CN109608709A - A kind of nano automobile chair cover material and its manufacturing method - Google Patents
A kind of nano automobile chair cover material and its manufacturing method Download PDFInfo
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
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- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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Abstract
The present invention relates to automotive material field, a kind of nano automobile chair cover material and its manufacturing method are disclosed.Including base material and coating material, it discloses in terms of mass fraction, the ingredient of the raw material of base material, the ingredient of the raw material of coating material, further illustrate the manufacturing method of nano automobile chair cover material, and its specific steps, nano material is quasi- by making chair cover obtain the multiple functions such as waterproof, antifouling, grease proofing, antiultraviolet, high adsorption the functionalization of raw material and finishing method, nano material is realized fiber as additive and is modified, functional fiber/nano material composite fibre is prepared.Solve how nanoparticle preferably combines with textile realization, how solution, which is it, is evenly distributed in textile or fiber, so that it is formed good firm combination with fiber polymer, fabric, to guarantee the stability of product quality, durability, uniformity.
Description
Technical field
The present invention relates to automotive material field more particularly to a kind of nano automobile chair cover material and its manufacturing methods.
Background technique
With the continuous improvement of quality of the life, automobile is not only the tool ridden instead of walk, and consumer gradually pacifies vehicle as one
Entirely, popular, multiple functional " second family ".As family, it is desirable that automobile should safely, it is beautiful, comfortable, have one again
Fixed function and protective effect.Internal equipment of the Chair cover for automobile as automobile is collection water suction, dust suction, decontamination, sound insulation, protecting seat
The automotive trim parts that the major functions such as chair are integrated play a leading role to vapour environment inside car, have decorative and functional
Double grading.Functional chair cover is the main selection of current various vehicle seats.In the technology baseset of functional chair cover
Chair cover fabric product selection on, the country have patent right have flame retardant property, water proof anti-soil oil preventing performance, health
Can etc..Nanotechnology is applied on seat-cover fabric, is to use utilization achievement of the nanometer in textile industry.With nanometer
Water-proof and oil-proof, anti-fouling effect nano fabrics made of chair cover, patent of invention (application number CN201610174917.2) discloses
A kind of manufacture automotive seat applies composite material and preparation method, mainly for the intensity of chair cover, but without for antifouling
Aspect is studied, and utility model patent (application number CN201620445394.6) discloses a kind of antimicrobial chair cover, illustrates nanometer
Material load is main antibacterial using release anion progress on woven fabric, but waterproof, anti-pollution function do not count specifically
According to support, effect is not complete enough.
Summary of the invention
The present invention provides one kind for that cannot carry out Water-proof and oil-proof, antifouling disadvantage by nano material in the prior art
Nano automobile chair cover material and its manufacturing method.
In order to solve the above-mentioned technical problem, the present invention is addressed by following technical proposals:
A kind of nano automobile chair cover material, including base material and coating material,
In terms of mass fraction, the raw material of base material includes following component: 40~55 parts of butadiene rubber, butyl rubber 15~
20 parts, 15~30 parts of polycarbonate, 15~30 parts of polyacrylic fiber, 2~15 parts of white carbon black, 1~7 part of zinc oxide,
8~10 parts of alginate fibre, 5~6 parts of viscose rayon, 2~5 parts of dinitrosopentamethylene tetramine, 2- hydroxyl -4- methoxyl group hexichol
1~5 part of ketone, 3~9 parts of aluminium borate whisker, 0.1~0.5 part of unsaturated polyester resin, 0.5~1.8 part of titanium dioxide, asphalt mixtures modified by epoxy resin
0.1~0.5 part of rouge, 2~5 parts of zinc hydroxyl stannate, 1~3 part of Masterbatch, 1~2 part of 2,4-DihydroxyBenzophenone；
In terms of mass fraction, the raw material of coating material includes following component: 5~10 part, nanometer of nano-titanium dioxide poly- four
13~15 3~8 parts of part, nanometer triallyl fulminuric acid rouge of vinyl fluoride, 5~8 parts of nano indium oxide, nano zircite 2~4
Part, 3~10 parts of nanometer silicon carbide, 10~19 parts of crosslinking agent, 10~20 parts of polyamide glue, 15~30 parts of novolac epoxy resin
With 35~50 parts of organic siliconresin.Suitable raw material system is selected, textile raw material are carried out with the combination of different proportion, it will
Raw material after combination carry out polytechnic weaving, reach the chair cover of the function admirables such as comfort level, anti-flammability, pattern, material
Raw material
Preferably, nano-titanium dioxide, nanometer polytetrafluoroethylcomposite, nanometer triallyl fulminuric acid rouge, nano oxygen
Change indium, nanometer silicon carbide, nano zircite partial size be 50~100nm.
A kind of manufacturing method of nano automobile chair cover material, comprising the following steps:
A. 40~55 parts of butadiene rubber, 15~20 parts of butyl rubber, 15~30 parts of polycarbonate, polyacrylic acid are weighed
15~30 parts of ester fiber, 2~15 parts of white carbon black mixing, are added in mixer and plasticate；
B. 1~7 part of zinc oxide, 8~10 parts of alginate fibre, 5~6 parts of viscose rayon, dinitroso pentamethylene four are weighed
2~5 parts of amine, 1~5 part of ESCALOL 567,3~9 parts of the aluminium borate whisker mixers for sequentially adding step A
In plasticate；
C. 0.1~0.5 part of unsaturated polyester resin, 0.5~1.8 part of titanium dioxide, 0.1~0.5 part of epoxy resin, hydroxyl are weighed
2~5 parts of base zinc stannate, 1~3 part of Masterbatch, 1~2 part of 2,4-DihydroxyBenzophenone, mixing are added in the mixer of step B
The discharging that plasticate obtains base material；
D. 10~19 parts of crosslinking agent, 15~30 parts of novolac epoxy resin and 35~50 parts of organic siliconresin are mixed and heated to
75~90 DEG C, it is different to sequentially add 5~10 parts of nano-titanium dioxide, 13~15 part, nanometer triallyl of nanometer polytetrafluoroethylcomposite
3~8 parts of cyanurate, 5~8 parts of nano indium oxide, 2~4 parts of nano zircite, 3~10 parts of nanometer silicon carbide, polyamide resin
10~20 parts of rouge glue, coating material is configured to after being sufficiently mixed；
E. Coating material and be dried on base material, then be higher than minimum film formation temperature at a temperature of into
Row first time aging, then be higher than the glass transition temperature of water-based paint compositions at a temperature of carry out second of aging and obtain
To nano automobile chair cover material.
Preferably, nano-titanium dioxide, nanometer polytetrafluoroethylcomposite, nanometer triallyl fulminuric acid rouge, nano oxygen
Change indium, nanometer silicon carbide, nano zircite partial size be 50~100nm.
Preferably, the plasticating temperature of step A is 170~230 DEG C, the time of plasticating is 2~3 minutes.
Preferably, the plasticating temperature of step B is 175~235 DEG C, the time of plasticating is 30~60min.
Preferably, the plasticating temperature of step C is 125~155 DEG C, the time of plasticating is 10~15min.
The present invention has a significant technical effect due to using above technical scheme: nano material is quasi- by by raw material
Functionalization and finishing method so that chair cover is obtained waterproof, antifouling, grease proofing, antiultraviolet, the multiple functions such as high adsorption, by nanometer
Material realizes fiber as additive to be modified, and functional fiber/nano material composite fibre is prepared.It, will with coating technology
Nanoparticle is added in additive, it is then formed a kind of functional coating in fabric surface, to reach waterproof, prevent
The function of dirty, grease proofing, antiultraviolet, high adsorption.It solves how nanoparticle preferably combines with textile realization, solves such as
What is that it is evenly distributed in textile or fiber, it is made to form good firm combination with fiber polymer, fabric, thus
Guarantee stability, durability, the uniformity of product quality.
Specific embodiment
Below with reference to embodiment, present invention is further described in detail.
Embodiment 1
A kind of nano automobile chair cover material, including base material and coating material,
In terms of mass fraction, the raw material of base material includes following component: 40~55 parts of butadiene rubber, butyl rubber 15~
20 parts, 15~30 parts of polycarbonate, 15~30 parts of polyacrylic fiber, 2~15 parts of white carbon black, 1~7 part of zinc oxide,
8~10 parts of alginate fibre, 5~6 parts of viscose rayon, 2~5 parts of dinitrosopentamethylene tetramine, 2- hydroxyl -4- methoxyl group hexichol
1~5 part of ketone, 3~9 parts of aluminium borate whisker, 0.1~0.5 part of unsaturated polyester resin, 0.5~1.8 part of titanium dioxide, asphalt mixtures modified by epoxy resin
0.1~0.5 part of rouge, 2~5 parts of zinc hydroxyl stannate, 1~3 part of Masterbatch, 1~2 part of 2,4-DihydroxyBenzophenone；The present embodiment
In, 40 parts of butadiene rubber, 15 parts of butyl rubber, 15 parts of polycarbonate, 15 parts of polyacrylic fiber, 2 parts of white carbon black, oxygen
1 part of zinc of change, 8 parts of alginate fibre, 5 parts of viscose rayon, 2 parts of dinitrosopentamethylene tetramine, 2- hydroxyl -4- methoxyl group hexichol first
1 part of ketone, 3 parts of aluminium borate whisker, 0.1 part of unsaturated polyester resin, 0.5 part of titanium dioxide, 0.1 part of epoxy resin, zinc hydroxyl stannate 2
Part, 1 part of Masterbatch, 1 part of 2,4-DihydroxyBenzophenone.
In terms of mass fraction, the raw material of coating material includes following component: 5~10 part, nanometer of nano-titanium dioxide poly- four
13~15 3~8 parts of part, nanometer triallyl fulminuric acid rouge of vinyl fluoride, 5~8 parts of nano indium oxide, nano zircite 2~4
Part, 3~10 parts of nanometer silicon carbide, 10~19 parts of crosslinking agent, 10~20 parts of polyamide glue, 15~30 parts of novolac epoxy resin
With 35~50 parts of organic siliconresin.In the present embodiment, 5 parts of nano-titanium dioxide, 13 three allyl of part, nanometer of nanometer polytetrafluoroethylcomposite
3 parts of base fulminuric acid rouge, 5 parts of nano indium oxide, 2 parts of nano zircite, 3 parts of nanometer silicon carbide, 10 parts of crosslinking agent, polyamide
10 parts of resin glue, 15 parts of novolac epoxy resin and 35 parts of organic siliconresin.
In the present embodiment, nano-titanium dioxide, nanometer polytetrafluoroethylcomposite, nanometer triallyl fulminuric acid rouge, nanometer
Indium oxide, nanometer silicon carbide, nano zircite partial size be 50~100nm.Nano-titanium dioxide, nanometer are poly- in the present embodiment
Tetrafluoroethene, nanometer triallyl fulminuric acid rouge, nano indium oxide, nanometer silicon carbide, nano zircite partial size be
50nm。
Embodiment 2
A kind of nano automobile chair cover material, including base material and coating material,
In terms of mass fraction, the raw material of base material includes following component: 40~55 parts of butadiene rubber, butyl rubber 15~
20 parts, 15~30 parts of polycarbonate, 15~30 parts of polyacrylic fiber, 2~15 parts of white carbon black, 1~7 part of zinc oxide,
8~10 parts of alginate fibre, 5~6 parts of viscose rayon, 2~5 parts of dinitrosopentamethylene tetramine, 2- hydroxyl -4- methoxyl group hexichol
1~5 part of ketone, 3~9 parts of aluminium borate whisker, 0.1~0.5 part of unsaturated polyester resin, 0.5~1.8 part of titanium dioxide, asphalt mixtures modified by epoxy resin
0.1~0.5 part of rouge, 2~5 parts of zinc hydroxyl stannate, 1~3 part of Masterbatch, 1~2 part of 2,4-DihydroxyBenzophenone；The present embodiment
In, 47 parts of butadiene rubber, 18 parts of butyl rubber, 22 parts of polycarbonate, 22 parts of polyacrylic fiber, 9 parts of white carbon black, oxygen
4 parts of zinc of change, 9 parts of alginate fibre, 5.5 parts of viscose rayon, 3.5 parts of dinitrosopentamethylene tetramine, 2- hydroxyl -4- methoxyl group two
3 parts of Benzophenone, 6 parts of aluminium borate whisker, 0.3 part of unsaturated polyester resin, 1.1 parts of titanium dioxide, 0.3 part of epoxy resin, hydroxyl tin
3.5 parts of sour zinc, 2 parts of Masterbatch, 1.5 parts of 2,4-DihydroxyBenzophenone.
In terms of mass fraction, the raw material of coating material includes following component: 5~10 part, nanometer of nano-titanium dioxide poly- four
13~15 3~8 parts of part, nanometer triallyl fulminuric acid rouge of vinyl fluoride, 5~8 parts of nano indium oxide, nano zircite 2~4
Part, 3~10 parts of nanometer silicon carbide, 10~19 parts of crosslinking agent, 10~20 parts of polyamide glue, 15~30 parts of novolac epoxy resin
With 35~50 parts of organic siliconresin.In the present embodiment, 7.5 parts of nano-titanium dioxide, 14 part, nanometer triolefin of nanometer polytetrafluoroethylcomposite
5.5 parts of propyl fulminuric acid rouge, 6.5 parts of nano indium oxide, 3 parts of nano zircite, 6.5 parts of nanometer silicon carbide, crosslinking agent 14
Part, 15 parts of polyamide glue, 22 parts of novolac epoxy resin and 42 parts of organic siliconresin.
In the present embodiment, nano-titanium dioxide, nanometer polytetrafluoroethylcomposite, nanometer triallyl fulminuric acid rouge, nanometer
Indium oxide, nanometer silicon carbide, nano zircite partial size be 50~100nm.Nano-titanium dioxide, nanometer are poly- in the present embodiment
Tetrafluoroethene, nanometer triallyl fulminuric acid rouge, nano indium oxide, nanometer silicon carbide, nano zircite partial size be
75nm。
Embodiment 3
A kind of nano automobile chair cover material, including base material and coating material,
In terms of mass fraction, the raw material of base material includes following component: 40~55 parts of butadiene rubber, butyl rubber 15~
20 parts, 15~30 parts of polycarbonate, 15~30 parts of polyacrylic fiber, 2~15 parts of white carbon black, 1~7 part of zinc oxide,
8~10 parts of alginate fibre, 5~6 parts of viscose rayon, 2~5 parts of dinitrosopentamethylene tetramine, 2- hydroxyl -4- methoxyl group hexichol
1~5 part of ketone, 3~9 parts of aluminium borate whisker, 0.1~0.5 part of unsaturated polyester resin, 0.5~1.8 part of titanium dioxide, asphalt mixtures modified by epoxy resin
0.1~0.5 part of rouge, 2~5 parts of zinc hydroxyl stannate, 1~3 part of Masterbatch, 1~2 part of 2,4-DihydroxyBenzophenone；The present embodiment
In, 55 parts of butadiene rubber, 20 parts of butyl rubber, 30 parts of polycarbonate, 30 parts of polyacrylic fiber, 15 parts of white carbon black,
7 parts of zinc oxide, 10 parts of alginate fibre, 6 parts of viscose rayon, 5 parts of dinitrosopentamethylene tetramine, 2- hydroxyl -4- methoxyl group two
5 parts of Benzophenone, 9 parts of aluminium borate whisker, 0.5 part of unsaturated polyester resin, 1.8 parts of titanium dioxide, 0.5 part of epoxy resin, hydroxyl tin
5 parts of sour zinc, 3 parts of Masterbatch, 2 parts of 2,4-DihydroxyBenzophenone.
In terms of mass fraction, the raw material of coating material includes following component: 5~10 part, nanometer of nano-titanium dioxide poly- four
13~15 3~8 parts of part, nanometer triallyl fulminuric acid rouge of vinyl fluoride, 5~8 parts of nano indium oxide, nano zircite 2~4
Part, 3~10 parts of nanometer silicon carbide, 10~19 parts of crosslinking agent, 10~20 parts of polyamide glue, 15~30 parts of novolac epoxy resin
With 35~50 parts of organic siliconresin.In the present embodiment, 10 parts of nano-titanium dioxide, 15 part, nanometer triolefin of nanometer polytetrafluoroethylcomposite
8 parts of propyl fulminuric acid rouge, 4 parts of nano zircite, 10 parts of nanometer silicon carbide, 19 parts of crosslinking agent, gathers 8 parts of nano indium oxide
20 parts of amide resin glue, 30 parts of novolac epoxy resin and 50 parts of organic siliconresin.
In the present embodiment, nano-titanium dioxide, nanometer polytetrafluoroethylcomposite, nanometer triallyl fulminuric acid rouge, nanometer
Indium oxide, nanometer silicon carbide, nano zircite partial size be 50~100nm.Nano-titanium dioxide, nanometer are poly- in the present embodiment
Tetrafluoroethene, nanometer triallyl fulminuric acid rouge, nano indium oxide, nanometer silicon carbide, nano zircite partial size be
100nm。
Embodiment 4
A kind of manufacturing method of nano automobile chair cover material, comprising the following steps:
A. 40~55 parts of butadiene rubber, 15~20 parts of butyl rubber, 15~30 parts of polycarbonate, polyacrylic acid are weighed
15~30 parts of ester fiber, 2~15 parts of white carbon black mixing, are added in mixer and plasticate；
B. 1~7 part of zinc oxide, 8~10 parts of alginate fibre, 5~6 parts of viscose rayon, dinitroso pentamethylene four are weighed
2~5 parts of amine, 1~5 part of ESCALOL 567,3~9 parts of the aluminium borate whisker mixers for sequentially adding step A
In plasticate；
C. 0.1~0.5 part of unsaturated polyester resin, 0.5~1.8 part of titanium dioxide, 0.1~0.5 part of epoxy resin, hydroxyl are weighed
2~5 parts of base zinc stannate, 1~3 part of Masterbatch, 1~2 part of 2,4-DihydroxyBenzophenone, mixing are added in the mixer of step B
The discharging that plasticate obtains base material；
D. 10~19 parts of crosslinking agent, 15~30 parts of novolac epoxy resin and 35~50 parts of organic siliconresin are mixed and heated to
75~90 DEG C, it is different to sequentially add 5~10 parts of nano-titanium dioxide, 13~15 part, nanometer triallyl of nanometer polytetrafluoroethylcomposite
3~8 parts of cyanurate, 5~8 parts of nano indium oxide, 2~4 parts of nano zircite, 3~10 parts of nanometer silicon carbide, polyamide resin
10~20 parts of rouge glue, coating material is configured to after being sufficiently mixed；
E. Coating material and be dried on base material, then be higher than minimum film formation temperature at a temperature of into
Row first time aging, then be higher than the glass transition temperature of water-based paint compositions at a temperature of carry out second of aging and obtain
To nano automobile chair cover material.
Nano-titanium dioxide, nanometer polytetrafluoroethylcomposite, nanometer triallyl fulminuric acid rouge, nano indium oxide, nanometer
Silicon carbide, nano zircite partial size be 50~100nm.In the present embodiment, nano-titanium dioxide, nanometer polytetrafluoroethylcomposite,
Nanometer triallyl fulminuric acid rouge, nano indium oxide, nanometer silicon carbide, nano zircite partial size be 50nm.
The plasticating temperature of step A is 170~230 DEG C, and the time of plasticating is 2~3 minutes.In the present embodiment, step A's plasticates
Temperature is 170 DEG C, and the time of plasticating is 2 minutes.
The plasticating temperature of step B is 175~235 DEG C, and the time of plasticating is 30~60min.In the present embodiment, the modeling of step B
Refining temperature is 175 DEG C, and the time of plasticating is 30min.
The plasticating temperature of step C is 125~155 DEG C, and the time of plasticating is 10~15min.In the present embodiment, the modeling of step C
Refining temperature is 125 DEG C, and the time of plasticating is 10min.
In the present embodiment, crosslinking agent, novolac epoxy resin and organic siliconresin part are mixed and heated to 75 DEG C by step D.
In the present embodiment, 40 parts of butadiene rubber, 15 parts of butyl rubber, 15 parts of polycarbonate, polyacrylic fiber
15 parts, 2 parts of white carbon black, 1 part of zinc oxide, 8 parts of alginate fibre, 5 parts of viscose rayon, 2 parts of dinitrosopentamethylene tetramine, 2- hydroxyl
1 part of base -4- methoxy benzophenone, 3 parts of aluminium borate whisker, 0.1 part of unsaturated polyester resin, 0.5 part of titanium dioxide, epoxy resin
0.1 part, 2 parts of zinc hydroxyl stannate, 1 part of Masterbatch, 1 part of 2,4-DihydroxyBenzophenone.5 part, nanometer of nano-titanium dioxide poly- four
13 3 parts of part, nanometer triallyl fulminuric acid rouge of vinyl fluoride, 5 parts of nano indium oxide, 2 parts of nano zircite, nanometer silicon carbide
3 parts, 10 parts of crosslinking agent, 10 parts of polyamide glue, 15 parts of novolac epoxy resin and 35 parts of organic siliconresin.
Embodiment 5
A kind of manufacturing method of nano automobile chair cover material, comprising the following steps:
A. 40~55 parts of butadiene rubber, 15~20 parts of butyl rubber, 15~30 parts of polycarbonate, polyacrylic acid are weighed
15~30 parts of ester fiber, 2~15 parts of white carbon black mixing, are added in mixer and plasticate；
B. 1~7 part of zinc oxide, 8~10 parts of alginate fibre, 5~6 parts of viscose rayon, dinitroso pentamethylene four are weighed
2~5 parts of amine, 1~5 part of ESCALOL 567,3~9 parts of the aluminium borate whisker mixers for sequentially adding step A
In plasticate；
C. 0.1~0.5 part of unsaturated polyester resin, 0.5~1.8 part of titanium dioxide, 0.1~0.5 part of epoxy resin, hydroxyl are weighed
2~5 parts of base zinc stannate, 1~3 part of Masterbatch, 1~2 part of 2,4-DihydroxyBenzophenone, mixing are added in the mixer of step B
The discharging that plasticate obtains base material；
D. 10~19 parts of crosslinking agent, 15~30 parts of novolac epoxy resin and 35~50 parts of organic siliconresin are mixed and heated to
75~90 DEG C, it is different to sequentially add 5~10 parts of nano-titanium dioxide, 13~15 part, nanometer triallyl of nanometer polytetrafluoroethylcomposite
3~8 parts of cyanurate, 5~8 parts of nano indium oxide, 2~4 parts of nano zircite, 3~10 parts of nanometer silicon carbide, polyamide resin
10~20 parts of rouge glue, coating material is configured to after being sufficiently mixed；
E. Coating material and be dried on base material, then be higher than minimum film formation temperature at a temperature of into
Row first time aging, then be higher than the glass transition temperature of water-based paint compositions at a temperature of carry out second of aging and obtain
To nano automobile chair cover material.
Nano-titanium dioxide, nanometer polytetrafluoroethylcomposite, nanometer triallyl fulminuric acid rouge, nano indium oxide, nanometer
Silicon carbide, nano zircite partial size be 50~100nm.In the present embodiment, nano-titanium dioxide, nanometer polytetrafluoroethylcomposite,
Nanometer triallyl fulminuric acid rouge, nano indium oxide, nanometer silicon carbide, nano zircite partial size be 50~100nm.
The plasticating temperature of step A is 170~230 DEG C, and the time of plasticating is 2~3 minutes.In the present embodiment, step A's plasticates
Temperature is 200 DEG C, and the time of plasticating is 2.5 minutes.
The plasticating temperature of step B is 175~235 DEG C, and the time of plasticating is 30~60min.In the present embodiment, the modeling of step B
Refining temperature is 200 DEG C, and the time of plasticating is 45min.
The plasticating temperature of step C is 125~155 DEG C, and the time of plasticating is 10~15min.In the present embodiment, the modeling of step C
Refining temperature is 140 DEG C, and the time of plasticating is 12min.
In the present embodiment, crosslinking agent, novolac epoxy resin and organic siliconresin part are mixed and heated to 82 DEG C by step D.
In the present embodiment, 47 parts of butadiene rubber, 18 parts of butyl rubber, 22 parts of polycarbonate, polyacrylic fiber
22 parts, 9 parts of white carbon black, 4 parts of zinc oxide, 9 parts of alginate fibre, 5.5 parts of viscose rayon, 3.5 parts of dinitrosopentamethylene tetramine,
3 parts of ESCALOL 567,6 parts of aluminium borate whisker, 0.3 part of unsaturated polyester resin, 1.1 parts of titanium dioxide, epoxy
0.3 part of resin, 3.5 parts of zinc hydroxyl stannate, 2 parts of Masterbatch, 1.5 parts of 2,4-DihydroxyBenzophenone, nano-titanium dioxide 7.5
It is part, 14 5.5 parts of part, nanometer triallyl fulminuric acid rouge of nanometer polytetrafluoroethylcomposite, 6.5 parts of nano indium oxide, nano oxidized
3 parts of zirconium, 6.5 parts of nanometer silicon carbide, 14 parts of crosslinking agent, 15 parts of polyamide glue, 22 parts of novolac epoxy resin and organosilicon tree
42 parts of rouge.
Embodiment 6
A kind of manufacturing method of nano automobile chair cover material, comprising the following steps:
A. 40~55 parts of butadiene rubber, 15~20 parts of butyl rubber, 15~30 parts of polycarbonate, polyacrylic acid are weighed
15~30 parts of ester fiber, 2~15 parts of white carbon black mixing, are added in mixer and plasticate；
B. 1~7 part of zinc oxide, 8~10 parts of alginate fibre, 5~6 parts of viscose rayon, dinitroso pentamethylene four are weighed
2~5 parts of amine, 1~5 part of ESCALOL 567,3~9 parts of the aluminium borate whisker mixers for sequentially adding step A
In plasticate；
C. 0.1~0.5 part of unsaturated polyester resin, 0.5~1.8 part of titanium dioxide, 0.1~0.5 part of epoxy resin, hydroxyl are weighed
2~5 parts of base zinc stannate, 1~3 part of Masterbatch, 1~2 part of 2,4-DihydroxyBenzophenone, mixing are added in the mixer of step B
The discharging that plasticate obtains base material；
D. 10~19 parts of crosslinking agent, 15~30 parts of novolac epoxy resin and 35~50 parts of organic siliconresin are mixed and heated to
75~90 DEG C, it is different to sequentially add 5~10 parts of nano-titanium dioxide, 13~15 part, nanometer triallyl of nanometer polytetrafluoroethylcomposite
3~8 parts of cyanurate, 5~8 parts of nano indium oxide, 2~4 parts of nano zircite, 3~10 parts of nanometer silicon carbide, polyamide resin
10~20 parts of rouge glue, coating material is configured to after being sufficiently mixed；
E. Coating material and be dried on base material, then be higher than minimum film formation temperature at a temperature of into
Row first time aging, then be higher than the glass transition temperature of water-based paint compositions at a temperature of carry out second of aging and obtain
To nano automobile chair cover material.
Nano-titanium dioxide, nanometer polytetrafluoroethylcomposite, nanometer triallyl fulminuric acid rouge, nano indium oxide, nanometer
Silicon carbide, nano zircite partial size be 50~100nm.In the present embodiment, nano-titanium dioxide, nanometer polytetrafluoroethylcomposite,
Nanometer triallyl fulminuric acid rouge, nano indium oxide, nanometer silicon carbide, nano zircite partial size be 50~100nm.
The plasticating temperature of step A is 170~230 DEG C, and the time of plasticating is 2~3 minutes.In the present embodiment, step A's plasticates
Temperature is 230 DEG C, and the time of plasticating is 3 minutes.
The plasticating temperature of step B is 175~235 DEG C, and the time of plasticating is 30~60min.In the present embodiment, the modeling of step B
Refining temperature is 235 DEG C, and the time of plasticating is 60min.
The plasticating temperature of step C is 125~155 DEG C, and the time of plasticating is 10~15min.In the present embodiment, the modeling of step C
Refining temperature is 155 DEG C, and the time of plasticating is 15min.
In the present embodiment, crosslinking agent, novolac epoxy resin and organic siliconresin part are mixed and heated to 90 DEG C by step D.
In the present embodiment, 55 parts of butadiene rubber, 20 parts of butyl rubber, 30 parts of polycarbonate, polyacrylic fiber
30 parts, 15 parts of white carbon black, 7 parts of zinc oxide, 10 parts of alginate fibre, 6 parts of viscose rayon, 5 parts of dinitrosopentamethylene tetramine, 2-
5 parts of hydroxyl -4- methoxy benzophenone, 9 parts of aluminium borate whisker, 0.5 part of unsaturated polyester resin, 1.8 parts of titanium dioxide, asphalt mixtures modified by epoxy resin
0.5 part of rouge, 5 parts of zinc hydroxyl stannate, 3 parts of Masterbatch, 2 parts of 2,4-DihydroxyBenzophenone.
In terms of mass fraction, the raw material of coating material includes following component: 5~10 part, nanometer of nano-titanium dioxide poly- four
13~15 3~8 parts of part, nanometer triallyl fulminuric acid rouge of vinyl fluoride, 5~8 parts of nano indium oxide, nano zircite 2~4
Part, 3~10 parts of nanometer silicon carbide, 10~19 parts of crosslinking agent, 10~20 parts of polyamide glue, 15~30 parts of novolac epoxy resin
With 35~50 parts of organic siliconresin, 10 parts of nano-titanium dioxide, the 15 different melamine of part, nanometer triallyl of nanometer polytetrafluoroethylcomposite
8 parts of sour rouge, 8 parts of nano indium oxide, 4 parts of nano zircite, 10 parts of nanometer silicon carbide, 19 parts of crosslinking agent, polyamide glue 20
Part, 30 parts of novolac epoxy resin and 50 parts of organic siliconresin.
Embodiment 7
The parameter for the Chair cover for automobile material that measurement embodiment 1-6 is obtained, obtains following data:
Thermal coefficient: between 0.04-0.07W (m.k)
Staining: PV3353, contrast are equivalent to the progressive series of greys, grade >=2.0
Antibiotic property: FZ/T73023-2015, antibacterial bandwidth D≤5MM
Grease proofness: 5-6 grades before washing, 4-5 grades after 30 washings
Waterproofness: first 100 points, 80 points after 30 washings are washed
Hydrophobic performance: PV3922 gos deep into 15 minutes without droplet
Anti-flammability: GB8410≤100mm/min
Antiultraviolet: UPF value > 400, average transmittance: < 5%
Tensile strength: 1681MPa
Bending strength: 358MPa
By data as it can be seen that the application will solve the uniformity and degree of adhesion of coating due to passing through nano coating technology.It solves
Water-proof and oil-proof after nano coating technology, antifouling protective capacities.Reach Chinese GB/T4745, GB/T19977 testing standard and
U.S. AATCC 22,118 testing standard of AATCC.The dehorn index for solving three proofings product meets the green reason of current market environment
It reads, small to environment and human body harm while protection or even zero harm.
In short, the foregoing is merely presently preferred embodiments of the present invention, it is all according to equalization made by scope of the present invention patent
Variation and modification, shall all be covered by the patent of the invention.
Claims (7)
1. a kind of nano automobile chair cover material, including base material and coating material, which is characterized in that
In terms of mass fraction, the raw material of base material includes following component: 40~55 parts of butadiene rubber, butyl rubber 15~20
Part, 15~30 parts of polycarbonate, 15~30 parts of polyacrylic fiber, 2~15 parts of white carbon black, 1~7 part of zinc oxide, sea
8~10 parts of algae fiber, 5~6 parts of viscose rayon, 2~5 parts of dinitrosopentamethylene tetramine, 2- hydroxyl -4- methoxyl group hexichol first
1~5 part of ketone, 3~9 parts of aluminium borate whisker, 0.1~0.5 part of unsaturated polyester resin, 0.5~1.8 part of titanium dioxide, epoxy resin
0.1~0.5 part, 2~5 parts of zinc hydroxyl stannate, 1~3 part of Masterbatch, 1~2 part of 2,4-DihydroxyBenzophenone；
In terms of mass fraction, the raw material of coating material includes following component: 5~10 part, nanometer polytetrafluoroethyl-ne of nano-titanium dioxide
13~15 3~8 parts of part, nanometer triallyl fulminuric acid rouge of alkene, 5~8 parts of nano indium oxide, 2~4 parts of nano zircite,
3~10 parts of nanometer silicon carbide, 10~19 parts of crosslinking agent, 10~20 parts of polyamide glue, 15~30 parts of novolac epoxy resin and
35~50 parts of organic siliconresin.
2. a kind of nano automobile chair cover material according to claim 1, it is characterised in that: nano-titanium dioxide, nanometer are poly-
Tetrafluoroethene, nanometer triallyl fulminuric acid rouge, nano indium oxide, nanometer silicon carbide, nano zircite partial size be
50~100nm.
3. a kind of manufacturing method of nano automobile chair cover material, which comprises the following steps:
A. it is fine that 40~55 parts of butadiene rubber, 15~20 parts of butyl rubber, 15~30 parts of polycarbonate, polyacrylate are weighed
15~30 parts of dimension, 2~15 parts of white carbon black mixing, are added in mixer and plasticate；
B. weigh 1~7 part of zinc oxide, 8~10 parts of alginate fibre, 5~6 parts of viscose rayon, dinitrosopentamethylene tetramine 2~
5 parts, 1~5 part of ESCALOL 567, carry out in 3~9 parts of the aluminium borate whisker mixers for sequentially adding step A
It plasticates；
C. 0.1~0.5 part of unsaturated polyester resin, 0.5~1.8 part of titanium dioxide, 0.1~0.5 part of epoxy resin, hydroxyl tin are weighed
2~5 parts of sour zinc, 1~3 part of Masterbatch, 1~2 part of 2,4-DihydroxyBenzophenone, mixing are added in the mixer of step B and carry out
Discharging of plasticating obtains base material；
D. 10~19 parts of crosslinking agent, 15~30 parts of novolac epoxy resin and 35~50 parts of organic siliconresin are mixed and heated to 75~
90 DEG C, sequentially add 5~10 parts of nano-titanium dioxide, 13~15 different trimerization of part, nanometer triallyl of nanometer polytetrafluoroethylcomposite
3~8 parts of cyanate ester, 5~8 parts of nano indium oxide, 2~4 parts of nano zircite, 3~10 parts of nanometer silicon carbide, polyamide glue
10~20 parts, coating material is configured to after being sufficiently mixed；
E. Coating material and be dried on base material, then be higher than minimum film formation temperature at a temperature of carry out the
Aging, then be higher than the glass transition temperature of water-based paint compositions at a temperature of carry out second of aging and received
Rice Chair cover for automobile material.
4. a kind of manufacturing method of nano automobile chair cover material according to claim 3, it is characterised in that: nanometer titanium dioxide
Titanium, nanometer polytetrafluoroethylcomposite, nanometer triallyl fulminuric acid rouge, nano indium oxide, nanometer silicon carbide, nano zircite
Partial size is 50~100nm.
5. a kind of manufacturing method of nano automobile chair cover material according to claim 3, it is characterised in that: the modeling of step A
Refining temperature is 170~230 DEG C, and the time of plasticating is 2~3 minutes.
6. a kind of manufacturing method of nano automobile chair cover material according to claim 3, it is characterised in that: the modeling of step B
Refining temperature is 175~235 DEG C, and the time of plasticating is 30~60min.
7. a kind of manufacturing method of nano automobile chair cover material according to claim 3, it is characterised in that: the modeling of step C
Refining temperature is 125~155 DEG C, and the time of plasticating is 10~15min.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110903520A (en) * | 2019-11-22 | 2020-03-24 | 浙江海啊汽车用品有限公司 | Color-changing bionic automobile seat cover material and manufacturing method thereof |
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