CN109735868A - A kind of electrolysis unit - Google Patents
A kind of electrolysis unit Download PDFInfo
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- CN109735868A CN109735868A CN201910107983.1A CN201910107983A CN109735868A CN 109735868 A CN109735868 A CN 109735868A CN 201910107983 A CN201910107983 A CN 201910107983A CN 109735868 A CN109735868 A CN 109735868A
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- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 64
- 230000005518 electrochemistry Effects 0.000 claims abstract description 662
- 108091006146 Channels Proteins 0.000 claims abstract description 260
- 230000005611 electricity Effects 0.000 claims abstract description 207
- 150000001875 compounds Chemical class 0.000 claims abstract description 117
- 239000003792 electrolyte Substances 0.000 claims abstract description 55
- 239000002245 particle Substances 0.000 claims description 114
- -1 dielectric Substances 0.000 claims description 70
- 239000003638 chemical reducing agent Substances 0.000 claims description 67
- 239000007800 oxidant agent Substances 0.000 claims description 67
- 230000001590 oxidative effect Effects 0.000 claims description 67
- 239000000126 substance Substances 0.000 claims description 50
- 239000007789 gas Substances 0.000 claims description 42
- 239000003990 capacitor Substances 0.000 claims description 41
- 238000009413 insulation Methods 0.000 claims description 37
- 239000002608 ionic liquid Substances 0.000 claims description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 28
- 238000002955 isolation Methods 0.000 claims description 28
- 239000001301 oxygen Substances 0.000 claims description 20
- 229910052760 oxygen Inorganic materials 0.000 claims description 20
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 19
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 14
- 239000001569 carbon dioxide Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 11
- 150000001335 aliphatic alkanes Chemical group 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 150000002431 hydrogen Chemical group 0.000 claims description 3
- 230000036962 time dependent Effects 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 description 35
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Abstract
The invention discloses a kind of electrolysis unit, including electrochemistry region, the electrochemistry region is connected to setting with compound feed channel, and the electrochemistry region includes the area alternating current Jie electricity, and the electrochemistry region is connected to setting with electrolysate export channel.Electrolysis unit disclosed in this invention will terminate traditional electrolyte device with the history for existing for necessary condition of electrolyte, and the exploitation for efficient, long-life, inexpensive electrolysis unit provides new approach.
Description
Technical field
The present invention relates to electricity field, electrochemical field more particularly to a kind of electrolysis units.
Background technique
Electrolysis unit is using very extensive, but all electrolysis units so far between electrode to transmit non-electronic band
Charged particle (such as proton, negative oxygen ion etc.) is necessary condition, mean that so all electrolysis units so far with
It the use of the electrolyte that non-electronic charged particle is connected is necessary condition, and the electrolyte that non-electronic charged particle is connected not only manufactures
It is difficult, using difficulty, and will be greatly reduced electrolytic efficiency.If can invent one kind does not exist for necessary item with electrolyte
The electrolysis unit of part will be of great significance.Therefore, it is necessary to invent a kind of novel electrolytic device.
Summary of the invention
To solve the above-mentioned problems, technical solution proposed by the present invention is as follows:
A kind of electrolysis unit of scheme 1., including electrochemistry region, the electrochemistry region are connected to compound feed channel
Setting, the electrochemistry region include the area alternating current Jie electricity, and the electrochemistry region is connected to electrolysate export channel and sets
It sets；
Or, the electrochemistry region is connected to setting with compound feed channel, the electrochemistry region includes alternating current
The area Jie electricity, the electrochemistry region are connected to setting with electrolysate export channel；The electrochemistry region and non-electronic band electrochondria
Sub- transmitter have non-electronic conducting electrical relation or the electrochemistry region successively with electronic conduction area and non-electronic band electrochondria
There is sub- transmitter non-electronic conducting electrical relation or the electrochemistry region and dielectric to close with non-electronic conducting electricity
System；
Or, the electrochemistry region is connected to setting with compound feed channel, the electrochemistry region includes alternating current
The area Jie electricity, the electrochemistry region are connected to setting with electrolysate export channel；The electrochemistry region and insulation, isolation sky
Between, in electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area at least
One kind having non-electronic conducting electrical relation.
A kind of electrolysis unit of scheme 2., including electrochemistry region and region B, the electrochemistry region and compound feed are logical
Road connection setting, the electrochemistry region includes alternating current Jie electricity area A, and the region B includes alternating current Jie electricity area B, institute
It states electrochemistry region and is connected to setting with electrolysate export channel；
Or, the electrochemistry region is connected to setting with compound feed channel, the electrochemistry region includes alternating current
The area Jie electricity A, the region B include alternating current Jie electricity area B, and the electrochemistry region is connected to electrolysate export channel and sets
It sets；The electrochemistry region has non-electronic conducting electrical relation or the electricity through non-electronic charged particle transmitter and region B
Chemical regions successively have non-electronic conducting electrical relation through electronic conduction area and non-electronic charged particle transmitter and region B,
Or the electrochemistry region has non-electronic conducting electrical relation through dielectric and region B；
Or, the electrochemistry region is connected to setting with compound feed channel, the electrochemistry region includes alternating current
The area Jie electricity A, the region B include alternating current Jie electricity area B, and the electrochemistry region is connected to electrolysate export channel and sets
It sets；The electrochemistry region is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ion
At least one of gas, solion and electronic conduction area have non-electronic conducting electrical relation with the region B.
A kind of electrolysis unit of scheme 3., including electrochemistry region A and electrochemistry region B, the electrochemistry region A and chemical combination
The connection setting of object feed channel, the electrochemistry region A includes alternating current Jie electricity area A, the electrochemistry region B and compound
The connection setting of feed channel, the electrochemistry region B includes alternating current Jie electricity area B, the electrochemistry region A and electrolysate
Channel connection setting is exported, the electrochemistry region B is connected to setting with electrolysate export channel；
Or, the electrochemistry region A is connected to setting with compound feed channel, the electrochemistry region A includes alternation electricity
The area Liu Jie electricity A, the electrochemistry region B are connected to setting with compound feed channel, and the electrochemistry region B includes alternating current
The area Jie electricity B, the electrochemistry region A are connected to setting with electrolysate export channel, and the electrochemistry region B is led with electrolysate
Channel connection setting out；The electrochemistry region A has non-electrical through non-electronic charged particle transmitter and the electrochemistry region B
Son conducting electrical relation or the electrochemistry region A successively through electronic conduction area and non-electronic charged particle transmitter with it is described
Electrochemistry region B has non-electronic conducting electrical relation or the electrochemistry region A through dielectric and the electrochemistry region B
With non-electronic conducting electrical relation；
Or, the electrochemistry region A is connected to setting with compound feed channel, the electrochemistry region A includes alternation electricity
The area Liu Jie electricity A, the electrochemistry region B are connected to setting with compound feed channel, and the electrochemistry region B includes alternating current
The area Jie electricity B, the electrochemistry region A are connected to setting with electrolysate export channel, and the electrochemistry region B is led with electrolysate
Channel connection setting out；The electrochemistry region A through insulation, isolation space, electrolyte, dielectric, capacitor, plasma,
At least one of ionic liquid, ionized gas, solion and electronic conduction area have non-electronic with the electrochemistry region B
Electrical relation is connected.
A kind of electrolysis unit of scheme 4., including electrochemistry region A and electrochemistry region B, the electrochemistry region A and described
Electrochemistry region B is connected to setting with compound feed channel, and the electrochemistry region A includes alternating current Jie electricity area A, the electricity
Chemical regions B includes alternating current Jie electricity area B, and the electrochemistry region A is connected to setting, the electricity with electrolysate export channel
Chemical regions B is connected to setting with electrolysate export channel；
Or, the electrochemistry region A and the electrochemistry region B are connected to setting, the electrification with compound feed channel
School district domain A includes alternating current Jie electricity area A, and the electrochemistry region B includes alternating current Jie electricity area B, the electrochemistry region A
It is connected to setting with electrolysate export channel, the electrochemistry region B is connected to setting with electrolysate export channel；The electrification
School district domain A has non-electronic conducting electrical relation or the electricity through non-electronic charged particle transmitter and the electrochemistry region B
Chemical regions A successively has non-electronic lead with the electrochemistry region B through electronic conduction area and non-electronic charged particle transmitter
Leading to electrical relation or the electrochemistry region A has non-electronic conducting electrical relation through dielectric and the electrochemistry region B；
Or, the electrochemistry region A and the electrochemistry region B are connected to setting, the electrification with compound feed channel
School district domain A includes alternating current Jie electricity area A, and the electrochemistry region B includes alternating current Jie electricity area B, the electrochemistry region A
It is connected to setting with electrolysate export channel, the electrochemistry region B is connected to setting with electrolysate export channel；The electrification
School district domain A is molten through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, ion
At least one of liquid and electronic conduction area have non-electronic conducting electrical relation with the electrochemistry region B.
A kind of electrolysis unit of scheme 5., including electrochemistry region A and electrochemistry region B, the electrochemistry region A and described
Electrochemistry region B is connected to setting with compound feed channel, and the electrochemistry region A includes alternating current Jie electricity area A, the electricity
Chemical regions B includes that alternating current Jie electricity area B, the electrochemistry region A and the electrochemistry region B and electrolysate export are logical
Road connection setting；
Or, the electrochemistry region A and the electrochemistry region B are connected to setting, the electrification with compound feed channel
School district domain A includes alternating current Jie electricity area A, and the electrochemistry region B includes alternating current Jie electricity area B, the electrochemistry region A
Setting is connected to the electrochemistry region B with electrolysate export channel；The electrochemistry region A is passed through non-electronic charged particle
Leading object and the electrochemistry region B has non-electronic conducting electrical relation or the electrochemistry region A successively through electronic conduction area
There is non-electronic conducting electrical relation or the electrochemical school district with non-electronic charged particle transmitter and the electrochemistry region B
Domain A has non-electronic conducting electrical relation through dielectric and the electrochemistry region B；
Or, the electrochemistry region A and the electrochemistry region B are connected to setting, the electrification with compound feed channel
School district domain A includes alternating current Jie electricity area A, and the electrochemistry region B includes alternating current Jie electricity area B, the electrochemistry region A
Setting is connected to the electrochemistry region B with electrolysate export channel；The electrochemistry region A through insulation, isolation space,
At least one in electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
Kind has non-electronic conducting electrical relation with the electrochemistry region B.
A kind of electrolysis unit of scheme 6., including electrochemistry region, the electrochemistry region are arranged in the cavity, the cavity
Setting is connected to compound feed channel, the electrochemistry region includes the area alternating current Jie electricity, the cavity and electrolysate
Export channel connection setting；
Or, the electrochemistry region setting is in the cavity, the cavity is connected to setting, the electricity with compound feed channel
Chemical regions include the area alternating current Jie electricity, and the cavity is connected to setting with electrolysate export channel；The electrochemistry region
With non-electronic charged particle transmitter have non-electronic conducting electrical relation or the electrochemistry region successively with electronic conduction area
With non-electronic charged particle transmitter there is non-electronic conducting electrical relation or the electrochemistry region and dielectric to have non-electrical
Son conducting electrical relation；
Or, the electrochemistry region setting is in the cavity, the cavity is connected to setting, the electricity with compound feed channel
Chemical regions include the area alternating current Jie electricity, and the cavity is connected to setting with electrolysate export channel；The electrochemistry region
With insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electricity
At least one of son conducting area has non-electronic conducting electrical relation.
A kind of electrolysis unit of scheme 7., including electrochemistry region and region B, the electrochemistry region are arranged in the cavity,
The cavity is connected to setting with compound feed channel, and the electrochemistry region includes alternating current Jie electricity area A, the region B
Including alternating current Jie electricity area B, the cavity is connected to setting with electrolysate export channel；
Or, the electrochemistry region setting is in the cavity, the cavity is connected to setting, the electricity with compound feed channel
Chemical regions include alternating current Jie electricity area A, and the region B includes alternating current Jie electricity area B, and the cavity is led with electrolysate
Channel connection setting out；The electrochemistry region has non-electronic conducting electricity through non-electronic charged particle transmitter and region B
Relationship or the electrochemistry region successively have through electronic conduction area and non-electronic charged particle transmitter with region B non-electronic
Electrical relation or the electrochemistry region, which is connected, has non-electronic conducting electrical relation through dielectric and region B；
Or, the electrochemistry region setting is in the cavity, the cavity is connected to setting, the electricity with compound feed channel
Chemical regions include alternating current Jie electricity area A, and the region B includes alternating current Jie electricity area B, and the cavity is led with electrolysate
Channel connection setting out；The electrochemistry region through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, from
At least one of sub- liquid, ionized gas, solion and electronic conduction area have non-electronic conducting electricity with the region B
Relationship.
A kind of electrolysis unit of scheme 8., including electrochemistry region A and electrochemistry region B, the electrochemistry region A setting exist
In cavity A, the cavity A is connected to setting with compound feed channel, and the electrochemistry region A includes alternating current Jie electricity area A,
The electrochemistry region B is arranged in cavity B, and the cavity B is connected to setting, the electrochemistry region with compound feed channel
B includes alternating current Jie electricity area B, and the cavity A is connected to setting, the cavity B and electrolysate with electrolysate export channel
Export channel connection setting；
Or, the electrochemistry region A is arranged in cavity A, the cavity A is connected to setting, institute with compound feed channel
Stating electrochemistry region A includes alternating current Jie electricity area A, and the electrochemistry region B is arranged in cavity B, the cavity B and chemical combination
The connection setting of object feed channel, the electrochemistry region B include alternating current Jie electricity area B, and the cavity A and electrolysate export
Channel connection setting, the cavity B are connected to setting with electrolysate export channel；The electrochemistry region A is through non-electronic electrification
Particle conduction object and the electrochemistry region B have non-electronic conducting electrical relation or the electrochemistry region A successively through electronics
Area and non-electronic charged particle transmitter and the electrochemistry region B, which is connected, has non-electronic conducting electrical relation or the electricity
Chemical regions A has non-electronic conducting electrical relation through dielectric and the electrochemistry region B；
Or, the electrochemistry region A is arranged in cavity A, the cavity A is connected to setting, institute with compound feed channel
Stating electrochemistry region A includes alternating current Jie electricity area A, and the electrochemistry region B is arranged in cavity B, the cavity B and chemical combination
The connection setting of object feed channel, the electrochemistry region B include alternating current Jie electricity area B, and the cavity A and electrolysate export
Channel connection setting, the cavity B are connected to setting with electrolysate export channel；The electrochemistry region A is through insulation, isolation
In space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area extremely
A kind of few and electrochemistry region B has non-electronic conducting electrical relation.
A kind of electrolysis unit of scheme 9., including electrochemistry region A and electrochemistry region B, the electrochemistry region A setting exist
In cavity A, the electrochemistry region B is arranged in cavity B, and the cavity A and the cavity B are connected to compound feed channel
Setting, the electrochemistry region A includes alternating current Jie electricity area A, and the electrochemistry region B includes alternating current Jie electricity area B, institute
It states cavity A and is connected to setting with electrolysate export channel, the cavity B is connected to setting with electrolysate export channel；
Or, the electrochemistry region A is arranged in cavity A, the electrochemistry region B is arranged in cavity B, the cavity
The A and cavity B is connected to setting with compound feed channel, and the electrochemistry region A includes alternating current Jie electricity area A, described
Electrochemistry region B includes alternating current Jie electricity area B, and the cavity A is connected to setting, the cavity B with electrolysate export channel
Setting is connected to electrolysate export channel；The electrochemistry region A is through non-electronic charged particle transmitter and the electrochemistry
Region B has non-electronic conducting electrical relation or the electrochemistry region A successively through electronic conduction area and non-electronic charged particle
Transmitter and the electrochemistry region B have non-electronic conducting electrical relation or the electrochemistry region A through dielectric with it is described
Electrochemistry region B has non-electronic conducting electrical relation；
Or, the electrochemistry region A is arranged in cavity A, the electrochemistry region B is arranged in cavity B, the cavity
The A and cavity B is connected to setting with compound feed channel, and the electrochemistry region A includes alternating current Jie electricity area A, described
Electrochemistry region B includes alternating current Jie electricity area B, and the cavity A is connected to setting, the cavity B with electrolysate export channel
Setting is connected to electrolysate export channel；The electrochemistry region A is through insulation, isolation space, electrolyte, dielectric, electricity
At least one of appearance, plasma, ionic liquid, ionized gas, solion and electronic conduction area and the electrochemical school district
Domain B has non-electronic conducting electrical relation.
A kind of electrolysis unit of scheme 10., including electrochemistry region A and electrochemistry region B, the electrochemistry region A setting
In cavity A, the electrochemistry region B is arranged in cavity B, and the cavity A and the cavity B and compound feed channel connect
Logical setting, the electrochemistry region A includes alternating current Jie electricity area A, and the electrochemistry region B includes alternating current Jie electricity area B,
The cavity A and cavity B is connected to setting with electrolysate export channel；
Or, the electrochemistry region A is arranged in cavity A, the electrochemistry region B is arranged in cavity B, the cavity
The A and cavity B is connected to setting with compound feed channel, and the electrochemistry region A includes alternating current Jie electricity area A, described
Electrochemistry region B, which includes alternating current Jie electricity area B, the cavity A and the cavity B, to be connected to electrolysate export channel and sets
It sets；The electrochemistry region A is closed through non-electronic charged particle transmitter and the electrochemistry region B with non-electronic conducting electricity
System or the electrochemistry region A successively have through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B
There are non-electronic conducting electrical relation or the electrochemistry region A that there is non-electronic conducting through dielectric and the electrochemistry region B
Electrical relation；
Or, the electrochemistry region A is arranged in cavity A, the electrochemistry region B is arranged in cavity B, the cavity
The A and cavity B is connected to setting with compound feed channel, and the electrochemistry region A includes alternating current Jie electricity area A, described
Electrochemistry region B, which includes alternating current Jie electricity area B, the cavity A and the cavity B, to be connected to electrolysate export channel and sets
It sets；The electrochemistry region A is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ion
At least one of gas, solion and electronic conduction area have non-electronic conducting electrical relation with the electrochemistry region B.
A kind of electrolysis unit of scheme 11., including electrochemistry region A and electrochemistry region B, the electrochemistry region A and institute
State electrochemistry region B setting in the cavity, the cavity is connected to setting, the electrochemistry region A packet with compound feed channel
Alternating current Jie electricity area A is included, the electrochemistry region B includes alternating current Jie electricity area B, and the cavity and electrolysate export are logical
Road connection setting；
Or, the electrochemistry region A and electrochemistry region B setting is in the cavity, the cavity and compound feed
Channel connection setting, the electrochemistry region A includes alternating current Jie electricity area A, and the electrochemistry region B includes that alternating current connects
Electric area B, the cavity are connected to setting with electrolysate export channel；The electrochemistry region A is conducted through non-electronic charged particle
Object and the electrochemistry region B have non-electronic conducting electrical relation or the electrochemistry region A successively through electronic conduction area and
Non-electronic charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation or the electrochemistry region A
There is non-electronic conducting electrical relation through dielectric and the electrochemistry region B；
Or, the electrochemistry region A and electrochemistry region B setting is in the cavity, the cavity and compound feed
Channel connection setting, the electrochemistry region A includes alternating current Jie electricity area A, and the electrochemistry region B includes that alternating current connects
Electric area B, the cavity are connected to setting with electrolysate export channel；The electrochemistry region A is through insulation, isolation space, electricity
At least one of Xie Zhi, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
There is non-electronic conducting electrical relation with the electrochemistry region B.
The compound on the basis of either a program, is further selectively set as mixed in scheme 1 to 11 by scheme 12.
Close the compound in object；Or, the compound is set as water, the reducing agent is hydrogen, and the oxidant is oxygen；Or, described
Compound is set as water, and water participates in reacting jointly with carbon dioxide, and the reducing agent is alcohol compound, and the oxidant is oxygen
Gas；Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide, and the reducing agent is ether compound, described
Oxidant is oxygen；Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide, and the reducing agent is alkane
Class compound, the oxidant are oxygen；Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide, described
Reducing agent is alkenes compounds, and the oxidant is oxygen；Or, the compound is set as water, and water and carbon dioxide are common
Reaction is participated in, the reducing agent is alkynes compound, and the oxidant is oxygen.
Scheme 13. on the basis of either a program, is further selectively arranged the electrolysate and leads in scheme 1 to 12
Channel includes reducing agent export channel and oxidant export channel out；
Or, electrolysate export channel includes reducing agent export channel and oxidant export channel, in the reduction
Agent exports setting reducing agent on channel and switchs, and setting oxidant switchs on oxidant export channel, and the reducing agent is opened
It closes and oxidant switch is controlled by control device and alternately opened and closed；
Or, electrolysate export channel includes reducing agent export channel and oxidant export channel, in the reduction
Agent exports setting reducing agent on channel and switchs, and setting oxidant switchs on oxidant export channel, and the reducing agent is opened
It closes and oxidant switch is controlled by control device and alternately opened and closed, the reducing agent switch and oxidant switch
The frequency and phase alternately opened and closed matches with the frequency of alternating current and phase applied to the area alternating current Jie electricity；
Or, electrolysate export channel is set as the molar mixture export channel of Oxidizing and Reducing Agents.
It, can be into the above-mentioned all schemes including the electrochemistry region of the present invention of scheme 14. on the basis of either a program
Selectively the electrochemistry area rotation is arranged for one step.
Appoint in the 15. above-mentioned all schemes including the electrochemistry region A and electrochemistry region B of the present invention of scheme
On the basis of one scheme, further selectively the electrochemistry region A can be rotated and be arranged, the electrochemistry region B rotation
Setting.
In the present invention, there is non-electronic electric conduction through electronic conduction area and the region B including the electrochemistry region
In the scheme of relationship, be selectively chosen make one in the electrochemistry region and the region B through capacitor or through non-
Electronic conduction area (such as the electrolyte such as proton exchange membrane) is again through external circuit and another electric communication, it is possible to realize normality
Work.
It is non-electronic having including the electrochemistry region A through electronic conduction area and the electrochemistry region B in the present invention
In the scheme that electrical relation is connected, it is selectively chosen one made in the electrochemistry region A and the electrochemistry region B
Through capacitor or through non-electronic conducting Qu Zaijing external circuit and another electric communication, it is possible to realize that normality works.
In the present invention, so that charged particle is stored in the means in electrochemistry region as realizing, be selectively chosen and pass through
Make electrochemistry region and participates in two kinds of metabolies contact of electrochemical reaction and the alternating of electric current changes to realize, it can also be with
Selectively selection contacts the two kinds of substances and the electrochemistry region that participate in electrochemical reaction alternately and the variation of the alternating of electric current
It realizes, however two electrodes of electrochemical reaction are (for example, the electrochemistry region and electric conductor, the electrochemistry region A and institute
State electrochemistry region B, the electrochemistry region and the region B) between the conducting of non-electronic charged particle then may exist
It can also be not present.
In the present invention, charged particle is set to be stored in the means in electrochemistry region as realizing, being selectively chosen makes electricity
The mixture contact of two kinds of substances of chemical regions and participation electrochemical reaction and the alternating of electric current change to realize, may be selected
Property select to make electrochemistry region and participate in the mixture makes discontinuous contact of two kinds of substances of electrochemical reaction and the alternating of electric current
Variation is to realize, however the conducting of the non-electronic charged particle between two electrodes of electrochemical reaction then may or may not
In the presence of.
The electrolysis unit disclosed in this invention is corresponding with alternating electromotive force and alternating current, i.e., electrochemistry region with
Alternating electromotive force and alternating current are corresponding.
In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen through non-electronic
Relationship is connected in the direct electricity that charged particle is formed, and relationship, warp is connected in the electricity formed through non-electronic charged particle reciprocating vibration
One of electricity conducting relationship that capacitance relation is formed, secondly conjunction or thirdly conjunction.
In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen including through exhausted
The electrical relation that alternating current can be made to be connected of edge body, dielectric and the conducting body isolation of non-electronic charged particle.
In the present invention, in two electrodes (for example, the electrochemistry region and electric conductor, the electrochemistry region A and the electricity
Chemical regions B, the electrochemistry region and the region B) between there are in the scheme of electrolyte, non-electronic charged particle can both be worn
More electrolyte reaches another electrode from an electrode, can also realize the work that alternating current is connected by reciprocating vibration in the electrolyte
With.
In the present invention, electrochemistry region corresponding with alternating electromotive force and alternating current is essence feature of the invention,
This feature eliminates the necessity of charged particle non-electronic between two electrodes transmission, thus no matter make between two electrodes in electronics every
Exhausted state, non-electronic charged particle state of isolation have the state for the electrolyte that non-electronic charged particle is connected between two electrodes, also
It is that can be worked normally in other states as long as can be realized the Oscillating flow of electronics.There are electrolyte between two electrodes
In scheme, non-electronic charged particle can both pass through electrolyte, reach another electrode from an electrode, can also be past in the electrolyte
Complex oscillation realizes the effect of alternating current conducting.This provides brand-new method for the manufacture and use of novel electrolytic device.
In the present invention, the alternation of electric current and substance replace and the effect of the alternation and substance of electric current is formed by alternation work
It is a kind of lasting course of work as process, is a kind of work normality, and its purpose is to eliminate non-electronic charged particle
In the necessity of two interelectrode transmitting, to promote the science of electrolysis unit, and then promoted and scheme disclosed in this invention
Service life, reliability, low cost and the efficiency of corresponding electrolysis unit.The principle and purpose and tradition of this electrolysis unit are fired
The purpose of material battery is catalyst regeneration temporary exchange Oxidizing and Reducing Agents feed channel forms temporary polarity of electrode and becomes
The principle and purpose of change has essential distinction, also and to prevent, weaken and the frequently pole-reversing electroosmosis of clearing electrode attachment
Principle and purpose have essential distinction.
In the present invention, it is formed by that the capacitance the big more to be conducive to electrolysis anti-between the electrochemistry region and the region B
Answer the promotion of density, therefore when carrying out cell reaction using scheme disclosed in this invention, should make the electrochemistry region and
Capacitance between the region B increases as much as possible.
It, can be in the electrochemical school district in order to increase the capacitance between the electrochemistry region and the region B in the present invention
Plasma, ionic liquid, ionized gas or solion are set between domain and the region B, and make ion in the electrification
It is vibrated between school district domain and the region B, and/or vibrates in the electrochemistry areas adjacent and oscillated around in the region B,
To realize the purpose for increasing the capacitance between the electrochemistry region and the region B.
In the present invention, it is more big more be conducive to electricity that the electrochemistry region A and the electrochemistry region B are formed by capacitance
The promotion of reaction density is solved, therefore when carrying out cell reaction using scheme disclosed in this invention, the electrochemical school district should be made
Capacitance between domain A and the electrochemistry region B increases as much as possible.
It, can be described in order to increase the capacitance between the electrochemistry region A and the electrochemistry region B in the present invention
Plasma, ionic liquid, ionized gas or solion are set between electrochemistry region A and the electrochemistry region B, and made
Ion vibrates between the electrochemistry region A and the electrochemistry region B, and/or oscillates around in the electrochemistry region A
And oscillated around in the electrochemistry region B, to realize the electricity between increasing the electrochemistry region A and electrochemistry region B
The purpose of capacity.
In the present invention, between the electrochemistry region and the region B and in the electrochemistry region A and the electrification
It is more big more be conducive to the promotion of electrochemical reaction density that capacitance is formed by between the B of school district domain, therefore public using present invention institute
When the scheme opened is electrochemically reacted, should make between the electrochemistry region and the region B and the electrochemistry region A and
Capacitance between the electrochemistry region B increases as much as possible.
Electrolysis unit disclosed in this invention, it is negative there are electrolyte can be reduced in the case where electrolyte between two electrodes
Lotus extends its service life and is conducive to the balance and stability operation of system.
In the present invention, reducing agent and oxidant is can be generated under electro ultrafiltration in the compound.
In the present invention, reducing agent and oxidant is can be generated through electro ultrafiltration in other materials presence in the compound.
In the present invention, the reducing agent is the substance for having reproducibility for the oxidant.
In the present invention, the oxidant is the substance for having oxidisability for the reducing agent.
In the present invention, electrochemistry region alternative selects one of the electrode for being set as electrochemical reaction or electrode
Point, the region B alternative selection is set as the electrode of electrochemical reaction or a part of electrode, and the electrochemistry region A can
Selectivity selection is set as the electrode of electrochemical reaction or a part of electrode, and the electrochemistry region B alternative selection is set as
The electrode of electrochemical reaction or a part of electrode.
In the present invention, the electrochemistry region, which is selectively chosen, is set as three-diemsnional electrode.
In the present invention, the electrochemistry region A, which is selectively chosen, is set as three-diemsnional electrode.
In the present invention, the electrochemistry region B, which is selectively chosen, is set as three-diemsnional electrode.
In the present invention, such as refer to J feed channel for J and K as synonym, J feed channel and the setting of K regional connectivity
Interior substance can contact the structural relation of setting with the region K.
In the present invention, such as using J and K as synonym, the region K is arranged in the cavity, and J feed channel is connected to the cavity
The structural relation for referring to that the substance in J feed channel can contact setting with the region K is set.
In the present invention, such as there is non-electronic conducting electrical relation using Y and X as synonym, Y and X, the electronics of the Y is led
The form of presentation imported out refers to that the Y, the X and electronics export import the composition that circuit three is same closed circuit
Part is selectively chosen electronics export importing circuit being set as external circuit, and non-electronic conducting electrical relation is formed
Circuit be set as interior circuit.
In the present invention, such as using U, W and V as synonym, U has non-electronic conducting electrical relation through W and V, and electronics is in institute
The form of presentation for exporting importing between U and the V is stated, refers to that the U, the W, the V and electronics export import circuit
It is the component part of same closed circuit, is selectively chosen and electronics export importing circuit is set as external circuit, and will be non-
Electronic conduction electrical relation is formed by circuit and is set as interior circuit.
In the present invention, the area Jie electricity that so-called " area alternating current Jie electricity " refers to alternating current is selectively chosen and sets
For a part of relative subject, also alternative selection is set as the conduction region contacted with relative subject, it is also an option that property select
Select the conduction region for being set as that there is capacitance relation with relative subject.So-called relative subject be exactly A include the area alternating current Jie electricity this
A in kind description.
In the present invention, so-called " alternating electromotive force " refers to that the changed electromotive force of electromotive force, such as direction become
The changed electromotive force of electromotive force or size of change.
In the present invention, so-called " alternating current " refers to the changed electric current of electric current, such as the changed electricity in direction
Stream, the changed electric current of size or alternating current.
In the present invention, so-called " alternating current " is selectively chosen the electric current for being set as the variation of electric current generating period,
Such as electric current or alternating current that electric current, the size generating period of direction generating period variation change.
In the present invention, so-called alternating current refers to the alternating current changed by sinusoidal rule.
In the present invention, so-called AC power source refers to the alternating source that electric current is changed by sinusoidal rule.
In the present invention, there is so-called A and B non-electronic conducting electrical relation to refer to having on interior circuit between A and B
Non-electronic conducting electrical relation, and its external circuit is selectively chosen electronic conduction relationship；Or, so-called A and B has non-electrical
Son conducting electrical relation, which refers to, has non-electronic conducting electrical relation on external circuit between A and B, and its interior circuit may be selected
Select electronic conduction relationship to property.
In the present invention, it is so-called " the electrochemistry region through insulation, isolation space, electrolyte, dielectric, capacitor, etc.
At least one of gas ions, ionic liquid, ionized gas, solion and electronic conduction area have non-electrical with the region B
Son conducting electrical relation " include the electrochemistry region and the region B through electronic conduction area, insulator, dielectric and/or from
The non-electronic conducting electrical relation that two solion ponds of son conducting body isolation have.In this device, optionally select
Selecting makes at least one in the electrochemistry region and the region B and capacitive region and/or non-electronic charged particle transmitter shape
At electrical relation.
In the present invention, it is so-called " the electrochemistry region A through insulation, isolation space, electrolyte, dielectric, capacitor,
At least one of plasma, ionic liquid, ionized gas, solion and electronic conduction area and the electrochemistry region B
With non-electronic conducting electrical relation " it include the electrochemistry region A and the electrochemistry region B through electronic conduction area, insulation
The non-electronic conducting electrical relation that two solion ponds of body, dielectric and/or ion conducting body isolation have.In this device
In, be selectively chosen make at least one in the electrochemistry region A and the electrochemistry region B with capacitive region and/or
Non-electronic charged particle transmitter forms electrical relation.
In the present invention, so-called " electronic conduction area " refers to that conduct electrons are not turned on the region of non-electronic charged particle, can
Selectively selection is set as metallic conductor area, carbon conductor region etc..
In the present invention, so-called " non-electronic charged particle transmitter " refer to non-conducting electronics but proton conducting or it is specific from
The substance of son, i.e. electrolyte in conventional electrochemical device, can be according to the electrochemical properties of the reducing agent and the oxidant
Non-electronic charged particle transmitter is selected, such as when the reducing agent is H2, the oxidant is O2When, the non-electronic electrification
Particle conduction object alternative selects proton exchange membrane.
In the present invention, select electronic conduction area shape when, should for the purpose of increasing its capacitance with neighbors into
Row selection.
In this present invention, so-called " non-electronic conducting electrical relation " refers to the electricity formed through the charged particle other than electronics
Conducting relationship is learned or the electricity to be formed conducting relationship of standing facing each other through electronics, for example, relationship, non-electronic band is connected in the electricity that capacitor is formed
The electricity conducting relationship etc. that charged particle reciprocating vibration is formed.
In the present invention, so-called electrochemistry region, so-called region B, so-called electrochemistry region A, so-called electrochemistry
Region B is equal with electrode.
In the present invention, the region that electronics export imports is equal with electrode.
It in the present invention, is selectively chosen, there is dielectric capacitance relationship between electrode.
In the present invention, it is selectively chosen, the electrochemistry region and the region B have dielectric capacitance relationship,
Dielectric can be gas, liquid, solid or vacuum.
It in the present invention, is selectively chosen, the electrochemistry region A and the electrochemistry region B have dielectric capacitance
Relationship, dielectric can be gas, liquid, solid or vacuum.
In the present invention, so-called dielectric capacitance relationship refers to the capacitance relation through dielectric formation, and dielectric can be
Gas, liquid, solid or vacuum.
In the present invention, so-called " capacitor " be selectively chosen be set as electrolytic capacitor, super capacitor, electric double layer capacitance,
All capacitors such as pseudo capacitance, fake capacitance.
The present invention in specific implementation, is selectively chosen using the electrochemistry region as an electrode, will be conductive
Body is completed the conversion of chemical energy electric energy, is selectively chosen an electricity as another electrode, two electrode cooperatings
Chemical regions are as an electrode, and using another described electrochemistry region as another electrode, two electrode cooperatings are completed
The conversion of chemical energy electric energy.
In the present invention, so that charged particle is stored in the means in electrochemistry region as realizing, be selectively chosen and pass through
The alternating of the contact of two kinds of metabolies and electric current that make electrochemistry region and participation electrochemical reaction changes to realize, also optional
Select to selecting property to make that two kinds of substances for participating in electrochemical reaction alternately contacts with electrochemistry region and the alternating of electric current changes
It realizes, however two electrodes of electrochemical reaction are (for example, the electrochemistry region and electric conductor, the electrochemistry region A and described
Electrochemistry region B, the electrochemistry region and the region B) between the conducting of non-electronic charged particle then may exist
It can be not present.
In the present invention, charged particle is set to be stored in the means in electrochemistry region as realizing, being selectively chosen makes electricity
The mixture contact of two kinds of substances of chemical regions and participation electrochemical reaction and the alternating of electric current change to realize, may be selected
Property select to make electrochemistry region and participate in the mixture makes discontinuous contact of two kinds of substances of electrochemical reaction and the alternating of electric current
Variation is to realize, however two electrodes of electrochemical reaction are (for example, the electrochemistry region and electric conductor, the electrochemistry region A
And the electrochemistry region B, the electrochemistry region and the region B) between the conducting of non-electronic charged particle then can be with
In the presence of can also be not present.
In the present invention, so-called " electrolyte " refer to all be arranged between two electrode of electrochemical appliance only allow it is specific
The substance that charged particle passes through but electronics is not allowed to pass through can be solid, liquid or membranous body etc., such as the proton of PEMFC
Film and solid oxide electrolyte etc..
In the present invention, so-called " electrochemistry region " refers to that the region of electrochemical reaction can occurs in all, for example including
Catalyst, ultra microstructure and/or region (such as electrode in fuel cell etc.) at a set temperature, then for example in setting temperature
Metallic region under degree.
It is so-called to refer to " including catalyst, ultra microstructure and/or electrochemistry region at a set temperature " in the present invention
The electrochemistry region or including catalyst or including ultra microstructure or under the set temperature or the electrification
School district domain includes two or three in these three conditions.
In the present invention, so-called " ultra microstructure " refers to the microcosmic knot that can cause electrochemical reaction under setting condition
Structure.
In the present invention, so-called " explosion limit " refers under conditions of the electrochemistry region, the reducing agent and institute
State the concentration ratio that oxidant cannot explode.
In the present invention, include the catalyst scheme in, the catalyst be set as include noble metal catalyst, or
The catalyst be set as include rare earth element catalyst.
In the present invention, so-called " non-electronic charged particle " refers to the charged particle other than electronics, such as proton or ion.
In the present invention, there is non-electronic electric conduction through electronic conduction area and the region B including the electrochemistry region
In the scheme of relationship, one in the electrochemistry region and the region B passes through outside again through capacitor or through non-electronic conducting area
Circuit and another electric communication, it is possible to realize that normality works.
It is non-electronic having including the electrochemistry region A through electronic conduction area and the electrochemistry region B in the present invention
In the scheme that electrical relation is connected, one in the electrochemistry region A and the electrochemistry region B is through capacitor or through non-electronic
Qu Zaijing external circuit and another electric communication is connected, it is possible to realize that normality works.
In the present invention, positive and negative non-electronic charged particle mixing is selectively chosen as non-electronic charged particle transmitter
Object.
In the present invention, the non-electronic charged particle transmitter A and the non-electronic charged particle transmitter B are alternative
Ground selection is set as same non-electronic charged particle transmitter, is also selectively chosen and is set as non-electronic charged particle not of the same race
How on earth transmitter selects, and should be determined according to the conductance calls of corresponding non-electronic charged particle.
It is the electrochemistry region, the non-electronic charged particle transmitter, the electronic conduction area, described in the present invention
When getting along near any the two in dielectric and the region B, at least one of neighbour the two got along is got along neighbour
Locate have ultra microstructure to increase the neighbour area got along, and then increases capacitance.
It is the electrochemistry region A, the non-electronic charged particle transmitter, the electronic conduction area, described in the present invention
When getting along near any the two in dielectric and the electrochemistry region B, at least one of neighbour the two got along than
It is adjacent mutually to have ultra microstructure to increase the neighbour area got along everywhere, and then increase capacitance.
In the present invention, the non-electronic charged particle transmitter A and the non-electronic charged particle transmitter B can be identical
It can also be different, but alternative when non-electronic charged particle transmitter A and non-electronic charged particle transmitter B are directly contacted
Selection is different, such as non-electronic charged particle transmitter A is proton conductive object, non-electronic charged particle transmitter B be negative oxygen from
Son conducting object.
In the present invention, so-called interpolar spacer refers to make to have required for non-electronic conducting electrical relation between electrode
Substance (including vacuum), for example, electrolyte, dielectric etc..
In the present invention, the selection of interpolar spacer alternative is set as insulation, isolation space, electrolyte, dielectric, electricity
At least one of appearance, plasma, ionic liquid, ionized gas, solion and electronic conduction area.
In the present invention, so-called interpolar spacer, which is selectively chosen, is set as interior circuit, is also selectively chosen and sets
For external circuit.
In the present invention, so-called electro ultrafiltration is a kind of selectivity selection.
In the present invention, " the non-electronic charged particle " refers to the charged particle other than electronics, including proton and ion.
In the present invention, after a certain component names plus the letter such as so-called " A ", " B " is merely to distinguish two or several
The identical component of title or substance.
In the present invention, necessary portion should be set in necessary place according to electricity field, the well-known technique of electrochemical field
Part, unit or system etc..
Beneficial effects of the present invention are as follows: electrolysis unit disclosed in this invention will terminate traditional electrolyte device with electrolyte
The history for existing for necessary condition, for efficiently, the exploitation of long-life, inexpensive electrolysis unit provide new approach.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the embodiment of the present invention 1；
Fig. 2 is the structural schematic diagram of the embodiment of the present invention 2；
Fig. 3 is the structural schematic diagram of the embodiment of the present invention 3；
Fig. 4 is the structural schematic diagram of the embodiment of the present invention 4；
Fig. 5 is the structural schematic diagram of the embodiment of the present invention 5；
Fig. 6 is the structural schematic diagram of the embodiment of the present invention 6；
Fig. 7 is the structural schematic diagram of the embodiment of the present invention 7；
Fig. 8 is the structural schematic diagram of the embodiment of the present invention 8；
Fig. 9 is the structural schematic diagram of the embodiment of the present invention 9；
Figure 10 is the structural schematic diagram of the embodiment of the present invention 10；
Figure 11 is the structural schematic diagram of the embodiment of the present invention 11；
In figure:
1 electrochemistry region, 11 electrochemistry region A, 2 region B, 21 electrochemistry region B, 3 compound feed channels, 4 electrolysis
Product exports channel, 5 cavitys, 51 cavity A, 52 cavity B.
Specific embodiment
Technical solution of the present invention is further illustrated in the following with reference to the drawings and specific embodiments.
Embodiment 1
Electrolysis unit as shown in Figure 1, including electrochemistry region 1, the electrochemistry region 1 and compound feed channel 3
Connection setting, the electrochemistry region 1 include the area alternating current Jie electricity, and the electrochemistry region 1 exports channel 4 with electrolysate
Connection setting.
As can embodiment in conversion, the electrochemistry region 1 and non-electronic band further can be selectively set
Charged particle transmitter has non-electronic conducting electrical relation, or the electrochemistry region 1 is selectively arranged and successively leads with electronics
Logical area and non-electronic charged particle transmitter have non-electronic conducting electrical relation, or the electrochemistry region is selectively arranged
1 has non-electronic conducting electrical relation with dielectric.
As can embodiment in conversion, further can selectively be arranged the electrochemistry region 1 and insulation, every
In exhausted space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
At least one has non-electronic conducting electrical relation.
Embodiment 2
Electrolysis unit as shown in Figure 2, including electrochemistry region 1 and region B2, the electrochemistry region 1 are supplied with compound
The connection setting of channel 3 is sent, the electrochemistry region 1 includes alternating current Jie electricity area A, and the region B2 includes that alternating current connects electricity
Area B, the electrochemistry region 1 are connected to setting with electrolysate export channel 4.
As can embodiment in conversion, the electrochemistry region 1 further can be selectively set through non-electronic band
Charged particle transmitter and region B2 have non-electronic conducting electrical relation, or the electrochemistry region 1 is selectively arranged successively
There is non-electronic conducting electrical relation through electronic conduction area and non-electronic charged particle transmitter and region B2, or selectively set
Setting the electrochemistry region 1 has non-electronic conducting electrical relation through dielectric and region B2.
As can embodiment in conversion, further can selectively be arranged the electrochemistry region 1 through insulation, every
In exhausted space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
It is at least one that there is non-electronic conducting electrical relation with the region B2.
Embodiment 3
Electrolysis unit as shown in Figure 3, including electrochemistry region A11 and electrochemistry region B21, the electrochemistry region
A11 is connected to setting with compound feed channel 3, and the electrochemistry region A11 includes alternating current Jie electricity area A, the electrochemistry
Region B21 is connected to setting with compound feed channel 3, and the electrochemistry region B21 includes alternating current Jie electricity area B, the electricity
Chemical regions A11 is connected to setting with electrolysate export channel 4, and the electrochemistry region B21 and electrolysate export channel 4 connect
Logical setting.
As can embodiment in conversion, the electrochemistry region A11 further can be selectively set through non-electronic
Charged particle transmitter and the electrochemistry region B21 have non-electronic conducting electrical relation, or the electricity is selectively arranged
Chemical regions A11 successively has non-electrical through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B21
Son conducting electrical relation, or the electrochemistry region A11 is selectively set has through dielectric and the electrochemistry region B21
Non-electronic conducting electrical relation.
As can embodiment in conversion, further can selectively be arranged the electrochemistry region A11 through insulation,
Completely cut off in space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
At least one with the electrochemistry region B21 have non-electronic conducting electrical relation.
Embodiment 4
Electrolysis unit as shown in Figure 4, including electrochemistry region A11 and electrochemistry region B21, the electrochemistry region
The A11 and electrochemistry region B21 is connected to setting with compound feed channel 3, and the electrochemistry region A11 includes alternating current
The area Jie electricity A, the electrochemistry region B21 include alternating current Jie electricity area B, and the electrochemistry region A11 and electrolysate export
The connection setting of channel 4, the electrochemistry region B21 are connected to setting with electrolysate export channel 4.
As can embodiment in conversion, the electrochemistry region A11 further can be selectively set through non-electronic
Charged particle transmitter and the electrochemistry region B21 have non-electronic conducting electrical relation, or the electricity is selectively arranged
Chemical regions A11 successively has non-electrical through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B21
Son conducting electrical relation, or the electrochemistry region A11 is selectively set has through dielectric and the electrochemistry region B21
Non-electronic conducting electrical relation.
As can embodiment in conversion, further can selectively be arranged the electrochemistry region A11 through insulation,
Completely cut off in space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
At least one with the electrochemistry region B21 have non-electronic conducting electrical relation.
Embodiment 5
Electrolysis unit as shown in Figure 5, including electrochemistry region A11 and electrochemistry region B21, the electrochemistry region
The A11 and electrochemistry region B21 is connected to setting with compound feed channel 3, and the electrochemistry region A11 includes alternating current
The area Jie electricity A, the electrochemistry region B21 include alternating current Jie electricity area B, the electrochemistry region A11 and the electrochemical school district
Domain B21 is connected to setting with electrolysate export channel 4.
As can embodiment in conversion, the electrochemistry region A11 further can be selectively set through non-electronic
Charged particle transmitter and the electrochemistry region B21 have non-electronic conducting electrical relation, or the electricity is selectively arranged
Chemical regions A11 successively has non-electrical through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B21
Son conducting electrical relation, or the electrochemistry region A11 is selectively set has through dielectric and the electrochemistry region B21
Non-electronic conducting electrical relation.
As can embodiment in conversion, further can selectively be arranged the electrochemistry region A11 through insulation,
Completely cut off in space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
At least one with the electrochemistry region B21 have non-electronic conducting electrical relation.
Embodiment 6
Electrolysis unit as shown in FIG. 6, including electrochemistry region 1, the electrochemistry region 1 is arranged in cavity 5, described
Cavity 5 is connected to setting with compound feed channel 3, and the electrochemistry region 1 includes the area alternating current Jie electricity, the cavity 5 with
Electrolysate exports the connection setting of channel 4.
As can embodiment in conversion, the electrochemistry region 1 and non-electronic band further can be selectively set
Charged particle transmitter has non-electronic conducting electrical relation, or the electrochemistry region 1 is selectively arranged and successively leads with electronics
Logical area and non-electronic charged particle transmitter have non-electronic conducting electrical relation, or the electrochemistry region is selectively arranged
1 has non-electronic conducting electrical relation with dielectric.
As can embodiment in conversion, further can selectively be arranged the electrochemistry region 1 and insulation, every
In exhausted space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
At least one has non-electronic conducting electrical relation.
Embodiment 7
Electrolysis unit as shown in Figure 7, including electrochemistry region 1 and region B2, the electrochemistry region 1 are arranged in cavity
In 5, the cavity 5 is connected to setting with compound feed channel 3, and the electrochemistry region 1 includes alternating current Jie electricity area A, institute
Stating region B2 includes alternating current Jie electricity area B, and the cavity 5 is connected to setting with electrolysate export channel 4.
As can embodiment in conversion, the electrochemistry region 1 further can be selectively set through non-electronic band
Charged particle transmitter and region B2 have non-electronic conducting electrical relation, or the electrochemistry region 1 is selectively arranged successively
There is non-electronic conducting electrical relation through electronic conduction area and non-electronic charged particle transmitter and region B2, or selectively set
Setting the electrochemistry region 1 has non-electronic conducting electrical relation through dielectric and region B2.
As can embodiment in conversion, further can selectively be arranged the electrochemistry region 1 through insulation, every
In exhausted space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
It is at least one that there is non-electronic conducting electrical relation with the region B2.
Embodiment 8
Electrolysis unit as shown in Figure 8, including electrochemistry region A11 and electrochemistry region B21, the electrochemistry region
A11 is arranged in cavity A51, and the cavity A51 is connected to setting with compound feed channel 3, and the electrochemistry region A11 includes
Alternating current Jie electricity area A, the electrochemistry region B21 setting is in cavity B52, the cavity B52 and compound feed channel 3
Connection setting, the electrochemistry region B21 include alternating current Jie electricity area B, and the cavity A51 and electrolysate export channel 4
Connection setting, the cavity B52 are connected to setting with electrolysate export channel 4.
As can embodiment in conversion, the electrochemistry region A11 further can be selectively set through non-electronic
Charged particle transmitter and the electrochemistry region B21 have non-electronic conducting electrical relation, or the electricity is selectively arranged
Chemical regions A11 successively has non-electrical through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B21
Son conducting electrical relation, or the electrochemistry region A11 is selectively set has through dielectric and the electrochemistry region B21
Non-electronic conducting electrical relation.
As can embodiment in conversion, further can selectively be arranged the electrochemistry region A11 through insulation,
Completely cut off in space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
At least one with the electrochemistry region B21 have non-electronic conducting electrical relation.
Embodiment 9
Electrolysis unit as shown in Figure 9, including electrochemistry region A11 and electrochemistry region B21, the electrochemistry region
A11 is arranged in cavity A51, and the electrochemistry region B21 is arranged in cavity B52, the cavity A51 and the cavity B52
Setting is connected to compound feed channel 3, the electrochemistry region A11 includes alternating current Jie electricity area A, the electrochemistry region
B21 includes alternating current Jie electricity area B, and the cavity A51 is connected to setting, the cavity B52 and electricity with electrolysate export channel 4
Solve the connection setting of product export channel 4.
As can embodiment in conversion, the electrochemistry region A11 further can be selectively set through non-electronic
Charged particle transmitter and the electrochemistry region B21 have non-electronic conducting electrical relation, or the electricity is selectively arranged
Chemical regions A11 successively has non-electrical through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B21
Son conducting electrical relation, or the electrochemistry region A11 is selectively set has through dielectric and the electrochemistry region B21
Non-electronic conducting electrical relation.
As can embodiment in conversion, further can selectively be arranged the electrochemistry region A11 through insulation,
Completely cut off in space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
At least one with the electrochemistry region B21 have non-electronic conducting electrical relation.
Embodiment 10
Electrolysis unit as shown in Figure 10, including electrochemistry region A11 and electrochemistry region B21, the electrochemistry region
A11 is arranged in cavity A51, and the electrochemistry region B21 is arranged in cavity B52, the cavity A51 and the cavity B52
Setting is connected to compound feed channel 3, the electrochemistry region A11 includes alternating current Jie electricity area A, the electrochemistry region
B21, which includes alternating current Jie electricity area B, the cavity A51 and the cavity B52, is connected to setting with electrolysate export channel 4.
As can embodiment in conversion, the electrochemistry region A11 further can be selectively set through non-electronic
Charged particle transmitter and the electrochemistry region B21 have non-electronic conducting electrical relation, or the electricity is selectively arranged
Chemical regions A11 successively has non-electrical through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B21
Son conducting electrical relation, or the electrochemistry region A11 is selectively set has through dielectric and the electrochemistry region B21
Non-electronic conducting electrical relation.
As can embodiment in conversion, further can selectively be arranged the electrochemistry region A11 through insulation,
Completely cut off in space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
At least one with the electrochemistry region B21 have non-electronic conducting electrical relation.
Embodiment 11
Electrolysis unit as shown in figure 11, including electrochemistry region A11 and electrochemistry region B21, the electrochemistry region
The A11 and electrochemistry region B21 is arranged in cavity 5, and the cavity 5 is connected to setting, the electricity with compound feed channel 3
Chemical regions A11 includes alternating current Jie electricity area A, and the electrochemistry region B21 includes alternating current Jie electricity area B, the cavity 5
Setting is connected to electrolysate export channel 4.
As can embodiment in conversion, the electrochemistry region A11 further can be selectively set through non-electronic
Charged particle transmitter and the electrochemistry region B21 have non-electronic conducting electrical relation, or the electricity is selectively arranged
Chemical regions A11 successively has non-electrical through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B21
Son conducting electrical relation, or the electrochemistry region A11 is selectively set has through dielectric and the electrochemistry region B21
Non-electronic conducting electrical relation.
As can embodiment in conversion, further can selectively be arranged the electrochemistry region A11 through insulation,
Completely cut off in space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
At least one with the electrochemistry region B21 have non-electronic conducting electrical relation.
As can embodiment in conversion, the above-mentioned all embodiments of the present invention and its convertible ground embodiment can be into
The compound is selectively set as the compound in mixture by one step；Or, the compound is set as water, the reducing agent is
Hydrogen, the oxidant are oxygen；Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide, it is described to go back
Former agent is alcohol compound, and the oxidant is oxygen；Or, the compound is set as water, and water participates in jointly with carbon dioxide
Reaction, the reducing agent are ether compound, and the oxidant is oxygen；Or, the compound is set as water, and water and dioxy
Change carbon to participate in reacting jointly, the reducing agent is alkane derivative, and the oxidant is oxygen；Or, the compound is set
For water, and water participates in reacting jointly with carbon dioxide, and the reducing agent is alkenes compounds, and the oxidant is oxygen；Or,
The compound is set as water, and water participates in reacting jointly with carbon dioxide, the reducing agent is alkynes compound, the oxygen
Agent is oxygen.
As can embodiment in conversion, the above-mentioned all embodiments of the present invention and its convertible ground embodiment can be into
It includes reducing agent export channel and oxidant export channel that electrolysate export channel 4, which is selectively arranged, in one step；
Or be further selectively arranged, electrolysate export channel 4 includes reducing agent export channel and oxidant
Channel is exported, setting reducing agent switchs on reducing agent export channel, and oxidation is arranged on oxidant export channel
Agent switch, the reducing agent switch and oxidant switch are controlled by control device and are alternately opened and closed；
Or be further selectively arranged, electrolysate export channel 4 includes reducing agent export channel and oxidant
Channel is exported, setting reducing agent switchs on reducing agent export channel, and oxidation is arranged on oxidant export channel
Agent switch, the reducing agent switch and oxidant switch are controlled by control device and are alternately opened and closed, the reducing agent
The frequency and phase that switch and oxidant switch alternately open and close and the alternation electricity that the area alternating current Jie electricity is applied
The frequency and phase of stream match；
Or be further selectively arranged, electrolysate export channel 4 is set as the molar ratio of Oxidizing and Reducing Agents
Mixture exports channel.
As can embodiment in conversion, the above-mentioned all embodiments including the electrochemistry region 1 of the present invention and its
Convertible ground embodiment, which can further selectively rotate the electrochemistry region 1, to be arranged.
As can embodiment in conversion, the present invention it is above-mentioned it is all include the electrochemistry region A11 and the electrification
The embodiment and its convertible ground embodiment of school district domain B21 can further selectively turn the electrochemistry region A11
Dynamic setting, the electrochemistry region B21 rotation setting.
As disposable embodiment, the electrolysis unit in only electrochemistry region disclosed in this invention is being embodied
When, being selectively chosen cooperates two electrodes using electric conductor as another electrode using electrochemistry region as an electrode
The conversion of chemical energy electric energy is completed in work；It is also selectively chosen using electrochemistry region as an electrode, by another electrification
As another electrode, two electrode cooperatings complete the conversion of chemical energy electric energy in school district domain.
Attached drawing of the invention is only a kind of signal, and any technical solution for meeting the application literature record belongs to the application
Protection scope.
It is clear that the invention is not restricted to above embodiments, according to techniques known and technology disclosed in this invention
Scheme, can derive or associate many variant schemes out, and all these variant schemes also are regarded as being protection model of the invention
It encloses.
Claims (17)
1. a kind of electrolysis unit, including electrochemistry region (1), it is characterised in that: the electrochemistry region (1) and compound feed
Channel (3) connection setting, the electrochemistry region (1) includes the area alternating current Jie electricity, and the electrochemistry region (1) and electrolysis produce
Object exports channel (4) connection setting；
Or, the electrochemistry region (1) is connected to setting with compound feed channel (3), the electrochemistry region (1) includes alternation
The area electric current Jie electricity, the electrochemistry region (1) are connected to setting with electrolysate export channel (4)；The electrochemistry region (1) with
Non-electronic charged particle transmitter have non-electronic conducting electrical relation or the electrochemistry region (1) successively with electronic conduction
There is non-electronic conducting electrical relation or the electrochemistry region (1) and dielectric to have for area and non-electronic charged particle transmitter
There is non-electronic conducting electrical relation；
Or, the electrochemistry region (1) is connected to setting with compound feed channel (3), the electrochemistry region (1) includes alternation
The area electric current Jie electricity, the electrochemistry region (1) are connected to setting with electrolysate export channel (4)；The electrochemistry region (1) with
Insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronics
At least one of area, which is connected, has non-electronic conducting electrical relation.
2. a kind of electrolysis unit, including electrochemistry region (1) and region B (2), it is characterised in that: the electrochemistry region (1) with
Compound feed channel (3) connection setting, the electrochemistry region (1) includes alternating current Jie electricity area A, region B (2) packet
Alternating current Jie electricity area B is included, the electrochemistry region (1) is connected to setting with electrolysate export channel (4)；
Or, the electrochemistry region (1) is connected to setting with compound feed channel (3), the electrochemistry region (1) includes alternation
Electric current Jie electricity area A, the region B (2) include alternating current Jie electricity area B, and the electrochemistry region (1) and electrolysate export are logical
Road (4) connection setting；The electrochemistry region (1) has non-electronic conducting through non-electronic charged particle transmitter and region B (2)
Electrical relation or the electrochemistry region (1) are successively through electronic conduction area and non-electronic charged particle transmitter and region B (2)
There is non-electronic electric conduction through dielectric and region B (2) with non-electronic conducting electrical relation or the electrochemistry region (1)
Relationship；
Or, the electrochemistry region (1) is connected to setting with compound feed channel (3), the electrochemistry region (1) includes alternation
Electric current Jie electricity area A, the region B (2) include alternating current Jie electricity area B, and the electrochemistry region (1) and electrolysate export are logical
Road (4) connection setting；The electrochemistry region (1) through insulation, isolation space, electrolyte, dielectric, capacitor, plasma,
At least one of ionic liquid, ionized gas, solion and electronic conduction area have non-electronic lead with the region B (2)
Logical electrical relation.
3. a kind of electrolysis unit, including electrochemistry region A (11) and electrochemistry region B (21), it is characterised in that: the electrochemistry
Region A (11) is connected to setting with compound feed channel (3), and the electrochemistry region A (11) includes alternating current Jie electricity area A,
The electrochemistry region B (21) is connected to setting with compound feed channel (3), and the electrochemistry region B (21) includes alternation electricity
The area Liu Jie electricity B, the electrochemistry region A (11) are connected to setting, the electrochemistry region B with electrolysate export channel (4)
(21) setting is connected to electrolysate export channel (4)；
Or, the electrochemistry region A (11) is connected to setting with compound feed channel (3), the electrochemistry region A (11) includes
Alternating current Jie electricity area A, the electrochemistry region B (21) are connected to setting, the electrochemistry region with compound feed channel (3)
B (21) includes alternating current Jie electricity area B, and the electrochemistry region A (11) is connected to setting, institute with electrolysate export channel (4)
It states electrochemistry region B (21) and is connected to setting with electrolysate export channel (4)；The electrochemistry region A (11) is through non-electronic band
Charged particle transmitter and the electrochemistry region B (21) have non-electronic conducting electrical relation or the electrochemistry region A (11)
Successively there is non-electronic conducting electricity through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B (21)
Relationship or the electrochemistry region A (11) are closed through dielectric and the electrochemistry region B (21) with non-electronic conducting electricity
System；
Or, the electrochemistry region A (11) is connected to setting with compound feed channel (3), the electrochemistry region A (11) includes
Alternating current Jie electricity area A, the electrochemistry region B (21) are connected to setting, the electrochemistry region with compound feed channel (3)
B (21) includes alternating current Jie electricity area B, and the electrochemistry region A (11) is connected to setting, institute with electrolysate export channel (4)
It states electrochemistry region B (21) and is connected to setting with electrolysate export channel (4)；The electrochemistry region A (11) through insulation, every
In exhausted space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
It is at least one that there is non-electronic conducting electrical relation with the electrochemistry region B (21).
4. a kind of electrolysis unit, including electrochemistry region A (11) and electrochemistry region B (21), it is characterised in that: the electrochemistry
Region A (11) and the electrochemistry region B (21) is connected to setting, the electrochemistry region A (11) with compound feed channel (3)
Including alternating current Jie electricity area A, the electrochemistry region B (21) includes alternating current Jie electricity area B, the electrochemistry region A
(11) setting is connected to electrolysate export channel (4), the electrochemistry region B (21) and electrolysate export channel (4) are even
Logical setting；Or, the electrochemistry region A (11) and the electrochemistry region B (21) are connected to compound feed channel (3) and set
It sets, the electrochemistry region A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) includes that alternating current connects electricity
Area B, the electrochemistry region A (11) are connected to setting, the electrochemistry region B (21) and electricity with electrolysate export channel (4)
Solve product export channel (4) connection setting；The electrochemistry region A (11) is through non-electronic charged particle transmitter and the electrification
School district domain B (21) has non-electronic conducting electrical relation or the electrochemistry region A (11) successively through electronic conduction area and non-electrical
Subband charged particle transmitter and the electrochemistry region B (21) have non-electronic conducting electrical relation or the electrochemistry region A
(11) there is non-electronic conducting electrical relation through dielectric and the electrochemistry region B (21)；
Or, the electrochemistry region A (11) and the electrochemistry region B (21) are connected to setting, institute with compound feed channel (3)
Stating electrochemistry region A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) includes alternating current Jie electricity area B,
The electrochemistry region A (11) is connected to setting with electrolysate export channel (4), and the electrochemistry region B (21) and electrolysis produce
Object exports channel (4) connection setting；The electrochemistry region A (11) is through insulation, isolation space, electrolyte, dielectric, electricity
At least one of appearance, plasma, ionic liquid, ionized gas, solion and electronic conduction area and the electrochemical school district
Domain B (21) has non-electronic conducting electrical relation.
5. a kind of electrolysis unit, including electrochemistry region A (11) and electrochemistry region B (21), it is characterised in that: the electrochemistry
Region A (11) and the electrochemistry region B (21) is connected to setting, the electrochemistry region A (11) with compound feed channel (3)
Including alternating current Jie electricity area A, the electrochemistry region B (21) includes alternating current Jie electricity area B, the electrochemistry region A
(11) channel (4) are exported with electrolysate and are connected to setting with the electrochemistry region B (21)；
Or, the electrochemistry region A (11) and the electrochemistry region B (21) are connected to setting, institute with compound feed channel (3)
Stating electrochemistry region A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) includes alternating current Jie electricity area B,
The electrochemistry region A (11) and the electrochemistry region B (21) export channel (4) with electrolysate and are connected to setting；The electricity
Chemical regions A (11) is closed through non-electronic charged particle transmitter and the electrochemistry region B (21) with non-electronic conducting electricity
System or the electrochemistry region A (11) are successively through electronic conduction area and non-electronic charged particle transmitter and the electrochemical school district
Domain B (21) has non-electronic conducting electrical relation or the electrochemistry region A (11) through dielectric and the electrochemistry region B
(21) there is non-electronic conducting electrical relation；
Or, the electrochemistry region A (11) and the electrochemistry region B (21) are connected to setting, institute with compound feed channel (3)
Stating electrochemistry region A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) includes alternating current Jie electricity area B,
The electrochemistry region A (11) and the electrochemistry region B (21) export channel (4) with electrolysate and are connected to setting；The electricity
Chemical regions A (11) through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas,
At least one of solion and electronic conduction area have non-electronic conducting electrical relation with the electrochemistry region B (21).
6. a kind of electrolysis unit, including electrochemistry region (1), it is characterised in that: the electrochemistry region (1) is arranged in cavity
(5) in, the cavity (5) is connected to setting with compound feed channel (3), and the electrochemistry region (1) includes that alternating current connects
Electric area, the cavity (5) are connected to setting with electrolysate export channel (4)；
Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is connected to compound feed channel (3) to be set
It sets, the electrochemistry region (1) includes the area alternating current Jie electricity, and the cavity (5) is connected to electrolysate export channel (4) and sets
It sets；The electrochemistry region (1) and non-electronic charged particle transmitter have non-electronic conducting electrical relation or the electrochemistry
Region (1) successively has non-electronic conducting electrical relation or the electricity with electronic conduction area and non-electronic charged particle transmitter
Chemical regions (1) and dielectric have non-electronic conducting electrical relation；
Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is connected to compound feed channel (3) to be set
It sets, the electrochemistry region (1) includes the area alternating current Jie electricity, and the cavity (5) is connected to electrolysate export channel (4) and sets
It sets；The electrochemistry region (1) and insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, from
At least one of sub- gas, solion and electronic conduction area have non-electronic conducting electrical relation.
7. a kind of electrolysis unit, including electrochemistry region (1) and region B (2), it is characterised in that: the electrochemistry region (1) sets
It sets in cavity (5), the cavity (5) is connected to setting with compound feed channel (3), and the electrochemistry region (1) includes handing over
Time-dependent current Jie electricity area A, the region B (2) include alternating current Jie electricity area B, and the cavity (5) and electrolysate export channel
(4) connection setting；
Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is connected to compound feed channel (3) to be set
It sets, the electrochemistry region (1) includes alternating current Jie electricity area A, and the region B (2) includes alternating current Jie electricity area B, described
Cavity (5) is connected to setting with electrolysate export channel (4)；The electrochemistry region (1) is through non-electronic charged particle transmitter
Have non-electronic conducting electrical relation or the electrochemistry region (1) successively through electronic conduction area and non-electronic with region B (2)
Charged particle transmitter and region B (2) have non-electronic conducting electrical relation or the electrochemistry region (1) through dielectric with
Region B (2) has non-electronic conducting electrical relation；
Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is connected to compound feed channel (3) to be set
It sets, the electrochemistry region (1) includes alternating current Jie electricity area A, and the region B (2) includes alternating current Jie electricity area B, described
Cavity (5) is connected to setting with electrolysate export channel (4)；The electrochemistry region (1) is through insulation, isolation space, electrolysis
At least one of matter, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area with
The region B (2) has non-electronic conducting electrical relation.
8. a kind of electrolysis unit, including electrochemistry region A (11) and electrochemistry region B (21), it is characterised in that: the electrochemistry
In cavity A (51), the cavity A (51) is connected to setting, the electrification with compound feed channel (3) for region A (11) setting
School district domain A (11) includes alternating current Jie electricity area A, and electrochemistry region B (21) setting is in cavity B (52), the cavity B
(52) setting is connected to compound feed channel (3), the electrochemistry region B (21) includes alternating current Jie electricity area B, the chamber
Body A (51) is connected to setting with electrolysate export channel (4), and the cavity B (52) is connected to electrolysate export channel (4) and sets
It sets；
Or, electrochemistry region A (11) setting is interior in cavity A (51), the cavity A (51) and compound feed channel (3)
Connection setting, the electrochemistry region A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) is arranged in cavity
In B (52), the cavity B (52) is connected to setting with compound feed channel (3), and the electrochemistry region B (21) includes alternation
Electric current Jie electricity area B, the cavity A (51) are connected to setting with electrolysate export channel (4), and the cavity B (52) and electrolysis produce
Object exports channel (4) connection setting；The electrochemistry region A (11) is through non-electronic charged particle transmitter and the electrochemical school district
Domain B (21) has non-electronic conducting electrical relation or the electrochemistry region A (11) successively through electronic conduction area and non-electronic band
Charged particle transmitter and the electrochemistry region B (21) have non-electronic conducting electrical relation or the electrochemistry region A (11)
There is non-electronic conducting electrical relation through dielectric and the electrochemistry region B (21)；
Or, electrochemistry region A (11) setting is interior in cavity A (51), the cavity A (51) and compound feed channel (3)
Connection setting, the electrochemistry region A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) is arranged in cavity
In B (52), the cavity B (52) is connected to setting with compound feed channel (3), and the electrochemistry region B (21) includes alternation
Electric current Jie electricity area B, the cavity A (51) are connected to setting with electrolysate export channel (4), and the cavity B (52) and electrolysis produce
Object exports channel (4) connection setting；The electrochemistry region A (11) is through insulation, isolation space, electrolyte, dielectric, electricity
At least one of appearance, plasma, ionic liquid, ionized gas, solion and electronic conduction area and the electrochemical school district
Domain B (21) has non-electronic conducting electrical relation.
9. a kind of electrolysis unit, including electrochemistry region A (11) and electrochemistry region B (21), it is characterised in that: the electrochemistry
Region A (11) setting is in cavity A (51), and electrochemistry region B (21) setting is in cavity B (52), the cavity A (51)
Setting is connected to compound feed channel (3) with the cavity B (52), the electrochemistry region A (11) includes that alternating current connects
Electric area A, the electrochemistry region B (21) include alternating current Jie electricity area B, and the cavity A (51) and electrolysate export channel
(4) connection setting, the cavity B (52) are connected to setting with electrolysate export channel (4)；
Or, electrochemistry region A (11) setting is in cavity A (51), the electrochemistry region B (21) is arranged in cavity B
(52) in, the cavity A (51) and the cavity B (52) are connected to setting, the electrochemistry region with compound feed channel (3)
A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) includes alternating current Jie electricity area B, the cavity A (51)
Setting is connected to electrolysate export channel (4), the cavity B (52) is connected to setting with electrolysate export channel (4)；It is described
Electrochemistry region A (11) has non-electronic conducting electricity through non-electronic charged particle transmitter and the electrochemistry region B (21)
Relationship or the electrochemistry region A (11) are successively through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry
Region B (21) has non-electronic conducting electrical relation or the electrochemistry region A (11) through dielectric and the electrochemistry region
B (21) has non-electronic conducting electrical relation；
Or, electrochemistry region A (11) setting is in cavity A (51), the electrochemistry region B (21) is arranged in cavity B
(52) in, the cavity A (51) and the cavity B (52) are connected to setting, the electrochemistry region with compound feed channel (3)
A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) includes alternating current Jie electricity area B, the cavity A (51)
Setting is connected to electrolysate export channel (4), the cavity B (52) is connected to setting with electrolysate export channel (4)；It is described
Electrochemistry region A (11) is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ion-gas
At least one of body, solion and electronic conduction area are closed with the electrochemistry region B (21) with non-electronic conducting electricity
System.
10. a kind of electrolysis unit, including electrochemistry region A (11) and electrochemistry region B (21), it is characterised in that: the electrification
School district domain A (11) setting is in cavity A (51), and electrochemistry region B (21) setting is in cavity B (52), the cavity A
(51) and the cavity B (52) is connected to setting with compound feed channel (3), and the electrochemistry region A (11) includes alternation electricity
The area Liu Jie electricity A, the electrochemistry region B (21) include alternating current Jie electricity area B, the cavity A (51) and the cavity B (52)
Setting is connected to electrolysate export channel (4)；
Or, electrochemistry region A (11) setting is in cavity A (51), the electrochemistry region B (21) is arranged in cavity B
(52) in, the cavity A (51) and the cavity B (52) are connected to setting, the electrochemistry region with compound feed channel (3)
A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) includes alternating current Jie electricity area B, the cavity A (51)
Setting is connected to the cavity B (52) with electrolysate export channel (4)；The electrochemistry region A (11) is through non-electronic electrification
Particle conduction object and the electrochemistry region B (21) have non-electronic conducting electrical relation or the electrochemistry region A (11) according to
It is secondary to be closed through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B (21) with non-electronic conducting electricity
System or the electrochemistry region A (11) have non-electronic conducting electrical relation through dielectric and the electrochemistry region B (21)；
Or, electrochemistry region A (11) setting is in cavity A (51), the electrochemistry region B (21) is arranged in cavity B
(52) in, the cavity A (51) and the cavity B (52) are connected to setting, the electrochemistry region with compound feed channel (3)
A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) includes alternating current Jie electricity area B, the cavity A (51)
Setting is connected to the cavity B (52) with electrolysate export channel (4)；The electrochemistry region A (11) is through insulation, isolation
In space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area extremely
A kind of few and electrochemistry region B (21) has non-electronic conducting electrical relation.
11. a kind of electrolysis unit, including electrochemistry region A (11) and electrochemistry region B (21), it is characterised in that: the electrification
School district domain A (11) and the electrochemistry region B (21) setting is in cavity (5), the cavity (5) and compound feed channel
(3) connection setting, the electrochemistry region A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) includes handing over
Time-dependent current Jie electricity area B, the cavity (5) are connected to setting with electrolysate export channel (4)；
Or, the electrochemistry region A (11) and the electrochemistry region B (21) setting be in the cavity (5), the cavity (5) with
Compound feed channel (3) connection setting, the electrochemistry region A (11) includes alternating current Jie electricity area A, the electrification school district
Domain B (21) includes alternating current Jie electricity area B, and the cavity (5) is connected to setting with electrolysate export channel (4)；The electrification
School district domain A (11) has non-electronic conducting electrical relation through non-electronic charged particle transmitter and the electrochemistry region B (21),
Or the electrochemistry region A (11) is successively through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B
(21) have non-electronic conducting electrical relation or the electrochemistry region A (11) through dielectric and the electrochemistry region B (21)
With non-electronic conducting electrical relation；
Or, the electrochemistry region A (11) and the electrochemistry region B (21) setting be in the cavity (5), the cavity (5) with
Compound feed channel (3) connection setting, the electrochemistry region A (11) includes alternating current Jie electricity area A, the electrification school district
Domain B (21) includes alternating current Jie electricity area B, and the cavity (5) is connected to setting with electrolysate export channel (4)；The electrification
School district domain A (11) through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, from
At least one of sub- solution and electronic conduction area have non-electronic conducting electrical relation with the electrochemistry region B (21).
12. the electrolysis unit as described in any one of claims 1 to 11, it is characterised in that: the compound is set as in mixture
Compound；Or, the compound is set as water, the reducing agent is hydrogen, and the oxidant is oxygen；Or, the compound
It is set as water, and water participates in reacting jointly with carbon dioxide, the reducing agent is alcohol compound, and the oxidant is oxygen；Or,
The compound is set as water, and water participates in reacting jointly with carbon dioxide, and the reducing agent is ether compound, the oxidant
For oxygen；Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide, and the reducing agent is alkanes chemical combination
Object, the oxidant are oxygen；Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide, the reducing agent
For alkenes compounds, the oxidant is oxygen；Or, the compound is set as water, and water and carbon dioxide participate in instead jointly
It answers, the reducing agent is alkynes compound, and the oxidant is oxygen.
13. the electrolysis unit as described in any one of claims 1 to 11, it is characterised in that: the electrolysate exports channel (4)
Channel is exported including reducing agent and oxidant exports channel；
Or, electrolysate export channel (4) includes reducing agent export channel and oxidant export channel, in the reducing agent
It exports setting reducing agent on channel to switch, setting oxidant switchs on oxidant export channel, the reducing agent switch
It is controlled with oxidant switch by control device and is alternately opened and closed；
Or, electrolysate export channel (4) includes reducing agent export channel and oxidant export channel, in the reducing agent
It exports setting reducing agent on channel to switch, setting oxidant switchs on oxidant export channel, the reducing agent switch
It is controlled with oxidant switch by control device and is alternately opened and closed, the reducing agent switch and oxidant switch are handed over
Match for the frequency and phase of open and close with the frequency of alternating current and phase applied to the area alternating current Jie electricity；
Or, electrolysate export channel (4) is set as the molar mixture export channel of Oxidizing and Reducing Agents.
14. electrolysis unit as claimed in claim 12, it is characterised in that: electrolysate export channel (4) includes reducing agent
It exports channel and oxidant exports channel；
Or, electrolysate export channel (4) includes reducing agent export channel and oxidant export channel, in the reducing agent
It exports setting reducing agent on channel to switch, setting oxidant switchs on oxidant export channel, the reducing agent switch
It is controlled with oxidant switch by control device and is alternately opened and closed；
Or, electrolysate export channel (4) includes reducing agent export channel and oxidant export channel, in the reducing agent
It exports setting reducing agent on channel to switch, setting oxidant switchs on oxidant export channel, the reducing agent switch
It is controlled with oxidant switch by control device and is alternately opened and closed, the reducing agent switch and oxidant switch are handed over
Match for the frequency and phase of open and close with the frequency of alternating current and phase applied to the area alternating current Jie electricity；
Or, electrolysate export channel (4) is set as the molar mixture export channel of Oxidizing and Reducing Agents.
15. the electrolysis unit as described in any one of claim 1 to 11 and 14, it is characterised in that: the electrochemistry region (1) turns
Dynamic setting；Or, in the device for including the electrochemistry region A (11) and the electrochemistry region B (21), the electrification school district
Domain A (11) rotation setting, electrochemistry region B (21) the rotation setting.
16. electrolysis unit as claimed in claim 12, it is characterised in that: electrochemistry region (1) the rotation setting；Or, wrapping
In the device for including the electrochemistry region A (11) and the electrochemistry region B (21), electrochemistry region A (11) rotation is set
It sets, electrochemistry region B (21) the rotation setting.
17. electrolysis unit as claimed in claim 13, it is characterised in that: electrochemistry region (1) the rotation setting；Or, wrapping
In the device for including the electrochemistry region A (11) and the electrochemistry region B (21), electrochemistry region A (11) rotation is set
It sets, electrochemistry region B (21) the rotation setting.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810977121X | 2018-08-26 | ||
| CN201810977121 | 2018-08-26 | ||
| CN2019100374303 | 2019-01-15 | ||
| CN201910037430 | 2019-01-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109735868A true CN109735868A (en) | 2019-05-10 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910107983.1A Pending CN109735868A (en) | 2018-08-26 | 2019-02-02 | A kind of electrolysis unit |
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| Country | Link |
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| CN (1) | CN109735868A (en) |
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Application publication date: 20190510 |