CN109535716A - A kind of and good polyphenylene sulfide/carbon fibre composite of metal adhesion - Google Patents
A kind of and good polyphenylene sulfide/carbon fibre composite of metal adhesion Download PDFInfo
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- CN109535716A CN109535716A CN201811217227.6A CN201811217227A CN109535716A CN 109535716 A CN109535716 A CN 109535716A CN 201811217227 A CN201811217227 A CN 201811217227A CN 109535716 A CN109535716 A CN 109535716A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/042—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with carbon fibres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2381/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
- C08J2381/02—Polythioethers; Polythioether-ethers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2461/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2461/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2461/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2463/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
The present invention provides a kind of and good polyphenylene sulfide/carbon fibre composite of metal adhesion, include polyphenylene sulfide, the short fine, epoxy resin of carbon fiber and linear phenol-aldehyde resin, and added up in terms of 100 parts by weight by polyphenylene sulfide and the short fibre of carbon fiber, contain 65~95 parts by weight of polyphenylene sulfide, short fine 5~35 parts by weight of carbon fiber.Polyphenylene sulfide/carbon fibre composite of the invention improves the cohesive force of same metal, and raw material used is heat-resist, will not work in-process decompose, so easy to process, the stability of properties of product is good.In addition, the tensile strength and impact strength to composite material also have some improvement.
Description
Technical field
The present invention relates to a kind of carbon fibre composite, the especially a kind of and good polyphenylene sulfide/carbon fibers of metal adhesion
Tie up composite material.
Background technique
Polyphenylene sulfide (PPS) is the thermoplastic resin that thiophenyl is had in molecular backbone, has high temperature resistant, corrosion-resistant, resistance to
The characteristics of radiation, fire-retardant, balanced physical mechanical property, fabulous dimensional stability and excellent electrical property is a kind of comprehensive
Close the special engineering plastics haveing excellent performance.Carbon fiber have low-density, high specific strength and specific modulus, high temperature resistant, resist chemical,
The good characteristics such as highly thermally conductive, low thermal expansion.Fibre reinforced polyphenylene sulfide can be further improved the tensile strength of polyphenylene sulfide
And impact strength, improve its toughness, expands its application range.
It is used on the way in automobile, electronic apparatus etc., needs for fibre reinforced polyphenylene sulfide to be used in combination with metal material, than
Such as fibre reinforced polyphenylene sulfide is molded on metalwork.Relative to Other Engineering plastics, although PPS is the same as the caking property of metal
Preferably, but under certain applications, however it remains the problem of interface is easily peeled off and falls off needs to further increase PPS same
The caking property of metal.
CN201711166435.3 improves the viscous of same metal by compounding ternary chlorine vinegar resin and fluororesin in PPS
Knot property, the tensile shear strength with metal can be improved nearly 70%, and compared with former PPS composite material, need to only change resin
Formula can be realized, and be not required to change existing technique, be not required to increase equipment, simple and easy.
But ternary chlorine vinegar resin heat resistance used in this method is bad, it in process, can part generation point
Solution causes difficulty of processing increase and properties of product unstable.
For this reason, it may be necessary to a kind of processing performance is good, properties of product are stable, can improve same metal cohesive force polyphenylene sulfide
Ether/carbon fibre composite.
Summary of the invention
To solve the above problems, the present invention provides a kind of and good polyphenylene sulfide/carbon fiber composites of metal adhesion
Material, while a kind of metal-resin composite according to made of this composite material being provided.
A kind of polyphenylene sulfide/carbon fibre composite includes polyphenylene sulfide, the short fine, epoxy resin of carbon fiber and line style phenol
Urea formaldehyde, and added up in terms of 100 parts by weight by polyphenylene sulfide and the short fibre of carbon fiber, contain 65~95 parts by weight of polyphenylene sulfide, carbon fiber
Tie up short fine 5~35 parts by weight.
Polyphenylene sulfide is the polymer that thiophenyl is had in molecular backbone, comprising to the equal of diphenyl sulfide and/or diphenyl sulfide
Polymers, copolymer and their mixture.
The short fibre of carbon fiber is to be chopped to form through fibre cutting machine by carbon fiber filament.Composite material as polyphenylene sulfide
The tensile strength, bending strength and impact resistant strength of polyphenylene sulfide can be improved in reinforcing fiber.
It is added up in terms of 100 parts by weight by polyphenylene sulfide and the short fibre of carbon fiber, when polyphenylene sulfide is more than 95 parts by weight, carbon fiber
Short fine less than 5 parts by weight, the humidification of carbon fiber poly-p-phenylene sulfide ether is unobvious；When polyphenylene sulfide is less than 65 parts by weight, carbon fiber
Tie up short fine more than 35 parts by weight, dispersion variation of the carbon fiber in polyphenylene sulfide matrix, performance uniformity reduction.
Epoxy resin refers to the compound in molecule containing two or more epoxy groups, is with aliphatic, alicyclic
Or aromatic segments are the macromolecule prepolymer of main chain, are a kind of important thermosetting resins.Common epoxy resin can be enumerated
Bisphenol A type epoxy resin, bisphenol f type epoxy resin, more phenolic tetraglycidel ether epoxy resins, aliphatic glycidyl ether ring out
Oxygen resin, glycidyl ester type epoxy resin, glycidyl amine type epoxy resin, epoxidation of olefins compound etc..Epoxy resin
Polyphenylene sulfide/carbon fibre composite be can be improved to the caking property of metal.
Linear phenol-aldehyde resin, also known as linear phenolic resin, be can be dissolved in organic solvent, heating can melt and long
Phase heating will not cured a kind of phenolic resin.Linear phenol-aldehyde resin can improve together polyphenylene sulfide with epoxy resin cure
Caking property of the ether/carbon fibre composite to metal.Common linear phenol-aldehyde resin can enumerate Bisphenol-A type linear phenolic aldehyde
Resin, cresols type linear phenol-aldehyde resin, phenol type linear phenol-aldehyde resin etc..
Further, in polyphenylene sulfide/carbon fibre composite of the present invention, with the short fine conjunction of polyphenylene sulfide and carbon fiber
100 parts by weight meters are calculated as, epoxy resin and linear phenol-aldehyde resin add up to 5~30 parts by weight, to raising polyphenylene sulfide/carbon fiber
Composite material is obvious and easy to process with the cohesive force effect of metal.If deviateing this range, polyphenylene sulfide/carbon fiber is improved
Composite material is invalid with the cohesive force of metal or effect is unobvious, and is not easy to process, especially linear phenol-aldehyde resin content compared with
When more, it is easy to form gel foreign matter in the base, it is unfavorable to the stability of composite materials property.
Further preferably, it is added up in terms of 100 parts by weight by polyphenylene sulfide and the short fibre of carbon fiber, epoxy resin and line style phenol
Urea formaldehyde adds up to 10~20 parts by weight.
Epoxide equivalent refers to the grams of the epoxy resin containing monovalent epoxy group, and it is to indicate epoxy that unit, which is gram/equivalent,
The important physical property index of epoxy group quantity contained by resin.
Hydroxyl equivalent refers to the grams of the linear phenol-aldehyde resin containing monovalent hydroxyl, and it is to indicate line that unit, which is gram/equivalent,
The important physical property index of hydroxyl quantity contained by type phenolic resin.
When in system simultaneously containing two or more epoxy resin (or linear phenol-aldehyde resin) when, epoxide equivalent
The weighed average that (or hydroxyl equivalent) presses the epoxide equivalent of these types of epoxy resin (or linear phenol-aldehyde resin) calculates, i.e. epoxy
Equivalent (or hydroxyl equivalent)=resin 1 epoxide equivalent (or hydroxyl equivalent) × resin 1 weight percentage+...+resin n
Epoxide equivalent (or hydroxyl equivalent) × resin n weight percentage.
When epoxide equivalent/linear phenol-aldehyde resin that the weight fraction ratio of epoxy resin and linear phenol-aldehyde resin is epoxy resin
When hydroxyl equivalent, theoretically the hydroxyl in the epoxy group and linear phenol-aldehyde resin in epoxy resin being capable of fully reacting.Asphalt mixtures modified by epoxy resin
The weight fraction ratio of rouge and linear phenol-aldehyde resin can be written as such as following formula 1, and wherein α is no unit quantity.
The weight fraction ratio of epoxy resin and linear phenol-aldehyde resin=(epoxide equivalent/linear phenol-aldehyde resin of epoxy resin
Hydroxyl equivalent) × α formula 1
Further, in polyphenylene sulfide/carbon fibre composite of the present invention, epoxy resin and linear phenol-aldehyde resin
It is the range between 0.8~1 that weight fraction ratio, which ranges preferably from the α value in formula 1, this is multiple to polyphenylene sulfide/carbon fiber is improved
Condensation material is more apparent with the cohesive force effect of metal.When α is greater than 1, or when less than 0.8, all it is unfavorable for epoxy resin and line style phenol
Urea formaldehyde is to raising polyphenylene sulfide/carbon fibre composite with the raising of the cohesive force of metal.Further preferably, α be 0.85~
Between 0.95.
Further, in polyphenylene sulfide/carbon fibre composite of the present invention, the fusing point of the epoxy resin is 90 DEG C
More than, preferably 120 DEG C or more, most preferably 140 DEG C or more.This based epoxy resin has preferable heat resistance, in composite material
Processing temperature under the side reactions such as be not susceptible to decompose, and the solidification temperature of epoxy resin synteny phenolic resin is higher, is adding
Curing reaction is easy to control during work.
Further, in polyphenylene sulfide/carbon fibre composite of the present invention, the linear phenol-aldehyde resin is bisphenol-A
One of type linear phenol-aldehyde resin, cresols type linear phenol-aldehyde resin are a variety of.Both linear phenol-aldehyde resins and epoxy resin
Matching degree more preferably, to improve polyphenylene sulfide/carbon fibre composite it is more effective with the cohesive force of metal.
Further, in polyphenylene sulfide/carbon fibre composite of the present invention, the linear phenol-aldehyde resin is bisphenol-A
Two kinds in type linear phenol-aldehyde resin and cresols type linear phenol-aldehyde resin, the weight fraction ratio 1:1~1:3 of the two, preferably 1:
1.5~1:2.5.
Further, in polyphenylene sulfide/carbon fibre composite of the present invention, the fusing point of the linear phenol-aldehyde resin exists
Between 90~120 DEG C, most preferably between 95~115 DEG C.Similar with epoxy resin, the linear phenol-aldehyde resin of higher melt has
Preferable heat resistance is not susceptible to the side reactions such as decomposition under the processing temperature of composite material, and solidification temperature is higher, is processing
It is easy to control curing reaction in the process；But there is the compatibility for being greater than the linear phenol-aldehyde resin of 120 DEG C of fusing points with epoxy resin
It is bad, it is unfavorable for composite material with the raising of the cohesive force of metal.
Further, in polyphenylene sulfide/carbon fibre composite of the present invention, with the short fine conjunction of polyphenylene sulfide and carbon fiber
100 parts by weight meters are calculated as, 0.2~10 parts by weight of silane coupling agent are also contained.Silane coupling agent is one kind in the molecule while containing
There are two types of the organo-silicon compound of different chemical property groups, molecule has and inanimate matter material (such as glass, metal simultaneously
Deng) ability for chemically reacting, chemically reacting with organic material (such as synthetic resin) occurs, so as to enhance polyphenyl
The mutual cohesive force of thioether, epoxy resin, linear phenol-aldehyde resin, carbon fiber, improves the performance of composite material.It is silane coupled
Agent can be enumerated containing one of amido, epoxy group, vinyl, isocyanate group, sulfydryl or a variety of siloxanes.
Further, in polyphenylene sulfide/carbon fibre composite of the present invention, the silane coupling agent contains epoxy group
Or one of isocyanate group or a variety of, they and epoxy resin, the compatibility of linear phenol-aldehyde resin, reactivity are preferably, right
It is obvious with the cohesive force of metal and the stabilizing effect of composite materials property to improve composite material.Most preferably contain epoxy
The silane coupling agent of base.
Metal-resin made of polyphenylene sulfide/carbon fibre composite of the present invention is utilized the present invention also provides a kind of
Complex, it includes the polyphenylene sulfide/carbon fibre composites and metalwork belonging to the present invention.
Effect of the invention:
Polyphenylene sulfide/carbon fibre composite of the invention improves the cohesive force of same metal, and raw material used is heat-resisting
Property it is good, will not work in-process decompose, so performance easy to process, the stability of properties of product is good.In addition, the drawing to composite material
It stretches intensity and impact strength also has some improvement.
Specific embodiment
It is a kind of with the good polyphenylene sulfide/carbon fibre composite of metal adhesion, original used in embodiment and comparative example
Expect as follows:
[the short fine enhancing polyphenylene sulfide of carbon fiber]
A1: Dongli Ltd. produces TORAYCAA630T-30V, short fine 30 parts by weight of carbon fiber-containing, 70 weight of polyphenylene sulfide
Part.Polyphenylene sulfide fusing point is 278 DEG C.
[epoxy resin]
B1:DIC Co., Ltd. production EPICLON 2050, bisphenol A type epoxy resin, 85 DEG C of fusing point, epoxide equivalent 700g/
eq。
B2:DIC Co., Ltd. production EPICLON4050, bisphenol A type epoxy resin, 100 DEG C of fusing point, epoxide equivalent 900g/
eq。
B3:DIC Co., Ltd. production EPICLON HM-091, bisphenol A type epoxy resin, 145 DEG C of fusing point, epoxide equivalent
2600g/eq。
[linear phenol-aldehyde resin]
C1:DIC Co., Ltd. produces PHENOLITE TD-2091, and phenol type linear phenol-aldehyde resin, 110 DEG C of fusing point, hydroxyl is worked as
Measure 100g/eq.
C2:DIC Co., Ltd. production PHENOLITE VH-4170, Bisphenol-A type linear phenolic resin, 105 DEG C of fusing point, hydroxyl
Equivalent 120g/eq.
C3:DIC Co., Ltd. produces PHENOLITEKA-1163, and cresols type linear phenol-aldehyde resin, 110 DEG C of fusing point, hydroxyl is worked as
Measure 120g/eq.
C4:DIC Co., Ltd. production PHENOLITEKA-1160, cresols type linear phenol-aldehyde resin, 85 DEG C of fusing point, hydroxyl equivalent
120g/eq。
[silane coupling agent]
D1: glycidylpropyl triethoxysilane, Shin-Etsu Chemial Co., Ltd produce KBM-403.
D2: isocyanatopropyl triethoxysilane, Shin-Etsu Chemial Co., Ltd produce KBE-9007.
D3:3- Mercaptopropyltriethoxysilane, Shin-Etsu Chemial Co., Ltd produce KBM-803.
Embodiment 1~13
It is sufficiently mixed according to the raw material and parts by weight of table 1, is added to extrusion pelletizing in extruder and obtains composite resin
Particle, extruder temperature are set as 300 DEG C.
Table 1
Remarks: formula 1 is shown in the definition of α.
Embodiment 14~19
On the basis of the composition of raw materials of embodiment 5, it is formulated according to shown in table 2, by the linear phenol-aldehyde resin of two kinds
It is used in mixed way, to substitute former linear phenol-aldehyde resin.After raw material is sufficiently mixed, it is added to extrusion pelletizing in extruder and obtains composite wood
Expect that resin particle, extruder temperature are set as 300 DEG C.
Table 2
Embodiment 20~24
It on the basis of the composition of raw materials of embodiment 16, is formulated according to shown in table 3, increases silane coupling agent.Raw material is abundant
After mixing, it is added to extrusion pelletizing in extruder and obtains nanocomposite resin particle, extruder temperature is set as 300 DEG C.
Table 3
Comparative example 1
The short fine enhancing polyphenylene sulfide A1 of carbon fiber.
Comparative example 2
Nanocomposite resin particle is prepared by the embodiment 6 of CN201711166435.3.
Composite resin made from embodiment and comparative example is melted at 300 DEG C respectively, is molded, is grown with injection molding machine
× width x thickness degree=200mm × 100mm × 4mm composite panel, and measure the tensile strength and impact strength of composite material.
By 5052 aluminium alloy plates of commercially available 1mm thickness, it is molten to be put into acetone for cut growth × wide=45mm × 18mm rectangular pieces
In liquid, after ultrasonic cleaning 15min, cleaned up with pure water；The perchloric acid second of volume ratio 1:3 is put into as anode again
In mixed alkoxide solution, room temperature is electrolysed 3min under 40V voltage；Continue thereafter with the phosphoric acid solution that 1mol/L is put into as anode
In, continue to be electrolysed 40min under 40V voltage；It is immersed in 30min in the phosphoric acid of 2mol/L again, taking-up is cleaned up with pure water
And dry the aluminium alloy plate being surface-treated.
Above-mentioned surface treatment aluminium alloy plate is embedded into injection mold, is prepared embodiment and comparative example with injection molding machine
Composite material be molded into obtain on aluminium alloy plate, obtain composite gauge be 45mm × 10mm × 5mm, joint surface 10mm
The aluminum alloy resin complex of × 5mm, and measure the tensile shear strength of aluminum alloy resin complex.
The performance measurement method of embodiment and comparative example is as follows:
1, tensile strength: being carried out by GB/T1447-2005, and composite material is cut into I type sample, a length of 200mm, test
Speed is 10mm/min.5 battens are tested, average value and standard deviation are calculated.
2, impact strength: being carried out by GB/T1043-1993, composite material is cut into 1 type sample, notch type is A.It surveys
5 battens are tried, average value and standard deviation are calculated.
3, tensile shear strength: clamping the metal of metal-resin composite with tensile testing machine and resin end be measured,
Distance is 60mm, test speed 10mm/min between fixture.5 battens are tested, average value and standard deviation are calculated.
Test result is as shown in table 4.
Table 4
As can be seen from Table 4, compared with comparative example 1, the tensile strength and impact property of the embodiment of the present invention are good, with
The cohesive force of metal improves a lot, and adhesive property is more preferable, and also has a degree of change to tensile strength and impact strength
It is kind；Compared with comparative example 2, adhesive property is close or more preferably, and due to improving processing performance, properties of product are more stable, standard
Deviation is smaller, more extensive with field.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, adds according to technical solution and inventive concept
With equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (10)
1. a kind of and good polyphenylene sulfide/carbon fibre composite of metal adhesion, which is characterized in that include polyphenylene sulfide, carbon
The short fine, epoxy resin of fiber and linear phenol-aldehyde resin, and added up in terms of 100 parts by weight by polyphenylene sulfide and the short fibre of carbon fiber, contain
Short fine 5~35 parts by weight of 65~95 parts by weight of polyphenylene sulfide, carbon fiber.
2. the according to claim 1 a kind of and good polyphenylene sulfide/carbon fibre composite of metal adhesion, feature exist
In being added up in terms of 100 parts by weight by polyphenylene sulfide and the short fibre of carbon fiber, epoxy resin and linear phenol-aldehyde resin add up to 5~30
Parts by weight.
3. the according to claim 2 a kind of and good polyphenylene sulfide/carbon fibre composite of metal adhesion, feature exist
In the weight fraction ratio of epoxy resin and linear phenol-aldehyde resin is (epoxide equivalent/linear phenol-aldehyde resin hydroxyl of epoxy resin
Equivalent) × 0.8~epoxy resin epoxide equivalent/linear phenol-aldehyde resin hydroxyl equivalent between.
4. the according to claim 3 a kind of and good polyphenylene sulfide/carbon fibre composite of metal adhesion, feature exist
In the fusing point of the epoxy resin is 90 DEG C or more.
5. the according to claim 1-4 a kind of and good polyphenylene sulfide/carbon fibre composite of metal adhesion,
It is characterized in that, the linear phenol-aldehyde resin be one of Bisphenol-A type linear phenolic resin, cresols type linear phenol-aldehyde resin or
It is a variety of.
6. the according to claim 5 a kind of and good polyphenylene sulfide/carbon fibre composite of metal adhesion, feature exist
In the linear phenol-aldehyde resin is two kinds in Bisphenol-A type linear phenolic resin and cresols type linear phenol-aldehyde resin, the weight of the two
Measure portion rate 1:1~1:3.
7. the according to claim 1-6 a kind of and good polyphenylene sulfide/carbon fibre composite of metal adhesion,
It is characterized in that, the fusing point of the linear phenol-aldehyde resin is between 90~120 DEG C.
8. the according to claim 1-7 a kind of and good polyphenylene sulfide/carbon fibre composite of metal adhesion,
It is characterized in that, adding up in terms of 100 parts by weight by polyphenylene sulfide and the short fibre of carbon fiber, also contain 0.2~10 weight of silane coupling agent
Measure part.
9. the according to claim 8 a kind of and good polyphenylene sulfide/carbon fibre composite of metal adhesion, feature exist
In the silane coupling agent contains one of epoxy group or isocyanate group or a variety of.
10. a kind of utilize metal-resin made of according to any one of claims 1 to 99 described in any item polyphenylene sulfide/carbon fibre composites
Complex.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811217227.6A CN109535716A (en) | 2018-10-18 | 2018-10-18 | A kind of and good polyphenylene sulfide/carbon fibre composite of metal adhesion |
| PCT/CN2018/111591 WO2020077657A1 (en) | 2018-10-18 | 2018-10-24 | Polyphenylene sulfide/carbon fiber composite material with good bonding force to metal |
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| CN201811217227.6A CN109535716A (en) | 2018-10-18 | 2018-10-18 | A kind of and good polyphenylene sulfide/carbon fibre composite of metal adhesion |
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Citations (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5933360A (en) * | 1982-08-19 | 1984-02-23 | Dainippon Ink & Chem Inc | Polyphenylene sulfide composition |
| JPS60206873A (en) * | 1984-03-30 | 1985-10-18 | Dainippon Ink & Chem Inc | Polyphenylene sulfide composition for paints |
| JPS63286467A (en) * | 1987-05-19 | 1988-11-24 | Yobea Rulon Kogyo Kk | Polyphenylene sulfide resin composition |
| JPH05214248A (en) * | 1992-02-07 | 1993-08-24 | Furukawa Electric Co Ltd:The | Resin composition for molded precision part |
| CN1115329A (en) * | 1994-03-30 | 1996-01-24 | 古尔德电子有限公司 | Epoxy adhesives and copper foils and copper clad laminates using same |
| JPH09278522A (en) * | 1996-04-17 | 1997-10-28 | Nippon Carbon Co Ltd | Glassy carbon for plasma etching electrode |
| JPH10237271A (en) * | 1997-02-27 | 1998-09-08 | Hitachi Chem Co Ltd | Thermosetting resin composition, film or sheet adhesive and adhesive-coated metal foil |
| CN1827789A (en) * | 2005-02-28 | 2006-09-06 | 宝山钢铁股份有限公司 | Joint filler for converter tuyere brick replacing |
| CN104204098A (en) * | 2012-03-23 | 2014-12-10 | Dic株式会社 | Polyarylene sulfide resin composition and molded body |
| CN105295266A (en) * | 2014-06-09 | 2016-02-03 | 南通慧源塑胶有限公司 | Formula of corrosion-resistant plastic composite material |
| CN106364067A (en) * | 2016-08-29 | 2017-02-01 | 上海国纪电子材料有限公司 | P10 copper-clad laminate |
| CN107163291A (en) * | 2017-07-11 | 2017-09-15 | 四川大学 | A kind of carbon fiber/polyphenyl thioether composite material and preparation method thereof |
| CN107674161A (en) * | 2017-10-17 | 2018-02-09 | 江苏宝安电缆有限公司 | A kind of epoxide resin material for strengthening metal adhesion and preparation method thereof |
| CN107698973A (en) * | 2017-09-14 | 2018-02-16 | 芜湖林电子科技有限公司 | A kind of heat-resisting 3D printing material of automobile high-strength |
| CN108530893A (en) * | 2017-11-21 | 2018-09-14 | 江苏澳盛复合材料科技有限公司 | A kind of composite material that can be bonded with metal |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106519696A (en) * | 2016-11-28 | 2017-03-22 | 江苏东钢新材料有限公司 | Fireproof circuit board and production method thereof |
| CN107312332A (en) * | 2017-06-19 | 2017-11-03 | 合肥斯科尔智能科技有限公司 | A kind of 3D printing material of architectural engineering high tenacity high temperature oxidation resisting |
| CN108424648B (en) * | 2018-04-20 | 2021-02-05 | 江苏澳盛复合材料科技有限公司 | Carbon fiber composite material for injection molding |
-
2018
- 2018-10-18 CN CN201811217227.6A patent/CN109535716A/en active Pending
- 2018-10-24 WO PCT/CN2018/111591 patent/WO2020077657A1/en active Application Filing
Patent Citations (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5933360A (en) * | 1982-08-19 | 1984-02-23 | Dainippon Ink & Chem Inc | Polyphenylene sulfide composition |
| JPS60206873A (en) * | 1984-03-30 | 1985-10-18 | Dainippon Ink & Chem Inc | Polyphenylene sulfide composition for paints |
| JPS63286467A (en) * | 1987-05-19 | 1988-11-24 | Yobea Rulon Kogyo Kk | Polyphenylene sulfide resin composition |
| JPH05214248A (en) * | 1992-02-07 | 1993-08-24 | Furukawa Electric Co Ltd:The | Resin composition for molded precision part |
| CN1115329A (en) * | 1994-03-30 | 1996-01-24 | 古尔德电子有限公司 | Epoxy adhesives and copper foils and copper clad laminates using same |
| JPH09278522A (en) * | 1996-04-17 | 1997-10-28 | Nippon Carbon Co Ltd | Glassy carbon for plasma etching electrode |
| JPH10237271A (en) * | 1997-02-27 | 1998-09-08 | Hitachi Chem Co Ltd | Thermosetting resin composition, film or sheet adhesive and adhesive-coated metal foil |
| CN1827789A (en) * | 2005-02-28 | 2006-09-06 | 宝山钢铁股份有限公司 | Joint filler for converter tuyere brick replacing |
| CN104204098A (en) * | 2012-03-23 | 2014-12-10 | Dic株式会社 | Polyarylene sulfide resin composition and molded body |
| CN105295266A (en) * | 2014-06-09 | 2016-02-03 | 南通慧源塑胶有限公司 | Formula of corrosion-resistant plastic composite material |
| CN106364067A (en) * | 2016-08-29 | 2017-02-01 | 上海国纪电子材料有限公司 | P10 copper-clad laminate |
| CN107163291A (en) * | 2017-07-11 | 2017-09-15 | 四川大学 | A kind of carbon fiber/polyphenyl thioether composite material and preparation method thereof |
| CN107698973A (en) * | 2017-09-14 | 2018-02-16 | 芜湖林电子科技有限公司 | A kind of heat-resisting 3D printing material of automobile high-strength |
| CN107674161A (en) * | 2017-10-17 | 2018-02-09 | 江苏宝安电缆有限公司 | A kind of epoxide resin material for strengthening metal adhesion and preparation method thereof |
| CN108530893A (en) * | 2017-11-21 | 2018-09-14 | 江苏澳盛复合材料科技有限公司 | A kind of composite material that can be bonded with metal |
Non-Patent Citations (3)
| Title |
|---|
| 卢会杰，赵文献主编: "《有机化学实验》", 31 July 2009, 河南科学技术出版社 * |
| 建筑材料科学研究院技术情报室编: "《无机纤维及其复合材料》", 30 June 1972, 建筑材料科学研究院技术情报室 * |
| 杨桂生等编著: "《工程塑料》", 31 December 2017, 中国铁道出版社 * |
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