C and stops adding after polyvinyl alcohol all dissolution Heat keeps the temperature 1.5h, is cooled to 45 kilograms of paraffin of 65 DEG C of additions, 120 kilograms of 42% urea liquid, and 16 kilograms of bentonite, I 10 kilograms of uncle's natural gum, 10 kilograms of sodium carboxymethylcellulose, 7.5 kilograms of sodium hydrogensulfite, 7.5 kilograms of sodium sulphate, antimildew disinfectant 0.6 kilogram of KL-303, after stirring 30min, 25 kilograms of poly- isocyanide ester is added, after mixing, lactic acid is added to adjust adhesive group The acidity for closing object, the pH value for adjusting adhesive composition is 5~6.
Although above-described embodiment is described in detail technical solution of the present invention, technical side of the invention Case is not limited to above embodiments, in the case where not departing from thought and objective of the invention, to technical solution of the present invention institute Any change done falls within claims of the present invention limited range.

Claims (8)

1. a kind of glued board adhesive composition, which is characterized in that described adhesive composition presses following matter by following substance Number is measured to form: 100~120 parts of water, 20~25 parts of polyvinyl alcohol, 20~25 parts of poly- isocyanide ester, 40~45 parts of paraffin, 42% 100~120 parts of urea liquid, 10~16 parts of bentonite, 10~20 parts of thickener, 10~15 parts of preservative, antimildew disinfectant 0.3~0.6 part, the dosage of acidity regulator, the acidity regulator is so that the pH value of adhesive composition is 2~6.
2. a kind of glued board adhesive composition according to claim 1, which is characterized in that the thickener is selected from: At least one of sodium alginate, seaweed propylene glycol ester, carragheen, gum arabic, sodium carboxymethylcellulose.
3. a kind of glued board adhesive composition according to claim 1, which is characterized in that the preservative is selected from: At least one of sorbic acid, potassium sorbate, sodium propionate, sodium hydrogensulfite, sodium sulphate.
4. a kind of glued board adhesive composition according to claim 1, which is characterized in that the antimildew disinfectant is Antimildew disinfectant KL-303.
5. a kind of glued board adhesive composition according to claim 1, which is characterized in that the acidity regulator choosing From: one kind in citric acid, acetic acid and lactic acid.
6. a kind of glued board adhesive composition according to claim 1, it is characterised in that: described adhesive composition PH value be 3~5.
7. a kind of glued board adhesive composition according to claim 1, which is characterized in that described adhesive composition It is made of following substance by following mass fraction: 110 parts of water, 22 parts of polyvinyl alcohol, 23 parts of poly- isocyanide ester, 43 parts of paraffin, 110 parts of 42% urea liquid, 10~16 parts of bentonite, 10~20 parts of thickener, 10~15 parts of preservative, antimildew disinfectant 0.3~0.6 part, the dosage of acidity regulator, the acidity regulator is so that the pH value of adhesive composition is 2~6.
8. preparing a kind of method of glued board adhesive composition as described in claim 1, which is characterized in that the method The following steps are included: 100~120 kilograms of water are added in a kettle, 45 DEG C are heated to, the side Bian Jiare is slowly added to polyvinyl alcohol It 20~25 kilograms, is warming up to 95~100 DEG C and stops heating after polyvinyl alcohol whole dissolution, keep the temperature 1.5h, be cooled to 65 DEG C and add Enter 40~45 kilograms of paraffin, 100~120 kilograms of 42% urea liquid, 10~16 kilograms of bentonite, thickener 10~20,000 Gram, 10~15 kilograms of preservative, 0.3~0.6 kilogram of antimildew disinfectant, after stirring 30min, poly- isocyanide ester 20~25,000 is added Gram, after mixing, acidity regulator is added, the pH value for adjusting adhesive composition is 2~6.
CN201711092134.0A 2017-11-08 2017-11-08 A kind of glued board adhesive composition and its preparation process Pending CN109749685A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711092134.0A CN109749685A (en) 2017-11-08 2017-11-08 A kind of glued board adhesive composition and its preparation process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711092134.0A CN109749685A (en) 2017-11-08 2017-11-08 A kind of glued board adhesive composition and its preparation process

Publications (1)

Publication Number Publication Date
CN109749685A true CN109749685A (en) 2019-05-14

Family

ID=66402045

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711092134.0A Pending CN109749685A (en) 2017-11-08 2017-11-08 A kind of glued board adhesive composition and its preparation process

Country Status (1)

Country Link
CN (1) CN109749685A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003093385A2 (en) * 2002-05-03 2003-11-13 Huntsman International Llc Lignocellulosic composites, adhesive systems, and process
CN1480502A (en) * 2002-09-04 2004-03-10 ϣ Adhesive and sealant layers for electrophoretic displays
CN1761730A (en) * 2003-01-21 2006-04-19 阿什兰许可和知识产权有限公司 Adhesive additives and adhesive compositions containing an adhesive additive
CN102504757A (en) * 2011-11-29 2012-06-20 南开大学 Biological environment-friendly adhesion agent and preparation method thereof
CN102516857A (en) * 2011-11-25 2012-06-27 东营市盛基环保工程有限公司 Formaldehyde-free cementing compound for profiled artificial board and preparation method thereof
CN103436198A (en) * 2013-08-20 2013-12-11 吴江市英力达塑料包装有限公司 Water-fast wood adhesive and preparation method thereof
CN104592911A (en) * 2015-02-09 2015-05-06 金思思 Adhesive composition for veneer sheets and preparation technique thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003093385A2 (en) * 2002-05-03 2003-11-13 Huntsman International Llc Lignocellulosic composites, adhesive systems, and process
CN1480502A (en) * 2002-09-04 2004-03-10 ϣ Adhesive and sealant layers for electrophoretic displays
CN1761730A (en) * 2003-01-21 2006-04-19 阿什兰许可和知识产权有限公司 Adhesive additives and adhesive compositions containing an adhesive additive
CN102516857A (en) * 2011-11-25 2012-06-27 东营市盛基环保工程有限公司 Formaldehyde-free cementing compound for profiled artificial board and preparation method thereof
CN102504757A (en) * 2011-11-29 2012-06-20 南开大学 Biological environment-friendly adhesion agent and preparation method thereof
CN103436198A (en) * 2013-08-20 2013-12-11 吴江市英力达塑料包装有限公司 Water-fast wood adhesive and preparation method thereof
CN104592911A (en) * 2015-02-09 2015-05-06 金思思 Adhesive composition for veneer sheets and preparation technique thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
蔡汉忠 等: "基于长白山丑冷杉胶合板强度的水性异氰酸酯胶黏剂配比", 《北华大学学报(自然科学版)》 *

Similar Documents

Publication Publication Date Title
CN102977844B (en) Modified vegetable protein adhesive and preparation method thereof
CN101412899B (en) Completely degradable plant protein wood adhesive and preparation thereof
CN103144178B (en) Production method of aldehyde-free bamboo floor
CN103122228B (en) Bio-oil starch adhesive for wood and preparation method
CN102719217A (en) Protein-based wood adhesive and preparation method thereof
CN103031095A (en) Adhesive for veneering of artificial board and preparation method of adhesive
CN101475790A (en) Novel timber adhesive and preparation thereof
CN104592911B (en) A kind of plywood adhesive composition and preparation technology thereof
CN103254842A (en) Modified starch wood adhesive, and preparation method and application thereof
CN103725253B (en) Wood-based plate with vinasse based reinforcement material and with its preparation vinasse base without aldehyde glue
CN103131360B (en) Bio-oil starch adhesive used for artificial board and preparation method
CN104861899A (en) Adhesive composition for plywood and preparation process of adhesive composition
CN102352199A (en) Composite adhesive for wood board veneering and blending process thereof
CN106318294A (en) Preparing method of pyrolytic tar resorcinol formaldehyde resin tackifier for use in timberwork building materials
CN109749685A (en) A kind of glued board adhesive composition and its preparation process
CN106753063B (en) The preparation method of water resistance wheat flour adhesive
CN103320082B (en) Plant-based polyester polyol adhesive, and preparation method and application thereof
CN102952470A (en) Environment-friendly adhesive and preparation method thereof
CN106079016A (en) A kind of artificial board containing powder of straw
CN103450841B (en) A kind of lac basic ring protects the preparation method of artificial board adhesive
CN100354386C (en) Biomass-base artifical plate wooden adhesive without formaldehyde indoor and production thereof
CN103101100A (en) Environment friendly recombination bamboo artificial board and manufacturing method thereof
CN102634298B (en) Biological oil-starch-glyoxal resin adhesive for artificial board and preparation method of biological oil-starch-glyoxal resin adhesive
CN101514279A (en) New type bonding agent and preparation method thereof
CN108795377B (en) A kind of preparation method of semi-solid bamboo liquid-protein hot-pressed board glue

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20190514

WD01 Invention patent application deemed withdrawn after publication