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CN109692565A - A kind of removal sludge drying generates stench deodorant and its preparation method and application - Google Patents

A kind of removal sludge drying generates stench deodorant and its preparation method and application Download PDF

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Publication number
CN109692565A
CN109692565A CN201910122553.7A CN201910122553A CN109692565A CN 109692565 A CN109692565 A CN 109692565A CN 201910122553 A CN201910122553 A CN 201910122553A CN 109692565 A CN109692565 A CN 109692565A
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CN
China
Prior art keywords
deodorant
sludge drying
essence
sorb
removal sludge
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201910122553.7A
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Chinese (zh)
Inventor
薛惠科
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Wisdom Gas Purification Technology Co Ltd
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Wuxi Wisdom Gas Purification Technology Co Ltd
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Publication date
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Priority to CN201910122553.7A priority Critical patent/CN109692565A/en
Publication of CN109692565A publication Critical patent/CN109692565A/en
Withdrawn legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/52Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/58Ammonia

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The present invention relates to a kind of removal sludge dryings to generate stench deodorant and its preparation method and application, it is prepared using following methods: water, emulsifier, pH adjusting agent, wing seed seed oil of Moringa oleigera, preservative, aromatic, thickener, pigment, wherein each component accounting are as follows: water 30%-98%, emulsifier 0.50%-20%, pH adjusting agent 0.01%-30.00%, wing seed seed oil of Moringa oleigera 1.00%-25.00%, preservative 0.0001-1%, aromatic 0.0001-1%, thickener 0.0001-1%, pigment 0-1%.This removal sludge drying generates stench deodorant and its preparation method and application and passes through the yield of foul gas in reduction mud drying process, and use aromatic, the foul odour come out is covered, the malodor problem in mud drying process is fundamentally solved.

Description

A kind of removal sludge drying generates stench deodorant and its preparation method and application
Technical field
The present invention relates to sludge drying processing technology field, specially a kind of removal sludge drying generates stench deodorant And its preparation method and application.
Background technique
Activated sludge, due to containing a large amount of moisture and organic matter, can generate a large amount of strong stimulations in storage, drying process Foul gas, surrounding enviroment and human health are caused with direct or indirect influence, to discharging in sewage sludge storage, drying process Foul gas removal technology out mainly has physical method, chemical method and bioanalysis.
Physical method be entire workshop is closed, gas in workshop is extracted out with negative pressure, by launch have adsorbent Gas holder absorbs stink substances, plays the effect of deodorization, but after adsorbent saturation, can not parse reuse, use cost Height, the adsorbent for being adsorbed with foul gas is hazardous waste, and processing cost is high, and chemical method mitigates evil by using aromatic It is smelly, only play the role of covering stink, after foul gas concentration is high or aromatic volatilizees completely, can not play well Deodorizing effect, bioanalysis are to be handled via the microorganism in water, by after gas extraction in workshop since water is to the molten of gas Speed and limited efficacy are solved, treatment effect is simultaneously bad, therefore now needs to prepare a kind of novel deodorant.
Summary of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of removal sludge dryings to generate stench deodorant and its system Preparation Method and application, solve the problems mentioned above in the background art.
In order to achieve the above object, the present invention is achieved by the following technical programs: a kind of removal sludge drying generation evil Smelly to use deodorant, the deodorant constituent includes: water, emulsifier, pH adjusting agent, wing seed seed oil of Moringa oleigera, preservative, fragrance Agent, thickener, pigment, wherein each component accounting are as follows: water 30%-98%, emulsifier 0.50%-20%, pH adjusting agent 0.01%- 30.00%, wing seed seed oil of Moringa oleigera 1.00%-25.00%, preservative 0.0001-1%, aromatic 0.0001-1%, thickener 0.0001-1%, pigment 0-1%.
Optionally, the emulsifier is specially one of following classifications or many kinds of substance combination: the smooth stearate of sorb, The smooth oleate of sorb, the smooth cocounut oil acid esters of sorb, the smooth olive oleate of sorb, the smooth caprylate of sorb, the smooth laurate of sorb, sorb Smooth palmitate, octyl phenol polyethers -11, octyl phenol polyethers -9, nonyl phenol polyethers -11, nonyl phenol polyethers -9, polysorbate - 20, polysorbate -21, polysorbate -40, polysorbate -60, Polyoxyethylene Sorbitan Monooleate, polysorbate -85, PEG- 40 rilanit specials, PEG-60 rilanit special;
Optionally, the preservative is specially one of following classifications or many kinds of substance combination: P-hydroxybenzoic acid first Ester, ethyl-para-hydroxybenzoate, propylparaben, butyl p-hydroxybenzoate, methylisothiazolinone, methyl chloride are different Thiazolinone, benzoisothiazolinone, potassium sorbate, sodium sorbate, Phenoxyethanol;
Optionally, the aromatic is specially one of following classifications or multiple combinations: flavoring rose essence, magnolia compound, Flores aurantii essence, gardenia compound, lavender oil, Yilan essence, green apple essence, orange essence, cherry essence, lemon extract, Mint Essence, almond flavour, citronellal, citral, cinnamic acid, English walnut essence, vanilla;
Optionally, the pigment is specially one of following classifications or multiple combinations: lemon yellow, sunset yellow, brilliant blue, rose It is rare red, carmine;
Optionally, the pH adjusting agent is specially one of following classifications or multiple combinations: hydrochloric acid, sulfuric acid, nitric acid, cream Acid, oxalic acid, citric acid, potassium dihydrogen phosphate, sodium hydroxide, potassium hydroxide, calcium hydroxide, dipotassium hydrogen phosphate, sodium lactate, oxalic acid Sodium, sodium citrate;
Optionally, the thickener is specially one of following classifications or multiple combinations: hydroxyethyl cellulose, hydroxypropyl Cellulose, carbomer, xanthan gum;
Optionally, the removal sludge drying generates the operating procedure of stench deodorant and its preparation method and application such as Under:
I, technological temperature: 20-90 DEG C;
II, water, thickener are uniformly mixed, control is spare in technological temperature;
III, emulsifier, wing seed seed oil of Moringa oleigera are uniformly mixed, control is spare in technological temperature;
IV, the mixture that step III is obtained is slowly added in step II, and homogeneous 5-30 divides to uniform within stirring 5-60 minute Clock;
V, preservative, aromatic, pigment is added, stirring 5-60 minutes to uniform;
VI, pH adjusting agent is added, adjusts pH value, stirring 5-60 minutes to uniformly.
Optionally, the deodorant is applied to removal sludge drying generation stench
The present invention provides a kind of removal sludge dryings to generate stench deodorant and its preparation method and application, have with Down the utility model has the advantages that this removal sludge drying generates stench deodorant and its preparation method and application by reducing sludge drying mistake The yield of foul gas in journey, and aromatic is used, the foul odour come out is covered, sludge is fundamentally solved Malodor problem in drying process.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.
For the ordinary skill in the art, above-mentioned term in the present invention specific can be understood with concrete condition Meaning.
Embodiment 1:
A kind of removal sludge drying generates in stench deodorant, and composition is composed of the following components in parts by weight:
Component 1, water 30%-98%;
Component 2, emulsifier 0.50%-20%;
Component 3, pH adjusting agent 0.01%-30.00%;
Component 4, wing seed seed oil of Moringa oleigera 1.00%-25.00%;
Component 5, preservative 0.0001-1%;
Component 6, aromatic 0.0001-1%;
Component 7, thickener 0.0001-1%;
Component 8, pigment 0-1%.
Emulsifier is specially one of following classifications or many kinds of substance combination: the smooth stearate of sorb, the smooth oleic acid of sorb The smooth olive oleate of the smooth cocounut oil acid esters of ester, sorb, sorb, the smooth caprylate of sorb, the smooth laurate of sorb, the smooth palmitinic acid of sorb Ester, octyl phenol polyethers -11, octyl phenol polyethers -9, nonyl phenol polyethers -11, nonyl phenol polyethers -9, polysorbate -20, poly- sorb Alcohol ester -21, polysorbate -40, polysorbate -60, Polyoxyethylene Sorbitan Monooleate, polysorbate -85, PEG-40 hydrogenate castor Sesame oil, PEG-60 rilanit special;
Preservative is specially one of following classifications or many kinds of substance combination: methyl p-hydroxybenzoate, para hydroxybenzene Ethyl formate, propylparaben, butyl p-hydroxybenzoate, methylisothiazolinone, methylchloroisothiazandnone, benzene And isothiazolinone, potassium sorbate, sodium sorbate, Phenoxyethanol;
Aromatic is specially one of following classifications or multiple combinations: flavoring rose essence, magnolia compound, flores aurantii essence, Cape jasmine Sub- essence, lavender oil, Yilan essence, green apple essence, orange essence, cherry essence, lemon extract, Mint Essence, apricot Benevolence essence, citronellal, citral, cinnamic acid, English walnut essence, vanilla;
Pigment is specially one of following classifications or multiple combinations: lemon yellow, sunset yellow, brilliant blue, rose-red, kermes It is red;
PH adjusting agent is specially one of following classifications or multiple combinations: hydrochloric acid, sulfuric acid, nitric acid, lactic acid, oxalic acid, lemon Lemon acid, potassium dihydrogen phosphate, sodium hydroxide, potassium hydroxide, calcium hydroxide, dipotassium hydrogen phosphate, sodium lactate, sodium oxalate, sodium citrate;
Thickener is specially one of following classifications or multiple combinations: hydroxyethyl cellulose, hydroxypropyl cellulose, card wave Nurse, xanthan gum;
Preparing process is as follows:
I, technological temperature: 20-90 DEG C;
II, water, thickener are uniformly mixed, control is spare in technological temperature;
III, emulsifier, wing seed seed oil of Moringa oleigera are uniformly mixed, control is spare in technological temperature;
IV, the mixture that step III is obtained is slowly added in step II, and homogeneous 5-30 divides to uniform within stirring 5-60 minute Clock;
V, preservative, aromatic, pigment is added, stirring 5-60 minutes to uniform;
VI, pH adjusting agent is added, adjusts pH value, stirring 5-60 minutes to uniformly.
Embodiment 2:
A kind of removal sludge drying generates in stench deodorant, and composition is composed of the following components in parts by weight:
Component 1, water: 96.33 parts;
The smooth laurate of component 2, sorb: 1 part;
- 20:0.4 parts of component 3, polysorbate;
Component 4, potassium hydroxide: 0.01 part;
Component 5, wing seed seed oil of Moringa oleigera: 2 parts;
Component 6, methylisothiazolinone: 0.01 part;
Component 7, carbomer: 0.15 part;
Component 8, orange essence: 0.1 part.
Preparing process:
I, component 1 and component 7 are uniformly mixed, are heated to 80 DEG C, it is spare.
II, component 2,3,5 is uniformly mixed, is heated to 80 DEG C, it is spare.
III, the mixture that step II is obtained is slowly added in step I, stirring 30 minutes to uniform, homogeneous 10 minutes.
IV, it is cooled to 43 DEG C, is added component 6,8, stirring 30 minutes is to uniform.
V, component 4 is added, stirring 30 minutes to uniformly.
Embodiment 3:
A kind of removal sludge drying generates in stench deodorant, and composition is composed of the following components in parts by weight:
Component 1, water: 95.99 parts
The smooth laurate of component 2, sorb: 1 part
- 20:0.4 parts of component 3, polysorbate
Component 4, sodium hydroxide: 0.01 part
Component 5, wing seed seed oil of Moringa oleigera: 2 parts
Component 6, methyl p-hydroxybenzoate: 0.2 part
Component 7, propylparaben: 0.1 part
Component 8, xanthan gum: 0.2 part
Component 9, lavender oil: 0.1 part
Preparing process:
I, component 1 and component 8 are uniformly mixed, are heated to 80 DEG C, it is spare.
II, component 2,3,5,6,7 is mixed, is heated to 80 DEG C, it is spare.
III, the mixture that step II is obtained is slowly added in step I, stirring 30 minutes to uniform, homogeneous 10 minutes.
IV, it is cooled to 43 DEG C, is added component 9, stirring 30 minutes is to uniform.
Illustrate deodorant deodorizing effect of the invention below with reference to test.
One, sludge drying processing workshop deodorizing test (one)
In Hubei Province, sludge drying handles workshop, by prepared complexing agent, dilutes 10 times with tap water, is sprayed at vehicle Between in air.Different collection points is arranged in workshop to be sampled, respectively before measurement sprinkling and 8 hours after sprinkling, 24 small When after in foul gas hydrogen sulfide and ammonia concentration, sampled point is liftoff 1.5 meters, 6 point samplings are averaged.Test result such as table 1。
1 deodorant of table handles workshop deodorizing test result in Hubei Province's sludge drying
Deodorant of the invention handles shop test in sludge drying, and the removal rate of hydrogen sulfide reaches 94.17%, ammonia Removal rate reach 93.46%.Lasting to use, effect is more preferable;
Two, sludge drying processing workshop deodorizing test (two)
In Jiangsu Province, sludge drying handles workshop, by prepared complexing agent, dilutes 10 times with tap water, is sprayed at vehicle Between in air.Different collection points is arranged in workshop to be sampled, respectively before measurement sprinkling and 8 hours after sprinkling, 24 small When after in foul gas hydrogen sulfide and ammonia concentration, sampled point is liftoff 1.5 meters, 6 point samplings are averaged.Test result such as table 2。
2 deodorant of table handles workshop deodorizing test result in Jiangsu Province's sludge drying
Composite drug of the invention handles shop test in sludge drying, and the removal rate of hydrogen sulfide reaches 93.75%, ammonia The removal rate of gas reaches 93.14%.Lasting to use, effect is more preferable.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (9)

1. a kind of removal sludge drying generates stench deodorant, be prepared using following methods: water, emulsifier, pH are adjusted Agent, wing seed seed oil of Moringa oleigera, preservative, aromatic, thickener, pigment, wherein each component accounting are as follows: water 30%-98%, emulsifier 0.50%-20%, pH adjusting agent 0.01%-30.00%, wing seed seed oil of Moringa oleigera 1.00%-25.00%, preservative 0.0001- 1%, aromatic 0.0001-1%, thickener 0.0001-1%, pigment 0-1%.
2. a kind of removal sludge drying according to claim 1 generates stench deodorant, it is characterised in that: the emulsification Agent is one of following classifications or many kinds of substance combination: the smooth stearate of sorb, the smooth oleate of sorb, the smooth coconut oil of sorb The smooth olive oleate of ester, sorb, the smooth caprylate of sorb, the smooth laurate of sorb, the smooth palmitate of sorb, octyl phenol polyethers -11, Octyl phenol polyethers -9, nonyl phenol polyethers -11, nonyl phenol polyethers -9, polysorbate -20, polysorbate -21, polysorbate Ester -40, polysorbate -60, Polyoxyethylene Sorbitan Monooleate, polysorbate -85, Cremophor RH40, PEG-60 hydrogenate castor Sesame oil.
3. a kind of removal sludge drying according to claim 1 generates stench deodorant, it is characterised in that: the anti-corrosion Agent is one of following classifications or many kinds of substance combination: methyl p-hydroxybenzoate, ethyl-para-hydroxybenzoate, para hydroxybenzene Propyl formate, butyl p-hydroxybenzoate, methylisothiazolinone, methylchloroisothiazandnone, benzoisothiazolinone, sorb Sour potassium, sodium sorbate, Phenoxyethanol.
4. a kind of removal sludge drying according to claim 1 generates stench deodorant, it is characterised in that: the fragrance Agent is one of following classifications or multiple combinations: flavoring rose essence, magnolia compound, flores aurantii essence, gardenia compound, lavender are fragrant Essence, Yilan essence, green apple essence, orange essence, cherry essence, lemon extract, Mint Essence, almond flavour, citronellal, lemon Lemon aldehyde, cinnamic acid, English walnut essence, vanilla.
5. a kind of removal sludge drying according to claim 1 generates stench deodorant, it is characterised in that: the pigment It is one of following classifications or multiple combinations: lemon yellow, sunset yellow, brilliant blue, rose-red, famille rose.
6. a kind of removal sludge drying according to claim 1 generates stench deodorant, it is characterised in that: the pH tune Save agent be one of following classifications or multiple combinations: hydrochloric acid, sulfuric acid, nitric acid, lactic acid, oxalic acid, citric acid, potassium dihydrogen phosphate, Sodium hydroxide, potassium hydroxide, calcium hydroxide, dipotassium hydrogen phosphate, sodium lactate, sodium oxalate, sodium citrate.
7. a kind of removal sludge drying according to claim 1 generates stench deodorant, it is characterised in that: the thickening Agent is one of following classifications or multiple combinations: hydroxyethyl cellulose, hydroxypropyl cellulose, carbomer, xanthan gum.
8. a kind of removal sludge drying according to claim 1-7 generates stench deodorant, it is characterised in that: The operating procedure that the removal sludge drying generates stench deodorant and its preparation method and application is as follows:
I, technological temperature: 20-90 DEG C;
II, water, thickener are uniformly mixed, control is spare in technological temperature;
III, emulsifier, wing seed seed oil of Moringa oleigera are uniformly mixed, control is spare in technological temperature;
IV, the mixture that step III is obtained is slowly added in step II, stirring 5-60 minutes to uniform, homogeneous 5-30 minutes;
V, preservative, aromatic, pigment is added, stirring 5-60 minutes to uniform;
VI, pH adjusting agent is added, adjusts pH value, stirring 5-60 minutes to uniformly.
9. a kind of removal sludge drying according to claim 1-7 generates stench deodorant, it is characterised in that: The deodorant is applied to removal sludge drying and generates stench.
CN201910122553.7A 2019-02-19 2019-02-19 A kind of removal sludge drying generates stench deodorant and its preparation method and application Withdrawn CN109692565A (en)

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CN110313492A (en) * 2019-05-20 2019-10-11 安徽启威生物科技有限公司 A kind of footgear deodorizing antibiotic composition and preparation method thereof
CN115231781A (en) * 2022-08-08 2022-10-25 阳城县安阳污水处理有限公司 A sewage treatment process with low sludge yield

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Publication number Priority date Publication date Assignee Title
CN110313492A (en) * 2019-05-20 2019-10-11 安徽启威生物科技有限公司 A kind of footgear deodorizing antibiotic composition and preparation method thereof
CN115231781A (en) * 2022-08-08 2022-10-25 阳城县安阳污水处理有限公司 A sewage treatment process with low sludge yield

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Application publication date: 20190430