CN109679606A - Foaming water discharge agent composition and its preparation method and application - Google Patents
Foaming water discharge agent composition and its preparation method and application Download PDFInfo
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- CN109679606A CN109679606A CN201710969486.3A CN201710969486A CN109679606A CN 109679606 A CN109679606 A CN 109679606A CN 201710969486 A CN201710969486 A CN 201710969486A CN 109679606 A CN109679606 A CN 109679606A
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 64
- 239000000203 mixture Substances 0.000 title claims abstract description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 238000005187 foaming Methods 0.000 title description 16
- 239000006260 foam Substances 0.000 claims abstract description 80
- 238000007599 discharging Methods 0.000 claims abstract description 59
- 229920000570 polyether Polymers 0.000 claims abstract description 51
- -1 nitrogenous compound Chemical class 0.000 claims abstract description 29
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 26
- 150000003973 alkyl amines Chemical class 0.000 claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 claims abstract description 10
- 238000005086 pumping Methods 0.000 claims abstract description 10
- 239000002105 nanoparticle Substances 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 34
- 239000000377 silicon dioxide Substances 0.000 claims description 17
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 125000000129 anionic group Chemical group 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims description 3
- 229910000271 hectorite Inorganic materials 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 150000004996 alkyl benzenes Chemical class 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 4
- 238000011161 development Methods 0.000 abstract description 3
- 241000521257 Hydrops Species 0.000 abstract description 2
- 206010030113 Oedema Diseases 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract description 2
- 239000002349 well water Substances 0.000 abstract description 2
- 235000020681 well water Nutrition 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 38
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 28
- 239000007789 gas Substances 0.000 description 24
- 239000011780 sodium chloride Substances 0.000 description 14
- 229960002668 sodium chloride Drugs 0.000 description 14
- 235000002639 sodium chloride Nutrition 0.000 description 14
- 239000007788 liquid Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 238000005259 measurement Methods 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- 239000004088 foaming agent Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000003483 aging Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003672 gas field water Substances 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/584—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/602—Compositions for stimulating production by acting on the underground formation containing surfactants
- C09K8/604—Polymeric surfactants
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/92—Compositions for stimulating production by acting on the underground formation characterised by their form or by the form of their components, e.g. encapsulated material
- C09K8/94—Foams
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2208/00—Aspects relating to compositions of drilling or well treatment fluids
- C09K2208/10—Nanoparticle-containing well treatment fluids
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Detergent Compositions (AREA)
- Degasification And Air Bubble Elimination (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
The present invention relates to a kind of high temperature deep well water pumping gas production foam discharging agent compositions and the preparation method and application thereof.Mainly solve the problem of existing high temperature deep well gas well in the process of development hydrops it is excessive cause the gas well underproduction even stop-spraying.The present invention by using in terms of mass fraction including following components: (1) 1 part of alkylamine polyethers；(2) 0.1~50 parts of long-chain polyether nitrogenous compound；(3) 0~10 parts of nano particle；The wherein alkylamine polyethers has general molecular formula shown in formula (I): the long-chain polyether nitrogenous compound, has general molecular formula shown in formula (II): R1For C8~C20Alkyl in any one；The arbitrary number that m, n, p, q are 0~20；R1For C10~C26The technical solution of fat-based preferably resolve the problem, can be used in the water pumping gas production industry of high temperature gas well.
Description
Technical field
The present invention relates to a kind of foaming water discharge agent compositions and its preparation method and application, especially suitable for high temperature deep well.
Background technique
With the reinforcement of gas-field exploitation dynamics, gas field is discharged the critical issue normally produced at gas well is restricted.Foam row
Hydromining gas is a kind of drainage gas recovery that recent domestic rapidly develops, simple, easy for construction, at low cost with equipment,
Applicable well depth range is big, does not influence the advantages that gas well normally produces.Foaming water discharge is exactly to pass through oil pipe or tubing and casing annular space to well
Interior injection foam discharging agent generates the foam with certain stability under the agitation of air-flow.The liquid phase that deposition is slipped in pipe becomes steeping
Foam changes the relative density of lower curtate bit stream body in managing, and quantity-produced gas phase displacement foam flows out pit shaft, so that well inner product be discharged
Liquid achievees the purpose that water pumping gas production.
The development of foreign countries' foam discharging agent since the eighties of last century sixties, multiselect sulfonate, benzene sulfonate, alkyl phenol are poly-
The surfactants such as ethylene oxide ether.Recompounded multielement system is mostly used greatly with foam discharging agent to current water pumping gas production, it is single in order to enhance
The stability of foam is usually additionally added the auxiliary agents such as alkali, alcohol, polymer, alkanolamide in formula and forms strengthening foam.
US7122509 reports a kind of high temperature foam discharging agent formula, and the Research Thinking neutralized using anionic surfactant plus amine is improved
The heat resistance of system.US20120279715 reports the aerated fluid that gas recovery in a kind of gas well increases oil yield, is one
Class phosphinylidyne-containing amine group quaternary surfactant has both bubble row and sterilizing function, and hydrophobic chain is to replace naphthalene nucleus, phenyl ring or natural oil
Hydrophobic patch in ester, the performance with very strong chlorine-resistant and condensate oil also have good corrosion inhibition.However due to dividing
Contain the amide group more sensitive to high temperature in minor structure, thus it is poor to 100 DEG C or more of gas well adaptability.China be from
Begin one's study in the year eighties in last century foam drainaging gas cutting process technology, and UT series is that more foam discharging agent is applied in domestic gas field,
UT series foaming water discharge agent and associated auxiliary products more than 20 are a at present, are suitble to the UT-11C of middle-deep well, ultradeep well
Anti- high salinity 250,000g/L, high temperature are up to 130 DEG C.
Summary of the invention
The first technical problem to be solved by the present invention is that hydrops is excessive in the process of development for existing high temperature deep well gas well,
The problem of leading to the gas well underproduction or even stop-spraying, a kind of foam discharging agent composition is provided, especially a kind of high temperature resistant water pumping gas production
Foam discharging agent composition, be used for gas well, especially high temperature deep well, can efficiently take liquid, have good heat resistance, frothing capacity and
Fluid-carrying capability.
The second technical problem to be solved by the present invention is corresponding to provide a kind of one of and solution above-mentioned technical problem
The preparation method of the foam discharging agent composition of high temperature resistant water pumping gas production.
The third technical problem to be solved by the present invention is corresponding to provide a kind of one of and solution above-mentioned technical problem
The application method of the foam discharging agent composition of high temperature resistant water pumping gas production.
One of to solve above-mentioned technical problem, The technical solution adopted by the invention is as follows: a kind of foam discharging agent composition, with matter
Measure number meter, including following components:
(1) 1 part of alkylamine polyethers；
(2) 0.1~50 parts of long-chain polyether nitrogenous compound；
(3) 0~10 parts of nano particle.
In above-mentioned technical proposal, the general molecular formula of the alkylamine polyethers is preferred are as follows:
Wherein, R1For C8~C20Alkyl in any one；M, n, p, q are independently selected from 0~20 arbitrary number, and m+n >=
1.Further, m+p is preferably 1~5 arbitrary number, and n+q is preferably 5~15 arbitrary number.
In above-mentioned technical proposal, the general molecular formula of the long-chain polyether nitrogenous compound is preferred are as follows:
Wherein, R1For C10~C26Fat-based or C10~C26Aromatic radical；Y=0~20, z=0~60；R4、R5Independent choosing
From C1~C5Alkyl, C1~C5Replace alkyl in any one；R6、R7It is independently selected from C1~C5Alkylidene, replace alkylene
Any one of base；Y, which is selected from, makes molecule shown in formula (II) be in the anionic group of electroneutral；Further, R1Preferably C10~C20
Alkyl, C10~C20Alkylbenzene, R7Preferably C2H4Or C3H6, z is preferably greater than 0；
In above-mentioned technical proposal, as long as the Y makes general molecular formula (II) to be in the anionic group of electroneutral, such as
But Y is not limited and preferably is selected from-COO—、-SO3 —、-HPO4 —At least one of, further preferably-COO—、-SO3 —In at least
It is a kind of.
In above-mentioned technical proposal, the nano particle is preferably nano silica, nanometer calcium carbonate, in nanometer hectorite
At least one, more preferably nano silica.
Foam discharging agent composition in the present invention does not have particular/special requirement to water, can be deionized water when preparing, can be with
It is the water containing inorganic mineral, and the water containing inorganic mineral can be tap water, oil field stratum water or oilfield injection water.
To solve above-mentioned technical problem two, The technical solution adopted by the invention is as follows: a kind of above-mentioned solution technical problem
One of described in technical solution any foam discharging agent composition preparation method, comprising the following steps:
By alkylamine polyethers, long-chain polyether nitrogenous compound and nano particle according to required mass fraction, mixed with water
It is even, obtain the water pumping gas production foam discharging agent composition.
To solve above-mentioned technical problem three, The technical solution adopted by the invention is as follows: a kind of above-mentioned solution technical problem
One of described in technical solution any foam discharging agent composition application.
In above-mentioned technical proposal, the application has no particular/special requirement, and those skilled in the art can be according to practical application ring
Border, to foam discharging agent composition of the present invention carry out using, such as but do not limit well temperature in the application and may be up to 180 DEG C, this
Invention foam discharging agent still has good application performance.
Key active ingredient alkylamine polyethers, the long-chain polyether nitrogenous compound of foam discharging agent of the present invention, those skilled in the art
Member knows, for the ease of transporting and storing or scene uses etc. considers, can use various supply forms, such as not aqueous
Solid-state form perhaps aqueous solid-state form perhaps aqueous cream form or aqueous solution form；Aqueous solution form packet
Include the form that concentrate is made into water, the foam discharging agent form of concentration needed for being directly made into the live displacement of reservoir oil；Wherein, not special to water
It is required that can be deionized water, can also be the water containing inorganic mineral, and the water containing inorganic mineral can be tap water,
Oil gas field water flooding or oil gas field inject water.
Foam discharging agent composition of the present invention has good compatibility, can also contain other inorganic agents commonly used in the art,
Such as surfactant, polymer, the oil recoveries auxiliary agent such as alkali.
The thermal decomposition temperature of alkylamine polyethers and long-chain polyether nitrogenous compound is 200 in foam discharging agent composition of the invention
DEG C, it does not hydrolyze in aqueous solution；Secondly, containing multiple hydrophilic radicals in composition simultaneously, more hydrophilic groups carry foaming agent
Combination water and irreducible water amount increase, foam carrier amount enhancing, analysis liquid slow down, make it possible to the high temperature applied to 180 DEG C
During deep-well water pumping gas production.
Using technical solution of the present invention, according to SY/T 6465-2000 " foam drainage gas recovery foaming agent evaluation method "
Foaming properties test is carried out to the foam discharging agent, foam height is greater than 140mm, and liquid carry over is greater than 140mL, 180 DEG C of high temperature ageings
For 24 hours, foam foam height and drainage performance change rate have good heatproof, frothing capacity and fluid-carrying capability, take less than 5%
Obtained preferable technical effect.
Below by embodiment, the present invention is further elaborated.
Detailed description of the invention
Fig. 1 show liquid carry over measurement device (jacketed vessel height is 1 meter).
Specific embodiment
In order to better understand the present invention, the content that the present invention is further explained with reference to embodiments, but it is of the invention
Content is not limited solely to the following examples.
[embodiment 1]
At normal temperatures and pressures, alkylamine polyethers, long-chain polyether nitrogenous compound are weighed, nano silica is according to mass ratio
Sodium-chloride water solution of the 1:2:1 in 100,000mg/L dissolves, and is configured to the solution of 1.0wt% to get foam discharging agent composition HF-
1.Component structure is as shown in table 1.
[embodiment 2]
At normal temperatures and pressures, alkylamine polyethers, long-chain polyether nitrogenous compound are weighed, nano silica is according to mass ratio
Sodium-chloride water solution of the 1:10:5 in 100,000mg/L dissolves, and is configured to the solution of 1.0wt% to get foam discharging agent composition HF-
2.Component structure is as shown in table 1.
[embodiment 3]
At normal temperatures and pressures, alkylamine polyethers, long-chain polyether nitrogenous compound are weighed, nano silica is according to mass ratio
Sodium-chloride water solution of the 1:0.2:0.5 in 100,000mg/L dissolves, and is configured to the solution of 1.0wt% to get foam discharging agent composition
HF-3.Component structure is as shown in table 1.
[embodiment 4]
At normal temperatures and pressures, alkylamine polyethers, long-chain polyether nitrogenous compound are weighed, nano silica is according to mass ratio
Sodium-chloride water solution of the 1:1:0.1 in 100,000mg/L dissolves, and is configured to the solution of 1.0wt% to get foam discharging agent composition
HF-4.Component structure is as shown in table 1.
[embodiment 5]
At normal temperatures and pressures, alkylamine polyethers, long-chain polyether nitrogenous compound are weighed, nano silica is according to mass ratio
Sodium-chloride water solution of the 1:0.5:0.5 in 100,000mg/L dissolves, and is configured to the solution of 1.0wt% to get foam discharging agent composition
HF-5.Component structure is as shown in table 1.
[embodiment 6]
At normal temperatures and pressures, alkylamine polyethers, long-chain polyether nitrogenous compound are weighed, nano silica is according to mass ratio
Sodium-chloride water solution of the 1:2:1 in 100,000mg/L dissolves, and is configured to the solution of 1.0wt% to get foam discharging agent composition HF-6
Component structure such as table 1 shows.
[embodiment 7]
At normal temperatures and pressures, alkylamine polyethers, long-chain polyether nitrogenous compound are weighed, nano silica is according to mass ratio
Sodium-chloride water solution of the 1:3:0.5 in 100,000mg/L dissolves, and is configured to the solution of 1.0wt% to get foam discharging agent composition
HF-7.Component structure is as shown in table 1.
[embodiment 8]
At normal temperatures and pressures, alkylamine polyethers, long-chain polyether nitrogenous compound are weighed, nano silica is according to mass ratio
Sodium-chloride water solution of the 1:50:10 in 100,000mg/L dissolves, and is configured to the solution of 1.0wt% to get foam discharging agent composition
HF-8.Component structure is as shown in table 1.
[embodiment 9]
At normal temperatures and pressures, alkylamine polyethers, long-chain polyether nitrogenous compound are weighed, nano silica is according to mass ratio
Sodium-chloride water solution of the 1:2:1 in 100,000mg/L dissolves, and is configured to the solution of 1.0wt% to get foam discharging agent composition HF-
9.Component structure is as shown in table 1.
[embodiment 10]
At normal temperatures and pressures, alkylamine polyethers, long-chain polyether nitrogenous compound are weighed, nano silica is according to mass ratio
Sodium-chloride water solution of the 1:2:1 in 100,000mg/L dissolves, and is configured to the solution of 1.0wt% to get foam discharging agent composition HF-
10.Component structure is as shown in table 1.
[embodiment 11]
At normal temperatures and pressures, alkylamine polyethers, long-chain polyether nitrogenous compound are weighed, nano silica is according to mass ratio
Sodium-chloride water solution of the 1:2:1 in 100,000mg/L dissolves, and is configured to the solution of 1.0wt% to get foam discharging agent composition HF-
11.Component structure is as shown in table 1.
[embodiment 12]
At normal temperatures and pressures, alkylamine polyethers, long-chain polyether nitrogenous compound are weighed, nanometer calcium carbonate is according to mass ratio 1:
Sodium-chloride water solution of the 2:1 in 100,000mg/L dissolves, and is configured to the solution of 1.0wt% to get foam discharging agent composition HF-12.
Component structure is as shown in table 1.
[embodiment 13]
At normal temperatures and pressures, alkylamine polyethers, long-chain polyether nitrogenous compound are weighed, nanometer hectorite is according to mass ratio 1:
Sodium-chloride water solution of the 2:1 in 100,000mg/L dissolves, and is configured to the solution of 1.0wt% to get foam discharging agent composition HF-13.
Component structure is as shown in table 1.
[embodiment 14]
At normal temperatures and pressures, alkylamine polyethers, long-chain polyether nitrogenous compound are weighed according to mass ratio 1:2 100,
The sodium-chloride water solution of 000mg/L dissolves, and is configured to the solution of 1.0wt% to get foam discharging agent composition HF-14.Component structure
As shown in table 1.
[embodiment 15]
Referring to SY/T 6465-2000 " foam drainage gas recovery foaming agent evaluation method " standard, the starting of foam discharging agent is measured
Foaming height, after five minutes foam height, the results are shown in Table shown in 2.
The nitrogen of 4000mL/min is continuously passed through foam discharging agent aqueous solution, measures foam carrier amount in 15 minutes, knot
Fruit is shown in Table 2.The liquid carry over measurement device of use is as shown in Figure 1.
It is tested using the acidproof aging equipment of pressure resistance, after 180 DEG C of agings for 24 hours, redeterminates starting foaming height, 5 points
The performances such as foaming height and 15 minutes liquid carry overs, the results are shown in Table shown in 2 after clock.
[comparative example 1]
The alkylamine polyethers and nano silica in [embodiment 1-5] are used, long-chain polyether nitrogenous compound is added without
It is prepared into foam discharging agent composition, with the starting foaming height of [embodiment 15] measurement foam discharging agent, after five minutes foam height, 15 points
Foam carrier amount in clock time, the results are shown in Table shown in 3.
[comparative example 2]
The long-chain polyether nitrogenous compound and nano silica in [embodiment 1-6] are used, alkylamine polyethers is added without
It is prepared into foam discharging agent composition, with the starting foaming height of [embodiment 15] measurement foam discharging agent, after five minutes foam height, 15 points
Foam carrier amount in clock time, the results are shown in Table shown in 4.
[comparative example 3]
Using dodecyldimethylamine base glycine betaine and cetylamine polyoxypropylene (2) polyoxyethylene (12) ether according to mass ratio 1:
2, it is prepared into foam discharging agent composition, with the starting foaming height of [embodiment 15] measurement foam discharging agent, after five minutes foam height, 15
Foam carrier amount in minutes, the results are shown in Table shown in 5.
Composition component structure in 1 embodiment of table
The foaming properties of foam discharging agent composition in 2 embodiment of table
The foaming properties of foam discharging agent composition in 3 comparative example 1 of table
The foaming properties of foam discharging agent composition in 4 comparative example 2 of table
The foaming properties of foam discharging agent composition in 5 comparative example 3 of table
Claims (10)
1. a kind of foam discharging agent composition, in terms of mass fraction, including following components:
(1) 1 part of alkylamine polyethers；
(2) 0.1~50 parts of long-chain polyether nitrogenous compound；
(3) 0~10 parts of nano particle.
2. foam discharging agent composition according to claim 1, it is characterised in that the general molecular formula of the alkylamine polyethers are as follows:
Wherein, R1For C8~C20Alkyl in any one；M, n, p, q are respectively and independently selected from 0~20 arbitrary number, m+n >=1.
3. foam discharging agent composition according to claim 2, it is characterised in that the m+p be 1~5 arbitrary number, n+q be 5~
15 arbitrary number.
4. foam discharging agent composition according to claim 1, it is characterised in that the molecule of the long-chain polyether nitrogenous compound is logical
Formula are as follows:
Wherein, the R1For C10~C26Fat-based or C10~C26Aromatic radical；Y=0~20, z=0~60；R4、R5Independent choosing
From C1~C5Alkyl, C1~C5Replace alkyl in any one；R6、R7It is independently selected from C1~C5Alkylidene, C1~C5's
Any one of substituted alkylene；Y, which is selected from, makes molecule shown in formula (II) be in the anionic group of electroneutral.
5. foam discharging agent composition according to claim 4, it is characterised in that the R1For C10~C20Alkyl, C10~C20's
Alkylbenzene, R7For C2H4Or C3H6。
6. foam discharging agent composition according to claim 4, it is characterised in that the z is greater than 0.
7. foam discharging agent composition according to claim 1, it is characterised in that the nano particle is nano silica, receives
At least one of rice calcium carbonate, nanometer hectorite.
8. foam discharging agent composition according to claim 1, it is characterised in that the nano particle is nano silica.
9. a kind of preparation method of any foam discharging agent composition of claim 1-8, comprising the following steps: gather alkylamine
Ether, long-chain polyether nitrogenous compound and nano particle are uniformly mixed according to required mass fraction with water, obtain the water pumping gas production
With foam discharging agent composition.
10. a kind of application of any foam discharging agent composition of claim 1-8.
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