CN109504281A - A kind of emulsion-type mould release and preparation method thereof - Google Patents
A kind of emulsion-type mould release and preparation method thereof Download PDFInfo
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- CN109504281A CN109504281A CN201811241961.6A CN201811241961A CN109504281A CN 109504281 A CN109504281 A CN 109504281A CN 201811241961 A CN201811241961 A CN 201811241961A CN 109504281 A CN109504281 A CN 109504281A
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- silicone oil
- vinyl
- emulsion
- mould release
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- 238000002360 preparation method Methods 0.000 title claims description 17
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 102
- 229920002545 silicone oil Polymers 0.000 claims abstract description 90
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 89
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 79
- 239000001257 hydrogen Substances 0.000 claims abstract description 61
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 61
- 239000008367 deionised water Substances 0.000 claims abstract description 42
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 42
- 150000002431 hydrogen Chemical class 0.000 claims abstract description 36
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 34
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 34
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 21
- 239000003054 catalyst Substances 0.000 claims abstract description 19
- 239000003381 stabilizer Substances 0.000 claims abstract description 18
- 239000003112 inhibitor Substances 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000003921 oil Substances 0.000 claims description 19
- 229920000570 polyether Polymers 0.000 claims description 19
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 18
- 238000006136 alcoholysis reaction Methods 0.000 claims description 18
- 150000003376 silicon Chemical class 0.000 claims description 18
- 229920001296 polysiloxane Polymers 0.000 claims description 13
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 12
- 239000001301 oxygen Substances 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- -1 poly(oxygen-silicon) Polymers 0.000 claims description 8
- 239000004593 Epoxy Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- QYLFHLNFIHBCPR-UHFFFAOYSA-N 1-ethynylcyclohexan-1-ol Chemical compound C#CC1(O)CCCCC1 QYLFHLNFIHBCPR-UHFFFAOYSA-N 0.000 claims description 4
- 239000007859 condensation product Substances 0.000 claims description 4
- WGRZHLPEQDVPET-UHFFFAOYSA-N 2-methoxyethoxysilane Chemical compound COCCO[SiH3] WGRZHLPEQDVPET-UHFFFAOYSA-N 0.000 claims description 3
- ZMWJQGOYIBHQJG-UHFFFAOYSA-N 3-[diethoxy(methyl)silyl]propan-1-ol Chemical compound CCO[Si](C)(OCC)CCCO ZMWJQGOYIBHQJG-UHFFFAOYSA-N 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 claims description 3
- QXLPXWSKPNOQLE-UHFFFAOYSA-N methylpentynol Chemical compound CCC(C)(O)C#C QXLPXWSKPNOQLE-UHFFFAOYSA-N 0.000 claims description 3
- 229960002238 methylpentynol Drugs 0.000 claims description 3
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 2
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 2
- BITPLIXHRASDQB-UHFFFAOYSA-N ethenyl-[ethenyl(dimethyl)silyl]oxy-dimethylsilane Chemical compound C=C[Si](C)(C)O[Si](C)(C)C=C BITPLIXHRASDQB-UHFFFAOYSA-N 0.000 claims description 2
- JROIGMXXSNIIQY-UHFFFAOYSA-N 2,4,6,8-tetrakis(ethenyl)-2-methyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound C[Si]1(O[SiH](O[SiH](O[SiH](O1)C=C)C=C)C=C)C=C JROIGMXXSNIIQY-UHFFFAOYSA-N 0.000 claims 1
- MJBPUQUGJNAPAZ-UHFFFAOYSA-N Butine Natural products O1C2=CC(O)=CC=C2C(=O)CC1C1=CC=C(O)C(O)=C1 MJBPUQUGJNAPAZ-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 125000003700 epoxy group Chemical group 0.000 claims 1
- 229920000647 polyepoxide Polymers 0.000 claims 1
- 229910000077 silane Inorganic materials 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 238000004873 anchoring Methods 0.000 abstract description 8
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000000243 solution Substances 0.000 description 27
- 238000000576 coating method Methods 0.000 description 19
- 239000000047 product Substances 0.000 description 19
- 239000011248 coating agent Substances 0.000 description 17
- 239000012224 working solution Substances 0.000 description 17
- 230000000903 blocking effect Effects 0.000 description 14
- 239000002904 solvent Substances 0.000 description 14
- 238000004519 manufacturing process Methods 0.000 description 10
- 238000009736 wetting Methods 0.000 description 9
- 238000004132 cross linking Methods 0.000 description 8
- 238000001723 curing Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 238000007711 solidification Methods 0.000 description 8
- 230000008023 solidification Effects 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- 229920002799 BoPET Polymers 0.000 description 7
- 238000000605 extraction Methods 0.000 description 7
- 239000004744 fabric Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 6
- MAWLKRJXJGHDRD-UHFFFAOYSA-N ethene;platinum Chemical group [Pt].C=C MAWLKRJXJGHDRD-UHFFFAOYSA-N 0.000 description 6
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- 238000005187 foaming Methods 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000007792 addition Methods 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000013007 heat curing Methods 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 238000009830 intercalation Methods 0.000 description 2
- 230000002687 intercalation Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241001515806 Stictis Species 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 150000001345 alkine derivatives Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000013005 condensation curing Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000010931 ester hydrolysis Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- ARLJCLKHRZGWGL-UHFFFAOYSA-N ethenylsilicon Chemical compound [Si]C=C ARLJCLKHRZGWGL-UHFFFAOYSA-N 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003847 radiation curing Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention provides a kind of emulsion-type mould releases, it includes following raw material: the vinyl silicone oil of 20~50wt%, the containing hydrogen silicone oil of 0.5~10wt%, the polyvinyl alcohol water solution of 5~20wt%, the stabilizer of 6~15wt%, the emulsifier of 0.3~3wt%, the catalyst of 0.5~20ppm, the inhibitor of 0.5~1.0wt%, the Anchor Agent of 5~10wt%, the deionized water of 30~50wt%, and the hydrogen-based in the containing hydrogen silicone oil and the molar ratio of the vinyl in the vinyl silicone oil are 2.0~3.5:1.Emulsion-type mould release provided by the present application is the safety and environmental protection emulsion-type mould release that a kind of curing rate is fast, anchoring is good, off-type force is light and remaining then rate is high.
Description
Technical field
The present invention relates to mould release technical fields more particularly to a kind of emulsion-type mould release and preparation method thereof.
Background technique
Silicone release agent is also known as paper release silicone, is to be coated on specific substrate (such as paper, film etc.) to pass through
Certain curing reaction, one layer of formation has the coating of isolation, anti-sticking and other effects.It is said on stricti jurise, silicone release agent
It is regarded as a kind of using organosilicon as the coating of film forming matter.Claimed after paper or the coated cured silicone mould release of film
It for release paper or release film, is applied with very extensive market, whether label, adhesive tape, show and colour or medical
Fields, release paper or the release films such as product, amenities, food processing packaging, express envelope and electronic die patch are in protection adhesive
It is all played in terms of from polluting, facilitating production and processing, facilitate the physical property of product such as storage and transport, holding adhesive important
Effect.
There are many product form for silicone release agent, and also there are many classification methods.Divide from product appearance state, can divide
For no-solvent type, solvent type and emulsion-type three categories；Can be divided into from curing mechanism heat cure (containing solvent type, no-solvent type and
Three kinds of states of emulsion-type) and UV/EB radiation curing (no-solvent type state) two major classes, the product of heat cure is from polymerization machine
It is divided into organotin catalyzed condensation curing reaction system (containing three kinds of solvent type, no-solvent type and emulsion-type states) and platinum in reason again
Gold or rhodium etc. catalytic additions solidification polymerization reaction system (containing three kinds of solvent type, no-solvent type and emulsion-type states) two major classes.
Solvent type mould release product can largely utilize toluene and industrial naptha in the production of mould release producer and client's use
Etc. diluent is made, this kind of product is caused to always exist the hidden danger and realistic problem of safety in production and environmental pollution；Especially make
With the client of mould release, fire incident caused by often occurring in coating process because of electrostatic, to the wealth of coating producer
It produces and personal safety all causes very big loss.And in coating process, if the solvent of Macrodilution without recycle or
Effectively recycling is just discharged into air, both polluted the significant wastage that environment is also resource.
A kind of mould release product of the emulsion-type silicone release agent as safety and environmental protection, be the substitution of solvent based product more
One of new product.But emulsion type products be using water as carrier, compared with solvent based product storage stability, reaction curing rate,
It is all insufficient in terms of the physical property such as spreadability and anchoring on substrate.
Application No. is the Chinese patents of CN201210147781 to disclose a kind of mould release, by polyvinyl alcohol water solution,
The agent of emulsion-type silicone release, stabilizer, emulsifier, catalyst and crosslinking agent mix, and have obtained a kind of without containing organic
The silicone release agent of solvent, but do not refer to off-type force, the numerical value of remaining adhesion, while also not mentioned in patent
And anchoring and working solution frothing capacity.
A kind of aqueous mould release and preparation method thereof is disclosed application No. is the Chinese patent of CN201310307678 and is utilized
The release paper of the aqueous mould release preparation, by organic silicon monomer, ethenyl blocking agent, alkyd resin, emulsifier, catalyst
It being mixed with deionized water, 0.5~1h of pre-emulsification at 10~50 DEG C then heats to 95~140 DEG C, 1~6h of isothermal reaction,
Being adjusted to pH value with pH adjusting agent after being cooled to room temperature is 7~8, is finally proportionally added into crosslinking agent and platinum-type catalyst, makes
Obtained aqueous mould release.But do not refer to off-type force, the numerical value of remaining adhesion, while anchor is not also referred in patent
Solidity and working solution frothing capacity.Therefore it provides it is a kind of have curing rate is fast, anchoring is good, off-type force is light, remnants then
The high emulsion-type mould release of rate is of great significance.
Summary of the invention
Present invention solves the technical problem that being to provide, a kind of curing rate is fast, anchoring is good, off-type force is light, remnants connect
Put forth effort high emulsion-type mould release.
In view of this, this application provides a kind of emulsion-type mould release, including following raw material:
The vinyl silicone oil is the compound with formula (I) structure, and the containing hydrogen silicone oil is with formula (II) structure
Compound；And the hydrogen-based in the containing hydrogen silicone oil and the molar ratio of the vinyl in the vinyl silicone oil are 2.0~3.5:1；
Wherein, R1And R2It is independent to be selected from methyl or vinyl, and R1And R2It is not simultaneously methyl；
M and n is natural number, and m and n are not 0 simultaneously；
R3And R4It is independent to be selected from methyl or hydrogen-based, and R3And R4It is not simultaneously methyl；
A and b is natural number, and a and b are not 0 simultaneously.
Preferably, the vinyl silicone oil is organopolysiloxane at least with two or more vinyl, institute
Stating containing hydrogen silicone oil is organic polyoxy silane at least with more than two hydrogen-baseds.
Preferably, 25 DEG C of viscosity of the vinyl silicone oil are 200~100000cps, the mass percentage of vinyl
It is 0.05~5%；25 DEG C of viscosity of the containing hydrogen silicone oil are 7~100cps, the mass percentage of hydrogen-based is 0.2~
1.6%；The concentration of the polyvinyl alcohol water solution is 4%, and 25 DEG C of viscosity are 4~80cps, and alcoholysis degree is 80~90%.
Preferably, the stabilizer is aqueous alkide resin, and the emulsifier is polyether modified silicon oil, the catalyst
For platinum-vinyl siloxane complex, the inhibitor be selected from 3- methyl-1-butine-3- alcohol, methylpentynol,
3,5- dimethyl -1- hexin -3- alcohol, 1- acetenyl -1- cyclohexanol, t etram-ethyltetravinylcyclotetrasiloxane, tetramethyl diethyl
Alkenyl disiloxane, 2- acrylic -2- methoxy acrylate, 2- acrylic -2- butoxyethyl and 2- phenyl -3- butine-ethyl alcohol
One of or it is a variety of, the Anchor Agent be selected from silane coupling agent, vinyltriethoxysilane, vinyl trimethoxy silicon
Alkane, vinyl three (2- methoxy ethoxy) silane, 3- (2,3 the third oxygen of epoxy) hydroxypropyl methyl diethoxy silane, 3- (2,3 rings
The third oxygen of oxygen) propyl-triethoxysilicane, 2- (3,4- 7-oxa-bicyclo[4.1.0 base) ethyl trimethoxy silane, γ-methacryloxypropyl
Base propyl trimethoxy silicane, γ-glycidyl ether oxygen propyl trimethoxy silicane, methyl orthosilicate, methyl orthosilicate contracting
Close one of object, ethyl orthosilicate and ethyl orthosilicate condensation product or a variety of.
Preferably, the concentration of the polyvinyl alcohol water solution is 4%, the content of the polyvinyl alcohol water solution is 5~
15wt%.
Preferably, the content of the stabilizer is 8~10wt%.
Preferably, the content of the emulsifier is 0.4~1wt%, and the content of the catalyst is 8~18ppm, described
The content of inhibitor is 0.5~0.8wt%, and the content of the Anchor Agent is 5~6wt%.
Present invention also provides the preparation methods of the emulsion-type mould release, comprising the following steps:
By the vinyl silicone oil of 20~50wt%, the containing hydrogen silicone oil of 0.5~10wt%, 5~20wt% polyvinyl alcohol water
Solution, the stabilizer of 6~15wt%, the emulsifier of 0.3~3wt%, the inhibitor of 0.5~1.0wt% and 5~10wt%
The deionized water of 30~50wt% is added after Anchor Agent mixing, homogeneous after the completion of phase inversion obtains component A；
The vinyl silicone oil of 5~20wt%, the catalyst of 60~2520ppm, the polyvinyl alcohol of 10~20wt% is water-soluble
30~50wt% deionized water is added after the mixing of the emulsifier of liquid and 0.3~3wt%, homogeneous after the completion of phase inversion obtains B component；
Component A, B component and deionized water are mixed according to the mass ratio of 20:1:100, obtain emulsion-type mould release.
Preferably, the viscosity of the component A is 50~200cps, and the viscosity of the B component is 25~50cps.
Preferably, in the step of preparing component A and preparation B component, the homogeneous carries out in high pressure homogenizer,
The pressure of the homogeneous is 30MPa, and the number of the homogeneous is 3~10 times.
This application provides a kind of emulsion-type mould releases comprising following raw material: the vinyl silicone oil of 20~50wt%,
The containing hydrogen silicone oil of 0.5~10wt%, the polyvinyl alcohol water solution of 5~20wt%, the stabilizer of 6~15wt%, 0.3~3wt%
Emulsifier, the catalyst of 0.5~20ppm, the inhibitor of 0.5~1.0wt%, the Anchor Agent of 5~10wt%, 30~
The deionized water of 50wt%, and the hydrogen-based in the containing hydrogen silicone oil and the molar ratio of the vinyl in the vinyl silicone oil are
2.0~3.5:1.The Anchor Agent added in the application can realize that, to the good adhesion property of various substrates, stabilizer can increase body
It is stability, while plays certain inhibiting effect to working solution foaming characteristic, suitable emulsifier can increases emulsion intercalation method
To extend storage time；Further adjust the ratio of vinyl silicone oil and containing hydrogen silicone oil, vinyl silicone oil vinyl with contain
The molar ratio of the hydrogen-based of hydrogen silicone oil determines the crosslinking degree of mould release, and then affects off-type force and remaining then rate, because
This application is by being added said components and adjustment proportionate relationship, the emulsion-type mould release made fast, anchor with curing rate
Solidity is good, the light feature high with remaining adhesion of off-type force.
Specific embodiment
For a further understanding of the present invention, the preferred embodiment of the invention is described below with reference to embodiment, still
It should be appreciated that these descriptions are only further explanation the features and advantages of the present invention, rather than to the claims in the present invention
Limitation.
The characteristics of for emulsion-type mould release in the prior art, this application provides a kind of emulsion-type mould releases, have
The feature that curing rate is fast, anchoring is good, off-type force is light and remaining then rate is high, and the also foaming characteristic that works requires generally, it can
For release paper.Specifically, the embodiment of the invention discloses a kind of emulsion-type mould release, including following raw material:
The vinyl silicone oil is the compound with formula (I) structure, and the containing hydrogen silicone oil is with formula (II) structure
Compound；And the hydrogen-based in the containing hydrogen silicone oil and the molar ratio of the vinyl in the vinyl silicone oil are 2.0~3.5:1；
Wherein, R1And R2It is independent to be selected from methyl or vinyl, and R1And R2It is not simultaneously methyl；
M and n is natural number, and m and n are not 0 simultaneously；
R3And R4It is independent to be selected from methyl or hydrogen-based, and R3And R4It is not simultaneously methyl；
A and b is natural number, and a and b are not 0 simultaneously.
In emulsion-type mould release, the vinyl silicone oil is vinyl-terminated silicone fluid, ethenyl of side chain silicone oil and branch second
One of alkenyl silicone oil is a variety of；More specifically, the vinyl silicone oil is at least to have two or more vinyl
Organopolysiloxane, 25 DEG C of viscosity are 200~100,000cps, in a particular embodiment, 25 DEG C of viscosity are 200~
1000cps, the mass percentage of vinyl are 0.05%~5%, and in a particular embodiment, the quality percentage of vinyl contains
Amount is 0.8%~3.0%.The content of the vinyl silicone oil is 20~50wt%, in a particular embodiment, the vinyl
The content of silicone oil is 25~40wt%.
The containing hydrogen silicone oil is organopolysiloxane at least with two or more hydrogen-baseds, and 25 DEG C of viscosity are 7
~100cps, in a particular embodiment, 25 DEG C of viscosity are 20~40cps, and the mass percentage of hydrogen-based is 0.2~1.6%,
In a particular embodiment, the mass percentage of hydrogen-based is 0.5~1.0%.The content of containing hydrogen silicone oil is 0.5~10wt%,
In specific embodiment, 3~8wt% of the content of the containing hydrogen silicone oil.
The molar ratio of hydrogen-based and the vinyl silicone oil medium vinyl in the containing hydrogen silicone oil is 2.0~3.5:1.This
Apply by adjusting the ratio of vinyl silicone oil and containing hydrogen silicone oil, the hydrogen-based of the vinyl of vinyl silicone oil and containing hydrogen silicone oil
Ratio, determines the crosslinking degree of entire emulsion-type mould release, and then affects the off-type force of emulsion-type mould release and remnants connect
Rate, the dosage of catalyst is also affected, to affect the cost of whole system；Hydrogen-based: the ratio of vinyl is too low to be made
Decline at crosslinking degree, adhesive easily penetrates into interleaving agent, causes removing difficult, off-type force adhesion bigger than normal and remaining is inclined
Small, ratio is excessively high to be caused crosslinking excessively release layer is crisp, easy to fall off and increase cost of material.In this application, described hydrogeneous
The molal quantity of hydrogen-based and the molal quantity of vinyl silicone oil medium vinyl are calculated according to formula (1) mode in silicone oil:
Molal quantity=quality/molal weight (1)；
Wherein, the molal weight of hydrogen-based is 1g/mol, the molal weight of vinyl silicone oil medium vinyl in containing hydrogen silicone oil
(molal weight for actually referring to average chain link in vinyl silicone oil) is 74g/mol.
In the emulsion-type mould release, the polyvinyl alcohol water solution is that one kind is obtained by polyvinyl acetate ester hydrolysis
To water-soluble polymer；Its concentration is 4%, and 25 DEG C of viscosity are 4~80cps, in a particular embodiment, 25 DEG C of viscosity are 30~
40cps；Alcoholysis degree be 80~90%, in a particular embodiment, alcoholysis degree be 86~89%, molecular weight be 8000~
2000000, in a particular embodiment, molecular weight is 800000~1200000.The content of the polyvinyl alcohol water solution is 5
~20wt%, in a particular embodiment, the content of the polyvinyl alcohol water solution are 5~15wt%.
The stabilizer can increase system stability, while certain inhibiting effect is played to working solution foaming characteristic, again
The wetting and levelling for playing the role of working solution and substrate are sprawled.The stabilizer is specially aqueous alkide resin, more specifically water
Property alkyd resin YG-AK342 or aqueous alkide resin YG-AK337.The content of the stabilizer is 6~15wt%, specific
In embodiment, the content of the stabilizer is 8~10wt%.
The emulsifier can increase emulsion intercalation method to extend storage time, be specially polyether modified silicon oil, more
Specially polyether modified silicon oil 7123.The content of the emulsifier is 0.3~3wt%, in a particular embodiment, the polyethers
The content of silicone oil is 0.4~1.0wt%, and content is excessive, and working solution is easy to foaming, and content is very few cannot to play emulsifying effectiveness, together
When working solution stability it is poor.
The catalyst is chosen in particular from platinum-vinyl siloxane complex, can be used Willing method preparation or
The preparation of Karstedt method；Above-mentioned platinum-type catalyst plays the role of catalytic crosslinking.The content of the catalyst be 0.5~
20ppm；Not exclusively, release effect is poor for the excessively few then crosslinking of the content of the catalyst；Crossing multipair release influences less, but meeting
Cause waste and increased costs.
The inhibitor be selected from 3- methyl-1-butine-3- alcohol, methylpentynol, 3,5- dimethyl-1- oneself
Alkynes -3- alcohol, 1- acetenyl -1- cyclohexanol, t etram-ethyltetravinylcyclotetrasiloxane, tetramethyl divinyl disiloxane, 2-
One of acrylic -2- methoxy acrylate, 2- acrylic -2- butoxyethyl and 2- phenyl -3- butine-ethyl alcohol are a variety of,
In a particular embodiment, the inhibitor be selected from one of pure and mild 1- acetenyl-1- cyclohexanol of 3- methyl-1-butine-3- or
Two kinds.The content of the inhibitor is 0.5~1.0wt%, and the additive amount of the inhibitor decides operating for working solution
Time, additive amount excessively will cause crosslinking not exclusively, and release effect is poor, and the very few crosslinking of additive amount has been completely but working solution
Just partial cross-linked before operating procedure is completed, operable time is short.
The Anchor Agent, which realizes, has good adhesion property good various substrates (paper, plastic film etc.)；It is specifically selected
From silane coupling agent, vinyltriethoxysilane, vinyltrimethoxysilane, vinyl three (2- methoxy ethoxy)
Silane, 3- (2,3 the third oxygen of epoxy) hydroxypropyl methyl diethoxy silane, 3- (2,3 the third oxygen of epoxy) propyl-triethoxysilicane, 2-
(3,4- 7-oxa-bicyclo[4.1.0 base) ethyl trimethoxy silane, γ-methacryloxypropyl trimethoxy silane, γ-contracting
Water glycerol ether oxygen propyl trimethoxy silicane, methyl orthosilicate, methyl orthosilicate condensation product, ethyl orthosilicate and positive silicic acid second
One of ester condensates are a variety of；In a particular embodiment, the Anchor Agent is selected from vinyltriethoxysilane and 3-
One or both of (2,3 the third oxygen of epoxy) propyl-triethoxysilicane.The content of the Anchor Agent is 5~10wt%, is being had
In body embodiment, the content of the Anchor Agent is 5wt%~6wt%.
Present invention also provides a kind of preparation methods of emulsion-type mould release, comprising the following steps:
By the vinyl silicone oil of 20~50wt%, the containing hydrogen silicone oil of 0.5~10wt%, the polyvinyl alcohol water of 5~20wt%
Solution, the stabilizer of 6~15wt%, the emulsifier of 0.3~3wt%, the inhibitor of 0.5~1.0wt% and 5~10wt%'s
The deionized water of 30~50wt% is added after Anchor Agent mixing, homogeneous after the completion of phase inversion obtains component A；
The polyvinyl alcohol of the vinyl silicone oil of 5~20wt%, the catalyst of 60~2520ppm, 10~20wt% is water-soluble
30~50wt% deionized water is added after the mixing of the emulsifier of liquid and 0.3~3wt%, homogeneous after the completion of phase inversion obtains B component；
Component A, B component and deionized water are mixed according to the mass ratio of 20:1:100, obtain emulsion-type mould release.
During preparing emulsion-type mould release, it is prepared for component A first, in accordance with said ratio, i.e., by vinyl silicon
Oil, containing hydrogen silicone oil, polyvinyl alcohol water solution, stabilizer, emulsifier, inhibitor and Anchor Agent disperse in high speed dispersion agent
It is even, add deionized water, after the completion of the above-mentioned raw materials phase inversion preferably in high pressure homogenizer homogeneous to get arriving component A；Institute
The pressure for stating homogeneous is 30MPa, and number is 3~10 times.The viscosity of the component A is 50~200cps.
After the completion of component A preparation, then the preparation of B component is carried out, specifically by vinyl silicone oil, catalyst, polyethylene
Alcohol solution and emulsifier are uniformly dispersed in high speed dispersion agent, add deionized water, excellent after the completion of above-mentioned raw materials phase inversion
Homogeneous is selected in high pressure homogenizer to get to B component；The pressure of the homogeneous is 30MPa, and number is 3~10 times.The B group
The viscosity divided is 25~50cps.
The application finally mixes component A obtained above, B component and water to get arriving according to the mass ratio of 20:1:100
Emulsion-type mould release can be scratched directly on substrate.
The present invention be added in emulsion-type mould release vinyl silicone oil, containing hydrogen silicone oil, polyvinyl alcohol water solution, stabilizer,
Emulsifier, catalyst, inhibitor and Anchor Agent, and adjust the proportion of said components and the Si -- H and second of containing hydrogen silicone oil
The molar ratio of the Si-Vi of alkenyl silicone oil has obtained the light remaining then high mould release of rate of off-type force, while with the emulsification of silicone oil
Property is emulsified into aqueous emulsion, solves the environmental protection and safety issue of solvent-type organosilicon mould release, the emulsifier of selection
Specially organosilyl surfactant, it is good to Miscibility, certain help is played to system stability, while passing through addition
Stabilizer and Anchor Agent solve stability of emulsion, working solution foaming characteristic, ask with the spreading wetting of substrate and anchoring etc.
Topic.Emulsion-type mould release composition prepared by the present invention has curing rate fast, and anchoring is good, and off-type force is light, and remnants are then
Rate is high；It is further mixed by component A, B component with water, scratches, can be used for the mould release of the substrates such as paper.
For a further understanding of the present invention, below with reference to embodiment to emulsion-type mould release provided by the invention and its system
Preparation Method is described in detail, and protection scope of the present invention is not limited by the following examples.
Following raw material is commercial product or is prepared according to existing method.
Embodiment 1
By viscosity 500cps, the ethenyl blocking vinyl silicone oil 40wt% of vinyl mass content 1.2%, viscosity
The containing hydrogen silicone oil 3wt% of 25cps, hydrogen-based mass content 0.6%, viscosity 40cps, alcoholysis degree 88%, molecular weight 100000~
120000 polyvinyl alcohol water solution 8wt%, aqueous alkide resin (trade mark YG-AK337) 9wt%, polyether modified silicon oil (board
Number 7123) 0.5wt%, 3- methyl-1-butine-3- alcohol 0.5wt%, vinyltriethoxysilane 5.0wt% are added simultaneously
It is uniformly dispersed in high speed disperser, is then slowly added into deionized water 34wt%, is transferred in high pressure homogenizer after the completion of phase inversion
30MPa is crossed 3 times, obtains component A；
By viscosity 500cps, the ethenyl blocking vinyl silicone oil 15wt% of vinyl mass content 1.2%, platinum-ethylene
Radical siloxane complex 1560ppm, viscosity 40cps, alcoholysis degree 88%, molecular weight 120000 polyvinyl alcohol water solution
15wt%, polyether modified silicon oil (trade mark 7123) 0.5wt%, while being added in high speed disperser and being uniformly dispersed, then slowly add
Enter deionized water 39.5wt%, is transferred to 30MPa in high pressure homogenizer after the completion of phase inversion and crosses 3 times, obtain B component；
Above-mentioned component A, above-mentioned B component and deionized water are mixed according to the mass ratio of 20:1:100, as final production
Product.
A/B/ deionized water derived above is mixed according to 20:1:100 ratio, scratches, applies on 50u transparent PET film
Cloth amount is 0.3~0.4g/inch, and 130 DEG C of * 10s solidifications obtain coating.
The off-type force of testing coating, remaining adhesion and extraction yield, observation stability, working solution frothing capacity and wetting
Spreadability；Specific data and performance are as shown in table 1.
Embodiment 2
By viscosity 500cps, the ethenyl blocking vinyl silicone oil 39.5wt% of vinyl mass content 1.2%, viscosity
The containing hydrogen silicone oil 3.5wt% of 25cps, hydrogen-based mass content 0.6%, viscosity 40cps, alcoholysis degree 88%, molecular weight 100000
~120000 polyvinyl alcohol water solution 8wt%, aqueous alkide resin (trade mark YG-AK337) 9wt%, polyether modified silicon oil
(trade mark 7123) 0.5wt%, 3- methyl-1-butine-3- alcohol 0.5wt%, vinyltriethoxysilane 5.0wt%, simultaneously
It is added in high speed disperser and is uniformly dispersed, be then slowly added into deionized water 34wt%, high pressure homogenizer is transferred to after the completion of phase inversion
Middle 30MPa is crossed 3 times, obtains component A；
By viscosity 500cps, the ethenyl blocking vinyl silicone oil 15wt% of vinyl mass content 1.2%, platinum-ethylene
Radical siloxane complex 1560ppm, viscosity 40cps, alcoholysis degree 88%, molecular weight 120000 polyvinyl alcohol water solution
15wt%, polyether modified silicon oil (trade mark 7123) 0.5wt%, while being added in high speed disperser and being uniformly dispersed, then slowly add
Enter deionized water 39.5wt%, is transferred to 30MPa in high pressure homogenizer after the completion of phase inversion and crosses 3 times, obtain B component；
Above-mentioned component A, above-mentioned B component and deionized water are mixed according to the mass ratio of 20:1:100, as final production
Product.
A/B/ deionized water derived above is mixed according to 20:1:100 ratio, scratches, applies on 50u transparent PET film
Cloth amount is 0.3~0.4g/inch, and 130 DEG C of * 10s solidifications obtain coating.
The off-type force of testing coating, remaining adhesion and extraction yield, observation stability, working solution frothing capacity and wetting
Spreadability；Specific data and performance are as shown in table 1.
Embodiment 3
By viscosity 500cps, the ethenyl blocking vinyl silicone oil 39.5wt% of vinyl mass content 1.2%, viscosity
The containing hydrogen silicone oil 3.5wt% of 25cps, hydrogen-based mass content 0.6%, viscosity 40cps, alcoholysis degree 88%, molecular weight 100000
~120000 polyvinyl alcohol water solution 8wt%, aqueous alkide resin (trade mark YG-AK337) 9wt%, polyether modified silicon oil
(trade mark 7123) 0.5wt%, 3- methyl-1-butine-3- alcohol 0.5wt%, 3- (2,3 the third oxygen of epoxy) propyl-triethoxysilicane
5.0wt%, while being added in high speed disperser and being uniformly dispersed, it is then slowly added into deionized water 34wt%, is turned after the completion of phase inversion
Enter 30MPa in high pressure homogenizer to cross 3 times, obtains component A；
By viscosity 500cps, the ethenyl blocking vinyl silicone oil 15wt% of vinyl mass content 1.2%, platinum-ethylene
Radical siloxane complex 1560ppm, viscosity 40cps, alcoholysis degree 88%, molecular weight 120000 polyvinyl alcohol water solution
15wt%, polyether modified silicon oil (trade mark 7123) 0.5wt%, while being added in high speed disperser and being uniformly dispersed, then slowly add
Enter deionized water 39.5wt%, is transferred to 30MPa in high pressure homogenizer after the completion of phase inversion and crosses 3 times, obtain B component；
Above-mentioned component A, above-mentioned B component and deionized water are mixed according to the mass ratio of 20:1:100, as final production
Product.
A/B/ deionized water derived above is mixed according to 20:1:100 ratio, scratches, applies on 50u transparent PET film
Cloth amount is 0.3~0.4g/inch, and 130 DEG C of * 10s solidifications obtain coating.
The off-type force of testing coating, remaining adhesion and extraction yield.Observe stability, working solution frothing capacity and wetting
Spreadability；Specific data and performance are as shown in table 1.
Comparative example 1
By viscosity 500cps, the ethenyl blocking vinyl silicone oil 40wt% of vinyl mass content 1.2%, viscosity
The containing hydrogen silicone oil 3wt% of 25cps, hydrogen-based mass content 0.6%, viscosity 40cps, alcoholysis degree 88%, molecular weight 100000~
120000 polyvinyl alcohol water solution 8wt%, aqueous alkide resin (trade mark YG-AK337) 9wt%, polyether modified silicon oil (board
Number 7123) 0.5wt%, 3- methyl-1-butine-3- alcohol 0.5wt%, while being added in high speed disperser and being uniformly dispersed, then delay
It is slow that deionized water 39wt% is added, 30MPa in high pressure homogenizer is transferred to after the completion of phase inversion and is crossed 3 times, and component A is obtained；
By viscosity 500cps, the ethenyl blocking vinyl silicone oil 15wt% of vinyl mass content 1.2%, platinum-ethylene
Radical siloxane complex 1560ppm, viscosity 40cps, alcoholysis degree 88%, molecular weight 120000 polyvinyl alcohol water solution
15wt%, polyether modified silicon oil (trade mark 7123) 0.5wt%, while being added in high speed disperser and being uniformly dispersed, then slowly add
Enter deionized water 39.5wt%, is transferred to 30MPa in high pressure homogenizer after the completion of phase inversion and crosses 3 times, obtain B component；
Above-mentioned component A, above-mentioned B component and deionized water are mixed according to the mass ratio of 20:1:100, as final production
Product.
A/B/ deionized water derived above is mixed according to 20:1:100 ratio, scratches, applies on 50u transparent PET film
Cloth amount is 0.3~0.4g/inch, and 130 DEG C of * 10s solidifications obtain coating.
The off-type force of testing coating, remaining adhesion and extraction yield, observation stability, working solution frothing capacity and wetting
Spreadability；Specific data and performance are as shown in table 1.
Comparative example 2
By viscosity 500cps, the ethenyl blocking vinyl silicone oil 39.5wt% of vinyl mass content 1.2%, viscosity
The containing hydrogen silicone oil 3.5wt% of 25cps, hydrogen-based mass content 0.6%, viscosity 40cps, alcoholysis degree 88%, molecular weight 100000
~120000 polyvinyl alcohol water solution 8%, aqueous alkide resin (trade mark YG-AK337) 9wt%, polyether modified silicon oil (board
Number 7123) 0.5wt%, 3- methyl-1-butine-3- alcohol 0.5wt%, while being added in high speed disperser and being uniformly dispersed, then
It is slowly added to deionized water 39wt%, 30MPa in high pressure homogenizer is transferred to after the completion of phase inversion and crosses 3 times, obtain component A；
By viscosity 500cps, the ethenyl blocking vinyl silicone oil 15wt% of vinyl mass content 1.2%, platinum-ethylene
Radical siloxane complex 1560ppm, viscosity 40cps, alcoholysis degree 88%, molecular weight 120000 polyvinyl alcohol water solution
15wt%, polyether modified silicon oil (trade mark 7123) 0.5wt%, while being added in high speed disperser and being uniformly dispersed, then slowly add
Enter deionized water 39.5wt%, is transferred to 30MPa in high pressure homogenizer after the completion of phase inversion and crosses 3 times, obtain B component；
Above-mentioned component A, above-mentioned B component and deionized water are mixed according to the mass ratio of 20:1:100, as final production
Product.
A/B/ deionized water derived above is mixed according to 20:1:100 ratio, scratches, applies on 50u transparent PET film
Cloth amount is 0.3~0.4g/inch, and 130 DEG C of * 10s solidifications obtain coating.
The off-type force of testing coating, remaining adhesion and extraction yield, observation stability, working solution frothing capacity and wetting
Spreadability；Specific data and performance are as shown in table 1.
Comparative example 3
By viscosity 500cps, the ethenyl blocking vinyl silicone oil 40wt% of vinyl mass content 1.2%, viscosity
The containing hydrogen silicone oil 3wt% of 25cps, hydrogen-based mass content 0.6%, viscosity 40cps, alcoholysis degree 88%, molecular weight 100000~
120000 polyvinyl alcohol water solution 8wt%, polyether modified silicon oil (trade mark 7123) 0.5wt%, 3- methyl-1-butine-3- alcohol
0.5wt%, while being added in high speed disperser and being uniformly dispersed, be then slowly added into deionized water 48wt%, after the completion of phase inversion
It is transferred to 30MPa in high pressure homogenizer to cross 3 times, obtains component A；
By viscosity 500cps, the ethenyl blocking vinyl silicone oil 15wt% of vinyl mass content 1.2%, platinum-ethylene
Radical siloxane complex 1560ppm, viscosity 40cps, alcoholysis degree 88%, molecular weight 120000 polyvinyl alcohol water solution
15wt%, polyether modified silicon oil (trade mark 7123) 0.5wt%, while being added in high speed disperser and being uniformly dispersed, then slowly add
Enter deionized water 39.5wt%, is transferred to 30MPa in high pressure homogenizer after the completion of phase inversion and crosses 3 times, obtain B component；
Above-mentioned component A, above-mentioned B component and deionized water are mixed according to the mass ratio of 20:1:100, as final production
Product.
A/B/ deionized water derived above is mixed according to 20:1:100 ratio, scratches, applies on 50u transparent PET film
Cloth amount is 0.3~0.4g/inch, and 130 DEG C of * 10s solidifications obtain coating.
The off-type force of testing coating, remaining adhesion and extraction yield, observation stability, working solution frothing capacity and wetting
Spreadability；Specific data and performance are as shown in table 1.
Comparative example 4
By viscosity 500cps, the ethenyl blocking vinyl silicone oil 41.5wt% of vinyl mass content 1.2%, viscosity
The containing hydrogen silicone oil 1.5wt% of 25cps, hydrogen-based mass content 0.6%, viscosity 40cps, alcoholysis degree 88%, molecular weight 100000
~120000 polyvinyl alcohol water solution 8wt%, aqueous alkide resin (trade mark YG-AK337) 9wt%, polyether modified silicon oil
(trade mark 7123) 0.5wt%, 3- methyl-1-butine-3- alcohol 0.5wt%, vinyltriethoxysilane 5.0wt%, simultaneously
It is added in high speed disperser and is uniformly dispersed, be then slowly added into deionized water 34wt%, high pressure homogenizer is transferred to after the completion of phase inversion
Middle 30MPa is crossed 3 times, obtains component A；
By the ethenyl blocking vinyl silicone oil 15wt% of the mass content 1.2% of viscosity 500cps, vinyl, platinum-second
Alkenylsiloxane complexes 1560ppm, viscosity 40cps, alcoholysis degree 88%, molecular weight 120000 polyvinyl alcohol water solution
15wt%, polyether modified silicon oil (trade mark 7123) 0.5wt%, while being added in high speed disperser and being uniformly dispersed, then slowly add
Enter deionized water 39.5wt%, is transferred to 30MPa in high pressure homogenizer after the completion of phase inversion and crosses 3 times, obtain B component；
Above-mentioned component A, above-mentioned B component and deionized water are mixed according to the mass ratio of 20:1:100, as final production
Product.
A/B/ deionized water derived above is mixed according to 20:1:100 ratio, scratches, applies on 50u transparent PET film
Cloth amount is 0.3~0.4g/inch, and 130 DEG C of * 10s solidifications obtain coating.
The off-type force of testing coating, remaining adhesion and extraction yield, observation stability, working solution frothing capacity and wetting
Spreadability；Specific data and performance are as shown in table 1.
The performance indicator tables of data of each embodiment of table 1 and comparative example
The above description of the embodiment is only used to help understand the method for the present invention and its core ideas.It should be pointed out that pair
For those skilled in the art, without departing from the principle of the present invention, the present invention can also be carried out
Some improvements and modifications, these improvements and modifications also fall within the scope of protection of the claims of the present invention.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention.
Various modifications to these embodiments will be readily apparent to those skilled in the art, defined herein
General Principle can realize in other embodiments without departing from the spirit or scope of the present invention.Therefore, originally
Invention is not intended to be limited to the embodiments shown herein, and is to fit to special with principles disclosed herein and novelty
The consistent widest scope of point.
Claims (10)
1. a kind of emulsion-type mould release, including following raw material:
The vinyl silicone oil is the compound with formula (I) structure, and the containing hydrogen silicone oil is the chemical combination with formula (II) structure
Object；And the hydrogen-based in the containing hydrogen silicone oil and the molar ratio of the vinyl in the vinyl silicone oil are 2.0~3.5:1；
Wherein, R1And R2It is independent to be selected from methyl or vinyl, and R1And R2It is not simultaneously methyl；
M and n is natural number, and m and n are not 0 simultaneously；
R3And R4It is independent to be selected from methyl or hydrogen-based, and R3And R4It is not simultaneously methyl；
A and b is natural number, and a and b are not 0 simultaneously.
2. emulsion-type mould release according to claim 1, which is characterized in that the vinyl silicone oil be at least tool there are two
Or the organopolysiloxane of more than two vinyl, the containing hydrogen silicone oil are organic poly(oxygen-silicon) at least with more than two hydrogen-baseds
Alkane.
3. emulsion-type mould release according to claim 1, which is characterized in that 25 DEG C of viscosity of the vinyl silicone oil are
200~100000cps, the mass percentage of vinyl are 0.05~5%；25 DEG C of viscosity of the containing hydrogen silicone oil be 7~
100cps, the mass percentage of hydrogen-based are 0.2~1.6%；The concentration of the polyvinyl alcohol water solution is 4%, 25 DEG C of viscosity
For 4~80cps, alcoholysis degree is 80~90%.
4. emulsion-type mould release according to claim 1, which is characterized in that the stabilizer is aqueous alkide resin, institute
Stating emulsifier is polyether modified silicon oil, and the catalyst is platinum-vinyl siloxane complex, and the inhibitor is selected from 3- first
Base -1- butine -3- alcohol, methylpentynol, 3,5- dimethyl -1- hexin -3- alcohol, 1- acetenyl -1- cyclohexanol, four
Methyl tetravinyl cyclotetrasiloxane, tetramethyl divinyl disiloxane, 2- acrylic -2- methoxy acrylate, 2- acrylic -
One of 2- butoxyethyl and 2- phenyl -3- butine-ethyl alcohol are a variety of, and the Anchor Agent is selected from silane coupling agent, ethylene
Ethyl triethoxy silicane alkane, vinyltrimethoxysilane, vinyl three (2- methoxy ethoxy) silane, 3- (2,3 epoxies third
Oxygen) hydroxypropyl methyl diethoxy silane, 3- (2,3 the third oxygen of epoxy) propyl-triethoxysilicane, 2- (3,4- 7-oxa-bicyclo[4.1.0 base)
Ethyl trimethoxy silane, γ-methacryloxypropyl trimethoxy silane, γ-glycidyl ether oxygen propyl trimethoxy
One of base silane, methyl orthosilicate, methyl orthosilicate condensation product, ethyl orthosilicate and ethyl orthosilicate condensation product are more
Kind.
5. emulsion-type mould release according to claim 1, which is characterized in that the concentration of the polyvinyl alcohol water solution is
4%, the content of the polyvinyl alcohol water solution is 5~15wt%.
6. emulsion-type mould release according to claim 1, which is characterized in that the content of the stabilizer is 8~10wt%.
7. emulsion-type mould release according to claim 1, which is characterized in that the content of the emulsifier be 0.4~
1wt%, the content of the catalyst are 8~18ppm, and the content of the inhibitor is 0.5~0.8wt%, the Anchor Agent
Content is 5~6wt%.
8. the preparation method of emulsion-type mould release described in claim 1, comprising the following steps:
By the vinyl silicone oil of 20~50wt%, the containing hydrogen silicone oil of 0.5~10wt%, 5~20wt% polyvinyl alcohol water solution,
The stabilizer of 6~15wt%, the emulsifier of 0.3~3wt%, the inhibitor of 0.5~1.0wt% and the Anchor Agent of 5~10wt%
The deionized water of 30~50wt% is added after mixing, homogeneous after the completion of phase inversion obtains component A；
By the vinyl silicone oil of 5~20wt%, the catalyst of 60~2520ppm, 10~20wt% polyvinyl alcohol water solution and
30~50wt% deionized water is added after the emulsifier mixing of 0.3~3wt%, homogeneous after the completion of phase inversion obtains B component；
Component A, B component and deionized water are mixed according to the mass ratio of 20:1:100, obtain emulsion-type mould release.
9. preparation method according to claim 8, which is characterized in that the viscosity of the component A is 50~200cps, described
The viscosity of B component is 25~50cps.
10. preparation method according to claim 8, which is characterized in that in the step of preparing component A and preparation B component,
The homogeneous carries out in high pressure homogenizer, and the pressure of the homogeneous is 30MPa, and the number of the homogeneous is 3~10 times.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111925727A (en) * | 2020-08-11 | 2020-11-13 | 浙江洁美电子科技股份有限公司 | Release agent for polaroid, release film and preparation method of release agent |
| CN114163656A (en) * | 2021-12-16 | 2022-03-11 | 杭州崇耀科技发展有限公司 | Silicone rubber emulsion, skin-feel emulsion type fabric coating agent and preparation method thereof |
| CN114316297A (en) * | 2020-10-09 | 2022-04-12 | 南京瑞思化学技术有限公司 | Preparation method of polysiloxane emulsion |
| CN114874700A (en) * | 2022-04-25 | 2022-08-09 | 杭州崇耀科技发展有限公司 | Environment-friendly release agent and preparation method thereof |
| CN115404117A (en) * | 2021-05-26 | 2022-11-29 | 中国石油天然气股份有限公司 | Isolation working fluid and preparation method thereof |
| CN115975428A (en) * | 2021-10-15 | 2023-04-18 | 山东东岳高分子材料有限公司 | Anchoring agent for fluorine-silicon release agent and application thereof |
| CN116082876A (en) * | 2023-01-10 | 2023-05-09 | 杭州崇耀科技发展有限公司 | Wax-feel parting agent |
| CN118459993A (en) * | 2024-04-03 | 2024-08-09 | 清远慧谷新材料技术有限公司 | Two-component paper molding silicone emulsion and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105899617A (en) * | 2013-11-26 | 2016-08-24 | 道康宁(中国)投资有限公司 | Anchorage additive emulsion for silicone release coating composition |
| KR20170140873A (en) * | 2016-06-14 | 2017-12-22 | 삼지산업 주식회사 | Film comprising antistatic layer and manufacturing method threrof |
| CN108178985A (en) * | 2017-12-20 | 2018-06-19 | 上海楚艺佳有机硅材料有限公司 | Aqueous mould release of transfer membrane and preparation method thereof |
-
2018
- 2018-10-24 CN CN201811241961.6A patent/CN109504281A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105899617A (en) * | 2013-11-26 | 2016-08-24 | 道康宁(中国)投资有限公司 | Anchorage additive emulsion for silicone release coating composition |
| KR20170140873A (en) * | 2016-06-14 | 2017-12-22 | 삼지산업 주식회사 | Film comprising antistatic layer and manufacturing method threrof |
| CN108178985A (en) * | 2017-12-20 | 2018-06-19 | 上海楚艺佳有机硅材料有限公司 | Aqueous mould release of transfer membrane and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张剑等: "《现代润滑技术》", 31 January 2008, 冶金工业出版社 * |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111925727A (en) * | 2020-08-11 | 2020-11-13 | 浙江洁美电子科技股份有限公司 | Release agent for polaroid, release film and preparation method of release agent |
| CN111925727B (en) * | 2020-08-11 | 2022-04-08 | 浙江洁美电子科技股份有限公司 | Release agent for polaroid, release film and preparation method of release agent |
| CN114316297B (en) * | 2020-10-09 | 2024-06-18 | 南京瑞思化学技术有限公司 | Preparation method of polysiloxane emulsion |
| CN114316297A (en) * | 2020-10-09 | 2022-04-12 | 南京瑞思化学技术有限公司 | Preparation method of polysiloxane emulsion |
| CN115404117B (en) * | 2021-05-26 | 2023-09-26 | 中国石油天然气股份有限公司 | Isolation working solution and preparation method thereof |
| CN115404117A (en) * | 2021-05-26 | 2022-11-29 | 中国石油天然气股份有限公司 | Isolation working fluid and preparation method thereof |
| CN115975428A (en) * | 2021-10-15 | 2023-04-18 | 山东东岳高分子材料有限公司 | Anchoring agent for fluorine-silicon release agent and application thereof |
| CN115975428B (en) * | 2021-10-15 | 2023-07-18 | 山东东岳高分子材料有限公司 | Anchoring agent for fluorine-silicon release agent and application thereof |
| CN114163656B (en) * | 2021-12-16 | 2023-07-07 | 杭州崇耀科技发展有限公司 | Silicone rubber emulsion, skin feel emulsion type fabric coating agent and preparation method thereof |
| CN114163656A (en) * | 2021-12-16 | 2022-03-11 | 杭州崇耀科技发展有限公司 | Silicone rubber emulsion, skin-feel emulsion type fabric coating agent and preparation method thereof |
| CN114874700A (en) * | 2022-04-25 | 2022-08-09 | 杭州崇耀科技发展有限公司 | Environment-friendly release agent and preparation method thereof |
| CN116082876A (en) * | 2023-01-10 | 2023-05-09 | 杭州崇耀科技发展有限公司 | Wax-feel parting agent |
| CN116082876B (en) * | 2023-01-10 | 2023-09-26 | 杭州崇耀科技发展有限公司 | Wax-feel parting agent |
| CN118459993A (en) * | 2024-04-03 | 2024-08-09 | 清远慧谷新材料技术有限公司 | Two-component paper molding silicone emulsion and preparation method thereof |
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