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CN109456599A - A kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape - Google Patents

A kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape Download PDF

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Publication number
CN109456599A
CN109456599A CN201811191943.1A CN201811191943A CN109456599A CN 109456599 A CN109456599 A CN 109456599A CN 201811191943 A CN201811191943 A CN 201811191943A CN 109456599 A CN109456599 A CN 109456599A
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CN
China
Prior art keywords
parts
fire
expansion
adhesive tape
retardant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811191943.1A
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Chinese (zh)
Inventor
陈国东
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHEJIANG YANHE NEW MATERIAL CO Ltd
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ZHEJIANG YANHE NEW MATERIAL CO Ltd
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Publication date
Application filed by ZHEJIANG YANHE NEW MATERIAL CO Ltd filed Critical ZHEJIANG YANHE NEW MATERIAL CO Ltd
Priority to CN201811191943.1A priority Critical patent/CN109456599A/en
Publication of CN109456599A publication Critical patent/CN109456599A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B7/00Special arrangements or measures in connection with doors or windows
    • E06B7/16Sealing arrangements on wings or parts co-operating with the wings
    • E06B7/22Sealing arrangements on wings or parts co-operating with the wings by means of elastic edgings, e.g. elastic rubber tubes; by means of resilient edgings, e.g. felt or plush strips, resilient metal strips
    • E06B7/23Plastic, sponge rubber, or like strips or tubes
    • E06B7/2314Plastic, sponge rubber, or like strips or tubes characterised by the material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0812Aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/06Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape, including the fire prevention Expandable strip and fire-retardant, Expansion sealing adhesive tape being connected, according to the component meter of parts by weight, the fire prevention Expandable strip includes following component: 15-25 parts of neat silicone powder, 3-8 parts of paraffin, 15-24 parts of expanded graphite, without 0.2-0.8 parts of fumicants, 3-5 parts of zinc stearate, 15-25 parts of toughener, 4-9 parts of promotor, 10 parts of curing agent;Fire-retardant, the Expansion sealing adhesive tape includes following component: 10-15 parts of the fire prevention Expandable strip, and 20-35 parts of neat silicone powder, 15-25 parts of aluminium powder, 8-15 parts of mica powder.The present invention does not allow easy firing when meeting fire conditions, timely automated can expand and block crack between a door and its frame gap, obstruct the air circulation of two spaces, effectively prevent the harm of dense smoke, poison gas to human body, reaches effectively control control fire spreading, prevents the condition of a disaster from expanding.

Description

A kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape
Technical field
The present invention relates to a kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape, belong to fire proofing material field.
Background technique
With the raising that the development of doors and windows sealing industry and quality of life require, sealing requirements of the people for door and window It is higher and higher.Sealing strip plays such as sound insulation, dust-proof, fire prevention and energy conservation in plastic-steel door and window and bridge cut-off aluminium door and window and Wood-door window and makees With;Currently, the sealing strip on fire resistant doorsets and fire window is to make outer tube with alumina silicate fibre, core is filled out with rock wool, fills out core packet It is rolled in manufactured round tubular sealing strip in outer tube.The shortcomings that this sealing strip, is easy to damage and falls off, and is harmful to the human body, only It can prevent fires non-ignitable, cannot play the role of sealing fire insulation every cigarette.Most importantly manufactured fire prevention industrial at this stage Material cannot rise with temperature and be expanded, thus sealing effect is bad always.
For example, the patent of invention that patent application publication number is CN1198421 discloses a kind of fire prevention expanding material, Yi Zhongfang Fiery expanding sealing strips and preparation method thereof, the fire prevention expanding material mainly include silica, barium metaborate, polyvinyl acetate Ester, ammonium polyphosphate, dicyandiamide, sodium metasilicate ingredient;Outside the sealing strip effective flame-proof PVC mixing material be made, fill out core with it is above-mentioned at The fire prevention expanding material divided is made;Sealing strip is first made outer tube, then fills out core, then will be filled out the technique that core is packed into outer tube and is done At.
Another fire proofing material for being used for fire-proof doors and windows set forth below.
Summary of the invention
The present invention expands and fire-retardant expansion combination sealing adhesive tape in view of the deficienciess of the prior art, providing a kind of fire prevention, Easy firing is not allowed when meeting fire conditions, timely automated can be expanded and be blocked crack between a door and its frame gap, obstruct the air stream of two spaces It is logical, the harm of dense smoke, poison gas to human body is effectively prevented, reaches effectively control control fire spreading, prevents the condition of a disaster from expanding.
The technical scheme to solve the above technical problems is that a kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape, Including the fire prevention Expandable strip and fire-retardant, Expansion sealing adhesive tape being connected, according to the component meter of parts by weight, the fire prevention Expandable strip packet Include following component: 15-25 parts of neat silicone powder, 3-8 parts of paraffin, 15-24 parts of expanded graphite, no fumicants 0.2-0.8 parts, stearic acid 3-5 parts of zinc, 15-25 parts of toughener, 4-9 parts of promotor, 10 parts of curing agent;Fire-retardant, the Expansion sealing adhesive tape includes with the following group Part: 10-15 parts of the fire prevention Expandable strip, 20-35 parts of neat silicone powder, 15-25 parts of aluminium powder, 8-15 parts of mica powder.
The present invention is further, and the fire prevention Expandable strip further includes following component according to the component meter of parts by weight: OOP oil 20-30 parts, 3-8 parts of carbon forming agent, 3-8 parts of fluoroprotein foam extinguishing agent, 2-4 parts of magnesium hydroxide.
The present invention is further, and the toughener is epoxy resin.
The present invention is further, and the promotor is triethanolamine.
The present invention is further, and the carbon forming agent is graphite oxide.
The present invention is further, and the no fumicants is wood powder.
The present invention is further, and fire-retardant, the Expansion sealing adhesive tape further includes uvioresistant according to the component meter of parts by weight 5-10 parts of master batch, 2-3 parts of age resister.
The present invention is further, and the fire prevention Expandable strip and fire-retardant, Expansion sealing adhesive tape are in clamping setting.
In conclusion the invention has the following advantages: fire proofing material is not when neat silicone powder high temperature is up to 900 DEG C or more Burning, and gradually expand, play the role of fire insulation every cigarette;Expanded graphite contains a kind of N-P cage modle macromolecular, and cage modle containing N-P is big Molecule expansion type flame retardant is a kind of new unimolecular expanding fire retardant for integrating carbon source, acid source and gas source three elements, tool Have flame retarding efficiency is high, thermal stability is good, compatibility is good, it is fast light, anti-aging, without melting dropping, low cigarette, nontoxic, corrosion-free gas The advantages that body discharges, meets the requirement of environmental-friendly flame-retardant system;Zinc stearate mainly uses neat silicone powder and expanded graphite etc. The lubricant of component in being formulated.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment 1, a kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape, it is described anti-according to the component meter of parts by weight Fiery Expandable strip includes following component: 15 parts of neat silicone powder, 8 parts of paraffin, and 24 parts of expanded graphite, 0.2 part of wood powder, zinc stearate 5 Part, 25 parts of epoxy resin, 9 parts of triethanolamine, 10 parts of curing agent;Fire-retardant, Expansion sealing adhesive tape includes following component: fire prevention expansion 15 parts of item, 20 parts of neat silicone powder, 25 parts of aluminium powder, 15 parts of mica powder.
Embodiment 2, a kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape, it is described anti-according to the component meter of parts by weight Fiery Expandable strip includes following component: 20 parts of neat silicone powder, 3 parts of paraffin, and 24 parts of expanded graphite, 0.8 part of wood powder, zinc stearate 5 Part, 25 parts of epoxy resin, 9 parts of triethanolamine, 10 parts of curing agent, further include following component: 30 parts of OOP oil, and 8 parts of graphite oxide, 3 parts of fluoroprotein foam extinguishing agent, 4 parts of magnesium hydroxide;Fire-retardant, Expansion sealing adhesive tape includes following component: the fire prevention Expandable strip 15 parts, 20 parts of neat silicone powder, 25 parts of aluminium powder, 15 parts of mica powder.
Embodiment 3, a kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape, it is described anti-according to the component meter of parts by weight Fiery Expandable strip includes following component: 17 parts of neat silicone powder, 6 parts of paraffin, and 19 parts of expanded graphite, 0.5 part of wood powder, zinc stearate 4 Part, 19 parts of epoxy resin, 7 parts of triethanolamine, 10 parts of curing agent, further include following component: 25 parts of OOP oil, and 4 parts of graphite oxide, 3 parts of fluoroprotein foam extinguishing agent, 4 parts of magnesium hydroxide;Fire-retardant, Expansion sealing adhesive tape includes following component: the fire prevention Expandable strip 13 parts, 27 parts of neat silicone powder, 18 parts of aluminium powder, 14 parts of mica powder, 8 parts of ultraviolet screening mother granule, 2.3 parts of age resister.
Embodiment 4, a kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape, it is described anti-according to the component meter of parts by weight Fiery Expandable strip includes following component: 25 parts of neat silicone powder, 6 parts of paraffin, and 17 parts of expanded graphite, 0.6 part of wood powder, zinc stearate 4 Part, 23 parts of epoxy resin, 7 parts of triethanolamine, 10 parts of curing agent, further include following component: 26 parts of OOP oil, and 7 parts of graphite oxide, 8 parts of fluoroprotein foam extinguishing agent, 4 parts of magnesium hydroxide, fire-retardant, Expansion sealing adhesive tape includes following component: the fire prevention Expandable strip 13 parts, 28 parts of neat silicone powder, 22 parts of aluminium powder, 13 parts of mica powder, 6 parts of ultraviolet screening mother granule, 2.5 parts of age resister.
Embodiment 5, a kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape, it is described anti-according to the component meter of parts by weight Fiery Expandable strip includes following component: 25 parts of neat silicone powder, 6 parts of paraffin, and 17 parts of expanded graphite, 0.6 part of wood powder, zinc stearate 4 Part, 23 parts of epoxy resin, 7 parts of triethanolamine, 10 parts of curing agent, fire-retardant, Expansion sealing adhesive tape includes following component: the fire prevention 13 parts of Expandable strip, 28 parts of neat silicone powder, 22 parts of aluminium powder, 13 parts of mica powder, 6 parts of ultraviolet screening mother granule, 2.5 parts of age resister.
Then above-described embodiment 1-5, Expandable strip of preventing fires and fire-retardant, Expansion sealing adhesive tape use bonding agent using snap fit It is fixed.
Comparative example 1, a kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape the difference is that, are prevented with embodiment 4 Fiery Expandable strip and fire-retardant, Expansion sealing adhesive tape directly adopt bonding agent and are fixed.
Embodiment 6, a kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape the difference is that, are hindered with embodiment 3 Combustion, Expansion sealing adhesive tape include following component: described 13 parts of fire prevention Expandable strip, 28 parts of neat silicone powder, and 22 parts of aluminium powder, mica powder 13 parts, 6 parts of ultraviolet screening mother granule.
Embodiment 7, a kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape the difference is that, are gone back with embodiment 4 Including following component: 7 parts of fluoroprotein foam extinguishing agent, 3 parts of magnesium hydroxide.
Comparative example 2, a kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape the difference is that, resist with embodiment 5 7 parts of ultraviolet light master batch, 2.3 parts of age resister
A kind of fire prevention expansion of the invention and fire-retardant expansion combination sealing adhesive tape are subjected to following test: detecting and records embodiment 1 into embodiment 8 ontology heat transfer (unit: W/m.K), wherein embodiment 1 be 0.26W/m.K, embodiment 2 be 0.21W/ M.K, embodiment 3 are 0.11W/m.K, and embodiment 4 is 0.09W/m.K, and embodiment 5 is 0.21W/m.K, and embodiment 6 is 0.26W/ M.K, embodiment 6 are 0.27W/m.K, and comparative example 1 is 1.01W/m.K, and comparative example 2 is 0.98 W/m.K, such visible embodiment Heat transfer very little, can be very good to play the efficiency of trap heat conduction, improve safety.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, it is all in spirit of the invention and Within principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (8)

1. a kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape, which is characterized in that including the fire prevention Expandable strip that is connected with Fire-retardant, Expansion sealing adhesive tape, according to the component meter of parts by weight, the fire prevention Expandable strip includes following component:
15-25 parts of neat silicone powder, 3-8 parts of paraffin,
15-24 parts of expanded graphite,
Without 0.2-0.8 parts of fumicants,
3-5 parts of zinc stearate,
15-25 parts of toughener,
4-9 parts of promotor,
10 parts of curing agent;
Fire-retardant, the Expansion sealing adhesive tape includes following component:
10-15 parts of the fire prevention Expandable strip,
20-35 parts of neat silicone powder,
15-25 parts of aluminium powder,
8-15 parts of mica powder.
2. a kind of fire prevention expansion according to claim 1 and fire-retardant expansion combination sealing adhesive tape, which is characterized in that described anti- Fiery Expandable strip further includes following component according to the component meter of parts by weight: 20-30 parts of OOP oil, 3-8 parts of carbon forming agent, and fluoroprotein foam 3-8 parts of extinguishing chemical, 2-4 parts of magnesium hydroxide.
3. a kind of fire prevention expansion according to claim 1 and fire-retardant expansion combination sealing adhesive tape, which is characterized in that the increasing Tough dose is epoxy resin.
4. a kind of fire prevention expansion according to claim 1 and fire-retardant expansion combination sealing adhesive tape, which is characterized in that the rush It is triethanolamine into agent.
5. a kind of fire prevention expansion according to claim 1 and fire-retardant expansion combination sealing adhesive tape, which is characterized in that it is described at Charcoal agent is graphite oxide.
6. a kind of fire prevention expansion according to claim 1 and fire-retardant expansion combination sealing adhesive tape, which is characterized in that the nothing Fumicants is wood powder.
7. a kind of fire prevention expansion according to claim 1 and fire-retardant expansion combination sealing adhesive tape, which is characterized in that the resistance Combustion, Expansion sealing adhesive tape further include 5-10 parts of ultraviolet screening mother granule, 2-3 parts of age resister according to the component meter of parts by weight.
8. a kind of fire prevention expansion according to claim 1 and fire-retardant expansion combination sealing adhesive tape, which is characterized in that described anti- Fiery Expandable strip and fire-retardant, Expansion sealing adhesive tape are in clamping setting.
CN201811191943.1A 2018-10-12 2018-10-12 A kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape Pending CN109456599A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811191943.1A CN109456599A (en) 2018-10-12 2018-10-12 A kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811191943.1A CN109456599A (en) 2018-10-12 2018-10-12 A kind of fire prevention expansion and fire-retardant expansion combination sealing adhesive tape

Publications (1)

Publication Number Publication Date
CN109456599A true CN109456599A (en) 2019-03-12

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112127780A (en) * 2020-10-19 2020-12-25 王小兰 Expansion sealing strip applied to fireproof space and preparation method thereof
CN115707754A (en) * 2021-08-18 2023-02-21 应急管理部四川消防研究所 Fireproof flame-retardant expandable sealant and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5344866A (en) * 1993-05-21 1994-09-06 General Electric Company Fire resistant composites
CN1572824A (en) * 2003-06-18 2005-02-02 希尔蒂股份公司 Use of thermally expandable graphite intercalation compounds for producing fire-protection seals and method for their production
CN104558716A (en) * 2015-01-14 2015-04-29 四川大学 Efficient halogen-free flame retardant rubber system as well as preparation method thereof
CN105820793A (en) * 2016-05-24 2016-08-03 长春科英精益技术有限公司 Expansive type double-component fireproof sealant and preparation method thereof
CN106967264A (en) * 2017-05-20 2017-07-21 尹书祥 A kind of fire-proof expansion seal strip and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5344866A (en) * 1993-05-21 1994-09-06 General Electric Company Fire resistant composites
CN1572824A (en) * 2003-06-18 2005-02-02 希尔蒂股份公司 Use of thermally expandable graphite intercalation compounds for producing fire-protection seals and method for their production
CN104558716A (en) * 2015-01-14 2015-04-29 四川大学 Efficient halogen-free flame retardant rubber system as well as preparation method thereof
CN105820793A (en) * 2016-05-24 2016-08-03 长春科英精益技术有限公司 Expansive type double-component fireproof sealant and preparation method thereof
CN106967264A (en) * 2017-05-20 2017-07-21 尹书祥 A kind of fire-proof expansion seal strip and preparation method thereof

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* Cited by examiner, † Cited by third party
Title
杨清芝: "《现代橡胶工艺学》", 30 August 1997 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112127780A (en) * 2020-10-19 2020-12-25 王小兰 Expansion sealing strip applied to fireproof space and preparation method thereof
CN115707754A (en) * 2021-08-18 2023-02-21 应急管理部四川消防研究所 Fireproof flame-retardant expandable sealant and preparation method thereof

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Application publication date: 20190312