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CN109500663A - A kind of polishing process reducing by 8 inches of silicon polished surface roughnesses - Google Patents

A kind of polishing process reducing by 8 inches of silicon polished surface roughnesses Download PDF

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Publication number
CN109500663A
CN109500663A CN201910015754.7A CN201910015754A CN109500663A CN 109500663 A CN109500663 A CN 109500663A CN 201910015754 A CN201910015754 A CN 201910015754A CN 109500663 A CN109500663 A CN 109500663A
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CN
China
Prior art keywords
polishing
silicon
pure water
inches
cleaning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910015754.7A
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Chinese (zh)
Inventor
石明
王广勇
吴镐硕
刘秒
吕莹
徐荣清
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin Zhonghuan Semiconductor Joint Stock Co Ltd
Tianjin Zhonghuan Advanced Material Technology Co Ltd
Original Assignee
Tianjin Zhonghuan Semiconductor Joint Stock Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin Zhonghuan Semiconductor Joint Stock Co Ltd filed Critical Tianjin Zhonghuan Semiconductor Joint Stock Co Ltd
Priority to CN201910015754.7A priority Critical patent/CN109500663A/en
Publication of CN109500663A publication Critical patent/CN109500663A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B1/00Processes of grinding or polishing; Use of auxiliary equipment in connection with such processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B53/00Devices or means for dressing or conditioning abrasive surfaces

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Mechanical Treatment Of Semiconductor (AREA)

Abstract

The present invention provides a kind of polishing process for reducing by 8 inches of silicon polished surface roughnesses, polishing process includes the following steps: to carry out waxing operation to silication corruption piece, obtains waxing silicon wafer;Waxing silicon wafer is polished according to the sequence of rough polishing, first time finishing polish, second of finishing polish, obtains polished silicon slice;Wax is carried out to polished silicon slice to clean, and is obtained silicon polished.Overcome the deficiencies in the prior art of the present invention, reduces polished silicon wafer surface roughness, and roughness can be reduced to 0.0001um or less.

Description

A kind of polishing process reducing by 8 inches of silicon polished surface roughnesses
Technical field
The invention belongs to silicon polished production fields, more particularly, to a kind of 8 inches of silicon polished processing of surface polishing.
Background technique
In recent years, with the high speed development of semicon industry and fierce market competition, the integrated level of semiconductor devices is not Disconnected to improve, feature sizes constantly reduce, and the requirement to the control of original silicon material and processing quality is also increasingly harsher;With silicon Material diameter becomes larger and the range of the controls such as silicon chip surface flatness, microroughness will be smaller and smaller, and this requires semiconductor devices The silicon polished level with higher in the technical indicator of substrate material used in part, and the country is on silicon polished surface at present It is had a certain gap in the control of roughness with international most advanced level, it would be highly desirable to improve.
Surface roughness occurs mainly in silicon wafer polishing and polished silicon wafer cleaning process, therefore polishing and cleaning process are exactly Prepare the key of silicon polished section with low-roughness concentration.
Summary of the invention
In view of this, the present invention is directed to propose a kind of polishing process for reducing by 8 inches of silicon polished surface roughnesses and its Using overcome the deficiencies in the prior art reduces polished silicon wafer surface roughness, and roughness can be reduced to 0.0001um or less.
In order to achieve the above objectives, the technical scheme of the present invention is realized as follows:
A kind of polishing process reducing by 8 inches of silicon polished surface roughnesses, includes the following steps:
Step 1: waxing operation being carried out to silication corruption piece, obtains waxing silicon wafer;
Step 2: waxing silicon wafer being polished according to the sequence of rough polishing, first time finishing polish, second of finishing polish, is obtained To polished silicon slice;
Step 3: wax being carried out to polished silicon slice and is cleaned, is obtained silicon polished.
Preferably, in rough polishing step, using rough polishing cloth, diluted rough polishing liquid, flow 8-12L/min, polish pressure For 250-400g/cm2, polishing machine price fixing revolving speed is 20-40rpm, polishing time 10-14min;Preferably, rough polishing step In, using rough polishing cloth, diluted rough polishing liquid, flow 9.5-10.5L/min, polish pressure 300g/cm2, polishing machine price fixing Revolving speed is 35rpm, polishing time 12min.
Preferably, diluted rough polishing liquid is to dilute rough polishing liquid, dilution ratio 1:20-1:40 by pure water;Preferably, dilute The rough polishing liquid released is to dilute rough polishing liquid, dilution ratio 1:30 by pure water.
Preferably, in first time finishing polish step, cloth, diluted fine polishing liquid, flow 1-4L/min, polishing are thrown using essence Pressure is 100-300g/cm2, polishing machine price fixing revolving speed is 20-40rpm, polishing time 7-10min;Preferably, smart for the first time In polishing step, cloth, diluted fine polishing liquid, flow 2.5-3.5L/min, polish pressure 200g/cm are thrown using essence2, polishing Machine price fixing revolving speed is 25rpm, polishing time 8min.
Preferably, in second of finishing polish step, cloth, diluted fine polishing liquid, flow 1-4L/min, polishing are thrown using essence Pressure is 50-200g/cm2, polishing machine price fixing revolving speed is 20-40rpm, polishing time 7-10min;Preferably, second of essence In polishing step, cloth, diluted fine polishing liquid, flow 2.5-3.5L/min, polish pressure 100g/cm are thrown using essence2, polishing Machine price fixing revolving speed is 25rpm, polishing time 8min.
Preferably, diluted fine polishing liquid is to dilute fine polishing liquid, dilution ratio 1:20-1:40 by pure water;Preferably, dilute The fine polishing liquid released is to dilute fine polishing liquid, dilution ratio 1:30 by pure water.
Preferably, remove wax cleaning step successively and sequentially include: SC-1 cleaning, pure water cleaning, SC-1 cleaning, pure water cleaning, Pure water cleaning, SC-2 cleaning, pure water cleaning, pure water cleaning, IR drying.
Preferably, wherein SC-1 is cleaned, and cleaning temperature is 50 DEG C, and scavenging period 5min, SC-1 medical fluid includes such as lower body The component of product ratio: ammonium hydroxide: hydrogen peroxide: pure water=1:1:30, wherein ammonia concn is 28-30%, hydrogen peroxide concentration 30- 32%, pure water resistivity > 18M Ω .CM;Preferably, wherein SC-2 is cleaned, and cleaning temperature is room temperature, scavenging period 5min, SC-2 medical fluid includes the component of following volume ratio: hydrochloric acid: hydrogen peroxide: pure water=1:1:25, and wherein concentration of hydrochloric acid is 36- 38%, hydrogen peroxide concentration 30-32%, pure water resistivity > 18M Ω .CM.
Preferably, what is obtained is silicon polished, and surface roughness is less than 0.0001um;Preferably, polishing removal amount is 18- 20um。
A kind of polishing process application reducing by 8 inches of silicon polished surface roughnesses, is applied to power device, integrated circuit Device, discrete device, IGBT device monocrystalline silicon buffing sheet polishing in.
Compared with the existing technology, a kind of polishing process reducing by 8 inches of silicon polished surface roughnesses of the present invention And its application has the advantage that
(1) polishing method that the present invention is thrown using rough polishing and two step essences, rough polishing can effectively remove surface damage layer, Reduce surface defect;The repair that two step essences are thrown can effectively remove the micro-damage of silicon chip surface after rough polishing, and it is thick to reduce surface Rugosity;
(2) polishing fluid dilution ratio used in is high, and pH value is relatively low, can reduce polishing fluid to silicon wafer polishing surface Corrosion;
(3) using the cleaning process of low concentration, low temperature after polishing, corruption of the cleaning solution to silicon wafer polishing surface can be reduced Erosion reduces the risk that silicon chip surface roughness is deteriorated;
(4) silicon chip surface that present invention processing obtains is smooth, and roughness can be reduced to 0.0001um or less;
(5) present invention controls silicon wafer polishing removal amount in 18-20um, can produce in batches, and quality is stablized.
Specific embodiment
In addition to being defined, technical term used in following embodiment has universal with those skilled in the art of the invention The identical meanings of understanding.Test reagent used in following embodiment is unless otherwise specified conventional biochemical reagent;It is described Experimental method is unless otherwise specified conventional method.
Below with reference to embodiment, the present invention will be described in detail.
Embodiment
The silicon polished example for having wax polishing process is gently mixed to the vertical pulling of 8 inches of 725um thickness to be described in detail:
Silicon wafer: 8 inches of vertical pullings gently mix silication corruption piece, crystal orientation<100>, resistivity 8-18 Ω .cm, thickness 744- before polishing 746um, quantity 300;
Process equipment: single side has wax polishing system, removes wax cleaning machine;
Auxiliary material: rough polishing solution: NP6504;Precise polishing solution: GLANZOX3105;Diluted rough polishing solution (dilution volume Ratio 1:30), diluted precise polishing solution (dilution volume ratio 1:30), rough polishing cloth, precision polishing cloth, ammonium hydroxide (concentration 29wt%), hydrogen peroxide (concentration 32wt%), hydrochloric acid (concentration 36wt%), pure water: pure water resistivity > 18M Ω .CM etc.;
Polishing process are as follows:
Step 1: waxing operation being carried out to silication corruption piece, obtains waxing silicon wafer;Certainly by chip mounter by clean silication corruption piece Dynamic to carry out waxing patch operation to silication corruption piece, ceramic disk patch terminates to be automatically sent to prepare polishing on polishing machine;
Step 2: waxing silicon wafer being polished according to the sequence of rough polishing, first time finishing polish, second of finishing polish, is obtained To polished silicon slice;After polishing, shovel piece is carried out to polished silicon slice on unloading platform, silicon wafer is removed from ceramic disk
Step 3: wax being carried out to polished silicon slice and is cleaned, is obtained silicon polished.
Step 4: silicon polished after cleaning is detected;Whether there is or not road plan, chippings etc. on visual inspection surface under major light no It is good.
In rough polishing step, using rough polishing cloth, diluted rough polishing liquid, flow 10L/min, polish pressure 300g/ cm2, polishing machine price fixing revolving speed is 35rpm, polishing time 12min.
In first time finishing polish step, cloth is thrown using essence, diluted fine polishing liquid, flow 3L/min, polish pressure is 200g/cm2, polishing machine price fixing revolving speed is 25rpm, polishing time 8min.
In second of finishing polish step, cloth is thrown using essence, diluted fine polishing liquid, flow 3L/min, polish pressure is 100g/cm2, polishing machine price fixing revolving speed is 25rpm, polishing time 8min.
Removing wax cleaning step successively sequentially includes: SC-1 cleaning, pure water cleaning, SC-1 is cleaned, pure water cleans, pure water is clear It washes, SC-2 cleaning, pure water cleaning, pure water cleaning, IR drying.
Wherein SC-1 is cleaned, and cleaning temperature is 50 DEG C, and scavenging period 5min, SC-1 medical fluid includes following volume ratio Component: ammonium hydroxide: hydrogen peroxide: pure water=1:1:30;Wherein SC-2 is cleaned, and cleaning temperature is room temperature, scavenging period 5min, SC-2 Medical fluid includes the component of following volume ratio: hydrochloric acid: hydrogen peroxide: pure water=1:1:25.
Geometric parameter (thickness, TTV, TIR, STIR etc.) is tested with ADE9600;Examine surface clean with particle detector SP1 Cleanliness;Burnishing surface surface roughness is tested using Chapman microscope;
Technical effect detection: it using the monocrystalline silicon buffing sheet of above-mentioned technique processing, is detected through microscope, surface roughness is equal Less than 0.0001um, reach world-class levels;Silicon wafer after polishing tests other parameters index, is higher than original process Level, comprehensive yield reach 96% or more;The testing result shows that this technique is able to achieve the silicon polished amount of low surface roughness It produces.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of polishing process for reducing by 8 inches of silicon polished surface roughnesses, characterized by the following steps:
Step 1: waxing operation being carried out to silication corruption piece, obtains waxing silicon wafer;
Step 2: waxing silicon wafer being polished according to the sequence of rough polishing, first time finishing polish, second of finishing polish, is thrown Light silicon wafer;
Step 3: wax being carried out to polished silicon slice and is cleaned, is obtained silicon polished.
2. a kind of polishing process for reducing by 8 inches of silicon polished surface roughnesses according to claim 1, feature exist In: in rough polishing step, using rough polishing cloth, diluted rough polishing liquid, flow 8-12L/min, polish pressure 250-400g/ cm2, polishing machine price fixing revolving speed is 20-40rpm, polishing time 10-14min;Preferably, in rough polishing step, using rough polishing Cloth, diluted rough polishing liquid, flow 9.5-10.5L/min, polish pressure 300g/cm2, polishing machine price fixing revolving speed is 35rpm, Polishing time is 12min.
3. a kind of polishing process for reducing by 8 inches of silicon polished surface roughnesses according to claim 2, feature exist In: diluted rough polishing liquid is to dilute rough polishing liquid, dilution ratio 1:20-1:40 by pure water;Preferably, diluted rough polishing liquid is Rough polishing liquid, dilution ratio 1:30 are diluted by pure water.
4. a kind of polishing process for reducing by 8 inches of silicon polished surface roughnesses according to claim 1, feature exist In: in first time finishing polish step, cloth, diluted fine polishing liquid, flow 1-4L/min, polish pressure 100- are thrown using essence 300g/cm2, polishing machine price fixing revolving speed is 20-40rpm, polishing time 7-10min;Preferably, first time finishing polish step In, cloth, diluted fine polishing liquid, flow 2.5-3.5L/min, polish pressure 200g/cm are thrown using essence2, polishing machine price fixing turn Speed is 25rpm, polishing time 8min.
5. a kind of polishing process for reducing by 8 inches of silicon polished surface roughnesses as claimed in claim 4, it is characterised in that: the In secondary fine polishing step, cloth, diluted fine polishing liquid, flow 1-4L/min, polish pressure 50-200g/ are thrown using essence cm2, polishing machine price fixing revolving speed is 20-40rpm, polishing time 7-10min;Preferably, it in second of finishing polish step, uses Essence throws cloth, diluted fine polishing liquid, flow 2.5-3.5L/min, polish pressure 100g/cm2, polishing machine price fixing revolving speed is 25rpm, polishing time 8min.
6. a kind of polishing process for reducing by 8 inches of silicon polished surface roughnesses according to claim 5, feature exist In: diluted fine polishing liquid is to dilute fine polishing liquid, dilution ratio 1:20-1:40 by pure water;Preferably, diluted fine polishing liquid is Fine polishing liquid, dilution ratio 1:30 are diluted by pure water.
7. a kind of polishing process for reducing by 8 inches of silicon polished surface roughnesses according to claim 1, feature exist In: removing wax cleaning step successively sequentially includes: SC-1 cleaning, pure water cleaning, SC-1 cleaning, pure water cleaning, pure water cleaning, SC-2 Cleaning, pure water cleaning, pure water cleaning, IR drying.
8. a kind of polishing process for reducing by 8 inches of silicon polished surface roughnesses as claimed in claim 7, it is characterised in that: its Middle SC-1 cleaning, cleaning temperature are 50 DEG C, and scavenging period 5min, SC-1 medical fluid includes the component of following volume ratio: ammonium hydroxide: Hydrogen peroxide: pure water=1:1:30, wherein ammonia concn is 28-30%, hydrogen peroxide concentration 30-32%, pure water resistivity > 18M Ω.CM;Preferably, wherein SC-2 is cleaned, and cleaning temperature is room temperature, and scavenging period 5min, SC-2 medical fluid includes such as lower volume The component of ratio: hydrochloric acid: hydrogen peroxide: pure water=1:1:25, wherein concentration of hydrochloric acid is 36-38%, hydrogen peroxide concentration 30- 32%, pure water resistivity > 18M Ω .CM.
9. a kind of polishing process for reducing by 8 inches of silicon polished surface roughnesses according to claim 1, feature exist In: what is obtained is silicon polished, and surface roughness is less than 0.0001um;Preferably, polishing removal amount is 18-20um.
10. a kind of -9 described in any item polishing processes for reducing by 8 inches of silicon polished surface roughnesses according to claim 1 are answered With, it is characterised in that: applied to power device, integrated circuit device, discrete device, IGBT device monocrystalline silicon buffing sheet throwing In light processing.
CN201910015754.7A 2019-01-08 2019-01-08 A kind of polishing process reducing by 8 inches of silicon polished surface roughnesses Pending CN109500663A (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110281082A (en) * 2019-05-28 2019-09-27 天津中环领先材料技术有限公司 A kind of polishing process of 8 inch silicon wafer of high-flatness
CN111659665A (en) * 2020-05-29 2020-09-15 徐州鑫晶半导体科技有限公司 Silicon wafer cleaning method and silicon wafer cleaning equipment
CN111681944A (en) * 2020-05-11 2020-09-18 中环领先半导体材料有限公司 Cleaning process for cleaning semiconductor silicon wafer of 200mm
CN111690987A (en) * 2020-07-19 2020-09-22 湖州飞鹿新能源科技有限公司 Crystal silicon surface fine polishing method based on alkaline polishing gel
CN112466998A (en) * 2020-12-09 2021-03-09 中国电子科技集团公司第四十六研究所 Manufacturing method of four-inch 80-micron gallium arsenide double polished wafer
CN112975578A (en) * 2019-12-12 2021-06-18 有研半导体材料有限公司 Polishing method for improving surface roughness of silicon polished wafer
CN113192823A (en) * 2021-04-27 2021-07-30 麦斯克电子材料股份有限公司 Regeneration processing method of substrate slice after SOI bonding process
CN113808918A (en) * 2021-09-14 2021-12-17 万华化学集团电子材料有限公司 A kind of preparation process of high cleanliness polishing sheet
CN113829221A (en) * 2021-09-14 2021-12-24 上海中欣晶圆半导体科技有限公司 A method for improving the poor polishing corrugation of thin slices
CN113927377A (en) * 2021-10-21 2022-01-14 中环领先半导体材料有限公司 Polishing process for improving surface roughness of silicon wafer
CN114378645A (en) * 2020-10-16 2022-04-22 万华化学集团电子材料有限公司 Preparation process of high-flatness polished wafer

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CN102019582A (en) * 2010-12-10 2011-04-20 天津中环领先材料技术有限公司 Polishing process of 8-inch polished wafers doped with silicon lightly
CN102490439A (en) * 2011-12-15 2012-06-13 天津中环领先材料技术有限公司 Waxy surface mount device process adopting zone-melt single crystal silicon double-side polished chip for IGBT (insulated gate bipolar transistor)
CN102974565A (en) * 2012-12-12 2013-03-20 天津中环领先材料技术有限公司 Method for cleaning monocrystalline silicon polished wafer
CN108242396A (en) * 2016-12-23 2018-07-03 有研半导体材料有限公司 A kind of processing method for reducing silicon polished surface roughness

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CN101934492A (en) * 2010-08-10 2011-01-05 天津中环领先材料技术有限公司 Polishing process of high-smoothness float-zone silicon polished wafer
CN102019582A (en) * 2010-12-10 2011-04-20 天津中环领先材料技术有限公司 Polishing process of 8-inch polished wafers doped with silicon lightly
CN102490439A (en) * 2011-12-15 2012-06-13 天津中环领先材料技术有限公司 Waxy surface mount device process adopting zone-melt single crystal silicon double-side polished chip for IGBT (insulated gate bipolar transistor)
CN102974565A (en) * 2012-12-12 2013-03-20 天津中环领先材料技术有限公司 Method for cleaning monocrystalline silicon polished wafer
CN108242396A (en) * 2016-12-23 2018-07-03 有研半导体材料有限公司 A kind of processing method for reducing silicon polished surface roughness

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110281082A (en) * 2019-05-28 2019-09-27 天津中环领先材料技术有限公司 A kind of polishing process of 8 inch silicon wafer of high-flatness
CN112975578A (en) * 2019-12-12 2021-06-18 有研半导体材料有限公司 Polishing method for improving surface roughness of silicon polished wafer
CN112975578B (en) * 2019-12-12 2022-06-24 有研半导体硅材料股份公司 Polishing method for improving surface roughness of silicon polished wafer
CN111681944A (en) * 2020-05-11 2020-09-18 中环领先半导体材料有限公司 Cleaning process for cleaning semiconductor silicon wafer of 200mm
CN111659665B (en) * 2020-05-29 2022-02-01 徐州鑫晶半导体科技有限公司 Silicon wafer cleaning method and silicon wafer cleaning equipment
CN111659665A (en) * 2020-05-29 2020-09-15 徐州鑫晶半导体科技有限公司 Silicon wafer cleaning method and silicon wafer cleaning equipment
CN111690987A (en) * 2020-07-19 2020-09-22 湖州飞鹿新能源科技有限公司 Crystal silicon surface fine polishing method based on alkaline polishing gel
CN114378645A (en) * 2020-10-16 2022-04-22 万华化学集团电子材料有限公司 Preparation process of high-flatness polished wafer
CN112466998A (en) * 2020-12-09 2021-03-09 中国电子科技集团公司第四十六研究所 Manufacturing method of four-inch 80-micron gallium arsenide double polished wafer
CN112466998B (en) * 2020-12-09 2022-08-12 中国电子科技集团公司第四十六研究所 A method of manufacturing a four-inch 80-micron gallium arsenide double-polished wafer
CN113192823A (en) * 2021-04-27 2021-07-30 麦斯克电子材料股份有限公司 Regeneration processing method of substrate slice after SOI bonding process
CN113192823B (en) * 2021-04-27 2022-06-21 麦斯克电子材料股份有限公司 Regeneration processing method of substrate slice after SOI bonding process
CN113829221A (en) * 2021-09-14 2021-12-24 上海中欣晶圆半导体科技有限公司 A method for improving the poor polishing corrugation of thin slices
CN113808918A (en) * 2021-09-14 2021-12-17 万华化学集团电子材料有限公司 A kind of preparation process of high cleanliness polishing sheet
CN113927377A (en) * 2021-10-21 2022-01-14 中环领先半导体材料有限公司 Polishing process for improving surface roughness of silicon wafer

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