CN109517520B - Aerogel coating, aerogel coating and method for preparing aerogel coating from aerogel coating - Google Patents
Aerogel coating, aerogel coating and method for preparing aerogel coating from aerogel coating Download PDFInfo
- Publication number
- CN109517520B CN109517520B CN201811409183.7A CN201811409183A CN109517520B CN 109517520 B CN109517520 B CN 109517520B CN 201811409183 A CN201811409183 A CN 201811409183A CN 109517520 B CN109517520 B CN 109517520B
- Authority
- CN
- China
- Prior art keywords
- coating
- aerogel
- auxiliary agent
- aerogel coating
- particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 205
- 239000011248 coating agent Substances 0.000 title claims abstract description 197
- 239000004964 aerogel Substances 0.000 title claims abstract description 178
- 238000000034 method Methods 0.000 title claims abstract description 31
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 45
- 239000002245 particle Substances 0.000 claims abstract description 41
- 239000012767 functional filler Substances 0.000 claims abstract description 30
- 239000000758 substrate Substances 0.000 claims abstract description 28
- 229920005989 resin Polymers 0.000 claims abstract description 25
- 239000011347 resin Substances 0.000 claims abstract description 25
- 239000011159 matrix material Substances 0.000 claims abstract description 24
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000001035 drying Methods 0.000 claims abstract description 17
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 12
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 12
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 12
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 12
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004593 Epoxy Substances 0.000 claims abstract description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 23
- 239000000835 fiber Substances 0.000 claims description 14
- 239000012763 reinforcing filler Substances 0.000 claims description 13
- 239000011521 glass Substances 0.000 claims description 7
- 239000004005 microsphere Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 239000010453 quartz Substances 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 239000004965 Silica aerogel Substances 0.000 claims description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 5
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 3
- 239000004917 carbon fiber Substances 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 125000003944 tolyl group Chemical group 0.000 claims description 2
- 239000003973 paint Substances 0.000 claims 5
- 229920002125 Sokalan® Polymers 0.000 claims 2
- 239000004584 polyacrylic acid Substances 0.000 claims 2
- 159000000000 sodium salts Chemical class 0.000 claims 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims 1
- 239000004408 titanium dioxide Substances 0.000 claims 1
- 238000009413 insulation Methods 0.000 abstract description 24
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 abstract description 9
- 229920002379 silicone rubber Polymers 0.000 abstract description 6
- 239000002671 adjuvant Substances 0.000 abstract 1
- 239000004945 silicone rubber Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 11
- 239000000843 powder Substances 0.000 description 9
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 8
- 238000005507 spraying Methods 0.000 description 8
- 235000012239 silicon dioxide Nutrition 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 239000012720 thermal barrier coating Substances 0.000 description 5
- 239000002131 composite material Substances 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229920002050 silicone resin Polymers 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 1
- 238000002679 ablation Methods 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007590 electrostatic spraying Methods 0.000 description 1
- -1 glycidyl amines Chemical class 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C09D161/14—Modified phenol-aldehyde condensates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Silicon Compounds (AREA)
Abstract
本发明涉及一种气凝胶涂料、气凝胶涂层及由气凝胶涂料制备气凝胶涂层的方法。气凝胶涂料包含以质量百分比计为35～90％的涂料基体、5～45％的功能填料和5～50％的助剂；涂料基体选自由环氧改性树脂、酚醛改性树脂、有机硅改性树脂和有机硅橡胶组成的组；功能填料包含气凝胶颗粒；助剂选自由甲苯、环己烷、聚乙二醇、聚乙烯醇、聚丙烯酸钠盐、丙酮和乙醇组成的组。所述方法包括：将气凝胶涂料涂布于基材表面，依次进行干燥和固化，制得所述涂层。本发明的气凝胶涂料分散性好、稳定性好，所述涂层耐高温性能及隔热性能好；本发明方法操作简便、易于实施，能适用在各种形状规格的构件上制备涂层，在航天、航空等领域具有广泛的应用前景。The invention relates to an aerogel coating, an aerogel coating and a method for preparing the aerogel coating from the aerogel coating. The aerogel coating contains 35-90% of the coating matrix, 5-45% of the functional filler and 5-50% of the auxiliary agent by mass percentage; the coating matrix is selected from epoxy modified resin, phenolic modified resin, organic the group consisting of silicon-modified resin and silicone rubber; the functional filler comprises aerogel particles; the adjuvant is selected from the group consisting of toluene, cyclohexane, polyethylene glycol, polyvinyl alcohol, polyacrylate sodium salt, acetone and ethanol . The method includes: coating the aerogel coating on the surface of the substrate, drying and curing in sequence to prepare the coating. The aerogel coating of the invention has good dispersibility and stability, and the coating has good high temperature resistance and heat insulation performance; the method of the invention is simple to operate and easy to implement, and can be applied to prepare coatings on components of various shapes and specifications , has a wide range of application prospects in aerospace, aviation and other fields.
Description
Technical Field
The invention belongs to the technical field of high-temperature-resistant coatings, and particularly relates to an aerogel coating, an aerogel coating and a method for preparing the aerogel coating from the aerogel coating.
Background
The thermal insulation coating used on the aerospace craft is mainly divided into two systems of an organic thermal insulation coating and an inorganic thermal insulation coating. The organic heat-insulating coating mainly utilizes the ablation resistance of cracking and carbonizing of the organic polymer to offset the temperature rise of the surface of the aircraft caused by pneumatic heating so as to realize the heat-insulating function. The liquid organic heat-insulating coating has the advantages of convenient paving, easy implementation and the like, but the density range of the organic heat-insulating coating layer which is usually prepared by the organic heat-insulating coating is about 0.5-1.3 g/cm3The heat conductivity coefficient at room temperature is about 0.2-0.3W/m.K, the specific heat capacity range is about 1.5-2.0J/g.K, the thickness is about 0.05-2 mm, the use temperature range is about 400-600 ℃, and the problems of high density and heat conductivity, poor temperature resistance and heat insulation performance and the like exist.
Compared with an organic thermal insulation coating, an inorganic thermal insulation coating, such as an aerogel thermal insulation coating, has the advantages of low density and thermal conductivity, excellent temperature resistance and thermal insulation performance and the like, because the nano-pores and the three-dimensional network structure of the aerogel can effectively prevent heat conduction, limit the free flow of air molecules, inhibit convection conduction, and infinite pore walls form a reflecting surface and a refracting surface of heat radiation, thereby maximally inhibiting radiation heat conduction and having very low thermal conductivity. Therefore, the aerogel is used in the thermal insulation coating, so that the thermal insulation effect of the aerogel is greatly improved. However, the aerogel is generally a powder product, and the aerogel composite material (e.g. fiber reinforced aerogel composite insulation material) is generally a block material or a powder material, and both the aerogel and the aerogel composite material have problems of complicated preparation process, difficulty in implementation and the like when the aerogel or the aerogel composite material is applied to the surface of a component to prepare an insulation coating.
At present, because of the problems of poor dispersibility, compatibility and stability between the liquid organic coating and the aerogel particles, no report on the preparation of an aerogel coating by using the liquid organic coating and the aerogel particles is found. Chinese patent application 200710144320.4 discloses a powder coating containing aerogel particles and a method for preparing the same, wherein the powder coating is not a mixture of pure powder resin particles and aerogel particles, but the powder coating used for preparing a coating can be prepared by sequentially carrying out the steps of premixing, melt extrusion, flaking, crushing and the like.
Disclosure of Invention
In order to solve the technical problems in the prior art, the invention provides an aerogel coating, an aerogel coating and a method for preparing the aerogel coating from the aerogel coating. The aerogel coating disclosed by the invention has the advantages of good dispersibility and good stability; the aerogel coating disclosed by the invention has the advantages of good high-temperature resistance, low density, low heat conductivity coefficient and the like; the method is simple, simple and convenient to operate, easy to implement and low in environmental pollution.
In order to achieve the above object, the present invention provides, in a first aspect, an aerogel coating including, by mass, 35 to 90% of a coating base, 5 to 45% of a functional filler, and 5 to 50% of an auxiliary agent; the coating matrix is selected from the group consisting of epoxy modified resin, phenolic modified resin, organic silicon modified resin and organic silicon rubber; the functional filler comprises aerogel particles; the auxiliary agent is selected from the group consisting of toluene, cyclohexane, polyethylene glycol, polyvinyl alcohol, sodium polyacrylate, acetone and ethanol.
Preferably, the functional filler further comprises a reinforcing filler.
Preferably, the mass ratio of the reinforcing filler to the aerogel particles is (0.1-1): 1.
Preferably, the reinforcing filler is selected from the group consisting of hollow glass microspheres, high silica fibers, glass fibers, quartz fibers, alumina fibers and carbon fibers.
Preferably, the aerogel particles are selected from the group consisting of silica aerogel particles, alumina aerogel particles, zirconia aerogel particles, and titania aerogel particles.
The present invention provides, in a second aspect, a method of preparing an aerogel coating from the aerogel coating of the present invention described in the first aspect, the method comprising the steps of:
(1) uniformly mixing 35-90% of a coating matrix, 5-45% of a functional filler and 5-50% of an auxiliary agent in percentage by mass to obtain the aerogel coating;
(2) coating the aerogel coating on the surface of a substrate;
(3) and sequentially performing a drying step and a curing step on the substrate coated with the aerogel coating, thereby preparing the aerogel coating on the substrate.
Preferably, the drying temperature is 20-120 ℃, and the drying time is 0.1-24 h.
Preferably, the curing temperature is 50-200 ℃, and the curing time is 1-72 hours.
Preferably, the method further comprises the step of cleaning the surface of the substrate before performing step (2).
In a third aspect, the present invention provides an aerogel coating made from the aerogel coating of the first aspect of the present invention or the method of the second aspect of the present invention.
Compared with the prior art, the invention at least has the following beneficial effects:
(1) the aerogel coating comprises, by mass, 35-90% of a coating matrix, 5-45% of a functional filler and 5-50% of an auxiliary agent, and by reasonable proportioning of the components and selection of the types of the coating matrix and the auxiliary agent, the problem that the heat insulation performance of a coating is poor due to poor dispersibility, compatibility and stability between a liquid organic coating and aerogel particles can be effectively avoided, and the problem that the heat insulation performance of an aerogel coating made of the aerogel coating is reduced due to the fact that the liquid organic coating is easily immersed into nano holes of the aerogel can be effectively avoided; the aerogel coating disclosed by the invention has the advantages of good dispersibility, good stability and the like.
(2) The method can directly adopt the aerogel coating to directly coat on the substrate to prepare the aerogel coating, and has the advantages of simple preparation method, simple and convenient operation, easy implementation, small environmental pollution and the like; the method can be used for preparing aerogel heat-insulating coatings on component products with various shapes and specifications, and has wide application prospect in the environments requiring high temperature resistance and high-efficiency heat insulation, such as aerospace and the like.
(3) The aerogel coating disclosed by the invention is good in high-temperature resistance, adjustable in use temperature and capable of being used for a long time at the temperature of 400-800 ℃; the aerogel coating has low heat conductivity, and the heat conductivity coefficient is 0.02-0.1W/m.K; the aerogel coating prepared by the invention has the advantages of smooth and clean surface and beautiful appearance.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the technical solutions of the present invention will be clearly and completely described below with reference to the embodiments of the present invention. It is to be understood that the embodiments described are only a few embodiments of the present invention, and not all embodiments. All other embodiments, which can be obtained by a person skilled in the art without any inventive step based on the embodiments of the present invention, are within the scope of the present invention.
The invention provides an aerogel coating in a first aspect, the aerogel coating (aerogel thermal insulation coating) comprises, by mass percent, 35-90% (e.g., 35%, 40%, 45%, 50%, 55%, 60%, 65%, 70%, 75%, 80%, 85%, or 90%) of a coating matrix, 5-45% (e.g., 5%, 10%, 15%, 20%, 25%, 30%, 35%, 40%, or 45%) of a functional filler, and 5-50% (e.g., 5%, 10%, 15%, 20%, 25%, 30%, 35%, 40%, 45%, or 50%) of an auxiliary agent; the coating matrix is selected from the group consisting of epoxy modified resins (e.g., glycidyl ethers, glycidyl esters, glycidyl amines or aliphatic epoxy modified resins), phenolic modified resins (e.g., borophenolic modified resins, barium phenolic modified resins, polyvinyl acetal phenolic modified resins or polyamide phenolic modified resins), silicone modified resins (e.g., alkyd modified silicone resins, epoxy modified silicone resins, acrylic silicone resins) and silicone rubbers; the functional filler comprises aerogel particles; the auxiliary agent is selected from the group consisting of toluene, cyclohexane, polyethylene glycol, polyvinyl alcohol, sodium polyacrylate, acetone and ethanol. The coating substrate in the present invention is a liquid coating substrate (liquid organic coating); according to the aerogel coating disclosed by the invention, through reasonable proportioning of the components and selection of the coating matrix and the types of the additives, the problems of poor dispersibility, compatibility and stability between the liquid organic coating and aerogel particles can be effectively avoided, and the problem that the heat insulation performance of an aerogel coating prepared from the aerogel coating is reduced due to the fact that the liquid organic coating is easily immersed into nano holes of the aerogel can be effectively avoided; the aerogel coating disclosed by the invention has the advantages of good dispersibility, good stability and the like, and can effectively improve the comprehensive performance of the aerogel coating prepared from the aerogel coating, so that the prepared aerogel coating has the advantages of low density, low heat conductivity coefficient (good heat insulation performance) and good high temperature resistance, and can be applied to a high-temperature environment for a long time (good stability).
According to some preferred embodiments, the aerogel coating comprises, by mass, 35 to 50% (e.g., 35%, 40%, 45%, or 50%) of a coating matrix, 15 to 35% (e.g., 15%, 20%, 25%, 30%, or 35%) of a functional filler, and 30 to 45% (e.g., 30%, 35%, 40%, or 45%) of an auxiliary agent, so that uniform dispersibility of the aerogel coating can be effectively ensured and coating is facilitated (good coatability) and comprehensive performance of the aerogel coating made of the aerogel coating can be further ensured.
According to some preferred embodiments, the auxiliary agent consists of a first auxiliary agent selected from the group consisting of polyethylene glycol (polyethylene glycol-based dispersing agent), polyvinyl alcohol (polyvinyl alcohol-based dispersing agent), and sodium polyacrylate salt (sodium polyacrylate-based dispersing agent), and a second auxiliary agent selected from the group consisting of toluene, cyclohexane, acetone, and ethanol; in the invention, preferably, the auxiliary agent is composed of a first auxiliary agent and a second auxiliary agent, so that the aerogel particles can be dispersed more uniformly in the liquid organic coating, the stability of the aerogel coating is better, and more importantly, the liquid organic coating can be more effectively prevented from being immersed into nano holes of the aerogel particles, so that the comprehensive properties of the aerogel coating made of the aerogel coating, such as heat insulation property, high-temperature stability, high-temperature resistance, and the like, can be further ensured.
According to some preferred embodiments, the volume ratio of the first auxiliary agent to the second auxiliary agent is (0.5-1: 1) (e.g., 0.5:1, 0.55:1, 0.6:1, 0.65:1, 0.7:1, 0.75:1, 0.8:1, 0.85:1, 0.9:1, 0.95:1, or 1: 1).
According to some preferred embodiments, the functional filler further comprises a reinforcing filler; the addition of the reinforcing filler can enhance the strength and the wear resistance of the aerogel coating in the process of preparing the aerogel coating by adopting the aerogel coating, and can further ensure the stability of the aerogel coating in the using process.
According to some preferred embodiments, the mass ratio of the reinforcing filler to the aerogel particles is (0.1 to 1:1) (e.g., 0.1:1, 0.15:1, 0.2:1, 0.25:1, 0.3:1, 0.35:1, 0.4:1, 0.45:1, 0.5:1, 0.55:1, 0.65:1, 0.7:1, 0.75:1, 0.8:1, 0.85:1, 0.9:1, 0.95:1, or 1:1), preferably (0.3 to 0.8): 1 (e.g., 0.3:1, 0.35:1, 0.4:1, 0.45:1, 0.5:1, 0.55:1, 0.65:1, 0.7:1, 0.75:1, or 0.8: 1). In the invention, the mass ratio of the reinforcing filler to the aerogel particles is preferably (0.1-1): 1, the content of the reinforcing filler cannot be too high, and the addition of too much reinforcing filler is not beneficial to forming the aerogel coating with good dispersibility, good compatibility and good stability.
According to some preferred embodiments, the reinforcing filler is selected from the group consisting of hollow glass microspheres, high silica fibers, glass fibers, quartz fibers, alumina fibers and carbon fibers.
According to some preferred embodiments, the aerogel particles are selected from the group consisting of silica aerogel particles, alumina aerogel particles, zirconia aerogel particles, and titania aerogel particles. In the present invention, the porosity of the aerogel particles may be, for example, 50 to 99%, and the particle size of the aerogel particles may be, for example, 0.0001 to 0.2 mm.
The present invention provides, in a second aspect, a method of preparing an aerogel coating from the aerogel coating of the present invention described in the first aspect, the method comprising the steps of:
(1) uniformly mixing 35-90% of a coating matrix, 5-45% of a functional filler and 5-50% of an auxiliary agent in percentage by mass to obtain the aerogel coating; for example, the coating matrix, the functional filler and the auxiliary agent are stirred, dispersed and uniformly mixed to prepare the aerogel coating (slurry);
(2) coating the aerogel coating on the surface of a substrate;
(3) the substrate coated with the aerogel coating is sequentially subjected to a drying step and a curing step, thereby producing the aerogel coating (aerogel thermal barrier coating) on the substrate.
In the present invention, the aerogel coating can be applied to the surface of the substrate by, for example, conventional brushing or conventional spraying, which can be performed by using, for example, an existing brushing tool or an existing spraying device, and the thickness of the aerogel coating can be determined according to the needs of the use environment; the substrate can be, for example, a component product for which a thermal barrier coating is to be prepared, such as a component product for use in an environment requiring high temperature resistance and high thermal insulation, such as aerospace and the like. According to the invention, the aerogel coating with good dispersibility and stability is adopted to prepare the aerogel coating, so that the uniformity of the dispersion of the coating matrix, the functional filler and the residual auxiliary agent in the aerogel coating can be effectively ensured, and the comprehensive performances of the aerogel coating, such as high temperature resistance, heat insulation performance, high temperature stability and the like, can be favorably ensured. The method can directly adopt the aerogel coating to directly coat on the substrate to prepare the aerogel coating without special treatment, and has the advantages of simple preparation method, simple and convenient operation, easy implementation, small environmental pollution and the like; the method can be used for preparing the aerogel coating on component products with various shapes and specifications, and has wide application prospect in the environments requiring high temperature resistance and high-efficiency heat insulation, such as aerospace and the like.
In the invention, the aerogel coating comprises, by mass, 35-90% of a coating matrix, 5-45% of a functional filler and 5-50% of an auxiliary agent, and within the range of the mixture ratio and the range of the types of the components, the aerogel coating prepared from the aerogel coating can have different densities, different tolerance to use environment temperatures, different heat insulation properties and the like under the combined action of the components in different types and different proportions.
According to some preferred embodiments, the drying is at a temperature of 20 to 120 ℃ (e.g., 20 ℃, 25 ℃, 30 ℃, 35 ℃, 40 ℃, 45 ℃, 50 ℃, 55 ℃, 60 ℃, 65 ℃, 70 ℃, 75 ℃, 80 ℃, 85 ℃, 90 ℃, 95 ℃, 100 ℃, 105 ℃, 110 ℃, 115 ℃ or 120 ℃), and the drying is for a time of 0.1 to 24 hours (e.g., 0.1, 0.5, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23 or 24 hours).
According to some preferred embodiments, the curing temperature is 50 to 200 ℃ (e.g., 50 ℃, 60 ℃, 70 ℃, 80 ℃, 90 ℃, 100 ℃, 110 ℃, 120 ℃, 130 ℃, 140 ℃, 150 ℃, 160 ℃, 170 ℃, 180 ℃, 190 ℃ or 200 ℃) and the curing time is 1 to 72 hours (e.g., 1, 3, 5, 6, 8, 10, 12, 15, 20, 24, 30, 36, 40, 48, 54, 58, 60, 65, 70 or 72 hours).
In the invention, the drying step is preferably carried out at the temperature of 20-120 ℃ for 0.1-24 h, and the curing step is preferably carried out at the temperature of 20-200 ℃ for 1-72 h, so that the uniformity of the dispersion of the coating matrix, the functional filler and the residual auxiliary agent in the aerogel coating can be further ensured, and the comprehensive performances of the aerogel coating, such as high-temperature resistance, heat insulation performance, high-temperature stability and the like, are better.
According to some preferred embodiments, the method further comprises the step of cleaning the surface of the substrate prior to performing step (2). In the present invention, for example, 400#, 800#, 1200# sandpaper may be used to abrade the surface of a substrate in sequence, and then the abraded surface of the substrate may be washed with clean water or ultrasonically cleaned with an acetone solution according to the size of the substrate.
In a third aspect, the present invention provides an aerogel coating made from the aerogel coating of the first aspect of the present invention or the method of the second aspect of the present invention. The aerogel coating disclosed by the invention is good in high-temperature resistance, adjustable in use temperature and capable of being used for a long time at the temperature of 400-800 ℃ (good in high-temperature stability); the aerogel coating has low heat conductivity, and the heat conductivity coefficient is 0.02-0.1W/m.K; the aerogel coating prepared by the invention has the advantages of smooth and clean surface and beautiful appearance.
The present invention will be further described with reference to the following examples. These examples are merely illustrative of preferred embodiments of the present invention and the scope of the present invention should not be construed as being limited to these examples.
The raw materials involved in the embodiments of the present invention are all commercially available.
Example 1
Preparing an aerogel coating by adopting the aerogel coating: the aerogel coating comprises a coating matrix, a functional filler, an auxiliary agent and a coating additive, wherein the coating matrix is organic silicon modified resin (epoxy resin modified organic silicon resin), the functional filler is silica aerogel particles and quartz fibers in a mass ratio of 1:0.5, and the auxiliary agent is polyethylene glycol, polyvinyl alcohol, sodium polyacrylate and toluene in a volume ratio of 0.3:0.3:0.3: 1; the preparation steps of the aerogel coating are as follows:
firstly, uniformly dispersing and mixing a coating matrix, a functional filler and an auxiliary agent according to the mass percent of 45 percent to 15 percent to 40 percent to prepare the aerogel coating (slurry).
Secondly, spraying the aerogel coating on the surface of the base material, drying at 50 ℃ for 60min, and curing at 150 ℃ for 3h to obtain the aerogel coating.
The performance of the aerogel coating in this example was tested: the sample can resist 500 ℃ (500 ℃ for 1h without shrinkage) and has density of 0.4g/cm3(GB/T6343-1995), the thermal conductivity at room temperature is 0.085W/m.K (GB/T10295-2008); the temperature resistance of the aerogel coating refers to the highest temperature which can be endured when the aerogel coating is subjected to high-temperature treatment for 1 hour and the sample of the aerogel coating is not shrunk, namely the enduring temperature.
Example 2
Preparing an aerogel coating by adopting the aerogel coating: the aerogel coating comprises a coating matrix which is organic silicon rubber, functional fillers which are silicon dioxide aerogel particles and hollow glass microspheres in a mass ratio of 1:0.5, and auxiliaries which are polyethylene glycol, polyvinyl alcohol, sodium polyacrylate and cyclohexane in a volume ratio of 0.3:0.3:0.3: 1; the preparation steps of the aerogel coating are as follows:
firstly, dispersing and mixing a coating matrix, a functional filler and an auxiliary agent uniformly according to the mass percentage of 40 percent to 25 percent to 35 percent to prepare the aerogel coating (slurry).
Secondly, spraying the aerogel coating on the surface of the base material, drying at 80 ℃ for 30min, and curing at 80 ℃ for 6h to obtain the aerogel coating.
The performance of the aerogel coating in this example was tested: the sample can resist 600 ℃ (600 ℃ for 1h without shrinkage) and has density of 0.35g/cm3(GB/T6343-1995) and the room-temperature thermal conductivity coefficient of 0.05W/m.K (GB/T10295-2008).
Example 3
Example 3 is essentially the same as example 1, except that:
the coating matrix is phenolic modified resin (boron phenolic modified resin); the auxiliary agent is polyethylene glycol, polyvinyl alcohol, sodium polyacrylate and ethanol with the volume ratio of 0.3:0.3:0.3: 1; 35 percent to 30 percent to 35 percent of the mass percentage of the coating substrate, the functional filler and the auxiliary agent; ②, the drying temperature is 80 ℃, the drying time is 60min, the curing temperature is 180 ℃, and the curing time is 6 h.
The properties of the aerogel coatings prepared in this example are shown in table 1.
Example 4
Example 4 is essentially the same as example 2, except that:
the functional filler is silicon dioxide aerogel particles, hollow glass microspheres and high silica fibers in a mass ratio of 1:0.25: 0.25; the mass percentage of the coating substrate, the functional filler and the auxiliary agent is 35 percent to 30 percent to 35 percent.
The properties of the aerogel coatings prepared in this example are shown in table 1.
Example 5
Example 5 is essentially the same as example 1, except that:
the mass percentage of the coating substrate, the functional filler and the auxiliary agent is 60 percent to 15 percent to 25 percent.
The properties of the aerogel coatings prepared in this example are shown in table 1.
Example 6
Example 6 is essentially the same as example 1, except that:
the mass percentage of the coating substrate, the functional filler and the auxiliary agent is 30 percent to 40 percent to 30 percent.
The properties of the aerogel coatings prepared in this example are shown in table 1.
Example 7
Example 7 is essentially the same as example 1, except that:
the auxiliary agent is toluene.
The properties of the aerogel coatings prepared in this example are shown in table 1.
Comparative example 1
Preparing an organic heat-insulating coating: the coating comprises organic silicon modified resin (epoxy resin modified organic silicon resin), quartz fiber as a filler, polyethylene glycol with the volume ratio of 0.3:0.3:0.3:1 as an auxiliary agent, polyvinyl alcohol, sodium polyacrylate and toluene; the preparation steps of the organic heat-insulating coating are as follows:
firstly, uniformly dispersing and mixing 45 mass percent of organoalkoxysilane resin, 15 mass percent of quartz fiber and 40 mass percent of auxiliary agent to prepare slurry.
Secondly, spraying the coating on the surface of the substrate, drying at 50 ℃ for 60min, and curing at 150 ℃ for 3h to obtain the organic heat-insulating coating.
The performance of the organic thermal barrier coating in this comparative example was tested: the sample can resist 500 ℃ (500 ℃ for 1h without shrinkage) and has a density of 1.0g/cm3(GB/T6343-1995) and the room-temperature thermal conductivity coefficient of 0.2W/m.K (GB/T10295-2008).
Comparative example 2
Preparing an organic heat-insulating coating: the coating comprises organic silicon rubber, filler which is hollow glass microspheres, and auxiliary agent which is polyethylene glycol, polyvinyl alcohol, sodium polyacrylate and cyclohexane with the volume ratio of 0.3:0.3:0.3: 1; the preparation steps of the organic heat-insulating coating are as follows:
firstly, uniformly dispersing and mixing organic silicon rubber, hollow glass microspheres and an auxiliary agent according to the mass percentage of 40 percent to 25 percent to 35 percent to prepare slurry.
Secondly, spraying the coating on the surface of the substrate, drying at 80 ℃ for 30min, and curing at 80 ℃ for 6h to obtain the organic heat-insulating coating.
The performance of the organic thermal barrier coating in this comparative example was tested: the sample can resist 350 ℃ (350 ℃ for 1h without shrinkage) and has a density of 0.6g/cm3(GB/T6343-1995) and the room-temperature thermal conductivity coefficient is 0.15W/m.K (GB/T10295-2008).
Comparative example 3
Weighing 50% of hydrophobic silica aerogel particles, 49.5% of powdered epoxy resin and 0.5% of acrylic flatting agent according to volume percentage, adding into a high-speed mixer, and premixing for 3min at 1000 r/min.
And feeding the mixed materials into a melt extruder for melt extrusion at the temperature of 90 ℃.
And thirdly, pressing the mixture into slices by a cooling tablet press, wherein the cooling temperature is 40 ℃.
And fourthly, crushing the cooled sheet into small sheets with the size of 1-2 mm by a roller mill.
Fifthly, feeding the small flaky material in the fourth step into air classification grinding equipment to be ground into powder with the particle size of 0.01-0.08 mm, and screening to obtain the powder coating with the particle size of 0.04-0.08 mm.
Spraying the prepared powder coating containing the aerogel on a metal sheet with the thickness of 0.16mm by adopting an electrostatic spraying process and the thickness of 100 multiplied by 100mm, and curing for 10min at the temperature of 200 ℃; and repeatedly spraying and curing for 5 times to obtain the heat-insulating coating.
The performance of the thermal barrier coating of this comparative example was tested: the sample can resist 300 ℃ (treated at 300 ℃ for 1h without shrinkage) and has density of 0.65g/cm3(GB/T6343-1995) and the room-temperature thermal conductivity coefficient of 0.1W/m.K (GB/T10295-2008).
Finally, the description is as follows: the above examples are only intended to illustrate the technical solution of the present invention, but not to limit it; although the invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical solutions described in the embodiments can still be modified, or some technical features can be equivalently replaced; and such modifications or substitutions do not depart from the spirit and scope of the present invention in its spirit and scope.
Claims (10)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811409183.7A CN109517520B (en) | 2018-11-23 | 2018-11-23 | Aerogel coating, aerogel coating and method for preparing aerogel coating from aerogel coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811409183.7A CN109517520B (en) | 2018-11-23 | 2018-11-23 | Aerogel coating, aerogel coating and method for preparing aerogel coating from aerogel coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109517520A CN109517520A (en) | 2019-03-26 |
| CN109517520B true CN109517520B (en) | 2021-04-30 |
Family
ID=65777481
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811409183.7A Active CN109517520B (en) | 2018-11-23 | 2018-11-23 | Aerogel coating, aerogel coating and method for preparing aerogel coating from aerogel coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109517520B (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110093141A (en) * | 2019-05-06 | 2019-08-06 | 深圳市华星光电技术有限公司 | The production method of combined material for flexible base board removing and preparation method thereof, flexible panel |
| CN110527400B (en) * | 2019-09-05 | 2021-09-07 | 九牧厨卫股份有限公司 | Water-based weather-resistant coating |
| CN110860450A (en) * | 2019-11-01 | 2020-03-06 | 河南爱彼爱和新材料有限公司 | Composite aerogel fiber spray coating and preparation process thereof |
| CN112029329B (en) * | 2020-07-24 | 2022-07-05 | 航天材料及工艺研究所 | High-temperature-resistant composite material protective coating and preparation method thereof |
| CN113929962B (en) * | 2021-10-22 | 2023-02-17 | 航天特种材料及工艺技术研究所 | Aerogel surface high-temperature-resistant composite coating and preparation method thereof |
| CN113881338B (en) * | 2021-10-28 | 2022-05-17 | 广东电网有限责任公司 | Moss-preventing hydrophobic paint and its preparing method |
| CN114015101A (en) * | 2022-01-06 | 2022-02-08 | 中建材科创新技术研究院(山东)有限公司 | Ocean engineering pipeline prepared based on aerogel coating and preparation method thereof |
| CN114479602B (en) * | 2022-03-15 | 2023-01-31 | 航天特种材料及工艺技术研究所 | Repair coating for aerogel surface defects and preparation method and application thereof |
| CN115627119B (en) * | 2022-10-11 | 2023-06-20 | 航天特种材料及工艺技术研究所 | Light temperature-resistant heat-insulating stealth coating, coating and preparation method thereof |
| CN115637061B (en) * | 2022-10-11 | 2024-05-07 | 航天特种材料及工艺技术研究所 | Preparation method of heat-insulating filler for high-performance heat-insulating coating |
| CN115651529B (en) * | 2022-10-11 | 2023-06-20 | 航天特种材料及工艺技术研究所 | High-performance nano heat-insulating coating, coating and preparation method thereof |
| CN116254033B (en) * | 2023-01-29 | 2024-06-21 | 上海箬宇新材料有限公司 | Flexible low-density ablation heat-resistant coating and preparation method thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9725601B2 (en) * | 2011-04-04 | 2017-08-08 | Carnegie Mellon University | Carbon nanotube aerogels, composites including the same, and devices formed therefrom |
| CN102367353B (en) * | 2011-10-12 | 2014-01-08 | 上海海隆赛能新材料有限公司 | Low thermal conductivity composite thermal insulation paint and preparation method thereof |
| CN103725124B (en) * | 2013-08-02 | 2017-02-15 | 太仓派欧技术咨询服务有限公司 | High-radiation heat-insulated coating |
| CN104017453B (en) * | 2014-06-16 | 2016-10-05 | 大连新俄科技有限公司 | A kind of non-toxic water-based microcapsule anti-mildew thermal insulation coating and preparation method thereof |
| CN105802486A (en) * | 2016-03-31 | 2016-07-27 | 华南理工大学 | Normal-temperature-curable high-temperature-resistant, corrosion-resistant and heat-insulating material for petrochemical pipelines as well as preparation method and applications of material |
| CN108610815A (en) * | 2016-12-28 | 2018-10-02 | 刘朝辉 | Aerosil composite thermal barrier coatings and preparation method thereof |
-
2018
- 2018-11-23 CN CN201811409183.7A patent/CN109517520B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN109517520A (en) | 2019-03-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109517520B (en) | Aerogel coating, aerogel coating and method for preparing aerogel coating from aerogel coating | |
| CN107903751B (en) | Graphene heat dissipation coating and preparation method thereof | |
| CN102807803B (en) | Method for preparing organic and inorganic composite super-hydrophobic coatings | |
| CN103214897B (en) | Graphene nonstick paint | |
| CN1297617C (en) | Aqueous emulsion type electromagnetic wave shielded coating and preparation process thereof | |
| CN102367353B (en) | Low thermal conductivity composite thermal insulation paint and preparation method thereof | |
| CN101857768B (en) | Ultrasonically-modified nano heat-insulating powder coating for aluminum alloy section and method for preparing same | |
| CN110484097A (en) | A kind of composite electromagnetic screen conductive coating and preparation method thereof and application method | |
| CN104789175A (en) | Insulating and thermal conductive ablation resistant adhesive and application thereof in lightning protection | |
| CN108624056A (en) | A kind of High thermal-conductive silicone grease boundary material and preparation method thereof | |
| CN109836996A (en) | Aqueous thermally conductive anticorrosive paint of one kind and preparation method thereof | |
| CN113308075A (en) | Hydrophobic powder/polytetrafluoroethylene composite material and preparation method thereof | |
| CN109439088B (en) | Preparation method of silver-plated graphene-containing composite slurry and application of composite slurry in electrothermal coating | |
| CN110760233A (en) | Heat-conducting composite coating and heat-conducting coating prepared from same | |
| CN107857593A (en) | A kind of high hydrophobic foam silicon carbide ceramics and its preparation method and application | |
| CN107674349A (en) | Low-dielectric-constant fluorine-containing polymer composite material and preparation method thereof | |
| CN101948649A (en) | Calcium silicate nanowire composite thermal-insulation coating | |
| Lv et al. | A PDMS modified polyurethane/Ag composite coating with super-hydrophobicity and low infrared emissivity | |
| CN102249652B (en) | Fiber composite material with microwave absorbing function and preparation method thereof | |
| CN116042132A (en) | Three-dimensional framework material, electronic packaging adhesive and preparation method and application thereof | |
| CN114103305B (en) | high-Tg high-heat-conductivity metal-based copper-clad plate and processing technology thereof | |
| KR102725353B1 (en) | Thermal insulation functional powder coating | |
| CN113801572B (en) | A kind of super-hydrophobic, highly stable nano-ceramic coating and using method thereof | |
| CN111500153A (en) | A kind of three-dimensional graphene water-based thermally conductive anti-corrosion coating and preparation method thereof | |
| CN111849275B (en) | Preparation method and application of water-based two-component electric heating coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |