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CN109528538A - Natural plants hair-care hair dye based on biological crosslinked action - Google Patents

Natural plants hair-care hair dye based on biological crosslinked action Download PDF

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Publication number
CN109528538A
CN109528538A CN201811357903.XA CN201811357903A CN109528538A CN 109528538 A CN109528538 A CN 109528538A CN 201811357903 A CN201811357903 A CN 201811357903A CN 109528538 A CN109528538 A CN 109528538A
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hair
hair dye
extract
dye according
plant
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尹光伟
郭静璇
雷振锋
孙军红
张文艳
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Tianjin University of Traditional Chinese Medicine
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Tianjin University of Traditional Chinese Medicine
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • A61K8/602Glycosides, e.g. rutin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/347Phenols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365Hydroxycarboxylic acids; Ketocarboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4973Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
    • A61K8/498Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom having 6-membered rings or their condensed derivatives, e.g. coumarin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9789Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9794Liliopsida [monocotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/10Preparations for permanently dyeing the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/12Preparations containing hair conditioners

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
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  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

本发明公开了一种基于生物交联作用的天然植物护发染发剂,按重量包括下述组分:植物花色苷色素类物质,交联剂,有机弱酸,增稠剂,抗氧化剂和水。本发明的护发染发剂能够有效将白发染黑,染发效果自然,染发速度快,所需条件温和易于实现,本发明采用了对人体无毒无害的天然产物花色苷,通过加入交联剂提高花色苷类色素与人体头发中蛋白质的结合,通过加入有机弱酸,其合适的pH值使其色泽接近正常头发。使头发染色后保持时间长。添加的具有养发护发作用的营养剂,能够在使用染发剂时对头发进行保护,促进头皮的血液循环,促进黑色素细胞再生,对于头发由白转黑有一定的促进作用。本发明原料来源广泛,成本低。The invention discloses a natural plant hair-care dyeing agent based on biological cross-linking action, which comprises the following components by weight: plant anthocyanin pigments, cross-linking agent, weak organic acid, thickener, antioxidant and water. The hair conditioner and hair dye of the invention can effectively dye white hair black, the hair dyeing effect is natural, the hair dyeing speed is fast, and the required conditions are mild and easy to achieve. The agent improves the combination of anthocyanin pigments and proteins in human hair, and by adding organic weak acid, its appropriate pH value makes its color close to normal hair. Keeps hair long after coloring. The added nutrient with hair care and hair care function can protect the hair when using the hair dye, promote the blood circulation of the scalp, promote the regeneration of melanocytes, and has a certain promotion effect on the hair from white to black. The invention has wide raw material sources and low cost.

Description

Natural plants hair-care hair dye based on biological crosslinked action
Technical field
The present invention relates to daily-use chemical industry industries, specially based on the natural plants hair-care hair dye of biological crosslinked action.
Background technique
In recent years, with the improvement of people's living standards, people's lives increasingly pursue quality, the middle-aged and the old and portion Divide and white hair is contaminated to black demand because physiologic factor causes the young man of white hair to have.Presently commercially available hair dye is mainly with p-phenylenediamine Based on class synthetic dyes, such hair dye has offensive odour, and can cause to hair black chromatophore permanently The injury of property, causes hair more to contaminate the more vicious circle of white hair.
Currently, the phytochrome for hair dyeing being extracted from plants is mostly water-soluble higher molecule, such chemical combination Object and hair adhesive force are weak, therefore lead to that it is poor with dyeing effect, dyeing kinetics are slow, stability is poor, colour fading is serious, using not The disadvantages of facilitating.Effective staining components are still poisonous and hazardous to body to aniline category matter to hair dye mostly on the market, very Just so-called safe and non-toxic pure natural hair dye is fewer and fewer.
Hair is not by having lived hard protein cutin to form.It forms in the amino acid molecular of these protein, often At least there is an amino (- NH2) and a carboxyl (- COOH) in a molecule;Water is condensed shape between every two amino acid molecular At peptide chain, it is formed by numerous peptide chains and passes through disulfide bond, sat linkage, hydrogen bond, amido bond, the ester bond etc. formed between amino acid molecular Combination forms the natural polymer fibrin with reticular structure.
Flower color glycosides pigment is natural pigment, and main component is anthocyanin, including Cyanidin -3-O- glucoside (I), delphinidin -3-O- glucoside (II) and Cyanidin -3-O- galactoside (III) etc..
Such pigment is good to the stability of heat, and raw material is easy to get, and extraction process is simple, and pigment content is higher, and safe and non-toxic, It is a kind of preferable natural hair dye resource.But these flower color glycosides pigments are water colo(u)r, due to its it is water-soluble compared with It is high, weak with hair binding ability, the disadvantages of dyeing effect is poor, dyeing kinetics are slow, stability is poor, colour fading is serious, inconvenient to use It is set still to cannot be used directly for hair dye.
Summary of the invention
The purpose of the present invention is overcome the deficiencies of the prior art and provide a kind of natural plants shield based on biological crosslinked action Send out hair dye.
Technical solution of the present invention is summarized as follows:
Natural plants hair-care hair dye based on biological crosslinked action includes following components: flower color glycosides color by weight Plain substance 0.5%-2%;Crosslinking agent 0.5%-0.8%;Organic monoacid 0.2%-0.3%;Thickener 0.5%-1%;Antioxygen Agent 0.5%-0.8%;Surplus is water.
The above-mentioned natural plants hair-care hair dye based on biological crosslinked action can also include nutritional agents 0.5%-1% and tune Manage agent 0.2%-0.4%.
Flower color glycosides colors are in the plant extracts of flower color glycosides pigment and the pigment of glycosides containing flower color It is at least one.
Preferred Cyanidin -3-O- the glucoside of flower color glycosides pigment, delphinidin -3-O- glucoside and corn flower At least one of element -3-O- galactoside;The preferred Semen sojae atricolor extract of plant extracts of the pigment of glycosides containing flower color, Semen sesami nigrum mention Take at least one of object and mulberries extract.
Crosslinking agent is preferred: vanillic aldehyde, salicylide, capejasmine extract, geniposide or Geniposide.
Organic monoacid is preferred: at least one of acetic acid, citric acid, lactic acid and malic acid.
Thickener is preferred: the Sodium Polyacrylate of number-average molecular weight 5000-10000, guar gum, carboxymethyl cellulose, hydroxyl first Base propyl cellulose or Tween 80.
Antioxidant is preferred: at least one of vitamin C, frerrous chloride and sodium sulfite.
Nutritional agents is preferred: radix-polygoni multiflori extract, ginseng extract, Ginger P.E or Ampelopsis grossedentata extrat.
Conditioner is preferred: glycerine, hydroxypropyl guar gum trimethyl ammonium chloride or water-soluble silicon oil.
Advantages of the present invention:
Hair dye of the invention effectively white hair can be contaminated it is black, hair dyeing effect naturally with normal color development no color differnece, hair dyeing speed Degree is fast, and required mild condition is easily achieved, and can complete within 15 minutes hair dyeing.
Present invention employs natural products anthocyanin non-toxic to humans, and improve anthocyanin by the way that crosslinking agent is added The combination degree of protein in class pigment and human hair, by the way that organic monoacid is added, suitable pH value keeps its color close Normal hair.Crosslinking agent effectively enhances the action time of anthocyanin class pigment, keeps the retention time after hair-dyeing long.
It especially is being added to the nutritional agents with hair care hair care effect, hair can protected when using hair dye Shield, promotes the blood circulation of scalp, promotes melanocyte regeneration, black has certain facilitation by white turn for hair.
Raw material sources of the present invention are extensive, at low cost.
Detailed description of the invention
Fig. 1 is the sample for being hair after bleaching.
Fig. 2 is the natural plants shield based on biological crosslinked action that the formula of embodiment 1 is prepared using the method for embodiment 12 Hair dye hair dyeing effect is sent out, still maintains color after 5 shampoos are had one's hair wash.
Fig. 3 is the natural plants shield based on biological crosslinked action that the formula of embodiment 8 is prepared using the method for embodiment 13 Hair dye hair dyeing effect is sent out, still maintains color after 5 shampoos are had one's hair wash.
Specific embodiment
Semen sojae atricolor extract, commercially available, Shaanxi Sen Fu natural product Co., Ltd, 25% anthocyanidin of content, 10:1 water extract;
Semen Sesami Nigrum extract, commercially available, Shaanxi Sen Fu natural product Co., Ltd, 25% anthocyanidin of content, 10:1 water extract;
Mulberries extract, commercially available, Shaanxi Sen Fu natural product Co., Ltd, 25% anthocyanidin of content, 10:1 water extract;
Radix-polygoni multiflori extract, commercially available, Xi'an Jin Heng Chemical Co., Ltd., content 10:1,70% alcohol-water extract;
Ginseng extract, commercially available, Shaanxi Sen Fu natural product Co., Ltd, content 10:1, water extract;
Ginger P.E, commercially available, Shaanxi Sen Fu natural product Co., Ltd, content 10:1, water extract;
Ampelopsis grossedentata extrat, commercially available, Shaanxi Hui Ke plant development corporation, Ltd., content 10:1, water extract;
Capejasmine extract, commercially available, Shaanxi Sen Fu natural product Co., Ltd, content 10:1, water extract.
To the application without limiting, the extract produced by other enterprises can also be used in the source of above-mentioned each extract In the present invention.
The present invention is described in further detail With reference to embodiment.But this should not be interpreted as to the present invention The range of above-mentioned theme is only limitted to following embodiments.Without departing from the idea case in the present invention described above, general according to this field Logical technological know-how and customary means, make various replacements and change, should all be included within the scope of the invention.
The natural plants hair-care hair dye based on biological crosslinked action of embodiment 1- embodiment 11 is shown in Table 1
Table 1
Embodiment 12
The preparation of natural plants hair-care hair dye based on biological crosslinked action:
By the formula of table 1, flower color glycosides colors are dissolved in suitable quantity of water, crosslinking agent, organic monoacid, increasing is added Thick dose and antioxidant add water to 100%, and stirring can obtain the thick natural plants shield based on biological crosslinked action of grey black Send out hair dye.
Embodiment 13
The preparation of natural plants hair-care hair dye based on biological crosslinked action:
By the formula of table 1, flower color glycosides colors are dissolved in suitable quantity of water, crosslinking agent, organic monoacid, increasing is added Thick dose, antioxidant, nutritional agents and conditioner add water to 100%, and it is thick based on biology crosslinking work that stirring can obtain grey black Natural plants hair-care hair dye.
Embodiment 14
The use of natural plants hair-care hair dye based on biological crosslinked action:
It is after being washed hair using 40-50 DEG C of warm water, the natural plants hair-care hair dye based on biological crosslinked action is appropriate, It is even to be applied to above moist white hair, it sufficiently rubs, warm water cleaning after being kept for 15 minutes.
Fig. 2 is the natural plants shield based on biological crosslinked action that the formula of embodiment 1 is prepared using the method for embodiment 12 Hair dye hair dyeing effect is sent out, still maintains color after 5 shampoos are had one's hair wash.Fig. 1 is sample of the hair after bleaching.
The natural plants hair care based on biological crosslinked action that the formula of Fig. 3 embodiment 8 is prepared using the method for embodiment 13 Hair dye hair dyeing effect still maintains color after 5 shampoos are had one's hair wash.
It is demonstrated experimentally that being handed over using prepared by the method for embodiment 12 based on biology with the formula of embodiment 2,3,4,5,6,7 The natural plants hair-care hair dye hair dyeing effect of connection effect still maintains color after 5 shampoos are had one's hair wash.
It is demonstrated experimentally that being made using prepared by the method for embodiment 13 based on biology crosslinking with the formula of embodiment 9,10,11 Natural plants hair-care hair dye hair dyeing effect still maintains color after 5 shampoos are had one's hair wash.
Rich in water-soluble group hydroxyl in flower color glycosides pigment molecular structure, the present invention, which passes through, is added all kinds of crosslinking agents, So that the groups such as amino, sulfydryl, carboxyl in hydroxyl and hair on pigment on the amino acid of protein occur to act in chemistry And it is crosslinked together, while it is also possible that the hydroxyl on anthocyanin molecule is crosslinked by cross-linking agent and to form molecular weight biggish big Molecule is not easy to be washed with water and cause to contaminate black hair bleaching to make the reduction of anthocyani pigment water solubility.

Claims (10)

1.基于生物交联作用的天然植物护发染发剂,其特征是按重量包括下述组分:植物花色苷色素类物质0.5%-2%;交联剂0.5%-0.8%;有机弱酸0.2%-0.3%;增稠剂0.5%-1%;抗氧化剂0.5%-0.8%;余量为水。1. The natural plant hair care hair dye based on biological cross-linking is characterized by comprising the following components by weight: 0.5%-2% of plant anthocyanin pigments; 0.5%-0.8% of cross-linking agent; 0.2% of organic weak acid %-0.3%; thickener 0.5%-1%; antioxidant 0.5%-0.8%; the balance is water. 2.根据权利要求1所述的染发剂,其特征是还包括营养剂0.5%-1%和调理剂0.2%-0.4%。2 . The hair dye according to claim 1 , further comprising 0.5%-1% of nutrient and 0.2%-0.4% of conditioning agent. 3 . 3.根据权利要求1所述的染发剂,其特征是所述植物花色苷色素类物质为植物花色苷色素和含植物花色苷色素的植物提取物中至少一种。3 . The hair dye according to claim 1 , wherein the plant anthocyanin pigment is at least one of a plant anthocyanin pigment and a plant extract containing a plant anthocyanin pigment. 4 . 4.根据权利要求3所述的染发剂,其特征是所述植物花色苷色素为矢车菊素-3-O-葡萄糖苷、飞燕草素-3-O-葡萄糖苷和矢车菊素-3-O-半乳糖苷中至少一种;所述含植物花色苷色素的植物提取物为黑豆提取物、黑芝麻提取物和桑葚提取物中至少一种。4. hair dye according to claim 3 is characterized in that described plant anthocyanin pigment is cyanidin-3-O-glucoside, delphinium-3-O-glucoside and cyanidin -At least one of 3-O-galactoside; the plant extract containing plant anthocyanin pigment is at least one of black soybean extract, black sesame extract and mulberry extract. 5.根据权利要求1所述的染发剂,其特征是所述交联剂为香草醛、水杨醛、栀子提取物、京尼平苷或京尼平。5. hair dye according to claim 1 is characterized in that described crosslinking agent is vanillin, salicylaldehyde, gardenia extract, geniposide or genipin. 6.根据权利要求1所述的染发剂,其特征是所述有机弱酸为醋酸、柠檬酸、乳酸和苹果酸中至少一种。6. hair dye according to claim 1 is characterized in that described organic weak acid is at least one in acetic acid, citric acid, lactic acid and malic acid. 7.根据权利要求1所述的染发剂,其特征是所述增稠剂为数均分子量5000-10000的聚丙烯酸钠、瓜尔胶、羧甲基纤维素、羟甲基丙基纤维素或吐温80。7. hair dye according to claim 1 is characterized in that described thickening agent is sodium polyacrylate, guar gum, carboxymethyl cellulose, hydroxymethyl propyl cellulose or polyester with number average molecular weight 5000-10000 Wen 80. 8.根据权利要求1所述的染发剂,其特征是所述抗氧化剂为维生素C、氯化亚铁和亚硫酸钠中至少一种。8. The hair dye according to claim 1, wherein the antioxidant is at least one of vitamin C, ferrous chloride and sodium sulfite. 9.根据权利要求2所述的染发剂,其特征是所述营养剂为何首乌提取物,人参提取物、生姜提取物或藤茶提取物。9 . The hair dye according to claim 2 , wherein the nutritional agent is He Shou Wu extract, ginseng extract, ginger extract or vine tea extract. 10 . 10.根据权利要求2所述的染发剂,其特征是所述调理剂为丙三醇、羟丙基瓜尔胶三甲基氯化铵或水溶性硅油。10. The hair dye according to claim 2, wherein the conditioning agent is glycerol, hydroxypropyl guar trimethyl ammonium chloride or water-soluble silicone oil.
CN201811357903.XA 2018-11-15 2018-11-15 Natural plants hair-care hair dye based on biological crosslinked action Pending CN109528538A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114344182A (en) * 2022-02-17 2022-04-15 刘子抄 Hair dye containing natural plant active ingredients and preparation method thereof
CN114869802A (en) * 2022-07-06 2022-08-09 美慕(北京)科技有限公司 Mussel protein composition with hair care and dyeing assisting effects and preparation method and application thereof

Citations (2)

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Publication number Priority date Publication date Assignee Title
JPH08268848A (en) * 1995-03-30 1996-10-15 Shiseido Co Ltd Hair oxidizing and dyeing agent composition
CN103505379A (en) * 2012-06-29 2014-01-15 西南民族大学 Natural hair dye prepared from iridoid and amino acid and hair dyeing method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08268848A (en) * 1995-03-30 1996-10-15 Shiseido Co Ltd Hair oxidizing and dyeing agent composition
CN103505379A (en) * 2012-06-29 2014-01-15 西南民族大学 Natural hair dye prepared from iridoid and amino acid and hair dyeing method

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
兰政文等: "《时尚女人66个年轻妙计》", 30 June 2011, 人民军医出版社 *
刘杰等: "黑豆多酚类物质研究进展", 《中国食品添加剂》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114344182A (en) * 2022-02-17 2022-04-15 刘子抄 Hair dye containing natural plant active ingredients and preparation method thereof
CN114869802A (en) * 2022-07-06 2022-08-09 美慕(北京)科技有限公司 Mussel protein composition with hair care and dyeing assisting effects and preparation method and application thereof
CN114869802B (en) * 2022-07-06 2022-10-04 美慕(北京)科技有限公司 Mussel protein composition with hair care and dyeing assisting effects and preparation method and application thereof

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