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CN109553352A - High-intensity fiber composite material and its preparation method for decoration element - Google Patents

High-intensity fiber composite material and its preparation method for decoration element Download PDF

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Publication number
CN109553352A
CN109553352A CN201811595078.7A CN201811595078A CN109553352A CN 109553352 A CN109553352 A CN 109553352A CN 201811595078 A CN201811595078 A CN 201811595078A CN 109553352 A CN109553352 A CN 109553352A
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China
Prior art keywords
fiber composite
composite material
agent
water
intensity fiber
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Pending
Application number
CN201811595078.7A
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Chinese (zh)
Inventor
薛兴勇
宋敦清
张科
韦锦长
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GUANGXI QINGLONG CHEMICAL BUILDING MATERIAL CO Ltd
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GUANGXI QINGLONG CHEMICAL BUILDING MATERIAL CO Ltd
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Priority to CN201811595078.7A priority Critical patent/CN109553352A/en
Publication of CN109553352A publication Critical patent/CN109553352A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of high-intensity fiber composite materials, comprise the following raw materials by weight percent: cement 30-50%, graded sand 40-60%, active reinforcing agent 5-15%, fibrous material 1-10%, filler 2-8%, pigment 0-2%, wood fibre 0.05-0.2%, water-retaining agent 0.05-0.2%, defoaming agent 0.05-0.1%, water-reducing agent 0.2%-2%, high molecular material 0.1-1%, retarder 0-0.2%, thixotropic lubricant 0.05-0.3%.Accordingly, inventor has also set up preparation method of the corresponding high-intensity fiber composite material for decoration element.High-intensity fiber composite products of the invention have the characteristics that intensity is high, environmentally protective, safety is good, good weatherability, have a wide range of application, and overcome the deficiencies of prior art the long duration strenth is poor, appearance colour is single, application range is narrow.

Description

High-intensity fiber composite material and its preparation method for decoration element
Technical field
The invention belongs to architectural decoration material field more particularly to a kind of high-intensity fiber composite material and its for decorating structure The preparation method of part.
Background technique
Building industrialization is using the production of element precast metaplasia, fabricated construction as production method, with design standard, component portion Product, mechanization of building operation are characterized, can the entire industrial chain such as Integration Design, production, construction realize building products energy conservation, ring It protects, the novel building production method of the sustainable development of Life cycle value maximization.The meaning for developing building industrialization exists In can Accelerating The Construction speed, reduce existing labor intensity, reduce manpower consumption, improve construction quality and labor productivity, build Building industrialization represents low-carbon, energy conservation, economizing type construction.
It proposes " to greatly develop assembled architecture, push industry restructuring liter in the Executive Meeting of the State Council of in September, 2016 Grade ", assembled architecture development have gone up as state basic policy, cause great attention of the various circles of society to assembled architecture.But assembled Product technology and management disunity in architectural engineering process of construction, the problems such as production efficiency and benefit are low, still restrict its hair Exhibition, wherein assembled architecture is greatly developed in the design studies and exploitation of the prefabricated concrete component of high-performance high standard Key is the guarantee for guaranteeing assembled architecture and making smooth advances.
The prefabricated components of concrete are common components in civil buildings, and output is very big, it is high-quality be badly related to The life and property safety of the safety of building structure and vast common people, if design is unreasonable, construction management is not stringent, product Off quality, severe compromise will be occurred by being installed in building.Since modern architecture is to high stratification, large span and heteromorphosis Stride forward, common precast concrete is difficult to meet application requirement.In recent years, with the development of assembled architecture, high standard Prefabricated components become research and development emphasis, wherein research of the high-strength and high performance fibrous composite in precast concrete The trend of future development is had become with application.
Application No. is the patent of invention of 201810120512.X, to disclose a kind of high-speed railway Reactive Powder Concrete prefabricated Component and preparation method thereof, material compression strength 137-148MPa or so, flexural strength 19-22MPa or so.Application No. is 201610078370.6 patent of invention disclose a kind of inorganic high performance composites decorative panel and preparation method thereof, Material compression strength 126-152MPa.The purpose of two patents is that powder concrete is applied to precast concrete, used Steel fiber material is used only in fiber, and is only applicable to prepare the prefabricated decoration element material of achromaticity class.
Application No. is 201611158222.1 patents of invention to disclose a kind of high performance composites and its preparation Method, application No. is 201410023331.7 patents of invention to disclose a kind of preparation side of high performance composites product Method, two patents all refer to fiber-reinforced resin, but do not provide the mechanical property of its material.
Application No. is 201820528614.5 patents of invention to disclose a kind of Portland cement base glass fiber reinforcement water Mud material and preparation method thereof, it uses glass fiber reinforced cement, and bending strength 10.9MPa-12.7MPa is not able to satisfy To GRC material high grade mark in " JGJ/T 423-2018 glass fiber reinforced cement (GRC) Application in Building technical standard " Quasi- requirement (15MPa and 18MPa strength grade).
Summary of the invention
That the technical problem to be solved in the present invention is to provide a kind of intensity is high, environmentally protective, safety is good, good weatherability, answers With the wide high-intensity fiber composite material of range and its for the preparation method of decoration element.
In order to solve the above technical problems, the invention adopts the following technical scheme:
High-intensity fiber composite material, comprises the following raw materials by weight percent: cement 30-50%, graded sand 40- 60%, active reinforcing agent 5-15%, fibrous material 1-10%, filler 2-8%, pigment 0-2%, wood fibre 0.05-0.2%, Water-retaining agent 0.05-0.2%, defoaming agent 0.05-0.1%, water-reducing agent 0.2%-2%, high molecular material 0.1-1%, retarder 0- 0.2%, thixotropic lubricant 0.05-0.3%.
Cement is ordinary portland cement or white portland cement;Graded sand is common quartz sand or white quartz sand; Active reinforcing agent is common silicon ash or white silicon ash;Filler is flyash, steel-making slag powder or heavy calcium carbonate;Water-retaining agent is low viscous Spend hydroxypropyl methyl cellulose ether.
Cement is the white silicon that 42.5 strength grade ordinary portland cements or 52.5 strength grades and whiteness are greater than 87% Acid salt cement;Graded sand is that dioxide-containing silica is greater than 96%, the common quartz sand of 40-100 purpose or white quartz sand;Activity increases Strong agent is that specific surface area is greater than 800m2The common silicon ash of/Kg, dioxide-containing silica greater than 90% or white silicon ash;Filler be than Surface area is greater than 400m2Flyash, steel-making slag powder or the heavy calcium carbonate of/kg;The average length of wood fibre is less than 500 μm; Water-retaining agent is low-viscosity hydroxypropylmethylc,llulose ether.
Fibrous material is one or more of steel fibre, carbon fiber, alkali-resistant glass fibre;Pigment is inorganic pigment; Defoaming agent is powdery defoaming agent;Water-reducing agent is modified polycarboxylic acid ethers powdery water-reducing agent;High molecular material is vinyl acetate-ethylene Copolymer emulsion;Retarder is citrate;Thixotropic lubricant is laminar silicic acid salt thixotropic lubricant.
Inorganic pigment is iron oxide red, iron oxide black, iron oxide yellow, cologne earth, cobalt blue or chrome green etc.;Powdery defoaming agent is liquid hydrocarbon The mixture of object, polyethylene glycol and inorganic carrier composition.
Above-mentioned high-intensity fiber composite material is used for the preparation method of decoration element, makes molding previously according to layout design Mold according to the ratio stirs evenly the raw material of high-intensity fiber composite material, by pouring or injection molding answers high-intensity fiber Condensation material injects mold, then demoulds, conserves and is surface-treated up to decoration element.
Mold is fiber reinforced plastic mold, wood mould, silica gel mould or steel mold.
Raw material stirring is carried out by following operation: water is put into blender, the addition of liquid type raw material is stirred evenly, then Slowly add powder by the suitable ratio of mud, then stirs into uniform thick shape slurry, stand.
Maintenance is conserved using showering curing or vapor.
Existing defect is applied in decoration element for traditional high-intensity fiber composite material, inventor has developed a kind of high Strong fibrous composite, comprises the following raw materials by weight percent: cement 30-50%, graded sand 40-60%, increased activity Agent 5-15%, fibrous material 1-10%, filler 2-8%, pigment 0-2%, wood fibre 0.05-0.2%, water-retaining agent 0.05- 0.2%, defoaming agent 0.05-0.1%, water-reducing agent 0.2%-2%, high molecular material 0.1-1%, retarder 0-0.2%, thixotroping profit Lubrication prescription 0.05-0.3%.Accordingly, inventor has also set up preparation side of the corresponding high-intensity fiber composite material for decoration element Method.High-intensity fiber composite products of the invention are with intensity is high, environmentally protective, safety is good, good weatherability, application range Wide feature overcomes the deficiencies of prior art the long duration strenth is poor, appearance colour is single, application range is narrow.Specifically, this hair Bright outstanding advantage is shown:
1, according to designing and applying needs, the strength of materials is easy to adjust, and compression strength can be adjusted between 100-200MPa, Bending strength can be adjusted between 10-30MPa;
2, material color is adjustable, by selecting high-intensitive white cement, white silicon ash and other additives, can prepare High performance polychromy component out;
3, break the mode of conventional Single Fiber, compounding fiber may be selected, fiber is made to achieve the purpose that collaboration enhancing;
4, it by adjusting strength and Exterior color of products, in addition the compression strength of material is higher, can be filled using as load-bearing Component is adornd, application range is wider, and bigger design space is provided for designer;
5, the industrial solid wastes such as flyash and steel-making slag powder can be added in material, are turned waste into wealth, and national energy conservation and emission reduction is met Policy.
Specific embodiment
The raw material ratio composition of following embodiment high-intensity fiber composite material is shown in Table 1.
1 embodiment 1-6 raw material ratio of table
In table 1, cement is 42.5 strength grade ordinary portland cements or 52.5 strength grades and whiteness is greater than 87% White portland cement;Graded sand is that dioxide-containing silica is greater than 96%, the common quartz sand of 40-100 purpose or white quartz sand; Active reinforcing agent is that specific surface area is greater than 800m2The common silicon ash of/Kg, dioxide-containing silica greater than 90% or white silicon ash;It fills out Material is that specific surface area is greater than 400m2Flyash, steel-making slag powder or the heavy calcium carbonate (dicalcium powder) of/kg;Wood fibre is averaged Length is less than 500 μm;Water-retaining agent is low-viscosity hydroxypropylmethylc,llulose ether (Samsung chemical company, South Korea hydroxypropyl methyl fiber ElementPMC-30US)。
Defoaming agent is powdery defoaming agent (German AGITAN P803 powder defoaming agent);Water-reducing agent is modified polycarboxylic acid ethers Powdery water-reducing agent (BASF AG's 2651F high efficiency water reducing agent);High molecular material is vinyl acetate-ethylene copolymerization emulsions (Germany 558 ED lotion of Wa Ke company VINNAPAS);Retarder is sodium citrate;Thixotropic lubricant is laminar silicic acid salt thixotroping profit Lubrication prescription (German ROCKWOOD company987 thixotropic lubricants).
Embodiment 1
High-intensity fiber composite material and decoration element are prepared by the raw material proportioning of 1 embodiment 1 of table, the specific steps are as follows:
<1>Silicon moulds are made according to design drawing;
<2>mold basal plane is checked, it is ensured that smooth, clear patterns, and brushing release agent;
<3>material stirs: agitated kettle is poured by the good clear water of 0.15 precise of the ratio of mud, by water-reducing agent, wood fibre, fibre Plain ether, defoaming agent, water-reducing agent, latex powder, retarder, thixotropic lubricant is tieed up to be proportionally added into and stir evenly, then be proportionally added into 52.5 white cements, white silicon ash and dicalcium powder stir evenly, and are finally proportionally added into white quartz sand, carbon fiber and glass fibre It is uniformly mixing to obtain a kind of thick shape slurry of high-intensity fiber composite material;
<4>the above-mentioned slurry stirred evenly is added to the Silicon moulds in<2>, guarantees slurry dense packing effect in mold;
It is demoulded after<5>24 hours, natural curing 3 days, appropriate water drenching processing;
<6>it is surface-treated: checking the smooth degree of component surface, part suitably polish up to decoration element.
Embodiment 2
High-intensity fiber composite material and decoration element are prepared by the raw material proportioning of 1 embodiment 2 of table, specific steps are substantially the same as real Apply example 1.
Embodiment 3
High-intensity fiber composite material and decoration element are prepared by the raw material proportioning of 1 embodiment 3 of table, specific steps are substantially the same as real Apply example 1,80 degree of vapor conserve 24 hours after demoulding, bronze-colored colorant are sprayed after polishing to obtain the final product.
Embodiment 4
High-intensity fiber composite material and decoration element are prepared by the raw material proportioning of 1 embodiment 4 of table, specific steps are substantially the same as real Apply example 1.
Embodiment 5
High-intensity fiber composite material and decoration element are prepared by the raw material proportioning of 1 embodiment 5 of table, specific steps are substantially the same as real Apply example 1.
Embodiment 6
High-intensity fiber composite material and decoration element are prepared by the raw material proportioning of 1 embodiment 6 of table, specific steps are substantially the same as real Apply example 1.
According to " JGJ/T 423-2018 glass fiber reinforced cement (GRC) Application in Building technical standard " detection implement 1 to The high-intensity fiber composite material decoration element of embodiment 6, the results are shown in Table 2.
28 days strength test results of material that 2 embodiment 1-6 of table is obtained
Detected intensities show that gained construction material intensity of the invention is more than " JGJ/T 423-2018 glass fibers in table 2 Dimension enhancing cement (GRC) Application in Building technical standard " in bending strength requirement, while compression strength is higher, is able to satisfy load-bearing Requirement.Fiber is compounded in embodiment 2 compared with Single Fiber in embodiment 1, pressure-proof and snap-resistent intensity increases.

Claims (9)

1. a kind of high-intensity fiber composite material, it is characterised in that comprise the following raw materials by weight percent: cement 30-50%, Graded sand 40-60%, active reinforcing agent 5-15%, fibrous material 1-10%, filler 2-8%, pigment 0-2%, wood fibre 0.05-0.2%, water-retaining agent 0.05-0.2%, defoaming agent 0.05-0.1%, water-reducing agent 0.2%-2%, high molecular material 0.1- 1%, retarder 0-0.2%, thixotropic lubricant 0.05-0.3%.
2. high-intensity fiber composite material according to claim 1, it is characterised in that: the cement is ordinary portland cement Or white portland cement;The graded sand is common quartz sand or white quartz sand;The active reinforcing agent is common silicon ash Or white silicon ash;The filler is flyash, steel-making slag powder or heavy calcium carbonate;The water-retaining agent is low viscosity hydroxypropyl methyl Cellulose ether.
3. high-intensity fiber composite material according to claim 2, it is characterised in that: the cement is that 42.5 strength grades are general Logical portland cement or 52.5 strength grades and whiteness are greater than 87% white portland cement;The graded sand is silica Content is greater than 96%, the common quartz sand of 40-100 purpose or white quartz sand;The active reinforcing agent is greater than for specific surface area 800m2The common silicon ash of/Kg, dioxide-containing silica greater than 90% or white silicon ash;The filler is that specific surface area is greater than 400m2/ Flyash, steel-making slag powder or the heavy calcium carbonate of kg;The average length of the wood fibre is less than 500 μm;The water-retaining agent is Low-viscosity hydroxypropylmethylc,llulose ether.
4. high-intensity fiber composite material according to claim 1, it is characterised in that: the fibrous material is steel fibre, carbon One or more of fiber, alkali-resistant glass fibre;The pigment is inorganic pigment;The defoaming agent is powdery defoaming agent; The water-reducing agent is modified polycarboxylic acid ethers powdery water-reducing agent;The high molecular material is vinyl acetate-ethylene copolymerization emulsions;Institute Stating retarder is citrate;The thixotropic lubricant is laminar silicic acid salt thixotropic lubricant.
5. high-intensity fiber composite material according to claim 4, it is characterised in that: the inorganic pigment be iron oxide red, iron oxide black, Iron oxide yellow, cologne earth, cobalt blue or chrome green;The powdery defoaming agent is liquid hydrocarbon, polyethylene glycol and inorganic carrier composition Mixture.
6. the preparation method that high-intensity fiber composite material described in claim 1 is used for decoration element, it is characterised in that: previously according to Layout design makes molding die, according to the ratio stirs evenly the raw material of high-intensity fiber composite material, by pouring or spraying It penetrates molding and high-intensity fiber composite material is injected into mold, then demould, conserve and be surface-treated up to decoration element.
7. preparation method according to claim 6, it is characterised in that: the mold is fiber reinforced plastic mold, wood mould, silica gel Mold or steel mold.
8. preparation method according to claim 6, it is characterised in that the raw material stirring is carried out by following operation: by water It is put into blender, the addition of liquid type raw material is stirred evenly, then slowly add powder by the suitable ratio of mud, then stirred into uniformly Thick shape slurry is stood.
9. preparation method according to claim 6, it is characterised in that the maintenance is conserved using showering curing or vapor.
CN201811595078.7A 2018-12-25 2018-12-25 High-intensity fiber composite material and its preparation method for decoration element Pending CN109553352A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110357509A (en) * 2019-08-09 2019-10-22 承德泰斯特新材料科技有限公司 A kind of novel environment friendly scumbling cement base ornament materials plaster
CN110423055A (en) * 2019-08-16 2019-11-08 北京市高强混凝土有限责任公司 A kind of super-long structural anti-crack concrete
CN111333377A (en) * 2020-03-09 2020-06-26 中南大学 A kind of high tensile strength concrete and preparation method thereof
CN114890747A (en) * 2022-05-17 2022-08-12 武汉陆锦时代建筑科技有限公司 Ultrahigh-strength active powder concrete and preparation method thereof
CN115140979A (en) * 2022-07-18 2022-10-04 三能集成房屋股份有限公司 Modified colorful UHPC mixture, decorative plate and preparation method thereof

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KR101567851B1 (en) * 2015-07-21 2015-11-10 고재형 KR powder containing an environmentally friendly polymer mortar and concrete repair section reinforcement method using the same
CN108264289A (en) * 2016-12-30 2018-07-10 南京理工大学 A kind of very-high performance architectural concrete and preparation method thereof

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KR101567851B1 (en) * 2015-07-21 2015-11-10 고재형 KR powder containing an environmentally friendly polymer mortar and concrete repair section reinforcement method using the same
CN108264289A (en) * 2016-12-30 2018-07-10 南京理工大学 A kind of very-high performance architectural concrete and preparation method thereof

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110357509A (en) * 2019-08-09 2019-10-22 承德泰斯特新材料科技有限公司 A kind of novel environment friendly scumbling cement base ornament materials plaster
CN110423055A (en) * 2019-08-16 2019-11-08 北京市高强混凝土有限责任公司 A kind of super-long structural anti-crack concrete
CN111333377A (en) * 2020-03-09 2020-06-26 中南大学 A kind of high tensile strength concrete and preparation method thereof
CN114890747A (en) * 2022-05-17 2022-08-12 武汉陆锦时代建筑科技有限公司 Ultrahigh-strength active powder concrete and preparation method thereof
CN115140979A (en) * 2022-07-18 2022-10-04 三能集成房屋股份有限公司 Modified colorful UHPC mixture, decorative plate and preparation method thereof
CN115140979B (en) * 2022-07-18 2024-03-19 三能集成房屋股份有限公司 Modified color UHPC (ultra high Performance) mixture, decorative plate and preparation method thereof

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Application publication date: 20190402