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CN109610235A - A kind of the maps with fluorescent colouring paper and its manufacturing method of high folding strength - Google Patents

A kind of the maps with fluorescent colouring paper and its manufacturing method of high folding strength Download PDF

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Publication number
CN109610235A
CN109610235A CN201811476492.6A CN201811476492A CN109610235A CN 109610235 A CN109610235 A CN 109610235A CN 201811476492 A CN201811476492 A CN 201811476492A CN 109610235 A CN109610235 A CN 109610235A
Authority
CN
China
Prior art keywords
coating
fluorescent
maps
paper
folding strength
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811476492.6A
Other languages
Chinese (zh)
Inventor
张瑞娟
苏艳群
刘金刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Pulp And Paper Research Institute Co Ltd
China National Pulp and Paper Research Institute
Original Assignee
China Pulp And Paper Research Institute Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Pulp And Paper Research Institute Co Ltd filed Critical China Pulp And Paper Research Institute Co Ltd
Priority to CN201811476492.6A priority Critical patent/CN109610235A/en
Publication of CN109610235A publication Critical patent/CN109610235A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/34Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising cellulose or derivatives thereof
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/30Luminescent or fluorescent substances, e.g. for optical bleaching

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paper (AREA)

Abstract

The present invention provides a kind of sunset glow time is long, light emission luminance is high, folding strength is good maps with fluorescent colouring paper and its manufacturing method, maps with fluorescent colouring paper described in this method includes substrate and fluoresent coating, in fluoresent coating of the method coating with overlength afterglow luminescent properties that the substrate surface of pure white paper passes through curtain coating.The composition of the fluoresent coating coating specifically: 10 parts of fluorescent powder, 8-12 parts of adhesive, curtain apply auxiliary agent 0.1-0.5 parts.Compared with prior art, maps with fluorescent colouring paper of the present invention, the sunset glow time is long, and light emission luminance is high, and folding strength is good, simple process, product cost are low, the method that manufacturing process uses curtain coating, coating layer thickness is uniform, surfacing, and coating process uses water paint, avoids destruction of the volatile organic matter (VOC) to environment.

Description

A kind of the maps with fluorescent colouring paper and its manufacturing method of high folding strength
Technical field
The invention belongs to paper technology methods, and in particular to a kind of with the maps with fluorescent colouring paper of high folding strength and its manufacturer Method.
Background technique
Maps with fluorescent colouring are the maps for having read function under the conditions of night gauge without light source, are navigated for night, night military affairs Action and underground mining engineering etc. use.There are mainly two types of its manufacturing methods, one is using fluorescent pigment, fluorescent dye and its His auxiliary material manufactures fluorescent paper, and with the ink of various colors on fluorescent paper printed map content;Another method is to use Luminescent material is made special ink and forms in printed on normal paper.Its principle of luminosity is from fluorescent material therein, glimmering Luminescent material absorbs light or the energy hankered and transits to excitation state (non-steady state), discharges energy in dark surrounds in the form of light again It measures and returns to ground state.It is reported that my army once researched and developed and tried out part maps with fluorescent colouring, but because containing radioactive element, use condition by The reasons such as limit, not very practical could not be promoted.With making constant progress for fluorescent material, the research of maps with fluorescent colouring is also taken Obtained certain achievement.
Compared with common paper map, 1) maps with fluorescent colouring, which have the advantage that, has night read function.It is unglazed at night , it can be achieved that accessible reading under conditions of source, under some abnormal conditions (not being available light source or without usable light source) With great advantage.2) safety and concealment are higher.When in military operation, the thermal light sources such as flashlight can not had to, and glimmering The light that light map issues is " cold light ", can perfectly escape the reconnaissance equipment of enemy.3) easy to use.Map is not being can guarantee Under conditions of absorbing luminous energy, can generate heat by rubbing map makes it shine.
Currently, having not been used in the maps with fluorescent colouring paper of maps with fluorescent colouring in the market, the country is also without relevant patent and document Report.Although having there is pertinent literature report to have developed the ink that can be used for printing maps with fluorescent colouring, exist with common ink The method printed on fluorescent paper is compared, complex process, higher cost.Therefore, developing one kind can be used for printing maps with fluorescent colouring Fluorescent paper be necessary.
It is provided in patent ZL200420015133.8 " light accumulating luminous paper " a kind of including the light storage of substrate and luminescent layer hair Machine-glazed paper, it is the luminescent layer with overlength afterglow luminescence performance in the spraying of the surface of the import high-grade pure blank sheet of paper with gum, The luminescent layer raw material is by light-accumulated luminous powder: Crystal varnish: diluent: curing agent 0.3-0.45: 0.3-0.4: 0.15-0.25 : the ratio of 0.115-0.2 is uniformly mixed.The diluent main component is day wax water, and curing agent is resinae.The light storage hair Machine-glazed paper is after daytime absorbs natural light, and sustainable 8 hours or more luminous at night, light is not soft dazzling, can be used for advertising. But its luminescent layer contains a large amount of organic solvent, can generate biggish pollutional load to environment in production process.Patent There is such problems in CN201546123U, CN1959526A etc..
Patent document 200910192786.0 " preparation method of long afterglow luminous paper " is by the aluminate of silica coating 1-2 parts of 10 parts of luminescent powder, 5 parts of calcium carbonate, 2-3 parts of adhesive, 5-8 parts of latex, 10-15 parts of water and pigment uniformly mixed conducts Luminous paint, and through silk screen process on the body paper of coating nano-titanium dioxide priming paint, and obtain long afterglow luminous paper.It is sending out In machine-glazed paper manufacturing process, Aqueous Adhesives have been selected, have avoided destruction of the volatile organic matter (VOC) to environment.But with it is current Fluorescent paper mentioned in other Patents documents is the same, which is primarily adapted for use in advertisement and night illumination instruction, base Originally it is not concerned with into the folding quality of paper.In view of the foldability of maps with fluorescent colouring and its may lead in use The mode for crossing rubbing makes it absorb heat and shine, so the fluorescent paper for being used to printed map needs folding strength with higher. In addition, fluorescent paper is to guarantee ideal illumination effect, the thickness of general luminescent coating at least needs to reach 60-150um, and shines For coating generally based on fluorescent pigment, the pigment coated folding strength for inevitably resulting in into paper of such thickness is poor, and can not expire The requirement of sufficient maps with fluorescent colouring paper.
Summary of the invention
In place of solving above-mentioned the deficiencies in the prior art, the present invention provides a kind of sunset glow time is long, light emission luminance is high, The good maps with fluorescent colouring paper of folding strength and its manufacturing method, this method simple process, product cost are low.Purpose to realize the present invention, Used technical solution is as follows: a kind of the maps with fluorescent colouring paper and its manufacturing method of high folding strength, the maps with fluorescent colouring paper include Substrate and fluoresent coating have overlength afterglow luminescent properties by the method coating of curtain coating in the substrate surface of pure white paper Fluoresent coating.The fluoresent coating includes fluorescent powder, adhesive, curtain painting auxiliary agent, composition specifically: 10 parts of fluorescent powder, gluing 8-12 parts of agent, curtain apply auxiliary agent 0.1-0.5 parts.The solid content of the fluorescent paint is 45-60%.The fluoresent coating with a thickness of 70-120um.The fluorescent powder is the alkaline earth aluminate salt long after glow luminous material by coating modification, partial size 0.1- 30um can be used for water paint.The adhesive is Aqueous Adhesives, including styrene-butadiene latex, polyurethane aqueous varnish, carboxymethyl Two or three in cellulose.
As a kind of Non-Contact Coating mode, compared with contact coating method print roll coating and blade coating, curtain is applied Cloth has advantage very outstanding, and such as small to the stress that paper web applies, coating covers more evenly.With other contact-free applicator sides Formula airblade coating is compared with spraying coating, and curtain coating can realize the coating of more high solids content.Fluorescent paper is to guarantee ideal hair Light effect, the thickness of general luminescent coating at least need to reach 60-150um, and luminescent coating is generally based on fluorescent pigment, such as The pigment coated folding strength for inevitably resulting in into paper of this thickness is poor, and is unable to satisfy the requirement of maps with fluorescent colouring paper.For The folding strength for improving maps with fluorescent colouring paper, is on the one hand the body paper and substrate using high folding strength, but more efficient way is exactly Guarantee to reduce coating layer thickness under conditions of fluorescent effect.The present invention selects the mode for reducing coating layer thickness to pass through optimization formulation for coating material On the basis of realized in conjunction with curtain coating with improving the uniformity of coating.In order to guarantee the homogeneity of surface light emitting, it is desirable that table Finishing coat is coated with more evenly, and at the same time, coating more evenly also can be reduced luminescent coating thickness, is connect based on this purpose is non- The profiling coating of touch is more advantageous to reduction coating layer thickness compared with the print roll coating and blade coating of contact.The curtain that the present invention uses Formula coating, by adjusting formulation for coating material, can operate coating solids range is 45-60%, far more than other contactless paintings Mode for cloth airblade coating and spraying coating can operate highest solid content, improve coating performability and production efficiency.
Maps with fluorescent colouring paper of the present invention compared with prior art, mainly there is following advantage: 1) the sunset glow time is long, hair Brightness is high, and folding strength is good, is suitable for printing;2) method that manufacturing process uses curtain coating, coating layer thickness is uniform, and surface is flat It is whole;3) coating process uses water paint, avoids destruction of the volatile organic matter (VOC) to environment.
Embodiment
The present invention will be further described with reference to the examples below, and embodiments of the present invention are not limited thereto.
Embodiment 1
By 10 parts of long lad phosphor, 5 parts of styrene-butadiene latex, 5 parts of polyurethane aqueous varnish, 0.5 part of CMC, curtain applies auxiliary agent 0.1 part of ratio mixed configuration obtains fluorescent paint, coating solids 55%: using the higher body paper of smoothness as body paper It is coated, coating layer thickness 90um obtains maps with fluorescent colouring paper.Its performance is as follows:
1 fluorescent brightness of table (1000Lx excites 1h)
Time/(min) 0 1 2 3 4 5 10
Fluorescent brightness/(cd.m-2) 4.6 0.536 0.291 0.192 0.143 0.118 0.055
Other performances of table 2
Xiao Baier folding strength (secondary) Ink absorption (%) Picking speed (m.s-1)
120 44.9 ≥3
Embodiment 2
By 10 parts of long lad phosphor, 8 parts of styrene-butadiene latex, 2 parts of polyurethane aqueous varnish, 1 part of CMC, 0.2 part of auxiliary agent Ratio mixed configuration obtains fluorescent paint, coating solids 59%;It is applied using the higher body paper of smoothness as body paper Cloth, coating layer thickness 90um obtain maps with fluorescent colouring paper.Its performance is as follows:
3 fluorescent brightness of table (1000Lx excites 1h)
Time/(min) 0 1 2 3 4 5 10
Fluorescent brightness/(cd.m-2) 4.5 0.533 0.275 0.182 0.135 0.108 0.05
Other performances of table 4
Xiao Baier folding strength (secondary) Ink absorption (%) Picking speed (m.s-1)
105 38.0 ≥3
Embodiment 3
By 10 parts of long lad phosphor, 5 parts of styrene-butadiene latex, 6 parts of polyurethane aqueous varnish, 0.5 part of CMC, 0.1 part of auxiliary agent Ratio mixed configuration obtain fluorescent paint, coating solids 58%;It is carried out using the higher body paper of smoothness as body paper Coating, coating layer thickness 120um obtain maps with fluorescent colouring paper.Its performance is as follows:
5 fluorescent brightness of table (1000Lx excites 1h)
Time/(min) 0 1 2 3 4 5 10
Fluorescent brightness/(cd.m-2) 5.57 0.661 0.35 0.235 0.176 0.14 0.067
Other performances of table 6
Xiao Baier folding strength (secondary) Ink absorption (%) Picking speed (m.s-1)
94 40.2 ≥3
The present invention is carried out according to above-mentioned specific embodiment, is achieved the desired results.

Claims (6)

1. the maps with fluorescent colouring paper and its manufacturing method of a kind of high folding strength, it is characterised in that: the maps with fluorescent colouring paper includes substrate And fluoresent coating, there is using the method for curtain coating in the substrate surface coating of pure white paper the fluorescence of overlength afterglow luminescent properties Coating.
2. the maps with fluorescent colouring paper and its manufacturing method of high folding strength according to claim 1, it is characterised in that the fluorescence Coating includes fluorescent powder, adhesive, auxiliary agent, composition specifically: 10 parts of fluorescent powder, 8-12 parts of adhesive, curtain apply auxiliary agent 0.1- 0.5 part.
3. the maps with fluorescent colouring paper and its manufacturing method of high folding strength according to claim 1, the fluorescent paint solid content For 45-60%.
4. the maps with fluorescent colouring paper and its manufacturing method of high folding strength according to claim 1, the thickness of the fluoresent coating For 70-120um.
5. the maps with fluorescent colouring paper and its manufacturing method of high folding strength according to claim 1, it is characterised in that described is glimmering Light powder is the alkaline earth aluminate salt long after glow luminous material by coating modification, partial size 0.1-30um.
6. the maps with fluorescent colouring paper and its manufacturing method of high folding strength according to claim 1, it is characterised in that the gluing Agent is Aqueous Adhesives, including two or three in styrene-butadiene latex, polyurethane aqueous varnish, carboxymethyl cellulose.
CN201811476492.6A 2018-12-05 2018-12-05 A kind of the maps with fluorescent colouring paper and its manufacturing method of high folding strength Pending CN109610235A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811476492.6A CN109610235A (en) 2018-12-05 2018-12-05 A kind of the maps with fluorescent colouring paper and its manufacturing method of high folding strength

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CN201811476492.6A CN109610235A (en) 2018-12-05 2018-12-05 A kind of the maps with fluorescent colouring paper and its manufacturing method of high folding strength

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1161689A (en) * 1997-08-05 1999-03-05 Oji Paper Co Ltd Pigment coated paper for printing with water repellency
JPH11130992A (en) * 1997-10-27 1999-05-18 Nippon Paint Co Ltd Luminous coating composition, method for forming luminous coating film, and luminous coated article
CN1817984A (en) * 2005-02-07 2006-08-16 吴振华 Light-storage luminescent coating and luminous fibre therefor
WO2008004810A1 (en) * 2006-07-04 2008-01-10 Kolon Glotech Inc. A high-visible cloth, a high-visible fluorescent/axis-lighting polyurethane film, and a method for preparation thereof
CN101463108A (en) * 2008-12-29 2009-06-24 西北师范大学 Organosilicon modified tert-fluoro emulsion and preparation of luminescent coating with the emulsion as base material
CN101691718A (en) * 2009-09-28 2010-04-07 广东轻工职业技术学院 Method for preparing long afterglow luminous paper
CN107189527A (en) * 2017-07-06 2017-09-22 上海大学 A kind of long afterglow waterproof luminous coating and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1161689A (en) * 1997-08-05 1999-03-05 Oji Paper Co Ltd Pigment coated paper for printing with water repellency
JPH11130992A (en) * 1997-10-27 1999-05-18 Nippon Paint Co Ltd Luminous coating composition, method for forming luminous coating film, and luminous coated article
CN1817984A (en) * 2005-02-07 2006-08-16 吴振华 Light-storage luminescent coating and luminous fibre therefor
WO2008004810A1 (en) * 2006-07-04 2008-01-10 Kolon Glotech Inc. A high-visible cloth, a high-visible fluorescent/axis-lighting polyurethane film, and a method for preparation thereof
CN101463108A (en) * 2008-12-29 2009-06-24 西北师范大学 Organosilicon modified tert-fluoro emulsion and preparation of luminescent coating with the emulsion as base material
CN101691718A (en) * 2009-09-28 2010-04-07 广东轻工职业技术学院 Method for preparing long afterglow luminous paper
CN107189527A (en) * 2017-07-06 2017-09-22 上海大学 A kind of long afterglow waterproof luminous coating and preparation method thereof

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